丝胶蛋白棉纤维的制备及其性能研究
摘要
为了将丝胶应用于棉纤维的功能化改性,以赋予棉纤维及其制品蛋白质属性,本研究采用先将棉纤维进行选择性氧化,再利用氧化后纤维中的醛基与丝胶蛋白中的氨基反应将丝胶蛋白固着在棉纤维上,从而获得丝胶蛋白棉纤维。
本论文首先对氧化棉纤维及丝胶蛋白棉纤维的结构进行红外光谱分析,以说明丝胶蛋白棉纤维的制备原理和可行性。再分别考察了棉纤维及棉织物高碘酸钠选择性氧化的氧化程度、丝胶蛋白溶液的浓度、pH值、处理时间及处理温度等因素对丝胶蛋白棉纤维增重率和力学性能的影响,以获得合适的氧化棉丝胶蛋白处理工艺。最后研究了改性前后棉纤维的微观形态和聚集态结构,讨论了不同工艺条件对棉织物抗皱性能的影响,并对其吸水性、白度和染色性进行了测试分析。
研究结果表明,氧化棉纤维中的醛基可以与丝胶蛋白分子中氨基直接发生化学交联反应,形成共价键结合;氧化棉纤维经丝胶蛋白溶液处理后表面变得光滑平整;氧化棉纤维经丝胶蛋白溶液处理后结晶度无明显变化,其热稳定性有所提高;不同工艺条件下丝胶蛋白溶液处理对氧化棉的增重率有一定的影响,但其力学性能基本不变;与普通棉织物相比,丝胶蛋白棉织物的抗皱性和吸水性有所提高,其白度和染色性没有明显变化。
In order to achieve the protein property of cotton fiber, combinative ability between dialdehyde cellulose cotton fiber and sericin was studied in this paper. The sericin proteinic cotton fiber is expected to be obtained by treating the oxidized cotton fiber with sericin solution.
Cotton fiber was selectively oxidized with NaIO4 and then the oxidized cotton fiber was treated with sericin solution. The preparation principle and feasibility of sericin proteinic cotton fiber was proved by FT-IR. And effect of different factors, such as oxidized degree, concentration of sericin solution, pH value, treating time and temperature, on the weight and the tensile properties of cotton yarns/fabric were discussed in this paper. The morphology and structure of sericin proteinic cotton fiber were analyzed by means of SEM, XRD, TG and DSC. The wrinkle resistance of cotton fabrics coated with sericin under different processing conditions was also studied, as well as their hydroscopicity, colourability and whiteness.
The results show that sericin could be directly coated onto the oxidized cotton fiber without any other reagent and a covalence formed between amido and aldehyde group. After treating with sericin solution, the thermal stability of the oxidized cotton fiber improved and the surface became smooth, but the crystallinity changed little. The weight gain of oxidized cotton treated by sericin solution was also affected by the above mentioned factors, but their mechanical properties changed little. Sericin proteinic cotton fabrics showed better wrinkle resistance and hydroscopicity than original cotton fabric, meanwhile their colourability and whiteness changed little.
本论文首先对氧化棉纤维及丝胶蛋白棉纤维的结构进行红外光谱分析,以说明丝胶蛋白棉纤维的制备原理和可行性。再分别考察了棉纤维及棉织物高碘酸钠选择性氧化的氧化程度、丝胶蛋白溶液的浓度、pH值、处理时间及处理温度等因素对丝胶蛋白棉纤维增重率和力学性能的影响,以获得合适的氧化棉丝胶蛋白处理工艺。最后研究了改性前后棉纤维的微观形态和聚集态结构,讨论了不同工艺条件对棉织物抗皱性能的影响,并对其吸水性、白度和染色性进行了测试分析。
研究结果表明,氧化棉纤维中的醛基可以与丝胶蛋白分子中氨基直接发生化学交联反应,形成共价键结合;氧化棉纤维经丝胶蛋白溶液处理后表面变得光滑平整;氧化棉纤维经丝胶蛋白溶液处理后结晶度无明显变化,其热稳定性有所提高;不同工艺条件下丝胶蛋白溶液处理对氧化棉的增重率有一定的影响,但其力学性能基本不变;与普通棉织物相比,丝胶蛋白棉织物的抗皱性和吸水性有所提高,其白度和染色性没有明显变化。
In order to achieve the protein property of cotton fiber, combinative ability between dialdehyde cellulose cotton fiber and sericin was studied in this paper. The sericin proteinic cotton fiber is expected to be obtained by treating the oxidized cotton fiber with sericin solution.
