含β-酮亚胺的席夫碱化合物的合成及配位化学研究
|
摘要
席夫碱化合物在生物化学、配位化学、超分子化学、催化、电化学等方面表现出许多新颖的性能，一直受到化学工作者的普遍重视。近年来，席夫碱配体由单齿发展到多齿和大坏，过渡金属的席夫碱配合物具有独特的结构、性能和广泛的应用研究前景，如氧化还原、催化、荧光材料以及生物体系的化学模拟等。以自组装战略为基础的有机-无机配位聚合物化学是目前国际化学界最跃、前沿的研究领域之一，亦是合成新型有机-无机复合功能材料的最有效的途径之一。为此，我们设计合成了一系列含β酮亚胺的新型Schiff Base化合物；研究它们与金属离子的自组装化学：合成了33个新型的有机-无机配位聚合物和超分子，并通过红外、核磁、元素分析、X-射线单晶衍射等技术表征了它们的结构。
本论文的研究工作如下：
一、用二胺和乙酰丙酮进行缩合，再与2,5-二巯基-1，3,4-噻二唑进行成环作用，得到了两个新型的含杂原子的席夫碱大环化合物，并用合成大环的中间体Schiff-base配体L和Ni~(2+)，Cu~(2+)离子反应，得到4个单核的Schiff-base配合物单晶结构。通过核磁共振谱(~1H NMR)、元素分析、质谱、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
二、合成了一系列以乙酰丙酮、苯甲酰丙酮为端基的柔性Schiff-base配体，并以之同金属离子Co~(2+)，Ni~(2+)，Cu~(2+)，Zn~(2+)，Ag~+进行配位反应得到了17个单核和聚合型的配合物。通过核磁共振谱(~1H NMR)、元素分析、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
三、合成了一系列以乙酰丙酮、苯甲酰丙酮为端基的手性环己二胺桥联的Schiff-base配体，并以之与金属离子Mn~(2+)，Co~(2+)，Zn~(2+)，Ag~+，Cd~(2+)，La~(3+)进行配位反应得到了12个多核型、大环型、聚合型配合物。通过核磁共振谱(~1H NMR)、元素分析、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
Because of the large flexibility and good coordination capability of schiff base ligands, the studies on Schiff base metal complexes are paid much attention, with lots of novel properties showing in biochemistry, coordination chemistry, supermolecular chemistry, catalysis, electrochemistry, etc. Schiff base ligands are developing from simple, monodentate ligands to multidentate and macrocyclic Schiff base ligands. Transition mental Schiff base complexes possess special structures, properties and widely uses, such as oxidation-reduction, catalysis and chemical simulation for biological systems. The chemistry of organic-inorganic coordination polymers has recently become area of increasing interest. Self-assembly of organic ligands and inorganic metal ions is one of the most efficient and widely used approaches for the construction of organic-inorganic composite materials. In this thesis, a series of new Schiff base ligands by the acetylacetone and benzoylacetone were synthesized. The coordination chemistry based on these new ligands and metal ions was investigated. Totally 33 new coordination compounds were prepared and fully characterized by IR, elemental analysis, X-ray single-crystal diffraction. This main content is shown as follows:
Ⅰ. Two Novel Schiff Base macrocyclic compounds have been synthesizedfromethylenediamine, 1,2-propanediamine, acetylacetone and 2,5-dimercapto-1,3, 4-thiadiazole by condensation, brominating and cyclic action. Then. Four complexes were prepared by coordination of the intermediates Schiff base ligands with copper acetate and nickelous acetate, A series of the new Sc hiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, Mass spectroscope, FT-IR and single crystal X-ray diffraction.
Ⅱ. The flexible Schiff-base ligands have been synthesized from the acetylacetone, benzoylacetone and diamine. Their coordination chemistry with Co~(2+), Ni~(2+), Cu~(2+), Zn~(2+) , Ag~+ salts was investigated. A series of the new Schiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, FT-IR and single crystal X-ray diffraction.
Ⅲ. The Schiff-base ligands have been synthesized from the acetylacetone, benzoylacetone and 1,2-Diaminocyclo hexane. Their coordination chemistry with Mn~(2+), Co~(2+), Zn~(2+), Ag~+, Cd~(2+), La~(3+) salts was investigated. A series of the new Schiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, FT-IR and single crystal X-ray diffraction.
本论文的研究工作如下：
一、用二胺和乙酰丙酮进行缩合，再与2,5-二巯基-1，3,4-噻二唑进行成环作用，得到了两个新型的含杂原子的席夫碱大环化合物，并用合成大环的中间体Schiff-base配体L和Ni~(2+)，Cu~(2+)离子反应，得到4个单核的Schiff-base配合物单晶结构。通过核磁共振谱(~1H NMR)、元素分析、质谱、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
二、合成了一系列以乙酰丙酮、苯甲酰丙酮为端基的柔性Schiff-base配体，并以之同金属离子Co~(2+)，Ni~(2+)，Cu~(2+)，Zn~(2+)，Ag~+进行配位反应得到了17个单核和聚合型的配合物。通过核磁共振谱(~1H NMR)、元素分析、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
三、合成了一系列以乙酰丙酮、苯甲酰丙酮为端基的手性环己二胺桥联的Schiff-base配体，并以之与金属离子Mn~(2+)，Co~(2+)，Zn~(2+)，Ag~+，Cd~(2+)，La~(3+)进行配位反应得到了12个多核型、大环型、聚合型配合物。通过核磁共振谱(~1H NMR)、元素分析、红外光谱、X-单晶衍射等对合成得到的席夫碱配体及其配合物进行了表征。
Because of the large flexibility and good coordination capability of schiff base ligands, the studies on Schiff base metal complexes are paid much attention, with lots of novel properties showing in biochemistry, coordination chemistry, supermolecular chemistry, catalysis, electrochemistry, etc. Schiff base ligands are developing from simple, monodentate ligands to multidentate and macrocyclic Schiff base ligands. Transition mental Schiff base complexes possess special structures, properties and widely uses, such as oxidation-reduction, catalysis and chemical simulation for biological systems. The chemistry of organic-inorganic coordination polymers has recently become area of increasing interest. Self-assembly of organic ligands and inorganic metal ions is one of the most efficient and widely used approaches for the construction of organic-inorganic composite materials. In this thesis, a series of new Schiff base ligands by the acetylacetone and benzoylacetone were synthesized. The coordination chemistry based on these new ligands and metal ions was investigated. Totally 33 new coordination compounds were prepared and fully characterized by IR, elemental analysis, X-ray single-crystal diffraction. This main content is shown as follows:
Ⅰ. Two Novel Schiff Base macrocyclic compounds have been synthesizedfromethylenediamine, 1,2-propanediamine, acetylacetone and 2,5-dimercapto-1,3, 4-thiadiazole by condensation, brominating and cyclic action. Then. Four complexes were prepared by coordination of the intermediates Schiff base ligands with copper acetate and nickelous acetate, A series of the new Sc hiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, Mass spectroscope, FT-IR and single crystal X-ray diffraction.
Ⅱ. The flexible Schiff-base ligands have been synthesized from the acetylacetone, benzoylacetone and diamine. Their coordination chemistry with Co~(2+), Ni~(2+), Cu~(2+), Zn~(2+) , Ag~+ salts was investigated. A series of the new Schiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, FT-IR and single crystal X-ray diffraction.
Ⅲ. The Schiff-base ligands have been synthesized from the acetylacetone, benzoylacetone and 1,2-Diaminocyclo hexane. Their coordination chemistry with Mn~(2+), Co~(2+), Zn~(2+), Ag~+, Cd~(2+), La~(3+) salts was investigated. A series of the new Schiff base ligands and complexes were characterized by ~1HNMR, elemental analsis, FT-IR and single crystal X-ray diffraction.
引文
[1] (a) Zaworotko, M . J. Moulton, B. Chem. Rev. 2001,101,1629.
(b) Hagrman, P. J.;Hagrman, D.; Zubieta, J. Angew.Chem.Int.Ed. 1999, 38, 2638.
(c) Eddaoudi, M.;Moler, D. B. Li, H.; Chen, B.; Reineke, T. M; Keeffe, M. O.; Yaghi, O. M.Acc.Chem.Res. 2001, 34, 319.
(d) Evans, O. R.; Lin, W. Acc.Chem.Res. 2002, 35,511.
(e) Kitagawa, S.; Kitayra, R.; Noro,S. Angew.Chem.Int.Ed. 2004, 43, 2334.
(f) Rao, C. N. R.; Natarajan.; Vaidhyanathan, R. Angew.Chem.Int.Ed. 2004,43, 1466.
(g) Leininger, S.; Olenyuk, B.; Stang, P. J. Chem.Rev. 2000,100, 853.
[2] (a) Yaghi, O. M.; Li, G; Li, H. Nature. 1995, 378, 703.
(b) Yaghi, O. M.; Li, G; Li,H. J.Am.Chem.Soc. 1995, 117, 10401.
(c) Yaghi, O. M.; Li, G; Li, H.; Groy, T. L.J.Am.Chem.Soc. 1996, 118, 9096.
(d) Fujita, M.; Oka, H.; Yamaguchi, K.; Ogura,K. Nature. 1995, 378,469.
(e) Fujita, M.; Kwon, Y. J.; Sasaki, O.; Yamaguchi, K.;Ogura, K. J.Am.Chem.Soc. 1995, 117, 7287.
(f) Losier, T. P.; Zaworotko, M. J.Angew.Chem.Int.Ed.Engl. 1996, 35, 2779.
(g) Power, K. N.; Hennigar, L.;Zaworotko, M. J. Chem.Commun. 1998, 595.
(h) Dong, Y.-B.; Smith, M. D.;zurLoye, H. -C. Angew.Chem.Int.Ed. 2000, 39,4271.
[3] (a) Heintz, R. A.; Zhao, H.; Ouyang, X.; Grandinetti, G; Cowen, J.; Dunbar, K. R.lnorg.Chem. 1999, 38, 144.
(b) Mayr, A.; Guo, J. Inorg.Chem. 1999, 38, 921.
(c)Mayr, A.; Mao, Li. F. Inorg.Chem. 1998, 37, 5776.
(d) Mao, L. F.; Mayr, A. Inorg.Chem. 1996, 35, 3183.
(e) Choi, H. J.; Suh, M. P. J.Am.Chem.Soc. 1998, 120,10622.
(f) Sharma, C. V. K.; Broker, G A.; Huddleston, J. G; Baldwin, J. W.;Metzger, R. M.; Rogers, R. D. J.Am.Chem.Soc. 1999, 121, 1137.
(g) Li, M. -X.;Cheung, K. -K.; Mayr, A. J.Solid.State.Chem. 2000, 152, 247.
(h) Pschirer, N. G;Ciurtin, D. M.; Smith, M. D.; Bunz, U. H. F.; zurLoye, H. -C. Angew.Chem.Int. Ed.2002, 41, 583.
(i) Su, C. -Y; Goforth, A. M.; Smith, M. D.; zur Loye, H. -C.Chem.Commun. 2004,2158.
[4] (a) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J.Am.Chem.Soc. 1994, 116,1151.
(b) Lin, W.; Evans, O. R.; Xiong, R. -G; Wang, Z. J.Am.Chem.Soc. 1998,120, 13272.
(c) Garder, G B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature,1995, 374, 792.
(d) Garder, G B.; Kiang, Y. -H.; Lee, S.; Asgaonkar, A.;Venkataraman, D. J.Am.Chem.Soc. 1996, 118, 6946.
(e) Kahn, O.; Pei, Y;Verdguer, M.; Renard, J. P.; Sletten, J. J.Am.Chem.Soc. 1998, 110, 782.
(f)Inoue,K.; Hayamizu, T.; Iwamura, H.; Hashizume, D.; Ohashi, Y. J.Am.Chem.Soc. 1996,118, 1803.
(g) Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.;Achiwa, N.; Hashimoto, Y; Okawa, H. J.Am.Chem.Soc. 1992, 114, 6974.
(h) Su,C. -Y; Cai, Y. -P.; Chen, C. -L.; Smith, D. M.; zur Loye, H. -C. J.Am.Chem.Soc.2003,125, 8595.
[5]王鹏，基于弯折型配体及富烯配体的有机-无机配位化合物的合成、结构几性 质研究，博士论文，2007年
[6] (a) Dietrich, B. etc. Tetrahedron.Lett. 1969, 2889.
(b) Cram, D. J. etcScience(Washington) 1974, 183, 803.
(c) Pedersen, C. J. J.Am.Chem.Soc. 1967,89, 2495.
[7] (a) Stoddart, J. F. Pure Appl.Chem. 1988, 60, 467.
(b) Ashton, P. A. etc??Angew.Chem.lnt.Ed. Engl. 1989, 28,1396.
[8] Ashton, P. R. etc Chem.Eur.J. 1997, 3,152.
[9] (a) Supramolecular Architecture: Synthetic Controlin Thin Filmsand Solids. T. Bein, Ed. ACSSymp. Ser.449, 1992.
(b) Desiraju, GR. The Design of Organic Solids, Elsiver, Amsterdam, 1989.
(c) Russel, V. A. etc Science(Washington) 1997, 276, 575.
