结构型催化氧化催化剂及在有机污染物降解中的应用
|
摘要
为降解挥发性有机物,并解决挥发性有机物带来的环境问题,分别以γ-Al_2O_3、SiO_2为载体,以V_2O_5、TiO_2、V_2O_5-TiO_2作为活性成分,采用溶胶-凝胶法负载TiO_2和浸渍法负载V_2O_5,制备出了负载型催化剂。同时,以甲苯的催化氧化为模型反应,建立了动态催化氧化反应体系。利用该反应体系研究了催化剂的催化活性,以及影响催化性能的因素。
通过对不同载体不同活性组分催化剂的活性测试,可以得出V_2O_5-TiO_2/SiO_2对甲苯的降解能力最强。同时,对载体粒径、不同前驱物及催化剂负载量与催化剂性能的关系进行了测试和分析,得出γ-Al_2O_3最佳载体粒径为60～80目;采用偏钒酸铵的乙二酸溶液作为前驱物制备的催化剂效果最好;V_2O_5的最佳负载量为1wt.%,V/Ti比值为0.127。
对催化反应中的三个主要因素:反应温度、进气流量、进气浓度进行了研究。实验结果表明V_2O_5-TiO_2/SiO_2催化剂具有较低的起燃温度,而且它对甲苯的去除率随温度的升高迅速上升,和贵金属的催化特性相似;进气流量及浓度的增加,并没有使V_2O_5-TiO_2/SiO_2催化剂对甲苯的去除效果发生太大的变化;相反却导致V_2O_5-TiO_2/Al_2O_3催化剂对甲苯去除率的降低。与V_2O_5-TiO_2/Al_2O_3相比,V_2O_5-TiO_2/SiO_2具有较强的抗冲击能力。
采用XRD、SEM、EDX、XPS对制备的催化剂的体相结构和表面特性进行了表征。结合表征和活性测试的结果,分析了催化剂结构与催化性能之间的关系。结果发现较少的V_2O_5负载量使得V离子嵌入了TiO_2的晶体结构中,而不是形成晶形V_2O_5,并形成了V-O-Ti键;TiO_2与SiO_2发生了化学反应,有Ti-O-Si键形成,而对于Al_2O_3载体来说,TiO_2和它之间只是简单的物理结合。由活性测试的结果可看出,这些化学键有可能是催化剂的活性位,它们的生成有利于提高催化剂的催化性能,有利于增加催化剂各组分间的结合力,增强催化剂的强度。
分别以γ-Al_2O_3、SiO_2为载体,CuO为活性组分,添加Ce,用浸渍法制备了负载型催化剂。同时,以甲苯的催化氧化为模型反应,建立了动态催化氧化反应体系。利用该反应体系研究了催化剂的催化活性,以及影响催化性能的因素。
在以不同载体制备的各种催化剂中,以60～80目的γ-Al_2O_3作载体的催化剂对甲苯的去除效果最好。相对于CuO/Al_2O_3催化剂,添加Ce后的CuO-CeO_2/Al_2O_3催化剂对甲苯催化氧化的起燃温度和完全转化温度均有明显的降低。研究表明,当以60～80目的γ-Al_2O_3作载体,Cu的负载量为5wt.%,Cu与Ce的比为1:1,催化剂的焙烧温度为500℃,焙烧时间为6小时的CuO-CeO_2/Al_2O_3催化剂的催化活性最高。
针对甲苯和二甲苯催化反应中的三个主要因素(反应温度、空速、进气浓度)进行了研究。在测试范围内,CuO-CeO_2/Al_2O_3对甲苯的最佳空速为8000h-1,对CuO/Al_2O_3为6000h-1。以二甲苯为目标物的催化性能影响因素实验所得结果与甲苯的相似,CuO-CeO_2/Al_2O_3和CuO/Al_2O_3的最佳空速均为8000 h-1。和催化氧化甲苯的实验相比,CuO/Al_2O_3催化剂对二甲苯的处理效果相对较好,在不同的空速和进气浓度下去除率都在90%以上,虽然能够达到二甲苯去除要求,但与CuO-CeO_2/Al_2O_3相比仍不能达到最佳的处理效果。CuO-CeO_2/Al_2O_3催化剂具有较强的抗冲击能力,能够更好的适用于实际应用中。
采用XRD、SEM、EDX、XPS对所制备的催化剂进行了表征。结果表明,添加了铈后的CuO-CeO_2/Al_2O_3催化剂表面氧化物颗粒的粒径有所减小,分散也更为均匀。在CuO/Al_2O_3催化剂中添加适量的CeO_2可促进催化剂表面Cu+含量的增加,从而有利于甲苯、二甲苯催化氧化活性的提高。
为实现用NH3对NOx的选择性催化还原,研究了一种V_2O_5/TiO_2/Al_2O_3/Al金属丝网蜂窝催化剂。以铝丝网为载体,先对其进行阳极氧化,使其表面变得多孔易于吸附,然后用溶胶凝胶方法负载TiO_2,最后采用浸渍法负载V_2O_5;制成V_2O_5/TiO_2/Al_2O_3/Al筛网蜂窝型催化剂。这种催化剂具有高开孔结构,较高的传质系数和适中的压力降。而且金属筛网良好的延展性,使其具有可变性,适合于各种形状反应器的安装。此外,该催化剂具有机械强度高、抗震性能好、成本低等优点。与此同时,采用60～80目的氧化铝小球为载体,用同样的方法负载同样的组分,制成V_2O_5/TiO_2/Al_2O_3催化剂,用于与筛网蜂窝催化剂做比较。
对两种催化剂进行活性考察,结果表明两种催化剂具有较宽的活性温度范围,在200～400℃下得到较好的处理效果,其中筛网蜂窝催化剂的最高NO转化率为86%,粉末催化剂为93.8%;两种催化剂均能在较大的空速范围内有较好的处理效果;对于两者来说提高氨氮比和进料气浓度都可以提高NO的转化率。采用XRD、SEM、EDX、XPS对制备的催化剂进行了表征。结果表明,在TiO_2煅烧的过程中发生了烧结,铝网上的氧化铝与二氧化钛粘结在一起,在筛网蜂窝催化剂上较好地负载了TiO_2;少量的V_2O_5负载到载体上,在载体上并未发现V_2O_5晶型。对两种催化剂进行了反应动力学的初步研究。研究结果认为V_2O_5/TiO_2催化剂进行选择性催化还原NO是按Eley-Rideal机理进行的,为一级反应。筛网蜂窝催化剂在低温下反应主要受化学动力学的控制,高温下反应受传质控制。
为探索组合电化学催化和光催化氧化过程降解反应性黑5的可行性,在三种不同的金属丝网电极上研究了染料反应性黑5的电化学催化氧化和光助电化学催化氧化。它们是H_2气氛中,800℃烧结10小时涂钛的金属丝网电极; H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极和纯钛金属丝网电极。试验结果表明以HCl为支持电解质和添加剂,对染料反应性黑5处理20分钟的脱色率:H_2气氛中,800℃烧结10小时涂钛的金属丝网电极和H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极上高达85%。在TiO_2/Ti金属丝网电极上利用紫外辐射研究了染料反应性黑5的光助电化学催化氧化。向电化学反应系统引入紫外辐射会提高染料反应性黑5的脱色效果,尤其在H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极上。恰是空气中煅烧形成的TiO_2在紫外辐射下光催化降解了染料反应性黑5。比较单独使用电化学和光催化降解过程可以肯定存在两种过程的协同作用。
In order to decompose volatile organic compounds (VOCs) and solve the problems caused by VOCs to the environment, catalysts for the catalytic oxidation of toluene were prepared by sol-gel and impregnation methods, usingγ-Al_2O_3 or SiO_2 as carriers, V_2O_5, TiO_2 or V_2O_5-TiO_2 as active components. Dynamic catalytic oxidation reaction system was established, from which, the activity of catalysts and reaction conditions were investigated. The results indicated that V_2O_5-TiO_2/SiO_2 illustrates the best ability for the degradation of toluene. The influence of carriers' size, precursor and loading amount on the activity of catalysts was experimented and analyzed. The best size ofγ-Al_2O_3 was 60-80 mesh; the best precursor was ammonium vanadate in an oxalic acid solution; the best loading amount of V_2O_5 was 1wt. %; and the molar ratio of nV/nTi was 0.127 in terms of treatment efficiency and costs.
Three main factors in catalytic oxidation reaction: reacting temperature, space velocity, inlet concentration were investigated. The experimental results indicated that V_2O_5-TiO_2/SiO_2 had low ignition temperature, and efficiency of toluene conversion rose quickly as temperature increases, proving that V_2O_5-TiO_2/SiO_2 possess similar temperature characteristics to noble metal. When space velocity and concentration were changed, efficiency of toluene conversion on V_2O_5-TiO_2/SiO_2 did not change too much. By contrast, efficiency of toluene conversion on V_2O_5-TiO_2/Al_2O_3 descended as space velocity and concentration increased. Compared with V_2O_5-TiO_2/Al_2O_3, V_2O_5-TiO_2/SiO_2 shows better resistance against impact.
The prepared catalysts were characterized on structure and morphology by X-ray diffraction (XRD), Scan Electron Microscope (SEM), energy dispersion X-ray energy spectrum (EDX) and X-ray photoelectron energy spectrum (XPS). According to the result of activity test and characterization, the relationship between catalyst structure and catalytic activity was analyzed. The results showed that vanadium ion was imbedded in the crystal structure of TiO_2, instead of creating V_2O_5 crystal form because of limited V_2O_5 loaded amount. The chemical bonds of V-O-Ti and Ti-O-Si were formed. However, there was only physical combination betweenγ-Al_2O_3 and TiO_2. The result of activity test indicated that these chemical bonds might be the active sites of catalysts which increase the catalytic capability of catalysts and strengthen the binding strength among the components of catalysts.
The CuO-CeO_2/Al_2O_3 catalysts were prepared by impregnation methods, usingγ-Al_2O_3 or SiO_2 as carriers, CuO as active component, and with addition of Ce. Using the catalytic oxidation of toluene and xylene as the model reaction, dynamic catalytic oxidation reaction system was established from which the activity of catalysts and reaction conditions were investigated. In all kinds of catalysts using different carriers, the one usingγ-Al_2O_3 (60～80mesh) as carrier had the best ability on the degradation of toluene. Compared with CuO/Al_2O_3 catalyst, CuO-CeO_2/Al_2O_3 catalyst which was added with Ce had lower initial combustion temperature and complete oxidation. The prepared process was optimized and the results showed that the catalyst with 5 wt.% Cu loading amount, molar ratio of Cu/Ce 1:1 and calcined at 500℃for 6 hours has the highest catalytic activity.
Three main factors such as reacting temperature, space velocity, inlet concentration in the catalytic oxidation reaction were researched for toluene and xylene degradation. In test range, the optimal space velocity of toluene on CuO-CeO_2/Al_2O_3 was 8000h-1, and 6000h-1 for CuO/Al_2O_3. The results of influencing factors experiment on catalytic capability of xylene were similar to that of toluene, and the optimal space velocity of xylene on CuO-CeO_2/Al_2O_3 and CuO/Al_2O_3 was 8000h-1. Compared with the catalytic oxidation of toluene, the xylene removal efficiency on CuO/Al_2O_3 was preferable, and it was over 90% in different space velocity and inlet concentration. The removal purpose of xylene could be achieved but it was not preferable compared to CuO-CeO_2/Al_2O_3. CuO-CeO_2/Al_2O_3 has better resistance against impact and can be better applied in the practice.
The prepared catalysts were characterized by XRD, SEM, EDX and XPS. The results indicated that surface particle diameter of CuO-CeO_2/Al_2O_3 catalyst became smaller when Ce added, and the dispersion was well proportioned. The presence of CeO_2 increased the Cu+ content on the surface of CuO/Al_2O_3 catalysts. So the activity of catalysts for toluene and xylene catalytic oxidation could be improved.
To realize the selective catalytic reduction (SCR) of NOx with NH3, a new type of V_2O_5/TiO_2/Al_2O_3/Al wire-mesh honeycomb (WMH) catalyst was developed. The wire-mesh honeycomb made of aluminum was first oxidized as anode electrochemically to form porous layer, and then TiO_2 was adsorbed by sol-gel method, and V_2O_5/TiO_2 catalyst powder was wash-coated onto the wire surface of the honeycomb. V_2O_5/TiO_2/Al_2O_3/Al/WMH catalyst was applied for SCR of NOx with NH3. The catalyst shown high mass transfer coefficient and moderate pressure drop because of its porous structure. Wire-mesh has high extendibility and flexibility, and is suitable to reactors with different structures.
The selective catalytic reduction activity of two types of catalysts, V_2O_5/TiO_2/Al_2O_3/Al WMH catalyst and powder catalyst, were investigated, and the results showed that they had wide active temperature range and high treatment efficiency within the temperature range of 200~400℃, the highest conversion of NO over V_2O_5/TiO_2/Al_2O_3/Al WMH catalyst being up to 86% and over powder catalyst 93.8%. They could both get high treatment efficiency in a wide range of space velocity. Increasing molar ratio nNH3/nNO and concentration of influent gas could enhance NO conversion for both of them. And the treatment effectiveness over powder catalyst was better than that over WMH catalyst, but bed pressure drop of powder catalyst was severely high which would limit its application. The manufactured catalysts were characterized by XRD, SEM, EDX and XPS and the results showed that TiO_2 was well combined with Al_2O_3 and V_2O_5 was fully dispersed. Reaction kinetics of two types of catalysts was primarily studied, and the results indicated that SCR of NOx with NH3 over V_2O_5/TiO_2 catalyst accorded with Eley-Rideal mechanism and belonged to first order reaction. Reaction over WMH catalyst was mainly controlled by chemical kinetics at low temperature and was affected by mass transfer characteristics at high temperature. For powder catalyst with 60~80 meshes, the reaction was controlled by reaction kinetics and not by mass transfer.
To investigate the feasibility to combine the electrochemically catalytic oxidation process and photo catalytic process to decompose Reactive Black 5, the efficiency of the electrochemically catalytic oxidation process and photo-electric catalytic process for the degradation of Reactive Black 5 were studied on three different wire-mesh electrodes. They are Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2; TiO_2/Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2 and calcined at 600℃for 3 hours with air and fresh titanium wire-mesh electrode. The experiment result shown that with HCl as supporting electrolyte and additive, the coloring removing efficiency of Reactive Black 5 reach as high as 85% less than 20 minutes at Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2 and at TiO_2/Ti coated wire-mesh electrode sintered at 800℃with H_2 for 10 hours and calcined at 600℃for 3 hours with air. Electrochemically promoted photo catalytic degradation of Reactive Black 5 was studied with UV irradiation on TiO_2/Ti wire-mesh electrodes. It is found that the introduction of UV irradiation to the electrochemical system would enhance the color removing efficiency for Reactive Black5 degradation especially on TiO_2/Ti coated wire-mesh sintered at 800℃for 10 hours with H_2 and calcined at 600℃for 3 hours with air. It is the TiO_2 formed after calcined at 600℃for 3 hours with air that photo-catalyzed the degradation decomposition of Reactive Black 5 with UV irradiation. Compared with decolourization efficiency obtained by individual application of electrochemical and photo catalytic oxidation procedures, a significant synergic function from these two processes could be concluded.
