羧酸调控的三/四唑类过渡金属含能配合物的合成、结构及燃烧催化性能研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
三/四唑类化合物由于具有配位能力优良、配位模式多样等特点,已受到研究者的广泛关注,同时,由于其与金属离子形成的含能配合物具有高能、高密度、钝感等特点,有单作为固体推进剂的燃烧催化剂。为构筑结构新颖的含能配合物,实现高能、饨感及推进剂组份的氧平衡,木论文将羧酸类(丙二酸、丁二酸、反丁烯二酸、对苯二甲酸、均苯三甲酸及吡啶2,6-二甲酸)引入到三/四唑类(1,2,4-三唑、3,5-二氨基-1,2,4-三唑、3-氨基-5-羧基-1,2,4-三唑、5-氨基四唑)过渡金属含能配合物的合成中,利用溶液法及水热/溶剂热法合成出30种未见文献报道的Cu、Co、Ni配合物,进行了化学分析、元素分析、红外光谱、热稳定性等研究,并通过X-射线单晶衍射技术测定了其中20种配合物的结构。主要研究内容及结论如下:
     1.结构分析结果表明:配合物中三唑类配体可同时存在中性及阴离子两种状态,四唑类配体可作为中性分子与金属离子单齿配位。金属与唑类配体可形成单核、双核、三核结构单元,羧酸类配体再通过不同的配位模式及分子间作用力将其连接成为配位聚合物及三维超分子结构。
     2.对配合物的液相生成反应热动力学研究表明,配合物的液相生成反应均为放热反应,有利于反应进行。对配合物的热稳定性研究表明,配合物脱水产物表现出较高的热稳定性(大部分主体框架在300℃以上仍保持稳定)。与含脂肪羧酸配体的配合物相比,含有芳香羧酸配体的配合物热稳定性更高一些,这是后者结构中存在稳定的簇状结构和螯合环导致的。
     3.通过DSC技术研究了配合物对推进剂主要组分(AP、HMX、RDX、NC/NG)热分解行为的影响。结果表明,配合物与推进剂主要组分形成的二元混合体系在热分解过程中都存在程度不同的分解峰温提前,放热量增大及活化能降低现象,配合物有作为含能燃烧催化剂应用于推进剂配方的潜质。配合物含氧量的增加对混合体系热分解的影响是明显的,通过将羧酸引入到Cu、Co、Ni/三唑、四唑体系来实现双基同体推进剂燃烧催化的思路合理。
Triazole, tetrazole and their derivatives have attracted a wide spread attention of researchers because their good coordination ability and various coordination modes. Meanwhile, the energy complexes with triazole and tetrazole can be used as combustion catalyst in solid propellant owing to the high energy, high densities and low sensitivity. In pursuit of the novel structure and the coordination of high energy, stability and oxygen balance of propellant components, co-ligangs carboxylic acid (malonic acid, succinic acid, fumaric aicd, 1,4-benzenedicarboxylic acid, 1,3,5-benzenetricarboxylic acid and 2,6-pyridine-dicarboxylic acid) are introduced to the triazole/tetrazole systems (1,2,4-triazole, 3,5-diamine-1,2,4-triazole, 3-diamine-5-carboxylic acid-1,2,4-triazole, 5-aminotetrazole) complexes of transition metals. Using solution method and hydrothermal/solvothermal method, thirty new Cu, Co, Ni complexes are prepared and characterized by chemical analyses, elemental analyses, IR spectra, TG-DTG techniques. The structures of twenty complexes among them are determained by X-ray single crystal diffraction. The main research contents and conclusions in this dissertation are summarized as follow:
     1. The structure analysis results of complexes reveal that the triazole ligand may coexist in two states of neutral and anion; tetrazole acting as a neutral unidentate ligand coordinate with metal. Metal and triazole/tetrazole can be built mononuclear, binuclear and trinuclear complexes. Carboxylic acid ligands are introduced the M- triazole/tetrazole system, leading to coordination polymers and supermolecular structures by different coordination modes and intermolecular interaction.