Cotton fiber was selectively oxidized with NaIO4 and then the oxidized cotton fiber was treated with sericin solution. The preparation principle and feasibility of sericin proteinic cotton fiber was proved by FT-IR. And effect of different factors, such as oxidized degree, concentration of sericin solution, pH value, treating time and temperature, on the weight and the tensile properties of cotton yarns/fabric were discussed in this paper. The morphology and structure of sericin proteinic cotton fiber were analyzed by means of SEM, XRD, TG and DSC. The wrinkle resistance of cotton fabrics coated with sericin under different processing conditions was also studied, as well as their hydroscopicity, colourability and whiteness.
The results show that sericin could be directly coated onto the oxidized cotton fiber without any other reagent and a covalence formed between amido and aldehyde group. After treating with sericin solution, the thermal stability of the oxidized cotton fiber improved and the surface became smooth, but the crystallinity changed little. The weight gain of oxidized cotton treated by sericin solution was also affected by the above mentioned factors, but their mechanical properties changed little. Sericin proteinic cotton fabrics showed better wrinkle resistance and hydroscopicity than original cotton fabric, meanwhile their colourability and whiteness changed little.
引文
[1] 徐亚美主编. 纺织材料[M]. 北京:中国纺织出版社,1999.
[2] 姚穆主编. 纺织材料学[M]. 北京:中国纺织出版社,1990.
[3] 陈家楠. 纤维素结构研究进展[J]. 纤维素科学与技术,1993,1(4):1~11.
[4] Deluca L.B., Orr R.S. Crystallite orientation and spiral structure of cotton[J]. Polymer Sci, 1961, (54): 457~470.
[5] 陶灵虎,刘新,刘稳生,等. 棉纤维超微结构的研究[J]. 生物物理学报,2001,17(2):245~252.
[6] 樱田一郎 著,戴承渠,章潭莉 译.纤维的化学[M]. 纺织工业出版社,1982.
[7] Gardner, K. H, Blackwell, J. The structure of native cellulose. Biopolymer, 1974.
[8] 胡玉洁. 天然高分子材料改性与应用[M]. 化学工业出版社, 2003.
[9] 邬义明. 植物纤维化学[M]. 轻工业出版社, 1991.
[10] Atalla R H. .The structure of cellulose: recent development. In: Soltes E J., Wood and agricultural residues. Academic Press, New York, 1983.
[11] Blackwell, J. The macromolecular organization of cellulose and chitin. In: Brown R M. Jr. Cellulose and other nature polymer systems: biogenesis, structure and degradation. Plenum, New York, 1982.
[12] 高洁,汤烈贵. 纤维素科学[M]. 科学出版社, 1996.
[13] 许云辉. 选择性氧化法制备环境友好型功能棉纤维研究[D]. 苏州大学博士论文, 2006.
[14] 付丽红. 胶原蛋白与植物纤维素的结合机理及利用[D]. 四川大学博士论文, 2002.
[15] 陈家楠. 纤维素化学的现状与发展趋势[J]. 纤维素科学与技术,1995,3(1):1~10.
[16] 日本化学纤维协会技术部. 纤维素化学纤维新技术(上). 化纤月报, 1986,(7): 17～23.
[17] Davidson R. L. Handbook of water soluble gums, polysaccharides and their derivatives.2nd. Academic Press, New York and London, 1973.
