低密度沸石曝气生物滤池处理低浓度氨氮实验研究
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摘要
本文以价廉易得的天然沸石矿物为主要材料,添加低密度颗粒材料和粘结剂,与沸石细粉混合、成球、固化,成功制备出粒径约为4-6mm的低密度沸石复合填料,构建了低密度沸石复合填料曝气生物滤池系统。
以人工配制低浓度含氨氮模拟水,首先通过静态、动态和再生吸附实验研究了沸石离子交换吸附氨氮的性能。系统考察了进水氨氮浓度、沸石用量、温度、沸石粒径、振荡时间、滤速、水质、再生时间和再生次数对沸石离子交换吸附氨氮的影响。静态实验结果表明,初始浓度为10mg/L、粒径为20～40目,静态吸附容量1.6mmolNH_4~+/g。动态实验结果表明,滤速为2m/h、停留时间为30min,出水氨氮浓度达到2mg/L以下,每克沸石产水量为0.62L。再生实验结果表明,用500mL浓度为5g/LNaCl溶液作为再生剂,再生时间为1h,一次再生恢复率较好。
以人工配制低浓度含氨氮模拟水,以低密度沸石复合材料为填料,构建曝气生物滤池小型试验系统装置,进行了系统低密度沸石沸石复合填料曝气生物滤池脱氮性能研究。主要对曝气生物滤池去除COD、氨氮的效果及其影响因素进行了研究。结果表明:采用粒径大小为4-6mm、颗粒密度1.25g/cm~3、颗粒强度大于50N的低密度沸石作为曝气生物滤池填料,影响曝气生物滤池工作性能的主要因素有:气水比、填料层高度、水力负荷及有机负荷等。在气水比1:1-5:1,有机负荷低于3.2kgCOD/m~3·d,水力负荷1-3m~3/m~2h,填料高度20-140cm条件下,COD去除率在63%-90.1%,氨氮去除率在79%-91.6%。曝气生物滤池的反冲洗方式采用气、水联合反冲洗效果较好,滤池冲洗后需要5-6h能恢复到最佳处理状态,即对CODcr的去除率达到70%以上。
Main material is considered as cheap easy natural Zeolite in the text.additive low density grain material and adhesive mix,conglobate and solidify Zeolite powder.Compound fillings of low density zeolite that are grain diameter of 4-6mm succeefully are prepared,which constitutes system of biological aerated filter with compound fillings of low density zeolite.
Manual work prepares simulation wastewater of low concentration ammonia nitrogen.Many factors such as ammonia nitrogen concentration,clinoptilolite amounts,temperature,clinoptilolite diameter,time,filtration velocity,water quality regenerative time and regenerative times have the influence of ammonia nitrogen removal were investigated by the static、dynastic and regenerative experiments firstly,The results of static experiment show static absorptive capacity of 1.6mmolNH_4~+/g in terms of initial ammonia nitrogen concentration of 10mg/Land clinoptilolite diameter of 20～40 item.The results of dynastic experiment show open water capacity of percent gram of 0.62L in terms of filtration velocity of 2m/h,retention period of 30min and ammonia nitrogen concentration of open water of 2m/L below.The results of regeneration experiment show the solution concentration of 500mL NaCl is 5g/L as the regeneration reagent of natural clinoptilolite,and the regenerative time is an hour and recovery rate of once regeneration is better.
Manual work prepares simulation wastewater of low concentration ammonia nitrogen.In lab-scale experiment,the removal ammonia nitrogen performance of BAF with compound fillings of low density zeolite is studied.The main objects studied here are the disposal efficiencies of COD and ammonia nitrogen which can influence the efficiency.The experiment reaches a conclusion that:When using 4-6mm grain diameter、1.05-1.5mg/L density and high 50N intensity as the media, the factors that can influence the performance of BAF are:the ratio of gas to liquid、the media height、hydraulic load and organic load.The removal rate of COD and NH_4~*-N respectively is 63%-90.1%,79%-91.6%under the conditions of the ratio of gas to liquid of 1∶1-5∶1,organic load of low 3.2 kgCOD/m~3·d,hydraulic load of 1-3 m~3/m~2 h and the media height of 20-140cm.The method of backwash using air- water backwashing has many advantages over other methods.After backwashing BAF,goove treatment resumes 5-6h.That is to say COD removal rate is above 70%.
以人工配制低浓度含氨氮模拟水,首先通过静态、动态和再生吸附实验研究了沸石离子交换吸附氨氮的性能。系统考察了进水氨氮浓度、沸石用量、温度、沸石粒径、振荡时间、滤速、水质、再生时间和再生次数对沸石离子交换吸附氨氮的影响。静态实验结果表明,初始浓度为10mg/L、粒径为20～40目,静态吸附容量1.6mmolNH_4~+/g。动态实验结果表明,滤速为2m/h、停留时间为30min,出水氨氮浓度达到2mg/L以下,每克沸石产水量为0.62L。再生实验结果表明,用500mL浓度为5g/LNaCl溶液作为再生剂,再生时间为1h,一次再生恢复率较好。
以人工配制低浓度含氨氮模拟水,以低密度沸石复合材料为填料,构建曝气生物滤池小型试验系统装置,进行了系统低密度沸石沸石复合填料曝气生物滤池脱氮性能研究。主要对曝气生物滤池去除COD、氨氮的效果及其影响因素进行了研究。结果表明:采用粒径大小为4-6mm、颗粒密度1.25g/cm~3、颗粒强度大于50N的低密度沸石作为曝气生物滤池填料,影响曝气生物滤池工作性能的主要因素有:气水比、填料层高度、水力负荷及有机负荷等。在气水比1:1-5:1,有机负荷低于3.2kgCOD/m~3·d,水力负荷1-3m~3/m~2h,填料高度20-140cm条件下,COD去除率在63%-90.1%,氨氮去除率在79%-91.6%。曝气生物滤池的反冲洗方式采用气、水联合反冲洗效果较好,滤池冲洗后需要5-6h能恢复到最佳处理状态,即对CODcr的去除率达到70%以上。
Main material is considered as cheap easy natural Zeolite in the text.additive low density grain material and adhesive mix,conglobate and solidify Zeolite powder.Compound fillings of low density zeolite that are grain diameter of 4-6mm succeefully are prepared,which constitutes system of biological aerated filter with compound fillings of low density zeolite.