(d) Brunet, P.; Simard, M; Wuest, J. D. J.Am.Chem.Soc. 1997, 119, 2737.
[10] (a) Xiong, R. -G; Zuo, J. -L.; You, X. -Z.; Abrahams, B. F.; Bai, Z. -P.; Che, C.-M.; Fun, H. -K. Chem.Commun. 2000, 2061.
(b) Pschirer, N. G; Vaughn, M. E.;Dong, Y. -B.; Zur Loye, H. -C; Bunz, U. H. F. Chem.Commun. 2000, 85.
[11] (a) Altmann, M.; Bunz, U. H. F. Angew.Chem. 1995, 34, 568.
(b) Bunz, U. H. F.Chem.Rev. 2000,100,1605.
[12] Barton, T. J.; Bull, L. M.; Klemperer, W. G; Loy, D. A.; McEnaney, B.; Misono,M.; monsoon, P. A.; Pez, G; Yaghi, O. M. Chem.Mater. 1999,11,2633.
[13] (a) Maruoka, K.; Murase, N.; Yamamoto, H. J. J.Org.Chem. 1993, 58,2938.
[14] Lin, W. -B.; Evens, O. R.; Xiong, R. -G, J.Am.Chem.Soc. 1998,120,13272.
[15] Venkataraman, D.; Gardner, G F.; Lee, S.; Moore, J. S. J.Am.Chem.Soc. 1995,117,11600.
[16] (a) Stumpf, H. O.; Ouahab, L.; Pei, Y; Grandjean, D.; Kahn, O. Science. 1993,261, 447
(b) Lloret, F.; Munno, G D.; Julve, M.; Cano, J.; Ruiz, R.; Caneschi, A.Angew.Chem.Int.Ed. 1998, 37, 135.
[17] Hoskin, B. F.; Robson, R. J.Am.Chem.Soc. 1990,112, 1546.
[18] (a) Kuroda-Sowa, T.; Horrino, T.; Yamamoto, m.; Ohno, Y; Maekawa, M.;Munakata, M. Inorg.Chem. 1997, 36, 6382.
(b) Hennigar, T. L.; Mac Quarrie, D.C; Losier, P.; Rogers, R. D.; Zaworotoko, M. J. Angew.Chem.Int.Ed. 1997, 36,972.
[19] Lu, L.; Paliwala, T.; Lim, S. C; Yu, C.; Niu, T.; Jacobson, A. J. Inorg.Chem.1997, 36, 923.
[20] Fujita, M.; Kwon, Y. J.; Sasaki, O.; Yamaguchi, K. J.Am.Chem.Soc. 1995, 117,7287.
[21] (a) Blake,A.J.; Champness,N.R.; Hubberstey,R; Li,W.-S.; Withersby, M.A.;Schrdder,M.Coord.Chem.Rev. 1999,183,117.
(b) Lu, J.Y; Cahrera,B.R.;Wang,R-J.;Li,J.Inorg.Chem. 1999, 38, 4608.
[22]游效曾，孟庆金，韩万书，配位化学进展.北京：高等教育出版社．2000，第 一版．
[23] Vsehurig, B. KopPenhoefer, W. Buerkle, preparation and determination of Eonfigurationally Pure trans-(2S, 3S)-2, 3-epoxybutane. J.Org.Chem.1980, 4 5(3), 538-541.
[24] VA. Osbom, C. A. Parkerand. M. J. Winter, Hydride to carbine migration at molybdenum; the isomerisation of Mo(H){=C[CH_2]_3NMe}(CO)_2(η-C_5H_5) to Mo(CO)_2{η-CH[CH_2]_3NMe}(η-C_5H_5) J. Chem.Soc.Chem.Commun.19S6, 1185.
[25] S. Chang, R. M. Heid, E. N. Jaeobsen, Enantioseleetive epoxidation of cy elicl, 3-diene Catalyzed by asterically and electronically optimized (salen)??Mn complex. Tetrahedron Lett. 1994, 35, 669-672.
[26] E. M. Hodnett, W. J. Dunn, Strueture-antitumor activity correlation of some Shiff bases. J.Med.Chem. 1970, 13(4), 768.
[27]徐国钧，中国药村学.北京：中国医药科技出版社，1996，793．
[28] Jiang Yao zhong, Zhou Xiang ge, Hu Wen hao, et al, Asymmetric synt hesis Asylllmetric catalytic trimethylsilyleyanation of benzaldehyde bynovel Ti(Ⅳ)-chiral shiff base complexes.Tetrahedron.Asymmetry. 1995, 6(2), 405-408.
[29] G A. Patani, E. J. Lavoie, Bioisosterism: A rational approach in drug desi gn. Chem.Review. 1996, 96, 3147-3176.
[30]牛瑞民，朱小蓉，孙真荣等，萘二甲酞亚氨基席夫碱类液晶材料的三阶非 线性光学性能研究．光学学报.2003，23(1)，17-21．
[31] Schiff H.,Annal.Chem, 1864, 131,118.
[32]钟霞，新型酮类Schiff碱配体金属配合物的研究，兰州大学，博士论文，2007 年
[33]杨高文，夏小平，涂欢等．Schiff碱、咪唑金属配合物合成及抗癌活性的荧 光筛选研究[J]．化学研究与应用，1995，7(1)：41-45．
[34] Praveen K Sharma, RAm N Kanda, et al , Inorg Met Org Chem, 1996,26(7): 1219 -1230
[35] A. Angoso, J. M. Martin-Llorente, J. L. Manzano, et al. Preparation andStudy of aminoOAcid(DL-leucine, L-isoleucine, L-histidine)Schif bases withethyl-a- ketocyclopentyl carboxylate the correspondingCoppe( Ⅱ )Complexes[J]. Inorganic Chimistry Acta, 1992, 195(1): 45-49.
[36]王积涛，许育明，杨晓萍等．含氨基酸Schiff碱-金属手性配合物的合成及 其相关反应的进展[J]，有机化学，1995，15：449-460．
[37] Virinder So Parmar, Amarjit Singh, Kirpal S. Bisht, et al. Schif Base of Amino Oacid Esters as New Substrates for the Enantioselective Enzymaric Hydrolysis and Oaccompanied Asymmetric Transformationsin Aqueous Org anic Solvents[J]. J.Org.Chem, 1996, 61: 1223- 1227.
[38] L E. Khoo, J. P. Charland, E. J Gabe, et al. Synthesis and Strurural Stud ies for a series of Aromatic Schiff Bases Complexes with Triphenyltin Chl oride and Triphenyltin Isothiceyanate[J]. Inorganic Chimistry Acta,1987,128: 139-145.
[39]龚任秋．混合配体络合物化学[J]，杭州大学出版社出版．
[40]毕思玮，李桂芝，刘树祥．联苯乙酮缩氨基硫脲过渡金属配合物的合成及其 对水稻白叶枯病菌的杀菌活性研究[J]．无机化学学报，1998，14(2)：153-156．
[41] S. K. Agarwal, J. P. Tandon. Schiff base derivatives of Lanthanides-Synthesis of La (Ⅲ), Pr(Ⅲ) and Md(Ⅲ) complexes of Alkyllimes Aryllimes derived from 2-hydroxy-l-naphthaldehyde, Synth.React.Inorg.Met-Org.Chem,1974,4, 387-407.
[42] T. N. Sribastava, A. K. S. Chauban. Coordination Complexes of Organotin(Ⅳ) ChlorideswithSchiffbasederivedfrom2-hydroxy-1 -naphthaldehyde. Synth.React. Inorg.Met-Org.Chem, 1977, 7(4): 373-385.
[43] Okafor. E. C. "Synthesis of Some New Tris Rare Earth Chelates of 1-phe nyl-3-methyl-4-benzoylpyrazolone-5 and Their UV, IR and NMRspeetral str??udies", J Inorg Nucl Chem, 1980, 42(8): 1155.
[44]林鸿，冯云龙．苯甲酰丙酮缩邻苯二胺单Schiff碱的合成和晶体结构，浙江 师范大学学报(自然科学版)，2002，25(3)：271-275．
[45] Tadeusz Glowiak and Jaroslaw M. Sobezak.Cystral and molecular structureof 1-phenyl-3-(2-hydroxyPhenylamino)-2-buten-l-one. C_(16)H_(15)N0_2, J.Cryst.and. spectres, 1992, 22(6): 673-678.
[46] Wang J-L, Zhang Sh-M, Miao F-M. 4-[(2-Hydroxyphenylamino)phenyl-Methylene]-5-methyl-2-Phenyl-2H-pyrazol-3(4H)-one, Acta Cryst Section E58,2002, 1365-1366.
[47]祝心德，党元林，王成刚等，2，4二羟基苯甲醛缩硫脲及其配合物的合成 与生物活性研究，无机化学学报，1997，13：68-72．
[48]史赞，娄全龄，张耕，王红．杂环席夫碱化合物及其过渡金属配合物的合成 与表征，无机化学学报，1993，9：303-308．
[49]胡培植，季立才，王亚夫．“二茂铁甲酰丙酮缩氨基硫脲金属配合物研究， 无机化学学报，1996，12(1)：28-29．
[50]、 Siddiq K S A, Bsshar, Tabassum S. Synth.React.Inorg.Met-Org.Chem. 1991,21(2): 217.
[51] Vinodkumar. C. R Synth.React.Inorg.Met-Org.Chem. 1997,27(9): 1365.
[52]李中芳，王素文，傅芳信．几种用途广泛的Schiff碱的合成，化学与粘合， 1996，4，194-197．
[53]金杜玉，侯震，任军，赵国锋．1-芳酰基-4-菊酰基氨基硫脲类化合物的合成 及生物活性，有机化学，1997，17(4)：349-353．
[54] Math. M. Sharma N., Sharma G, Synth. React. Inorg.Met-Org.Chem, 1989, 19(4): 339-356.
[55]张秀英，张有娟．中国稀士学，1999，17(增刊)：392-394．
[56] Xiuying Zhang, Youjuan Zhang, Synth.ReactInorg.Met-Org.Chem, 2000, 30(1): 45-55.
[57]孟庆金，王瑞雪，步修仁，游效曾．新的不对称双Schiff碱镍配合物，高等 化学学报，1990，11(10)：1126-1128．
[58]姚克敏，周文，鲁贵，沈联芳．一种新的不对称Schiff碱与稀土配合物合成 机理及波谱，中国科学(B辑)，1999，29(3)：259-263．
[59] Geodken C L, Reng S M, Melin J A-Norris and Parky, J. Am.Chem.Soc. 1976,98: 8391.
[60] Truecs. T. J and Holm. R. H. J.Am.Chem.Soc, 1971, 93: 85.
[61] Place A A, Ferrare F P, etal.,J. Heterocyclic.Chem, 1980,17, 439.
[62] Maretell A E, Menif. R, Squattrio. P. J, Inorg.Chem, 1989,28: 1133.
[63]陆勤，罗勤慧，梅光泉，沈孟长，孙琼丽二24元大环双核铜配合物的合成 及对超氧化物歧化酶的模拟，化学学报，1993，51(11)：1082-1087．
[64] Nagata Y, Ikawa Y, Maruyama K.J. Chem.Soc. Commun, 1994:471.
[65]肖文，张华新，卢忠林等，酰腙化合物的分类、配位和性质，中山大学学 报(自然科学版)，2001，40(1)：39-42．
[66] Zheng-YinYang, Ru-Do Yang, Fa-Shen Li, Kai-BeiYu Cystal structure and antitumor activity of some rare earth metal complexes with Schiff base, polyhedron, 2000, 19: 2599-2604.
[67]徐国钧．中国药材学，北京：中国医药科技出版社，1996，793．
[68] Kimball Dasd, etal. Heterocyclic Thrombin Inhibitors. U. S. A. No. 5741799, 1998,4,21.
[69]黄春辉．稀土配位化学(第一版)，北京：科学出版社，1997，258．
[70]鲁桂，姚克敏，陈伟国，沈联芳，袁汉珍．稀土与H_2salen配合物的合成与 波谱性质，应用化学，1997，14(4)：1-5
[71]杨正银，王流芳．3d过渡金属的2-羧基丙酸(4-吡啶甲酰基)腙配合物的合成、 表征及导电性研究，化学学报，1993，51(2)：184-190．
[72]孙宏建，李晓燕，崔学桂等．过渡金属Schiff碱配合物研究，高等化学学报 1992，13(9)：1168-1170．
[73]余宝源，孙逸芳，傅本秋等．含硫Schiff碱配合物的研究，高等化学学报， 1989，10(1)．
[74] Panchanans, Hamalaienr, Royps. Synthesis, chiroptical and electrochemical studies of dioxouranium(Vl) complexes of aldimine derivatives of L-/D-histidine and crystal structure of (2,2-bipyridyl)dioxo-(N-vanil-lylidene-L-histidinato) uranium(Vl)-water-methanol(l/l/1), J.Chem.Soc.Dalton. Trans, 1994, 16: 2381.
[75] Bastosm B R, Moreim J C, Fariasp A M. Adosorptive striping voltammetric behaviour of UO_2(Ⅱ) complexed with the Schiff base N,N'-ethylenebis (salicyliden-imine)inaqueous-4-(2-hydroxyethyl)-1-Piperazineethanesulfonicacid medium, Anafy.Chim.Acta, 2000,408: 83.