[18] 魏述众. 生物化学[M]. 轻工业出版社, 1996.
[19] 陈宇岳,许云辉,王华锋.棉纤维绿色改性研究进展及其产品开发[J].纺织导报,2005,(1):1～4.
[20] 王鸿博,高卫东. 甲壳素及壳聚糖在纺织工业中的应用[J]. 纺织导报,2003(1):26-28.
[21] 叶全鑫. 壳聚糖在纺织品染整加工中的应用[J]. 丝绸技术,1999,7(2):22-28.
[22] Chong Yong-SIK, Lee Kwang-Keun, Klm Jin-Woo. Double press and antimicrobial finishing of cotton fabrics with a citric acid and chitosan treatment[J]. TRJ, 1998, 68(10):722.
[23] X.D.Liu, N.Nishi, S.Tokura, N.Sakairi. Chitosan coated cotton fiber: preparation and physical properties[J]. Carbohydrate Polymers, 2001(44):233-238.
[24] 陈宇岳. 丝绸和纤维技术的研究进展及发展趋势[J]. 第五届全国丝绸新产品开发论坛论文集.2002:10-18.
[25] 祝莹,杨宏. 丝素蛋白对棉纤维化学涂覆的研究(一)[J]. 印染,1993,19(5):5-10.
[26] 祝莹,杨宏. 丝素蛋白对棉纤维化学涂覆的研究(二)[J]. 印染,1993,19(6):5-8.
[27] 蒲宗耀,陈松. 纺织品中的甲醛问题[J]. 四川纺织科技,2003(6):38-40.
[28] 孙卫国,张迎晨. Tencel 织物的马来酸酐防皱整理[J]. 印染,2000(4):9-10.
[29] 武利顺,王庆瑞.纤维素的选择性氧化反应及其体系[J].人造纤维,2000(3):27～31.
[30] 孙宾,武利顺,梁伯润. 医用可吸收氧化纤维素及其氧化体系研究进展[J]. 中国纺织大学学报,2000,26(4):110-114.
[31] 杨之礼,王庆瑞,邬国铭.粘胶纤维工艺学[M]. 纺织工业出版社,1989.
[32] J.F.Kennedy,et al.Cellulose and its derivatives[J].Ellis Horwood Limited.1985,19.
[33] Emest L. Jackson, C.S. Hudson. Application of the cleavage type of oxidation by periodic acid to starch and cellulose[J]. Journal of the American Chemical Society, 1937,(59):2049.
[34] Edward C Yackel, William O Kenyon. The oxidation of cellulose by nitrogen dioxide[J]. Journal of the American Chemical Society, 1942, (64):121-127.
[35] 吉冈敏雄. 组织修复用纤维. 纤维学会志[J], 1998,(11):401.
[36] U.S. Patent NO. 4,347,056.
[37] 熊犍,叶君,吴奏谦,梁文芷. 羧酸纤维素的制备及其抗凝血性能的研究[J]. 功能高分子学报,1997,10(4):559-563.
[38] 冯亚青,刘燕,张晓东,李熙凤. 氧化纤维素的制备及吸附性能的研究[J]. 天津大学学报,2002,35(6):765-768.
[39] Jing Shibing, et al. Effect of chitosan-coated dialdehyde cellulose, a newly developed oral adsorbent on normal and chronic renal failure rats[J]. Journal of Nephrol Dialy Transplant, 1994, 3(2):83-88.
[40] 孔德领,俞耀庭,贾永会,彭小文. 纤维素固定化血红蛋白研究[J]. 高分子学报,1999,(2):221-226.
[41] Ung-Jin Kim, Shigenori Kuga. Ion-exchange chromatography by dicarboxyl cellulose gel[J]. Journal of Chromatography, 2001, 919:29-37.
[42] Ung-Jin Kim, Shigenori Kuga. Ion-exchange separation of proteins by polyallylamine-grafted cellulose gel[J]. Journal of Chromatography, 2002, 955:191-196.
