循环冷却水系统环保型防垢防腐蚀剂的研制
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摘要
本文根据绿色化学原理，研究设计了以水为溶剂，以马莱酸酐、丙烯酸、次亚磷酸钠为原料，过氧化氢为引发剂，添加催化剂一步合成的低磷有机聚膦羧酸型多元共聚物缓蚀阻垢剂的方法，最佳工艺条件及合适的物料比，并对产品进行了缓蚀阻垢性能的测试，总磷含量(以PO_4~(3-)计≤1.46％)，经静态、动态实验及现场试验结果表明：该产品具有优异的缓蚀阻垢性能，含磷低，符合环保要求，具有广阔应用前景。
研究的主要内容是，以水为溶剂聚羧酸反应高效的催化剂；筛选以水为溶剂聚羧酸反应的引发剂；聚合物单体及物料比的选择；聚合物磷化条件试验；对产品进行结构分析、分子量测定、缓蚀阻垢性能的测试、未反应单体的测定、总磷含量的测定。设计出条经济、高效的工艺合成路线；确定聚合物的分子量。
With principle of green chemistry, we design a one-step synthesis method todevelop a polybasic copolymer, phosphonic carboxylic acid, which takes water as solution,malefic anhydride, acrylic acid and sodium hypophosphite as raw materials and hydrogenperoxide as initiator with some catalyst added. Optimized processing conditions andproper mole ratio of reactants also have been established, and the total phosphorouscontent is less than 1.46％(based on PO_4~(3-)). The results of static, dynamic and field testsshow that this kind of product has a excellent corrosion inhibition and scale inhibition, lowphosphorous content, meets requirements of environment protection and has a promisingapplication future.
The major research fields is to produce polycarboxyl acid based on aqueous solvents, including developing catalysts with high efficiency, screening initiator, determining conditions for polymer phosphorization, analyzing structure analysis,measuringmolecular weight, testing corrosion inhibition and scale inhibition ofproduct, metering unreacted monomer, assaying total phosphorous content, establishing a economic,effective synthesis process and evaluation molecular of polymers produced.
研究的主要内容是，以水为溶剂聚羧酸反应高效的催化剂；筛选以水为溶剂聚羧酸反应的引发剂；聚合物单体及物料比的选择；聚合物磷化条件试验；对产品进行结构分析、分子量测定、缓蚀阻垢性能的测试、未反应单体的测定、总磷含量的测定。设计出条经济、高效的工艺合成路线；确定聚合物的分子量。
With principle of green chemistry, we design a one-step synthesis method todevelop a polybasic copolymer, phosphonic carboxylic acid, which takes water as solution,malefic anhydride, acrylic acid and sodium hypophosphite as raw materials and hydrogenperoxide as initiator with some catalyst added. Optimized processing conditions andproper mole ratio of reactants also have been established, and the total phosphorouscontent is less than 1.46％(based on PO_4~(3-)). The results of static, dynamic and field testsshow that this kind of product has a excellent corrosion inhibition and scale inhibition, lowphosphorous content, meets requirements of environment protection and has a promisingapplication future.
The major research fields is to produce polycarboxyl acid based on aqueous solvents, including developing catalysts with high efficiency, screening initiator, determining conditions for polymer phosphorization, analyzing structure analysis,measuringmolecular weight, testing corrosion inhibition and scale inhibition ofproduct, metering unreacted monomer, assaying total phosphorous content, establishing a economic,effective synthesis process and evaluation molecular of polymers produced.
