载毒死蜱表面活性剂缔合体系形成规律及影响因素的研究
|
摘要
随着人们对环境保护及资源有效利用的重视,农药剂型也向着高效、安全、低毒、使用方便的方向发展。农药微乳液适应了这一发展的需要,研究微乳剂温度稳定性的影响因素,可提高微乳剂配制的科学性。此外,液晶相是微乳液体系相转变过程中的一种特殊状态,形成液晶体系的界面层存在明显的粘弹性,此种具有粘弹性的乳化剂体系能形成更稳定的乳状液。本论文以毒死蜱为研究对象,在已做工作的基础上,对表面活性剂缔合结构作为药物载体进行了进一步的研究。本论文主要研究了以下几个方面的内容:
1.研究了n-CnH2n+1OH(5≤n≤8)对微乳剂透明温度范围的影响。结果表明:n增大,混合表面活性剂含量增加,体系易于形成微乳;当醇种类及其含量一定时,混合表面活性剂配比对微乳剂的透明温度范围有较大影响;随醇含量增加,微乳剂的透明温度上限降低,下限略有增加;随n增大,透明温度范围上限温度基本升高,下限温度变化不规律。
2.研究了电解质对毒死蜱微乳剂透明温度范围的影响。研究发现:表面活性剂含量变化会影响到微乳剂的透明温度范围;随阳离子含量增加,体系的上限温度逐渐下降,下限温度变化相对较小。随阴离子含量增加,体系上限温度整体下降,趋势与阴离子的含量及结构类型有关,体系下限温度变化无规律性;在强酸性或强碱性溶液中,体系的上限温度均下降,且在弱酸性条件下,上限温度达最大值。体系下限温度随pH值的增加缓慢升高。
3.为探讨载毒死蜱液晶系形成规律,研究了有机溶剂种类、温度、正构醇碳数及无机盐对液晶相形成规律的影响。结果表明:苯(毒死蜱溶剂)环上取代基,有利于液晶“骨架”的形成及维持;高温导致液晶相形成及消失时,体系含水量均上升;随醇链的增长,体系形成液晶相所需最低含水量增加缓慢,而液晶相消失时的最高含水量则先上升后下降;添加无机盐,体系液晶相消失时所需最高含水量随阳离子水合半径降低而降低,说明液晶相结构易于破坏。
4.对液晶体系稳定性进行研究,结果显示:水含量的增加导致体系浊点下降。向体系中添加醇,发现两种水分含量下(30%、50%)体系的浊点随醇链长的变化趋势基本一致,即n≤5时,体系浊点变化较小,当碳链n>5后,浊点随碳链的增长明显降低。将样品稀释至10g并进行观察,发现碳链越长稀释后的粒径越大。对含正戊醇体系,正戊醇含量增加体系浊点下降,体系稀释后的粒径先变小后增大。
5.通过样品的偏光照片发现,随含水量增加体系液晶区微观结构的转变顺序为:层状及六角状—反相六角状—层状。加正戊醇体系微观结构的转变顺序不变,但转变点向含水量增加处移动。研究体系的粘度,发现粘度变化与相区转化有关,随含水的增加呈先上升后下降的趋势,高粘度出现在液晶区,最大值在含水量为33%处,此时为反六角状液晶,随后进入层状液晶区,粘度明显下降,此时体系的粘度受层间距的影响,层间距变大,粘度降低。此外,我们还研究发现25℃时含水量为50%的层状液晶体系为假塑性型流体。
With great attention pay to the environmental protection and efficient use of resources, the pesticide agent producing is developing to efficient, safe, low toxic and easy-to-use. Agro-microemulsion can meet the need. Studying the factors on the transparent temperature region of agro-microemulsion, we can develop the scientific of the microemulsion preparation. In addition, liquid crystal phase is the special stage in the microemulsion phase transition, the interface layer forming liquid crystal has obviously viscoelasticity, this viscoelastic systerm can form more stable emulsion. This thesis chose chlorpyrifos as the research object. On the base of the research we have done before, we did more research about surfactant aggregates as drug carrier. The following aspects were studied in this thesis:
1. Effects of n-CnH2n+1OH (5≤n≤8) on the transparent temperature region of chlorpyrifos microemulsion were investigated. The results showed that with the increasing of the n and the mixed surfactant content, the formation of microemulsion became easier;When the alcohol and its amount were known, the proportion of surfactants had a great influence on the transparent temperature region of the micro-emulsion; With the increasing of the alcohol content, the upper limit of the transparent temperature declined, and the lower limit of the transparent temperature increased slightly; With the increasing of n, the upper limit of transparent temperature increased mostly, but the changes of the lower limit of transparent temperature was in an irregular course.
2. Effects of electrolytes on the transparent temperature region of chlorpyrifos micro-emulsion were investigated. The results showed that the surfactant content could influence on the transparent temperature region of micro-emulsion; Adding electrolytes found with the increasing of cationic content, the upper limit of transparent temperature of mixed systems gradually decreased,the changes of the lower limit of transparent temperature were relatively slight. With the increasing of anionic content, the upper limit of transparent temperature decreased on the whole,and the tendency was related to the anionic content and the anionic structure types,the changes of the lower limit of transparent temperature had no laws; Both in strong acid and strong base solutions, the upper limit of transparent temperature both decreased, and in weak acid solutions the upper limit of transparent temperature reached a maximum. With the increasing of pH values, the lower limit of transparent temperature increased slightly.
3. Effects of organic solvents, temperature, n-alcohols and inorganic salt on the formation of liquid crystal phase were investigated to discuss the formation law of liquid crystal system loading chlorphyrifos. The results showed that the substituent in the phenyl ring was advantageous to the formation and maintenance of liquid crystal phase; The system water content rose when the liquid crystalline phase formed and vanished caused by high temperature; With the increasing of the chain length for n-alcohols, the minimum water content for the formation of liquid crystal increased slowly. But when the liquid crystal phase vanished, the maximum water content first rose, then dropped; Adding inorganic salt, the maximum water content needed for the disappearance of liquid crystal phase decreased with hydrated radius of positive ion decreasing, it showed that structure of liquid crystal was unstable.
4. Effects of stability of liquid crystal phase were investigated. The results showed that with the increasing of water content, the cloud point of system decreased; Adding n-CnH2n+1OH to the system, cloud point changed similarly with the changes of chain length under the different water content (30%、50%), that was to say when n less than or equal to 5, the changes of cloud point was less, but when n more than 5, the cloud point significantly decreased with the increasing of the chain length for n-alcohols. Diluted the sample to 10g and it was observed that after diluting the particle size of the emulsion increased with the increasing of the chain length for n-alcohols. For the system which contained n-pentanol, the cloud point decreased with the increasing of n-pentanol content, and the particle size of the emulsion after diluted first dropped, then rose.
5. By the investigation on the polarizing photos could find that with the water content increasing, the order of liquid crystal microstructure was lamellar liquid crystal and hexagonal liquid crystal; reversed phase hexagonal liquid crystal; lamellar liquid crystal. Adding n-pentanol, the convert order of liquid crystal microstructure did not change, but the convert point moved to the area containing more water. By researching the viscosity of the system, we found the change of viscosity had close relationships with the change of liquid crystal microstructure, with the increasing of the water content the viscosity first rose, then dropped, the high viscosity areas is in the liquid crystal phase. When the water content was 33%, the viscosity of system is the highest, its microstructure is reversed phase hexagonal liquid crystal, then the system came into lamellar liquid crystal, the viscosity significantly decreased. In the lamellar liquid crystal phase, the viscosity had close relationships with the spacing of layers, the viscosity decreased when the spacing of layers increased. Moreover, we found that, the lamellar liquid crystal system which contains 50% water in 25℃was pseudoplastic fluid.