[43] Simona Margutti, Silvia Vicini, Noemi Proietti, et al. Physical-chemical characterisation of acrylic polymers grafted on cellulose[J]. Polymer, 2002, 43:6183-6194.
[44] A.J. Varma, V.B. Chavan. Calcium complexation by low molecular weight dicarboxycellulose in aqueous solution[J]. Carbohydrate Polymers, 2001, 45:101-103.
[45] Premamay Ghosh, Debaprasad Dev. Graft copolymerization of mixtures of acrylamide and methyl methacrylate on dialdehyde cellulose(DAC) from cotton in a limited aqueous system[J]. European Polymer Journal, 1996, 32(2):165-171.
[46] 陈华,朱良均,闵思佳等.蚕丝丝胶蛋白的利用研究[J].东华大学学报,2002(3):132～135.
[47] Zhu L. J.,Arai M., Hirabayayhi Kiyshi.Relationship between adhesive provities and structure of sericin in cocoon filaments[J].J Seric Sci Jpn,1995,64(5):420～426.
[48] 小松计一 著,周晦若 译.丝胶溶解特性和结构特性的研究[M].四川省绵阳地区纺织工程学会.
[49] 周宏湘.纤维用丝胶改性加工技术的进展[J].丝绸,1995(1):23～25.
[50] 盛家镛,林红,王磊,等.易溶性丝胶粉的微细结构及理化性能研究[J].丝绸,2000(6):6～9.
[51] 陈华,朱良均,闵思佳,等.蚕丝丝胶蛋白的结构、性能及利用[J].功能高分子学报,2001(3):344～347.
[52] 陈文兴,尤奇,刘冠峰,等.丝胶研究的一些进展[J].丝绸,1995(6):13～15.
[53] Yu-Qing Zhang. Applications of natural silk protein sericin in biomaterials. Biotechnology Advances, 2002(20): 91～100.
[54] 纪佩珍.丝胶改性聚酯和聚酰氨纤维吸放湿的研究[J].浙江丝绸工学院学报,1994(2):23～26.
[55] Norinisa Kato,SeijiSato,Atsushi Yamanaka,et al.Silk protein,sericin,inhibits lipid peroxidation and tryosinase activity[J].Biosci BiotechnolBiochem,1998,62(1):145～147.
[56] Sasaki M,Yamada H,Kato N. Consumption of silk protein,sericin elevates intestinal absorption of zinc,iron,magnesium and calcium in rats[J].Nutrition Research.2000,20(10):1505～1511.
[57] Sasaki M,Kato N., Watanabe H,et a1. Silk protein,scricin,suppresses colon carcinogenesis induced by1,2-dimethylhydrazine in mice[J].Oncology Reports,2000,7(5):1049～1052.
[58] Kato N,Kayashita J,Sasaki M.Physiological functions of buckwheat protein and sericin as resistant proteins[J].Journal of the Japanese Society of Nutrition and Food Science,2000,53(2):71～75.
[59] Minora N,Aiba S,Gotoh Y,et a1.Attachment and growth of cultured fibroblast cells on silk protein matrices[J].Journal of Biomedical Materials Research.1995,29(10):1215～1221.
[60] Sachio Miyairi,Masaaki Sugiura.Properties β-glucosidase immobilized in sericin membrance[J].Journal of Ferment Technology,1978,56(4):303～308.
[61] 唐蜀忠,李午辰,易飞,等.丝胶用作固井水泥浆外加剂的室内初步研究[J].油田化学,1989,6(2):156～158.
[62] 阳建斌,朱谱新,杨红伟,等.丝胶蛋白质溶液的动态表面吸附过程[J].纺织学报,2007,28(5):18～22.
[63] Yu-Qing Zhang, Yan Ma, Yun-Yue Xia, et al. Silk sericin-insulin bioconjugates: Synthesis,characterization and biological activity[J]. Journal of Controlled Release, 2006(115):307～315.