引文
[1] 中国腐蚀与防护学会编．工业冷却水系统中金属的腐蚀与防护[M]．北京：化学工业出版社．1993．10．
[2] 黄伯芬，王刚．ZG-93丙烯酸共聚物阻垢分散剂的研制及阻垢机理探讨[J]．化学世界，1996，(2)：88．
[3] 阎乃本，晶体生长的物理基础[M]．上海科学技术出版社，1980．
[4] 朱志良，张冰如，苏耀东等．PBTCA及马丙共聚物对碳酸钙垢阻垢机理的动力学研究[J]．工业水处理，2000，20(2)：20-23．
[5] 解鲁生，锅炉水处理原理与实践[M]．北京：中国建筑工业出版社，1997．
[6] 天津大学物理化学教研室，物理化学[M]．北京：人民教育出版社，1979．
[7] 郭德济，曾月香．马来酸酐-丙烯酰胺共聚物阻垢效果的研究[J]．工业水处理，1993．16(2)：16-17．
[8] Zahid Amjad. Calcium Sulfate Dihydrate Scale Formation on Heat Exchanger Surfaces in the Presence of Inhibitors[J].Environmental Treatment&Control, 1989,11:52-55.
[9] B R Smith and F Sweet. The Crystallization of Calcium Sulfate Dihydrate[J]. J. Coll. and Interfac. Sci., 1971, 37: 612-618.
[10] 林明鹤．冷却水处理用缓蚀阻垢剂的研制进展[J]，工业水处理，1987，7(3)：3-6．
[11] 朱志良，张冰如，苏耀东等．聚丙烯酸及马丙共聚物对硫酸钙垢阻垢机理的结晶动力学研究[J]．工业水处理，2000，20(12)：17-21．
[12] 索振莉．有机磷酸的缓蚀和阻垢作用[J]，工业水处理，1999．19(5)：19-20．
[13] 张庆闲，杨国华等．以水为溶剂马来酸酐—丙烯酸共聚物的合成及阻垢性能研究[J]，工业水处理，2000．20(12)：26-28．
[14] 熊容春等．水处理剂合成工艺的绿色化研究—水解聚马来酸酐的绿色合成技术[J]，工业水处理，2001，2(5)：12-14．
[15] Johnson D, Mizuno W G. Treatment of water used in heat transfor eqyipment[P]. US Pat 3715307, 1973.
[16] Li Jia. Study of water repellent and oil-soluble corrosion inhibitor[J]. Electroplating Finishing. 2000, 19(5): 24-27.
[17] Ao Jianping, Sun GuoZhong et. Progress of Ressarch for Corrosion inhibitors of Cleaning in Hydrochloric Acid[J]. Journal of Nanchang Institute of Aeronautical Technology. 2000, 14(1):50.
[18] 汪晓军，肖锦．天然高分子接枝吡啶季钱盐缓蚀剂的研究[J]．现代化工．1998，4：23-24．
[19] Zidovec D F. Prabhu P M. Calcium carbonate scale controlling method[P]. US 5562830, 199 6-10-08.
[20] Ross R J, Low K C, Shannon J E. Polyaspartate scale inhibitors biodegradable alternatives to polyacrylates[J], Material Performance. 1997. (4):52-57.
[21] 王勤娜，张国华．绿色阻垢剂ZU-101的制备与阻垢性能的研究[J]．石油化工．2000，6：447-448．
[22] 韩晶，张小燕，余中．我国水处理剂的研究与应用现状展望．精细石油化工[J]．2000，5(3)：38．
[23] 杨文忠等．循环冷却水处理新化学药剂的发展．工业用水与废水[J]．2000，31：6．
[24] Chartes L K. New corrosion inhibitors for high temperature applications[J]. Materials perf ormance. 1999, 38(5):60-64.
[25] 胡玉国．水处理缓蚀剂应用现状发展方向[J]．化工进展．2000．5：29-31．
[26] 金熙等．工业水处理技术问答及常用数据[M]．北京：化学工业出版社，1997：315．
[27] 吴纯素．化学转化膜[M]．北京化学工业出版社[J]，1988：118．
[28] Wang Cheng, Jiang Feng, Lin HaiChao. The Inhibition For LY12 Alloy By Ammonium Heptamolybdate. Corrosion & Protection[J]. 2001, 22(3): 115.
[29] Li YuChun Et. Experimental Study of Using Mollybdate in Industry Cooling Water[J]. Nor th China Electric Power.2001, 3(4).