Manual work prepares simulation wastewater of low concentration ammonia nitrogen.Many factors such as ammonia nitrogen concentration,clinoptilolite amounts,temperature,clinoptilolite diameter,time,filtration velocity,water quality regenerative time and regenerative times have the influence of ammonia nitrogen removal were investigated by the static、dynastic and regenerative experiments firstly,The results of static experiment show static absorptive capacity of 1.6mmolNH_4~+/g in terms of initial ammonia nitrogen concentration of 10mg/Land clinoptilolite diameter of 20～40 item.The results of dynastic experiment show open water capacity of percent gram of 0.62L in terms of filtration velocity of 2m/h,retention period of 30min and ammonia nitrogen concentration of open water of 2m/L below.The results of regeneration experiment show the solution concentration of 500mL NaCl is 5g/L as the regeneration reagent of natural clinoptilolite,and the regenerative time is an hour and recovery rate of once regeneration is better.
Manual work prepares simulation wastewater of low concentration ammonia nitrogen.In lab-scale experiment,the removal ammonia nitrogen performance of BAF with compound fillings of low density zeolite is studied.The main objects studied here are the disposal efficiencies of COD and ammonia nitrogen which can influence the efficiency.The experiment reaches a conclusion that:When using 4-6mm grain diameter、1.05-1.5mg/L density and high 50N intensity as the media, the factors that can influence the performance of BAF are:the ratio of gas to liquid、the media height、hydraulic load and organic load.The removal rate of COD and NH_4~*-N respectively is 63%-90.1%,79%-91.6%under the conditions of the ratio of gas to liquid of 1∶1-5∶1,organic load of low 3.2 kgCOD/m~3·d,hydraulic load of 1-3 m~3/m~2 h and the media height of 20-140cm.The method of backwash using air- water backwashing has many advantages over other methods.After backwashing BAF,goove treatment resumes 5-6h.That is to say COD removal rate is above 70%.
引文
[1]赵黎安,吴俊辉,张洪大,等.沸石矿物与沸石水泥[M].北京:石油工业出版社,1997.
[2]余振宝,宋乃忠.沸石加工与应用[M].北京:化学工业出版社,2005.
[3]冯乃谦.天然沸石混凝土应用技术[M].北京:中国铁道出版社,1996.
[4]Chis Kladis,Suresh K.Bhargava,Karl Foger,et al.Effects of air pollutants on the cerium exchanged high silica zeolite catalyst:a Fourier transform infrared study[J].Journal of Molecular Catalysis A:Chemical,2001,171:243-249.
[5]Indra Perdana,Derek Creaser,Olov Ohrman,et al.NOx adsorption over a wide temperature range on Na-ZSM-5 films[J].Journal of Catalysis,2005,234:219-229.
[6]V.B.Kazansky,I R,Subbotina,R.A.van Santen,et al.DRIFTS study of the nature and chemical reactivity of gallium ions in Ga/ZSM-5 Ⅱ.Oxidation of reduced Ga species in ZSM-5 by nitrous oxide or water[J].Journal of Catalysis,2005,233:351-358.
[7]Farkas A,Rozic M,Barbaric-Mikocevic Z.Ammonium exchange in leakage waters of waste dumps using natural zeolite from the Krapina region,Croatia[J].Journal of Hazardous Materials,2005,B117:25-33.
[8]张曦,吴为中,温东辉,等.氨氮在天然沸石上的吸附及解析[J].环境化学,2003,22(2):166-171.
[9]Li Z.Use of surfactant-modified zeolite as fertilizer carriers to control nitrate release[J].Microporous and Mesoporous Materials,2003,61:181-188.
[10]袁俊生,郎宇琪,张林栋,等.沸石法工业污水氨氮治理技术研究[J].环境污染治理技术与设备,2002,3(12):60-63
[11]王利平,冯俊生,陈莉荣,等.用沸石吸附稀土冶炼氯铵废水中的氨氮[J].化工环保,2005,25(3):214-216.
[12]Keiji Hashimoto,Kazuhiko Wasada,Masato Osaki,et al.Photocatalytic oxidation of nitrogen oxide over titania-zeolite composite catalyst to remove nitrogen oxides in the atmosphere[J].Applied Catalysis B:Environmental,2001,30:429-436
[13]高滋.沸石催化与分离技术[M].北京:中国石化出版社,1999.
[14]曾霞,成官文.沸石强化SBR生物脱氮的影响因素研究[J].环境科学与 技术,2005,28(5):90-92.
[15]张曦,吴为中,温东辉,等.生物沸石床污水脱氮效果及机理[J].环境科学.2003,24(5):75-80.
[16]李旭东,张旭,薛玉等.沸石芦苇床除氮中试研究[J].环境科学,2003,24(3):158-160.
[17]田文华,文湘华,杨爱华,等.沸石生物滤池处理低浓度生活污水的工艺性能及影响因素[J].环境科学,2003,24(5):97-101.
[18]卢少勇,张彭义,余刚.人工湿地沸石填充方式研究[J].环境科学研究,2006,19(3):91-95.
[19]陈和谦,吴志超,黄友谊.沸石联合生物吸附再生工艺可行性研究[J].环境污染治理技术与设备,2005,6(8):26-29.
[20]Havva Merih 6tker,Isll Akmehmet-Balcloglu.Adsorption and degradation of enrofloxacin,a veterinary antibiotic on natural zeolite[J].Journal of Hazardous Materials,2005,122:251-258.
[21]肖羽堂,张晶品,吴鸣等.我国水资源污染与饮用水安全性研究长江流域资源与环境,2001,Vol.10(1):51-59.
[22]黄仲杰.我国城市供水现状、问题及对策.给水排水,1998,Vol.24(2):18-20.
[23]李青山.中国水资源保护问题及其对策措施,水资源保护,1999,Vol.56(2):28-30.