[64] 许云辉,陈宇岳,林红.氧化纤维素的研究进展及发展趋势[J]. 苏州大学学报(工科版),2006,26(2):1-6.
[65] 赵希荣,夏文水.高碘酸钠氧化棉布纤维反应条件的研究[J].纤维素科学与技术,2003,(11):17～21.
[66] A.J. Varma, M. P. Kulkarni. Oxidation of cellulose under controlled conditions [J] . Polymer Degradation and Stability, 2002, (77): 25～27.
[67] 谢瑞娟,邢铁玲,谢丽莹.丝胶蛋白用于涤纶织物改性的研究[J].丝绸,2002(11):14～16.
[68] 许云辉,陈宇岳,黄晨.胶原蛋白涂覆棉纤维的研究[J].纺织学报,2007,28(5):23-27.
[69] Arunee Kongdee, Thomas Bechtold, Linda Teufel. Modification of cellulose fiber with silk sericin[J].Journal of Applied Polymer Science.2005,96(4):1421～1428.
[70] 罗伯特 D·布朗著. 最新仪器分析技术全书[M].化学工业出版社.
[71] Marte R L, Owens M L. Rapid determination of carbonyl content in acrylonitrile[J]. Anal Chem., 1956, (28):1312-1314.
[72] 钱军民,李旭祥. 高碘酸钠氧化纤维素的研究[J]. 现代化工,2001,21(7):27-30.
[73] Fabiana S, Attilio C. The Kinetics of periodate oxidation of carbohydrates: a calorimetric approach[ J]. Carbohydrate Research, 2000, (329):87～95.
[74] Ung J K, Shigenori K. Thermal decomposition of dialdehyde cellulose and its nitrogen containing derivatives[ J]. Thermochimica Acta, 2001, (369):79～85.
[75] 许云辉,林红,陈宇岳.选择性氧化棉纤维的聚集态结构[J].纺织学报,2006,27(11):1～5.
[76] 许云辉,黄晨,陈宇岳,等.棉纤维经胶原蛋白涂覆处理后的结构[J].纺织学报,2007,28(6):1～4.
[77] Stefano Tiziani, Fabiana Sussich, Attilio Cesaro. The Kinetics of periodate oxidation of carbohydrates 2. Polymeric substrates[J]. Carbohydrate Research, 2003, (338): 1083~1095.
[78] Hannes Sihtola. Chemical Properties of Modified Celluloses[J]. Macromolecular Chemistry and Physics, 1960,35(1):250-265.
[79] 李栋高,蒋蕙钧 编著.丝绸材料学[M].中国纺织出版社,1994.
[80] 朱宜等.扫描电镜图象的形成处理和显微分析[M].北京大学出版社.
[81] 李汝勤等.纤维和纺织品的测试原理与仪器[M].中国纺织大学出版社.
[82] 陈烯等.化学纤维实验教程[M].纺织工业出版社.
[83] 马礼敦.高等结构分析[M].复旦大学出版社.
[84] 潘志娟 主编.纤维材料近代测试技术[M].中国纺织出版社.
[85] Cuiyu Yin. Jianbo Li. Qun Xu.et al. Chemical modification of cotton cellulose in supercritical carbon dioxide:Synthesis and characterization of cellulose carbamate[J]. Carbohydrate Polymers. 2007, 67:147～154.
[86] 熊犍,叶君,梁文芷.二醛纤维素储能材料的研究[J].新能源,1998,20(4):9～12.
[87] 姚理荣,林红,陈宇岳.经胶原蛋白处理的氧化棉性状比较[J].苏州科技学院学报,2007,20(2):70～74.
[88] 张雨青.丝胶在功能性材料、纤维及织物上的应用[J].纺织学报,2002,23(3):243～245.
[89] 李辉芹.丝胶在纺织品整理中的应用[J].江苏丝绸,2005(3):9～11.
[90] 纤维学会志,2001(10).
[91] 何中琴 译,钱镇海 校.丝胶的再开发和在纤维上的应用[J].国外丝绸,2002(5):19～23.