通过对不同载体不同活性组分催化剂的活性测试,可以得出V_2O_5-TiO_2/SiO_2对甲苯的降解能力最强。同时,对载体粒径、不同前驱物及催化剂负载量与催化剂性能的关系进行了测试和分析,得出γ-Al_2O_3最佳载体粒径为60～80目;采用偏钒酸铵的乙二酸溶液作为前驱物制备的催化剂效果最好;V_2O_5的最佳负载量为1wt.%,V/Ti比值为0.127。
对催化反应中的三个主要因素:反应温度、进气流量、进气浓度进行了研究。实验结果表明V_2O_5-TiO_2/SiO_2催化剂具有较低的起燃温度,而且它对甲苯的去除率随温度的升高迅速上升,和贵金属的催化特性相似;进气流量及浓度的增加,并没有使V_2O_5-TiO_2/SiO_2催化剂对甲苯的去除效果发生太大的变化;相反却导致V_2O_5-TiO_2/Al_2O_3催化剂对甲苯去除率的降低。与V_2O_5-TiO_2/Al_2O_3相比,V_2O_5-TiO_2/SiO_2具有较强的抗冲击能力。
采用XRD、SEM、EDX、XPS对制备的催化剂的体相结构和表面特性进行了表征。结合表征和活性测试的结果,分析了催化剂结构与催化性能之间的关系。结果发现较少的V_2O_5负载量使得V离子嵌入了TiO_2的晶体结构中,而不是形成晶形V_2O_5,并形成了V-O-Ti键;TiO_2与SiO_2发生了化学反应,有Ti-O-Si键形成,而对于Al_2O_3载体来说,TiO_2和它之间只是简单的物理结合。由活性测试的结果可看出,这些化学键有可能是催化剂的活性位,它们的生成有利于提高催化剂的催化性能,有利于增加催化剂各组分间的结合力,增强催化剂的强度。
分别以γ-Al_2O_3、SiO_2为载体,CuO为活性组分,添加Ce,用浸渍法制备了负载型催化剂。同时,以甲苯的催化氧化为模型反应,建立了动态催化氧化反应体系。利用该反应体系研究了催化剂的催化活性,以及影响催化性能的因素。
在以不同载体制备的各种催化剂中,以60～80目的γ-Al_2O_3作载体的催化剂对甲苯的去除效果最好。相对于CuO/Al_2O_3催化剂,添加Ce后的CuO-CeO_2/Al_2O_3催化剂对甲苯催化氧化的起燃温度和完全转化温度均有明显的降低。研究表明,当以60～80目的γ-Al_2O_3作载体,Cu的负载量为5wt.%,Cu与Ce的比为1:1,催化剂的焙烧温度为500℃,焙烧时间为6小时的CuO-CeO_2/Al_2O_3催化剂的催化活性最高。
针对甲苯和二甲苯催化反应中的三个主要因素(反应温度、空速、进气浓度)进行了研究。在测试范围内,CuO-CeO_2/Al_2O_3对甲苯的最佳空速为8000h-1,对CuO/Al_2O_3为6000h-1。以二甲苯为目标物的催化性能影响因素实验所得结果与甲苯的相似,CuO-CeO_2/Al_2O_3和CuO/Al_2O_3的最佳空速均为8000 h-1。和催化氧化甲苯的实验相比,CuO/Al_2O_3催化剂对二甲苯的处理效果相对较好,在不同的空速和进气浓度下去除率都在90%以上,虽然能够达到二甲苯去除要求,但与CuO-CeO_2/Al_2O_3相比仍不能达到最佳的处理效果。CuO-CeO_2/Al_2O_3催化剂具有较强的抗冲击能力,能够更好的适用于实际应用中。
采用XRD、SEM、EDX、XPS对所制备的催化剂进行了表征。结果表明,添加了铈后的CuO-CeO_2/Al_2O_3催化剂表面氧化物颗粒的粒径有所减小,分散也更为均匀。在CuO/Al_2O_3催化剂中添加适量的CeO_2可促进催化剂表面Cu+含量的增加,从而有利于甲苯、二甲苯催化氧化活性的提高。
为实现用NH3对NOx的选择性催化还原,研究了一种V_2O_5/TiO_2/Al_2O_3/Al金属丝网蜂窝催化剂。以铝丝网为载体,先对其进行阳极氧化,使其表面变得多孔易于吸附,然后用溶胶凝胶方法负载TiO_2,最后采用浸渍法负载V_2O_5;制成V_2O_5/TiO_2/Al_2O_3/Al筛网蜂窝型催化剂。这种催化剂具有高开孔结构,较高的传质系数和适中的压力降。而且金属筛网良好的延展性,使其具有可变性,适合于各种形状反应器的安装。此外,该催化剂具有机械强度高、抗震性能好、成本低等优点。与此同时,采用60～80目的氧化铝小球为载体,用同样的方法负载同样的组分,制成V_2O_5/TiO_2/Al_2O_3催化剂,用于与筛网蜂窝催化剂做比较。
对两种催化剂进行活性考察,结果表明两种催化剂具有较宽的活性温度范围,在200～400℃下得到较好的处理效果,其中筛网蜂窝催化剂的最高NO转化率为86%,粉末催化剂为93.8%;两种催化剂均能在较大的空速范围内有较好的处理效果;对于两者来说提高氨氮比和进料气浓度都可以提高NO的转化率。采用XRD、SEM、EDX、XPS对制备的催化剂进行了表征。结果表明,在TiO_2煅烧的过程中发生了烧结,铝网上的氧化铝与二氧化钛粘结在一起,在筛网蜂窝催化剂上较好地负载了TiO_2;少量的V_2O_5负载到载体上,在载体上并未发现V_2O_5晶型。对两种催化剂进行了反应动力学的初步研究。研究结果认为V_2O_5/TiO_2催化剂进行选择性催化还原NO是按Eley-Rideal机理进行的,为一级反应。筛网蜂窝催化剂在低温下反应主要受化学动力学的控制,高温下反应受传质控制。
为探索组合电化学催化和光催化氧化过程降解反应性黑5的可行性,在三种不同的金属丝网电极上研究了染料反应性黑5的电化学催化氧化和光助电化学催化氧化。它们是H_2气氛中,800℃烧结10小时涂钛的金属丝网电极; H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极和纯钛金属丝网电极。试验结果表明以HCl为支持电解质和添加剂,对染料反应性黑5处理20分钟的脱色率:H_2气氛中,800℃烧结10小时涂钛的金属丝网电极和H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极上高达85%。在TiO_2/Ti金属丝网电极上利用紫外辐射研究了染料反应性黑5的光助电化学催化氧化。向电化学反应系统引入紫外辐射会提高染料反应性黑5的脱色效果,尤其在H_2气氛中,800℃下烧结10小时然后在空气中600℃煅烧3小时的TiO_2/Ti涂层金属丝网电极上。恰是空气中煅烧形成的TiO_2在紫外辐射下光催化降解了染料反应性黑5。比较单独使用电化学和光催化降解过程可以肯定存在两种过程的协同作用。
In order to decompose volatile organic compounds (VOCs) and solve the problems caused by VOCs to the environment, catalysts for the catalytic oxidation of toluene were prepared by sol-gel and impregnation methods, usingγ-Al_2O_3 or SiO_2 as carriers, V_2O_5, TiO_2 or V_2O_5-TiO_2 as active components. Dynamic catalytic oxidation reaction system was established, from which, the activity of catalysts and reaction conditions were investigated. The results indicated that V_2O_5-TiO_2/SiO_2 illustrates the best ability for the degradation of toluene. The influence of carriers' size, precursor and loading amount on the activity of catalysts was experimented and analyzed. The best size ofγ-Al_2O_3 was 60-80 mesh; the best precursor was ammonium vanadate in an oxalic acid solution; the best loading amount of V_2O_5 was 1wt. %; and the molar ratio of nV/nTi was 0.127 in terms of treatment efficiency and costs.
Three main factors in catalytic oxidation reaction: reacting temperature, space velocity, inlet concentration were investigated. The experimental results indicated that V_2O_5-TiO_2/SiO_2 had low ignition temperature, and efficiency of toluene conversion rose quickly as temperature increases, proving that V_2O_5-TiO_2/SiO_2 possess similar temperature characteristics to noble metal. When space velocity and concentration were changed, efficiency of toluene conversion on V_2O_5-TiO_2/SiO_2 did not change too much. By contrast, efficiency of toluene conversion on V_2O_5-TiO_2/Al_2O_3 descended as space velocity and concentration increased. Compared with V_2O_5-TiO_2/Al_2O_3, V_2O_5-TiO_2/SiO_2 shows better resistance against impact.
The prepared catalysts were characterized on structure and morphology by X-ray diffraction (XRD), Scan Electron Microscope (SEM), energy dispersion X-ray energy spectrum (EDX) and X-ray photoelectron energy spectrum (XPS). According to the result of activity test and characterization, the relationship between catalyst structure and catalytic activity was analyzed. The results showed that vanadium ion was imbedded in the crystal structure of TiO_2, instead of creating V_2O_5 crystal form because of limited V_2O_5 loaded amount. The chemical bonds of V-O-Ti and Ti-O-Si were formed. However, there was only physical combination betweenγ-Al_2O_3 and TiO_2. The result of activity test indicated that these chemical bonds might be the active sites of catalysts which increase the catalytic capability of catalysts and strengthen the binding strength among the components of catalysts.
The CuO-CeO_2/Al_2O_3 catalysts were prepared by impregnation methods, usingγ-Al_2O_3 or SiO_2 as carriers, CuO as active component, and with addition of Ce. Using the catalytic oxidation of toluene and xylene as the model reaction, dynamic catalytic oxidation reaction system was established from which the activity of catalysts and reaction conditions were investigated. In all kinds of catalysts using different carriers, the one usingγ-Al_2O_3 (60～80mesh) as carrier had the best ability on the degradation of toluene. Compared with CuO/Al_2O_3 catalyst, CuO-CeO_2/Al_2O_3 catalyst which was added with Ce had lower initial combustion temperature and complete oxidation. The prepared process was optimized and the results showed that the catalyst with 5 wt.% Cu loading amount, molar ratio of Cu/Ce 1:1 and calcined at 500℃for 6 hours has the highest catalytic activity.
Three main factors such as reacting temperature, space velocity, inlet concentration in the catalytic oxidation reaction were researched for toluene and xylene degradation. In test range, the optimal space velocity of toluene on CuO-CeO_2/Al_2O_3 was 8000h-1, and 6000h-1 for CuO/Al_2O_3. The results of influencing factors experiment on catalytic capability of xylene were similar to that of toluene, and the optimal space velocity of xylene on CuO-CeO_2/Al_2O_3 and CuO/Al_2O_3 was 8000h-1. Compared with the catalytic oxidation of toluene, the xylene removal efficiency on CuO/Al_2O_3 was preferable, and it was over 90% in different space velocity and inlet concentration. The removal purpose of xylene could be achieved but it was not preferable compared to CuO-CeO_2/Al_2O_3. CuO-CeO_2/Al_2O_3 has better resistance against impact and can be better applied in the practice.
The prepared catalysts were characterized by XRD, SEM, EDX and XPS. The results indicated that surface particle diameter of CuO-CeO_2/Al_2O_3 catalyst became smaller when Ce added, and the dispersion was well proportioned. The presence of CeO_2 increased the Cu+ content on the surface of CuO/Al_2O_3 catalysts. So the activity of catalysts for toluene and xylene catalytic oxidation could be improved.
To realize the selective catalytic reduction (SCR) of NOx with NH3, a new type of V_2O_5/TiO_2/Al_2O_3/Al wire-mesh honeycomb (WMH) catalyst was developed. The wire-mesh honeycomb made of aluminum was first oxidized as anode electrochemically to form porous layer, and then TiO_2 was adsorbed by sol-gel method, and V_2O_5/TiO_2 catalyst powder was wash-coated onto the wire surface of the honeycomb. V_2O_5/TiO_2/Al_2O_3/Al/WMH catalyst was applied for SCR of NOx with NH3. The catalyst shown high mass transfer coefficient and moderate pressure drop because of its porous structure. Wire-mesh has high extendibility and flexibility, and is suitable to reactors with different structures.
The selective catalytic reduction activity of two types of catalysts, V_2O_5/TiO_2/Al_2O_3/Al WMH catalyst and powder catalyst, were investigated, and the results showed that they had wide active temperature range and high treatment efficiency within the temperature range of 200~400℃, the highest conversion of NO over V_2O_5/TiO_2/Al_2O_3/Al WMH catalyst being up to 86% and over powder catalyst 93.8%. They could both get high treatment efficiency in a wide range of space velocity. Increasing molar ratio nNH3/nNO and concentration of influent gas could enhance NO conversion for both of them. And the treatment effectiveness over powder catalyst was better than that over WMH catalyst, but bed pressure drop of powder catalyst was severely high which would limit its application. The manufactured catalysts were characterized by XRD, SEM, EDX and XPS and the results showed that TiO_2 was well combined with Al_2O_3 and V_2O_5 was fully dispersed. Reaction kinetics of two types of catalysts was primarily studied, and the results indicated that SCR of NOx with NH3 over V_2O_5/TiO_2 catalyst accorded with Eley-Rideal mechanism and belonged to first order reaction. Reaction over WMH catalyst was mainly controlled by chemical kinetics at low temperature and was affected by mass transfer characteristics at high temperature. For powder catalyst with 60~80 meshes, the reaction was controlled by reaction kinetics and not by mass transfer.
To investigate the feasibility to combine the electrochemically catalytic oxidation process and photo catalytic process to decompose Reactive Black 5, the efficiency of the electrochemically catalytic oxidation process and photo-electric catalytic process for the degradation of Reactive Black 5 were studied on three different wire-mesh electrodes. They are Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2; TiO_2/Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2 and calcined at 600℃for 3 hours with air and fresh titanium wire-mesh electrode. The experiment result shown that with HCl as supporting electrolyte and additive, the coloring removing efficiency of Reactive Black 5 reach as high as 85% less than 20 minutes at Ti coated wire-mesh electrode sintered at 800℃for 10 hours with H_2 and at TiO_2/Ti coated wire-mesh electrode sintered at 800℃with H_2 for 10 hours and calcined at 600℃for 3 hours with air. Electrochemically promoted photo catalytic degradation of Reactive Black 5 was studied with UV irradiation on TiO_2/Ti wire-mesh electrodes. It is found that the introduction of UV irradiation to the electrochemical system would enhance the color removing efficiency for Reactive Black5 degradation especially on TiO_2/Ti coated wire-mesh sintered at 800℃for 10 hours with H_2 and calcined at 600℃for 3 hours with air. It is the TiO_2 formed after calcined at 600℃for 3 hours with air that photo-catalyzed the degradation decomposition of Reactive Black 5 with UV irradiation. Compared with decolourization efficiency obtained by individual application of electrochemical and photo catalytic oxidation procedures, a significant synergic function from these two processes could be concluded.