[24]崔玉川,傅涛.我国城市给水发展现状与特点.中国给水排水,1999,Vol.15(2):52-55.
[25]王占生,刘文君.微污染水源饮用水处理.北京:中国建筑工业出版社,1999.
[26]姜文来.中国21世纪水资源安全对策研究.水科学进展,2001,Vol.(3):66-68.
[27]崔玉川,傅涛.我国水污染及饮用水游中有机污染物的危害.城市环境与城市生态,1998,Vol.11(3):23-25.
[28]S.J.Randtke.Organic contaminant removal by coagulation and related process combinations,JAWWA,1988,Voi.80(5):40-42.
[29]包卫彬.宁波姚江微污染水源水处理试验研究:[硕士学位论文].上海:同济大学环境科学与工程学院,2004.
[30]施锦岳.O_3-生物沸石-活性炭处理姚江微污染水源水研究:[硕士学位论文].上海:同济大学环境科学与工程学院,2005.
[31]徐斌.悬浮填料床处理黄浦江原水及动态模拟研究:[博士学位论文].上海:同济大学环境科学与工程学院,2003.
[32]吴启洲.饮用水中有机污染物的危害及对策水处理技术,1997,(4):67.
[33]魏宏斌.二氧化钦膜催化氧化水中微量有机污染物的研究:[博士学位论文].上海:同济大学环境科学与工程学院,1996.
[34]中国环境优先检测研究课题组.环境优先污染物.北京:中国环境科学出社,1989.
[35]戴之荷.受污染水处理技术在我国的应用.给水排水,2002,Vol.28(1):8-12.
[36]崔玉川,傅涛.我国水污染及饮用水源中有机污染物的危害.城市环境与城市生态,1998,Vol.11(3):23-25.
[37]郝晓地,张自杰.水体氮污染及其防治对策.环境污染与防治,1990,Vol.12(4):25-27.
[38]郑兴灿,李亚新.污水除磷脱氮技术.北京:中国建筑工业出版社,1986.
[39]黄文强,李晨曦.吸附分离材料[M].北京:化学工业出版社,2005.
[40]李旭祥.分离膜制备与应用[M].北京:材料科学与工程出版社,2004.
[41]刘茉娥,蔡邦肖,陈益棠.膜技术在污水治理及回用中的应用[M].北京:化学工业出版社,2005.
[42]戴猷元,张瑾.有机废水萃取处理技术[M].北京:化学工业出版社,2003.
[43]刘景明,王德安.污水处理工[M].北京:中国建筑工业出版社,2004.
[44]高廷耀,顾国维.水污染控制工程[M].北京:高等教育出版社,1999.
[45]上海市环境保护局.废水生化处理[M].上海:同济大学出版社,1999.
[46]吴婉娥,葛红光,张克峰.废水生物处理技术[M].北京:化学工业出版社,2003.
[47]刘雨,赵庆良,郑兴灿.生物膜法污水处理技术[M].北京:中国建筑工业出版社,2000.
[48]郑俊,吴浩汀.曝气生物滤池污水处理新技术及工程实例[M].北京:化学工业出版社,2002.
[49]崔康平,钟佐燊,沈照理.上流式曝气生物滤池深度处理炼油厂外排污水[J].地学前缘,2005,12(S1):55-60.
[50]Pujol R,Hamon M,Kandel X,Lemmel,H Biofilters:flexible,reliable biological reactors[J].Wat Sci Tech,1994,29(10-11):33-38.
[51]J Canler P,Perret J M.Biological aerated filters:assessment of the process based on 12 sewage treatment plants[J].War Sci Tech,1994,29(10-11):13-22;
[52]徐亚明,蒋彬.曝气生物滤池的原理及工艺[J].工业水处理,2002,22(6): 1-5.
[53]Chudoba P,Pujol R.A.three stage biofiltration process:performances of a pilot plant[J].Wat Sci Tech,1998,38(8-9):257-265.
[54]Rogalla F,Bourbigot M.M.New developments in complete nitrogen removal with biological aerated filters[J].Wat Sci Tech,1990,22(1-2):273-280.
[55]Pujol R,Lemmel H,Gousailles M.A keypoint of nitrification in an upflow biofiltration reactor[J].Wat Sci Tech,1998,38(3):43-49.
[56]马军,邱立平.曝气生物滤池及其研究进展[J].环境工程,2002,20(3):7-11.
[57]张杰,曹相生,孟雪征.曝气生物滤池的研究进展[J].中国给水排水,2002,18(8):26-28.
[58]方战强,朱又春,宁寻安.工业废水处理水回用技术的研究进展[J].环境保护,1999,7:16-20.
[59]张小玲,彭党聪,王志盈.传统与短程反硝化的影响因素及特性研究[J].中国给水排水,2002,18(9):1-3.
[60]袁林江,彭党聪,王志盈.短程硝化-反硝化生物脱氮[J].中国给水排水,2000,16(2):29-31.
[61]邱立平,马军.曝气生物滤池的短程硝化反硝化机理研究[J].中国给水排水,2002,18(11):1-4.
[62]Tsitsishvili G.V,Andronikashvili T.G,N.Kirov G,et al.Natural Zeolites.Chichester(England):Ellis Horwood,1992.
[63]Schulthess C P,Huang C P.Adsorption of Heavy Metals by Silicon and Aluminum Oxide Surfaces on Clay Minerals[J].Soil Science Society of America Journal,1990,54(3):679-688.
[64]Koon J H,Kauiman,W J.Water Pollution Control Fed.1974,47:448.
[65]Bergero D,Boccignone M,et al.Ammonia Removal Capacity of European Natural.Zeolite Tuffs:Application to Aquaculture Waste Water[J].Aquacult,Fish,Manage,1994,25(8):813-821.
[66]Singh G,Prasad B.Removal of Ammonia from Coke-plant Wastewater by Using Synthetic Zeolite[J].Water Environment Research,1997,69(2):157-161.
[67]Booker N.A,Cooney E.L,A J Priestley.Ammonia Removal from Sewage Using Natural Australian Zeolite[J].Water Science and Technology,1996,34(9):17-24.