1.研究了n-CnH2n+1OH(5≤n≤8)对微乳剂透明温度范围的影响。结果表明:n增大,混合表面活性剂含量增加,体系易于形成微乳;当醇种类及其含量一定时,混合表面活性剂配比对微乳剂的透明温度范围有较大影响;随醇含量增加,微乳剂的透明温度上限降低,下限略有增加;随n增大,透明温度范围上限温度基本升高,下限温度变化不规律。
2.研究了电解质对毒死蜱微乳剂透明温度范围的影响。研究发现:表面活性剂含量变化会影响到微乳剂的透明温度范围;随阳离子含量增加,体系的上限温度逐渐下降,下限温度变化相对较小。随阴离子含量增加,体系上限温度整体下降,趋势与阴离子的含量及结构类型有关,体系下限温度变化无规律性;在强酸性或强碱性溶液中,体系的上限温度均下降,且在弱酸性条件下,上限温度达最大值。体系下限温度随pH值的增加缓慢升高。
3.为探讨载毒死蜱液晶系形成规律,研究了有机溶剂种类、温度、正构醇碳数及无机盐对液晶相形成规律的影响。结果表明:苯(毒死蜱溶剂)环上取代基,有利于液晶“骨架”的形成及维持;高温导致液晶相形成及消失时,体系含水量均上升;随醇链的增长,体系形成液晶相所需最低含水量增加缓慢,而液晶相消失时的最高含水量则先上升后下降;添加无机盐,体系液晶相消失时所需最高含水量随阳离子水合半径降低而降低,说明液晶相结构易于破坏。
4.对液晶体系稳定性进行研究,结果显示:水含量的增加导致体系浊点下降。向体系中添加醇,发现两种水分含量下(30%、50%)体系的浊点随醇链长的变化趋势基本一致,即n≤5时,体系浊点变化较小,当碳链n>5后,浊点随碳链的增长明显降低。将样品稀释至10g并进行观察,发现碳链越长稀释后的粒径越大。对含正戊醇体系,正戊醇含量增加体系浊点下降,体系稀释后的粒径先变小后增大。
5.通过样品的偏光照片发现,随含水量增加体系液晶区微观结构的转变顺序为:层状及六角状—反相六角状—层状。加正戊醇体系微观结构的转变顺序不变,但转变点向含水量增加处移动。研究体系的粘度,发现粘度变化与相区转化有关,随含水的增加呈先上升后下降的趋势,高粘度出现在液晶区,最大值在含水量为33%处,此时为反六角状液晶,随后进入层状液晶区,粘度明显下降,此时体系的粘度受层间距的影响,层间距变大,粘度降低。此外,我们还研究发现25℃时含水量为50%的层状液晶体系为假塑性型流体。
With great attention pay to the environmental protection and efficient use of resources, the pesticide agent producing is developing to efficient, safe, low toxic and easy-to-use. Agro-microemulsion can meet the need. Studying the factors on the transparent temperature region of agro-microemulsion, we can develop the scientific of the microemulsion preparation. In addition, liquid crystal phase is the special stage in the microemulsion phase transition, the interface layer forming liquid crystal has obviously viscoelasticity, this viscoelastic systerm can form more stable emulsion. This thesis chose chlorpyrifos as the research object. On the base of the research we have done before, we did more research about surfactant aggregates as drug carrier. The following aspects were studied in this thesis:
1. Effects of n-CnH2n+1OH (5≤n≤8) on the transparent temperature region of chlorpyrifos microemulsion were investigated. The results showed that with the increasing of the n and the mixed surfactant content, the formation of microemulsion became easier;When the alcohol and its amount were known, the proportion of surfactants had a great influence on the transparent temperature region of the micro-emulsion; With the increasing of the alcohol content, the upper limit of the transparent temperature declined, and the lower limit of the transparent temperature increased slightly; With the increasing of n, the upper limit of transparent temperature increased mostly, but the changes of the lower limit of transparent temperature was in an irregular course.
2. Effects of electrolytes on the transparent temperature region of chlorpyrifos micro-emulsion were investigated. The results showed that the surfactant content could influence on the transparent temperature region of micro-emulsion; Adding electrolytes found with the increasing of cationic content, the upper limit of transparent temperature of mixed systems gradually decreased,the changes of the lower limit of transparent temperature were relatively slight. With the increasing of anionic content, the upper limit of transparent temperature decreased on the whole,and the tendency was related to the anionic content and the anionic structure types,the changes of the lower limit of transparent temperature had no laws; Both in strong acid and strong base solutions, the upper limit of transparent temperature both decreased, and in weak acid solutions the upper limit of transparent temperature reached a maximum. With the increasing of pH values, the lower limit of transparent temperature increased slightly.
3. Effects of organic solvents, temperature, n-alcohols and inorganic salt on the formation of liquid crystal phase were investigated to discuss the formation law of liquid crystal system loading chlorphyrifos. The results showed that the substituent in the phenyl ring was advantageous to the formation and maintenance of liquid crystal phase; The system water content rose when the liquid crystalline phase formed and vanished caused by high temperature; With the increasing of the chain length for n-alcohols, the minimum water content for the formation of liquid crystal increased slowly. But when the liquid crystal phase vanished, the maximum water content first rose, then dropped; Adding inorganic salt, the maximum water content needed for the disappearance of liquid crystal phase decreased with hydrated radius of positive ion decreasing, it showed that structure of liquid crystal was unstable.
4. Effects of stability of liquid crystal phase were investigated. The results showed that with the increasing of water content, the cloud point of system decreased; Adding n-CnH2n+1OH to the system, cloud point changed similarly with the changes of chain length under the different water content (30%、50%), that was to say when n less than or equal to 5, the changes of cloud point was less, but when n more than 5, the cloud point significantly decreased with the increasing of the chain length for n-alcohols. Diluted the sample to 10g and it was observed that after diluting the particle size of the emulsion increased with the increasing of the chain length for n-alcohols. For the system which contained n-pentanol, the cloud point decreased with the increasing of n-pentanol content, and the particle size of the emulsion after diluted first dropped, then rose.
5. By the investigation on the polarizing photos could find that with the water content increasing, the order of liquid crystal microstructure was lamellar liquid crystal and hexagonal liquid crystal; reversed phase hexagonal liquid crystal; lamellar liquid crystal. Adding n-pentanol, the convert order of liquid crystal microstructure did not change, but the convert point moved to the area containing more water. By researching the viscosity of the system, we found the change of viscosity had close relationships with the change of liquid crystal microstructure, with the increasing of the water content the viscosity first rose, then dropped, the high viscosity areas is in the liquid crystal phase. When the water content was 33%, the viscosity of system is the highest, its microstructure is reversed phase hexagonal liquid crystal, then the system came into lamellar liquid crystal, the viscosity significantly decreased. In the lamellar liquid crystal phase, the viscosity had close relationships with the spacing of layers, the viscosity decreased when the spacing of layers increased. Moreover, we found that, the lamellar liquid crystal system which contains 50% water in 25℃was pseudoplastic fluid.
引文
1.安娅,徐军,张晋. Brij35/油酸钠/油酸/水体系的溶致液晶性质[J].中国科学B辑化学2006,36(3):234-243.
2.陈福良,田慧琴,王仪,等.农药微乳液稳定性研究[J].农药学学报,2005,7(1):63-68.
3.程敬丽,黄雅丽,朱国念.30%毒死蜱水乳剂的研究和开发[J].农药, 2002,43(8):15-17.
4.曹泉,于丽,孙立新,等.由碳酸钠诱导形成的油酸钠蠕虫状胶束的流变学性质[J].化学学报. 2007,65(17):1821-1825.
5.陈庆春,邓慧宇,马燕明,等.添加剂对聚乙二醇辛基苯基醚浊点的影响[J].华东地质大学学报,2003,26(3):284-286.
6.曹同玉,刘庆普,胡金生.聚合物乳液合成原理性能及应用[M].北京:化学工业出版社,1999.
7.崔正刚,殷福珊.微乳化技术及应用[M].北京:中国轻工业出版社,1999:311～319.
8.戴乐荣,卜林涛.离子型与非离子型混合表面活性剂体系溶致液晶相图及结构的研究[J].北京大学学报,1999,35(2):138-147.