引文
1 N. De Nevers. Air Pollution Control Engineering. International Editions. McGraw-Hill, 2000,
2 P. Papaefthimiou, T. Ioannides and X. E. Verykios. Catalytic Incineration of Volatile Organic Compounds Present in Industrial Waste Streams. Applied Thermal Engineering. 1998, 18(11): 1005~1012
3 Jo Dewulf, Herman Van Langenhove and Jeroen Dirckx. Energy Analysis in the Assessment of the Sustainability of Waste Gas Treatment Systems. The Science of the Total Environment. 2001, 273(6): 41~52
4 Andrey N. Zagoruiko, Oleg V. Kostenko and Alexander S. Noskov. Development of the Adsorption-Catalytic Reverse-Process for Incineration of Volatile Organic Compounds in Diluted Waste Gases. Chemical Engineering Science. 1996, 51(6): 2989~2994
5 Sumaeth Chavadej, Witan Kiatubolpaiboon and Pramoch Rangsunvigit, et al. A Combined Multistage Corona Discharge and Catalytic System for Gaseous Benzene Removal. Journal of Molecular Catalysis A: Chemical. 2007, 263(2): 128~136
6 A. O’Malley and B. K. Hodnett. The Influence of Volatile Organic Compound Structure on Conditions Required for Total Oxidation. Catalysis Today. 1999, 54(11): 31~38
7 K.P. Francke, H. Miessner and R. Rudolph. Plasmacatalytic Processes for Environmental Problems. Catalysis Today.2000, 59(6): 411~416
8 Jim Van Durme, Jo Dewulf and Christophe Leys, et al. Combining Non-thermal Plasma with Heterogeneous Catalysis in Waste Gas Treatment: A Review, Applied Catalysis B: Environmental. 2008, 78(2): 324~333
9 Monica Magureanu, Nicolae Bogdan Mandache and Juncheng Hu, et al. Parvulescu, Plasma-Assisted Catalysis Total Oxidation of Trichloroethylene over Gold Nano-particles Embedded in SBA-15 Catalysts. Applied Catalysis B: Environmental. 2007, 76(11): 275~281
10 Ch. Subrahmanyam, M. Magureanu and A. Renken L, et al. Catalytic Abatement of Volatile Organic Compounds Assisted by Non-thermal Plasma:Part 1. A Novel Dielectric Barrier Discharge Reactor Containing Catalytic Electrode, Applied Catalysis B: Environmental. 2006, 65(5): 150~156
11 Ch. Subrahmanyam, A. Renken and L. Kiwi-Minsker. Catalytic Abatement of Volatile Organic Compounds Assisted by Non-thermal Plasma: Part II. Optimized Catalytic Electrode and Operating Conditions. Applied Catalysis B: Environmental. 2006, 65(5): 157~162
12 Ch. Subrahmanyam, A. Renken and L. Kiwi-Minsker. Novel Catalytic Non-thermal Plasma Reactor for the Abatement of VOCs. Chemical Engineering Journal. 2007, 134(11): 78~83
13 M. Magureanu, N.B. Mandache and V.I. Parvulescu, et al. Improved Performance of Non-thermal Plasma Reactor during Decomposition of Trichloroethylene: Optimization of the Reactor Geometry and Introduction of Catalytic Electrode. Applied Catalysis B: Environmental. 2007, 74(7): 270~277
14 Monica Magureanu, Nicolae B. Mandache and Pierre Eloy, et al. Parvulescu, Plasma-Assisted Catalysis for Volatile Organic Compounds Abatement. Applied Catalysis B: Environmental. 2005, 61(10): 12~20
15 J. Van Durme, J. Dewulf and W. Sysmans, et al. Efficient Toluene Abatement in Indoor Air by a Plasma Catalytic Hybrid System. Applied Catalysis B: Environmental. 2007, 74(6): 161~169
16 U. Roland, F. Holzer and F.-D. Kopinke. Combination of Non-thermal Plasma and Heterogeneous Catalysis for Oxidation of Volatile Organic Compounds: Part 2. Ozone Decomposition and Deactivation ofγ-Al2O3. Applied Catalysis B: Environmental. 2005, 58(6): 217~226
17张林,陈欢林,柴红.挥发性有机物废气的膜法处理工艺研究进展.化工环保. 2002, 22(2):75~80
18徐志康,刘振梅,戴清文.基于溶解的扩散机理的聚合物膜分离烯烃/烷烃的研究进展.石油化工. 2002, 31(2):135~140
19 L. Guczi, L. Borkóand Z. Schay. Some Problems on Environmental Catalysis. Studies in Surface Science and Catalysis. 1998, 113: 69~80
20 J. Tsou, P. Magnoux and M. Guisnet, et al. Figueiredo Oscillations in the Catalytic Oxidation of Volatile Organic Compounds. Journal of Catalysis. 2004, 225(7): 147~154
21 K. Everaert and J. Baeyens. Catalytic Combustion of Volatile Organic Compounds. Journal of Hazardous Materials. 2004, 109(6): 113~139
22 E. Noordally, J. R. Richmond and S. F. Tahir. P. Papaefthimiou, et al. Destruction of Volatile Organic Compounds by Catalytic Oxidation, Catalysis Today, 1993, 17(5): 359~366
23 C. Libanati, D.A. Ullenius and C.J. Pereira. Silica Deactivation of Bead VOC Catalysts. Applied Catalysis B: Environmental.1998, 15(1): 21~28
24 Antonella Gervasini, Carlo Pirola and Vittorio Ragaini. Destruction of Carbon Tetrachloride in the Presence of Hydrogen-Supplying Compounds with Ionisation and Catalytic Oxidation. Applied Catalysis B: Environmental. 2002, 38(7): 17~28
25 S.K. Agarwal, J.J. Spivey and J.B. Butt. Catalyst Deactivation during Deep Oxidation of Chlorohydrocarbons. Applied Catalysis A: General. 1992, 82(3): 259~275
26 Anna Musialik-Piotrowska and Bo ena Mendyka. Catalytic Oxidation of Chlorinated Hydrocarbons in Two-component Mixtures with Selected VOCs. Catalysis Today. 2004, 90(6): 139-144
27 H. Windawi and Z. C. Zhang. Catalytic Destruction of Halogenated Air Toxins and the Effect of Admixture with VOCs. Catalysis Today. 1996, 30(6): 99~105
28杨显万,孙佩石,黄若华.生物法净化低浓度挥发性有机废气的研究.中国工程科学, 2001, 3(9):64~68
29李国文,胡洪营,郝吉明,等.生物过滤塔甲苯降解性能研究.环境科学, 2001, 22(2):31~35
30陈建孟,王家德,庄利,等.生物滴滤池净化二氯甲烷废气的实验研究.环境科学, 2002, 23(4):8~12
31 G. Sinquin, C. Petit and S. Libs, et al. Catalytic Destruction of Chlorinated C1 Volatile Organic Compounds (CVOCs) Reactivity, Oxidation and Hydrolysis Mechanisms. Applied Catalysis B: Environmental. 2000, 27(7): 105~115
32黄正宏,康飞宇,吴慧,等.湿氧化改性多孔炭对低浓度苯和丁酮蒸汽的吸附.清华大学学报(自然科学版). 2000, 40(10):111~115
33 John R. Hart. Emissions of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from Catalytic and Thermal Oxidizers Burning Dilute Chlorinated Vapors. Chemosphere. 2004, 54(3): 1539~1547
34 S.K. Gangwal, M.E. Mullins and J.J. Spivey, et al. Kinetics and Selectivity of Deep Catalytic Oxidation of n-Hexane and Benzene. Applied Catalysis. 1988, 36: 231~247
35 M. Guillemot, J. Mijoin and P. Magnoux, et al. Volatile Organic Compounds (VOCs) Removal over Dual Functional Adsorbent/Catalyst System. Applied Catalysis B: Environmental. 2007, 75(9): 249~255
36 Anna Musialik-Piotrowska and Krystyna Syczewska. Catalytic Oxidation of Trichloroethylene in Two-component Mixtures with Selected Volatile Organic Compounds. Catalysis Today. 2002, 73(4): 333~342
37 Alan Janbey, Wayne Clark and Ehsan Noordally, et al. Noble Metal Catalysts for Methane Removal. Chemosphere. 2003, 52(8): 1041~1046
38 Ting-Ke Tseng, Hsin Chu and Tzu-Hsing Ko, et al. The Kinetic of the Catalytic Decomposition of Methyl Isobutyl Ketone over a Pt/γ-Al2O3 Catalyst Chemosphere. 2005, 61(10): 469~477
39 Ting-Ke Tseng, Hsin Chu and Tzu-Hsing Ko, et al. The Operating Performance and Products Distribution of the Catalytic Oxidation of Methyl-Isobutyl-Ketone over a Pt/γ-Al2O3 Catalyst. Journal of Hazardous Materials. 2005, 122(6): 155~160
40 Rubén López-Fonseca, Jose I. Gutiérrez-Ortiz and Miguel A. Gutiérrez-Ortiz, et al. Catalytic Oxidation of Aliphatic Chlorinated Volatile Organic Compounds over Pt/H-BETA Zeolite Catalyst under Dry and Humid Conditions. Catalysis Today. 2005, 107-108(10): 200~207
41 George Avgouropoulos, Evaggelos Oikonomopoulos and Dimitrios Kanistras, et al. Complete Oxidation of Ethanol over Alkali-Promoted Pt/Al2O3 Catalysts. Applied Catalysis B: Environmental. 2006, 65(5): 62~69
42 M. Guisnet, P. Dégéand P. Magnoux. Catalytic Oxidation of Volatile Organic Compounds 1. Oxidation of Xylene over a 0.2 wt% Pd/HFAU (17) Catalyst. Applied Catalysis B: Environmental. 1999, 20(1): 1~13
43 Panagiotis Papaefthimiou, Theophilos Ioannides and Xenophon E. Verykios. Performance of Doped Pt/TiO2 (W6+) Catalysts for Combustion of Volatile Organic Compounds (VOCs). Applied Catalysis B: Environmental. 1998, 15(1): 75~92
44 Philippe Dégé, Ludovic Pinard and Patrick Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds (VOCs), Oxidation of O-xylene over Pd and Pt/HFAU Catalysts. Comptes Rendus de l’Académie des Sciences - Series IIC– Chemistry. 2001, (1): 41~47
45 Ph. Dégé, L. Pinard and P. Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds: II. Influence of the Physicochemical Characteristics of Pd/HFAU Catalysts on the Oxidation of o-xylene. Applied Catalysis B: Environmental. 2000, 27(6): 17-26
46 Lifeng Wang, Makoto Sakurai and Hideo Kameyama. Catalytic Oxidation of Dichloromethane and Toluene over Platinum Alumite Catalyst. Journal of Hazardous Materials. 2007, (10)
47 A.V. Kucherov, I.M. Sinev and S. Ojala, et al. Adsorptive-Catalytic Removal of CH3OH, CH3SH, and CH3SSCH3 from Air over the Bifunctional System Noble Metals/HZSM-5. Studies in Surface Science and Catalysis. 2007, 170: 1129~1136
48 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Characterization of New Pd/hierarchical Macro-mesoporous ZrO2, TiO2, and ZrO2-TiO2 Catalysts for Toluene Total Oxidation. Studies in Surface Science and Catalysis. 2007, 160: 201~208
49 Jeffrey Chi-Sheng Wu, Zhi-An Lin and Feng-Ming, et al. Low-temperature Complete Oxidation of BTX on Pt/activated Carbon Catalysts. Catalysis Today. 2000, 63(12): 419~426
50 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Characterization of Palladium Supported on Exchanged BEA and FAU Zeolites for VOCs Catalytic Oxidation. Studies in Surface Science and Catalysis. 2007, 160: 209~216
51 Salvatore Scirè, Simona Minicòand Carmelo Crisafulli. Pt Catalysts Supported on H-type Zeolites for the Catalytic Combustion of Chlorobenzene. Applied Catalysis B: Environmental. 2003, 45(9): 117~125
52 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Influence of the Exchanged Cation in Pd/BEA and Pd/FAU Zeolites for Catalytic Oxidation of VOCs. Applied Catalysis B: Environmental. 2007, 70(1): 377~383
53 Jeffrey C. S. Wu, Zhi-An Lin and Jen-Wei Pan, et al. A Novel Boron Nitride Supported Pt Catalyst for VOC Incineration. Applied Catalysis A: General. 2001, 219(10): 117~124
54 J. Tsou, L. Pinard and P. Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds (VOCs): Oxidation of O-xylene over Pt/HBEA Catalysts. Applied Catalysis B: Environmental. 2003, 46(11): 371~379
55 Taizo Sano, Nobuaki Negishi and Koji Takeuchi, et al. Degradation of Toluene and Acetaldehyde with Pt-loaded TiO2 Catalyst and Parabolic Trough Concentrator. Solar Energy. 2004, 77(11): 543~552
56 M. Hosseini, S. Siffert and H.L. Tidahy, et al. Promotional Effect of Gold Added to Palladium Supported on a New Mesoporous TiO2 for Total Oxidation of Volatile Organic Compounds. Catalysis Today. 2007, 122(4): 391~396
57 Simona Minicò, Salvatore Scirèand Carmelo Crisafulli, et al. Catalytic Combustion of Volatile Organic Compounds on Gold/Iron Oxide Catalysts. Applied Catalysis B: Environmental. 2000, 28(12): 245~251
58 Salvatore Scirè, Simona Minicòand Carmelo Crisafulli, et al. Catalytic Combustion of Volatile Organic Compounds on Gold/Cerium Oxide Catalysts. Applied Catalysis B: Environmental. 2003, 40(1): 43~49
59 M. A. Centeno, M. Paulis and M. Montes, et al. Catalytic Combustion of Volatile Organic Compounds on Au/CeO2/Al2O3 and Au/Al2O3 Catalysts. Applied Catalysis A: General. 2002, 234(8): 65~78
60 Simona Minicò, Salvatore Scirèand Carmelo Crisafulli, et al. Influence of Catalyst Pretreatments on Volatile Organic Compounds Oxidation over Gold/Iron Oxide. Applied Catalysis B: Environmental. 2001, 34(11): 277~285
61 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. New Pd/hierarchical Macro-mesoporous ZrO2, TiO2 and ZrO2-TiO2 Catalysts for VOCs Total Oxidation. Applied Catalysis A: General. 2006, 310(8): 61-69
62 Sophie Giraud, Guillaume Loupias and Hicham Maskrot, et al. Dip-coating on TiO2 Foams Using a Suspension of Pt–TiO2 Nanopowder Synthesized by Laser Pyrolysis—Preliminary Evaluation of the Catalytic Performances of the Resulting Composites in deVOC Reactions. Journal of the European Ceramic Society. 2007, 27: 931~936
63 J. R. González-Velasco, A. Aranzabal and J. I. Gutiérrez-Ortiz, et al. Activity and Product Distribution of Alumina Supported Platinum and Palladium Catalysts in the Gas-Phase Oxidative Decomposition of Chlorinated Hydrocarbons. Applied Catalysis B: Environmental. 1998, 19(12): 189~197
64 Anna Musialik-Piotrowska. Destruction of Trichloroethylene (TCE) and Trichloromethane (TCM) in the Presence of Selected VOCs over Pt-Pd-based Catalyst. Catalysis Today. 2007, 119(1): 301-304
65 Ruud W. van den Brink, Robert Louw and Peter Mulder. Formation of Polychlorinated Benzenes during the Catalytic Combustion of Chlorobenzene Using a Pt/γ-Al2O3 Catalyst. Applied Catalysis B: Environmental. 1998, 16(5): 219~226
66 Mingqian Zhang, Bing Zhou and Karl T. Chuang. Catalytic Deep Oxidation of Volatile Organic Compounds over Fluorinated Carbon Supported Platinum Catalysts at Low Temperatures. Applied Catalysis B: Environmental. 1997, 13(10): 123~130
