太阳能光合生物连续制氢系统的火用分析研究
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摘要
本论文是在国家自然科学基金项目“超微秸秆类生物质光合连续产氢过程及代谢热研究”(项目编号50976029)和国家863计划项目“中小型太阳能光合生物制氢系统及其生产性运行研究”(项目编号2006AA05z119)的资助下完成的。
随着低碳经济成为世界环境日的主题和哥本哈根气候大会的召开,合理用能和加强各方面节能的管理,成为降低能源消耗、提高能源效率和应对能源短缺和环境污染的有效措施。未来中国可持续发展的基础和必由之路也将是转变传统经济增长方式、大力推进节能减排和发展低碳经济。
本论文是在热力学第二定律火用分析的基础上,以农业部可再生能源重点开放实验室研制的太阳能光合生物连续制氢系统为研究对象,通过分析系统中各部分输入和输出的能量流动过程,建立火用分析模型和火用平衡方程,分析计算了系统的火用效率,探索性的提出了太阳能光合生物连续制氢系统内部用能的薄弱环节及其低能耗高效率生产性运行的途径,为提高太阳能光合生物连续制氢系统的有效能,降低系统对常规能源的消耗,加快太阳能光合生物连续制氢技术研发进程具有重要的实际意义。
主要研究内容及结果如下:
(1)根据系统的特点,通过分析输入和输出各个能量,建立火用分析模型;
(2)建立太阳能光合生物连续制氢系统的火用平衡方程,并对太阳能光合生物连续制氢系统进行火用分析,太阳能光合生物连续制氢系统的火用效率为21.99%,其中耗散火用损中大部分为光能火用损,占整个系统总输入能量的23%。
(3)分析了太阳能光合生物连续制氢系统中影响光转化率的主要因素,包括产氢微生物对太阳光特性波长的选择性吸收、光照强度中光饱和作用和培养液自身的遮蔽效应等光能转化率的影响因素,并提出了相应的解决方法,为系统内部设备的改进提供方向,以提高系统有效能的利用,为推进光合生物制氢技术应用的工业化进程提供了科学参考。
This paper is a research supported by the National Natural Science Foundation which named the study on micro straw from biomass of photosynthetic continuous hydrogen production and metabolic heat of the process(No.50676029),and the National plans of 863 program which named the study on the operation performance of photosynthetic biological hydrogen production system in midsize(No. 2006AA05z119).
With the low-carbon economy has become the theme of World Environment Day and the convening of the Copenhagen Climate Conference, rational use of energy and enhance energy efficiency in all aspects of management has become the effective measures responding to lower energy consumption, improve energy efficiency and energy shortages and environmental pollution. China's future sustainable development will also be the basis and the only way to change the traditional mode of economic growth, vigorously promote energy conservation and development of low-carbon economy.
This paper is on the basis of the second law of thermodynamics to exergy analysis, as the research object to the continuous hydrogen production from solar energy system which develop by the Ministry of Agriculture Key Laboratory of Renewable Energy Development. By analyzing the energy flow process through various parts of the system the input and output, established of exergy analysis models and exergy balance equation, analysis and calculation of the system exergy efficiency, exploratory proposed the weaknesses in the internal use of energy efficiency and low energy production means running in the photosynthetic biological continuous hydrogen production system. In order to improve the available energy in continuous hydrogen production from solar energy systems, reduce consumption of conventional energy systems, speed up the development process in the continuous hydrogen production from solar energy systems has important practical significance.
The result shows that:
(1) by analyzing the various energy inputs and outputs, established model of exergy analysis according to the characteristics of the system;
(2)established exergy balance equations in the continuous biological hydrogen production from solar energy system, and carry out that the exergy efficiency was 21.99%, the light exergy loss was the most loss of the total system, which account for 23%;
(3) analysis of the main factors of light conversion in the continuous hydrogen production from solar energy systems, including solar hydrogen production characteristics of microorganisms on the selective absorption of wavelengths, light intensity of the light saturation effect and the culture medium of self-shadowing effect of light energy conversion rate and other factors, and the corresponding solution.Improving on the aspects in system and the utilization of the effective energy, providing a science reference for the process of the industrialization in the photosynthetic biological hydrogen production system.