9.方云,沈晓勤,陆婕.助乳化机对化妆品乳液稳定性和液晶性的影响[J].日用化学工业,2002,32(1):8-11.
10.冯尚华,王红霞,张高勇,等.NP-10/硝酸钠水溶液体系层状液晶的流变性[J].日用化学工业.2004,34(3):147-150.
11.冯尚华,王红霞,张高勇,等.表面活性剂溶致液晶的流变学性质.化学进展. 2004,16(5):688-695.
12.冯尚华,王红霞.温度对两种不同立方相液晶流变性的影响[J].精细化工. 2006,23(9):863-866.
13.龚福忠,周立亚,李成海. OP-7/醇/正庚烷/HCl体系形成微乳液的势力学性质研究[J].广西大学学报,2000,25(4):271-275.
14.顾强,李干佐,苑世领.添加剂对非离子表面活性剂DYNOL-604浊点的影响[J].日用化学品科学,1999(8):40-43.
15.郭荣,张晓红,刘天晴. Igepal CO 520/CnH2n+1OH/H2O体系的相行为与结构特性[J].物理化学学报.1999,15(4):319-326.
16.郭荣,于卫里,张晓红.维生素C对表面活性剂体系项行为的影响[J]. 2000,16(4):325-330.
17.郭睿劼，张宝泉，孙远，等.溶致液晶及其在纳米结构材料合成中的应用.化学进展,2007,19(1):1695-1702.
18.郝京诚,黄建滨,徐桂英,等.两亲分子溶液聚集体结构的冷冻刻蚀电子显微镜研究[J].中国科学(B辑),2003,33(4):273-279.
19.胡尚林,黄龙,戴乐蓉.正、负离子表面活性剂混合体系溶致液晶生成的相行为[J].物理化学学报,2001,17(8):692一695.
20.侯震山,李之平,汪汉卿,等.油、水和混合表面活性剂“混相体系”的超低界面张力[J],化学研究与应用,2000,12(4):383—386.
21.蒋绪川,杨永会,孙思修,等. NaDEHP/醇/正庚烷/水微乳液体系的结构参数研究[J].山东大学学报,1998,33(4):422-426.
22.刘程,米裕民.表面活性剂性质理论与应用[M],北京:工业大学出版社,2003:160～203.
23.吕锋锋,候天江,刘杰,等.一种新型表面活性剂的表面活性的研究[J].化学学报,2003,61(11):1747-1751.
24.李干佐,顾强. AEO-9体系溶致液晶性能及其组成方程[J].化学学报,2001,59(1):6-10.
25.李干佐,肖洪地,李英.溶致液晶体系研究及其在三次采油中的应用[J].高等学校化学学报,2001,22(1):108-111.
26.李干佐,刘杰,吕锋锋,等.非离子表面活性剂吐温80的复合驱油体系研究[J].日用化学工业,2003,33(1):1-7.
27.刘杰,刘少杰,吕锋锋,等.微乳液体系作为药物载体的研究进展[D],日用化学工业,2004,34(2):1-4.
28.林嘉平,周达飞.分子链构象变化对高分子液晶相行为的影响[J].高分子学报,1999,8(4):436-443.
29.刘建平,郑玉斌.高分子科学与材料工程实验[M].北京:化学工业出版社,2005:31-32.
30.李丽芳,王开运,宋东升,等.农药微乳液中阴/非离子复合表面活性剂作用机理研究[J],农药,2008,47(2):100-102.
31.李娜,刘少杰,吕锋锋,等. C9FK的表面活性测定[J].精细化工,2005,22(12):62-66.
32.梁文平.表面活性剂及其在分散体系中的应用[J].日用化学工业,1999,22(1):7～11.
33.李学静,Christian Quellet,Claire Vautrin,等.层状液晶乳液的相行为[J].应用化学.2006,23(11):1152-1155.
34.刘小键,王迎军,魏坤,等. MAP-乙醇-三元相图的绘制及其在纳米羟基磷灰石制备中的应用[J].硅酸盐通报,2007,26(1):1-4.
35.陆杨燕,夏勇,等.载药微乳液相行为研究[J].物理化学学报,2005,21(1):98-101.
36.刘志俊.农药剂型加工新进展[J].农药,1993,32(2):44～46.
37.孟凡宝,廉娇,高永梅.含氟液晶研究进展[D].化学进展,2008,20(4):499-507.
38.马利静,周卯星,敬登伟,等.温度及无机盐对LMEE和SDS混合溶液表面张力的影响[J].精细化工,2004,21(2):108-111.
39.莫小刚,刘尚营.非离子表面活性剂浊点的研究进展[J].化学通报, 2001(8):483-487.
40.南延青,郝力生.卤化盐对CRTAB-AS-H2O复配体系相行为的影响[J].湖南师范大学自然科学学报,2005,28(3):48-51.
41.任智,陈志荣.表面活性剂结构与乳液稳定性之间关系研究[J].浙江大学化学学报,2003,37(1):78-81.
42.孙华,路福绥,李培强,赵辉.氰戊菊酯微乳剂形成规律的研究[J].农药,2004,43(12):547～548.
43.沈吉静,赵振国,马季铭.微乳在有机反应中的应用[J].化学通报, 1998,21(1):11-18.
44.水玲玲,郑利强,赵剑曦,等.双子表面活性剂体系的界面活性研究[J].精细化工,2001,18(2):67-82.
45.邵庆辉,古国榜,章莉娟等.微乳液系统的研究和应用现状与展望[J] .江苏化工,2002,30(1):18～27.
46.滕弘霓,孙艳芝,周帆,等. pH及有机小分子物质对SDS/CTAB/H2O系统双水相性质的影响[J].物理化学学报,2002,14(6):659-692.
47.滕弘霓,孙美娟,王利.混合表面活性剂水溶液的浊点性质[J].化学研究与应用,2004,2(16):239-240.
48.王红霞,陆用海.碳酸钠对烷基磺酸钠/脂肪醇聚氧乙烯醚/H2O体系相行为和流变性的影响[J].物理化学学报,2001,6(1):1-4.
49.王红霞,张高勇.硝酸银及其产物银对六角相液晶流变性影响[J].化学学报,2003,61(1):40-46.
50.王红霞,张高勇,刘滇生,等.层状液晶的小振幅振荡频率扫描研究[J].物理化学学报,2005,21(12):1411-1414.
51.吴锦屏,顾惕人.非离子表面活性剂的雾点研究-电解质的影响[J].物理化学学报,1996,12(11):965-967.
52.王任芳,李克群,李军.无机盐对原油破乳剂破乳效果的影响[J].石油炼制与化工,1999,30(2):60-64.
53.王寿武.无机盐对多组分表面活性剂粘度效应的研究[J],海湖盐与化工,2004,33(2):32—34.
54.完茂林,鲁传华,张玉莲.醇的链长对非离子表面活性剂微乳增溶水量的影响研究[J].安徽大学学报,2007,34(4):74-76.
55.王玉东,傅经过.作为药物载体新型微乳液的研究[D].郑州大学, 2006,16(1):1-79.
56.王仲妮,李干佐,张高勇.表面活性剂缔合结构作为药物载体的研究进展[J].自然科学进展,2004,14(11):1209-1214.
57.王志宁,郑利强,李干佐.蔗糖对MO/水立方液晶体系流变性质的影响[J].化学学报,2005,63(4):274-278.
58.王志宁,郑利强.类脂立方液晶作为药物载体的研究[J].化学进展,2005,17(3):812-224.
59.徐健,李干佐,翟利民,等.脉冲梯度场自旋回波NMR和TEM研究微乳液的微观结构[J].科学通报,2001,46(6):466-470.
60.肖进新,赵振国.表面活性剂应用原理[M],北京:化学工业出版社, 2003:133.
61.夏立新,曹国英,陆世维,等.原油乳状液稳定性和破乳研究进展[J].化学研究与应用,2002,14(6):623-627.
62.杨丽珍,赵贤淑,孙文贤.非离子表面活性剂在油溶液中的流变性质[J].日用化学工业,2000,5(1):6-8.
