印染废水预处理提高BOD_5/CODcr的技术研究
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摘要
本研究的目的在于,通过预处理提高印染废水的可生化性。本研究以BOD5/CODcr(以下简称B/C)为主要考察指标,以现场试验和数量分析为主要研究方法,探讨物化法以及物化-生化联用法提高印染废水B/C的可能性和各方法的优势。物化法主要包括Fenton氧化法、硫酸亚铁混凝法,物化-生化联用法主要是指硫酸亚铁前混凝和ABR反应池的联用。
Fenton氧化法处理印染废水,当双氧水和硫酸亚铁的摩尔投加比(n(H2O2)/n(Fe2+))为5～10、H2O2投加量在1.3-2.5mmol/L、Fenton反应时间为20～30min、起始pH为3～5时,COD去除率能稳定在40%以下,而B/C能提高到0.3以上。在此操作条件下,本反应既可以在一点程度上为后续处理降低COD负荷,又可以提高B/C到0.3以上
硫酸亚铁混凝法处理印染废水时,当硫酸亚铁投加量为500mg/L,起始pH值为10,反应时间为5min,回调pH至10,沉淀时间为60min, B/C基本维持在0.3以上,而预处理COD去除率在40%以下。
通过技术比较和经济比较,本课题认为硫酸亚铁加碱法更适合预处理段,在中试试验中选择硫酸亚铁加碱法为主要工艺。
硫酸亚铁加碱法单独运行的中试试验中,在不调节pH值,保证沉淀时间60min的前提下,硫酸亚铁投加量为300ppm、400ppm、500ppm时,B/C比能提升至0.30～0.33,而COD去除率为20%～30%。
物化-生化联用法处理印染废水的处理效果要好于两者单独运行。
本研究为“十一五国家水体污染控制与治理科技重大专项”《水乡城镇水环境整治技术研究与综合示范》的子课题《场地信息调查与污水厂预处理技术研究》的研究项目。(子课题编号：2008ZX07313-006-02)
The purpose of this study is to improve the biodegradability of dyeing and printing wastewater through the pretreatment. This study takes BOD5/CODcr (hereinafter referred to as "B/C") as main investigation index, takes field test and quantitative analysis as the main research method, explore the possibility of raising B/C under the treatment of physicochemical method and physicochemical-biochemical method, and the advantage of them. Physicochemical method mainly includes Fenton oxidation, ferrous sulfate coagulation method. Physicochemical-biochemical method mainly refers to the synergy effects of ferrous sulfate coagulation method and ABR reaction pond.
Fenton oxidation process treats with printing and dyeing wastewater, when hydrogen peroxide and ferrous sulfate's Moore dosing ratio (n (H2O2)/n (Fe2+)) is between 5-10, H2O2 dosage is between 1.3-2.5 mmol/L, reaction time is between 20-30 min, initial pH is between 3-5, the COD removal rate can stabilize in below 40 percent, and the B/C can be improve to 0.3 above. In this operation condition, this reaction can both reduce COD load in a small degree for the subsequent processing, and improve B/C to 0.3 above.
Ferrous sulfate coagulation method processes printing and dyeing wastewater, when ferrous sulfate dosage is 500mg/L, initial pH is 10, reaction time is 5min, adjusting pH to 10, precipitation time is 60min, the ratio of B/C basic maintaining at 0.3 above, and the preprocessing COD removal rate would below 40 percent.
Through technology and economic comparison, this study thinks ferrous sulfate coagulation process is more suitable for preprocessing section, and selects ferrous sulfate coagulation process as the main technology for pilot test.
In the pilot test with ferrous sulfate method running separately, no pH value adjustment, ensuring precipitation time 60min, ferrous sulfate dosage is 300ppm,400ppm, 500ppm, B/C then can ascend to 0.18-0.33, and for COD removal rate 20% to 30%.
The treatment results of physicochemical-biochemical method are in better shape than both run separately.