[68]Cooney E.L,Booker N.A,et al.Ammonia Removal from Wastewater Using Natural Australian Zeolite I.Characterization of the Zeolite[J].Separation Science and Technology,1999,34(12):2307-2327.
[69]Cooney E.L.,Booker N.A.et al..Ammonia Removal from Wastewater Using Natural Australian Zeolite Ⅱ.Pilot-scale STUDY Using Continuous Packed Column Process[J].Separation Science and Technology,1999,34(14):2741-2760.
[70]韩惠茹.利用天然沸石处理含铵废水的工艺研究[J].工业水处理,1997,17(5):33-34.
[71]何杰,刘玉林.天然沸石对含酚废水的处理[J].矿产综合利用,1999,1:39-42.
[72]何杰,刘玉林.动态法研究天然沸石去除氨氮效果[J].水处理技术,1999,25(6):358-361.
[73]张晓丽,温俨.沸石去除废水中氨氮的实验研究[J].科技情报开发与经济,1999,9(1):14.
[74]杨胜科,郭春林.沸石去除地下水中的氨氮的影响因素分析及作用机理探讨[J].西安工程学院学报,2000,22(3):69-72.
[75]Komarowaki S,Yu Q.Ammonium Ion Removal from Wastewater Using Australian Natural Zeolite:Batch Equilibrium and Kinetic Studies[J].Environmental Technology,1997,18(11):1085-1097.
[76]Nguyen M L,Tanner C C.Ammonium Removal from Wastewater Using Natural New Zealand Zeolite[J].New Zealand Journal of Agricultural Research,1998,41(3):427-446.
[77]Semmens M J.,Klieve J,Schnobrich D,et al.Modelling ammonium exchange and regeneration on.clinoptilolite[J].Water Research,1981,15(6):655-666.
[78]Chmielewská- Horváthová,E,Konecny,J,Bosan,Z.Removal from Tannery Waste-waters by Selective Ion Exchange on Slovak Clinoptilolite[J].Acta hydrochimica et hydrobiologica,1992,20(5):269-272.
[79]傅忠全.城市污水回用的生物沸石填料试验[J].中国给水排水,1990,6(4):50-52.
[80]Sims,R.C,Slezak,L.A.Slow Sand Filtration:Present.Practice in the United States,Slow Sand Filtration[J].American Society of Civil Engineers,1991,1-18
[81]Martin Oldenburg,Ivan Sekoulov.Multipurpose Filters with Ion-exchange for the Equalization of Ammonia Peaks[J].Water Science and Technology, 1995,32(7):199-206.
[82]Gisvold B.,Odegaard H.,Follesdal M.Enhancing the Removal of Ammonia in Nitrifying Biofilters by the Use of a Zeolite Containing Expanded Clay Aggregate Filtermedia[J].Water Science and Technology,2000,41(9):107-114.
[83]Hiroshi Tsuno,Fumitake Nishimura,Isao Somiya.Removal of Ammonium Nitrogen in Bio-zeolite Reactor[J].Doku Gakkai Bombun Hokokushu,1994,03:159-166.
[84]Michal Green,Adriaan Mels,nOri Lahav,et al.Biological-ion Exchange Process for Ammonium Removal from Secondary Effluent[J].Water Science and Technology,1996,34(1-2):449-458.
[85]Lahav O,Green M.Ammonium Removal Using Ion Exchange and Biological Regeneration[J].Water Research,1998,32(7):2019-2028.
[86]Lahav O,Green M.Ammonium Removal from Primary and Secondary Effluent Using a Bioregenerated Ion-exchange Process[J].Water Science and Technology,2000,42(1):179-185.
[87]Ori Lahav,Michal Green.Bioregenerated Ion-exchange Process:The Effect of the Biofilm on Ion-exchange Capacity and Kinetic[J].Water S.A,2000,26(1):51-58.
[88]李德生.沸石在微污染水源水质净化中的试验研究[D].清华大学硕士学位论文,2000.
[89]浦哲.沸石滤池深度处理石化废水二级出水研究[J].工业安全与环保,2005,31(9):29-31.
[90]陈和谦,吴志超,黄友谊.沸石联合生物吸附再生工艺可行性研究[J].环境污染治理技术与设备,2005,6(8):26-29.
[91]麦穗海,吴志超,陈绍伟.沸石强化生物脱氮工艺研究[J].上海环境科学,2002,21(10):640-642.
[92]温东辉,张曦,吴为中,等.天然沸石对铵吸附能力的生物再生试验研究[J].北京大学学报(自然科学版),2003,39(4):494-500.
[93]翟俊,何强,肖海文,等.折流湿地滤池+侧向潜流湿地床污水处理系统及方法.发明专利,2005.
[94]张兵,张学洪,崔福义,魏彩春.一种小区污水脱氨氮的方法.发明专利,2005.
[95]周少奇.活化沸石生物滤池脱氮方法.发明专利,2005.
[96]钟佐燊,杨小毛.人工快速渗滤污水处理系统.发明专利,2004.
[97]成官文.一种可分期建设的污水脱氮除磷工艺.发明专利,2004.
[98]成官文.一种使传统污水处理工艺脱氮除磷的工艺.2004.
[99]张涉,陆晓春,朱兆华.用于污水处理生物膜工艺的复合填料.发明专利,2003.
[100]张旭,李广贺,周琪,张荣社,等.氮磷污染控制的复合湿地生态方法及其系统.发明专利,2003.
[101]马军,邱立平.曝气生物滤池及其研究进展[J].环境工程,2002,20(3):7-11.
[102]徐亚明,蒋彬.曝气生物滤池的原理及工艺[J].工业水理,2002,22(6):1-5.
[103]张杰,曹相生,孟雪征,曝气生物滤池的研究进展[J].中国给水排水,2002,18(8):26-29.
[104]严煦世.水和废水.技术研究[M].北京:中国建筑工业出版社,1991.
[105]郑兴灿,李亚新.污水除磷脱氮技术[M].北京:中国建筑工业出版社,1998.
[106]李丛娜,吕锡武,吴华明.溶解氧及活性污泥浓度对同步硝化反硝化的影响[J].华东给水排水,2002,(3):12-16.