[92] 野村正和等.纤维复合体[P]. 公开特许公报,1996:08-058006.
[93] 森一雄等.吸收性物品[P]. 公开特许公报,1997:09-322911.
[94] 陈丽华.超细纤维毛巾织物的结构和吸水性分析[J].针织工业,2005(6):59～60.
[95] 陈英 主编. 染整工艺实验教程[M]. 北京:中国纺织出版社,2004:2-26.
[96] 王健.丝胶整理剂对棉织物抗皱性能的影响[J].纺织科技进展,2005,(5):57-58.
[97] 潘福奎,潘廷松,王善元.利用丝胶改善棉织物洗后平整度的研究[J].青岛大学学报,2004,19(2):51～53.
[98] Fujie Kurroka, Akira Kurioka, Akir Aoki, et al. Fixation of sericin on cotton fabrio via crosslinking with citric acid[J].日蚕杂,2004(2,3):83～87.
[99] 金建平,乔海燕,邵卫东,等.织物丝胶/甲壳素改性舒适卫生整理技术研究[J].丝绸,2004(1):22～23.
[2] 姚穆主编. 纺织材料学[M]. 北京:中国纺织出版社,1990.
[3] 陈家楠. 纤维素结构研究进展[J]. 纤维素科学与技术,1993,1(4):1~11.
[4] Deluca L.B., Orr R.S. Crystallite orientation and spiral structure of cotton[J]. Polymer Sci, 1961, (54): 457~470.
[5] 陶灵虎,刘新,刘稳生,等. 棉纤维超微结构的研究[J]. 生物物理学报,2001,17(2):245~252.
[6] 樱田一郎 著,戴承渠,章潭莉 译.纤维的化学[M]. 纺织工业出版社,1982.
[7] Gardner, K. H, Blackwell, J. The structure of native cellulose. Biopolymer, 1974.
[8] 胡玉洁. 天然高分子材料改性与应用[M]. 化学工业出版社, 2003.
[9] 邬义明. 植物纤维化学[M]. 轻工业出版社, 1991.
[10] Atalla R H. .The structure of cellulose: recent development. In: Soltes E J., Wood and agricultural residues. Academic Press, New York, 1983.
[11] Blackwell, J. The macromolecular organization of cellulose and chitin. In: Brown R M. Jr. Cellulose and other nature polymer systems: biogenesis, structure and degradation. Plenum, New York, 1982.
[12] 高洁,汤烈贵. 纤维素科学[M]. 科学出版社, 1996.
[13] 许云辉. 选择性氧化法制备环境友好型功能棉纤维研究[D]. 苏州大学博士论文, 2006.
[14] 付丽红. 胶原蛋白与植物纤维素的结合机理及利用[D]. 四川大学博士论文, 2002.
[15] 陈家楠. 纤维素化学的现状与发展趋势[J]. 纤维素科学与技术,1995,3(1):1~10.
[16] 日本化学纤维协会技术部. 纤维素化学纤维新技术(上). 化纤月报, 1986,(7): 17～23.
[17] Davidson R. L. Handbook of water soluble gums, polysaccharides and their derivatives.2nd. Academic Press, New York and London, 1973.
[18] 魏述众. 生物化学[M]. 轻工业出版社, 1996.
[19] 陈宇岳,许云辉,王华锋.棉纤维绿色改性研究进展及其产品开发[J].纺织导报,2005,(1):1～4.
[20] 王鸿博,高卫东. 甲壳素及壳聚糖在纺织工业中的应用[J]. 纺织导报,2003(1):26-28.
[21] 叶全鑫. 壳聚糖在纺织品染整加工中的应用[J]. 丝绸技术,1999,7(2):22-28.
[22] Chong Yong-SIK, Lee Kwang-Keun, Klm Jin-Woo. Double press and antimicrobial finishing of cotton fabrics with a citric acid and chitosan treatment[J]. TRJ, 1998, 68(10):722.