The study is the research project of the subproject(the study on spot informantion survey and sewage farm pretreatment technology) of the major science and technology project on national water body pollution control and treatment(the study on water environment management technology in water town and integrated demonstration) during 11th Five-year plan. (subproject:No.2008ZX07313-006-02)
Fenton氧化法处理印染废水,当双氧水和硫酸亚铁的摩尔投加比(n(H2O2)/n(Fe2+))为5～10、H2O2投加量在1.3-2.5mmol/L、Fenton反应时间为20～30min、起始pH为3～5时,COD去除率能稳定在40%以下,而B/C能提高到0.3以上。在此操作条件下,本反应既可以在一点程度上为后续处理降低COD负荷,又可以提高B/C到0.3以上
硫酸亚铁混凝法处理印染废水时,当硫酸亚铁投加量为500mg/L,起始pH值为10,反应时间为5min,回调pH至10,沉淀时间为60min, B/C基本维持在0.3以上,而预处理COD去除率在40%以下。
通过技术比较和经济比较,本课题认为硫酸亚铁加碱法更适合预处理段,在中试试验中选择硫酸亚铁加碱法为主要工艺。
硫酸亚铁加碱法单独运行的中试试验中,在不调节pH值,保证沉淀时间60min的前提下,硫酸亚铁投加量为300ppm、400ppm、500ppm时,B/C比能提升至0.30～0.33,而COD去除率为20%～30%。
物化-生化联用法处理印染废水的处理效果要好于两者单独运行。
本研究为“十一五国家水体污染控制与治理科技重大专项”《水乡城镇水环境整治技术研究与综合示范》的子课题《场地信息调查与污水厂预处理技术研究》的研究项目。(子课题编号：2008ZX07313-006-02)
The purpose of this study is to improve the biodegradability of dyeing and printing wastewater through the pretreatment. This study takes BOD5/CODcr (hereinafter referred to as "B/C") as main investigation index, takes field test and quantitative analysis as the main research method, explore the possibility of raising B/C under the treatment of physicochemical method and physicochemical-biochemical method, and the advantage of them. Physicochemical method mainly includes Fenton oxidation, ferrous sulfate coagulation method. Physicochemical-biochemical method mainly refers to the synergy effects of ferrous sulfate coagulation method and ABR reaction pond.
Fenton oxidation process treats with printing and dyeing wastewater, when hydrogen peroxide and ferrous sulfate's Moore dosing ratio (n (H2O2)/n (Fe2+)) is between 5-10, H2O2 dosage is between 1.3-2.5 mmol/L, reaction time is between 20-30 min, initial pH is between 3-5, the COD removal rate can stabilize in below 40 percent, and the B/C can be improve to 0.3 above. In this operation condition, this reaction can both reduce COD load in a small degree for the subsequent processing, and improve B/C to 0.3 above.
Ferrous sulfate coagulation method processes printing and dyeing wastewater, when ferrous sulfate dosage is 500mg/L, initial pH is 10, reaction time is 5min, adjusting pH to 10, precipitation time is 60min, the ratio of B/C basic maintaining at 0.3 above, and the preprocessing COD removal rate would below 40 percent.
Through technology and economic comparison, this study thinks ferrous sulfate coagulation process is more suitable for preprocessing section, and selects ferrous sulfate coagulation process as the main technology for pilot test.
In the pilot test with ferrous sulfate method running separately, no pH value adjustment, ensuring precipitation time 60min, ferrous sulfate dosage is 300ppm,400ppm, 500ppm, B/C then can ascend to 0.18-0.33, and for COD removal rate 20% to 30%.
The treatment results of physicochemical-biochemical method are in better shape than both run separately.
The study is the research project of the subproject(the study on spot informantion survey and sewage farm pretreatment technology) of the major science and technology project on national water body pollution control and treatment(the study on water environment management technology in water town and integrated demonstration) during 11th Five-year plan. (subproject:No.2008ZX07313-006-02)
引文
[1]戴日成,张统,郭茜等.印染废水水质特征即处理技术综述[J].工业给排水,2000,26(10)：33-37.
[2]奚旦立,马春燕.印染废水的组成、分类及性质[J].印染,2010(14)：51-53.
[3]张竹林Fenton试剂处理印染废水的实验研究[D]：[硕士学位论文].武汉：武汉理工大学土木工程与建筑学院,2009.
[4]黄长盾,杨西昆,汪凯民.印染废水处理[M].北京：纺织工业出版社,1987.5-7.
[5]王振东,张志祥.印染废水的污染与控制[J].环境科学与技术,2001(1)：19-23.
[6]许宏良.印染废水集中处理的污染源分析[J].工业安全与环保,2005,31(7)：12-13.
[7]陈一飞,施成良.印染废水成分分析及进化处理技术[J].四川丝绸,2002(3)：15-17.
[8]朱宏飞,李定龙,朱传为.印染废水的危害及源头治理举措[J].环境科学与管理,2007,32(11)：89-92.
