席夫碱配位聚合物的水热合成、表征、及其性质研究
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摘要
本论文工作运用水热合成法,通过调节反应物的比例、温度、溶剂、酸碱度和反应时间,合成了两个系列十一种席夫碱配位聚合物,Co_3(salpn)_2(CO_2)_2 (1)、[Ni_2Cd(salpn)_2(CO_2)_2(H_2O)_2](H_2O)_2 (2)、Zn_2Cd(salpn)_2(CO_2)_2 (3)、Co_3(salpn)_2(OAc)_2 (4)、[Zn_2Ni_3(salpn)_2(dca)_2]_n (5)、[CdNi_2(salpn)_2(dca)_2]_n (6)、[Co_2Zn(sapln)_2(dca)_2]_n (7)、[Co_2Cd (sapln)_2(dca)_2]n (8) (salpn = N,N’– bis(salicylidene) -1,3– diamino propane , dca = dicyanamide) , [Zn(C6_H_5N) (C_8H_3NO_4)·2H_2O]_n (9) [Cd(C_6H_5N)(C_8H_3NO_4)·H_2O]_n (10)和[Co(C_6H_5N)(C_8H_3NO_4)·2H_2O]_n (11)。通过元素分析和红外光谱对这些配合物进行了表征,并用X射线单晶衍射仪测定了其晶体结构。通过热重分析仪来测定其稳定性,热重分析表明,水杨醛和丙二胺形成的席夫碱配合物都具有较高的稳定,而吡啶醛和间苯二甲酸胺形成的席夫碱配合物稳定性较弱。
In our work,two series of Schiff base coordination polymers have been synthesized with hydrothermal method by adjusting the ratio of the reactants, temperature, solvent, pH value and reaction time , which are Co_3(salpn)_2(CO_2)_2 (1)、[Ni_2Cd(salpn)_2(CO_2)_2(H_2O)_2](H_2O)_2 (2)、Zn_2Cd(salpn)_2(CO_2)_2 (3)、Co_3(salpn)_2(OAc)_2 (4)、[Zn_2Ni_3(salpn)_2(dca)_2]_n (5)、[CdNi_2(salpn)_2(dca)_2]_n (6)、[Co_2Zn(sapln)_2(dca)_2]_n (7)、[Co_2Cd (sapln)_2(dca)_2]n (8) (salpn = N,N’– bis(salicylidene) -1,3– diamino propane , dca = dicyanamide) , [Zn(C6_H_5N) (C_8H_3NO_4)·2H_2O]_n (9) [Cd(C_6H_5N)(C_8H_3NO_4)·H_2O]_n (10)和[Co(C_6H_5N)(C_8H_3NO_4)·2H_2O]_n. (11). All the complexes have been characterized by elemental analyses, IR spectra and X-ray diffraction analyses. The thermal analyses shown that the former eight complexes were thermal stabler than the latter three ones.
In our work,two series of Schiff base coordination polymers have been synthesized with hydrothermal method by adjusting the ratio of the reactants, temperature, solvent, pH value and reaction time , which are Co_3(salpn)_2(CO_2)_2 (1)、[Ni_2Cd(salpn)_2(CO_2)_2(H_2O)_2](H_2O)_2 (2)、Zn_2Cd(salpn)_2(CO_2)_2 (3)、Co_3(salpn)_2(OAc)_2 (4)、[Zn_2Ni_3(salpn)_2(dca)_2]_n (5)、[CdNi_2(salpn)_2(dca)_2]_n (6)、[Co_2Zn(sapln)_2(dca)_2]_n (7)、[Co_2Cd (sapln)_2(dca)_2]n (8) (salpn = N,N’– bis(salicylidene) -1,3– diamino propane , dca = dicyanamide) , [Zn(C6_H_5N) (C_8H_3NO_4)·2H_2O]_n (9) [Cd(C_6H_5N)(C_8H_3NO_4)·H_2O]_n (10)和[Co(C_6H_5N)(C_8H_3NO_4)·2H_2O]_n. (11). All the complexes have been characterized by elemental analyses, IR spectra and X-ray diffraction analyses. The thermal analyses shown that the former eight complexes were thermal stabler than the latter three ones.
引文
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