[107]Robertson L A,Van Neil E W J,Torremans R A M,et al.Simultaneous nitrification and in aerobic chemostat cultures of thiosphaera pantotropha[J].Appl Environ Microbiol,1998,54(1I):2812-2818.
[108]Zhao H W,Donalds M.Controlling factor for simultaneous nitrification and denitrification in a two-stage intermittent aeration process treating domestic sewage[J].Water Research.1999,33(4):961-978.
[109]Meiberg J B M,Bruinenberg P M,Harder W.Effect of dissolved oxygen tension on the metabolism of methylated amines in hyphom icrobium X in the absence and presence of nitrate:aerobic denitrification[J].J Gen Microbiol,1980,120:453-463.
[110]吕锡武.同时硝化反硝化的理论和实践[J].环境化学,2002,21(6):564-570.
[111]刘玉亮,罗固源,阙添,等.斜发沸石对氨氮吸附性能的试验分析[J].重庆大学学报,2004,1(1):62-65,
[112]熊小京,叶均磊,王新红,等.天然沸石处理低浓度含氨废水的实验研究[J].厦门大学学报,2006,11(11):828-831.
[113]Zorpas A,Constantinides T,Vlyyssides A G,et al.Heavy Metal Uptake by Natural Zeolite and Metals Partitioning in Sewage Sludge Compost[J].Bioresource Technology,2000,72:113-119
[114]Mercer B W.Ammonia removal from secondary effluents by selective ion exchange[J].JWPCF,1970,42(2):95-107.
[115]James R.Boles.Composition,Optical properties,Cell dimensions,and Thermal Stability of Some Heulandite Group Zeolites[J].American Mineralogist,1972,57:1463-1493.
[116]Komarowski S,Yu Q.Ammonium ion removal from wastewater using Australian natural zeolite:batch equilibrium and kinetic studies[J].Environmental Technology,1997,18(11):1085-1097.
[117]Nguyen M L,Tanner C C.Ammonium removal from wastewaters using natural New Zealand zeolites[J].New Zealand Journal of Agricultural Research,1998,41(3):427-446.
[118]温东辉,唐孝炎.天然斜发沸石对溶液中NH_4~+的物化作用机理[J].中国环境科学,2003,23(5):509-514.
[119]Dongyuan Zhao,Keera Cleare,Crystal Oliver,et al.Characteristics of the synthetic heulandite clinoptilolite family of zeolites[J].Microporous and Mesoporous Materials,1998,21:371-379.
[120]Konstantinos P,Kitsopoulos.The Relationship Between the Thermal Behavior of Clinoptilolite and its Chemical Composition[J].Clays and Clay Minerals,2001,49(3):236-243.
[121]国家环境保护总局.水和废水监测分析方法[M].第四版,北京:中国环境科学出版社,2002.
[122]周云,戴婕,王占生.曝气生物滤池在上海周家渡水厂的应用[J].中国给水排水,2002,(10):68.
[123]Seguret F.Hydrodynamic behavior of a full-scale submerged biofilter and its possible influence on performances[J].Wat Sci Tech,1998,38(89):249-256.
[124]郭安祥.BAF处理低浓度生活污水[D].西安:西安建筑科技大学,2004.
[125]周晴,傅金祥,赵玉华,等.UBAF两种挂膜方式的试验研究[J].工业安全与环保,2005,31(5):28-30.
[126]邱立平,杜茂安,冯琦.二段曝气生物滤池处理生活污水的试验研究[J].环境工程,2001,19(2):22-24.
[127]田文华,文湘华,钱易.沸石滤料曝气生物滤池去除COD和氨氮性能研究.中国给水排水,2002,18(12):13-15.
[128]Oldenburg M.,Sekoulov I Multipurpose filters with ionexchanger for the equatization of ammonia peaks.Wat Sci Tech,1995,32(7):199-206
[129]袁志忠,陈晓如.滤池冲洗方式探讨[J].给水排水,1999,25(1):8-9.
[130]A Amirtharajah.Optimum Back-Washing of Filters with Ainswur:a Review.Wat Sci Tech,1993,27(10):195-211.
[131]曹相生.污水深度处理中的生物强化过滤技术研究[D].哈尔滨工业大学博士学位论文,2003:103-106
[2]余振宝,宋乃忠.沸石加工与应用[M].北京:化学工业出版社,2005.
[3]冯乃谦.天然沸石混凝土应用技术[M].北京:中国铁道出版社,1996.
[4]Chis Kladis,Suresh K.Bhargava,Karl Foger,et al.Effects of air pollutants on the cerium exchanged high silica zeolite catalyst:a Fourier transform infrared study[J].Journal of Molecular Catalysis A:Chemical,2001,171:243-249.
[5]Indra Perdana,Derek Creaser,Olov Ohrman,et al.NOx adsorption over a wide temperature range on Na-ZSM-5 films[J].Journal of Catalysis,2005,234:219-229.
[6]V.B.Kazansky,I R,Subbotina,R.A.van Santen,et al.DRIFTS study of the nature and chemical reactivity of gallium ions in Ga/ZSM-5 Ⅱ.Oxidation of reduced Ga species in ZSM-5 by nitrous oxide or water[J].Journal of Catalysis,2005,233:351-358.
[7]Farkas A,Rozic M,Barbaric-Mikocevic Z.Ammonium exchange in leakage waters of waste dumps using natural zeolite from the Krapina region,Croatia[J].Journal of Hazardous Materials,2005,B117:25-33.
[8]张曦,吴为中,温东辉,等.氨氮在天然沸石上的吸附及解析[J].环境化学,2003,22(2):166-171.
[9]Li Z.Use of surfactant-modified zeolite as fertilizer carriers to control nitrate release[J].Microporous and Mesoporous Materials,2003,61:181-188.
[10]袁俊生,郎宇琪,张林栋,等.沸石法工业污水氨氮治理技术研究[J].环境污染治理技术与设备,2002,3(12):60-63
[11]王利平,冯俊生,陈莉荣,等.用沸石吸附稀土冶炼氯铵废水中的氨氮[J].化工环保,2005,25(3):214-216.