[9]杨书铭,黄长盾.纺织印染工业废水治理技术[M].第一版.北京：化学工业出版社,2002.166-171.
[10]张宇峰,滕洁,张雪英等.印染废水处理技术的研究进展[J].工业水处理,2003,23(4)：23-27.
[11]王佳伟.印染废水的处理方法及其研究动向[J].广西纺织科技,2010,39(1)：64-66.
[12]姜方新,兰尧中.印染废水处理技术研究进展[J].云南师范大学学报,2002,22(2)：24-27.
[13]赵灵霞.印染废水的物化处理技术[J].广东化工,2009,38(8)：175-176,187.
[14]闫金霞,成庆利.印染废水治理技术综述[J].染料与染色,2007,44(2)：48-51.
[15]周学双.染料工业三废治理的发展方向[J].化工环保,1992,12(6)：333-336.
[16]张建英,梁缘东,陈曙光等.染色废水吸附混凝效应研究[J].环境污染与防治,1998,20(3)：9-12.
[17]杭瑚等.膨润土吸附——絮凝法处理废水中的有机染料[J].环境科学,1994,15(1)：42.
[18]史红香,胡晓敏Fenton试剂氧化处理印染废水的实验研究[J].辽宁化工,2006,35(4)：202-204,210.
[19]高蓉菁,夏明芳,尹协东等.污染防治技术,2003,16(4)：68-70.
[20]韩虹,陈文松,韦朝海.印染废水的慈混凝-高梯度磁分离协同[J].环境工程学报,2007,1(1)：64-67.
[21]刘冬莲,黄艳斌.OH的形成机理及在水处理中的应用[J].环境科学与技术,2003,26(1)：44-46.
[22]包木太,王娜,陈庆国等Fenton法的氧化机理及在废水处理中的应用进展[J].化工进展,2008,27(5)：660-665.
[23]Neyens E, Baeyens J. A review of classic Fenton's peroxidation as an advanced oxidation technique[J]. Journal of Hazardous Materials,2003(98):33-50.
[24]Galvao Sara Amelia O, Mota Andre L N, Silva Douglas N, et al. Application of the photo-Fenton process to the treatment of wastewaters contaminated with diesel[J]. Science of the Total Environment,2006(367):42-49.
[25]Duran A, Monteagudo J M, Amores E. Solar photo-fenton degradation of reactive blue 4 in a CPC reactor[J]. Applied Catalysis B:Environmental,2008,80(1-2):42-50.
[26]Hideyuki Katsumata, Satoshi Kaneco, Tohru Suzuki, et al. Degradation of linuron in aqueous solution by the photo-Fenton reaction[J]. Chemical Engineering Journal,2005(108): 269-276.
[27]马玉,黄娟,王世和等.综合印染废水的混凝实验研究[J].电力环境保护,2009,25(6),1-3.
[28]洪金德.几种铁盐处理印染废水的研究[J].福建化工,2001(1)：27-30.
[29]芦家娟,王毅力,赵洪涛等.ABR反应器的启动及颗粒污泥特征的研究[J].环境化学,2007,26(1)：10-16.
[30]Zheng Huaili, Pan Yunxia, Xiang Xinyi. Oxidation of acidic dye Eosin Y by the solar photo-Fenton processes[J]. Journal of Hazardous Materials,2007,141:457-464.
[31]Boopathy R, Tilche A, Anaerobic Digestion of High StrengthMolassesWastewaterUsing Hybrid Anaerobic Baffled Reactor [J]. Wat.Res.,1991,25 (7):785—790
[32]沈耀良,赵丹,王惠民.ABR处理高浓度淀粉制品加工废水运行特性的研究[J].给水排水,2002,28(9)：33-36.
[33]王建龙,生物固定化技术与水污染控制[M].北京：科学出版社,2002,181-187
[34]相欣奕,郑怀礼Fenton反应处理染料废水研究进展[J].重庆建筑大学学报,2004,26(4)：126-130.
[35]李金莲,金永峰,钱慧娟,等Fenton试剂在水处理中的应用研究[J].化工科技市场,2006,29(6)：28-33.
[36]张乃东,郑威Fenton法在水处理中的发展趋势[J].化工进展,2001,20(12)：1-3.
[37]王春敏,张捷.类Fenton试剂及其在废水处理中的应用[J].山西化工,2006,26(6)：40-42.