[30] Zhang Wenzheng. The Prospect of Appl for Sodium Molybdate Ication[J]. China Molybden um Industry.2000, 24(4):7-11.
[31] 郭良生．自来水、海水和食盐溶液中新型碳钢缓蚀剂的研究．腐蚀与防护[J]．1999，20(7)：321
[32] 黄霓裳．钢铁新型复合缓蚀剂．腐蚀与防护[J]．1999，20(6)：264-273．
[33] Sumitomo Metal Industries Ltd. Corrosion Inhibitors for an acidizing solution for petro leum or natural gas wells[A]. Jpn. Kokai Tokkyo Kobo JP 59, 228, 591184, 228, 591] 21 Dec. 1984, 4-11.
[34] Li Yan, Zhang GuanYong, Lu Zhu. Corrosion Inhibition Mechanism of Carbon Steel With Tungstate in deaerated neutral aquatic medium. Journal of Chinese Society for Corrosion and Protection[J]. 2000, 20 (6): 349-354.
[35] Robjtaille D R. Sodium molybdate as a Corrosion Inhibitor in Cooling tower Water[J]. Materials performance. 1976,15(11):40-52.
[36] Vukasovich M S, Farr J P GMolybdate in Corrosion Inhibitor A Review[J].Materials performance. 1986,25(5):9-18.
[37] Vukasovich M S. Applications for the versatile molybdate Inhibitor[J]. Materials performance. 1990,29(5):48-51.
[38] Tang Yongming, Yang Wenzhong. Study on synergistic effects of molybdate[J]. Journal of Nanjing university of chemical technology.2001,23 (2):64-66.
[39] Ni TieJun, Cai LanKun. Effects of steel oxide on silicate interphase corrosion inhibitor[J]. Journal of east china university of science and technology. 2001, 27 (1):80-83.
[40] Gao LiXin, Zhang DaQuang et al.Preparation performance of copper corrosion inhibitors containing benzotriazole and thiadiazole moiety [J]. Journal of east china university of science and technology. 2001,27 (1):84-88.
[41] Zhou GuoDing, Ma ZhiChuan et al.Corrosion Inhibitor of copperwith benzotriazole and tolytriazole in a 3% NaCl solution[J].Bull Eleochem.1991, 7 (2):60-74.
[42] Zhou GuoDing. Shao Hua and Loo B H. A Study of the copper Electrode behaviour in borax buffer solutions contaiing chloride ions and benzotriazole-type inhibitors by voltammetry and photocurrent response method[J].J Electroanal chern. 1997, 421:129.
[43] Xu QunJie. Zhou GuoDing et al.Corrosion Inhibitor of BTA and its derivative 4 CBTA on copper electrode in 3% NaCl solution.The Chinese Journal of nonferrous metals[J].2001, 11(1):135-137.
[44] Zheng Jiaxin. The present situation and of research and application of Inhibitors in Chins[J].Corrosion&Protection. 1997, 18(3): 132-136.
[45] Zheng Jiaxin, Zhao J G Control of corrosion by inhibitors in drilling muds containing high concentration of H_2S[J].Corrosion. 1993,49(2): 170-174.
[46] Ning S G. Shi M L, et al. The relationship of corrosion inhibitor efficiency on steel in acide with electron density and the energy of frontical orbital of imidzoline derivatives[J].Chinese Society for Corrosion&Protection. 1990,10(4):383-390.
[47] Sastri V S, Perumareddi J R. Selection of corrosioninhibitors for use in sour media[J].Corrosion, 1994,50(6):432-437.
[48] 张林,邓春光．水溶性缓蚀剂HS-2000研究开发．石油化工腐蚀与防护[J]．2001,18(3)：30—34．
[49] Sedahmaed G H. 5SEIC,1980:15.
[50] Guo Ying, Song Shizhe. Synergistic inhibitor of Tw-20 and polyacrylic acid on corrosion in hydrochloric acid. Journal of Chemical Industry and Engineering[J]. 2001, 52 (3):262-265.