67 J. Tsou, P. Magnoux and M. Guisnet, et al. Catalytic Oxidation of Volatile Organic Compounds: Oxidation of Methyl-Isobutyl-Ketone over Pt/zeolite catalysts. Applied Catalysis B: Environmental. 2005, 57(4): 117~123
68 Tomas Garcia, Benjamin Solsona and Diego Cazorla-Amorós, et al. Total Oxidation of Volatile Organic Compounds by Vanadium Promoted Palladium-Titania Catalysts: Comparison of Aromatic and Polyaromatic Compounds. Applied Catalysis B: Environmental. 2006, 62(1): 66~76
69 Shih Yin Liu and Sze Ming Yang. Complete Oxidation of 2-propanol over Gold-based Catalysts Supported on Metal Oxides. Applied Catalysis A: General. 2008, 334(1): 92~99
70 Panagiotis Papaefthimiou, Theophilos Ioannides and Xenophon E. Verykios. Combustion of Non-halogenated Volatile Organic Compounds over Group VIII Metal Catalysts. Applied Catalysis B: Environmental. 1997, 13(11) 175~184
71 Serge Vigneron, Pascal Deprelle and Jacques Hermia. Comparison of Precious Metals and Base Metal Oxides for Catalytic Deep Oxidation of Volatile Organic Compounds from Coating Plants: Test Results on an Industrial Pilot Scale Incinerator, Catalysis Today. 1996, 27(11): 229~236
72 Marco Baldi, Elisabetta Finocchio and Fabio Milella, et al. Catalytic Combustion of C3 Hydrocarbons and Oxygenates over Mn3O4. Applied Catalysis B: Environmental. 1998, 16(3): 43~51
73 Luciano Lamaita, M. Andrés Peluso and Jorge E. Sambeth, et al. A Theoretical and Experimental Study of Manganese Oxides Used as Catalysts for VOCs Emission Reduction. Catalysis Today. 2005, 107-108(10): 133~138
74 Vivekanand Gaur, Ashutosh Sharma and Nishith Verma. Catalytic Oxidation of Toluene and M-xylene by Activated Carbon Fiber Impregnated with Transition Metals. Carbon. 2005, 43(12): 3041~3053
75 Chi-Yuan Lu and Ming-Yen Wey. Simultaneous Removal of VOC and NO by Activated Carbon Impregnated with Transition Metal Catalysts in Combustion Flue Gas. Fuel Processing Technology. 2007, 88(6): 557~567
76 Chi-Yuan Lu, Ming-Yen Wey and Li-Ing Chen. Application of Polyol Process to Prepare AC-supported Nanocatalyst for VOC Oxidation. Applied Catalysis A: General. 2007, 325(5): 163~174
77 Catherine S. Heneghan, Graham J. Hutchings and Shane R. O’Leary, et al. A Temporal Analysis of Products Study of the Mechanism of VOC Catalytic Oxidation Using Uranium Oxide Catalysts. Catalysis Today. 1999 54(11): 3~12
78 Stuart H. Taylor, Catherine S. Heneghan and Graham J. Hutchings, et al. The Activity and Mechanism of Uranium Oxide Catalysts for the Oxidative Destruction of Volatile Organic Compounds. Catalysis Today. 2000, 59(6): 249~259
79 Sang Chai Kim and Wang Geun Shim. Recycling the Oopper Based Spent Catalyst for Catalytic Combustion of VOCs. Applied Catalysis B: Environmental, 2008, 2(79): 149-156
80 M. Stoyanova, P. Konova and P. Nikolov, et al. Alumina-Supported Nickel Oxide for Ozone Decomposition and Catalytic Ozonation of CO and VOCs. Chemical Engineering Journal. 2006, 122(12): 41~46
81 I.Z. Ismagilov, R.P. Ekatpure and L.T. Tsykoza, et al. Optimization of Anodic Oxidation and Cu–Cr Oxide Catalyst Preparation on Structured Aluminum Plates Processed by Electro Discharge Machining. Catalysis Today. 2005, 105(8): 516~528
82 A. Rougier, S. Soiron and I. Haihal, et al. Influence of Grinding on the Catalytic Properties of Oxides. Powder Technology. 2002, 128(12): 139~147
83 D.P. Das and K.M. Parida. Mn(III) Oxide Pillared Titanium Phosphate (TiP) for Catalytic Deep Oxidation of VOCs. Applied Catalysis A: General. 2007, 324(5): 1~8
84 D.P. Das and K.M. Parida. Fe(III) Oxide Pillared Titanium Phosphate (TiP): An Effective Catalyst for Deep Oxidation of VOCs. Journal of Molecular Catalysis A: Chemical. 2007, 276(10): 17~23
85 F. Bertinchamps, C. Grégoire and E.M. Gaigneaux. Systematic Investigation of Supported Transition Metal Oxide Based Formulations for the Catalytic Oxidative Elimination of (chloro)-Aromatics: Part II: Influence of the Natureand Addition Protocol of Secondary Phases to VOx/TiO2. Applied Catalysis B: Environmental. 2006, 66(6): 10~22
86 M. C. M. Alvim Ferraz, S. M?ser and M. Tonh?euser. Control of Atmospheric Emissions of Volatile Organic Compounds Using Impregnated Activated carbons. Fuel. 1999, 78(10): 1567~1573
87 R. Beauchet, P. Magnoux and J. Mijoin. Catalytic Oxidation of Volatile Organic Compounds (VOCs) Mixture (Isopropanol/o-Xylene) on Zeolite Catalysts. Catalysis Today. 2007, 124(6): 118~123
88 R. López-Fonseca, A. Aranzabal and P. Steltenpohl, et al. Performance of Zeolites and Product Selectivity in the Gas-phase Oxidation of 1,2-dichloroethane. Catalysis Today, 2000, 62(12): 367~377
89 Teresa S. C. Law, Christopher Chao and George Y. W. Chan, et al. Confined Catalytic Oxidation of Volatile Organic Compounds by Transition Metal Containing Zeolites and Ionizer. Atmospheric Environment. 2003, 37(12): 5433~5437
90 R. López-Fonseca, A. Aranzabal and J. I. Gutiérrez-Ortiz, et al. Comparative Study of the Oxidative Decomposition of Trichloroethylene over H-type Zeolites under Dry and Humid Conditions. Applied Catalysis B: Environmental. 2001, 30(3): 303~313
91 J. R. González-Velasco, R. López-Fonseca and A. Aranzabal, et al. Evaluation of H-type Zeolites in the Destructive Oxidation of Chlorinated Volatile Organic Compounds. Applied Catalysis B: Environmental. 2000, 24(2): 233~242
92 R. López-Fonseca, J. I. Gutiérrez-Ortiz and M. A. Gutiérrez-Ortiz, et al. Dealuminated Y Zeolites for Destruction of Chlorinated Volatile Organic Compounds. Journal of Catalysis. 2002, 209(7): 145~150
93 A.P. Antunes, J.M. Silva and M.F. Ribeiro, et al. 30-P-23-Total Oxidation of Volatile Organic Compounds-Catalytic Oxidation of Toluene over CuY Zeolites. Studies in Surface Science and Catalysis. 2001, 135: 325
94 A. P. Antunes, M. F. Ribeiro and J. M. Silva, et al. Catalytic Oxidation of Toluene over CuNaHY Zeolites: Coke Formation and Removal. Applied Catalysis B: Environmental. 2001, 33(9): 149~164
95 R. López-Fonseca, J. I. Gutiérrez-Ortiz and J. R. González-Velasco. Catalytic Combustion of Chlorinated Hydrocarbons over H-BETA and PdO/H-BETA Zeolite Catalysts. Applied Catalysis A: General, 2004, 271(9): 39~46
96 Jian Luo, Qiuhua Zhang and Aimin Huang, et al. Total Oxidation of Volatile Organic Compounds with Hydrophobic Cryptomelane-type Octahedral Molecular Sieves. Microporous and Mesoporous Materials. 2000, 35-36(4): 209~217
97 Haifeng Huang, Yaqin Liu and Wei Tang, et al. Catalytic Activity of Nanometer La1?xSrxCoO3 (x = 0, 0.2) Perovskites towards VOCs Combustion, Catalysis Communications. 2008, 9(1): 55~59
98 G. Sinquin, C. Petit and J. P. Hindermann, et al. Study of the Formation of LaMO3 (M=Co, Mn) Perovskites by Propionates Precursors: Application to the Catalytic Destruction of Chlorinated VOCs. Catalysis Today. 2001, 70(10): 183~196
99 Jianrong Niu, Jiguang Deng and Wei Liu, et al. Nanosized Perovskite-type Oxides La1?xSrxMO3?δ(M = Co, Mn; x = 0, 0.4) for the Catalytic Removal of Ethyl acetate. Catalysis Today. 2007, 126(8): 420~429 100 V. Blasin-Aubé, J. Belkouch and L. Monceaux. General Study of Catalytic Oxidation of Various VOCs over La0.8Sr0.2MnO3+x Perovskite Catalyst—Influence of Mixture. Applied Catalysis B: Environmental. 2003, 43(6):
175~186
101 Bibiana P. Barbero, Julio Andrade Gamboa and Luis E. Cadús. Synthesis and Characterization of La1?xCaxFeO3 Perovskite-type Oxide Catalysts for Total Oxidation of Volatile Organic Compounds. Applied Catalysis B: Environmental. 2006, 65(5): 21~30
102 R. Spinicci, M. Faticanti and P. Marini, et al. Catalytic Activity of LaMnO3 and LaCoO3 Perovskites towards VOCs Combustion. Journal of Molecular Catalysis A: Chemical. 2003, 197(4): 147~155
103 G. Sinquin, J. P. Hindermann and C. Petit, et al. Perovskites as Polyvalent Catalysts for Total Destruction of C1, C2 and Aromatic Chlorinated Volatile Organic Compounds. Catalysis Today. 1999, 54(11): 107~118
104 J. Haber, K. Bahranowski and J. Janas, et al. Hydrotalcite-Derived Catalysts for Removal of Nitrogen-Containing Volatile Organic Compounds. Studies in Surface Science and Catalysis. 2000, 130: 599~604
105 Hongyi Dong, Shijin Shuai and Rulong Li, et al. Study of NOx Selective Catalytic Reduction by Ethanol over Ag/Al2O3 Catalyst on a HD Diesel Engine. Chemical Engineering Journal. 2008, 135(2): 195~201
106 Gian Luca Chiarello, Davide Ferri and Jan-Dierk Grunwaldt, et al. Flame-synthesized LaCoO3-Supported Pd: 2. Catalytic Behavior in the Reduction of NO by H2 under Lean Conditions. Journal of Catalysis. 2007, 252(12): 137~147
107 JoséR. Hernández Carucci, Kalle Arve and Kari Er?nen, et al. Microreactors for Environmental Catalysis—Selective Catalytic Reduction of NOX with Hydrocarbons over a Ag/alumina Catalyst. Catalysis Today. 2007,(12)
108 Robert D. Clayton, Michael P. Harold and Vemuri Balakotaiah. Selective Catalytic Reduction of NO by H2 in O2 on Pt/BaO/Al2O3 Monolith NOx Storage Catalysts. Applied Catalysis B: Environmental. 2007, (12)
109 A. Abu-Jrai, A. Tsolakis and A. Megaritis. The Influence of H2 and CO on Diesel Engine Combustion Characteristics, Exhaust Gas Emissions, and after Treatment Selective Catalytic NOx Reduction, International Journal of Hydrogen Energy. 2007, 32(10): 3565~3571
110 Cristian Ciardelli, Isabella Nova and Enrico Tronconi, et al. NH3 SCR of NOx for Diesel Exhausts After Treatment: Role of NO2 in Catalytic Mechanism, Unsteady Kinetics and Monolith Converter Modeling. Chemical Engineering Science. 2007, 62(9): 5001~5006
111 J.-I. Park, J.-S. Yun and K.-E. Jeong, et al. Platinum Catalysts Supported on Macrostructured MCM-41 for the Selective Catalytic Reduction of Lean NOx with Hydrocarbons. Studies in Surface Science and Catalysis. 2007, 170: 1362~1367
112 Kwang-Eun Jeong, Joo-Il Park and Son-Ki Ihm. Platinum Catalysts Supported on SBA-15 for the Selective Catalytic Reduction of Lean NOx with Propylene. Studies in Surface Science and Catalysis. 2007, 165: 733~736
113 Ulrich G. Alkemade and Bernd Schumann. Engines and Exhaust after Treatment Systems for Future Automotive Applications. Solid State Ionics. 2006, 177(10): 2291-2296
114 Min Kang, Dae Jung Kim and Eun Duck Park, et al. Eyring, Two-Stage Catalyst System for Selective Catalytic Reduction of NOx by NH3 at Low Temperatures. Applied Catalysis B: Environmental. 2006, 68(10): 21~27
115 Eduard Iojoiu, Patrick Gélin and Hélène Praliaud, et al. Reduction of NO by Propene over Supported Iridium Catalysts under Lean-Burn Conditions: an in Situ FTIR Study. Applied Catalysis A: General. 2004, 263(5): 39~48
116 Jong Yeol Jeon, Hee Young Kim and Seong Ihl Woo. Selective Catalytic Reduction of NOx in Lean-Burn Engine Exhaust over a Pt/V/MCM-41 Catalyst. Applied Catalysis B: Environmental. 2003, 44(9): 311~323
117 G. Schaub, D. Unruh and J. Wang, et al. Kinetic Analysis of Selective Catalytic NOx Reduction (SCR) in a Catalytic Filter. Chemical Engineering and Processing, 2003, 42(5): 365~371
118 Hirofumi Ohtsuka. The Selective Catalytic Reduction of Nitrogen Oxides by Methane on Noble Metal-Loaded Sulfated Zirconia. Applied Catalysis B: Environmental. 2001, 33(10): 325~333
119 D. Niakolas, Ch. Andronikou and Ch. Papadopoulou, et al. Influence of Metal Oxides on the Catalytic Behavior of Au/Al2O3 for the Selective Reduction of NOx by Hydrocarbons. Catalysis Today. 2006, 112(3): 184~187
120 Mikaela Wallin, Neil Cruise and Uta Klement, et al. Preparation of Mn, Fe and Co Based Perovskite Catalysts Using Microemulsions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2004, 238(5): 27~35
121 Javier Pérez-Ramírez and Freek Kapteijn. Effect of NO on the SCR of N2O with Propane over Fe-zeolites. Applied Catalysis B: Environmental. 2004, 47(2): 177~187
122 E S. Djerad, L. Tifouti and M. Crocoll, et al. Effect of Vanadia and Tungsten Loadings on the Physical and Chemical Characteristics of V2O5-WO3/TiO2 Catalysts. Journal of Molecular Catalysis A: Chemical. 2004, 208(2): 257~265
123 Chung Jongshik, Charles Junghanns and Dietmar Schlosser. Potential of Aquatic Fungi Derived from Diverse Freshwater Environments to Decolourize Synthetic Azo and Anthraquinone Dyes. Bioresource Technology. 2008, 99(3): 1225~1235
124 Hedi Ben Mansour, David Corroler and Daniel Barillier, et al. Evaluation of Genotoxicity and Pro-oxidant Effect of the Azo Dyes: Acids Yellow 17, Violet 7 and Orange 52, and of Their Degradation Products by Pseudomonas Putida mt-2. Food and Chemical Toxicology. 2007, 45(9): 1670~1677
125 L. Wojnárovits, T. Pálfi and E. Takács. Kinetics and Mechanism of Azo Dye Destruction in Advanced Oxidation Processes. Radiation Physics and Chemistry. 2007, 76(8-9): 1497~1501
126 Mustafa I?ik and Delia Teresa Sponza. Fate and Toxicity of Azo Dye Metabolites under Batch Long-term Anaerobic Incubations. Enzyme and Microbial Technology. 2007, 40(3): 934~939