63.苑世领,冯大诚,徐桂英,等.用定量结构关系预测表面活性剂的krafft点[J].结构化学,2003,22(7):739-742.
64.曾红霞,李之平,汪汉卿.十二烷基硫酸钠多相微乳液的研究[J].化学学报. 1999,57(1):1055-1061.
65.曾红霞,李之平,王敏,等.十二烷基硫酸钠中相微乳液的液晶结构[J].物理化学学报,2000,16(1):60-64.
66.赵国玺,朱埗瑶.表面活性剂作用原理[M].中国轻工业出版社,2003: 68.
67.赵辉,路福绥,李培强,等.醇对高效氯氟氰菊酯微乳液相图的影响[J].应用化学,2006,23(5):503-507.
68.赵辉,路福绥,李培强,等.三氟氯氰菊酯微乳剂配方筛选及形成规律[J].农药,2005,44(12):546～548.
69.张国栋,陈晓,靖波.温室离子液体中的有序分子组合体[J].化学进展,2006,18(9):1085-1091.
70.张晋,刘少杰,郑利强,等.表面活性剂在药物制剂中的应用及其与药物分子之间的相互作用[J].山东大学学报(理学版),2006,41(4):131-136.
71.张晓红,郭荣,刘天晴. Igepal CO系列表面活性剂溶致液晶的结构[J].物理化学学报,1999,15(1):57-63.
72.张晓光,张高勇,王红霞,等.农药微乳液相行为及微乳结构的研究[J].精细化工,2003,20(8):475-477.
73.张松梅,娄清香,毛国梁.阴离子聚电解质与阴离子表面活性剂大分子复合物的形成及其溶液流变性能[J].化学世界,2005,2(1):79-82.
74.周兰芳,傅绍斌,徐亚双,等.无机盐对非离子表面活性剂水溶液的雾点影响[J].江汉石油学院学报,1998,20(4):66-70.
75.朱森,程发,郑宝江,等. Geminni阴离子表面活性剂水溶液的聚集性质[J].高等化学学报,2004,20(10):1245-1248.
76. A. Cid-Samamed, L. Garcia-Rio, D. Fernandez-Gandara, et al. Influence of n-alkylacids on the percolative phenomena in AOT-based microemulsions [J]. Journal of Colloid and Interface Science, 2008, 318(1):525-529.
77. Anna Imberg. On the microstructures of ethyl acetate/monoolein/water [J]. Colloid and Surfaces B: Biointerfaces, 2006, 53(2):233-240.
78. A ttwood D. Colloid drug delivery system s. Drug Pharm SciSer [M]. New York: M arcel Dekker, 1994:31-71.
79. Babette Biruss, Claudia Valenta. The advantage of polymer addition to a non-ionic oil in water microemulsion for the dermal delivery of progesterone [J]. International Journal of Pharmaceutics, 2008, 349:269-273.
80. Ben J. Boyd, Darryl V. Whittaker, Shui-Mei Khoo, et al. Lyotropic liquid crystalline phases formed from glycerate surfactants as sustained release drug delivery system [J]. International Journal of Pharmaceutics,2006, 309:218-226.
81. Bin Lin, Alon V. McCormick, H. Ted Davis,et a l. Solubility of Sodium Soaps in Aqueous Salt Solutions [J]. J Colloid and Interface Sci, 2005, 291: 543-549.
82. BoutonnetM,K izling J, Stenins P etal.The preparation of monodisperse colloidal metal particles rommi croemulsion [J]. Colloids and Surfaces, 1982, 212(5):209.
83. Bourel M and Schechter R S. Surfactant Science Series [M]. Plenum Press, NewYork, 1988.
84. Carlos Rodriguez-Abreu, Massimo Lazzari. Emulsions with structured continuous phases [J]. Current Opinion in Colloid and Interface Science. 2007:1-8.
85. Chhater A S,Joshi R A, K alkarni B D. M icroem ulsions as media fororganic synthesis: selective N itration ofphenolto ortho-N itropheno lu- sing Dilute Nitric Acid [J]. J Colloid Interface Sci,1993, 158(11):183-187.
86. Chunsheng Mo, Xiaoge Li. Microstructure and structural transition in coconut oil microemulsion using semidifferential electroanalysis [J]. Journal of Colloid and Interface Science, 2007, 312:355-362.
87. Debolina Mitra, Subhas C, Bhattacharya, et al. ALB film morphological study with reference to biopolymer-surfactant interaction taking gelatin-CTAB system as a model [J]. Biophysical Chemistry, 2009, 139:123-136.
88. Donglin Li, Daisuke Fujikawa, Takumi Yoshimura, et al. Additive-stabilizedhexagonally ordered mixed lyotropic liquid crystal [J]. Journal of Molecular Liquids, 2008, 138:113-119.
89. Elena Blanco, Juan M. Ruso, Gerardo Prieto, et al. On relationships between surfactant type and globular proteins interactions in solution [J]. Journal of Colloid and Interface Science, 2007, 316:37-42.
90. E. Jurado, V. Bravo, J. M. Vicaria, et al. Triolein solubilization using highly biodegradable non-ionic surfactants [J]. Colloids and Surfaces A: Physicochem, Eng. Aspects, 2008:3-7.
91. Engstrom S. Cubic phases as drug delivery systems [J]. Polymer Preprint, 1990, 31(2):157-158.
92. Frederic Marchal, Veronique Nardello-Rataj, Nelly Chailloux, et al. Lyotropic liquid crystal behaviour of azelate and succinate monoester surfactants based on fragrance alcohols [J]. Journal of Colloid and Interface Science, 2008, 21: 177-185.
93. Guangqiang Zhao, Shing Bor Chen. Nonlinear rheology of aqueous solutions of hydrophobically modified hydroxyethyl cellulose with nonionic surfactant [J]. Journal of Colloid and Interface Science, 2007, 316:858-866.
94. Guodong Zhang, Xiao Chen, Yizhou Xie, et al. Lyotropic liquid crystalline phases in a ternary system of 1-hexadecyl-3- methylimidazolium chloride/ 1-decanol /water [J]. Journal of Colloid and Interface Science, 2007, 315: 601-606.
95. H. Matsubara, H. Obata, T. Matsuda, et al. Surface adsorption and aggregate formation of aqueous binary mixture of cationic surfactant and sugar surfactant [J]. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 315:183-188.
96. Jedrzej Szymanski, Agnieszka Wilk, Robert Holyst, et al. Micro- and macro-shear viscosity in dispersed lamellar phases [J]. J.Non-Newtonian Fluid Mech, 2008, 148:134-140.
97. Jin Zhang, Bin Dong, Liqiang Zheng, et al. Lyotropic liquid crystalline phases formed in ternary mixtures of 1-cetyl-3-methylimidazolium bromide/p-xylene /water: A SAXS, POM, and rheology study [J]. Journal of Colloid and Interface Science, 2008, 321:159-165.
98. J.L. Blin, R. Bleta, M.J. Stebe. Cloud point curve of nonionic surfactant related tothe structures of mesoporous materials [J]. Journal of Colloid and Interface Science, 2006, 300:765-773.
99. J.Th.G.OverbeeK, G.J.Verhoeckx, P.L. Bruyn and H.N.W. Lecker, J. CoIloid Interface Sci [J]. Journal of Colloid and Interface Science, 1987, 19:422-427.
100. J.Th.G.Overbeek, Faraday Disc. Chem.Soc [J], Journal of Colloid and Interface Science, 1978, 65:7-15.
101. KABIR. MD H, ARAMAKI. K, ISHITOBI. M, et al. Cloud point and formation of microemulsions in sucrose dodecanoate systems [J]. Colloids and Surfaces, 2003, 21(6): 65-74.
102. Katarzyna Zielinska, Kazimiera A. Wilk, Adam Jezierski, et al. Microstructure and structural transition in microemusions stabilized by aldonamide-type surfactants [J]. Journal of Colloid and Interface Science, 2008, 321:408-417.