[51] 郭良生，黄霓裳等．一种抑制钢铁在自来水中腐蚀的新型缓蚀剂．水处理信息报导．2000，5：2-3．
[52] Sastri V S. Packwood R H, Brown J R, et al. Corrosion inhibitor by some oxyanions in coal-water slurries[J]. Br Corrosion J. 1989, 24(1):30-35.
[53] 郭良生，黄霓裳等．一种抑制钢铁在海水中腐蚀的新型缓蚀剂[J]．水处理信息报导．2000，5：4-5．
[54] 李宇春，龙沟洁等．复配钥酸盐缓蚀剂在自来水中的电化学研究[J]．全面腐蚀控制．14(6)：42-44．
[55] 贾能铀，陆柱．水煤气系统钨酸盐的缓蚀作用[J]．华东化工学院学报．1990，16(30)：309-331．
[56] Baiiramov A Kh, Verdiev S Ch. Oxidising type inhibitors for protection of aluminum and steel surfaces in sodium chloride solutions[J]. Br Corrosion J. 1992, 27 (2): 128-134.
[57] Kenneth, Soeder, Joseph S, Roli. Molbdate-based cooling water treatment. NewDevelopments which expand their application areas[C]. iwc-87-12: 115-118.
[58] Kurosawa K, Fukushima T. Effects ofpH of an Na_2MoO_4-H_3PO_4 type aqueous solution on the fomation of chemical conversion coatings on steels[J]. Corrosion Science. 29(9): 1103-1114.
[59] 朱锦棠．一种复合水处理剂[M]．CN40769．2000，1．12．
[60] 赵宏泽，林整．碳钢在高温氯酸盐中的缓蚀剂保护研究．劳动安全与健康[J]．2001，1：38-39．
[61] 鲍其戴．我国水处理剂的现状与未来[J]．上海化工．1999，4(16)：4．
[62] 项成林．我国大化肥厂循环冷却水处理现状[J]．工业水处理．1992，12．
[63] 李裕芳．我国循环冷却水处理技术的回顾及展望[J]．工业水处理．1991，1．
[64] 张淑云等．多元共聚物马来酸醉与丙烯酸的合成及其阻垢性能的研究技术[J]．1996，22 (1)：35-37．
[65] 沈敬芝，赵彦生．一种新型防垢剂的合成与研究．太原工业大学学报[J]．1988，19(4)：76-83
[66] 汪祖模．水质稳定剂[J]．华东化工学院出版社，1991：1-3
[67] 沈敬芝等．MA-AA-AM共聚物的合成及阻垢效果[J]．太原工业大学学报．1994，25(2)：60-64．
[68] Lu Zhifang, Dong wei et al. The scale and corrosion Inhibiton of polyepoxysuccinic acid. Industrial Water Treatmen[J]. 2001, 21(3): 23-25.
[69] J Michael Brown, John F Me Domell. Method of controlling scale formation in aqueous systems[p]. US 5147555, 1992.
[70] Foknmoto Yasuhisa, TangiuchiTtskao. Water treating agents for prevention of metal corrosion and scale generation[p]. JP 04166298.
[71] Xiao Xingcheng, Chang Chunzhi et al. Study of complex scale and corrosion Inhibitor for effluent reused as circulating cooling water[J]. Idustrial Water Treatment.2000, 22(4):42-44.
[72] 鲍其鼐，我国冷却水处理剂二十年[J]．工业水处理．2000，20(增刊)：5-8．
[73] 胡玉国．水处理缓蚀剂应用现状发展方向[J]．化工进展．2000，5：3 1．
[74] 郑家炎．缓蚀剂的研究现状及其应用[J]．腐蚀与防护．1997，1：34-37．
[75] 李庆．碱性循环水处理技术[J]．沪天化科技．2000，4：302-306．
[76] 李瑞华．工业循环冷却水处理药剂进展[J]．工业水处理．1991，5．
[77] 李继友．水处理阻垢剂的研究和发展[J]．天津化工．2001，2：22-23．
[78] 王勤娜，施宝昌等．工业循环冷却水缓蚀阻垢剂的发展状况[J]．化进展．2001，5：26-27．
[79] 崔晓明．国内外水处理药剂研究现状与发展[J]．石化工业水处理技术．1998，(3)：72-76．
[80] 何铁林．国外循环冷却水处理技术进展[J]．工业水处理．1992，4．
[81] 魏存发，吕红等．环冷却水阻垢剂的现状与发展．石化技术与应用[J]．2000，10．18(5)：302-304．
[82] Tim Cavanaugh. Chemical Marker Reporter. 1994, 245, (8).