[12]Keiji Hashimoto,Kazuhiko Wasada,Masato Osaki,et al.Photocatalytic oxidation of nitrogen oxide over titania-zeolite composite catalyst to remove nitrogen oxides in the atmosphere[J].Applied Catalysis B:Environmental,2001,30:429-436
[13]高滋.沸石催化与分离技术[M].北京:中国石化出版社,1999.
[14]曾霞,成官文.沸石强化SBR生物脱氮的影响因素研究[J].环境科学与 技术,2005,28(5):90-92.
[15]张曦,吴为中,温东辉,等.生物沸石床污水脱氮效果及机理[J].环境科学.2003,24(5):75-80.
[16]李旭东,张旭,薛玉等.沸石芦苇床除氮中试研究[J].环境科学,2003,24(3):158-160.
[17]田文华,文湘华,杨爱华,等.沸石生物滤池处理低浓度生活污水的工艺性能及影响因素[J].环境科学,2003,24(5):97-101.
[18]卢少勇,张彭义,余刚.人工湿地沸石填充方式研究[J].环境科学研究,2006,19(3):91-95.
[19]陈和谦,吴志超,黄友谊.沸石联合生物吸附再生工艺可行性研究[J].环境污染治理技术与设备,2005,6(8):26-29.
[20]Havva Merih 6tker,Isll Akmehmet-Balcloglu.Adsorption and degradation of enrofloxacin,a veterinary antibiotic on natural zeolite[J].Journal of Hazardous Materials,2005,122:251-258.
[21]肖羽堂,张晶品,吴鸣等.我国水资源污染与饮用水安全性研究长江流域资源与环境,2001,Vol.10(1):51-59.
[22]黄仲杰.我国城市供水现状、问题及对策.给水排水,1998,Vol.24(2):18-20.
[23]李青山.中国水资源保护问题及其对策措施,水资源保护,1999,Vol.56(2):28-30.
[24]崔玉川,傅涛.我国城市给水发展现状与特点.中国给水排水,1999,Vol.15(2):52-55.
[25]王占生,刘文君.微污染水源饮用水处理.北京:中国建筑工业出版社,1999.
[26]姜文来.中国21世纪水资源安全对策研究.水科学进展,2001,Vol.(3):66-68.
[27]崔玉川,傅涛.我国水污染及饮用水游中有机污染物的危害.城市环境与城市生态,1998,Vol.11(3):23-25.
[28]S.J.Randtke.Organic contaminant removal by coagulation and related process combinations,JAWWA,1988,Voi.80(5):40-42.
[29]包卫彬.宁波姚江微污染水源水处理试验研究:[硕士学位论文].上海:同济大学环境科学与工程学院,2004.
[30]施锦岳.O_3-生物沸石-活性炭处理姚江微污染水源水研究:[硕士学位论文].上海:同济大学环境科学与工程学院,2005.
[31]徐斌.悬浮填料床处理黄浦江原水及动态模拟研究:[博士学位论文].上海:同济大学环境科学与工程学院,2003.
[32]吴启洲.饮用水中有机污染物的危害及对策水处理技术,1997,(4):67.
[33]魏宏斌.二氧化钦膜催化氧化水中微量有机污染物的研究:[博士学位论文].上海:同济大学环境科学与工程学院,1996.
[34]中国环境优先检测研究课题组.环境优先污染物.北京:中国环境科学出社,1989.
[35]戴之荷.受污染水处理技术在我国的应用.给水排水,2002,Vol.28(1):8-12.
[36]崔玉川,傅涛.我国水污染及饮用水源中有机污染物的危害.城市环境与城市生态,1998,Vol.11(3):23-25.
[37]郝晓地,张自杰.水体氮污染及其防治对策.环境污染与防治,1990,Vol.12(4):25-27.
[38]郑兴灿,李亚新.污水除磷脱氮技术.北京:中国建筑工业出版社,1986.
[39]黄文强,李晨曦.吸附分离材料[M].北京:化学工业出版社,2005.
[40]李旭祥.分离膜制备与应用[M].北京:材料科学与工程出版社,2004.
[41]刘茉娥,蔡邦肖,陈益棠.膜技术在污水治理及回用中的应用[M].北京:化学工业出版社,2005.
[42]戴猷元,张瑾.有机废水萃取处理技术[M].北京:化学工业出版社,2003.
[43]刘景明,王德安.污水处理工[M].北京:中国建筑工业出版社,2004.
[44]高廷耀,顾国维.水污染控制工程[M].北京:高等教育出版社,1999.
[45]上海市环境保护局.废水生化处理[M].上海:同济大学出版社,1999.
[46]吴婉娥,葛红光,张克峰.废水生物处理技术[M].北京:化学工业出版社,2003.
[47]刘雨,赵庆良,郑兴灿.生物膜法污水处理技术[M].北京:中国建筑工业出版社,2000.
[48]郑俊,吴浩汀.曝气生物滤池污水处理新技术及工程实例[M].北京:化学工业出版社,2002.
[49]崔康平,钟佐燊,沈照理.上流式曝气生物滤池深度处理炼油厂外排污水[J].地学前缘,2005,12(S1):55-60.
[50]Pujol R,Hamon M,Kandel X,Lemmel,H Biofilters:flexible,reliable biological reactors[J].Wat Sci Tech,1994,29(10-11):33-38.
[51]J Canler P,Perret J M.Biological aerated filters:assessment of the process based on 12 sewage treatment plants[J].War Sci Tech,1994,29(10-11):13-22;
[52]徐亚明,蒋彬.曝气生物滤池的原理及工艺[J].工业水处理,2002,22(6): 1-5.
[53]Chudoba P,Pujol R.A.three stage biofiltration process:performances of a pilot plant[J].Wat Sci Tech,1998,38(8-9):257-265.
[54]Rogalla F,Bourbigot M.M.New developments in complete nitrogen removal with biological aerated filters[J].Wat Sci Tech,1990,22(1-2):273-280.
[55]Pujol R,Lemmel H,Gousailles M.A keypoint of nitrification in an upflow biofiltration reactor[J].Wat Sci Tech,1998,38(3):43-49.