103. Kishida M., Fujita T., Umakoshik, et al. Novel preparation of metal- supported catalysts by colloilalm icroparticles in a water-in-oil microe- mulsion catalytic-hydrogenation of carbon-dioxide [J]. J chem soc chem com m, 1995, 11(7):763-764.
104. K. Shivaji Sharma, P.A. Hassan, Animesh K. Rakshit. Surface acticity and association behavior of nonaoxyethylene n-dodecylether in aquo amino acid medium: Tensiometry, small-angle neutron scattering, dynamic light scattering and viscosity studies [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 308:100-110.
105. Md. Hamidul Kabir, Kenji Aramaki, Masahiko Ishitobi, et al. Cloud Point and Formation of Microemulsions in Sucrose Dodecanoate Systems[J]. Colloids and Surfaces, 2003, 216: 65-74.
106. Meller A. Stavans J. Stability of emulsion with nonadsorbing polymers [J]. Langmuir, 1996, 12(2):301-304.
107. MITRA. R K, PAUL.B K, Effect of NaCl and temperature on the water solubilization behavior of AOT/nonionics mixed reverse micellar systems stabilized in IPM oil [J]. Colloids and Surfaces A: Physicochem. Eng, 2005, 255: 165-180.
108. Monzer Fanun. Phase behavior, transport, diffusion and structural parameters of nonionic surfactants microemulsions [J]. Journal of Molecular Liquids, 2007:1-9.
109. Monzer Fanun. Structure probing of water/mixed nonionic surfactants/ caprylic-capric triglyceride system using conductivity and NMR [J]. Journal of Molecular Liquids, 2007, 133:22-27.
110. Monzer Fanun. Conductivity, viscosity, NMR and diclofenac solubilization capacity studies of mixed nonionic surfactants microemulsions [J]. Journal of Molecular Liquids, 2007, 135:5-13.
111. Na Li, Jie Liu, Xueyan Zhao, et al. Complex formation of ionic liquid surfactant and cyclodextrin [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 292:196-201.
112. Nina Vlachy, Markus Drechsler, Jean-Marc Verbavatz, et al. Role of the surfactant headgroup on the counterion specificity in the micelle-to-vesicle transition through salt addition [J]. Journal of Colloid and Interface Science, 2007:1-7.
113. Nissim Garti, Marganit Avrahami, Abraham Aserin. Improved solubilization of Celecoxib in U- type nonionic microemulsions and their structural transitions with progressive aqueous dilution [J]. Journal of Colloid and Interface Science, 2006, 299: 352-365.
114. Prince L.M.A. Colloid Inter Sci [J].1969, 29:2166.
115. Prince L.M. Microemulsions Theory and Practice [M]. New York: Academic Press, 1977:83-88.
116. Qiang Xia, Xiaozheng Hao, Yangyan Lu, et al. Production of drug-loaded lipid nanoparticles based on phase behaviors of special hot microemulsions [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314:27-30.
117. R. Efrat, A. Aserin, N. Garti. On structural transitions in a discontinuous micellar cubic phase loaded with sodium diclofenac [J]. Journal of Colloid and Interface Science, 2008:1-11.
118. Rivka Efrat, Abraham Aserin, Ellina Kesselman, et al. Liquid micellar discontinuous cubic mesophase from ternary monoolein/ethanol/water mixtures [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 299:133-145.
119. Rodrigo Montecinos, Hernan Ahumada, Victor E.Bahamonde-Padilla, et al. Counterion and composition effects on discotic nematic lyotropic liquid crystals [J].Journal of Colloid and Interface Science, 2007, 316:120-125.
120. Sadhale Y, Shah J C, Stabilization of insulin against agitation-induced aggregation by the GMO cubic phase gel [J]. Intermational J Pham, 1999, 191 (1):51-64.
121. Sadhale Y, Shah J C, Biological activity of insulin in GMO gels and the effect of agitation [J]. Int J Pham, 1999, 191 (1):65-74.
122. S.B. Rizwan, Y.-D. Dong, B.J. Boyd, et al. Characterisation of bicontinuous cubic liquid crystalline systems of phytantriol and water using cryo field emission scanning electron microscopy (cryo FESEM) [J]. Micron, 2007, 38:478-485.
123. Schulman J.H, et al. Mechanism of formation and structure of microem- ulsions by electron microscopy [J]. Phys Chem, 1959, 63(10):1677.
124. S.K.Mehta, Shweta Sharma. Temperature-induced percolation behavior of AOT reverse micelles affected by poly (ethylene glycol) s [J]. Journal of Colloid and Interface Science, 2006, 296:690-699.
125. S.M. Ramaraju, B.J. Carroll, J.G. Chambers, et al. The liquid crystalline phases formed by linear-dodecylbenzene sulphonic acid during neutralization with sodium carbonate [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2006, 288:77-85.
126. T.P.Hoar and J.H.Schulman, Nature, 1943, 152:102.
127. Tsuyoshi Kijima, Yuki Nishida, Daisuke Fujikawa, et al. Long-chain alcohol induced phase transition in lyotropic mixed polyoxyethylene-type surfactant liquid-crystals [J]. Journal of Molecular Liquid, 2007, 133:54-60.
128. V, G, Gailar, K.V. Padalkar, V.K. Aswal. Characterization of mixed micelles of structural isomers of sodium butyl benzene sulfonate and sodium dodecyl sulfate by SANS, FTIR spectroscopy and NMR spectroscopy [J]. Journal of Molecular Liquids, 2008, 138:155-167.
129. Wei liu, Wei-jun Zhao, Jian-bo Chen, et al. A cloud point extraction approach using Trition X-100 for the separation and preconcentration of Sudan dyes in chilli powder [J]. Analytica Chimica Acta, 2007, 605:41-45.
130. Wenchang Zhuang, Xiao Chen, Jinguang Cai, et al. Characterization of lamellar phases fabricated from Brij-30/water/1-butyl-3-methylimida- zolium salts ternary systems by small-angle X-ray scattering [J]. Colloid and Surfaces A: Physicochem.Eng. Aspects, 2008:1-9.
131. WANG Li-juan, LI Xue-fen, ZHANG Gao-yong, et al. Oil-in-water nanoemulsions for pesticide formulations [J]. Journal of Colloid and Interface Science, 2007, 314 (1): 230-235.
132. Xiaoguang Zhang, Jinfeng Dong, Gaoyong Zhang, et al. The effect of additives on the water solubilization capacity and conductivity in n-pentanol microemulsions [J]. Journal of Colloid and Interface Science, 2005, 285:336-341.
133. Yanan Gao, Suqing Wang, Liqiang Zheng, et al. Microregion detection of ionic liquid microemulsions [J]. Journal of Colloid and Interface Science, 2006, 301:612-616.
134. Yuji Yamashita, Hironobu Kunieda, Eiko Oshimura, et al. Formation of intermediate micellar phase between hexagonal and discontinuous cubic liquid crystals in brine/N-acylamino acid surfactant/ N-acylamino acid oil syetem [J]. Journal of Colloid and Interface Science, 2007, 312:172-178.
135. Yuksel Bayrak, Mehmet Iscan. Studies on the phase behavior of the system non-ionic surfactant/alcohol/alkane/H2O [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2005, 268:99-103.
136.Zhongni Wang, Wu Zhou, Ganzuo Li. Ternary cubic phases containing ionic liquid [J]. Journal of Colloid and Interface Science, 2008, 318:405-410.
2.陈福良,田慧琴,王仪,等.农药微乳液稳定性研究[J].农药学学报,2005,7(1):63-68.
3.程敬丽,黄雅丽,朱国念.30%毒死蜱水乳剂的研究和开发[J].农药, 2002,43(8):15-17.
4.曹泉,于丽,孙立新,等.由碳酸钠诱导形成的油酸钠蠕虫状胶束的流变学性质[J].化学学报. 2007,65(17):1821-1825.
5.陈庆春,邓慧宇,马燕明,等.添加剂对聚乙二醇辛基苯基醚浊点的影响[J].华东地质大学学报,2003,26(3):284-286.