[83] Ross J. Low KC. Shannon J E. Materials performance. 1997, (2): 53.
[84] 刘明等．国内外水稳定剂现状及应采取的措施[J]．齐鲁石油化工．2001，29(1)：75-78．
[85] 王胜利等．HZ缓蚀阻垢剂研制与应用[J]．石油钻采工艺．2001，23(4)：75-76．
[86] 刘烈炜等．油水两相共存下咪哇琳缓蚀剂的缓蚀效率[J]．油气田地面工程．2001，20(1)：25-26．
[87] 梁平等．天然气管线内腐蚀影响因素分析[J]．河南石油．2000，6：28-30．
[88] 姚晓．国内外气田开发中管内二氧化碳腐蚀研究进展[J]．油气储运．1996，15(2)：18-23．
[89] Cai Rudi, Jiang Ping. Harm of hydrogen sulfide to circulating cooling water systems and its countermeasures[J]. Industrial Water Treatment. 2001, 21 (4):40-42.
[90] Chen Jun. Research on XYH-1 Corrosion Inhibitor for caiman oilfield[J]. Jourmal of Xinjiang petroleum institute. 2001, 13 (2):49-51.
[91] 张天胜．表面活性剂应用技术[M]．北京：化学工业出版社，2001：414-421．
[2] 黄伯芬，王刚．ZG-93丙烯酸共聚物阻垢分散剂的研制及阻垢机理探讨[J]．化学世界，1996，(2)：88．
[3] 阎乃本，晶体生长的物理基础[M]．上海科学技术出版社，1980．
[4] 朱志良，张冰如，苏耀东等．PBTCA及马丙共聚物对碳酸钙垢阻垢机理的动力学研究[J]．工业水处理，2000，20(2)：20-23．
[5] 解鲁生，锅炉水处理原理与实践[M]．北京：中国建筑工业出版社，1997．
[6] 天津大学物理化学教研室，物理化学[M]．北京：人民教育出版社，1979．
[7] 郭德济，曾月香．马来酸酐-丙烯酰胺共聚物阻垢效果的研究[J]．工业水处理，1993．16(2)：16-17．
[8] Zahid Amjad. Calcium Sulfate Dihydrate Scale Formation on Heat Exchanger Surfaces in the Presence of Inhibitors[J].Environmental Treatment&Control, 1989,11:52-55.
[9] B R Smith and F Sweet. The Crystallization of Calcium Sulfate Dihydrate[J]. J. Coll. and Interfac. Sci., 1971, 37: 612-618.
[10] 林明鹤．冷却水处理用缓蚀阻垢剂的研制进展[J]，工业水处理，1987，7(3)：3-6．
[11] 朱志良，张冰如，苏耀东等．聚丙烯酸及马丙共聚物对硫酸钙垢阻垢机理的结晶动力学研究[J]．工业水处理，2000，20(12)：17-21．
[12] 索振莉．有机磷酸的缓蚀和阻垢作用[J]，工业水处理，1999．19(5)：19-20．
[13] 张庆闲，杨国华等．以水为溶剂马来酸酐—丙烯酸共聚物的合成及阻垢性能研究[J]，工业水处理，2000．20(12)：26-28．
[14] 熊容春等．水处理剂合成工艺的绿色化研究—水解聚马来酸酐的绿色合成技术[J]，工业水处理，2001，2(5)：12-14．
[15] Johnson D, Mizuno W G. Treatment of water used in heat transfor eqyipment[P]. US Pat 3715307, 1973.