[56]马军,邱立平.曝气生物滤池及其研究进展[J].环境工程,2002,20(3):7-11.
[57]张杰,曹相生,孟雪征.曝气生物滤池的研究进展[J].中国给水排水,2002,18(8):26-28.
[58]方战强,朱又春,宁寻安.工业废水处理水回用技术的研究进展[J].环境保护,1999,7:16-20.
[59]张小玲,彭党聪,王志盈.传统与短程反硝化的影响因素及特性研究[J].中国给水排水,2002,18(9):1-3.
[60]袁林江,彭党聪,王志盈.短程硝化-反硝化生物脱氮[J].中国给水排水,2000,16(2):29-31.
[61]邱立平,马军.曝气生物滤池的短程硝化反硝化机理研究[J].中国给水排水,2002,18(11):1-4.
[62]Tsitsishvili G.V,Andronikashvili T.G,N.Kirov G,et al.Natural Zeolites.Chichester(England):Ellis Horwood,1992.
[63]Schulthess C P,Huang C P.Adsorption of Heavy Metals by Silicon and Aluminum Oxide Surfaces on Clay Minerals[J].Soil Science Society of America Journal,1990,54(3):679-688.
[64]Koon J H,Kauiman,W J.Water Pollution Control Fed.1974,47:448.
[65]Bergero D,Boccignone M,et al.Ammonia Removal Capacity of European Natural.Zeolite Tuffs:Application to Aquaculture Waste Water[J].Aquacult,Fish,Manage,1994,25(8):813-821.
[66]Singh G,Prasad B.Removal of Ammonia from Coke-plant Wastewater by Using Synthetic Zeolite[J].Water Environment Research,1997,69(2):157-161.
[67]Booker N.A,Cooney E.L,A J Priestley.Ammonia Removal from Sewage Using Natural Australian Zeolite[J].Water Science and Technology,1996,34(9):17-24.
[68]Cooney E.L,Booker N.A,et al.Ammonia Removal from Wastewater Using Natural Australian Zeolite I.Characterization of the Zeolite[J].Separation Science and Technology,1999,34(12):2307-2327.
[69]Cooney E.L.,Booker N.A.et al..Ammonia Removal from Wastewater Using Natural Australian Zeolite Ⅱ.Pilot-scale STUDY Using Continuous Packed Column Process[J].Separation Science and Technology,1999,34(14):2741-2760.
[70]韩惠茹.利用天然沸石处理含铵废水的工艺研究[J].工业水处理,1997,17(5):33-34.
[71]何杰,刘玉林.天然沸石对含酚废水的处理[J].矿产综合利用,1999,1:39-42.
[72]何杰,刘玉林.动态法研究天然沸石去除氨氮效果[J].水处理技术,1999,25(6):358-361.
[73]张晓丽,温俨.沸石去除废水中氨氮的实验研究[J].科技情报开发与经济,1999,9(1):14.
[74]杨胜科,郭春林.沸石去除地下水中的氨氮的影响因素分析及作用机理探讨[J].西安工程学院学报,2000,22(3):69-72.
[75]Komarowaki S,Yu Q.Ammonium Ion Removal from Wastewater Using Australian Natural Zeolite:Batch Equilibrium and Kinetic Studies[J].Environmental Technology,1997,18(11):1085-1097.
[76]Nguyen M L,Tanner C C.Ammonium Removal from Wastewater Using Natural New Zealand Zeolite[J].New Zealand Journal of Agricultural Research,1998,41(3):427-446.
[77]Semmens M J.,Klieve J,Schnobrich D,et al.Modelling ammonium exchange and regeneration on.clinoptilolite[J].Water Research,1981,15(6):655-666.
[78]Chmielewská- Horváthová,E,Konecny,J,Bosan,Z.Removal from Tannery Waste-waters by Selective Ion Exchange on Slovak Clinoptilolite[J].Acta hydrochimica et hydrobiologica,1992,20(5):269-272.
[79]傅忠全.城市污水回用的生物沸石填料试验[J].中国给水排水,1990,6(4):50-52.
[80]Sims,R.C,Slezak,L.A.Slow Sand Filtration:Present.Practice in the United States,Slow Sand Filtration[J].American Society of Civil Engineers,1991,1-18
[81]Martin Oldenburg,Ivan Sekoulov.Multipurpose Filters with Ion-exchange for the Equalization of Ammonia Peaks[J].Water Science and Technology, 1995,32(7):199-206.
[82]Gisvold B.,Odegaard H.,Follesdal M.Enhancing the Removal of Ammonia in Nitrifying Biofilters by the Use of a Zeolite Containing Expanded Clay Aggregate Filtermedia[J].Water Science and Technology,2000,41(9):107-114.
[83]Hiroshi Tsuno,Fumitake Nishimura,Isao Somiya.Removal of Ammonium Nitrogen in Bio-zeolite Reactor[J].Doku Gakkai Bombun Hokokushu,1994,03:159-166.
[84]Michal Green,Adriaan Mels,nOri Lahav,et al.Biological-ion Exchange Process for Ammonium Removal from Secondary Effluent[J].Water Science and Technology,1996,34(1-2):449-458.
[85]Lahav O,Green M.Ammonium Removal Using Ion Exchange and Biological Regeneration[J].Water Research,1998,32(7):2019-2028.
[86]Lahav O,Green M.Ammonium Removal from Primary and Secondary Effluent Using a Bioregenerated Ion-exchange Process[J].Water Science and Technology,2000,42(1):179-185.
[87]Ori Lahav,Michal Green.Bioregenerated Ion-exchange Process:The Effect of the Biofilm on Ion-exchange Capacity and Kinetic[J].Water S.A,2000,26(1):51-58.
[88]李德生.沸石在微污染水源水质净化中的试验研究[D].清华大学硕士学位论文,2000.
[89]浦哲.沸石滤池深度处理石化废水二级出水研究[J].工业安全与环保,2005,31(9):29-31.
[90]陈和谦,吴志超,黄友谊.沸石联合生物吸附再生工艺可行性研究[J].环境污染治理技术与设备,2005,6(8):26-29.