     2. The thermokinetic research of liquid-phase reactions of complexes reveal that all the liquid phase formation reaction of the complexes are exothermic and benefit the proceeding of reactions. The thermal stability of the complexes reveals that the dehydration products of complexes possess high thermal stability (most main framework still keep stabilization above 300℃). Compared with the complexes contained aliphatic acids, the complexes contained aromatic acids exhibit higher stability because of the steady cluster structures and chelate ring.
     3. The effects on the thermal decomposition behavior of complexes for the main component of propellant (AP、HMX、RDX、NC/NG) are investigated by DSC technique. The results indicate that all the binary mixture system composed of complexes and main component of propellant shows ahead of decomposed peak temperature, increase of heat and decrease of active energy during thermal decomposition. The complexes can be used as energetic combustion catalyst in propellants. The increasing of oxygen content in complexes have a significant influence on the thermal decomposition of mixture system, which approves that the idea adding carboxylic acid to the M/triazole/tetrazole system is reasonable for the combustion catalysis in double-base solid propellant.
引文
[1]刘所恩,杜宝玉,张健,等.新型含能催化剂在低特征信号推进剂中的应用研究[J].含能材料,2001,9(3):130-132
    [2]Fogelxang A.E.,Sinditoskii V.P.,Scmushkin V.V.,et al.Combustion of Explosives Database Flame.Version 2.4[C],Moscow,1990-1994
    [3]赵凤起,李上文.RDX-CMDB推进剂中组合催化剂的研究[J].推进技术,1992,13(2):57-64
    [4]李上文,孟燮铨,张蕊娥,等.螺压硝胺无烟改性双基推进剂燃烧性能调节和控制规律[J].推进技术,1995,16(3):63-69
    [5]Klapotke,T.M.,Rienacker,Claudia M.Drop hammer test investigations on some inorganic and organic azides[J].Propellants Explosive Pyrotechnics,2001,26(1):43-47
    [6]李上文,赵凤起,刘所恩,等.惰性与含能催化剂对Al-RDX-CMDB推进剂燃烧性能的影响[J].含能材料,1997,6(2):49-54
    [7]赵凤起,陈沛,李上文,等.四唑类化合物的金属盐作为微烟推进剂燃烧催化剂的研究[J].兵工学报,2004,25(1):30-33
    [8]柴玉萍,张同来.国内外复合固体推进刺燃速催化剂研究进展[J].固体火箭技术,2007,30(1):44-47
    [9]Pundlik S.K.,Palaiah R.S.,Nair J.K.,et al.Influence of metal salts of 4-(2,4,6-trinitroanilino)benzoic acid on the burning rate of double base propellants[J].Journal of Energetic Materials,2001,19:339-347
    [10]王宏社,杜志明.富氮化合物研究进展[J],含能材料.2005,13(3):196-203
    [11]张德雄,张衍,王伟平.高能量密度材料(HEDM)研究开发现状及展望[J].固体火箭技术,2005,28(4):284-288
    [12]阳世清,岳守体.国外四嗪四唑类高氮含能材料研究进展[J].含能材料,2003,11(4):232-235
    [13]Hiskey M.,Goldman N.,Stine J.,Highnitrogen energetic material derived from azotetrazolate[J].Journal of Energetic Materials,1998,16:119-127
    [14]Thomas M.K.,Caries M.S.,Bistetrazoles:Nitrogen-Rich,High-Performing,Insensitive Energetic Compounds[J].Chemistry of materials,2008,20:3629-3637
    [15]Michael A.H.,Nit G.,James R.S.,High-nitrogen energetic materials derived from azotetrazo late [J].Journal of Energetic Materials,1998,16:119-127
    [16]李加荣.唑系含能化合物的特征[J].火炸药学报,1998,1:57-58
    [17]Huynh M.H.V.,Hiskey M.,Ernest L.,et al.Polyazido High-Nitrogen Compounds:Hydrazo and Azo 1,3,5-triazine[J].Angewandte Chemic International Edition,2004,43:4924-4928.