[23] X.D.Liu, N.Nishi, S.Tokura, N.Sakairi. Chitosan coated cotton fiber: preparation and physical properties[J]. Carbohydrate Polymers, 2001(44):233-238.
[24] 陈宇岳. 丝绸和纤维技术的研究进展及发展趋势[J]. 第五届全国丝绸新产品开发论坛论文集.2002:10-18.
[25] 祝莹,杨宏. 丝素蛋白对棉纤维化学涂覆的研究(一)[J]. 印染,1993,19(5):5-10.
[26] 祝莹,杨宏. 丝素蛋白对棉纤维化学涂覆的研究(二)[J]. 印染,1993,19(6):5-8.
[27] 蒲宗耀,陈松. 纺织品中的甲醛问题[J]. 四川纺织科技,2003(6):38-40.
[28] 孙卫国,张迎晨. Tencel 织物的马来酸酐防皱整理[J]. 印染,2000(4):9-10.
[29] 武利顺,王庆瑞.纤维素的选择性氧化反应及其体系[J].人造纤维,2000(3):27～31.
[30] 孙宾,武利顺,梁伯润. 医用可吸收氧化纤维素及其氧化体系研究进展[J]. 中国纺织大学学报,2000,26(4):110-114.
[31] 杨之礼,王庆瑞,邬国铭.粘胶纤维工艺学[M]. 纺织工业出版社,1989.
[32] J.F.Kennedy,et al.Cellulose and its derivatives[J].Ellis Horwood Limited.1985,19.
[33] Emest L. Jackson, C.S. Hudson. Application of the cleavage type of oxidation by periodic acid to starch and cellulose[J]. Journal of the American Chemical Society, 1937,(59):2049.
[34] Edward C Yackel, William O Kenyon. The oxidation of cellulose by nitrogen dioxide[J]. Journal of the American Chemical Society, 1942, (64):121-127.
[35] 吉冈敏雄. 组织修复用纤维. 纤维学会志[J], 1998,(11):401.
[36] U.S. Patent NO. 4,347,056.
[37] 熊犍,叶君,吴奏谦,梁文芷. 羧酸纤维素的制备及其抗凝血性能的研究[J]. 功能高分子学报,1997,10(4):559-563.
[38] 冯亚青,刘燕,张晓东,李熙凤. 氧化纤维素的制备及吸附性能的研究[J]. 天津大学学报,2002,35(6):765-768.
[39] Jing Shibing, et al. Effect of chitosan-coated dialdehyde cellulose, a newly developed oral adsorbent on normal and chronic renal failure rats[J]. Journal of Nephrol Dialy Transplant, 1994, 3(2):83-88.
[40] 孔德领,俞耀庭,贾永会,彭小文. 纤维素固定化血红蛋白研究[J]. 高分子学报,1999,(2):221-226.
[41] Ung-Jin Kim, Shigenori Kuga. Ion-exchange chromatography by dicarboxyl cellulose gel[J]. Journal of Chromatography, 2001, 919:29-37.
[42] Ung-Jin Kim, Shigenori Kuga. Ion-exchange separation of proteins by polyallylamine-grafted cellulose gel[J]. Journal of Chromatography, 2002, 955:191-196.
[43] Simona Margutti, Silvia Vicini, Noemi Proietti, et al. Physical-chemical characterisation of acrylic polymers grafted on cellulose[J]. Polymer, 2002, 43:6183-6194.
[44] A.J. Varma, V.B. Chavan. Calcium complexation by low molecular weight dicarboxycellulose in aqueous solution[J]. Carbohydrate Polymers, 2001, 45:101-103.
[45] Premamay Ghosh, Debaprasad Dev. Graft copolymerization of mixtures of acrylamide and methyl methacrylate on dialdehyde cellulose(DAC) from cotton in a limited aqueous system[J]. European Polymer Journal, 1996, 32(2):165-171.
[46] 陈华,朱良均,闵思佳等.蚕丝丝胶蛋白的利用研究[J].东华大学学报,2002(3):132～135.