[38]罗刚,黄君礼,孙红.活性炭吸附/Fenton试剂氧化法处理造纸厂污冷凝水的研究[J].哈尔滨建筑大学学报,1999,32(6)：59-62.
[39]Xu Xiangrong, Li Huabin, Wang Wenhua, et al. Degradation of dyes solutions by the Fenton process[J]. Chemosphere,2004,57(7):595-600.
[40]王罗春,闻人勤,丁桓如Fenton试剂在处理难降解有机废水及其应用[J].环境保护科学,2001,27(5)：11-14.
[41]钟理,陈建军.高级氧化处理有机污水技术进展[J].工业水处理,2002,22(1)：1-5.
[42]张乃东,郑威.羟基自由基OH在水处理中的应用[J].哈尔滨商业大学学报,2001,17(3)：22-24.
[43]徐勇弟,徐寿昌.几种类Fenton试剂的氧化特性及在工业废水处理的应用[J].上海环境科学,1994,13(3)：26-28.
[44]张国卿,王罗春,徐高田等Fenton试剂在处理难降解有机废水中的应用[J].工业安全与环保,2004,30(3)：17-20.
[45]Dong Xiaoli, Ding Wei, Zhang Xiufang, et al. Mechanism and kinetics model of degradation of synthetic dyes by UVvis/H202/Ferrioxalate complexes[J]. Dyes and Pigments,2007,74(2): 470-476.
[46]Huang Yaohui, Chou Shanshan, Peng Mingging, et al. Case study on the bioeffluent of petrochemical wastewater by electro-Fenton method[J]. Wat.Sci.Technol.,1999,39(10):145-149.
[47]李金莲Fenton技术处理含聚丙烯酰胺废水的研究[D].大庆：大庆石油学院,2005.
[48]张乃东,郑威,彭永臻.电Fenton法处理难降解有机物的研究进展[J].上海环境科学,2002,21(7)：440-441.
[49]Ventura A, Jacquet G, Bermomd A, et al. Electrochemical generation of the Fenton's reagent: application to atrazine degradation[J]. Water Research,2002, (36):3517-3522.
[50]Marco Panizza, Giacomo Cerisola. Removal of oganic pollutants from industrial wastewater by electrogenerated Fenton's reagent[J].Water Res.,2001,35(16):3987-3922.
[51]Birame Boye, Enric Brillas, Momar M. Electrochemical degradation of the herbicide 4-chloro-2-methylphenoxyacetic acid in aqueous medium by peroxi-coagulation and photoperoxi-coagulation[J].Journal of Electroanalytical Chemistry,2003,540:25-34.
[52]袁松虎,王琳玲,陆晓华.阴极电Fenton法处理硝基苯酚模拟废水的研究[J].工业水处理,2004,24(4)：33-36.
[53]顾晓扬,汪晓军,林德贤Fenton试剂-曝气生物滤池处理酸性玫瑰红印染废水[J].工业水处理,2006,26(11)：28-31.
[54]Scott Jon P, David F. Integration of chemical and biological degradation processes for water treatment:Review and recommendations [J]. Environmental Progress,1995,14(2):88-103.
[55]杨琦,尚海涛,王雪莲等Fenton氧化膜-生物反应器出水中丙烯腈实验研究[J].现代地质,2004,18(5)：586-589.
[56]徐颖,陈磊,周俊晓Fenton氧化-生化组合工艺处理染料中间体废水[J].环境工程学报,2007,1(4)：57-60.
[57]陈思莉,汪晓军,顾晓扬Fenton氧化-生物接触氧化工艺处理甲醛和乌洛托品废水[J].化工环保,2007,27(2)：121-124.
[58]于庆满,颜家保,褚华宁.混凝-Fenton试剂氧化联合处理焦化废水的试验研究[J].工业水处理,2007,27(3)：40-43.
[59]宫磊,徐晓军Fenton试剂和化学沉淀法联合处理垃圾渗滤液[J].净水技术,2003,23(1)：13-15.
[2]奚旦立,马春燕.印染废水的组成、分类及性质[J].印染,2010(14)：51-53.
[3]张竹林Fenton试剂处理印染废水的实验研究[D]：[硕士学位论文].武汉：武汉理工大学土木工程与建筑学院,2009.
[4]黄长盾,杨西昆,汪凯民.印染废水处理[M].北京：纺织工业出版社,1987.5-7.