    [18]Hiskey M.,Chavez D.Insensitive High-Nitrogen Compounds.DE 2001776133
    [19]Haasnoot J.G,Mononuclear,oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands[J].Coordination Chemistry Review.2000,200-202:131-185
    [20]张建国,张同来,张志刚,等.唑类杂环化合物及其配合物的研究概述[J].含能材料,2001, 9(2):90-93
    [21]Xue H.,Gao Y.,Brendan T.,et al.New Energetic Salts Based on Nitrogen-Containing Heterocycles[J],Chemistry of Materials,2005,17:191- 198
    [22]Wang R.H.,Gao H.X.,Ye C.F.,et al.Strategies toward syntheses of triazolyl-or triazolium functionalized unsymmetrical energetic salts[J],Chemistry of Materials,2007,19:144-152
    [23]Xue H.,Gao H.X.,Brendan T.,et al.Energetic salts of 3-nitro-1,2,4-triazole,5-nitroaminotetrazole,and other nitro substituted azoles[J],Chemistry of Materials,2007,19(7):1731- 1739
    [24]Gamézo V.N.,Odiot S.,Blain M.,et al.Theoretical analysis of the effects of nitration of the explosive properties of triazole:4-nitro-2H-1,2,3-triazole and 4,5-dinitro-2H-1,2,3-triazole[J].Journal of Molecular Structure(Theochem.).1995,337:189-197
    [25]Oxley J.C.,Smith J.L.,Zhou Z.L.,et al.Thermal Decomposition Studies on NTO and NTO/TNT[J],Journal of Physical Chemistry,1995,99(25):10383-10391
    [26]蒋琪英,沈娟,钟国清,等.含能配合物的研究进展[J].现代化工,2006,26(4):24-28
    [27]邓敏智,杜恒,赵凤起,等.四唑类盐的制备及其在固体推进剂中的应用初探[J].国体火箭技术,2003,26(3):53-57
    [28]郑玉梅,邓敏钾,赵凤起,等.4-羟基-3,5-二硝基吡啶氮氧化物铅及铜盐的合成[J].火炸药学报.2002.4:51-56
    [29]吴瑞凤,张同来,张建国,等.芳香羧酸类配位聚合物在含能材料中的应用研究[J].含能材料,2006,14(2):159-160
    [30]田德余,刘剑洪.化学推进剂计算能量学[M].河南科学技术出版社.1999,42-48
    [31]阳世清,徐松林,黄亨健,等.高氮化合物及其含能材料[J].化学进展,2008,20(4),526-537
    [32]宋纪蓉.NTO金属配合物单晶制备、晶体结构、热行为和量子化学研究[D].南京:南京理工大学.1997
    [33]张同来.NTO金属盐的制备、结构农征、热分解机理和非等温反应动力学的研究[D].南京:南京理工大学.1993
    [34]Kulkarni P.B.,Purandare G.N.,Nair J.K.,et al.Synthesis,characterization,thermolysis and performance evaluation Studies on alkali metal salts of TABA and NTO[J].Journal of Hazardous Materials,2005,119(1-3):53-61
    [35]Kulkarni P.B.,Reddy T.S.,Nair J.K.,et al.Studies on salts of 3-nitro-1,2,4-triazol-5-one(NTO)and 2,4,6-trinitroanilino benzoic acid(TABA):Potential energetic ballistic modifiers[J].Journal of Hazardous Materials,2005,123(1-3):54-60
    [36]Singh G.,Kapoor I.P.S.,Prem F.S.,et al.Studies on energetic compounds part 23:Preparation,thermal and explosive characteristics of transition metal salts of 5-nitro-2,4-dihydro-3H-1,2,4-triazole-3-one[J].Propellants Explosive Pyrotechnics,2002,27(1):16-22
    [37]Singh G.,Felix S.P.,Studies of energetic compounds,part 29:Effect of NTO and its salts on the combustion and condensed phase thermolysis of composite solid propellants[J].Combustion and Flame,2003,132(3):422-432.