[16] Li Jia. Study of water repellent and oil-soluble corrosion inhibitor[J]. Electroplating Finishing. 2000, 19(5): 24-27.
[17] Ao Jianping, Sun GuoZhong et. Progress of Ressarch for Corrosion inhibitors of Cleaning in Hydrochloric Acid[J]. Journal of Nanchang Institute of Aeronautical Technology. 2000, 14(1):50.
[18] 汪晓军，肖锦．天然高分子接枝吡啶季钱盐缓蚀剂的研究[J]．现代化工．1998，4：23-24．
[19] Zidovec D F. Prabhu P M. Calcium carbonate scale controlling method[P]. US 5562830, 199 6-10-08.
[20] Ross R J, Low K C, Shannon J E. Polyaspartate scale inhibitors biodegradable alternatives to polyacrylates[J], Material Performance. 1997. (4):52-57.
[21] 王勤娜，张国华．绿色阻垢剂ZU-101的制备与阻垢性能的研究[J]．石油化工．2000，6：447-448．
[22] 韩晶，张小燕，余中．我国水处理剂的研究与应用现状展望．精细石油化工[J]．2000，5(3)：38．
[23] 杨文忠等．循环冷却水处理新化学药剂的发展．工业用水与废水[J]．2000，31：6．
[24] Chartes L K. New corrosion inhibitors for high temperature applications[J]. Materials perf ormance. 1999, 38(5):60-64.
[25] 胡玉国．水处理缓蚀剂应用现状发展方向[J]．化工进展．2000．5：29-31．
[26] 金熙等．工业水处理技术问答及常用数据[M]．北京：化学工业出版社，1997：315．
[27] 吴纯素．化学转化膜[M]．北京化学工业出版社[J]，1988：118．
[28] Wang Cheng, Jiang Feng, Lin HaiChao. The Inhibition For LY12 Alloy By Ammonium Heptamolybdate. Corrosion & Protection[J]. 2001, 22(3): 115.
[29] Li YuChun Et. Experimental Study of Using Mollybdate in Industry Cooling Water[J]. Nor th China Electric Power.2001, 3(4).
[30] Zhang Wenzheng. The Prospect of Appl for Sodium Molybdate Ication[J]. China Molybden um Industry.2000, 24(4):7-11.
[31] 郭良生．自来水、海水和食盐溶液中新型碳钢缓蚀剂的研究．腐蚀与防护[J]．1999，20(7)：321
[32] 黄霓裳．钢铁新型复合缓蚀剂．腐蚀与防护[J]．1999，20(6)：264-273．
[33] Sumitomo Metal Industries Ltd. Corrosion Inhibitors for an acidizing solution for petro leum or natural gas wells[A]. Jpn. Kokai Tokkyo Kobo JP 59, 228, 591184, 228, 591] 21 Dec. 1984, 4-11.
[34] Li Yan, Zhang GuanYong, Lu Zhu. Corrosion Inhibition Mechanism of Carbon Steel With Tungstate in deaerated neutral aquatic medium. Journal of Chinese Society for Corrosion and Protection[J]. 2000, 20 (6): 349-354.
[35] Robjtaille D R. Sodium molybdate as a Corrosion Inhibitor in Cooling tower Water[J]. Materials performance. 1976,15(11):40-52.
[36] Vukasovich M S, Farr J P GMolybdate in Corrosion Inhibitor A Review[J].Materials performance. 1986,25(5):9-18.
[37] Vukasovich M S. Applications for the versatile molybdate Inhibitor[J]. Materials performance. 1990,29(5):48-51.
[38] Tang Yongming, Yang Wenzhong. Study on synergistic effects of molybdate[J]. Journal of Nanjing university of chemical technology.2001,23 (2):64-66.
[39] Ni TieJun, Cai LanKun. Effects of steel oxide on silicate interphase corrosion inhibitor[J]. Journal of east china university of science and technology. 2001, 27 (1):80-83.