随着低碳经济成为世界环境日的主题和哥本哈根气候大会的召开,合理用能和加强各方面节能的管理,成为降低能源消耗、提高能源效率和应对能源短缺和环境污染的有效措施。未来中国可持续发展的基础和必由之路也将是转变传统经济增长方式、大力推进节能减排和发展低碳经济。
本论文是在热力学第二定律火用分析的基础上,以农业部可再生能源重点开放实验室研制的太阳能光合生物连续制氢系统为研究对象,通过分析系统中各部分输入和输出的能量流动过程,建立火用分析模型和火用平衡方程,分析计算了系统的火用效率,探索性的提出了太阳能光合生物连续制氢系统内部用能的薄弱环节及其低能耗高效率生产性运行的途径,为提高太阳能光合生物连续制氢系统的有效能,降低系统对常规能源的消耗,加快太阳能光合生物连续制氢技术研发进程具有重要的实际意义。
主要研究内容及结果如下:
(1)根据系统的特点,通过分析输入和输出各个能量,建立火用分析模型;
(2)建立太阳能光合生物连续制氢系统的火用平衡方程,并对太阳能光合生物连续制氢系统进行火用分析,太阳能光合生物连续制氢系统的火用效率为21.99%,其中耗散火用损中大部分为光能火用损,占整个系统总输入能量的23%。
(3)分析了太阳能光合生物连续制氢系统中影响光转化率的主要因素,包括产氢微生物对太阳光特性波长的选择性吸收、光照强度中光饱和作用和培养液自身的遮蔽效应等光能转化率的影响因素,并提出了相应的解决方法,为系统内部设备的改进提供方向,以提高系统有效能的利用,为推进光合生物制氢技术应用的工业化进程提供了科学参考。
This paper is a research supported by the National Natural Science Foundation which named the study on micro straw from biomass of photosynthetic continuous hydrogen production and metabolic heat of the process(No.50676029),and the National plans of 863 program which named the study on the operation performance of photosynthetic biological hydrogen production system in midsize(No. 2006AA05z119).
With the low-carbon economy has become the theme of World Environment Day and the convening of the Copenhagen Climate Conference, rational use of energy and enhance energy efficiency in all aspects of management has become the effective measures responding to lower energy consumption, improve energy efficiency and energy shortages and environmental pollution. China's future sustainable development will also be the basis and the only way to change the traditional mode of economic growth, vigorously promote energy conservation and development of low-carbon economy.
This paper is on the basis of the second law of thermodynamics to exergy analysis, as the research object to the continuous hydrogen production from solar energy system which develop by the Ministry of Agriculture Key Laboratory of Renewable Energy Development. By analyzing the energy flow process through various parts of the system the input and output, established of exergy analysis models and exergy balance equation, analysis and calculation of the system exergy efficiency, exploratory proposed the weaknesses in the internal use of energy efficiency and low energy production means running in the photosynthetic biological continuous hydrogen production system. In order to improve the available energy in continuous hydrogen production from solar energy systems, reduce consumption of conventional energy systems, speed up the development process in the continuous hydrogen production from solar energy systems has important practical significance.
The result shows that:
(1) by analyzing the various energy inputs and outputs, established model of exergy analysis according to the characteristics of the system;
(2)established exergy balance equations in the continuous biological hydrogen production from solar energy system, and carry out that the exergy efficiency was 21.99%, the light exergy loss was the most loss of the total system, which account for 23%;
(3) analysis of the main factors of light conversion in the continuous hydrogen production from solar energy systems, including solar hydrogen production characteristics of microorganisms on the selective absorption of wavelengths, light intensity of the light saturation effect and the culture medium of self-shadowing effect of light energy conversion rate and other factors, and the corresponding solution.Improving on the aspects in system and the utilization of the effective energy, providing a science reference for the process of the industrialization in the photosynthetic biological hydrogen production system.
引文
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