    [38]白广梅,梁育民,张续柱,等.硝胺推进剂燃烧性能的改善[J].火炸药学报,1998(2):7-9
    [39]贝茨.起爆药系统中四唑类的潜力[J].火工品,1988,(1):6-9
    [40]Lu Y.C.,Wierenga P.H.,Advanced propellant/additive development for fire suppressing gas generators[A].Proceedings of Halon Options Technical Working Conference[C].2000:361-370
    [41]Thomas M.K.,Jorg S.,Andreas U.W.Nitrogen-Rich Salts of 1-Methyl-5-nitriminotetrazolate:An Auspicious Class of Thermally Stable Energetic Materials[J].Chemistry of Mateials.2008,20:4519-4530
    [42]Zhang J.P.,Lin Y.Y.,Zhang W.X.,et al.Temperature-or guest-induced drastic single-crystal to single-crystal transformations of a nanoporous coordination polymer[J].Journal of American Chemistry Soceity,2005,127(41):14162-14163
    [43]Zhang J.P.,Lin Y.Y.,Huang X.C.,et al.Copper(Ⅰ) 1,2,4-Triazolates and Related Complexes:Studies of the Solvothermal Ligand Reactions,Network Topologies,and Photoluminescence Properties[J].Journal of American Chemistry Society,2005,127(5),5495-5506
    [44]Li W.,Jia H.P.,Ju Z.F.,et al.A novel chiral Cd(Ⅱ) coordination polymer based on chiral unsymmetrical 3-amino-1,2,4-triazole with an unprecedented bridging mode[J].Crystal Growth &Design,2006,6(9):2136-2140
    [45]Galvez-Ruiz J.C.,Holl G.,Karaghiosoff K.,et al.Derivatives of 1,5-Diamino-1H-tetrazole:A New Family of Energetic Heterocyclic-Based Salts[J].Inorganic Chemistry,2005,44:4237-4253
    [46]Ouellette W.,Galan-Mascaros J.R.,Dunbar K.R.,et al.Hydrothermal Synthesis and Structure of a Three-Dimensional Cobalt(Ⅱ) Triazolate Magnet[J].Inorganic chemistry,2006,45:1909-1911
    [47]Ouellette W.,Prosvirin A.V.,Chieffo V.,et al.Solid-State Coordination Chemistry of Cu/Triazole/X System(X = F~-,Cl~-,Br~-,I~-,OH~- and SO_4~(2-))[J].Inorganic chemistry,2006,45:9346-9366
    [48]Ouellette W.,Hudson B.S.,Zubieta J.,Hydrothermal and Structural Chemistry of the Zn(Ⅱ) and Cd(Ⅱ)-1,2,4-Triazolate Systems[J].Inorganic chemistry,2007,46:4887-4904
    [49]Ouellette W.,Prosvirin A.V.,Valeich J.,et al.Hydrothermal Synthesis,Structural Chemistry,and Magnetic Properties of Materials of the M/Triazolate/Anion Family,Where M = Mn,Fe,and Ni[J].Inorganic chemistry,2007,46:9067-9082
    [50]Ouellette W.,Yu M.H.,O'Connor C.J.,et al.Hydrothermal Chemistry of the Copper-Triazolate System:A Microporous Metal-Organic Framework Constructed from Magnetic {Cu_3(μ_3-OH)(triazolate)_3}~(2+) Building Blocks,and Related Materials[J].Angewandte Chemie International Edition,2006,45:3497-3500
    [51]Ding B.,Yi L.,Cheng P.,et al.Synthesis and Characterization of a 3D Coordination Polymer Based on Trinuclear Triangular Cull as Secondary Building Units[J].Inorganic Chemistry,2006,45(15):5799-5803
    [52]Zhai Q.G.,Lu C.Z.,Chen S.M.,et al.Design of Novel Three-Dimensional Coordination Polymers Based on Triangular Trinuclear Copper 1,2,4-Triazolate Units[J].Crystal Growth & Design, 2006, 6: 1393-1398
    [53] He X., Lu C. Z., Yuan D. Q., Two 3D Porous Cadmium Tetrazolate Frameworks with Hexagonal Tunnels[J]. Inorganic Chemistry, 2006, 45: 5760-5766
    [54] Yao Y. L., Xue L., Che Y. X., et al. Syntheses, Structures, and Characterizations of Two Pairs of Cd(Ⅱ)-5-Aminotetrazolate Coordination Polymers[J]. Crystal Growth & Design, 2009, 9(1):606-610