[76]徐汉红，朱传方，席夫碱及其络合物的可逆热致变色材料．化学通报，2000， 8，15-20．
[77]杜锡光，陈冬菊，王艳等，四种新的水杨醛缩氨基酞著Shiff碱的合成及光 学性质．分子科学学报.2003，19(3)．
[78]赵建章，赵冰，徐蔚青等，水杨醛缩胺类Schiff碱光致变色性质．高等化学 学报,2003，24(2)，24-328．
[79]田颜清，林凤等，手性席夫碱型液晶化合物的合成．应用化学.1995，12(4)， 90．
[80]林静，陈立，林敏等，侧链型Shiff碱液晶研究一单体的合成与聚合．合成 化学.1997，5(1)，49-53．
[81]程鹏，廖代正，阎世平等，外源桥和互变异构对μ-酚氧Shiff碱双核铜(Ⅱ) 配合物磁性的影响．中国科学(B辑)，1996，26(2)，97-104．
[82] Lsseaa, Gennaroa, Vianelloe. Electrochemical reduction of Schiff base ligands H_2salophen, Electrochim Acta, 1997,42: 2065.
[83]魏丹毅，李冬成，姚克敏．稀土元素与β-丙氨酸席夫碱双核配合物的合成、 表征及催化活性，无机化学学报,1998，14(2)：209-214．
[84]姚克敏，吴静，陈德余，沈联芳，袁汉珍．稀土与直连醚-乙酰丙酮Schiff 碱新配合物合成形成机理与波谱，化学学报,1998，56(9)：900-904．
[85]姚克敏，李宁，黄巧虹，沈联芳．Ln(Ⅲ)-Cu(Ⅱ)与直链醚-氨基酸新型Schiff 碱异核配合物，中国科学(B辑)，1998，28(6)：517-523．
[86]刘永红，刘晓岚，石尧成，营盘名．希夫碱在有机合成中的应用研究，有机 化学,2002，22(7)：482-488．
[87]唐波，刘阳，梁芳珍．β-CD-Schiff碱铜(Ⅱ)配合物模拟酶催化光度法的研究， 化学学报，2000，58(8)：1031-1036．
[88]汪焱钢，曹蕾，杨军，叶文法，周青春，卢冰熙．具有植物激素活性的Schiff 碱化合物的研究*(Ⅱ)-噻二唑类Schiff碱的合成及其生物活性．高等化学学 报,1999，20(12)：1903-1905．
[89] Ernest H. GB. 2078, 06 Jan, 1982.
[90]冯英，刘义，谢昌礼，等．D-氨基葡萄糖Schiff碱及其金属配合物的抗菌活性，物理化学学报,1996，12(8)：746．
[91]陈德余，姚克敏．三种Gd~(3+)直链醚席夫碱配合物的EPR波谱研究，中国科 学(B辑)，1993，23(7)：696-701．
[92]姚克敏，陈德余，王晓南．直链醚席夫碱钆配合物EPR特性及其溶剂效应， 中国科学(B辑)，1995，25(11)：1144-1148．
[93] Fridovich I. The Biology of oxygen Radieals Comments, Acc.Chem.Res. 1982,15(7): 200.
[94] Mccord. J. M., Superoxide Dismutase, An Enzymic Function forErythroeuprein(hemoeuprein),J.Biol.Chem, 1969, 244: 6049-6052.
[95]何秀英，吴纪梅，严振寰．邻甲氧基苯甲醛丙氨酸席夫碱及其金属配合物的 合成、表征和对02自由基的抑制作用，无机化学学报，1995，11(3)：302．
[96]陈德余．天冬酰胺缩2，4-二羟基苯甲醛Schiff碱及其稀土配合物的合成 与抗O_2~-研究，化学研究与应用,2001，13(2)：145-148．
[97] Muger W., Boehner B, Dawes D. Pesticdalo-1,2,4-Thiadiaiazolyl Phosphorot hioates, [P] Ger. Offen: 2418363, 1974.
[98]李崇嘉，张文涛，郭国霖，谢有畅．Co(Ⅱ)Schiff碱载氧载氮性能研究，物 理化学学报,1994，10(3)：230-234．
[99]赵吉寿，颜莉，张丽娟．钴(Ⅱ)席夫碱配合物氧载体性能研究，云南民族学 院学报(自然科学版)，1999，8(2)：23-27．
[100]王吉德，王瑶，张翼等．氧载体及其除氧应用研究Ⅰ：乙二胺-Co配合物氧 化作用，应用化学，1998，15(2)：97-99．
[101]张妹明，β-二酮缩芳胺类席夫碱及其过渡金属配合物的合成、表征、反应 机理、结构与性能的研究，硕士论文,天津师范大学，2003年．
[102] Dong, Y.-B., Wang, L., Ma, J.-P., Shen, D.-Z., Zhao, X.-X., Huang, R.-Q.Crystal Growth&Design . 2006, 6, 2475.
[103] Dong, Y.-B.; Wang, L.; Ma, J.-P.; Huang, R.-Q. Inorg.Chem. 2006,45, 9157.
[104] Dong, Y.-B.; Zhang, H.Q.; Ma, J.P.; Su, C.-Y; Huang, R. -Q. CrystalGrowth&Design. 2005, 5, 1857.
[105] Dong, Y.-B.; Zhao, X.; Huang, R.-Q.; Smith, M.D.; zurLoye, H.-C. Inorg.Chem.2004,43, 5603.
[106] Dong, Y.-B.; Zhao, X.; Tang, B.; Wang, H.-Y; Huang, R.-Q.; Smith, MD.; zur Loye, H.-C. Chem.Commun. 2004, 2, 220.
[107] McCarthy P J, Hovey R J, Ueihei.K, Innercomplex chelates: analogs ofbisacetylacetone ethylene diinine and its me-talchelates. J.Am.Chem.Soc.1955(77): 5820-5824.
[108] Laurence J B, Victor W D. Manganese Schiff base complexes synthesisandSpectroscopy of some anion complexes of N,N'-ethylene bis(aeetylacetonelininato) manganese, Inorganic.Chemistry. 1977, 16(6): 1360-1367.
[109] Oezkar S U D, Yildirim L T, Biricik.N, Guemguem. B. Synthesis, structure and??magnetic property of a 2D grid-like copper( Ⅱ )complex with end-on azido and Pyrazine bridges. Journal of Molecular Structure. 2004, 688( 1 -3), 207-211.
[110]王寿武，戴卫东，双乙酰丙酮缩乙二胺的Cu(Ⅱ)，Ni(Ⅱ)金属配合物的合 成，淮阴师范学院学报(自然科学版)，2003，2：4-8．
[111]姚克敏，吴大庆，杨卫红，苯甲酞丙酮缩乙二胺与镧系元素多核本合物的 合成及表征，应用化学,1992，9(4)：812-520．
[112] Hill, HughA.O.; Morallee K.G; Pellizer, G. Univ. Oxford, Oxford,UK. Tr ansmission of electronic effects in some substituted phenylderivatives of c obalt(Ⅲ) bis(aeetylacetone) ethylenediimine complexes. Journal of the Che mical Society [Seetion] A:Inorganic.physical.Theoretical. 1969, 14: 2096-1 01.
[113] Hill H O, Costa G, Pellizer G, Mestroni G, Costa G Electronic transmis sionIn some organometallic derivatives of cobalt(Ⅲ)bis(acetylacetone)ethyl ene diimine(BAE)andbis(salieylaldehyde)ethylenediiminecomplexes.Journal of Organometallic Chemistry. 1968, 11(1): 167-73.
[114] Asadi M, Sarvestani A, Asadi Z, Setoodehkhah .Synthesis and thermodynamic studies of cobalt(Ⅲ)Schiff base complexes.Iran. Synthesis and Reactivity in Inorganic Metal-Organic, and Nano-Metal.Chemistly. 2005, 35(8), 639-644.
[115] Boettcher A, Takeuchi T, Hardeastle K, Meade T.J, Gray H.B. Spectrosco pyand electrochemistry of cobalt(Ⅲ)Schiff base complexes. Inorganic Chemistry, 1997, 36(12): 2498-2504.
[116] Gambarotta S, Corazzo F, Floriani C, Zehnder M.A tetranuclear iron(Ⅱ)-sodium complex formed from the complexation of sodium ethoxide by N, N,-ethylenebis(3-hydroxy-l-methy-ylbut-2-enylid-eneaminato)iron( Ⅱ). Ita ly. Journal of the Chemical Society, Chemical Communications. 1984, (19): 1305-1307.
[117]胡培植，徐霞，孙绍，发张伦．双乙酰丙酮缩乙二胺双核稀土(Ⅲ)配合物的 合成．武汉大学学报(自然科学版)，1995，44(4)：430-432．
[118]李国壁，基于双乙酰丙酮缩乙二胺配体的过渡金属配合物的合成与表征， 硕士论文,华南师范大学，2007年．
[119] Tadanodu Sato, Harumi Takeda, Ken Sakai, Taro Tsubomura*. Two novel typesof metal complexes derived form triped amines and acetyacetone, InorganicaChimicaActa, 1996,246,413-421.
[120] Malachy McCann, Sean Townsend, Michael Devereux, Vickie McKee, Brian Walker~d, Polyhedron, 2001, 20, 2799-2806
[121] Yu-Bin Dong, Qiang Zhang, Li-Li Liu, Jian-Ping Ma, Bo Tang and Ru-Qi Huang, J.Am.Chem.Soc. 2007, 129, 1514-1515
[122] Eisenberg, A.H.; Ovchinnikov, M.V.; Mirkin, C.A. J.Am.Chem.Soc. 2003,125(10), 2836.
[123] (a)Larsen, F.K.; McInnes, E.J.L.; Mkami, H.E.; Overgaard, J.; Piligkos,S.; Rajaraman, G.; Rentschler, E.; Smith, A.A.; Smith, G.M.; Boote, V.;Jennings, M.; Timco, G.A.; and Winpenny, R..E.P., Angew.Chem.Int.Ed.2003, 42(1), 101.
(b) Sun, X.-K.; Johnson, D.W.; Caulder, D.L.; Powers,R.E.; Raymond, K.N.; Wong, E.H. Angew.Chem.Int.Ed. 1999, 38(9),1303.
[124] Que, E.L.; Chang, C.J. J.Am.Chem.Soc. 2006,128(50), 15942.
[125] Debasis, D.; Cheu P.C. J. Chem. Soc.Dalton Trans. 2000,1081.
[126] Zhong-Hai Ni, Li-Fang Zhang, Vassilis Tangoulis, Wolfgang Wernsdorfer,Ai-Li Cui, Osamu Sato, and Hui-Zhong Kou, Inorganic Chemistry, 2007,46 (15) , 6029
[127] Nathan C. Gianneschi, Paul A. Bertin, SonBinh T. Nguyen, and Chad A. Mirkin,J.Am.Chem.Soc. 2003,125, 10508-10509.
[128] Zhao, B.; Cheng, P.; Dai, Y.; Cheng, C; Liao, D.-Zh.; Yan, S.-P.; Jiang, Z.-H.;Wang, G.-L. Angew.Chem.Int.Ed. 2003,42(8), 934.
[129]杨高文，夏小平，涂欢等．化学研究与应用，1995，7(1)：41-45
[130] Praveen K Sharma, Ram N Handa, et al. Synth.React[J]. Inorg Met Org Chem,1996, 26(7): 1219-1230
[131] A.Angoso J.M.Martin-Lorente, Inorganic Chimica Acta, 1992, 195(1): 45-49
[132]王积涛，许育明，杨晓萍等．有机化学，1995，15：449-460
[133] Virinder So Parmar, Amarjit Singh, Kirpal S. Bisht, et al. J Org Chem, 1996, 61:1223 -1227
[134] Jian Gao, Joseph H. Reibenspies, Ralph A. Zingaro, F. Ross Woolley, Arthur E.Martell, and Abraham Clearfield, Inorganic Chemistry, 2005,44, 232-241.
[135] Jonathan L. Sessler, Elisa Tomat, and Vincent M. Lynch, J.Am.Chem.Sos. 2006,128,4184-4185
[136] Jungseok Heo, You-Moon Jeon, and Chad A. Mirkin, J.Am.Chem.Soc. 2007,129, 7712-7713.
[137] Xiu B R, Jackson C R, Derveer D V, et al. Polyhedron, 1997,16: 2991-1995
[138]李锦州，李刚，于文锦，呋喃甲酰吡唑啉酮双席夫碱与铀(Ⅵ)、钍(Ⅳ)配 合物的合成、表征及生物活性，核化学与放射化学，2000，22(1)：19-23．
[139] Lehaire, M. L.; Scopelliti, R.; Piotrowski, H. and Severin, K. Angew.Chem.Int.Ed.2002,41,1419.
[140] Keefe, M. H.; Benkstein, K. D. and Hupp, J. T. Coord.Chem.Rev., 2002, 225,91.
[141] Shan, N.; Vickers, S. J.; Adams, H.; Ward, M. D. and Thomas, J.A. Angew.Chem.Int.Ed, 2004,43, 3938.
[142] Gaynor, D.; Starikova, Z. A. Ostrovsky, S.; Haase, W. and Nolan, K. B.Chem.Commun., 2002, 506.