6.曹同玉,刘庆普,胡金生.聚合物乳液合成原理性能及应用[M].北京:化学工业出版社,1999.
7.崔正刚,殷福珊.微乳化技术及应用[M].北京:中国轻工业出版社,1999:311～319.
8.戴乐荣,卜林涛.离子型与非离子型混合表面活性剂体系溶致液晶相图及结构的研究[J].北京大学学报,1999,35(2):138-147.
9.方云,沈晓勤,陆婕.助乳化机对化妆品乳液稳定性和液晶性的影响[J].日用化学工业,2002,32(1):8-11.
10.冯尚华,王红霞,张高勇,等.NP-10/硝酸钠水溶液体系层状液晶的流变性[J].日用化学工业.2004,34(3):147-150.
11.冯尚华,王红霞,张高勇,等.表面活性剂溶致液晶的流变学性质.化学进展. 2004,16(5):688-695.
12.冯尚华,王红霞.温度对两种不同立方相液晶流变性的影响[J].精细化工. 2006,23(9):863-866.
13.龚福忠,周立亚,李成海. OP-7/醇/正庚烷/HCl体系形成微乳液的势力学性质研究[J].广西大学学报,2000,25(4):271-275.
14.顾强,李干佐,苑世领.添加剂对非离子表面活性剂DYNOL-604浊点的影响[J].日用化学品科学,1999(8):40-43.
15.郭荣,张晓红,刘天晴. Igepal CO 520/CnH2n+1OH/H2O体系的相行为与结构特性[J].物理化学学报.1999,15(4):319-326.
16.郭荣,于卫里,张晓红.维生素C对表面活性剂体系项行为的影响[J]. 2000,16(4):325-330.
17.郭睿劼，张宝泉，孙远，等.溶致液晶及其在纳米结构材料合成中的应用.化学进展,2007,19(1):1695-1702.
18.郝京诚,黄建滨,徐桂英,等.两亲分子溶液聚集体结构的冷冻刻蚀电子显微镜研究[J].中国科学(B辑),2003,33(4):273-279.
19.胡尚林,黄龙,戴乐蓉.正、负离子表面活性剂混合体系溶致液晶生成的相行为[J].物理化学学报,2001,17(8):692一695.
20.侯震山,李之平,汪汉卿,等.油、水和混合表面活性剂“混相体系”的超低界面张力[J],化学研究与应用,2000,12(4):383—386.
21.蒋绪川,杨永会,孙思修,等. NaDEHP/醇/正庚烷/水微乳液体系的结构参数研究[J].山东大学学报,1998,33(4):422-426.
22.刘程,米裕民.表面活性剂性质理论与应用[M],北京:工业大学出版社,2003:160～203.
23.吕锋锋,候天江,刘杰,等.一种新型表面活性剂的表面活性的研究[J].化学学报,2003,61(11):1747-1751.
24.李干佐,顾强. AEO-9体系溶致液晶性能及其组成方程[J].化学学报,2001,59(1):6-10.
25.李干佐,肖洪地,李英.溶致液晶体系研究及其在三次采油中的应用[J].高等学校化学学报,2001,22(1):108-111.
26.李干佐,刘杰,吕锋锋,等.非离子表面活性剂吐温80的复合驱油体系研究[J].日用化学工业,2003,33(1):1-7.
27.刘杰,刘少杰,吕锋锋,等.微乳液体系作为药物载体的研究进展[D],日用化学工业,2004,34(2):1-4.
28.林嘉平,周达飞.分子链构象变化对高分子液晶相行为的影响[J].高分子学报,1999,8(4):436-443.
29.刘建平,郑玉斌.高分子科学与材料工程实验[M].北京:化学工业出版社,2005:31-32.
30.李丽芳,王开运,宋东升,等.农药微乳液中阴/非离子复合表面活性剂作用机理研究[J],农药,2008,47(2):100-102.
31.李娜,刘少杰,吕锋锋,等. C9FK的表面活性测定[J].精细化工,2005,22(12):62-66.
32.梁文平.表面活性剂及其在分散体系中的应用[J].日用化学工业,1999,22(1):7～11.
33.李学静,Christian Quellet,Claire Vautrin,等.层状液晶乳液的相行为[J].应用化学.2006,23(11):1152-1155.
34.刘小键,王迎军,魏坤,等. MAP-乙醇-三元相图的绘制及其在纳米羟基磷灰石制备中的应用[J].硅酸盐通报,2007,26(1):1-4.
35.陆杨燕,夏勇,等.载药微乳液相行为研究[J].物理化学学报,2005,21(1):98-101.
36.刘志俊.农药剂型加工新进展[J].农药,1993,32(2):44～46.
37.孟凡宝,廉娇,高永梅.含氟液晶研究进展[D].化学进展,2008,20(4):499-507.
38.马利静,周卯星,敬登伟,等.温度及无机盐对LMEE和SDS混合溶液表面张力的影响[J].精细化工,2004,21(2):108-111.
39.莫小刚,刘尚营.非离子表面活性剂浊点的研究进展[J].化学通报, 2001(8):483-487.
40.南延青,郝力生.卤化盐对CRTAB-AS-H2O复配体系相行为的影响[J].湖南师范大学自然科学学报,2005,28(3):48-51.
41.任智,陈志荣.表面活性剂结构与乳液稳定性之间关系研究[J].浙江大学化学学报,2003,37(1):78-81.
42.孙华,路福绥,李培强,赵辉.氰戊菊酯微乳剂形成规律的研究[J].农药,2004,43(12):547～548.
43.沈吉静,赵振国,马季铭.微乳在有机反应中的应用[J].化学通报, 1998,21(1):11-18.
44.水玲玲,郑利强,赵剑曦,等.双子表面活性剂体系的界面活性研究[J].精细化工,2001,18(2):67-82.
45.邵庆辉,古国榜,章莉娟等.微乳液系统的研究和应用现状与展望[J] .江苏化工,2002,30(1):18～27.
46.滕弘霓,孙艳芝,周帆,等. pH及有机小分子物质对SDS/CTAB/H2O系统双水相性质的影响[J].物理化学学报,2002,14(6):659-692.
47.滕弘霓,孙美娟,王利.混合表面活性剂水溶液的浊点性质[J].化学研究与应用,2004,2(16):239-240.
48.王红霞,陆用海.碳酸钠对烷基磺酸钠/脂肪醇聚氧乙烯醚/H2O体系相行为和流变性的影响[J].物理化学学报,2001,6(1):1-4.
49.王红霞,张高勇.硝酸银及其产物银对六角相液晶流变性影响[J].化学学报,2003,61(1):40-46.
50.王红霞,张高勇,刘滇生,等.层状液晶的小振幅振荡频率扫描研究[J].物理化学学报,2005,21(12):1411-1414.
51.吴锦屏,顾惕人.非离子表面活性剂的雾点研究-电解质的影响[J].物理化学学报,1996,12(11):965-967.
52.王任芳,李克群,李军.无机盐对原油破乳剂破乳效果的影响[J].石油炼制与化工,1999,30(2):60-64.
53.王寿武.无机盐对多组分表面活性剂粘度效应的研究[J],海湖盐与化工,2004,33(2):32—34.
54.完茂林,鲁传华,张玉莲.醇的链长对非离子表面活性剂微乳增溶水量的影响研究[J].安徽大学学报,2007,34(4):74-76.
55.王玉东,傅经过.作为药物载体新型微乳液的研究[D].郑州大学, 2006,16(1):1-79.
56.王仲妮,李干佐,张高勇.表面活性剂缔合结构作为药物载体的研究进展[J].自然科学进展,2004,14(11):1209-1214.
57.王志宁,郑利强,李干佐.蔗糖对MO/水立方液晶体系流变性质的影响[J].化学学报,2005,63(4):274-278.
58.王志宁,郑利强.类脂立方液晶作为药物载体的研究[J].化学进展,2005,17(3):812-224.