[91]麦穗海,吴志超,陈绍伟.沸石强化生物脱氮工艺研究[J].上海环境科学,2002,21(10):640-642.
[92]温东辉,张曦,吴为中,等.天然沸石对铵吸附能力的生物再生试验研究[J].北京大学学报(自然科学版),2003,39(4):494-500.
[93]翟俊,何强,肖海文,等.折流湿地滤池+侧向潜流湿地床污水处理系统及方法.发明专利,2005.
[94]张兵,张学洪,崔福义,魏彩春.一种小区污水脱氨氮的方法.发明专利,2005.
[95]周少奇.活化沸石生物滤池脱氮方法.发明专利,2005.
[96]钟佐燊,杨小毛.人工快速渗滤污水处理系统.发明专利,2004.
[97]成官文.一种可分期建设的污水脱氮除磷工艺.发明专利,2004.
[98]成官文.一种使传统污水处理工艺脱氮除磷的工艺.2004.
[99]张涉,陆晓春,朱兆华.用于污水处理生物膜工艺的复合填料.发明专利,2003.
[100]张旭,李广贺,周琪,张荣社,等.氮磷污染控制的复合湿地生态方法及其系统.发明专利,2003.
[101]马军,邱立平.曝气生物滤池及其研究进展[J].环境工程,2002,20(3):7-11.
[102]徐亚明,蒋彬.曝气生物滤池的原理及工艺[J].工业水理,2002,22(6):1-5.
[103]张杰,曹相生,孟雪征,曝气生物滤池的研究进展[J].中国给水排水,2002,18(8):26-29.
[104]严煦世.水和废水.技术研究[M].北京:中国建筑工业出版社,1991.
[105]郑兴灿,李亚新.污水除磷脱氮技术[M].北京:中国建筑工业出版社,1998.
[106]李丛娜,吕锡武,吴华明.溶解氧及活性污泥浓度对同步硝化反硝化的影响[J].华东给水排水,2002,(3):12-16.
[107]Robertson L A,Van Neil E W J,Torremans R A M,et al.Simultaneous nitrification and in aerobic chemostat cultures of thiosphaera pantotropha[J].Appl Environ Microbiol,1998,54(1I):2812-2818.
[108]Zhao H W,Donalds M.Controlling factor for simultaneous nitrification and denitrification in a two-stage intermittent aeration process treating domestic sewage[J].Water Research.1999,33(4):961-978.
[109]Meiberg J B M,Bruinenberg P M,Harder W.Effect of dissolved oxygen tension on the metabolism of methylated amines in hyphom icrobium X in the absence and presence of nitrate:aerobic denitrification[J].J Gen Microbiol,1980,120:453-463.
[110]吕锡武.同时硝化反硝化的理论和实践[J].环境化学,2002,21(6):564-570.
[111]刘玉亮,罗固源,阙添,等.斜发沸石对氨氮吸附性能的试验分析[J].重庆大学学报,2004,1(1):62-65,
[112]熊小京,叶均磊,王新红,等.天然沸石处理低浓度含氨废水的实验研究[J].厦门大学学报,2006,11(11):828-831.
[113]Zorpas A,Constantinides T,Vlyyssides A G,et al.Heavy Metal Uptake by Natural Zeolite and Metals Partitioning in Sewage Sludge Compost[J].Bioresource Technology,2000,72:113-119
[114]Mercer B W.Ammonia removal from secondary effluents by selective ion exchange[J].JWPCF,1970,42(2):95-107.
[115]James R.Boles.Composition,Optical properties,Cell dimensions,and Thermal Stability of Some Heulandite Group Zeolites[J].American Mineralogist,1972,57:1463-1493.
[116]Komarowski S,Yu Q.Ammonium ion removal from wastewater using Australian natural zeolite:batch equilibrium and kinetic studies[J].Environmental Technology,1997,18(11):1085-1097.
[117]Nguyen M L,Tanner C C.Ammonium removal from wastewaters using natural New Zealand zeolites[J].New Zealand Journal of Agricultural Research,1998,41(3):427-446.
[118]温东辉,唐孝炎.天然斜发沸石对溶液中NH_4~+的物化作用机理[J].中国环境科学,2003,23(5):509-514.
[119]Dongyuan Zhao,Keera Cleare,Crystal Oliver,et al.Characteristics of the synthetic heulandite clinoptilolite family of zeolites[J].Microporous and Mesoporous Materials,1998,21:371-379.
[120]Konstantinos P,Kitsopoulos.The Relationship Between the Thermal Behavior of Clinoptilolite and its Chemical Composition[J].Clays and Clay Minerals,2001,49(3):236-243.
[121]国家环境保护总局.水和废水监测分析方法[M].第四版,北京:中国环境科学出版社,2002.
[122]周云,戴婕,王占生.曝气生物滤池在上海周家渡水厂的应用[J].中国给水排水,2002,(10):68.
[123]Seguret F.Hydrodynamic behavior of a full-scale submerged biofilter and its possible influence on performances[J].Wat Sci Tech,1998,38(89):249-256.
[124]郭安祥.BAF处理低浓度生活污水[D].西安:西安建筑科技大学,2004.
[125]周晴,傅金祥,赵玉华,等.UBAF两种挂膜方式的试验研究[J].工业安全与环保,2005,31(5):28-30.
[126]邱立平,杜茂安,冯琦.二段曝气生物滤池处理生活污水的试验研究[J].环境工程,2001,19(2):22-24.
[127]田文华,文湘华,钱易.沸石滤料曝气生物滤池去除COD和氨氮性能研究.中国给水排水,2002,18(12):13-15.
[128]Oldenburg M.,Sekoulov I Multipurpose filters with ionexchanger for the equatization of ammonia peaks.Wat Sci Tech,1995,32(7):199-206
[129]袁志忠,陈晓如.滤池冲洗方式探讨[J].给水排水,1999,25(1):8-9.
[130]A Amirtharajah.Optimum Back-Washing of Filters with Ainswur:a Review.Wat Sci Tech,1993,27(10):195-211.
[131]曹相生.污水深度处理中的生物强化过滤技术研究[D].哈尔滨工业大学博士学位论文,2003:103-106