    [55] Wu T., Chen M., Li D., A Coordination Polymer Containing Inorganic Buckybowl Analogues[J]. European Journal of Inorganic Chemistry, 2006, 2132-2135
    [56] Shyu E., Supkowski R. M., LaDuca R. L., A Chiral Luminescent Coordination Polymer Featuring a Unique 4-Connected Self-Catenated Topology Built from Helical Motifs[J]. Inorganic Chemistry,2009, 48(7): 2723-2725
    [57] Rosi N. L., Kim J., Eddaoudi M., et al. Rod Packings and Metal-Organic Frameworks Constructed from Rod-Shaped Secondary Building Units[J]. Journal of American Chemistry Society, 2005,127(5), 1504-1518
    [58] Chen S. P., Yuan Y. X., Pan L. L., et al. A Novel Supramolecular Plaster Based on An Organic Acid-Base Compound: Synthesis, Structure, Mechanical Properties, and Sterilizing Performance[J].Crystal Growth & Design, 2009, 9(2), 874-879
    [59] Montney M. R., Krishnan S. M., Patel N. M., et al. Divalent Metal Succinate/4,4'-Dipyridylamine Extended Solids: From Helical Chains to Diverse Three-Dimensional Networks Featuring Double,Quadruple, or Self-Interpenetration[J]. Crystal Growth & Design, 2007, 7: 1145-1153
    [60] Rao C. N. R., Natarajan S., Vaidhyanathan R., A Homochiral Metal-Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity[J]. Angewandte Chemie International Edition, 2004, 43(38): 1466-1496
    [61] Bernini M. C., Brusau E. V., Narda G. E., et al. The Effect of Hydrothermal and Non-Hydrothermal Synthesis on the Formation of Holmium(Ⅲ) Succinate Hydrate Frameworks[J]. European Journal of Inorganic Chemistry, 2007, 684-693
    [62] Livage C., Forster P. M., Guillou N., et al. Effect of Mixing of Metal Cation on the Topology of Metal Oxide Networks[J]. Angewandte Chemie International Edition, 2007, 46(31): 5877-5879
    [63] Yang C. Y., Wang S. L., Intrinsic Yellow Light Phosphor: An Organic-Inorganic Hybrid Gallium Oxalatophosphate with Hexameric Octahedral Ga_6(OH)_4O_(26) Cluster[J]. Journal of American Chemistry Society, 2008, 130(4): 1146-1147
    [64] He J., Zhang J. X., Tan G. P., et al. Second Ligand-Directed Assembly of Photoluminescent Zn(Ⅱ) Coordination Frameworks[J]. Crystal Growth & Design, 2007, 7, 1508-1513
    [65] Du M., Zhang Z. H., You Y. P., et al. R-Isophthalate (R = -H, -NO_2, and -COOH) as modular building blocks for mixed-ligand coordination polymers incorporated with a versatile connector 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole[J]. Crystal Engineering Communication, 2008, 10:306-321
    [66] Manna S. C., Zangrando E., Chauhuri N. R. Dinuclear Cu(Ⅱ) complexes using pyridine-2,6- dicarboxylate in combination with donor spacer[J].Journal of Molecular Structure 2008,877:145-151
    [67]Banerjee A.,Mahata P.,Natarajan S.The Use of Liquid-Liquid Interface(Biphasic) for the Preparation of Benzenetricarboxylate Complexes of Cobalt and Nickel[J].European Journal of Inorganic Chemistry.2008,22:3501-3514
    [68]Chen B.L.,Wang L.B.,Zapata F.,et al.A Luminescent Microporous Metal-Organic Framework for the Recognition and Sensing of Anions[J].Journal of American Chemistry Society,2008,130:6718-6719