[143] Du, M.; Guo, Y.-M. Bu, X.-H. Ribas, J. and Monfort, M. NewJ.Chem, 2002,26,645.
[144] Clifford, T.; Danby, A. M.; Lightfoot, P.; Richens, D. T. and Hay, R. W. J.Chem.Soc, Dalton Trans, 2001, 240.
[145] Veauthier, J. M.; Tomat, E.; Lynch, V. M.; Sessler, J. L. Inorg.Chem. 2005, 44,2125.
[146] Yuan, Z. L.; Zhang, Q. L.; Zhu, B. X. Chin. J.Org.Chem. 2006, 26(11), 1590(inChinese). (袁泽利，张奇龙，朱必学， 有机化学， 2006,26(11), 1590.)
[147] X.-F. Zhang, H. Chen, C.-B. Ma, C.-N. Chen & Q.-T. Liu, Dalton Trans., 2006,4047.
[148] McCarthy, P. J.; Hovey, R. J.; Ueno, K.; Martell, A. E.; J.Am.Chem.Soc. 1955, 77, 5820.
[149] Nie, G C. Fine Chemical Intermediates, 2003, 33(5), 32(in Chinese). (聂国朝．精细化工中间体, 2003, 33(5), 32.)
[150] Sheldrick, G. M. SHELXL-97, A Program for Structure Refinement, University of Gottingen, Germany, 1997.
[151] Ozkar, S.; Ulkü, D.; Y(?)ld(?)m, L. T.; Biricik, N.; Gumgüm, B. J.Mol.Structure, 2004,688,207.
[152] HE Xiang, LU Can-Zhong, WU Chuan-De, et al. Jiegou Huaxue (Chinese J. Struct. Chem.), 2005,24(2): 174-178.
[153] Nishtda Y, Takeuchi M, Takahashi K, et al. Chem.Soc. Jpa. 1983,1815-1818
[154] Halper S R, Cohen M. Inorg.Chem, 2005,44:4139-4141
[155] Zhu, Q. Y.; Bian, G. Q.; Zhang, Y.; Dai, J.; Zhang, D. Q.; Lu, W. Inorg.Chim. Acta, 2006,359, 2303.
[156] M.Eddaoudi, J.Kim, N.Rosi, D.Vodik, J.Wachter, M.O.Keeffe, Yaghi, Science 2001,295,469.
[157] Fujita, M.; Kwon, Y.J.; Washizu, S.; Ogura,K. J. Am. Chem. Soc. 1994, 116, 1151.
(b)Lin, W.; Evans, O.R.; Xiong, R.-G.; Wang, Z. J.Am.Chem.Soc. 1998, 120,13272.
[158] (a)Yaghi, D.M.; Li, H. J. Am. Chem. Soc. 1995,117, 10401
(b)Yaghi, D.M.; Li, H.; Groy, T.L. J.Am.Chem.Soc. 1996,118, 9096.
[159] (a) Garder, G.B.; Venkataraman, D.; Moore, J.S.; Lee, S. Nature, 1995, 374, 792.
(b) Garder, G.B.; Kiang, Y.-H.; Lee, S.; Asgaonkar, A.; Venkataraman, D. J.Am.Chem.Soc. 1996, 118, 6946.
(c) Maggard, P.A.; Stern, C.L.; Poeppelmeier, K.R. J.Am.Chem.Soc. 2001,123,7742.
[160] (a) Kahn, O.; Pei, Y.; Verdguer, M.; Renard, J.P.; Sletten, J. J.Am.Chem.Soc. 1988, 110, 782.
(b) Inoue, K.; Hayamizu, T.; Iwamura, H.; Hashizume, D.; Ohashi, Y. J.Am.Chem.Soc. 1996, 118, 1803.
(c) Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.; Achiwa, N.; Hashimoto, Y.; Okawa, H. J.Am.Chem.Soc. 1992, 114, 6974.
[161] (a) Kuroda-Sowa, T.; Horrino, T.; Yamamoto, M.; Ohno, Y.; Maekawa, M.; Munakat M. Inorg.Chem. 1997, 36, 6382.
(b) Munakata, M.; Wu, L.P.; Kuroda-Sowa, T. Bull. Chem. Soc. Jpn. 1997, 70, 1727.
(c) Munakata, M.; Wu, L.P.; Kuroda-Sowa, T.; Maekawa, M.; Moriwaki, K.; Kitagawa, S. Inorg.Chem. 1997, 36, 5416.
(d) Hennigar, .L.; Mac Quarrie, D.C.; Losier, P.; Rogers, R.D.; Zaworotko. M. J. Angew.Chem.Int.Ed.Engl. 1997, 36, 972.
(e) Lloret, F.; Munno, G.D.; Julve, M.; Cano, J.; Ruiz, R.; Caneschi, A. Angew.Chem.Int.Ed. Engl. 1998,37,135.
[162] (a) L.R. MacGillvray, R.H. Groeneman, J.L. Atwood, J.Am.Chem.Soc. 1998, 120, 2627;
(b) G. B. Gardner, D. Venkataraman, J. S. Moore, S.Lee, Nature. 1995, 374, 792;
(c) M. Eddaoudi, J.M. O'Keeffe, O. M.Yaghi, J.Am.Chem.Soc. 2002, 124, 376.
[163] (a) D. M..L.Goodgame, S. Menzer, A. M.Smith, D.J.Viliams,Angew.Chem. Int. Ed. 1995, 34, 574;
(b) B.F.Hoskins, R.Robson, D.A.Slizys,J.Am. Chem. Soc. 1997, 119, 2952;
(c) X.M.Chen, G.F.Liu, Chem.Eur.J. 2002, 8, 4811.
(d) X.J.Luan, Y.Y.Wang, D.S.Li, P.Liu, H.M.Hu, Q.Z.Shi, S.M.Peng, Ang ew. Chem.Int.Ed. 2005, 44, 3864.
[164] Qi-Long Zhang, Xin-Chen Zhu, Yun-Qian Zhang and Bi-Xue Zhu. 1,10-Bis(2-aminophenoxy)decane. Acta Cryst. (2007). E63, o4039
[165] S. Ozkar, D.Ulku, L.T. Yildirim, N. Biricik, B. Gumgum, J.Mol.Structure, 688(2004), 207.
[166] C.T. Zeyrek, A. Elmali, Y. Elerman, I. Svoboda, H. Fuess, Z. Naturforsch. 55b(2000) 1067.
[167] Blake, A. J.; Champness, N. R.; Hubberstey P.; Li, W-S.; Withersby, M. A., Schroder M., Coord. Chem. Rev. 1999, 183, 117; Lindoy L. F.; Atkinson, I. M. Self-Assembly in Supramolecular Systems, Royal Society of Chemistry, Cambridge, UK, 2000; Eddaoudi, M.; Moler, D. B.; Li, H. L.; Chen, B. L.; Reineke, T. M.; O'Keefe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319; Yeh, R. M;. Davis, A. V.; Raymond, K.N. in Comprehensive Coordination Chemistry II, Eds. McClevety, J. A.; Meyer, T. J. 2004, 7, 327.
[168] Millward, A. R.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127,17998; Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B.; O'Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc, 2005, 127, 1504; Ockwig, N. W.; Gado-friedrichs, O. D.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res., 2005, 38,176.
[169] Ciurtin, D. M.; Dong, Y.-B.; Smith, M. D.; Barclay, T.; zur Loye, H.-C. Inorg. Chem. 2001, 40, 2825; Janiak, C. Dalton Trans. 2003, 2781; Kitagawa, S.; Khlobystov, A. N.; Brett, M. T.; Blake, A. J.; Champness, N. R.;. Gill, P. M. W; O'Neill, D. P.; Teat, S.J.; Wilson, C.; Schroder, M. J. Am. Chem. Soc, 2003, 125, 6753; Uemura, T.; Kitagawa, S. J. Am. Chem. Soc, 2003, 125, 7814; Dong, Y.-B.; Zhao, X.; Huang, R.-Q. Inorg. Chem. 2004, 43, 5603; Dong, Y.-B.; Zhao, X.; Tang, B.; Wang, H.-Y; Huang, R.-Q.; Smith, M. D.; zur Loye, H.-C. Chem. Comm. 2004, 2. 220; Zhao, X.; Xiao, B.; Fletcher, A. J.; Thomas, K. M.; Bradshaw, D.; Rosseinsky, M. J. Science, 2004, 306, 1012.; Kitaura, R.; Noro, S.-I. Angew. Chem., Int. Ed. 2004, 43, 2334; A. J. Fletcher, E. J. Cussen, Bradshaw, D.; Rosseinsky, M. J.; Thomas, K. M. J. Am. Chem. Soc, 2004, 126, 9750; Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kato, K., Sakata, M.; Kobayashi, T. C. Angew. Chem. Int. Ed., 2005, 44, 920; Zaworotko, M. J. Cryst. Growth Des. 2007, 7, 4; Zaworotko, M. J. Cryst. Growth Des. 2007, 7, 1154; McManus, G. J.; Wang, Z.; Beauchamp, D. A.; Zaworotko, M. J.; Chem. Comm. 2007, 5212; Perry, J. J.; Kravtsov, V. C.; McManus, G. J.; Zaworotko, M. J. J. Am. Chem. Soc 2007, 129, 10076; Won T.-J.; Clegg J. K.; Lindoy, L. F.; McMurtrie, J.,C. Cryst. Growth Des. 2007, 7, 972; Nouar, F.; Eubank, J. F.; Bousquet, T.; Wojtas, L.; Zaworotko, M. J.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 1833; Cairns, A. J.; Perman, J. A.; Wojtas, L.; Kravtsov, V. C.; Alkordi, M. H.; Eddaoudi, M.; Zaworotko, M. J. J. Am. Chem. Soc. 2008, 130, 1560.
[170] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schroder, M. Coord. Chem. Rev. 2001, 222, 155; Inoue, K.; Imai, H.; Ghalsasi, P. S.; Kikuchi, K.; Ohba, M.; Okawa, H.; Yakhmi, J. V. Angew. Chem., Int. Ed. 2001,40,4242; Masaoka, S.; Furukawa, S.; Chang, H. C.; Mizutani, T.; Kitagawa, S. Angew. Chem., Int. Ed. 2001, 40, 3817; Armstrong, R. S.; Atkinson, I. M.; Carter, E.; Mahinay, M. S.; Skelton B. W.; Turner, P.; Wei, G.; White, A. H.; Lindoy, L. F. Proc. Nat. Acad. Sci. 2002, 99, 4987; Cao, R.; Sun, D.; Liang. Y.; Hong, M.; Tatsumi, K.; Shi, Q. Inorg. Chem. 2002,41,2098; Dai, J.-C.; Wu, X.-T.; Fu, Z.-Y.; Cui, C.-P.; Hu, S.-M.; Du, W.-X. Wu, L.M.; Zhang, H.-H.; Sun, R.-O. Inorg. Chem. 2002,41, 1391; Batten, S. R.; Murray, K. S. Coord. Chem. Rev. 2003, 246, 103; Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246, 247; Kitaura, R.; Fujimoto, K.; Perry, J. J.; McManus, G J.; Zaworotko, M. J. Chem. Commun. 2004, 2534; 41, 133; Chen, B.; Fronczek, F. R.; Maverick, A. W. Inorg. Chem. 2004, 43, 8209: Lee, E. Y.; Jang, S. Y.; Suh, M. P. J. Am. Chem. Soc. 2005, 127, 6374; Mulana, Y.; Kepert, C. J.; Lindoy, L.F.; Parkin, A.; Turner, P. Dalton Trans. 2005, 1598; Domasevitch, K. V.; Vreshch, V. D.; Lysenko, A. B.; Krautscheid, H. Acta Cryst. 2006, C62, m443; Kepert, C. J. Chem. Commun. 2006, 695; Won T.-J.; Clegg, J. K.; Bray, D. J.; Gloe, K.; Gloe, K.; Hayter, M. J.;Jolliffe, K. A.; Lawrance, G. A.; Meehan, G V.; McMurtrie, J. C.; Lindoy, L. F.; Wenzel, M. Dalton Trans. 2007, 1719; Wang, Z.; Kravtsov, V. C.; Walsh, R. B.; Zaworotko, M. J.; Cryst. Growth Des. 2007, 7, 1154; McManus, G J.; Wang, Z.; Beauchamp, D. A.; Zaworotko, M. J.; Chem. Commun. 2007, 5212; Perry, J. J.; Kravtsov, V. C.; McManus, G J.; Zaworotko, M. J. J. Am. Chem. Soc. 2007, 129,10076; Sarkar, M.; Biradha, K. Cryst. Growth Des. 2007, 7, 1318; Nouar, F.; Eubank, J. F.; Bousquet, T.; Wojtas, L.; Zaworotko, M. J.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 1833; Cairns, A. J.; Perman, J. A.; Wojtas, L.; Kravtsov, V. C.; Alkordi, M. H.; Eddaoudi, M.; Zaworotko, M. J. J. Am. Chem. Soc. 2008, 130, 1560.
