B30铜镍合金在海水中的腐蚀电化学性能研究
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摘要
本文对B30铜镍合金在海水环境中的腐蚀行为及相关电化学性能进行研究,探讨海水流速、异种金属接触、全浸时间、温度、pH值、盐度各因素对该材料的腐蚀性能和电化学性能的影响,综合评价B30材料的环境适应性能。
通过海水全浸腐蚀试验,结合扫描电镜(SEM)及能谱分析(EDS)等微观分析手段研究了B30铜镍合金的腐蚀速率、腐蚀类型以及微观腐蚀形貌。并采用原子力显微镜(AFM)、EDS等方法考察其表面膜的形成及生长规律,探讨表面膜的存在对材料耐蚀性的影响。
借助旋转圆筒冲刷腐蚀实验机、流动海水试验台架等装置,研究不同流速条件下B30铜镍合金的冲刷腐蚀速率以及微观腐蚀形貌。结果表明:B30材料在流速低于5m/s海水中具有较高的耐冲刷腐蚀性能。
通过静态海水和流动海水中的电偶腐蚀试验,研究异种金属类型、海水流速、阴/阳极面积比等因素变化对B30铜镍合金电偶腐蚀性能的影响。结果表明:B30材料与316L不锈钢和TA2钛合金偶接时腐蚀加剧,而与紫铜、黄铜、B10铜镍合金等材料偶接时可得到有效保护。
采用电化学阻抗谱、循环阳极极化曲线等测试方法,研究浸泡时间、Cl-浓度、pH值、温度等环境因素对B30铜镍合金腐蚀行为和电化学行为的影响。结果表明:B30材料的平均腐蚀速率随着浸泡时间延长而降低,点蚀现象随着Cl-浓度增大而加重,耐蚀性能随着温度升高和pH值降低而有所下降。
The corrosion behavior of 70/30Cu-Ni alloy in seawater was introduced. The corrosion behavior of 70/30Cu-Ni alloy and the corrosion mechanism were studied by immersion test, galvanic corrosion test, erosion-corrosion test and corrosion electrochemical tests.
The immersion corrosion behavior was studied by scanning electron microscope(SEM), atomic force microscopy(AFM)and X-ray energy diffraction spectrometers(EDS). The corrosion velocity of the material was studied by weight-loss method. The results show that 70/30Cu-Ni alloy is a kind of material with high anticorrosion performance, which depends on the formation of an intact and compact oxide film on the surface of the alloy. The corrosion velocity is reduced by the formation of the oxide film.
Galvanic corrosion characteristics of 70/30Cu-Ni alloy connected with other materials such as titanium-alloy, stainless steel and copper alloy, were studied by testing the corrosion current, voltage and velocity. The galvanic corrosion behavior of 70/30Cu-Ni alloy and TUP copper in different area was also studied. The results show that 70/30Cu-Ni alloy performs as the anode of the galvanic corrosion while connected with titanium-alloy and stainless steel, otherwise performing as the cathode while connected with copper alloy. The galvanic corrosion will turn severely with the increase area ration of anode and cathode.
The emersion-corrosion behavior of 70/30Cu-Ni alloy in different speed flowing seawater was studied by circumrotate canister emersion-corrosion test and flowing water tube test. The results show that the ultimate speed is 5m/s. The galvanic corrosion will turn severity with the increase of the speed.
The corrosion behavior of 70/30Cu-Ni influenced by immersion time, pH and temperature were studied by electrochemical impedance spectroscopy(EIS), potectiondynamic, liner polarization and cyclic polarization. The results show that the anticorrosion performance of 70/30Cu-Ni alloy will enhanced with the increase of immersion time and pH. The alloy is eroded easily with the increase of consistence of Cl- and temperature.
通过海水全浸腐蚀试验,结合扫描电镜(SEM)及能谱分析(EDS)等微观分析手段研究了B30铜镍合金的腐蚀速率、腐蚀类型以及微观腐蚀形貌。并采用原子力显微镜(AFM)、EDS等方法考察其表面膜的形成及生长规律,探讨表面膜的存在对材料耐蚀性的影响。
借助旋转圆筒冲刷腐蚀实验机、流动海水试验台架等装置,研究不同流速条件下B30铜镍合金的冲刷腐蚀速率以及微观腐蚀形貌。结果表明:B30材料在流速低于5m/s海水中具有较高的耐冲刷腐蚀性能。
通过静态海水和流动海水中的电偶腐蚀试验,研究异种金属类型、海水流速、阴/阳极面积比等因素变化对B30铜镍合金电偶腐蚀性能的影响。结果表明:B30材料与316L不锈钢和TA2钛合金偶接时腐蚀加剧,而与紫铜、黄铜、B10铜镍合金等材料偶接时可得到有效保护。
采用电化学阻抗谱、循环阳极极化曲线等测试方法,研究浸泡时间、Cl-浓度、pH值、温度等环境因素对B30铜镍合金腐蚀行为和电化学行为的影响。结果表明:B30材料的平均腐蚀速率随着浸泡时间延长而降低,点蚀现象随着Cl-浓度增大而加重,耐蚀性能随着温度升高和pH值降低而有所下降。
The corrosion behavior of 70/30Cu-Ni alloy in seawater was introduced. The corrosion behavior of 70/30Cu-Ni alloy and the corrosion mechanism were studied by immersion test, galvanic corrosion test, erosion-corrosion test and corrosion electrochemical tests.
The immersion corrosion behavior was studied by scanning electron microscope(SEM), atomic force microscopy(AFM)and X-ray energy diffraction spectrometers(EDS). The corrosion velocity of the material was studied by weight-loss method. The results show that 70/30Cu-Ni alloy is a kind of material with high anticorrosion performance, which depends on the formation of an intact and compact oxide film on the surface of the alloy. The corrosion velocity is reduced by the formation of the oxide film.
Galvanic corrosion characteristics of 70/30Cu-Ni alloy connected with other materials such as titanium-alloy, stainless steel and copper alloy, were studied by testing the corrosion current, voltage and velocity. The galvanic corrosion behavior of 70/30Cu-Ni alloy and TUP copper in different area was also studied. The results show that 70/30Cu-Ni alloy performs as the anode of the galvanic corrosion while connected with titanium-alloy and stainless steel, otherwise performing as the cathode while connected with copper alloy. The galvanic corrosion will turn severely with the increase area ration of anode and cathode.
The emersion-corrosion behavior of 70/30Cu-Ni alloy in different speed flowing seawater was studied by circumrotate canister emersion-corrosion test and flowing water tube test. The results show that the ultimate speed is 5m/s. The galvanic corrosion will turn severity with the increase of the speed.
The corrosion behavior of 70/30Cu-Ni influenced by immersion time, pH and temperature were studied by electrochemical impedance spectroscopy(EIS), potectiondynamic, liner polarization and cyclic polarization. The results show that the anticorrosion performance of 70/30Cu-Ni alloy will enhanced with the increase of immersion time and pH. The alloy is eroded easily with the increase of consistence of Cl- and temperature.
引文
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