59.徐健,李干佐,翟利民,等.脉冲梯度场自旋回波NMR和TEM研究微乳液的微观结构[J].科学通报,2001,46(6):466-470.
60.肖进新,赵振国.表面活性剂应用原理[M],北京:化学工业出版社, 2003:133.
61.夏立新,曹国英,陆世维,等.原油乳状液稳定性和破乳研究进展[J].化学研究与应用,2002,14(6):623-627.
62.杨丽珍,赵贤淑,孙文贤.非离子表面活性剂在油溶液中的流变性质[J].日用化学工业,2000,5(1):6-8.
63.苑世领,冯大诚,徐桂英,等.用定量结构关系预测表面活性剂的krafft点[J].结构化学,2003,22(7):739-742.
64.曾红霞,李之平,汪汉卿.十二烷基硫酸钠多相微乳液的研究[J].化学学报. 1999,57(1):1055-1061.
65.曾红霞,李之平,王敏,等.十二烷基硫酸钠中相微乳液的液晶结构[J].物理化学学报,2000,16(1):60-64.
66.赵国玺,朱埗瑶.表面活性剂作用原理[M].中国轻工业出版社,2003: 68.
67.赵辉,路福绥,李培强,等.醇对高效氯氟氰菊酯微乳液相图的影响[J].应用化学,2006,23(5):503-507.
68.赵辉,路福绥,李培强,等.三氟氯氰菊酯微乳剂配方筛选及形成规律[J].农药,2005,44(12):546～548.
69.张国栋,陈晓,靖波.温室离子液体中的有序分子组合体[J].化学进展,2006,18(9):1085-1091.
70.张晋,刘少杰,郑利强,等.表面活性剂在药物制剂中的应用及其与药物分子之间的相互作用[J].山东大学学报(理学版),2006,41(4):131-136.
71.张晓红,郭荣,刘天晴. Igepal CO系列表面活性剂溶致液晶的结构[J].物理化学学报,1999,15(1):57-63.
72.张晓光,张高勇,王红霞,等.农药微乳液相行为及微乳结构的研究[J].精细化工,2003,20(8):475-477.
73.张松梅,娄清香,毛国梁.阴离子聚电解质与阴离子表面活性剂大分子复合物的形成及其溶液流变性能[J].化学世界,2005,2(1):79-82.
74.周兰芳,傅绍斌,徐亚双,等.无机盐对非离子表面活性剂水溶液的雾点影响[J].江汉石油学院学报,1998,20(4):66-70.
75.朱森,程发,郑宝江,等. Geminni阴离子表面活性剂水溶液的聚集性质[J].高等化学学报,2004,20(10):1245-1248.
76. A. Cid-Samamed, L. Garcia-Rio, D. Fernandez-Gandara, et al. Influence of n-alkylacids on the percolative phenomena in AOT-based microemulsions [J]. Journal of Colloid and Interface Science, 2008, 318(1):525-529.
77. Anna Imberg. On the microstructures of ethyl acetate/monoolein/water [J]. Colloid and Surfaces B: Biointerfaces, 2006, 53(2):233-240.
78. A ttwood D. Colloid drug delivery system s. Drug Pharm SciSer [M]. New York: M arcel Dekker, 1994:31-71.
79. Babette Biruss, Claudia Valenta. The advantage of polymer addition to a non-ionic oil in water microemulsion for the dermal delivery of progesterone [J]. International Journal of Pharmaceutics, 2008, 349:269-273.
80. Ben J. Boyd, Darryl V. Whittaker, Shui-Mei Khoo, et al. Lyotropic liquid crystalline phases formed from glycerate surfactants as sustained release drug delivery system [J]. International Journal of Pharmaceutics,2006, 309:218-226.
81. Bin Lin, Alon V. McCormick, H. Ted Davis,et a l. Solubility of Sodium Soaps in Aqueous Salt Solutions [J]. J Colloid and Interface Sci, 2005, 291: 543-549.
82. BoutonnetM,K izling J, Stenins P etal.The preparation of monodisperse colloidal metal particles rommi croemulsion [J]. Colloids and Surfaces, 1982, 212(5):209.
83. Bourel M and Schechter R S. Surfactant Science Series [M]. Plenum Press, NewYork, 1988.
84. Carlos Rodriguez-Abreu, Massimo Lazzari. Emulsions with structured continuous phases [J]. Current Opinion in Colloid and Interface Science. 2007:1-8.
85. Chhater A S,Joshi R A, K alkarni B D. M icroem ulsions as media fororganic synthesis: selective N itration ofphenolto ortho-N itropheno lu- sing Dilute Nitric Acid [J]. J Colloid Interface Sci,1993, 158(11):183-187.
86. Chunsheng Mo, Xiaoge Li. Microstructure and structural transition in coconut oil microemulsion using semidifferential electroanalysis [J]. Journal of Colloid and Interface Science, 2007, 312:355-362.
87. Debolina Mitra, Subhas C, Bhattacharya, et al. ALB film morphological study with reference to biopolymer-surfactant interaction taking gelatin-CTAB system as a model [J]. Biophysical Chemistry, 2009, 139:123-136.
88. Donglin Li, Daisuke Fujikawa, Takumi Yoshimura, et al. Additive-stabilizedhexagonally ordered mixed lyotropic liquid crystal [J]. Journal of Molecular Liquids, 2008, 138:113-119.
89. Elena Blanco, Juan M. Ruso, Gerardo Prieto, et al. On relationships between surfactant type and globular proteins interactions in solution [J]. Journal of Colloid and Interface Science, 2007, 316:37-42.
90. E. Jurado, V. Bravo, J. M. Vicaria, et al. Triolein solubilization using highly biodegradable non-ionic surfactants [J]. Colloids and Surfaces A: Physicochem, Eng. Aspects, 2008:3-7.
91. Engstrom S. Cubic phases as drug delivery systems [J]. Polymer Preprint, 1990, 31(2):157-158.
92. Frederic Marchal, Veronique Nardello-Rataj, Nelly Chailloux, et al. Lyotropic liquid crystal behaviour of azelate and succinate monoester surfactants based on fragrance alcohols [J]. Journal of Colloid and Interface Science, 2008, 21: 177-185.
93. Guangqiang Zhao, Shing Bor Chen. Nonlinear rheology of aqueous solutions of hydrophobically modified hydroxyethyl cellulose with nonionic surfactant [J]. Journal of Colloid and Interface Science, 2007, 316:858-866.
94. Guodong Zhang, Xiao Chen, Yizhou Xie, et al. Lyotropic liquid crystalline phases in a ternary system of 1-hexadecyl-3- methylimidazolium chloride/ 1-decanol /water [J]. Journal of Colloid and Interface Science, 2007, 315: 601-606.
95. H. Matsubara, H. Obata, T. Matsuda, et al. Surface adsorption and aggregate formation of aqueous binary mixture of cationic surfactant and sugar surfactant [J]. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 315:183-188.
96. Jedrzej Szymanski, Agnieszka Wilk, Robert Holyst, et al. Micro- and macro-shear viscosity in dispersed lamellar phases [J]. J.Non-Newtonian Fluid Mech, 2008, 148:134-140.
97. Jin Zhang, Bin Dong, Liqiang Zheng, et al. Lyotropic liquid crystalline phases formed in ternary mixtures of 1-cetyl-3-methylimidazolium bromide/p-xylene /water: A SAXS, POM, and rheology study [J]. Journal of Colloid and Interface Science, 2008, 321:159-165.
98. J.L. Blin, R. Bleta, M.J. Stebe. Cloud point curve of nonionic surfactant related tothe structures of mesoporous materials [J]. Journal of Colloid and Interface Science, 2006, 300:765-773.
99. J.Th.G.OverbeeK, G.J.Verhoeckx, P.L. Bruyn and H.N.W. Lecker, J. CoIloid Interface Sci [J]. Journal of Colloid and Interface Science, 1987, 19:422-427.