127 A. Víg, K. Sirbiladze and H.J. Nagy, et al. The Light Stability of Azo Dyes and Dyeings V. The impact of the Atmosphere on the Light Stability of Dyings with Heterobifunctional Reactive Azo Dyes. Dyes and Pigments. 2007, 72: 16~22
128 Bor-Yann Chen. Toxicity Assessment of Aromatic Amines to Pseudomonas Luteola: Chemostat Pulse Technique and Dose–response Analysis. Process Biochemistry. 2006, 41(7): 1529~1538
129 ?eněk Novotny, Nicolina Dias and Anu Kapanen, et al. Comparative Use of Bacterial, Algal and Protozoan Tests to Study Toxicity of Azo- and Anthraquinone Dyes. Chemosphere. 2006, 63(6): 1436~1442
130 Robert Maas and Sanjeev Chaudhari. Adsorption and Biological Decolourization of Azo Dye Reactive Red 2 in Semicontinuous Anaerobic Reactors. Process Biochemistry. 2005, 40(2): 699~705
131 M. Muruganandham and M. Swaminathan. Decolourisation of Reactive Orange 4 by Fenton and Photo-Fenton Oxidation Technology. Dyes and Pigments. 2004, 63(12): 315~321
132 Mariana Neamtu, Ayfer Yediler and Ilie Siminiceanu, et al. Oxidation of Commercial Reactive Azo Dye Aqueous Solutions by the Photo-Fenton and Fenton-like Processes. Journal of Photochemistry and Photobiology A: Chemistry. 2003, 161(11): 87~93
133 Yolanda Flores, Roberto Flores and Alberto Alvarez Gallegos. Heterogeneous Catalysis in the Fenton-type System Reactive Black 5/H2O2. Journal of Molecular Catalysis A: Chemical. 2007, (10)
134 Bharat Lodha and Sanjeev Chaudhari. Optimization of Fenton-biological Rreatment Scheme for the Treatment of Aqueous Dye Solutions. Journal of Hazardous Materials. 2007, 148(9): 459~466
135 A. Riga, K. Soutsas and K. Ntampegliotis, et al. Papapolymerou, Effect of System Parameters and of Inorganic Salts on the Decolorization and Degradation of Procion H-exl Dyes. Comparison of H2O2/UV, Fenton, UV/Fenton, TiO2/UV and TiO2/UV/H2O2 Processes. Desalination. 2007, 211(6): 72~86
136 K. Selvam, M. Muruganandham and N. Sobana, et al. Enhancement of UV-assisted Photo-Fenton Degradation of Reactive Orange 4 Using TiO2-P25 Nanoparticles. Separation and Purification Technology. 2007, 54(4): 241~247
137 Sumandeep Kaur and Vasundhara Singh. TiO2 Mediated Photocatalytic Degradation Studies of Reactive Red 198 by UV Irradiation. Journal of Hazardous Materials. 2007, 141(3): 230~236
138 Il-Hyoung Cho and Kyung-Duk Zoh. Photocatalytic Degradation of Azo Dye (Reactive Red 120) in TiO2/UV System: Optimization and Modeling Using a Response Surface Methodology (RSM) Based on the Central Composite Design. Dyes and Pigments. 2007, 75: 533~543
139 Mohammad Hossein Habibi and Nasrin Talebian. Photocatalytic Degradation of an Azo Dye X6G in Water: A Comparative Study Using Nanostructured Indium tin Oxide and Titanium Oxide Thin Films. Dyes and Pigments. 2007, 73: 186~194
140 Xiwang Zhang, Guoting Li and Yizhong Wang. Microwave Assisted Photocatalytic Degradation of High Concentration Azo Dye Reactive Brilliant Red X-3B with Microwave Electrodeless Lamp as Light Source. Dyes and Pigments. 2007, 74: 536~544
141 Mohammad Hossein Habibi and Mojtaba Nasr-Esfahani. Preparation, Characterization and Photocatalytic Activity of a Novel Nanostructure Composite Film Derived from Nanopowder TiO2 and Sol–gel Process Using Organic Dispersant. Dyes and Pigments. 2007, 75: 714~722
142 Mohammad Hossein Habibi, Nasrin Talebian and Jong-Ha Choi. Characterization and Photocatalytic Activity of Nanostructured Indium tin Oxide Thin-film Electrode for Azo-dye Degradation. Thin Solid Films. 2006, 515(12): 1461~1469
143 V. López-Grimau and M.C. Gutiérrez. Decolourisation of Simulated Reactive Dyebath Effluents by Electrochemical Oxidation Assisted by UV Light. Chemosphere. 2006, 62(1): 106~112
144 Chen-Lu Yang and Jared McGarrahan. Electrochemical Coagulation for Textile Effluent Decolorization. Journal of Hazardous Materials. 2005, 127(12): 40~47
145 Patricia A. Carneiro, Marly E. Osugi and Jeosadaque J. Sene, et al. Evaluation of Color Removal and Degradation of a Reactive Textile Azo Dye onNanoporous TiO2 Thin-film Electrodes. Electrochimica Acta. 2004, 49(9): 3807~3820
146 Maria Valnice B. Zanoni, Jeosadaque J. Sene and Marc A. Anderson. Photoelectrocatalytic Degradation of Remazol Brilliant Orange 3R on Titanium Dioxide Thin-film Electrodes. Journal of Photochemistry and Photobiology A: Chemistry. 2003, 157(4): 55~63
147 Kyung Shik Yang, Guido Mul, Jin Seong Choi, Jacob A. Moulijn and Jong Shik Chung. Development of TiO2/Ti wire-mesh honeycomb for catalytic combustion of ethyl acetate in air. Applied Catalysis A: General. 2006, 1 (313):86~93
148 A.F. Pérez-Cadenas, S. Morales-Torres and F. Kapteijn, et al. Carbon-based Monolithic Supports for Palladium Catalysts: The Role of the Porosity in the Gas-Phase Total Combustion of M-xylene. Applied Catalysis B: Environmental. 2008, 77(1): 272~277
149 Barbara Kucharczyk and W?odzimierz Tylus. Effect of Pd Additive on the Activity of Monolithic LaMnO3-Based Catalysts for Methane Combustion. Catalysis Today. 2008, (1)
150 Barbara Kucharczyk and W?odzimierz Tylus. Partial Substitution of Lanthanum with Silver in the LaMnO3 Perovskite: Effect of the Modification on the Activity of Monolithic Catalysts in the Reactions of Methane and Carbon Oxide Oxidation. Applied Catalysis A: General. 2007, (11)
151 Shemin Zhu, Yuesong Shen and Jialei Wang, et al. Preparation and Performance of Al2 TiO5 -TiO2 -SiO2 Honeycomb Ceramics by Doping Rare Earth. Journal of Rare Earths. 2007, 25(8): 457~461
152 Dae Jung Kim, Namgoo Kang and Wang Geun Shim, et al. Isothermal Adsorption Equilibrium and Dynamics of Binary Mixture Gasoline Constituents on Honeycomb Monoliths. Chemical Engineering Journal. 2007, (4)
153 Wang Jianli, Cao Hongyan and Zhong Junbo, et al. Effect of Metal Oxide Doping into Ce0.5Zr0.5O2 on Catalytic Activity of MnOx/γ-Al2O3/Ce0.45Zr0.45M0.1Ox (M = Y, La, Mn) Honeycomb Catalysts. Journal of Rare Earths. 2007, 25(2): 111~113
154 E. García-Bordejé, M.J. Lázaro and R. Moliner, et al. Vanadium Supported on Carbon Coated Honeycomb Monoliths for the Selective Catalytic Reduction ofNO at Low Temperatures: Influence of the Oxidation Pre-treatment, Carbon, 2006, 44(3): 407~417
155 Gianpiero Groppi and Enrico Tronconi. Honeycomb Supports with High Thermal Conductivity for Gas/Solid Chemical Processes. Catalysis Today. 2005, 105(8): 297~304
156 Ki-Suk Chung, Zhidong Jiang and Bong-Seok Gill, et al. Chung.Oxidative decomposition of o-dichlorobenzene over V2O5/TiO2 catalyst washcoated onto wire-mesh honeycombs. Applied Catalysis A: General. 2002, 1-2(237):81~89
157 Enrico Tronconi, Gianpiero Groppi and Thorsten Boger, et al. Monolithic Catalysts with‘High Conductivity’Honeycomb Supports for Gas/Solid Exothermic Reactions: Characterization of the Heat-Transfer Properties. Chemical Engineering Science. 2004, 59(11-12): 4941~4949
158 Yansong Han, Hai Sheng Zeng and Naijia Guan. Thermal and Hydrothermal Stability of Monolithic TS-1/Cordierite Catalyst. Catalysis Communications. 2002, 3(6): 221~225
159 Silvester Tursiloadi, Hiroaki Imai and Hiroshi Hirashima. Preparation and Characterization of Mesoporous Titania–Alumina Ceramic by Modified Sol–gel Method. Journal of Non-Crystalline Solids. 2004, 350(12): 271~276
160 E. García-Bordejé, L. Calvillo and M. J. Lázaro, et al. Vanadium Supported on Carbon-Coated Monoliths for the SCR of NO at Low Temperature: Effect of Pore Structure. Applied Catalysis B: Environmental. 2004, 50(7): 235~242
161 E. García-Bordejé, M. J. Lázaro and R. Moliner, et al. Structure of Vanadium Oxide Supported on Mesoporous Carbon-coated Monoliths and Relationship with Its Catalytic Performance in the SCR of NO at Low Temperatures. Journal of Catalysis. 2004, 223(4): 395~403
162 Alicia V. Boix, Juan M. Zamaro and Eduardo A. Lombardo, et al. The Beneficial Effect of Silica on the Activity and Thermal Stability of PtCoFerrierite-washcoated Cordierite Monoliths for the SCR of NOx with CH4. Applied Catalysis B: Environmental. 2003, 46(10): 121~132
163 Sian-Jie Ciou, Kuan-Zong Fung and Kai-Wei Chiang. Behaviors and Mechanism of Electrolyte Electrophoresis during Electrophoretic Deposition. Journal of Power Sources. 2008, 175(1): 33~39
164 Kyung Shik Yang, Jin Seong Choi and Jong Shik Chung. Evaluation of wire-mesh honeycomb containing porous Al/Al2O3 layer for catalytic combustion of ethyl acetate in air. Catalysis Today. 2004, 2-3(97): 159~165
165 Kyung Shik Yang, Zhidong Jiang and Jong Shik Chung. Electrophoretically Al-coated wire mesh and its application for catalytic oxidation of 1,2-dichlorobenzene.Surface and Coatings Technology. 2003, 2-3(168):103~110
166 I. Mazzarino and A. A. Barresi. Catalytic Combustion of Voc Mixtures in a Monolithic Reactor. Catalysis Today. 1993, 17(5): 335~347
167 Nerea Burgos, María Paulis and M. Mirari Antxustegi, et al. Deep Oxidation of VOC Mixtures with Platinum Supported on Al2O3/Al Monoliths. Applied Catalysis B: Environmental.2002, 38(10): 251~258
168 Gaurav Mohanty, Laxmidhar Besra and Sarama Bhattacharjee, et al. Optimization of Electrophoretic Deposition of Alumina onto Steel Substrates from Its Suspension in Iso-propanol Using Statistical Design of Experiments. Materials Research Bulletin.2007, (7)
169 Kyung Shik Yang, Guido Mul and Jacob A. Moulijn. Electrochemical Generation of Hydrogen Peroxide Using Surface Area-Enhanced Ti-mesh Electrodes. Electrochimica Acta. 2007, 52(6): 6304~6309
170 Junhua Li, Jianjun Chen and Rui Ke, et al. Effects of Precursors on the Surface Mn Species and the Activities for NO Reduction over MnOx/TiO2 Catalysts. Catalysis Communications. 2007, 8(12): 1896~1900
171 Juan Antonio Martín, Malcolm Yates and Pedroávila, et al. Nitrous Oxide Formation in Low Temperature Selective Catalytic Reduction of Nitrogen Oxides with V2O5/TiO2 Catalysts. Applied Catalysis B: Environmental. 2007, 70(1): 330~334
172 S. Djerad, M. Crocoll and S. Kureti, et al. Effect of Oxygen Concentration on the NOx Reduction with Ammonia over V2O5–WO3/TiO2 Catalyst. Catalysis Today. 2006, 113(4): 208~214
173 Motonobu Kobayashi, Ryoji Kuma and Sinyuki Masaki, et al. TiO2-SiO2 and V2O5/TiO2-SiO2 Catalyst: Physico-chemical Characteristics and Catalytic Behavior in Selective Catalytic Reduction of NO by NH3. Applied Catalysis B: Environmental. 2005, 60(10): 173~179
174 Yuanjing Zheng, Anker Degn Jensen and Jan Erik Johnsson. Deactivation of V2O5-WO3-TiO2 SCR Catalyst at a Biomass-fired Combined Heat and Power Plant. Applied Catalysis B: Environmental. 2005, 60(10): 253~264
175 Khanh-Quang Tran, Pia Kilpinen and Narendra Kumar. In-situ Catalytic Abatement of NOx during Fluidized Bed Combustion—A Literature Study. Applied Catalysis B: Environmental. 2008, 78(1): 129~138
176 Miguel A.G. Hevia and Javier Pérez-Ramírez. Assessment of the Low-Temperature EnviNOx? Variant for Catalytic N2O Abatement over Steam-activated FeZSM-5. Applied Catalysis B: Environmental. 2008, 77(1): 248~254
177 In-Young Lee, Dong-Wha Kim and Jung-Bin Lee, et al. A Practical Scale Evaluation of Sulfated V2O5/TiO2 Catalyst from Metatitanic Acid for Selective Catalytic Reduction of NO by NH3. Chemical Engineering Journal. 2002, 90(12): 267~272
178 Ha Heon Phil, Maddigapu Pratap Reddy and Pullur Anil Kumar, et al. SO2 Resistant Antimony Promoted V2O5/TiO2 Catalyst for NH3-SCR of NOx at Low Temperatures. Applied Catalysis B: Environmental. 2008, 78(2): 301~308
179 Xinping Wang, Shanshan Yu and Hongliang Yang, et al. Selective Catalytic Reduction of NO by C2H2 over MoO3/HZSM-5. Applied Catalysis B: Environmental. 2007, 71(2): 246~253
180 S. Suárez, J.A. Martín and M. Yates, et al. N2O Formation in the Selective Catalytic Reduction of NOx with NH3 at Low Temperature on CuO-supported Monolithic Catalysts. Journal of Catalysis. 2005, 229(1): 227~236
181 Landong Li, Jixin Chen and Shujuan Zhang, et al. Selective Catalytic Reduction of Nitrogen Oxides from Exhaust of Lean Burn Engine over in Situ Synthesized Monolithic Cu–TS-1/cordierite. Catalysis Today. 2004, 90(7): 207~213
182 Jesús Blanco, Pedro Avila and Silvia Suárez, et al. CuO/NiO Monolithic Catalysts for NOx Removal from Nitric Acid Plant Flue Gas. Chemical Engineering Journal, 2004, 97(1): 1~9
183 A. Bahamonde, S. Campuzano and M. Yates, et al. Influence of Zirconia Raw Materials on the Development of DeNOx Monolithic Catalysts. Applied Catalysis B: Environmental. 2003, 44(9): 333~346
184 M. Muruganandham and M. Swaminathan.TiO2–UV Photocatalytic Oxidation of Reactive Yellow 14: Effect of Operational Parameters. Journal of Hazardous Materials. 2006, 135(7): 78~86
185 M. Muruganandham and M. Swaminathan. Advanced Ooxidative Decolourisation of Reactive Yellow 14 azo dye by UV/TiO2, UV/H2O2, UV/H2O2/Fe2+ Processes—a Comparative Study. Separation and Purification Technology. 2006, 48(3): 297~303
186 Igor Peternel, Natalija Koprivanac and Hrvoje Kusic. UV-based Processes for Reactive Azo Dye Mineralization. Water Research. 2006, 40(2): 525~532