    [69]Chen B.L.,Zhao X.B.,Putkham A.,et al.Surface Interactions and Quantum Kinetic Molecular Sieving for H_2 and D_2 Adsorption on a Mixed Metal-Organic Framework Material[J].Journal of American Chemistry Society,2008,130:6411-6423
    [70]Park H.,Moureau D.M.,Parise J.B.,Hydrothermal Synthesis and Structural Characterization of Novel Zn-Triazole-Benzenedicarboxylate Frameworks[J],Chemistry of Materials,2006,18:525-531
    [71]Park H.,Britten J.F.,Mueller U.,et al.Synthesis,Structure Determination,and Hydrogen Sorption Studies of New Metal-Organic Frameworks Using Triazole and Naphthalenedicarboxylic Acid[J],Chemistry of Materials,2007,19:1302-1308
    [72]Zhai Q.G.,Lu C.Z.,Wu X.Y.,et al,Coligand Modulated Six-,Eight-,and Ten-Connected Zn/Cd-1,2,4-Triazolate Frameworks Based on Mono-,Bi-,Tri-,Penta-,and Heptanuclear Cluster Units[J].Crystal Growth & Design,2007,7(11):2332-2342
    [73]Lin Y.Y.,Zhang Y.B.,Zhang J.P.,et al.Pillaring Zn-Triazolate Layers with Flexible Aliphatic Dicarboxylates into Three-Dimensional Metal-Organic Frameworks[J],Crystal Growth & Design,2008,8(10):3673-3679
    [74]王晗,赵凤起,李上文,等.碳物质在固体推进剂中的功能及其作用机理[J],火炸药学报,2006,29(4),32-35
    [75]焦宝娟.双四唑类过渡金属含能配合物的合成及性质研究[J].西安:西北大学,2006
    [1]Yang J.,Ma J.F.,Liu Y.Y.,et al.A Series of Cu(Ⅱ) Complexes Based on Different Bis(imidazole)Ligands and Organic Acids:Formation of Water Clusters and Fixation of Atmospheric Carbon Dioxide[J].Crystal Growth & Design,2008,8(12):4383-4393
    [2]Livage C.Forster P.M.Guillou N.et al,Effect of Mixing of Metal Cations on the Topology of Metal Oxide Networks[J].Angewandte Chemie International Edition,2007,46(31):5877-5879
    [3]Kilday M.V.,The enthalpy of solution of SRM 1655(KCl) in H_2O[J],Journal of Research of the National Bureau of Standards, 1980, 85(6), 467-469.
    [4] Sheldrick G. M., SHELXS-97, Program for X-ray Crystal Structure Solution, G(o|¨)ttingen University, Germany, 1997
    [5] Sheldrick G. M., SHELXL-97, Program for X-ray Crystal Structure Refinement, G(o|¨)ttingen University, Germany, 1997
    [6] Herrmann W. A., Herdltweck E., Scherer W., et al. Metallkomplexe in Biologie und Medizin, V. Neue Hydroxycarboxylat-Komplexe von Bismut. Synthese und Struktur von Bismut(Ⅲ)-malat-monohydrat und Bismut(Ⅲ)-tartrat-trihydrat[J]. Chemische berichte, 1993, 126:51-56
    [7] Gong Y. Q., Wang R. H., Yuan D. Q., et al. Chains, ladders and sheets of d~(10) metal-organic polymers generated from the flexible bipyridyl ligands[J]. Polyhedron, 2007,26: 5309-5316
    [8] Song Y. S., Yan B., Chen Z. X., Hydrothermal synthesis, crystal structure and luminescence of four novel metal-organic frameworks[J]. Journal of Solid State Chemistry, 2006, 179:4037-4060
    [9] Zheng Y. Q., Xie H. Z., Fumarato-bridged open layers Syntheses and crystal structures of M(H_2O)_2L with M = Cu, Cd and H_2L = fumaric acid[J]. Journal of Coordination Chemistry, 2005, 58: 539-548
    [10] Spek, A. L. PLATON, Utrecht University: Utrecht, The Netherlands, 2003
    [11] Zhang L. P., Huang L., Qu L. B., et al. Two novel R and S malato-bridged coordination polymers by reacting lanthanide chloride and maleic anhydride, 1,10-phenanthroline at hydrothermal condition Journal of molecular structure[J]. 2006, 787: 14-17