[171] Ma, L.; Evans, O. R.; Foxman, B. M.; Lin, W. Inorg. Chem. 1999, 38, 5837; Dai, J.-C; Wu, S.-T.; Fu, Z.-Y.; Cui, C.-P.; Hu, S.-M.; Du, W.-X.; Wu, L.-M.; Zhang, H.-H.; Sun, R.-Q. Inorg Chem. 2002,41,1391; Wen, L.; Lu, Z.; Lin, J.; Tian, Z; Zhu, H.; Meng, Q. Cryst. Growth Des. 2007, 7, 93; McManus, G. J.; Perry, J. J.; Perry, M.; Wagner, B. D.; Zaworotko, M. J. J. Am. Chem. Soc. 2007, 129, 9094.
[172] Zhang, L.-J.; Yu, J.-H.; Xu, J.-Q.; Lu, J.; Bie, H.- Y.; Zhang, X. Inorg. Chem. Comm. 2005, 8, 638.
[173] Maspoch, D.; Ruiz-Molina, D.; Veciana, J. J. Mater. Chem. 2004, 14, 2713; Lecren, L.; Wernsdorfer, W.; Li, Y.-G.; Vindigni, A.; Miyasaka, H.; Clérac, R. J. Am. Chem. Soc. 2007, 129, 5045.
[174] Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y J.; Kim, K. Nature, 2000,404, 982.
[175] Rowsell, J. L. C.; Yaghi, O. M. Angew. Chem. Int. Ed. 2005, 44, 4670; Wong-Foy, A. G.; Matzger, A. J.; Yaghi, O. M. J. Am. Chem. Soc, 2006, 128, 3494; Liu, Y.; Brown, C. M.; Neumann, D. A.; Long, J. R. J. Am. Chem. Soc. 2006,128,1687; Clancy, Y L.; Lobkovsky, E. B.; Yaghi, O. M.; Dai, S. Angew. Chem. Int. Ed. 2006, 45, 1390; Collins, D. J.; Zhou, H.-C. J. Mater. Chem. 2007, 17, 3154; Furukawa, H,; Miller, M. A.; Yaghi, O. M. J. Mater. Chem. 2007, 17,
??3197; Lin, X.; Jia, J.; Hubberstey, P.; Schroder, M.; Champness, N. R.CrystEngComm. 2007, 9,438.; Dinca, M.; Dailly, A.; Jia, J.; Lin, X.; Wilson, C;Blake, A. J.; Champness, N. R.; Hubberstey, P.; Walker, G; Cussen, E. J.;Schroder, M. Chem. Comm. 2007,840; Chen, B.; Liang, C; Yang, J.; Contreras,D. S.; Banerjee, R; Bo Wang, A. P.; Knobler, C.; Furukawa, H.; O'Keeffe,M.;Yaghi, O. M. Science, 2008, 319,939.
[176] Lee, E.; Kim, J.; Heo, J.; Whang, D.; Kim, K. Angew. Chem. Int. Ed. 2001, 40,399.
[177] Zaworotko, M. J. Angew. Chem. Int. Ed. 2000, 39,3052.
[178] Pan, L.; Adams, K. M; Hernandez, H. E.; Wang, X.; Zheng, C.; Hattori, Y.;Kaneko, K. J. Am. Chem. Soc. 2003,125, 3062.
[179] (a) G.S.Hanan; J-M.Lehn; N.Krytsakas; J.Fisher, Chem. Commun, 1995, 765;
(b)D.M.Bassani, J-M.Lehn; G.Baum, D.Fenske, Angew. Chem. Int. Ed, 1997, 36,1845
[180]肖冬荣，新型螺旋体配合物的合成，结构和性质研究，东北师范大学，博 士论文，2007年
[181] Patra, S.; Mondal, B.; Sarkar, B.; Niemeyer, M; Lahiri, G. K. Inorg. Chem. 2003,42,1322.
(b) Hagrman, P. J.;Hagrman, D.; Zubieta, J. Angew.Chem.Int.Ed. 1999, 38, 2638.
(c) Eddaoudi, M.;Moler, D. B. Li, H.; Chen, B.; Reineke, T. M; Keeffe, M. O.; Yaghi, O. M.Acc.Chem.Res. 2001, 34, 319.
(d) Evans, O. R.; Lin, W. Acc.Chem.Res. 2002, 35,511.
(e) Kitagawa, S.; Kitayra, R.; Noro,S. Angew.Chem.Int.Ed. 2004, 43, 2334.
(f) Rao, C. N. R.; Natarajan.; Vaidhyanathan, R. Angew.Chem.Int.Ed. 2004,43, 1466.
(g) Leininger, S.; Olenyuk, B.; Stang, P. J. Chem.Rev. 2000,100, 853.
[2] (a) Yaghi, O. M.; Li, G; Li, H. Nature. 1995, 378, 703.
(b) Yaghi, O. M.; Li, G; Li,H. J.Am.Chem.Soc. 1995, 117, 10401.
(c) Yaghi, O. M.; Li, G; Li, H.; Groy, T. L.J.Am.Chem.Soc. 1996, 118, 9096.
(d) Fujita, M.; Oka, H.; Yamaguchi, K.; Ogura,K. Nature. 1995, 378,469.
(e) Fujita, M.; Kwon, Y. J.; Sasaki, O.; Yamaguchi, K.;Ogura, K. J.Am.Chem.Soc. 1995, 117, 7287.
(f) Losier, T. P.; Zaworotko, M. J.Angew.Chem.Int.Ed.Engl. 1996, 35, 2779.
(g) Power, K. N.; Hennigar, L.;Zaworotko, M. J. Chem.Commun. 1998, 595.
(h) Dong, Y.-B.; Smith, M. D.;zurLoye, H. -C. Angew.Chem.Int.Ed. 2000, 39,4271.
[3] (a) Heintz, R. A.; Zhao, H.; Ouyang, X.; Grandinetti, G; Cowen, J.; Dunbar, K. R.lnorg.Chem. 1999, 38, 144.
(b) Mayr, A.; Guo, J. Inorg.Chem. 1999, 38, 921.
(c)Mayr, A.; Mao, Li. F. Inorg.Chem. 1998, 37, 5776.
(d) Mao, L. F.; Mayr, A. Inorg.Chem. 1996, 35, 3183.
(e) Choi, H. J.; Suh, M. P. J.Am.Chem.Soc. 1998, 120,10622.
(f) Sharma, C. V. K.; Broker, G A.; Huddleston, J. G; Baldwin, J. W.;Metzger, R. M.; Rogers, R. D. J.Am.Chem.Soc. 1999, 121, 1137.
(g) Li, M. -X.;Cheung, K. -K.; Mayr, A. J.Solid.State.Chem. 2000, 152, 247.
(h) Pschirer, N. G;Ciurtin, D. M.; Smith, M. D.; Bunz, U. H. F.; zurLoye, H. -C. Angew.Chem.Int. Ed.2002, 41, 583.
(i) Su, C. -Y; Goforth, A. M.; Smith, M. D.; zur Loye, H. -C.Chem.Commun. 2004,2158.
[4] (a) Fujita, M.; Kwon, Y. J.; Washizu, S.; Ogura, K. J.Am.Chem.Soc. 1994, 116,1151.
(b) Lin, W.; Evans, O. R.; Xiong, R. -G; Wang, Z. J.Am.Chem.Soc. 1998,120, 13272.
(c) Garder, G B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature,1995, 374, 792.
(d) Garder, G B.; Kiang, Y. -H.; Lee, S.; Asgaonkar, A.;Venkataraman, D. J.Am.Chem.Soc. 1996, 118, 6946.
(e) Kahn, O.; Pei, Y;Verdguer, M.; Renard, J. P.; Sletten, J. J.Am.Chem.Soc. 1998, 110, 782.
(f)Inoue,K.; Hayamizu, T.; Iwamura, H.; Hashizume, D.; Ohashi, Y. J.Am.Chem.Soc. 1996,118, 1803.
(g) Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.;Achiwa, N.; Hashimoto, Y; Okawa, H. J.Am.Chem.Soc. 1992, 114, 6974.
(h) Su,C. -Y; Cai, Y. -P.; Chen, C. -L.; Smith, D. M.; zur Loye, H. -C. J.Am.Chem.Soc.2003,125, 8595.
[5]王鹏，基于弯折型配体及富烯配体的有机-无机配位化合物的合成、结构几性 质研究，博士论文，2007年
[6] (a) Dietrich, B. etc. Tetrahedron.Lett. 1969, 2889.
(b) Cram, D. J. etcScience(Washington) 1974, 183, 803.
(c) Pedersen, C. J. J.Am.Chem.Soc. 1967,89, 2495.
[7] (a) Stoddart, J. F. Pure Appl.Chem. 1988, 60, 467.
(b) Ashton, P. A. etc??Angew.Chem.lnt.Ed. Engl. 1989, 28,1396.
[8] Ashton, P. R. etc Chem.Eur.J. 1997, 3,152.
[9] (a) Supramolecular Architecture: Synthetic Controlin Thin Filmsand Solids. T. Bein, Ed. ACSSymp. Ser.449, 1992.
(b) Desiraju, GR. The Design of Organic Solids, Elsiver, Amsterdam, 1989.
(c) Russel, V. A. etc Science(Washington) 1997, 276, 575.
(d) Brunet, P.; Simard, M; Wuest, J. D. J.Am.Chem.Soc. 1997, 119, 2737.
[10] (a) Xiong, R. -G; Zuo, J. -L.; You, X. -Z.; Abrahams, B. F.; Bai, Z. -P.; Che, C.-M.; Fun, H. -K. Chem.Commun. 2000, 2061.
(b) Pschirer, N. G; Vaughn, M. E.;Dong, Y. -B.; Zur Loye, H. -C; Bunz, U. H. F. Chem.Commun. 2000, 85.
[11] (a) Altmann, M.; Bunz, U. H. F. Angew.Chem. 1995, 34, 568.
(b) Bunz, U. H. F.Chem.Rev. 2000,100,1605.
[12] Barton, T. J.; Bull, L. M.; Klemperer, W. G; Loy, D. A.; McEnaney, B.; Misono,M.; monsoon, P. A.; Pez, G; Yaghi, O. M. Chem.Mater. 1999,11,2633.
[13] (a) Maruoka, K.; Murase, N.; Yamamoto, H. J. J.Org.Chem. 1993, 58,2938.
[14] Lin, W. -B.; Evens, O. R.; Xiong, R. -G, J.Am.Chem.Soc. 1998,120,13272.
[15] Venkataraman, D.; Gardner, G F.; Lee, S.; Moore, J. S. J.Am.Chem.Soc. 1995,117,11600.
[16] (a) Stumpf, H. O.; Ouahab, L.; Pei, Y; Grandjean, D.; Kahn, O. Science. 1993,261, 447
(b) Lloret, F.; Munno, G D.; Julve, M.; Cano, J.; Ruiz, R.; Caneschi, A.Angew.Chem.Int.Ed. 1998, 37, 135.
[17] Hoskin, B. F.; Robson, R. J.Am.Chem.Soc. 1990,112, 1546.
[18] (a) Kuroda-Sowa, T.; Horrino, T.; Yamamoto, m.; Ohno, Y; Maekawa, M.;Munakata, M. Inorg.Chem. 1997, 36, 6382.
(b) Hennigar, T. L.; Mac Quarrie, D.C; Losier, P.; Rogers, R. D.; Zaworotoko, M. J. Angew.Chem.Int.Ed. 1997, 36,972.
[19] Lu, L.; Paliwala, T.; Lim, S. C; Yu, C.; Niu, T.; Jacobson, A. J. Inorg.Chem.1997, 36, 923.
[20] Fujita, M.; Kwon, Y. J.; Sasaki, O.; Yamaguchi, K. J.Am.Chem.Soc. 1995, 117,7287.
[21] (a) Blake,A.J.; Champness,N.R.; Hubberstey,R; Li,W.-S.; Withersby, M.A.;Schrdder,M.Coord.Chem.Rev. 1999,183,117.
(b) Lu, J.Y; Cahrera,B.R.;Wang,R-J.;Li,J.Inorg.Chem. 1999, 38, 4608.
[22]游效曾，孟庆金，韩万书，配位化学进展.北京：高等教育出版社．2000，第 一版．
[23] Vsehurig, B. KopPenhoefer, W. Buerkle, preparation and determination of Eonfigurationally Pure trans-(2S, 3S)-2, 3-epoxybutane. J.Org.Chem.1980, 4 5(3), 538-541.
[24] VA. Osbom, C. A. Parkerand. M. J. Winter, Hydride to carbine migration at molybdenum; the isomerisation of Mo(H){=C[CH_2]_3NMe}(CO)_2(η-C_5H_5) to Mo(CO)_2{η-CH[CH_2]_3NMe}(η-C_5H_5) J. Chem.Soc.Chem.Commun.19S6, 1185.
[25] S. Chang, R. M. Heid, E. N. Jaeobsen, Enantioseleetive epoxidation of cy elicl, 3-diene Catalyzed by asterically and electronically optimized (salen)??Mn complex. Tetrahedron Lett. 1994, 35, 669-672.
[26] E. M. Hodnett, W. J. Dunn, Strueture-antitumor activity correlation of some Shiff bases. J.Med.Chem. 1970, 13(4), 768.