2 P. Papaefthimiou, T. Ioannides and X. E. Verykios. Catalytic Incineration of Volatile Organic Compounds Present in Industrial Waste Streams. Applied Thermal Engineering. 1998, 18(11): 1005~1012
3 Jo Dewulf, Herman Van Langenhove and Jeroen Dirckx. Energy Analysis in the Assessment of the Sustainability of Waste Gas Treatment Systems. The Science of the Total Environment. 2001, 273(6): 41~52
4 Andrey N. Zagoruiko, Oleg V. Kostenko and Alexander S. Noskov. Development of the Adsorption-Catalytic Reverse-Process for Incineration of Volatile Organic Compounds in Diluted Waste Gases. Chemical Engineering Science. 1996, 51(6): 2989~2994
5 Sumaeth Chavadej, Witan Kiatubolpaiboon and Pramoch Rangsunvigit, et al. A Combined Multistage Corona Discharge and Catalytic System for Gaseous Benzene Removal. Journal of Molecular Catalysis A: Chemical. 2007, 263(2): 128~136
6 A. O’Malley and B. K. Hodnett. The Influence of Volatile Organic Compound Structure on Conditions Required for Total Oxidation. Catalysis Today. 1999, 54(11): 31~38
7 K.P. Francke, H. Miessner and R. Rudolph. Plasmacatalytic Processes for Environmental Problems. Catalysis Today.2000, 59(6): 411~416
8 Jim Van Durme, Jo Dewulf and Christophe Leys, et al. Combining Non-thermal Plasma with Heterogeneous Catalysis in Waste Gas Treatment: A Review, Applied Catalysis B: Environmental. 2008, 78(2): 324~333
9 Monica Magureanu, Nicolae Bogdan Mandache and Juncheng Hu, et al. Parvulescu, Plasma-Assisted Catalysis Total Oxidation of Trichloroethylene over Gold Nano-particles Embedded in SBA-15 Catalysts. Applied Catalysis B: Environmental. 2007, 76(11): 275~281
10 Ch. Subrahmanyam, M. Magureanu and A. Renken L, et al. Catalytic Abatement of Volatile Organic Compounds Assisted by Non-thermal Plasma:Part 1. A Novel Dielectric Barrier Discharge Reactor Containing Catalytic Electrode, Applied Catalysis B: Environmental. 2006, 65(5): 150~156
11 Ch. Subrahmanyam, A. Renken and L. Kiwi-Minsker. Catalytic Abatement of Volatile Organic Compounds Assisted by Non-thermal Plasma: Part II. Optimized Catalytic Electrode and Operating Conditions. Applied Catalysis B: Environmental. 2006, 65(5): 157~162
12 Ch. Subrahmanyam, A. Renken and L. Kiwi-Minsker. Novel Catalytic Non-thermal Plasma Reactor for the Abatement of VOCs. Chemical Engineering Journal. 2007, 134(11): 78~83
13 M. Magureanu, N.B. Mandache and V.I. Parvulescu, et al. Improved Performance of Non-thermal Plasma Reactor during Decomposition of Trichloroethylene: Optimization of the Reactor Geometry and Introduction of Catalytic Electrode. Applied Catalysis B: Environmental. 2007, 74(7): 270~277
14 Monica Magureanu, Nicolae B. Mandache and Pierre Eloy, et al. Parvulescu, Plasma-Assisted Catalysis for Volatile Organic Compounds Abatement. Applied Catalysis B: Environmental. 2005, 61(10): 12~20
15 J. Van Durme, J. Dewulf and W. Sysmans, et al. Efficient Toluene Abatement in Indoor Air by a Plasma Catalytic Hybrid System. Applied Catalysis B: Environmental. 2007, 74(6): 161~169
16 U. Roland, F. Holzer and F.-D. Kopinke. Combination of Non-thermal Plasma and Heterogeneous Catalysis for Oxidation of Volatile Organic Compounds: Part 2. Ozone Decomposition and Deactivation ofγ-Al2O3. Applied Catalysis B: Environmental. 2005, 58(6): 217~226
17张林,陈欢林,柴红.挥发性有机物废气的膜法处理工艺研究进展.化工环保. 2002, 22(2):75~80
18徐志康,刘振梅,戴清文.基于溶解的扩散机理的聚合物膜分离烯烃/烷烃的研究进展.石油化工. 2002, 31(2):135~140
19 L. Guczi, L. Borkóand Z. Schay. Some Problems on Environmental Catalysis. Studies in Surface Science and Catalysis. 1998, 113: 69~80
20 J. Tsou, P. Magnoux and M. Guisnet, et al. Figueiredo Oscillations in the Catalytic Oxidation of Volatile Organic Compounds. Journal of Catalysis. 2004, 225(7): 147~154
21 K. Everaert and J. Baeyens. Catalytic Combustion of Volatile Organic Compounds. Journal of Hazardous Materials. 2004, 109(6): 113~139
22 E. Noordally, J. R. Richmond and S. F. Tahir. P. Papaefthimiou, et al. Destruction of Volatile Organic Compounds by Catalytic Oxidation, Catalysis Today, 1993, 17(5): 359~366
23 C. Libanati, D.A. Ullenius and C.J. Pereira. Silica Deactivation of Bead VOC Catalysts. Applied Catalysis B: Environmental.1998, 15(1): 21~28
24 Antonella Gervasini, Carlo Pirola and Vittorio Ragaini. Destruction of Carbon Tetrachloride in the Presence of Hydrogen-Supplying Compounds with Ionisation and Catalytic Oxidation. Applied Catalysis B: Environmental. 2002, 38(7): 17~28
25 S.K. Agarwal, J.J. Spivey and J.B. Butt. Catalyst Deactivation during Deep Oxidation of Chlorohydrocarbons. Applied Catalysis A: General. 1992, 82(3): 259~275
26 Anna Musialik-Piotrowska and Bo ena Mendyka. Catalytic Oxidation of Chlorinated Hydrocarbons in Two-component Mixtures with Selected VOCs. Catalysis Today. 2004, 90(6): 139-144
27 H. Windawi and Z. C. Zhang. Catalytic Destruction of Halogenated Air Toxins and the Effect of Admixture with VOCs. Catalysis Today. 1996, 30(6): 99~105
28杨显万,孙佩石,黄若华.生物法净化低浓度挥发性有机废气的研究.中国工程科学, 2001, 3(9):64~68
29李国文,胡洪营,郝吉明,等.生物过滤塔甲苯降解性能研究.环境科学, 2001, 22(2):31~35
30陈建孟,王家德,庄利,等.生物滴滤池净化二氯甲烷废气的实验研究.环境科学, 2002, 23(4):8~12
31 G. Sinquin, C. Petit and S. Libs, et al. Catalytic Destruction of Chlorinated C1 Volatile Organic Compounds (CVOCs) Reactivity, Oxidation and Hydrolysis Mechanisms. Applied Catalysis B: Environmental. 2000, 27(7): 105~115
32黄正宏,康飞宇,吴慧,等.湿氧化改性多孔炭对低浓度苯和丁酮蒸汽的吸附.清华大学学报(自然科学版). 2000, 40(10):111~115
33 John R. Hart. Emissions of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans from Catalytic and Thermal Oxidizers Burning Dilute Chlorinated Vapors. Chemosphere. 2004, 54(3): 1539~1547
34 S.K. Gangwal, M.E. Mullins and J.J. Spivey, et al. Kinetics and Selectivity of Deep Catalytic Oxidation of n-Hexane and Benzene. Applied Catalysis. 1988, 36: 231~247
35 M. Guillemot, J. Mijoin and P. Magnoux, et al. Volatile Organic Compounds (VOCs) Removal over Dual Functional Adsorbent/Catalyst System. Applied Catalysis B: Environmental. 2007, 75(9): 249~255
36 Anna Musialik-Piotrowska and Krystyna Syczewska. Catalytic Oxidation of Trichloroethylene in Two-component Mixtures with Selected Volatile Organic Compounds. Catalysis Today. 2002, 73(4): 333~342
37 Alan Janbey, Wayne Clark and Ehsan Noordally, et al. Noble Metal Catalysts for Methane Removal. Chemosphere. 2003, 52(8): 1041~1046
38 Ting-Ke Tseng, Hsin Chu and Tzu-Hsing Ko, et al. The Kinetic of the Catalytic Decomposition of Methyl Isobutyl Ketone over a Pt/γ-Al2O3 Catalyst Chemosphere. 2005, 61(10): 469~477
39 Ting-Ke Tseng, Hsin Chu and Tzu-Hsing Ko, et al. The Operating Performance and Products Distribution of the Catalytic Oxidation of Methyl-Isobutyl-Ketone over a Pt/γ-Al2O3 Catalyst. Journal of Hazardous Materials. 2005, 122(6): 155~160
40 Rubén López-Fonseca, Jose I. Gutiérrez-Ortiz and Miguel A. Gutiérrez-Ortiz, et al. Catalytic Oxidation of Aliphatic Chlorinated Volatile Organic Compounds over Pt/H-BETA Zeolite Catalyst under Dry and Humid Conditions. Catalysis Today. 2005, 107-108(10): 200~207
41 George Avgouropoulos, Evaggelos Oikonomopoulos and Dimitrios Kanistras, et al. Complete Oxidation of Ethanol over Alkali-Promoted Pt/Al2O3 Catalysts. Applied Catalysis B: Environmental. 2006, 65(5): 62~69
42 M. Guisnet, P. Dégéand P. Magnoux. Catalytic Oxidation of Volatile Organic Compounds 1. Oxidation of Xylene over a 0.2 wt% Pd/HFAU (17) Catalyst. Applied Catalysis B: Environmental. 1999, 20(1): 1~13
43 Panagiotis Papaefthimiou, Theophilos Ioannides and Xenophon E. Verykios. Performance of Doped Pt/TiO2 (W6+) Catalysts for Combustion of Volatile Organic Compounds (VOCs). Applied Catalysis B: Environmental. 1998, 15(1): 75~92
44 Philippe Dégé, Ludovic Pinard and Patrick Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds (VOCs), Oxidation of O-xylene over Pd and Pt/HFAU Catalysts. Comptes Rendus de l’Académie des Sciences - Series IIC– Chemistry. 2001, (1): 41~47
45 Ph. Dégé, L. Pinard and P. Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds: II. Influence of the Physicochemical Characteristics of Pd/HFAU Catalysts on the Oxidation of o-xylene. Applied Catalysis B: Environmental. 2000, 27(6): 17-26
46 Lifeng Wang, Makoto Sakurai and Hideo Kameyama. Catalytic Oxidation of Dichloromethane and Toluene over Platinum Alumite Catalyst. Journal of Hazardous Materials. 2007, (10)
47 A.V. Kucherov, I.M. Sinev and S. Ojala, et al. Adsorptive-Catalytic Removal of CH3OH, CH3SH, and CH3SSCH3 from Air over the Bifunctional System Noble Metals/HZSM-5. Studies in Surface Science and Catalysis. 2007, 170: 1129~1136
48 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Characterization of New Pd/hierarchical Macro-mesoporous ZrO2, TiO2, and ZrO2-TiO2 Catalysts for Toluene Total Oxidation. Studies in Surface Science and Catalysis. 2007, 160: 201~208
49 Jeffrey Chi-Sheng Wu, Zhi-An Lin and Feng-Ming, et al. Low-temperature Complete Oxidation of BTX on Pt/activated Carbon Catalysts. Catalysis Today. 2000, 63(12): 419~426
50 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Characterization of Palladium Supported on Exchanged BEA and FAU Zeolites for VOCs Catalytic Oxidation. Studies in Surface Science and Catalysis. 2007, 160: 209~216
51 Salvatore Scirè, Simona Minicòand Carmelo Crisafulli. Pt Catalysts Supported on H-type Zeolites for the Catalytic Combustion of Chlorobenzene. Applied Catalysis B: Environmental. 2003, 45(9): 117~125
52 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. Influence of the Exchanged Cation in Pd/BEA and Pd/FAU Zeolites for Catalytic Oxidation of VOCs. Applied Catalysis B: Environmental. 2007, 70(1): 377~383
53 Jeffrey C. S. Wu, Zhi-An Lin and Jen-Wei Pan, et al. A Novel Boron Nitride Supported Pt Catalyst for VOC Incineration. Applied Catalysis A: General. 2001, 219(10): 117~124
54 J. Tsou, L. Pinard and P. Magnoux, et al. Catalytic Oxidation of Volatile Organic Compounds (VOCs): Oxidation of O-xylene over Pt/HBEA Catalysts. Applied Catalysis B: Environmental. 2003, 46(11): 371~379
55 Taizo Sano, Nobuaki Negishi and Koji Takeuchi, et al. Degradation of Toluene and Acetaldehyde with Pt-loaded TiO2 Catalyst and Parabolic Trough Concentrator. Solar Energy. 2004, 77(11): 543~552
56 M. Hosseini, S. Siffert and H.L. Tidahy, et al. Promotional Effect of Gold Added to Palladium Supported on a New Mesoporous TiO2 for Total Oxidation of Volatile Organic Compounds. Catalysis Today. 2007, 122(4): 391~396
57 Simona Minicò, Salvatore Scirèand Carmelo Crisafulli, et al. Catalytic Combustion of Volatile Organic Compounds on Gold/Iron Oxide Catalysts. Applied Catalysis B: Environmental. 2000, 28(12): 245~251
58 Salvatore Scirè, Simona Minicòand Carmelo Crisafulli, et al. Catalytic Combustion of Volatile Organic Compounds on Gold/Cerium Oxide Catalysts. Applied Catalysis B: Environmental. 2003, 40(1): 43~49
59 M. A. Centeno, M. Paulis and M. Montes, et al. Catalytic Combustion of Volatile Organic Compounds on Au/CeO2/Al2O3 and Au/Al2O3 Catalysts. Applied Catalysis A: General. 2002, 234(8): 65~78
60 Simona Minicò, Salvatore Scirèand Carmelo Crisafulli, et al. Influence of Catalyst Pretreatments on Volatile Organic Compounds Oxidation over Gold/Iron Oxide. Applied Catalysis B: Environmental. 2001, 34(11): 277~285
61 H.L. Tidahy, S. Siffert and J.-F. Lamonier, et al. New Pd/hierarchical Macro-mesoporous ZrO2, TiO2 and ZrO2-TiO2 Catalysts for VOCs Total Oxidation. Applied Catalysis A: General. 2006, 310(8): 61-69
62 Sophie Giraud, Guillaume Loupias and Hicham Maskrot, et al. Dip-coating on TiO2 Foams Using a Suspension of Pt–TiO2 Nanopowder Synthesized by Laser Pyrolysis—Preliminary Evaluation of the Catalytic Performances of the Resulting Composites in deVOC Reactions. Journal of the European Ceramic Society. 2007, 27: 931~936
63 J. R. González-Velasco, A. Aranzabal and J. I. Gutiérrez-Ortiz, et al. Activity and Product Distribution of Alumina Supported Platinum and Palladium Catalysts in the Gas-Phase Oxidative Decomposition of Chlorinated Hydrocarbons. Applied Catalysis B: Environmental. 1998, 19(12): 189~197
64 Anna Musialik-Piotrowska. Destruction of Trichloroethylene (TCE) and Trichloromethane (TCM) in the Presence of Selected VOCs over Pt-Pd-based Catalyst. Catalysis Today. 2007, 119(1): 301-304
65 Ruud W. van den Brink, Robert Louw and Peter Mulder. Formation of Polychlorinated Benzenes during the Catalytic Combustion of Chlorobenzene Using a Pt/γ-Al2O3 Catalyst. Applied Catalysis B: Environmental. 1998, 16(5): 219~226
66 Mingqian Zhang, Bing Zhou and Karl T. Chuang. Catalytic Deep Oxidation of Volatile Organic Compounds over Fluorinated Carbon Supported Platinum Catalysts at Low Temperatures. Applied Catalysis B: Environmental. 1997, 13(10): 123~130
67 J. Tsou, P. Magnoux and M. Guisnet, et al. Catalytic Oxidation of Volatile Organic Compounds: Oxidation of Methyl-Isobutyl-Ketone over Pt/zeolite catalysts. Applied Catalysis B: Environmental. 2005, 57(4): 117~123