[5]王振东,张志祥.印染废水的污染与控制[J].环境科学与技术,2001(1)：19-23.
[6]许宏良.印染废水集中处理的污染源分析[J].工业安全与环保,2005,31(7)：12-13.
[7]陈一飞,施成良.印染废水成分分析及进化处理技术[J].四川丝绸,2002(3)：15-17.
[8]朱宏飞,李定龙,朱传为.印染废水的危害及源头治理举措[J].环境科学与管理,2007,32(11)：89-92.
[9]杨书铭,黄长盾.纺织印染工业废水治理技术[M].第一版.北京：化学工业出版社,2002.166-171.
[10]张宇峰,滕洁,张雪英等.印染废水处理技术的研究进展[J].工业水处理,2003,23(4)：23-27.
[11]王佳伟.印染废水的处理方法及其研究动向[J].广西纺织科技,2010,39(1)：64-66.
[12]姜方新,兰尧中.印染废水处理技术研究进展[J].云南师范大学学报,2002,22(2)：24-27.
[13]赵灵霞.印染废水的物化处理技术[J].广东化工,2009,38(8)：175-176,187.
[14]闫金霞,成庆利.印染废水治理技术综述[J].染料与染色,2007,44(2)：48-51.
[15]周学双.染料工业三废治理的发展方向[J].化工环保,1992,12(6)：333-336.
[16]张建英,梁缘东,陈曙光等.染色废水吸附混凝效应研究[J].环境污染与防治,1998,20(3)：9-12.
[17]杭瑚等.膨润土吸附——絮凝法处理废水中的有机染料[J].环境科学,1994,15(1)：42.
[18]史红香,胡晓敏Fenton试剂氧化处理印染废水的实验研究[J].辽宁化工,2006,35(4)：202-204,210.
[19]高蓉菁,夏明芳,尹协东等.污染防治技术,2003,16(4)：68-70.
[20]韩虹,陈文松,韦朝海.印染废水的慈混凝-高梯度磁分离协同[J].环境工程学报,2007,1(1)：64-67.
[21]刘冬莲,黄艳斌.OH的形成机理及在水处理中的应用[J].环境科学与技术,2003,26(1)：44-46.
[22]包木太,王娜,陈庆国等Fenton法的氧化机理及在废水处理中的应用进展[J].化工进展,2008,27(5)：660-665.
[23]Neyens E, Baeyens J. A review of classic Fenton's peroxidation as an advanced oxidation technique[J]. Journal of Hazardous Materials,2003(98):33-50.
[24]Galvao Sara Amelia O, Mota Andre L N, Silva Douglas N, et al. Application of the photo-Fenton process to the treatment of wastewaters contaminated with diesel[J]. Science of the Total Environment,2006(367):42-49.
[25]Duran A, Monteagudo J M, Amores E. Solar photo-fenton degradation of reactive blue 4 in a CPC reactor[J]. Applied Catalysis B:Environmental,2008,80(1-2):42-50.
[26]Hideyuki Katsumata, Satoshi Kaneco, Tohru Suzuki, et al. Degradation of linuron in aqueous solution by the photo-Fenton reaction[J]. Chemical Engineering Journal,2005(108): 269-276.
[27]马玉,黄娟,王世和等.综合印染废水的混凝实验研究[J].电力环境保护,2009,25(6),1-3.
[28]洪金德.几种铁盐处理印染废水的研究[J].福建化工,2001(1)：27-30.
[29]芦家娟,王毅力,赵洪涛等.ABR反应器的启动及颗粒污泥特征的研究[J].环境化学,2007,26(1)：10-16.
[30]Zheng Huaili, Pan Yunxia, Xiang Xinyi. Oxidation of acidic dye Eosin Y by the solar photo-Fenton processes[J]. Journal of Hazardous Materials,2007,141:457-464.
[31]Boopathy R, Tilche A, Anaerobic Digestion of High StrengthMolassesWastewaterUsing Hybrid Anaerobic Baffled Reactor [J]. Wat.Res.,1991,25 (7):785—790
[32]沈耀良,赵丹,王惠民.ABR处理高浓度淀粉制品加工废水运行特性的研究[J].给水排水,2002,28(9)：33-36.
[33]王建龙,生物固定化技术与水污染控制[M].北京：科学出版社,2002,181-187
[34]相欣奕,郑怀礼Fenton反应处理染料废水研究进展[J].重庆建筑大学学报,2004,26(4)：126-130.