[27]徐国钧，中国药村学.北京：中国医药科技出版社，1996，793．
[28] Jiang Yao zhong, Zhou Xiang ge, Hu Wen hao, et al, Asymmetric synt hesis Asylllmetric catalytic trimethylsilyleyanation of benzaldehyde bynovel Ti(Ⅳ)-chiral shiff base complexes.Tetrahedron.Asymmetry. 1995, 6(2), 405-408.
[29] G A. Patani, E. J. Lavoie, Bioisosterism: A rational approach in drug desi gn. Chem.Review. 1996, 96, 3147-3176.
[30]牛瑞民，朱小蓉，孙真荣等，萘二甲酞亚氨基席夫碱类液晶材料的三阶非 线性光学性能研究．光学学报.2003，23(1)，17-21．
[31] Schiff H.,Annal.Chem, 1864, 131,118.
[32]钟霞，新型酮类Schiff碱配体金属配合物的研究，兰州大学，博士论文，2007 年
[33]杨高文，夏小平，涂欢等．Schiff碱、咪唑金属配合物合成及抗癌活性的荧 光筛选研究[J]．化学研究与应用，1995，7(1)：41-45．
[34] Praveen K Sharma, RAm N Kanda, et al , Inorg Met Org Chem, 1996,26(7): 1219 -1230
[35] A. Angoso, J. M. Martin-Llorente, J. L. Manzano, et al. Preparation andStudy of aminoOAcid(DL-leucine, L-isoleucine, L-histidine)Schif bases withethyl-a- ketocyclopentyl carboxylate the correspondingCoppe( Ⅱ )Complexes[J]. Inorganic Chimistry Acta, 1992, 195(1): 45-49.
[36]王积涛，许育明，杨晓萍等．含氨基酸Schiff碱-金属手性配合物的合成及 其相关反应的进展[J]，有机化学，1995，15：449-460．
[37] Virinder So Parmar, Amarjit Singh, Kirpal S. Bisht, et al. Schif Base of Amino Oacid Esters as New Substrates for the Enantioselective Enzymaric Hydrolysis and Oaccompanied Asymmetric Transformationsin Aqueous Org anic Solvents[J]. J.Org.Chem, 1996, 61: 1223- 1227.
[38] L E. Khoo, J. P. Charland, E. J Gabe, et al. Synthesis and Strurural Stud ies for a series of Aromatic Schiff Bases Complexes with Triphenyltin Chl oride and Triphenyltin Isothiceyanate[J]. Inorganic Chimistry Acta,1987,128: 139-145.
[39]龚任秋．混合配体络合物化学[J]，杭州大学出版社出版．
[40]毕思玮，李桂芝，刘树祥．联苯乙酮缩氨基硫脲过渡金属配合物的合成及其 对水稻白叶枯病菌的杀菌活性研究[J]．无机化学学报，1998，14(2)：153-156．
[41] S. K. Agarwal, J. P. Tandon. Schiff base derivatives of Lanthanides-Synthesis of La (Ⅲ), Pr(Ⅲ) and Md(Ⅲ) complexes of Alkyllimes Aryllimes derived from 2-hydroxy-l-naphthaldehyde, Synth.React.Inorg.Met-Org.Chem,1974,4, 387-407.
[42] T. N. Sribastava, A. K. S. Chauban. Coordination Complexes of Organotin(Ⅳ) ChlorideswithSchiffbasederivedfrom2-hydroxy-1 -naphthaldehyde. Synth.React. Inorg.Met-Org.Chem, 1977, 7(4): 373-385.
[43] Okafor. E. C. "Synthesis of Some New Tris Rare Earth Chelates of 1-phe nyl-3-methyl-4-benzoylpyrazolone-5 and Their UV, IR and NMRspeetral str??udies", J Inorg Nucl Chem, 1980, 42(8): 1155.
[44]林鸿，冯云龙．苯甲酰丙酮缩邻苯二胺单Schiff碱的合成和晶体结构，浙江 师范大学学报(自然科学版)，2002，25(3)：271-275．
[45] Tadeusz Glowiak and Jaroslaw M. Sobezak.Cystral and molecular structureof 1-phenyl-3-(2-hydroxyPhenylamino)-2-buten-l-one. C_(16)H_(15)N0_2, J.Cryst.and. spectres, 1992, 22(6): 673-678.
[46] Wang J-L, Zhang Sh-M, Miao F-M. 4-[(2-Hydroxyphenylamino)phenyl-Methylene]-5-methyl-2-Phenyl-2H-pyrazol-3(4H)-one, Acta Cryst Section E58,2002, 1365-1366.
[47]祝心德，党元林，王成刚等，2，4二羟基苯甲醛缩硫脲及其配合物的合成 与生物活性研究，无机化学学报，1997，13：68-72．
[48]史赞，娄全龄，张耕，王红．杂环席夫碱化合物及其过渡金属配合物的合成 与表征，无机化学学报，1993，9：303-308．
[49]胡培植，季立才，王亚夫．“二茂铁甲酰丙酮缩氨基硫脲金属配合物研究， 无机化学学报，1996，12(1)：28-29．
[50]、 Siddiq K S A, Bsshar, Tabassum S. Synth.React.Inorg.Met-Org.Chem. 1991,21(2): 217.
[51] Vinodkumar. C. R Synth.React.Inorg.Met-Org.Chem. 1997,27(9): 1365.
[52]李中芳，王素文，傅芳信．几种用途广泛的Schiff碱的合成，化学与粘合， 1996，4，194-197．
[53]金杜玉，侯震，任军，赵国锋．1-芳酰基-4-菊酰基氨基硫脲类化合物的合成 及生物活性，有机化学，1997，17(4)：349-353．
[54] Math. M. Sharma N., Sharma G, Synth. React. Inorg.Met-Org.Chem, 1989, 19(4): 339-356.
[55]张秀英，张有娟．中国稀士学，1999，17(增刊)：392-394．
[56] Xiuying Zhang, Youjuan Zhang, Synth.ReactInorg.Met-Org.Chem, 2000, 30(1): 45-55.
[57]孟庆金，王瑞雪，步修仁，游效曾．新的不对称双Schiff碱镍配合物，高等 化学学报，1990，11(10)：1126-1128．
[58]姚克敏，周文，鲁贵，沈联芳．一种新的不对称Schiff碱与稀土配合物合成 机理及波谱，中国科学(B辑)，1999，29(3)：259-263．
[59] Geodken C L, Reng S M, Melin J A-Norris and Parky, J. Am.Chem.Soc. 1976,98: 8391.
[60] Truecs. T. J and Holm. R. H. J.Am.Chem.Soc, 1971, 93: 85.
[61] Place A A, Ferrare F P, etal.,J. Heterocyclic.Chem, 1980,17, 439.
[62] Maretell A E, Menif. R, Squattrio. P. J, Inorg.Chem, 1989,28: 1133.
[63]陆勤，罗勤慧，梅光泉，沈孟长，孙琼丽二24元大环双核铜配合物的合成 及对超氧化物歧化酶的模拟，化学学报，1993，51(11)：1082-1087．
[64] Nagata Y, Ikawa Y, Maruyama K.J. Chem.Soc. Commun, 1994:471.
[65]肖文，张华新，卢忠林等，酰腙化合物的分类、配位和性质，中山大学学 报(自然科学版)，2001，40(1)：39-42．
[66] Zheng-YinYang, Ru-Do Yang, Fa-Shen Li, Kai-BeiYu Cystal structure and antitumor activity of some rare earth metal complexes with Schiff base, polyhedron, 2000, 19: 2599-2604.
[67]徐国钧．中国药材学，北京：中国医药科技出版社，1996，793．
[68] Kimball Dasd, etal. Heterocyclic Thrombin Inhibitors. U. S. A. No. 5741799, 1998,4,21.
[69]黄春辉．稀土配位化学(第一版)，北京：科学出版社，1997，258．
[70]鲁桂，姚克敏，陈伟国，沈联芳，袁汉珍．稀土与H_2salen配合物的合成与 波谱性质，应用化学，1997，14(4)：1-5
[71]杨正银，王流芳．3d过渡金属的2-羧基丙酸(4-吡啶甲酰基)腙配合物的合成、 表征及导电性研究，化学学报，1993，51(2)：184-190．
[72]孙宏建，李晓燕，崔学桂等．过渡金属Schiff碱配合物研究，高等化学学报 1992，13(9)：1168-1170．
[73]余宝源，孙逸芳，傅本秋等．含硫Schiff碱配合物的研究，高等化学学报， 1989，10(1)．
[74] Panchanans, Hamalaienr, Royps. Synthesis, chiroptical and electrochemical studies of dioxouranium(Vl) complexes of aldimine derivatives of L-/D-histidine and crystal structure of (2,2-bipyridyl)dioxo-(N-vanil-lylidene-L-histidinato) uranium(Vl)-water-methanol(l/l/1), J.Chem.Soc.Dalton. Trans, 1994, 16: 2381.
[75] Bastosm B R, Moreim J C, Fariasp A M. Adosorptive striping voltammetric behaviour of UO_2(Ⅱ) complexed with the Schiff base N,N'-ethylenebis (salicyliden-imine)inaqueous-4-(2-hydroxyethyl)-1-Piperazineethanesulfonicacid medium, Anafy.Chim.Acta, 2000,408: 83.
[76]徐汉红，朱传方，席夫碱及其络合物的可逆热致变色材料．化学通报，2000， 8，15-20．
[77]杜锡光，陈冬菊，王艳等，四种新的水杨醛缩氨基酞著Shiff碱的合成及光 学性质．分子科学学报.2003，19(3)．
[78]赵建章，赵冰，徐蔚青等，水杨醛缩胺类Schiff碱光致变色性质．高等化学 学报,2003，24(2)，24-328．
[79]田颜清，林凤等，手性席夫碱型液晶化合物的合成．应用化学.1995，12(4)， 90．
[80]林静，陈立，林敏等，侧链型Shiff碱液晶研究一单体的合成与聚合．合成 化学.1997，5(1)，49-53．
[81]程鹏，廖代正，阎世平等，外源桥和互变异构对μ-酚氧Shiff碱双核铜(Ⅱ) 配合物磁性的影响．中国科学(B辑)，1996，26(2)，97-104．
[82] Lsseaa, Gennaroa, Vianelloe. Electrochemical reduction of Schiff base ligands H_2salophen, Electrochim Acta, 1997,42: 2065.
[83]魏丹毅，李冬成，姚克敏．稀土元素与β-丙氨酸席夫碱双核配合物的合成、 表征及催化活性，无机化学学报,1998，14(2)：209-214．
[84]姚克敏，吴静，陈德余，沈联芳，袁汉珍．稀土与直连醚-乙酰丙酮Schiff 碱新配合物合成形成机理与波谱，化学学报,1998，56(9)：900-904．
[85]姚克敏，李宁，黄巧虹，沈联芳．Ln(Ⅲ)-Cu(Ⅱ)与直链醚-氨基酸新型Schiff 碱异核配合物，中国科学(B辑)，1998，28(6)：517-523．
[86]刘永红，刘晓岚，石尧成，营盘名．希夫碱在有机合成中的应用研究，有机 化学,2002，22(7)：482-488．
[87]唐波，刘阳，梁芳珍．β-CD-Schiff碱铜(Ⅱ)配合物模拟酶催化光度法的研究， 化学学报，2000，58(8)：1031-1036．
[88]汪焱钢，曹蕾，杨军，叶文法，周青春，卢冰熙．具有植物激素活性的Schiff 碱化合物的研究*(Ⅱ)-噻二唑类Schiff碱的合成及其生物活性．高等化学学 报,1999，20(12)：1903-1905．
[89] Ernest H. GB. 2078, 06 Jan, 1982.
[90]冯英，刘义，谢昌礼，等．D-氨基葡萄糖Schiff碱及其金属配合物的抗菌活性，物理化学学报,1996，12(8)：746．
[91]陈德余，姚克敏．三种Gd~(3+)直链醚席夫碱配合物的EPR波谱研究，中国科 学(B辑)，1993，23(7)：696-701．
[92]姚克敏，陈德余，王晓南．直链醚席夫碱钆配合物EPR特性及其溶剂效应， 中国科学(B辑)，1995，25(11)：1144-1148．
[93] Fridovich I. The Biology of oxygen Radieals Comments, Acc.Chem.Res. 1982,15(7): 200.
[94] Mccord. J. M., Superoxide Dismutase, An Enzymic Function forErythroeuprein(hemoeuprein),J.Biol.Chem, 1969, 244: 6049-6052.
[95]何秀英，吴纪梅，严振寰．邻甲氧基苯甲醛丙氨酸席夫碱及其金属配合物的 合成、表征和对02自由基的抑制作用，无机化学学报，1995，11(3)：302．
[96]陈德余．天冬酰胺缩2，4-二羟基苯甲醛Schiff碱及其稀土配合物的合成 与抗O_2~-研究，化学研究与应用,2001，13(2)：145-148．
[97] Muger W., Boehner B, Dawes D. Pesticdalo-1,2,4-Thiadiaiazolyl Phosphorot hioates, [P] Ger. Offen: 2418363, 1974.