100. J.Th.G.Overbeek, Faraday Disc. Chem.Soc [J], Journal of Colloid and Interface Science, 1978, 65:7-15.
101. KABIR. MD H, ARAMAKI. K, ISHITOBI. M, et al. Cloud point and formation of microemulsions in sucrose dodecanoate systems [J]. Colloids and Surfaces, 2003, 21(6): 65-74.
102. Katarzyna Zielinska, Kazimiera A. Wilk, Adam Jezierski, et al. Microstructure and structural transition in microemusions stabilized by aldonamide-type surfactants [J]. Journal of Colloid and Interface Science, 2008, 321:408-417.
103. Kishida M., Fujita T., Umakoshik, et al. Novel preparation of metal- supported catalysts by colloilalm icroparticles in a water-in-oil microe- mulsion catalytic-hydrogenation of carbon-dioxide [J]. J chem soc chem com m, 1995, 11(7):763-764.
104. K. Shivaji Sharma, P.A. Hassan, Animesh K. Rakshit. Surface acticity and association behavior of nonaoxyethylene n-dodecylether in aquo amino acid medium: Tensiometry, small-angle neutron scattering, dynamic light scattering and viscosity studies [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 308:100-110.
105. Md. Hamidul Kabir, Kenji Aramaki, Masahiko Ishitobi, et al. Cloud Point and Formation of Microemulsions in Sucrose Dodecanoate Systems[J]. Colloids and Surfaces, 2003, 216: 65-74.
106. Meller A. Stavans J. Stability of emulsion with nonadsorbing polymers [J]. Langmuir, 1996, 12(2):301-304.
107. MITRA. R K, PAUL.B K, Effect of NaCl and temperature on the water solubilization behavior of AOT/nonionics mixed reverse micellar systems stabilized in IPM oil [J]. Colloids and Surfaces A: Physicochem. Eng, 2005, 255: 165-180.
108. Monzer Fanun. Phase behavior, transport, diffusion and structural parameters of nonionic surfactants microemulsions [J]. Journal of Molecular Liquids, 2007:1-9.
109. Monzer Fanun. Structure probing of water/mixed nonionic surfactants/ caprylic-capric triglyceride system using conductivity and NMR [J]. Journal of Molecular Liquids, 2007, 133:22-27.
110. Monzer Fanun. Conductivity, viscosity, NMR and diclofenac solubilization capacity studies of mixed nonionic surfactants microemulsions [J]. Journal of Molecular Liquids, 2007, 135:5-13.
111. Na Li, Jie Liu, Xueyan Zhao, et al. Complex formation of ionic liquid surfactant and cyclodextrin [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 292:196-201.
112. Nina Vlachy, Markus Drechsler, Jean-Marc Verbavatz, et al. Role of the surfactant headgroup on the counterion specificity in the micelle-to-vesicle transition through salt addition [J]. Journal of Colloid and Interface Science, 2007:1-7.
113. Nissim Garti, Marganit Avrahami, Abraham Aserin. Improved solubilization of Celecoxib in U- type nonionic microemulsions and their structural transitions with progressive aqueous dilution [J]. Journal of Colloid and Interface Science, 2006, 299: 352-365.
114. Prince L.M.A. Colloid Inter Sci [J].1969, 29:2166.
115. Prince L.M. Microemulsions Theory and Practice [M]. New York: Academic Press, 1977:83-88.
116. Qiang Xia, Xiaozheng Hao, Yangyan Lu, et al. Production of drug-loaded lipid nanoparticles based on phase behaviors of special hot microemulsions [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2008, 313-314:27-30.
117. R. Efrat, A. Aserin, N. Garti. On structural transitions in a discontinuous micellar cubic phase loaded with sodium diclofenac [J]. Journal of Colloid and Interface Science, 2008:1-11.
118. Rivka Efrat, Abraham Aserin, Ellina Kesselman, et al. Liquid micellar discontinuous cubic mesophase from ternary monoolein/ethanol/water mixtures [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2007, 299:133-145.
119. Rodrigo Montecinos, Hernan Ahumada, Victor E.Bahamonde-Padilla, et al. Counterion and composition effects on discotic nematic lyotropic liquid crystals [J].Journal of Colloid and Interface Science, 2007, 316:120-125.
120. Sadhale Y, Shah J C, Stabilization of insulin against agitation-induced aggregation by the GMO cubic phase gel [J]. Intermational J Pham, 1999, 191 (1):51-64.
121. Sadhale Y, Shah J C, Biological activity of insulin in GMO gels and the effect of agitation [J]. Int J Pham, 1999, 191 (1):65-74.
122. S.B. Rizwan, Y.-D. Dong, B.J. Boyd, et al. Characterisation of bicontinuous cubic liquid crystalline systems of phytantriol and water using cryo field emission scanning electron microscopy (cryo FESEM) [J]. Micron, 2007, 38:478-485.
123. Schulman J.H, et al. Mechanism of formation and structure of microem- ulsions by electron microscopy [J]. Phys Chem, 1959, 63(10):1677.
124. S.K.Mehta, Shweta Sharma. Temperature-induced percolation behavior of AOT reverse micelles affected by poly (ethylene glycol) s [J]. Journal of Colloid and Interface Science, 2006, 296:690-699.
125. S.M. Ramaraju, B.J. Carroll, J.G. Chambers, et al. The liquid crystalline phases formed by linear-dodecylbenzene sulphonic acid during neutralization with sodium carbonate [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2006, 288:77-85.
126. T.P.Hoar and J.H.Schulman, Nature, 1943, 152:102.
127. Tsuyoshi Kijima, Yuki Nishida, Daisuke Fujikawa, et al. Long-chain alcohol induced phase transition in lyotropic mixed polyoxyethylene-type surfactant liquid-crystals [J]. Journal of Molecular Liquid, 2007, 133:54-60.
128. V, G, Gailar, K.V. Padalkar, V.K. Aswal. Characterization of mixed micelles of structural isomers of sodium butyl benzene sulfonate and sodium dodecyl sulfate by SANS, FTIR spectroscopy and NMR spectroscopy [J]. Journal of Molecular Liquids, 2008, 138:155-167.
129. Wei liu, Wei-jun Zhao, Jian-bo Chen, et al. A cloud point extraction approach using Trition X-100 for the separation and preconcentration of Sudan dyes in chilli powder [J]. Analytica Chimica Acta, 2007, 605:41-45.
130. Wenchang Zhuang, Xiao Chen, Jinguang Cai, et al. Characterization of lamellar phases fabricated from Brij-30/water/1-butyl-3-methylimida- zolium salts ternary systems by small-angle X-ray scattering [J]. Colloid and Surfaces A: Physicochem.Eng. Aspects, 2008:1-9.
131. WANG Li-juan, LI Xue-fen, ZHANG Gao-yong, et al. Oil-in-water nanoemulsions for pesticide formulations [J]. Journal of Colloid and Interface Science, 2007, 314 (1): 230-235.
132. Xiaoguang Zhang, Jinfeng Dong, Gaoyong Zhang, et al. The effect of additives on the water solubilization capacity and conductivity in n-pentanol microemulsions [J]. Journal of Colloid and Interface Science, 2005, 285:336-341.
133. Yanan Gao, Suqing Wang, Liqiang Zheng, et al. Microregion detection of ionic liquid microemulsions [J]. Journal of Colloid and Interface Science, 2006, 301:612-616.
134. Yuji Yamashita, Hironobu Kunieda, Eiko Oshimura, et al. Formation of intermediate micellar phase between hexagonal and discontinuous cubic liquid crystals in brine/N-acylamino acid surfactant/ N-acylamino acid oil syetem [J]. Journal of Colloid and Interface Science, 2007, 312:172-178.
135. Yuksel Bayrak, Mehmet Iscan. Studies on the phase behavior of the system non-ionic surfactant/alcohol/alkane/H2O [J]. Colloid and Surfaces A: Physicochem. Eng. Aspects, 2005, 268:99-103.
136.Zhongni Wang, Wu Zhou, Ganzuo Li. Ternary cubic phases containing ionic liquid [J]. Journal of Colloid and Interface Science, 2008, 318:405-410.