68 Tomas Garcia, Benjamin Solsona and Diego Cazorla-Amorós, et al. Total Oxidation of Volatile Organic Compounds by Vanadium Promoted Palladium-Titania Catalysts: Comparison of Aromatic and Polyaromatic Compounds. Applied Catalysis B: Environmental. 2006, 62(1): 66~76
69 Shih Yin Liu and Sze Ming Yang. Complete Oxidation of 2-propanol over Gold-based Catalysts Supported on Metal Oxides. Applied Catalysis A: General. 2008, 334(1): 92~99
70 Panagiotis Papaefthimiou, Theophilos Ioannides and Xenophon E. Verykios. Combustion of Non-halogenated Volatile Organic Compounds over Group VIII Metal Catalysts. Applied Catalysis B: Environmental. 1997, 13(11) 175~184
71 Serge Vigneron, Pascal Deprelle and Jacques Hermia. Comparison of Precious Metals and Base Metal Oxides for Catalytic Deep Oxidation of Volatile Organic Compounds from Coating Plants: Test Results on an Industrial Pilot Scale Incinerator, Catalysis Today. 1996, 27(11): 229~236
72 Marco Baldi, Elisabetta Finocchio and Fabio Milella, et al. Catalytic Combustion of C3 Hydrocarbons and Oxygenates over Mn3O4. Applied Catalysis B: Environmental. 1998, 16(3): 43~51
73 Luciano Lamaita, M. Andrés Peluso and Jorge E. Sambeth, et al. A Theoretical and Experimental Study of Manganese Oxides Used as Catalysts for VOCs Emission Reduction. Catalysis Today. 2005, 107-108(10): 133~138
74 Vivekanand Gaur, Ashutosh Sharma and Nishith Verma. Catalytic Oxidation of Toluene and M-xylene by Activated Carbon Fiber Impregnated with Transition Metals. Carbon. 2005, 43(12): 3041~3053
75 Chi-Yuan Lu and Ming-Yen Wey. Simultaneous Removal of VOC and NO by Activated Carbon Impregnated with Transition Metal Catalysts in Combustion Flue Gas. Fuel Processing Technology. 2007, 88(6): 557~567
76 Chi-Yuan Lu, Ming-Yen Wey and Li-Ing Chen. Application of Polyol Process to Prepare AC-supported Nanocatalyst for VOC Oxidation. Applied Catalysis A: General. 2007, 325(5): 163~174
77 Catherine S. Heneghan, Graham J. Hutchings and Shane R. O’Leary, et al. A Temporal Analysis of Products Study of the Mechanism of VOC Catalytic Oxidation Using Uranium Oxide Catalysts. Catalysis Today. 1999 54(11): 3~12
78 Stuart H. Taylor, Catherine S. Heneghan and Graham J. Hutchings, et al. The Activity and Mechanism of Uranium Oxide Catalysts for the Oxidative Destruction of Volatile Organic Compounds. Catalysis Today. 2000, 59(6): 249~259
79 Sang Chai Kim and Wang Geun Shim. Recycling the Oopper Based Spent Catalyst for Catalytic Combustion of VOCs. Applied Catalysis B: Environmental, 2008, 2(79): 149-156
80 M. Stoyanova, P. Konova and P. Nikolov, et al. Alumina-Supported Nickel Oxide for Ozone Decomposition and Catalytic Ozonation of CO and VOCs. Chemical Engineering Journal. 2006, 122(12): 41~46
81 I.Z. Ismagilov, R.P. Ekatpure and L.T. Tsykoza, et al. Optimization of Anodic Oxidation and Cu–Cr Oxide Catalyst Preparation on Structured Aluminum Plates Processed by Electro Discharge Machining. Catalysis Today. 2005, 105(8): 516~528
82 A. Rougier, S. Soiron and I. Haihal, et al. Influence of Grinding on the Catalytic Properties of Oxides. Powder Technology. 2002, 128(12): 139~147
83 D.P. Das and K.M. Parida. Mn(III) Oxide Pillared Titanium Phosphate (TiP) for Catalytic Deep Oxidation of VOCs. Applied Catalysis A: General. 2007, 324(5): 1~8
84 D.P. Das and K.M. Parida. Fe(III) Oxide Pillared Titanium Phosphate (TiP): An Effective Catalyst for Deep Oxidation of VOCs. Journal of Molecular Catalysis A: Chemical. 2007, 276(10): 17~23
85 F. Bertinchamps, C. Grégoire and E.M. Gaigneaux. Systematic Investigation of Supported Transition Metal Oxide Based Formulations for the Catalytic Oxidative Elimination of (chloro)-Aromatics: Part II: Influence of the Natureand Addition Protocol of Secondary Phases to VOx/TiO2. Applied Catalysis B: Environmental. 2006, 66(6): 10~22
86 M. C. M. Alvim Ferraz, S. M?ser and M. Tonh?euser. Control of Atmospheric Emissions of Volatile Organic Compounds Using Impregnated Activated carbons. Fuel. 1999, 78(10): 1567~1573
87 R. Beauchet, P. Magnoux and J. Mijoin. Catalytic Oxidation of Volatile Organic Compounds (VOCs) Mixture (Isopropanol/o-Xylene) on Zeolite Catalysts. Catalysis Today. 2007, 124(6): 118~123
88 R. López-Fonseca, A. Aranzabal and P. Steltenpohl, et al. Performance of Zeolites and Product Selectivity in the Gas-phase Oxidation of 1,2-dichloroethane. Catalysis Today, 2000, 62(12): 367~377
89 Teresa S. C. Law, Christopher Chao and George Y. W. Chan, et al. Confined Catalytic Oxidation of Volatile Organic Compounds by Transition Metal Containing Zeolites and Ionizer. Atmospheric Environment. 2003, 37(12): 5433~5437
90 R. López-Fonseca, A. Aranzabal and J. I. Gutiérrez-Ortiz, et al. Comparative Study of the Oxidative Decomposition of Trichloroethylene over H-type Zeolites under Dry and Humid Conditions. Applied Catalysis B: Environmental. 2001, 30(3): 303~313
91 J. R. González-Velasco, R. López-Fonseca and A. Aranzabal, et al. Evaluation of H-type Zeolites in the Destructive Oxidation of Chlorinated Volatile Organic Compounds. Applied Catalysis B: Environmental. 2000, 24(2): 233~242
92 R. López-Fonseca, J. I. Gutiérrez-Ortiz and M. A. Gutiérrez-Ortiz, et al. Dealuminated Y Zeolites for Destruction of Chlorinated Volatile Organic Compounds. Journal of Catalysis. 2002, 209(7): 145~150
93 A.P. Antunes, J.M. Silva and M.F. Ribeiro, et al. 30-P-23-Total Oxidation of Volatile Organic Compounds-Catalytic Oxidation of Toluene over CuY Zeolites. Studies in Surface Science and Catalysis. 2001, 135: 325
94 A. P. Antunes, M. F. Ribeiro and J. M. Silva, et al. Catalytic Oxidation of Toluene over CuNaHY Zeolites: Coke Formation and Removal. Applied Catalysis B: Environmental. 2001, 33(9): 149~164
95 R. López-Fonseca, J. I. Gutiérrez-Ortiz and J. R. González-Velasco. Catalytic Combustion of Chlorinated Hydrocarbons over H-BETA and PdO/H-BETA Zeolite Catalysts. Applied Catalysis A: General, 2004, 271(9): 39~46
96 Jian Luo, Qiuhua Zhang and Aimin Huang, et al. Total Oxidation of Volatile Organic Compounds with Hydrophobic Cryptomelane-type Octahedral Molecular Sieves. Microporous and Mesoporous Materials. 2000, 35-36(4): 209~217
97 Haifeng Huang, Yaqin Liu and Wei Tang, et al. Catalytic Activity of Nanometer La1?xSrxCoO3 (x = 0, 0.2) Perovskites towards VOCs Combustion, Catalysis Communications. 2008, 9(1): 55~59
98 G. Sinquin, C. Petit and J. P. Hindermann, et al. Study of the Formation of LaMO3 (M=Co, Mn) Perovskites by Propionates Precursors: Application to the Catalytic Destruction of Chlorinated VOCs. Catalysis Today. 2001, 70(10): 183~196
99 Jianrong Niu, Jiguang Deng and Wei Liu, et al. Nanosized Perovskite-type Oxides La1?xSrxMO3?δ(M = Co, Mn; x = 0, 0.4) for the Catalytic Removal of Ethyl acetate. Catalysis Today. 2007, 126(8): 420~429 100 V. Blasin-Aubé, J. Belkouch and L. Monceaux. General Study of Catalytic Oxidation of Various VOCs over La0.8Sr0.2MnO3+x Perovskite Catalyst—Influence of Mixture. Applied Catalysis B: Environmental. 2003, 43(6):
175~186
101 Bibiana P. Barbero, Julio Andrade Gamboa and Luis E. Cadús. Synthesis and Characterization of La1?xCaxFeO3 Perovskite-type Oxide Catalysts for Total Oxidation of Volatile Organic Compounds. Applied Catalysis B: Environmental. 2006, 65(5): 21~30
102 R. Spinicci, M. Faticanti and P. Marini, et al. Catalytic Activity of LaMnO3 and LaCoO3 Perovskites towards VOCs Combustion. Journal of Molecular Catalysis A: Chemical. 2003, 197(4): 147~155
103 G. Sinquin, J. P. Hindermann and C. Petit, et al. Perovskites as Polyvalent Catalysts for Total Destruction of C1, C2 and Aromatic Chlorinated Volatile Organic Compounds. Catalysis Today. 1999, 54(11): 107~118
104 J. Haber, K. Bahranowski and J. Janas, et al. Hydrotalcite-Derived Catalysts for Removal of Nitrogen-Containing Volatile Organic Compounds. Studies in Surface Science and Catalysis. 2000, 130: 599~604
105 Hongyi Dong, Shijin Shuai and Rulong Li, et al. Study of NOx Selective Catalytic Reduction by Ethanol over Ag/Al2O3 Catalyst on a HD Diesel Engine. Chemical Engineering Journal. 2008, 135(2): 195~201
106 Gian Luca Chiarello, Davide Ferri and Jan-Dierk Grunwaldt, et al. Flame-synthesized LaCoO3-Supported Pd: 2. Catalytic Behavior in the Reduction of NO by H2 under Lean Conditions. Journal of Catalysis. 2007, 252(12): 137~147
107 JoséR. Hernández Carucci, Kalle Arve and Kari Er?nen, et al. Microreactors for Environmental Catalysis—Selective Catalytic Reduction of NOX with Hydrocarbons over a Ag/alumina Catalyst. Catalysis Today. 2007,(12)
108 Robert D. Clayton, Michael P. Harold and Vemuri Balakotaiah. Selective Catalytic Reduction of NO by H2 in O2 on Pt/BaO/Al2O3 Monolith NOx Storage Catalysts. Applied Catalysis B: Environmental. 2007, (12)
109 A. Abu-Jrai, A. Tsolakis and A. Megaritis. The Influence of H2 and CO on Diesel Engine Combustion Characteristics, Exhaust Gas Emissions, and after Treatment Selective Catalytic NOx Reduction, International Journal of Hydrogen Energy. 2007, 32(10): 3565~3571
110 Cristian Ciardelli, Isabella Nova and Enrico Tronconi, et al. NH3 SCR of NOx for Diesel Exhausts After Treatment: Role of NO2 in Catalytic Mechanism, Unsteady Kinetics and Monolith Converter Modeling. Chemical Engineering Science. 2007, 62(9): 5001~5006
111 J.-I. Park, J.-S. Yun and K.-E. Jeong, et al. Platinum Catalysts Supported on Macrostructured MCM-41 for the Selective Catalytic Reduction of Lean NOx with Hydrocarbons. Studies in Surface Science and Catalysis. 2007, 170: 1362~1367
112 Kwang-Eun Jeong, Joo-Il Park and Son-Ki Ihm. Platinum Catalysts Supported on SBA-15 for the Selective Catalytic Reduction of Lean NOx with Propylene. Studies in Surface Science and Catalysis. 2007, 165: 733~736
113 Ulrich G. Alkemade and Bernd Schumann. Engines and Exhaust after Treatment Systems for Future Automotive Applications. Solid State Ionics. 2006, 177(10): 2291-2296
114 Min Kang, Dae Jung Kim and Eun Duck Park, et al. Eyring, Two-Stage Catalyst System for Selective Catalytic Reduction of NOx by NH3 at Low Temperatures. Applied Catalysis B: Environmental. 2006, 68(10): 21~27
115 Eduard Iojoiu, Patrick Gélin and Hélène Praliaud, et al. Reduction of NO by Propene over Supported Iridium Catalysts under Lean-Burn Conditions: an in Situ FTIR Study. Applied Catalysis A: General. 2004, 263(5): 39~48
116 Jong Yeol Jeon, Hee Young Kim and Seong Ihl Woo. Selective Catalytic Reduction of NOx in Lean-Burn Engine Exhaust over a Pt/V/MCM-41 Catalyst. Applied Catalysis B: Environmental. 2003, 44(9): 311~323
117 G. Schaub, D. Unruh and J. Wang, et al. Kinetic Analysis of Selective Catalytic NOx Reduction (SCR) in a Catalytic Filter. Chemical Engineering and Processing, 2003, 42(5): 365~371
118 Hirofumi Ohtsuka. The Selective Catalytic Reduction of Nitrogen Oxides by Methane on Noble Metal-Loaded Sulfated Zirconia. Applied Catalysis B: Environmental. 2001, 33(10): 325~333
119 D. Niakolas, Ch. Andronikou and Ch. Papadopoulou, et al. Influence of Metal Oxides on the Catalytic Behavior of Au/Al2O3 for the Selective Reduction of NOx by Hydrocarbons. Catalysis Today. 2006, 112(3): 184~187
120 Mikaela Wallin, Neil Cruise and Uta Klement, et al. Preparation of Mn, Fe and Co Based Perovskite Catalysts Using Microemulsions. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2004, 238(5): 27~35
121 Javier Pérez-Ramírez and Freek Kapteijn. Effect of NO on the SCR of N2O with Propane over Fe-zeolites. Applied Catalysis B: Environmental. 2004, 47(2): 177~187
122 E S. Djerad, L. Tifouti and M. Crocoll, et al. Effect of Vanadia and Tungsten Loadings on the Physical and Chemical Characteristics of V2O5-WO3/TiO2 Catalysts. Journal of Molecular Catalysis A: Chemical. 2004, 208(2): 257~265
123 Chung Jongshik, Charles Junghanns and Dietmar Schlosser. Potential of Aquatic Fungi Derived from Diverse Freshwater Environments to Decolourize Synthetic Azo and Anthraquinone Dyes. Bioresource Technology. 2008, 99(3): 1225~1235
124 Hedi Ben Mansour, David Corroler and Daniel Barillier, et al. Evaluation of Genotoxicity and Pro-oxidant Effect of the Azo Dyes: Acids Yellow 17, Violet 7 and Orange 52, and of Their Degradation Products by Pseudomonas Putida mt-2. Food and Chemical Toxicology. 2007, 45(9): 1670~1677
125 L. Wojnárovits, T. Pálfi and E. Takács. Kinetics and Mechanism of Azo Dye Destruction in Advanced Oxidation Processes. Radiation Physics and Chemistry. 2007, 76(8-9): 1497~1501
126 Mustafa I?ik and Delia Teresa Sponza. Fate and Toxicity of Azo Dye Metabolites under Batch Long-term Anaerobic Incubations. Enzyme and Microbial Technology. 2007, 40(3): 934~939
127 A. Víg, K. Sirbiladze and H.J. Nagy, et al. The Light Stability of Azo Dyes and Dyeings V. The impact of the Atmosphere on the Light Stability of Dyings with Heterobifunctional Reactive Azo Dyes. Dyes and Pigments. 2007, 72: 16~22