[40] Gao LiXin, Zhang DaQuang et al.Preparation performance of copper corrosion inhibitors containing benzotriazole and thiadiazole moiety [J]. Journal of east china university of science and technology. 2001,27 (1):84-88.
[41] Zhou GuoDing, Ma ZhiChuan et al.Corrosion Inhibitor of copperwith benzotriazole and tolytriazole in a 3% NaCl solution[J].Bull Eleochem.1991, 7 (2):60-74.
[42] Zhou GuoDing. Shao Hua and Loo B H. A Study of the copper Electrode behaviour in borax buffer solutions contaiing chloride ions and benzotriazole-type inhibitors by voltammetry and photocurrent response method[J].J Electroanal chern. 1997, 421:129.
[43] Xu QunJie. Zhou GuoDing et al.Corrosion Inhibitor of BTA and its derivative 4 CBTA on copper electrode in 3% NaCl solution.The Chinese Journal of nonferrous metals[J].2001, 11(1):135-137.
[44] Zheng Jiaxin. The present situation and of research and application of Inhibitors in Chins[J].Corrosion&Protection. 1997, 18(3): 132-136.
[45] Zheng Jiaxin, Zhao J G Control of corrosion by inhibitors in drilling muds containing high concentration of H_2S[J].Corrosion. 1993,49(2): 170-174.
[46] Ning S G. Shi M L, et al. The relationship of corrosion inhibitor efficiency on steel in acide with electron density and the energy of frontical orbital of imidzoline derivatives[J].Chinese Society for Corrosion&Protection. 1990,10(4):383-390.
[47] Sastri V S, Perumareddi J R. Selection of corrosioninhibitors for use in sour media[J].Corrosion, 1994,50(6):432-437.
[48] 张林,邓春光．水溶性缓蚀剂HS-2000研究开发．石油化工腐蚀与防护[J]．2001,18(3)：30—34．
[49] Sedahmaed G H. 5SEIC,1980:15.
[50] Guo Ying, Song Shizhe. Synergistic inhibitor of Tw-20 and polyacrylic acid on corrosion in hydrochloric acid. Journal of Chemical Industry and Engineering[J]. 2001, 52 (3):262-265.
[51] 郭良生，黄霓裳等．一种抑制钢铁在自来水中腐蚀的新型缓蚀剂．水处理信息报导．2000，5：2-3．
[52] Sastri V S. Packwood R H, Brown J R, et al. Corrosion inhibitor by some oxyanions in coal-water slurries[J]. Br Corrosion J. 1989, 24(1):30-35.
[53] 郭良生，黄霓裳等．一种抑制钢铁在海水中腐蚀的新型缓蚀剂[J]．水处理信息报导．2000，5：4-5．
[54] 李宇春，龙沟洁等．复配钥酸盐缓蚀剂在自来水中的电化学研究[J]．全面腐蚀控制．14(6)：42-44．
[55] 贾能铀，陆柱．水煤气系统钨酸盐的缓蚀作用[J]．华东化工学院学报．1990，16(30)：309-331．
[56] Baiiramov A Kh, Verdiev S Ch. Oxidising type inhibitors for protection of aluminum and steel surfaces in sodium chloride solutions[J]. Br Corrosion J. 1992, 27 (2): 128-134.
[57] Kenneth, Soeder, Joseph S, Roli. Molbdate-based cooling water treatment. NewDevelopments which expand their application areas[C]. iwc-87-12: 115-118.
[58] Kurosawa K, Fukushima T. Effects ofpH of an Na_2MoO_4-H_3PO_4 type aqueous solution on the fomation of chemical conversion coatings on steels[J]. Corrosion Science. 29(9): 1103-1114.
