基于BST的多层薄膜及其可调器件的研究
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摘要
当代无线电技术与微电子技术朝着小型化、集成化方向发展。铁电材料因其具有介电性、压电性、热释电、铁电性等重要特性,越来越受到研究者的重视。Ba_xSr_(1-x)TiO_3具有高介电常数、较低的损耗等良好的性能,成为研究的热点之一。顺电相下BST材料具有介电常数随外加偏压而改变的特性,且在微波范围仍具有很大的介电常数,这使得BaxSr1-xTiO3材料成为移相器、滤波器、变容器等微波射频器件潜在的功能材料,具有很好的应用前景。但是在实际应用和研究中还存在着一些问题:如与硅基半导体工艺的集成,介电可调性能与损耗性能存在着矛盾。
     MgO具有和BST相近的晶格参数,并且具有很好的微波特性和稳定性,已经被广泛应用于微波领域。本文通过在硅衬底上射频磁控溅射MgO,并对其工艺进行优化,以此作为缓冲层生长Ba_(0.5)Sr_(0.5)TiO_3。本文加工了插指式电容,并利用HP4192测量其介电性能,同时对比了LNO/MgO/BST复合缓冲层结构。实验研究表明:MgO缓冲层不仅改善了Ba_(0.5)Sr_(0.5)TiO_3的结晶性能,而且缓冲层的插入提高了Ba_(0.5)Sr_(0.5)TiO_3的介电可调性,可调率从原来的14.7%(1MHz)增加到61.5%,而且介电损耗从原来的0.15减小到0.05左右。同时在前期研究基础上,制备了LNO/MgO/BST多层复合薄膜结构,复合缓冲层结构具有更高的可调性,但同时损耗也较大,这可能与介面层的低性能有关。在此基础上,利用微细加工技术制备了共面波导结构,借助网络分析仪Agilent 8722ES S-parameter Network Analyzer测试了共面波导的传输性能。
With the trend of wireless communication and microelectronics technology becoming smaller and integrated, the ferroelectric material has received much more attention for its dielectric piezoelectricity, pyro-electricity and Ferro-electricity. Ba_xSr_(1-x)TiO_3 has aroused great interest with its high dielectrics and low dielectric loss under high frequency. The BaxSr1-xTiO3 at paraelectric phase has dielectric tunability under biased electrical field and comparatively high permittivity under microwave band, which make BaxSr1-xTiO3 a promising functional material for tunable microwave devices, such as phase shifter, voltage tunable filter etc. However, there still exist some problems in utilization and research: the integration of BST with silicon semiconductor fabrication and the conflict between high tunability and low dielectric loss.
     MgO has excellent microwave properties and stability, which has been widely utilized in RF and microwave area. Also, the parameter of crystallization of MgO is close to that of BST. In this study, the Ba_(0.5)Sr_(0.5)TiO_3 was deposited on Si with MgO and LNO/MgO as the buffer layer which were deposited by rf. Magnetron sputtering. Then the interdigital capacitors have been produced by photolithographic techniques.
     The structural and electric properties of the multi-layer films were investigated. It has been shown that the MgO buffer layer not only enhanced the crystallization of Ba_(0.5)Sr_(0.5)TiO_3, but also improved the tunability from 14.7% (1MHz) to 61.5%, and the dielectric loss was decreased from 0.15 to around 0.05. The LNO/MgO/BST composite films had higher tunability with comparatively higher dielectric loss, which depended on the better crystallization of Ba_(0.5)Sr_(0.5)TiO_3 and the bad interface of composite films. The CPW structure has been produced with micro-fabrication technology, and the property of CPW was tested by network analyzer Agilent 8722ES S-parameter Network Analyzer.
引文
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