[35]李金莲,金永峰,钱慧娟,等Fenton试剂在水处理中的应用研究[J].化工科技市场,2006,29(6)：28-33.
[36]张乃东,郑威Fenton法在水处理中的发展趋势[J].化工进展,2001,20(12)：1-3.
[37]王春敏,张捷.类Fenton试剂及其在废水处理中的应用[J].山西化工,2006,26(6)：40-42.
[38]罗刚,黄君礼,孙红.活性炭吸附/Fenton试剂氧化法处理造纸厂污冷凝水的研究[J].哈尔滨建筑大学学报,1999,32(6)：59-62.
[39]Xu Xiangrong, Li Huabin, Wang Wenhua, et al. Degradation of dyes solutions by the Fenton process[J]. Chemosphere,2004,57(7):595-600.
[40]王罗春,闻人勤,丁桓如Fenton试剂在处理难降解有机废水及其应用[J].环境保护科学,2001,27(5)：11-14.
[41]钟理,陈建军.高级氧化处理有机污水技术进展[J].工业水处理,2002,22(1)：1-5.
[42]张乃东,郑威.羟基自由基OH在水处理中的应用[J].哈尔滨商业大学学报,2001,17(3)：22-24.
[43]徐勇弟,徐寿昌.几种类Fenton试剂的氧化特性及在工业废水处理的应用[J].上海环境科学,1994,13(3)：26-28.
[44]张国卿,王罗春,徐高田等Fenton试剂在处理难降解有机废水中的应用[J].工业安全与环保,2004,30(3)：17-20.
[45]Dong Xiaoli, Ding Wei, Zhang Xiufang, et al. Mechanism and kinetics model of degradation of synthetic dyes by UVvis/H202/Ferrioxalate complexes[J]. Dyes and Pigments,2007,74(2): 470-476.
[46]Huang Yaohui, Chou Shanshan, Peng Mingging, et al. Case study on the bioeffluent of petrochemical wastewater by electro-Fenton method[J]. Wat.Sci.Technol.,1999,39(10):145-149.
[47]李金莲Fenton技术处理含聚丙烯酰胺废水的研究[D].大庆：大庆石油学院,2005.
[48]张乃东,郑威,彭永臻.电Fenton法处理难降解有机物的研究进展[J].上海环境科学,2002,21(7)：440-441.
[49]Ventura A, Jacquet G, Bermomd A, et al. Electrochemical generation of the Fenton's reagent: application to atrazine degradation[J]. Water Research,2002, (36):3517-3522.
[50]Marco Panizza, Giacomo Cerisola. Removal of oganic pollutants from industrial wastewater by electrogenerated Fenton's reagent[J].Water Res.,2001,35(16):3987-3922.
[51]Birame Boye, Enric Brillas, Momar M. Electrochemical degradation of the herbicide 4-chloro-2-methylphenoxyacetic acid in aqueous medium by peroxi-coagulation and photoperoxi-coagulation[J].Journal of Electroanalytical Chemistry,2003,540:25-34.
[52]袁松虎,王琳玲,陆晓华.阴极电Fenton法处理硝基苯酚模拟废水的研究[J].工业水处理,2004,24(4)：33-36.
[53]顾晓扬,汪晓军,林德贤Fenton试剂-曝气生物滤池处理酸性玫瑰红印染废水[J].工业水处理,2006,26(11)：28-31.
[54]Scott Jon P, David F. Integration of chemical and biological degradation processes for water treatment:Review and recommendations [J]. Environmental Progress,1995,14(2):88-103.
[55]杨琦,尚海涛,王雪莲等Fenton氧化膜-生物反应器出水中丙烯腈实验研究[J].现代地质,2004,18(5)：586-589.
[56]徐颖,陈磊,周俊晓Fenton氧化-生化组合工艺处理染料中间体废水[J].环境工程学报,2007,1(4)：57-60.
[57]陈思莉,汪晓军,顾晓扬Fenton氧化-生物接触氧化工艺处理甲醛和乌洛托品废水[J].化工环保,2007,27(2)：121-124.
[58]于庆满,颜家保,褚华宁.混凝-Fenton试剂氧化联合处理焦化废水的试验研究[J].工业水处理,2007,27(3)：40-43.
[59]宫磊,徐晓军Fenton试剂和化学沉淀法联合处理垃圾渗滤液[J].净水技术,2003,23(1)：13-15.