[98]李崇嘉，张文涛，郭国霖，谢有畅．Co(Ⅱ)Schiff碱载氧载氮性能研究，物 理化学学报,1994，10(3)：230-234．
[99]赵吉寿，颜莉，张丽娟．钴(Ⅱ)席夫碱配合物氧载体性能研究，云南民族学 院学报(自然科学版)，1999，8(2)：23-27．
[100]王吉德，王瑶，张翼等．氧载体及其除氧应用研究Ⅰ：乙二胺-Co配合物氧 化作用，应用化学，1998，15(2)：97-99．
[101]张妹明，β-二酮缩芳胺类席夫碱及其过渡金属配合物的合成、表征、反应 机理、结构与性能的研究，硕士论文,天津师范大学，2003年．
[102] Dong, Y.-B., Wang, L., Ma, J.-P., Shen, D.-Z., Zhao, X.-X., Huang, R.-Q.Crystal Growth&Design . 2006, 6, 2475.
[103] Dong, Y.-B.; Wang, L.; Ma, J.-P.; Huang, R.-Q. Inorg.Chem. 2006,45, 9157.
[104] Dong, Y.-B.; Zhang, H.Q.; Ma, J.P.; Su, C.-Y; Huang, R. -Q. CrystalGrowth&Design. 2005, 5, 1857.
[105] Dong, Y.-B.; Zhao, X.; Huang, R.-Q.; Smith, M.D.; zurLoye, H.-C. Inorg.Chem.2004,43, 5603.
[106] Dong, Y.-B.; Zhao, X.; Tang, B.; Wang, H.-Y; Huang, R.-Q.; Smith, MD.; zur Loye, H.-C. Chem.Commun. 2004, 2, 220.
[107] McCarthy P J, Hovey R J, Ueihei.K, Innercomplex chelates: analogs ofbisacetylacetone ethylene diinine and its me-talchelates. J.Am.Chem.Soc.1955(77): 5820-5824.
[108] Laurence J B, Victor W D. Manganese Schiff base complexes synthesisandSpectroscopy of some anion complexes of N,N'-ethylene bis(aeetylacetonelininato) manganese, Inorganic.Chemistry. 1977, 16(6): 1360-1367.
[109] Oezkar S U D, Yildirim L T, Biricik.N, Guemguem. B. Synthesis, structure and??magnetic property of a 2D grid-like copper( Ⅱ )complex with end-on azido and Pyrazine bridges. Journal of Molecular Structure. 2004, 688( 1 -3), 207-211.
[110]王寿武，戴卫东，双乙酰丙酮缩乙二胺的Cu(Ⅱ)，Ni(Ⅱ)金属配合物的合 成，淮阴师范学院学报(自然科学版)，2003，2：4-8．
[111]姚克敏，吴大庆，杨卫红，苯甲酞丙酮缩乙二胺与镧系元素多核本合物的 合成及表征，应用化学,1992，9(4)：812-520．
[112] Hill, HughA.O.; Morallee K.G; Pellizer, G. Univ. Oxford, Oxford,UK. Tr ansmission of electronic effects in some substituted phenylderivatives of c obalt(Ⅲ) bis(aeetylacetone) ethylenediimine complexes. Journal of the Che mical Society [Seetion] A:Inorganic.physical.Theoretical. 1969, 14: 2096-1 01.
[113] Hill H O, Costa G, Pellizer G, Mestroni G, Costa G Electronic transmis sionIn some organometallic derivatives of cobalt(Ⅲ)bis(acetylacetone)ethyl ene diimine(BAE)andbis(salieylaldehyde)ethylenediiminecomplexes.Journal of Organometallic Chemistry. 1968, 11(1): 167-73.
[114] Asadi M, Sarvestani A, Asadi Z, Setoodehkhah .Synthesis and thermodynamic studies of cobalt(Ⅲ)Schiff base complexes.Iran. Synthesis and Reactivity in Inorganic Metal-Organic, and Nano-Metal.Chemistly. 2005, 35(8), 639-644.
[115] Boettcher A, Takeuchi T, Hardeastle K, Meade T.J, Gray H.B. Spectrosco pyand electrochemistry of cobalt(Ⅲ)Schiff base complexes. Inorganic Chemistry, 1997, 36(12): 2498-2504.
[116] Gambarotta S, Corazzo F, Floriani C, Zehnder M.A tetranuclear iron(Ⅱ)-sodium complex formed from the complexation of sodium ethoxide by N, N,-ethylenebis(3-hydroxy-l-methy-ylbut-2-enylid-eneaminato)iron( Ⅱ). Ita ly. Journal of the Chemical Society, Chemical Communications. 1984, (19): 1305-1307.
[117]胡培植，徐霞，孙绍，发张伦．双乙酰丙酮缩乙二胺双核稀土(Ⅲ)配合物的 合成．武汉大学学报(自然科学版)，1995，44(4)：430-432．
[118]李国壁，基于双乙酰丙酮缩乙二胺配体的过渡金属配合物的合成与表征， 硕士论文,华南师范大学，2007年．
[119] Tadanodu Sato, Harumi Takeda, Ken Sakai, Taro Tsubomura*. Two novel typesof metal complexes derived form triped amines and acetyacetone, InorganicaChimicaActa, 1996,246,413-421.
[120] Malachy McCann, Sean Townsend, Michael Devereux, Vickie McKee, Brian Walker~d, Polyhedron, 2001, 20, 2799-2806
[121] Yu-Bin Dong, Qiang Zhang, Li-Li Liu, Jian-Ping Ma, Bo Tang and Ru-Qi Huang, J.Am.Chem.Soc. 2007, 129, 1514-1515
[122] Eisenberg, A.H.; Ovchinnikov, M.V.; Mirkin, C.A. J.Am.Chem.Soc. 2003,125(10), 2836.
[123] (a)Larsen, F.K.; McInnes, E.J.L.; Mkami, H.E.; Overgaard, J.; Piligkos,S.; Rajaraman, G.; Rentschler, E.; Smith, A.A.; Smith, G.M.; Boote, V.;Jennings, M.; Timco, G.A.; and Winpenny, R..E.P., Angew.Chem.Int.Ed.2003, 42(1), 101.
(b) Sun, X.-K.; Johnson, D.W.; Caulder, D.L.; Powers,R.E.; Raymond, K.N.; Wong, E.H. Angew.Chem.Int.Ed. 1999, 38(9),1303.
[124] Que, E.L.; Chang, C.J. J.Am.Chem.Soc. 2006,128(50), 15942.
[125] Debasis, D.; Cheu P.C. J. Chem. Soc.Dalton Trans. 2000,1081.
[126] Zhong-Hai Ni, Li-Fang Zhang, Vassilis Tangoulis, Wolfgang Wernsdorfer,Ai-Li Cui, Osamu Sato, and Hui-Zhong Kou, Inorganic Chemistry, 2007,46 (15) , 6029
[127] Nathan C. Gianneschi, Paul A. Bertin, SonBinh T. Nguyen, and Chad A. Mirkin,J.Am.Chem.Soc. 2003,125, 10508-10509.
[128] Zhao, B.; Cheng, P.; Dai, Y.; Cheng, C; Liao, D.-Zh.; Yan, S.-P.; Jiang, Z.-H.;Wang, G.-L. Angew.Chem.Int.Ed. 2003,42(8), 934.
[129]杨高文，夏小平，涂欢等．化学研究与应用，1995，7(1)：41-45
[130] Praveen K Sharma, Ram N Handa, et al. Synth.React[J]. Inorg Met Org Chem,1996, 26(7): 1219-1230
[131] A.Angoso J.M.Martin-Lorente, Inorganic Chimica Acta, 1992, 195(1): 45-49
[132]王积涛，许育明，杨晓萍等．有机化学，1995，15：449-460
[133] Virinder So Parmar, Amarjit Singh, Kirpal S. Bisht, et al. J Org Chem, 1996, 61:1223 -1227
[134] Jian Gao, Joseph H. Reibenspies, Ralph A. Zingaro, F. Ross Woolley, Arthur E.Martell, and Abraham Clearfield, Inorganic Chemistry, 2005,44, 232-241.
[135] Jonathan L. Sessler, Elisa Tomat, and Vincent M. Lynch, J.Am.Chem.Sos. 2006,128,4184-4185
[136] Jungseok Heo, You-Moon Jeon, and Chad A. Mirkin, J.Am.Chem.Soc. 2007,129, 7712-7713.
[137] Xiu B R, Jackson C R, Derveer D V, et al. Polyhedron, 1997,16: 2991-1995
[138]李锦州，李刚，于文锦，呋喃甲酰吡唑啉酮双席夫碱与铀(Ⅵ)、钍(Ⅳ)配 合物的合成、表征及生物活性，核化学与放射化学，2000，22(1)：19-23．
[139] Lehaire, M. L.; Scopelliti, R.; Piotrowski, H. and Severin, K. Angew.Chem.Int.Ed.2002,41,1419.
[140] Keefe, M. H.; Benkstein, K. D. and Hupp, J. T. Coord.Chem.Rev., 2002, 225,91.
[141] Shan, N.; Vickers, S. J.; Adams, H.; Ward, M. D. and Thomas, J.A. Angew.Chem.Int.Ed, 2004,43, 3938.
[142] Gaynor, D.; Starikova, Z. A. Ostrovsky, S.; Haase, W. and Nolan, K. B.Chem.Commun., 2002, 506.
[143] Du, M.; Guo, Y.-M. Bu, X.-H. Ribas, J. and Monfort, M. NewJ.Chem, 2002,26,645.
[144] Clifford, T.; Danby, A. M.; Lightfoot, P.; Richens, D. T. and Hay, R. W. J.Chem.Soc, Dalton Trans, 2001, 240.
[145] Veauthier, J. M.; Tomat, E.; Lynch, V. M.; Sessler, J. L. Inorg.Chem. 2005, 44,2125.
[146] Yuan, Z. L.; Zhang, Q. L.; Zhu, B. X. Chin. J.Org.Chem. 2006, 26(11), 1590(inChinese). (袁泽利，张奇龙，朱必学， 有机化学， 2006,26(11), 1590.)
[147] X.-F. Zhang, H. Chen, C.-B. Ma, C.-N. Chen & Q.-T. Liu, Dalton Trans., 2006,4047.
[148] McCarthy, P. J.; Hovey, R. J.; Ueno, K.; Martell, A. E.; J.Am.Chem.Soc. 1955, 77, 5820.
[149] Nie, G C. Fine Chemical Intermediates, 2003, 33(5), 32(in Chinese). (聂国朝．精细化工中间体, 2003, 33(5), 32.)
[150] Sheldrick, G. M. SHELXL-97, A Program for Structure Refinement, University of Gottingen, Germany, 1997.
[151] Ozkar, S.; Ulkü, D.; Y(?)ld(?)m, L. T.; Biricik, N.; Gumgüm, B. J.Mol.Structure, 2004,688,207.
[152] HE Xiang, LU Can-Zhong, WU Chuan-De, et al. Jiegou Huaxue (Chinese J. Struct. Chem.), 2005,24(2): 174-178.
[153] Nishtda Y, Takeuchi M, Takahashi K, et al. Chem.Soc. Jpa. 1983,1815-1818
[154] Halper S R, Cohen M. Inorg.Chem, 2005,44:4139-4141
[155] Zhu, Q. Y.; Bian, G. Q.; Zhang, Y.; Dai, J.; Zhang, D. Q.; Lu, W. Inorg.Chim. Acta, 2006,359, 2303.
[156] M.Eddaoudi, J.Kim, N.Rosi, D.Vodik, J.Wachter, M.O.Keeffe, Yaghi, Science 2001,295,469.
[157] Fujita, M.; Kwon, Y.J.; Washizu, S.; Ogura,K. J. Am. Chem. Soc. 1994, 116, 1151.
(b)Lin, W.; Evans, O.R.; Xiong, R.-G.; Wang, Z. J.Am.Chem.Soc. 1998, 120,13272.
[158] (a)Yaghi, D.M.; Li, H. J. Am. Chem. Soc. 1995,117, 10401
(b)Yaghi, D.M.; Li, H.; Groy, T.L. J.Am.Chem.Soc. 1996,118, 9096.
[159] (a) Garder, G.B.; Venkataraman, D.; Moore, J.S.; Lee, S. Nature, 1995, 374, 792.
(b) Garder, G.B.; Kiang, Y.-H.; Lee, S.; Asgaonkar, A.; Venkataraman, D. J.Am.Chem.Soc. 1996, 118, 6946.
(c) Maggard, P.A.; Stern, C.L.; Poeppelmeier, K.R. J.Am.Chem.Soc. 2001,123,7742.
[160] (a) Kahn, O.; Pei, Y.; Verdguer, M.; Renard, J.P.; Sletten, J. J.Am.Chem.Soc. 1988, 110, 782.
(b) Inoue, K.; Hayamizu, T.; Iwamura, H.; Hashizume, D.; Ohashi, Y. J.Am.Chem.Soc. 1996, 118, 1803.
(c) Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.; Achiwa, N.; Hashimoto, Y.; Okawa, H. J.Am.Chem.Soc. 1992, 114, 6974.
[161] (a) Kuroda-Sowa, T.; Horrino, T.; Yamamoto, M.; Ohno, Y.; Maekawa, M.; Munakat M. Inorg.Chem. 1997, 36, 6382.
(b) Munakata, M.; Wu, L.P.; Kuroda-Sowa, T. Bull. Chem. Soc. Jpn. 1997, 70, 1727.