    [12] He X., Lu C. Z., Yan Y., Hydrothermal synthesis, crystal structures of two new transition metal coordination chain polymers with mixed ligands[J].Inorganic Chemistry Communications[J]. 2004, 7:851-853
    [13] Zhang X. M., Chen X. M., A New Porous 3-D Framework Constructed From Fivefold Parallel Interpenetration of 2-D (6,3) Nets: A Mixed-Valence Copper(Ⅰ,Ⅱ) Coordination Polymer [Cu~Ⅰ_2Cu~Ⅱ(4,4'-bpy)_2(pydc)_2]·4H_2O[J]. European Journal of Inorganic Chemistry, 2003,413-417
    [14] Antolini L., Fabretti A. C., Gatteschi D., et al. Synthesis, crystal and molecular structure, and magnetic properties of bis[(3,5-diamino-1,2,4-triazole-N1 ,N2-bis(3,5-diamino-1,2,4-triazolato-N1 ,N2)triaqua cobalt(Ⅱ))]cobalt(Ⅲ) trichloride nonahydrate[J]. Inorganic chemistry, 1991, 30(25):4858-4860
    [15] Antolini L., Fabretti A.C., Gatteschi D., et al, Synthesis, crystal and molecular structure, and magnetic properties of bis[tris(.mu.-3,5-diamino-1 ,2,4-triazole-N1,N2) tris(thiocyanato-N)nickel(Ⅱ)]nickel(Ⅱ) hexahydrate[J]. Inorganic Chemistry, 1990,29(1): 143-145
    [16] Vos G., Rudolf A. G., Haasnoot J. G., et al. Crystal structure at 300 and 105 K, magnetic properties and Moessbauer spectra of bis(triaquatris(4-ethyltriazole-N1)iron(Ⅱ)-N2,N2',N2") iron(Ⅱ) hexakis(trifluoromethanesulfonate). A linear, trinuclear iron(Ⅱ) compound, showing a unique high-spin-low-spin transition of the central iron atom[J]. Inorganic chemistry, 1984, 23: 2905-2910
    [17] Sun S. Chen S. P., Gao S. L., Inclusion cages constructed from trinuclear linear Zn~Ⅱ/Co~Ⅱ building blocks[J]. Journal of Coordination Chemistry, 2008, 61(13): 2068-2078
    [18]Yao Y.L.,Xue L.,Che Y.X.,et al.Syntheses,Structures,and Characterizations of Two Pairs of Cd(Ⅱ)-5-Aminotetrazolate Coordination Polymers[J].Crystal Growth & Design,2009,9(1):606-610
    [19]Ouellette W.,Prosvirin A.V.,Chieffo V.,et al.Solid-State Coordination Chemistry of the Cu/Triazolate/X System(X= F~-,Cl~-,Br~-,I~-,OH~-,and SO_4~(2-))[J].Inorganic Chemistry,2006,45:9346-9366
    [20]Zhang X.C.,Chen Y.H.,Liu B.,A new 1D coordination chain containing 4,4'-bi-1,2,4-triazole bridge:Synthesis,structure and optical properties[J].Inorganic Chemmistry Communication,2008,11:446-449
    [21]Nakamoto,K.Infrared and Raman Spectra of inorganic and Coordination Compounds,Wiley,New York,1986
    [22]Gao S.L.,Chen S.P.,Hu R.Z.,et al.化学反应的热动力学方程及其应用[J].Chinese Journal of Inoragnic Chemistry,2002,18:362-366
    [1]Wei W.,Wu M.Y.,Gao Q.,et al.A Novel Supramolecular Tetrahedron Assembled from Tetranuclear Copper(Ⅰ) Cluster Molecules via Aryl Embrace Interactions[J].Inorganic Chemistry.2009,48(2):420-422
    [2]Li X.,Cheng D.Y.,Lin J.L.,et al.Di-,Tetra-,and Hexanuclear Hydroxy-Bridged Copper(Ⅱ)Cluster Compounds:Syntheses,Structures,and Properties[J].Crystal Growth & Design,2008,8(8):2853-2861
    [3]Choi S.B.,Seo M.J.,Cho.M.Y.,A Porous and Interpenetrated Metal-Organic Framework Comprising Tetranuclear IronⅢ-Oxo Clusters and Tripodal Organic Carboxylates and Its Implications for(3,8)-Coordinated Networks[J].Crystal Growth & Design,2007,7(11):2290-2293