128 Bor-Yann Chen. Toxicity Assessment of Aromatic Amines to Pseudomonas Luteola: Chemostat Pulse Technique and Dose–response Analysis. Process Biochemistry. 2006, 41(7): 1529~1538
129 ?eněk Novotny, Nicolina Dias and Anu Kapanen, et al. Comparative Use of Bacterial, Algal and Protozoan Tests to Study Toxicity of Azo- and Anthraquinone Dyes. Chemosphere. 2006, 63(6): 1436~1442
130 Robert Maas and Sanjeev Chaudhari. Adsorption and Biological Decolourization of Azo Dye Reactive Red 2 in Semicontinuous Anaerobic Reactors. Process Biochemistry. 2005, 40(2): 699~705
131 M. Muruganandham and M. Swaminathan. Decolourisation of Reactive Orange 4 by Fenton and Photo-Fenton Oxidation Technology. Dyes and Pigments. 2004, 63(12): 315~321
132 Mariana Neamtu, Ayfer Yediler and Ilie Siminiceanu, et al. Oxidation of Commercial Reactive Azo Dye Aqueous Solutions by the Photo-Fenton and Fenton-like Processes. Journal of Photochemistry and Photobiology A: Chemistry. 2003, 161(11): 87~93
133 Yolanda Flores, Roberto Flores and Alberto Alvarez Gallegos. Heterogeneous Catalysis in the Fenton-type System Reactive Black 5/H2O2. Journal of Molecular Catalysis A: Chemical. 2007, (10)
134 Bharat Lodha and Sanjeev Chaudhari. Optimization of Fenton-biological Rreatment Scheme for the Treatment of Aqueous Dye Solutions. Journal of Hazardous Materials. 2007, 148(9): 459~466
135 A. Riga, K. Soutsas and K. Ntampegliotis, et al. Papapolymerou, Effect of System Parameters and of Inorganic Salts on the Decolorization and Degradation of Procion H-exl Dyes. Comparison of H2O2/UV, Fenton, UV/Fenton, TiO2/UV and TiO2/UV/H2O2 Processes. Desalination. 2007, 211(6): 72~86
136 K. Selvam, M. Muruganandham and N. Sobana, et al. Enhancement of UV-assisted Photo-Fenton Degradation of Reactive Orange 4 Using TiO2-P25 Nanoparticles. Separation and Purification Technology. 2007, 54(4): 241~247
137 Sumandeep Kaur and Vasundhara Singh. TiO2 Mediated Photocatalytic Degradation Studies of Reactive Red 198 by UV Irradiation. Journal of Hazardous Materials. 2007, 141(3): 230~236
138 Il-Hyoung Cho and Kyung-Duk Zoh. Photocatalytic Degradation of Azo Dye (Reactive Red 120) in TiO2/UV System: Optimization and Modeling Using a Response Surface Methodology (RSM) Based on the Central Composite Design. Dyes and Pigments. 2007, 75: 533~543
139 Mohammad Hossein Habibi and Nasrin Talebian. Photocatalytic Degradation of an Azo Dye X6G in Water: A Comparative Study Using Nanostructured Indium tin Oxide and Titanium Oxide Thin Films. Dyes and Pigments. 2007, 73: 186~194
140 Xiwang Zhang, Guoting Li and Yizhong Wang. Microwave Assisted Photocatalytic Degradation of High Concentration Azo Dye Reactive Brilliant Red X-3B with Microwave Electrodeless Lamp as Light Source. Dyes and Pigments. 2007, 74: 536~544
141 Mohammad Hossein Habibi and Mojtaba Nasr-Esfahani. Preparation, Characterization and Photocatalytic Activity of a Novel Nanostructure Composite Film Derived from Nanopowder TiO2 and Sol–gel Process Using Organic Dispersant. Dyes and Pigments. 2007, 75: 714~722
142 Mohammad Hossein Habibi, Nasrin Talebian and Jong-Ha Choi. Characterization and Photocatalytic Activity of Nanostructured Indium tin Oxide Thin-film Electrode for Azo-dye Degradation. Thin Solid Films. 2006, 515(12): 1461~1469
143 V. López-Grimau and M.C. Gutiérrez. Decolourisation of Simulated Reactive Dyebath Effluents by Electrochemical Oxidation Assisted by UV Light. Chemosphere. 2006, 62(1): 106~112
144 Chen-Lu Yang and Jared McGarrahan. Electrochemical Coagulation for Textile Effluent Decolorization. Journal of Hazardous Materials. 2005, 127(12): 40~47
145 Patricia A. Carneiro, Marly E. Osugi and Jeosadaque J. Sene, et al. Evaluation of Color Removal and Degradation of a Reactive Textile Azo Dye onNanoporous TiO2 Thin-film Electrodes. Electrochimica Acta. 2004, 49(9): 3807~3820
146 Maria Valnice B. Zanoni, Jeosadaque J. Sene and Marc A. Anderson. Photoelectrocatalytic Degradation of Remazol Brilliant Orange 3R on Titanium Dioxide Thin-film Electrodes. Journal of Photochemistry and Photobiology A: Chemistry. 2003, 157(4): 55~63
147 Kyung Shik Yang, Guido Mul, Jin Seong Choi, Jacob A. Moulijn and Jong Shik Chung. Development of TiO2/Ti wire-mesh honeycomb for catalytic combustion of ethyl acetate in air. Applied Catalysis A: General. 2006, 1 (313):86~93
148 A.F. Pérez-Cadenas, S. Morales-Torres and F. Kapteijn, et al. Carbon-based Monolithic Supports for Palladium Catalysts: The Role of the Porosity in the Gas-Phase Total Combustion of M-xylene. Applied Catalysis B: Environmental. 2008, 77(1): 272~277
149 Barbara Kucharczyk and W?odzimierz Tylus. Effect of Pd Additive on the Activity of Monolithic LaMnO3-Based Catalysts for Methane Combustion. Catalysis Today. 2008, (1)
150 Barbara Kucharczyk and W?odzimierz Tylus. Partial Substitution of Lanthanum with Silver in the LaMnO3 Perovskite: Effect of the Modification on the Activity of Monolithic Catalysts in the Reactions of Methane and Carbon Oxide Oxidation. Applied Catalysis A: General. 2007, (11)
151 Shemin Zhu, Yuesong Shen and Jialei Wang, et al. Preparation and Performance of Al2 TiO5 -TiO2 -SiO2 Honeycomb Ceramics by Doping Rare Earth. Journal of Rare Earths. 2007, 25(8): 457~461
152 Dae Jung Kim, Namgoo Kang and Wang Geun Shim, et al. Isothermal Adsorption Equilibrium and Dynamics of Binary Mixture Gasoline Constituents on Honeycomb Monoliths. Chemical Engineering Journal. 2007, (4)
153 Wang Jianli, Cao Hongyan and Zhong Junbo, et al. Effect of Metal Oxide Doping into Ce0.5Zr0.5O2 on Catalytic Activity of MnOx/γ-Al2O3/Ce0.45Zr0.45M0.1Ox (M = Y, La, Mn) Honeycomb Catalysts. Journal of Rare Earths. 2007, 25(2): 111~113
154 E. García-Bordejé, M.J. Lázaro and R. Moliner, et al. Vanadium Supported on Carbon Coated Honeycomb Monoliths for the Selective Catalytic Reduction ofNO at Low Temperatures: Influence of the Oxidation Pre-treatment, Carbon, 2006, 44(3): 407~417
155 Gianpiero Groppi and Enrico Tronconi. Honeycomb Supports with High Thermal Conductivity for Gas/Solid Chemical Processes. Catalysis Today. 2005, 105(8): 297~304
156 Ki-Suk Chung, Zhidong Jiang and Bong-Seok Gill, et al. Chung.Oxidative decomposition of o-dichlorobenzene over V2O5/TiO2 catalyst washcoated onto wire-mesh honeycombs. Applied Catalysis A: General. 2002, 1-2(237):81~89
157 Enrico Tronconi, Gianpiero Groppi and Thorsten Boger, et al. Monolithic Catalysts with‘High Conductivity’Honeycomb Supports for Gas/Solid Exothermic Reactions: Characterization of the Heat-Transfer Properties. Chemical Engineering Science. 2004, 59(11-12): 4941~4949
158 Yansong Han, Hai Sheng Zeng and Naijia Guan. Thermal and Hydrothermal Stability of Monolithic TS-1/Cordierite Catalyst. Catalysis Communications. 2002, 3(6): 221~225
159 Silvester Tursiloadi, Hiroaki Imai and Hiroshi Hirashima. Preparation and Characterization of Mesoporous Titania–Alumina Ceramic by Modified Sol–gel Method. Journal of Non-Crystalline Solids. 2004, 350(12): 271~276
160 E. García-Bordejé, L. Calvillo and M. J. Lázaro, et al. Vanadium Supported on Carbon-Coated Monoliths for the SCR of NO at Low Temperature: Effect of Pore Structure. Applied Catalysis B: Environmental. 2004, 50(7): 235~242
161 E. García-Bordejé, M. J. Lázaro and R. Moliner, et al. Structure of Vanadium Oxide Supported on Mesoporous Carbon-coated Monoliths and Relationship with Its Catalytic Performance in the SCR of NO at Low Temperatures. Journal of Catalysis. 2004, 223(4): 395~403
162 Alicia V. Boix, Juan M. Zamaro and Eduardo A. Lombardo, et al. The Beneficial Effect of Silica on the Activity and Thermal Stability of PtCoFerrierite-washcoated Cordierite Monoliths for the SCR of NOx with CH4. Applied Catalysis B: Environmental. 2003, 46(10): 121~132
163 Sian-Jie Ciou, Kuan-Zong Fung and Kai-Wei Chiang. Behaviors and Mechanism of Electrolyte Electrophoresis during Electrophoretic Deposition. Journal of Power Sources. 2008, 175(1): 33~39
164 Kyung Shik Yang, Jin Seong Choi and Jong Shik Chung. Evaluation of wire-mesh honeycomb containing porous Al/Al2O3 layer for catalytic combustion of ethyl acetate in air. Catalysis Today. 2004, 2-3(97): 159~165
165 Kyung Shik Yang, Zhidong Jiang and Jong Shik Chung. Electrophoretically Al-coated wire mesh and its application for catalytic oxidation of 1,2-dichlorobenzene.Surface and Coatings Technology. 2003, 2-3(168):103~110
166 I. Mazzarino and A. A. Barresi. Catalytic Combustion of Voc Mixtures in a Monolithic Reactor. Catalysis Today. 1993, 17(5): 335~347
167 Nerea Burgos, María Paulis and M. Mirari Antxustegi, et al. Deep Oxidation of VOC Mixtures with Platinum Supported on Al2O3/Al Monoliths. Applied Catalysis B: Environmental.2002, 38(10): 251~258
168 Gaurav Mohanty, Laxmidhar Besra and Sarama Bhattacharjee, et al. Optimization of Electrophoretic Deposition of Alumina onto Steel Substrates from Its Suspension in Iso-propanol Using Statistical Design of Experiments. Materials Research Bulletin.2007, (7)
169 Kyung Shik Yang, Guido Mul and Jacob A. Moulijn. Electrochemical Generation of Hydrogen Peroxide Using Surface Area-Enhanced Ti-mesh Electrodes. Electrochimica Acta. 2007, 52(6): 6304~6309
170 Junhua Li, Jianjun Chen and Rui Ke, et al. Effects of Precursors on the Surface Mn Species and the Activities for NO Reduction over MnOx/TiO2 Catalysts. Catalysis Communications. 2007, 8(12): 1896~1900
171 Juan Antonio Martín, Malcolm Yates and Pedroávila, et al. Nitrous Oxide Formation in Low Temperature Selective Catalytic Reduction of Nitrogen Oxides with V2O5/TiO2 Catalysts. Applied Catalysis B: Environmental. 2007, 70(1): 330~334
172 S. Djerad, M. Crocoll and S. Kureti, et al. Effect of Oxygen Concentration on the NOx Reduction with Ammonia over V2O5–WO3/TiO2 Catalyst. Catalysis Today. 2006, 113(4): 208~214
173 Motonobu Kobayashi, Ryoji Kuma and Sinyuki Masaki, et al. TiO2-SiO2 and V2O5/TiO2-SiO2 Catalyst: Physico-chemical Characteristics and Catalytic Behavior in Selective Catalytic Reduction of NO by NH3. Applied Catalysis B: Environmental. 2005, 60(10): 173~179
174 Yuanjing Zheng, Anker Degn Jensen and Jan Erik Johnsson. Deactivation of V2O5-WO3-TiO2 SCR Catalyst at a Biomass-fired Combined Heat and Power Plant. Applied Catalysis B: Environmental. 2005, 60(10): 253~264
175 Khanh-Quang Tran, Pia Kilpinen and Narendra Kumar. In-situ Catalytic Abatement of NOx during Fluidized Bed Combustion—A Literature Study. Applied Catalysis B: Environmental. 2008, 78(1): 129~138
176 Miguel A.G. Hevia and Javier Pérez-Ramírez. Assessment of the Low-Temperature EnviNOx? Variant for Catalytic N2O Abatement over Steam-activated FeZSM-5. Applied Catalysis B: Environmental. 2008, 77(1): 248~254
177 In-Young Lee, Dong-Wha Kim and Jung-Bin Lee, et al. A Practical Scale Evaluation of Sulfated V2O5/TiO2 Catalyst from Metatitanic Acid for Selective Catalytic Reduction of NO by NH3. Chemical Engineering Journal. 2002, 90(12): 267~272
178 Ha Heon Phil, Maddigapu Pratap Reddy and Pullur Anil Kumar, et al. SO2 Resistant Antimony Promoted V2O5/TiO2 Catalyst for NH3-SCR of NOx at Low Temperatures. Applied Catalysis B: Environmental. 2008, 78(2): 301~308
179 Xinping Wang, Shanshan Yu and Hongliang Yang, et al. Selective Catalytic Reduction of NO by C2H2 over MoO3/HZSM-5. Applied Catalysis B: Environmental. 2007, 71(2): 246~253
180 S. Suárez, J.A. Martín and M. Yates, et al. N2O Formation in the Selective Catalytic Reduction of NOx with NH3 at Low Temperature on CuO-supported Monolithic Catalysts. Journal of Catalysis. 2005, 229(1): 227~236
181 Landong Li, Jixin Chen and Shujuan Zhang, et al. Selective Catalytic Reduction of Nitrogen Oxides from Exhaust of Lean Burn Engine over in Situ Synthesized Monolithic Cu–TS-1/cordierite. Catalysis Today. 2004, 90(7): 207~213
182 Jesús Blanco, Pedro Avila and Silvia Suárez, et al. CuO/NiO Monolithic Catalysts for NOx Removal from Nitric Acid Plant Flue Gas. Chemical Engineering Journal, 2004, 97(1): 1~9
183 A. Bahamonde, S. Campuzano and M. Yates, et al. Influence of Zirconia Raw Materials on the Development of DeNOx Monolithic Catalysts. Applied Catalysis B: Environmental. 2003, 44(9): 333~346
184 M. Muruganandham and M. Swaminathan.TiO2–UV Photocatalytic Oxidation of Reactive Yellow 14: Effect of Operational Parameters. Journal of Hazardous Materials. 2006, 135(7): 78~86
185 M. Muruganandham and M. Swaminathan. Advanced Ooxidative Decolourisation of Reactive Yellow 14 azo dye by UV/TiO2, UV/H2O2, UV/H2O2/Fe2+ Processes—a Comparative Study. Separation and Purification Technology. 2006, 48(3): 297~303
186 Igor Peternel, Natalija Koprivanac and Hrvoje Kusic. UV-based Processes for Reactive Azo Dye Mineralization. Water Research. 2006, 40(2): 525~532