[59] 朱锦棠．一种复合水处理剂[M]．CN40769．2000，1．12．
[60] 赵宏泽，林整．碳钢在高温氯酸盐中的缓蚀剂保护研究．劳动安全与健康[J]．2001，1：38-39．
[61] 鲍其戴．我国水处理剂的现状与未来[J]．上海化工．1999，4(16)：4．
[62] 项成林．我国大化肥厂循环冷却水处理现状[J]．工业水处理．1992，12．
[63] 李裕芳．我国循环冷却水处理技术的回顾及展望[J]．工业水处理．1991，1．
[64] 张淑云等．多元共聚物马来酸醉与丙烯酸的合成及其阻垢性能的研究技术[J]．1996，22 (1)：35-37．
[65] 沈敬芝，赵彦生．一种新型防垢剂的合成与研究．太原工业大学学报[J]．1988，19(4)：76-83
[66] 汪祖模．水质稳定剂[J]．华东化工学院出版社，1991：1-3
[67] 沈敬芝等．MA-AA-AM共聚物的合成及阻垢效果[J]．太原工业大学学报．1994，25(2)：60-64．
[68] Lu Zhifang, Dong wei et al. The scale and corrosion Inhibiton of polyepoxysuccinic acid. Industrial Water Treatmen[J]. 2001, 21(3): 23-25.
[69] J Michael Brown, John F Me Domell. Method of controlling scale formation in aqueous systems[p]. US 5147555, 1992.
[70] Foknmoto Yasuhisa, TangiuchiTtskao. Water treating agents for prevention of metal corrosion and scale generation[p]. JP 04166298.
[71] Xiao Xingcheng, Chang Chunzhi et al. Study of complex scale and corrosion Inhibitor for effluent reused as circulating cooling water[J]. Idustrial Water Treatment.2000, 22(4):42-44.
[72] 鲍其鼐，我国冷却水处理剂二十年[J]．工业水处理．2000，20(增刊)：5-8．
[73] 胡玉国．水处理缓蚀剂应用现状发展方向[J]．化工进展．2000，5：3 1．
[74] 郑家炎．缓蚀剂的研究现状及其应用[J]．腐蚀与防护．1997，1：34-37．
[75] 李庆．碱性循环水处理技术[J]．沪天化科技．2000，4：302-306．
[76] 李瑞华．工业循环冷却水处理药剂进展[J]．工业水处理．1991，5．
[77] 李继友．水处理阻垢剂的研究和发展[J]．天津化工．2001，2：22-23．
[78] 王勤娜，施宝昌等．工业循环冷却水缓蚀阻垢剂的发展状况[J]．化进展．2001，5：26-27．
[79] 崔晓明．国内外水处理药剂研究现状与发展[J]．石化工业水处理技术．1998，(3)：72-76．
[80] 何铁林．国外循环冷却水处理技术进展[J]．工业水处理．1992，4．
[81] 魏存发，吕红等．环冷却水阻垢剂的现状与发展．石化技术与应用[J]．2000，10．18(5)：302-304．
[82] Tim Cavanaugh. Chemical Marker Reporter. 1994, 245, (8).
[83] Ross J. Low KC. Shannon J E. Materials performance. 1997, (2): 53.
[84] 刘明等．国内外水稳定剂现状及应采取的措施[J]．齐鲁石油化工．2001，29(1)：75-78．
[85] 王胜利等．HZ缓蚀阻垢剂研制与应用[J]．石油钻采工艺．2001，23(4)：75-76．
[86] 刘烈炜等．油水两相共存下咪哇琳缓蚀剂的缓蚀效率[J]．油气田地面工程．2001，20(1)：25-26．
[87] 梁平等．天然气管线内腐蚀影响因素分析[J]．河南石油．2000，6：28-30．
[88] 姚晓．国内外气田开发中管内二氧化碳腐蚀研究进展[J]．油气储运．1996，15(2)：18-23．
[89] Cai Rudi, Jiang Ping. Harm of hydrogen sulfide to circulating cooling water systems and its countermeasures[J]. Industrial Water Treatment. 2001, 21 (4):40-42.
[90] Chen Jun. Research on XYH-1 Corrosion Inhibitor for caiman oilfield[J]. Jourmal of Xinjiang petroleum institute. 2001, 13 (2):49-51.
[91] 张天胜．表面活性剂应用技术[M]．北京：化学工业出版社，2001：414-421．