    [4]Sheldrick G.M.,SHELXS-97,Program for X-ray Crystal Structure Solution,G(o|¨)ttingen University,Germany,1997
    [5]Sheldrick G.M.,SHELXL-97,Program for X-ray Crystal Structure Refinement,G(o|¨)ttingen University,Germany,1997
    [6]Park H.,Moureau D.M.,Parise J.B.,Hydrothermal Synthesis and Structural Characterization of Novel Zn-Triazole-Benzenedicarboxylate Frameworks[J].Chemistry of Materials,2006,18:525-531
    [7]Spek A.L.,PLATON,Utrecht University:Utrecht,The Netherlands,2003
    [8]Chen W.X.,Wu S.T.,Long L.S.,et al.Construction of a Three-fold Parallel Interpenetration Network and Bilayer Structure Based on Copper(Ⅱ) and Trimesic Acid[J].Crystal Growth & Design,2007,7(6),1171-1175
    [9]Nakamoto K.Infrared and Raman Spectra of Inorganic and Coordination Compounds,4th Edit,Wiley,New York,1986
    [1]曲艳斌,萧忠良.汽车安全气囊用气体发生剂[J].华北工学院学报,2003,24(6):428-431
    [2]Neidert.Double base propellent containing 5-aminotetrazole[P].US 6,228,192,1999
    [3]Ramaswamy C.P.,Grzelczyk C.Gas generating composition[P].US P5 661 261,2000
    [4]阳世清,岳守体,国外四嗪四唑类高氮含能材料研究进展[J].含能材料,2003,11(4):232-235
    [5]张苏杭,韩琳,王新德.5-氨基四唑及其衍生物的合成和应用综述[J].洛阳师范学院学报,2006,5:74-78
    [6]Wang W.X.,Chen J.Z.,Liu J.H.Photoluminescent Zn(Ⅱ) Metal-Organic Frameworks Built from Tetrazole Ligand:2D Four-Connected Regular Honeycomb(4~36~3)-net[J].Crystal Growth & Design,2007,7(7):1227-1229
    [7]耿春宇,胡满成,李淑妮,等.Cs(ATZ)的制备、晶体结构与热力学性质[J].化学学报,2005,63(21):1974-1978
    [8]张建国,张同来.[Cd(ATZ)_4(H_2O)_2](PA)_2·2H_2O的合成、晶体结构和热分解机理研究[J].化学学报,2001,59(1):84-90
    [9]He X.,Lu C.Z.,Yuan D.Q.,Two 3D Porous Cadmium Tetrazolate Frameworks with Hexagonal Tunnels[J].Inorganic Chemistry,2006,45:5760-5766
    [10]Yao Y.L.,Xue L.,Che Y.X.,et al.Syntheses,Structures,and Characterizations of Two Pairs of Cd(Ⅱ)-5-Aminotetrazolate Coordination Polymers[J].Crystal Growth & Design,2009,9(1):606-610
    [11]Sheldrick G.M.,SHELXS-97,Program for X-ray Crystal Structure Solution,G(o|¨)ttingen University,Germany,1997
    [12]Sheldrick G.M.,SHELXL-97,Program for X-ray Crystal Structure Refinement,G(o|¨)ttingen University,Germany,1997
    [13]Nakamoto K.Infrared and Raman Spectra of Inorganic and Coordination Compounds,4th Edit,Wiley,New York 1986
    [1]Tompa A.S.DSC and TG study of the stability in vacuum of ferrocenyl compounds and their compatibility with ammonium perchlorate[J].Thermochimica Acta.1984,77(1-3):133-138
    [2]胡荣祖,史启祯.热分析动力学[M].北京,科学出版社.2001
    [3]Zhang J.P.,Lin Y.Y.,Huang X.C.,et al.Copper(Ⅰ) 1,2,4-Triazolates and Related Complexes,Studies of the Solvothermal Ligand Reactions,Network Topologies,and Photoluminescence Properties[J].Journal of the American Chemical Society,2005,127:5495-5506
    [4]《炸药理论》编写组.炸药理论[M].北京,国防工业出版社,1982,74-76
    [5]松全才,杨崇惠,金韶华.炸药理论[M].北京,兵器工业出版社,1997,116-118
    [6]GJB 772A-97-501.2,炸药试验方法[S].机械电子工业部兵器标准化研究所,1997
    [7]赵凤起,陈沛,李上文,等.燃速调节剂对RDX/AP/HTPB推进剂热分解的影响[J].推进技术,2003,24(1):80-82
    [8]洪伟良,赵凤起,刘剑洪.邻苯二甲酸Pb(Ⅱ)配合物纳米颗粒的合成及其燃烧催化性能[J].无机化学学报,2004,20(8):996-998

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700