(c) Munakata, M.; Wu, L.P.; Kuroda-Sowa, T.; Maekawa, M.; Moriwaki, K.; Kitagawa, S. Inorg.Chem. 1997, 36, 5416.
(d) Hennigar, .L.; Mac Quarrie, D.C.; Losier, P.; Rogers, R.D.; Zaworotko. M. J. Angew.Chem.Int.Ed.Engl. 1997, 36, 972.
(e) Lloret, F.; Munno, G.D.; Julve, M.; Cano, J.; Ruiz, R.; Caneschi, A. Angew.Chem.Int.Ed. Engl. 1998,37,135.
[162] (a) L.R. MacGillvray, R.H. Groeneman, J.L. Atwood, J.Am.Chem.Soc. 1998, 120, 2627;
(b) G. B. Gardner, D. Venkataraman, J. S. Moore, S.Lee, Nature. 1995, 374, 792;
(c) M. Eddaoudi, J.M. O'Keeffe, O. M.Yaghi, J.Am.Chem.Soc. 2002, 124, 376.
[163] (a) D. M..L.Goodgame, S. Menzer, A. M.Smith, D.J.Viliams,Angew.Chem. Int. Ed. 1995, 34, 574;
(b) B.F.Hoskins, R.Robson, D.A.Slizys,J.Am. Chem. Soc. 1997, 119, 2952;
(c) X.M.Chen, G.F.Liu, Chem.Eur.J. 2002, 8, 4811.
(d) X.J.Luan, Y.Y.Wang, D.S.Li, P.Liu, H.M.Hu, Q.Z.Shi, S.M.Peng, Ang ew. Chem.Int.Ed. 2005, 44, 3864.
[164] Qi-Long Zhang, Xin-Chen Zhu, Yun-Qian Zhang and Bi-Xue Zhu. 1,10-Bis(2-aminophenoxy)decane. Acta Cryst. (2007). E63, o4039
[165] S. Ozkar, D.Ulku, L.T. Yildirim, N. Biricik, B. Gumgum, J.Mol.Structure, 688(2004), 207.
[166] C.T. Zeyrek, A. Elmali, Y. Elerman, I. Svoboda, H. Fuess, Z. Naturforsch. 55b(2000) 1067.
[167] Blake, A. J.; Champness, N. R.; Hubberstey P.; Li, W-S.; Withersby, M. A., Schroder M., Coord. Chem. Rev. 1999, 183, 117; Lindoy L. F.; Atkinson, I. M. Self-Assembly in Supramolecular Systems, Royal Society of Chemistry, Cambridge, UK, 2000; Eddaoudi, M.; Moler, D. B.; Li, H. L.; Chen, B. L.; Reineke, T. M.; O'Keefe, M.; Yaghi, O. M. Acc. Chem. Res. 2001, 34, 319; Yeh, R. M;. Davis, A. V.; Raymond, K.N. in Comprehensive Coordination Chemistry II, Eds. McClevety, J. A.; Meyer, T. J. 2004, 7, 327.
[168] Millward, A. R.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127,17998; Rosi, N. L.; Kim, J.; Eddaoudi, M.; Chen, B.; O'Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc, 2005, 127, 1504; Ockwig, N. W.; Gado-friedrichs, O. D.; O'Keeffe, M.; Yaghi, O. M. Acc. Chem. Res., 2005, 38,176.
[169] Ciurtin, D. M.; Dong, Y.-B.; Smith, M. D.; Barclay, T.; zur Loye, H.-C. Inorg. Chem. 2001, 40, 2825; Janiak, C. Dalton Trans. 2003, 2781; Kitagawa, S.; Khlobystov, A. N.; Brett, M. T.; Blake, A. J.; Champness, N. R.;. Gill, P. M. W; O'Neill, D. P.; Teat, S.J.; Wilson, C.; Schroder, M. J. Am. Chem. Soc, 2003, 125, 6753; Uemura, T.; Kitagawa, S. J. Am. Chem. Soc, 2003, 125, 7814; Dong, Y.-B.; Zhao, X.; Huang, R.-Q. Inorg. Chem. 2004, 43, 5603; Dong, Y.-B.; Zhao, X.; Tang, B.; Wang, H.-Y; Huang, R.-Q.; Smith, M. D.; zur Loye, H.-C. Chem. Comm. 2004, 2. 220; Zhao, X.; Xiao, B.; Fletcher, A. J.; Thomas, K. M.; Bradshaw, D.; Rosseinsky, M. J. Science, 2004, 306, 1012.; Kitaura, R.; Noro, S.-I. Angew. Chem., Int. Ed. 2004, 43, 2334; A. J. Fletcher, E. J. Cussen, Bradshaw, D.; Rosseinsky, M. J.; Thomas, K. M. J. Am. Chem. Soc, 2004, 126, 9750; Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kato, K., Sakata, M.; Kobayashi, T. C. Angew. Chem. Int. Ed., 2005, 44, 920; Zaworotko, M. J. Cryst. Growth Des. 2007, 7, 4; Zaworotko, M. J. Cryst. Growth Des. 2007, 7, 1154; McManus, G. J.; Wang, Z.; Beauchamp, D. A.; Zaworotko, M. J.; Chem. Comm. 2007, 5212; Perry, J. J.; Kravtsov, V. C.; McManus, G. J.; Zaworotko, M. J. J. Am. Chem. Soc 2007, 129, 10076; Won T.-J.; Clegg J. K.; Lindoy, L. F.; McMurtrie, J.,C. Cryst. Growth Des. 2007, 7, 972; Nouar, F.; Eubank, J. F.; Bousquet, T.; Wojtas, L.; Zaworotko, M. J.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 1833; Cairns, A. J.; Perman, J. A.; Wojtas, L.; Kravtsov, V. C.; Alkordi, M. H.; Eddaoudi, M.; Zaworotko, M. J. J. Am. Chem. Soc. 2008, 130, 1560.
[170] Khlobystov, A. N.; Blake, A. J.; Champness, N. R.; Lemenovskii, D. A.; Majouga, A. G.; Zyk, N. V.; Schroder, M. Coord. Chem. Rev. 2001, 222, 155; Inoue, K.; Imai, H.; Ghalsasi, P. S.; Kikuchi, K.; Ohba, M.; Okawa, H.; Yakhmi, J. V. Angew. Chem., Int. Ed. 2001,40,4242; Masaoka, S.; Furukawa, S.; Chang, H. C.; Mizutani, T.; Kitagawa, S. Angew. Chem., Int. Ed. 2001, 40, 3817; Armstrong, R. S.; Atkinson, I. M.; Carter, E.; Mahinay, M. S.; Skelton B. W.; Turner, P.; Wei, G.; White, A. H.; Lindoy, L. F. Proc. Nat. Acad. Sci. 2002, 99, 4987; Cao, R.; Sun, D.; Liang. Y.; Hong, M.; Tatsumi, K.; Shi, Q. Inorg. Chem. 2002,41,2098; Dai, J.-C.; Wu, X.-T.; Fu, Z.-Y.; Cui, C.-P.; Hu, S.-M.; Du, W.-X. Wu, L.M.; Zhang, H.-H.; Sun, R.-O. Inorg. Chem. 2002,41, 1391; Batten, S. R.; Murray, K. S. Coord. Chem. Rev. 2003, 246, 103; Carlucci, L.; Ciani, G.; Proserpio, D. M. Coord. Chem. Rev. 2003, 246, 247; Kitaura, R.; Fujimoto, K.; Perry, J. J.; McManus, G J.; Zaworotko, M. J. Chem. Commun. 2004, 2534; 41, 133; Chen, B.; Fronczek, F. R.; Maverick, A. W. Inorg. Chem. 2004, 43, 8209: Lee, E. Y.; Jang, S. Y.; Suh, M. P. J. Am. Chem. Soc. 2005, 127, 6374; Mulana, Y.; Kepert, C. J.; Lindoy, L.F.; Parkin, A.; Turner, P. Dalton Trans. 2005, 1598; Domasevitch, K. V.; Vreshch, V. D.; Lysenko, A. B.; Krautscheid, H. Acta Cryst. 2006, C62, m443; Kepert, C. J. Chem. Commun. 2006, 695; Won T.-J.; Clegg, J. K.; Bray, D. J.; Gloe, K.; Gloe, K.; Hayter, M. J.;Jolliffe, K. A.; Lawrance, G. A.; Meehan, G V.; McMurtrie, J. C.; Lindoy, L. F.; Wenzel, M. Dalton Trans. 2007, 1719; Wang, Z.; Kravtsov, V. C.; Walsh, R. B.; Zaworotko, M. J.; Cryst. Growth Des. 2007, 7, 1154; McManus, G J.; Wang, Z.; Beauchamp, D. A.; Zaworotko, M. J.; Chem. Commun. 2007, 5212; Perry, J. J.; Kravtsov, V. C.; McManus, G J.; Zaworotko, M. J. J. Am. Chem. Soc. 2007, 129,10076; Sarkar, M.; Biradha, K. Cryst. Growth Des. 2007, 7, 1318; Nouar, F.; Eubank, J. F.; Bousquet, T.; Wojtas, L.; Zaworotko, M. J.; Eddaoudi, M. J. Am. Chem. Soc. 2008, 130, 1833; Cairns, A. J.; Perman, J. A.; Wojtas, L.; Kravtsov, V. C.; Alkordi, M. H.; Eddaoudi, M.; Zaworotko, M. J. J. Am. Chem. Soc. 2008, 130, 1560.
[171] Ma, L.; Evans, O. R.; Foxman, B. M.; Lin, W. Inorg. Chem. 1999, 38, 5837; Dai, J.-C; Wu, S.-T.; Fu, Z.-Y.; Cui, C.-P.; Hu, S.-M.; Du, W.-X.; Wu, L.-M.; Zhang, H.-H.; Sun, R.-Q. Inorg Chem. 2002,41,1391; Wen, L.; Lu, Z.; Lin, J.; Tian, Z; Zhu, H.; Meng, Q. Cryst. Growth Des. 2007, 7, 93; McManus, G. J.; Perry, J. J.; Perry, M.; Wagner, B. D.; Zaworotko, M. J. J. Am. Chem. Soc. 2007, 129, 9094.
[172] Zhang, L.-J.; Yu, J.-H.; Xu, J.-Q.; Lu, J.; Bie, H.- Y.; Zhang, X. Inorg. Chem. Comm. 2005, 8, 638.
[173] Maspoch, D.; Ruiz-Molina, D.; Veciana, J. J. Mater. Chem. 2004, 14, 2713; Lecren, L.; Wernsdorfer, W.; Li, Y.-G.; Vindigni, A.; Miyasaka, H.; Clérac, R. J. Am. Chem. Soc. 2007, 129, 5045.
[174] Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y J.; Kim, K. Nature, 2000,404, 982.
[175] Rowsell, J. L. C.; Yaghi, O. M. Angew. Chem. Int. Ed. 2005, 44, 4670; Wong-Foy, A. G.; Matzger, A. J.; Yaghi, O. M. J. Am. Chem. Soc, 2006, 128, 3494; Liu, Y.; Brown, C. M.; Neumann, D. A.; Long, J. R. J. Am. Chem. Soc. 2006,128,1687; Clancy, Y L.; Lobkovsky, E. B.; Yaghi, O. M.; Dai, S. Angew. Chem. Int. Ed. 2006, 45, 1390; Collins, D. J.; Zhou, H.-C. J. Mater. Chem. 2007, 17, 3154; Furukawa, H,; Miller, M. A.; Yaghi, O. M. J. Mater. Chem. 2007, 17,
??3197; Lin, X.; Jia, J.; Hubberstey, P.; Schroder, M.; Champness, N. R.CrystEngComm. 2007, 9,438.; Dinca, M.; Dailly, A.; Jia, J.; Lin, X.; Wilson, C;Blake, A. J.; Champness, N. R.; Hubberstey, P.; Walker, G; Cussen, E. J.;Schroder, M. Chem. Comm. 2007,840; Chen, B.; Liang, C; Yang, J.; Contreras,D. S.; Banerjee, R; Bo Wang, A. P.; Knobler, C.; Furukawa, H.; O'Keeffe,M.;Yaghi, O. M. Science, 2008, 319,939.
[176] Lee, E.; Kim, J.; Heo, J.; Whang, D.; Kim, K. Angew. Chem. Int. Ed. 2001, 40,399.
[177] Zaworotko, M. J. Angew. Chem. Int. Ed. 2000, 39,3052.
[178] Pan, L.; Adams, K. M; Hernandez, H. E.; Wang, X.; Zheng, C.; Hattori, Y.;Kaneko, K. J. Am. Chem. Soc. 2003,125, 3062.
[179] (a) G.S.Hanan; J-M.Lehn; N.Krytsakas; J.Fisher, Chem. Commun, 1995, 765;
(b)D.M.Bassani, J-M.Lehn; G.Baum, D.Fenske, Angew. Chem. Int. Ed, 1997, 36,1845
[180]肖冬荣，新型螺旋体配合物的合成，结构和性质研究，东北师范大学，博 士论文，2007年
[181] Patra, S.; Mondal, B.; Sarkar, B.; Niemeyer, M; Lahiri, G. K. Inorg. Chem. 2003,42,1322.