[47] Zhu L. J.,Arai M., Hirabayayhi Kiyshi.Relationship between adhesive provities and structure of sericin in cocoon filaments[J].J Seric Sci Jpn,1995,64(5):420～426.
[48] 小松计一 著,周晦若 译.丝胶溶解特性和结构特性的研究[M].四川省绵阳地区纺织工程学会.
[49] 周宏湘.纤维用丝胶改性加工技术的进展[J].丝绸,1995(1):23～25.
[50] 盛家镛,林红,王磊,等.易溶性丝胶粉的微细结构及理化性能研究[J].丝绸,2000(6):6～9.
[51] 陈华,朱良均,闵思佳,等.蚕丝丝胶蛋白的结构、性能及利用[J].功能高分子学报,2001(3):344～347.
[52] 陈文兴,尤奇,刘冠峰,等.丝胶研究的一些进展[J].丝绸,1995(6):13～15.
[53] Yu-Qing Zhang. Applications of natural silk protein sericin in biomaterials. Biotechnology Advances, 2002(20): 91～100.
[54] 纪佩珍.丝胶改性聚酯和聚酰氨纤维吸放湿的研究[J].浙江丝绸工学院学报,1994(2):23～26.
[55] Norinisa Kato,SeijiSato,Atsushi Yamanaka,et al.Silk protein,sericin,inhibits lipid peroxidation and tryosinase activity[J].Biosci BiotechnolBiochem,1998,62(1):145～147.
[56] Sasaki M,Yamada H,Kato N. Consumption of silk protein,sericin elevates intestinal absorption of zinc,iron,magnesium and calcium in rats[J].Nutrition Research.2000,20(10):1505～1511.
[57] Sasaki M,Kato N., Watanabe H,et a1. Silk protein,scricin,suppresses colon carcinogenesis induced by1,2-dimethylhydrazine in mice[J].Oncology Reports,2000,7(5):1049～1052.
[58] Kato N,Kayashita J,Sasaki M.Physiological functions of buckwheat protein and sericin as resistant proteins[J].Journal of the Japanese Society of Nutrition and Food Science,2000,53(2):71～75.
[59] Minora N,Aiba S,Gotoh Y,et a1.Attachment and growth of cultured fibroblast cells on silk protein matrices[J].Journal of Biomedical Materials Research.1995,29(10):1215～1221.
[60] Sachio Miyairi,Masaaki Sugiura.Properties β-glucosidase immobilized in sericin membrance[J].Journal of Ferment Technology,1978,56(4):303～308.
[61] 唐蜀忠,李午辰,易飞,等.丝胶用作固井水泥浆外加剂的室内初步研究[J].油田化学,1989,6(2):156～158.
[62] 阳建斌,朱谱新,杨红伟,等.丝胶蛋白质溶液的动态表面吸附过程[J].纺织学报,2007,28(5):18～22.
[63] Yu-Qing Zhang, Yan Ma, Yun-Yue Xia, et al. Silk sericin-insulin bioconjugates: Synthesis,characterization and biological activity[J]. Journal of Controlled Release, 2006(115):307～315.
[64] 许云辉,陈宇岳,林红.氧化纤维素的研究进展及发展趋势[J]. 苏州大学学报(工科版),2006,26(2):1-6.
[65] 赵希荣,夏文水.高碘酸钠氧化棉布纤维反应条件的研究[J].纤维素科学与技术,2003,(11):17～21.
[66] A.J. Varma, M. P. Kulkarni. Oxidation of cellulose under controlled conditions [J] . Polymer Degradation and Stability, 2002, (77): 25～27.
[67] 谢瑞娟,邢铁玲,谢丽莹.丝胶蛋白用于涤纶织物改性的研究[J].丝绸,2002(11):14～16.
[68] 许云辉,陈宇岳,黄晨.胶原蛋白涂覆棉纤维的研究[J].纺织学报,2007,28(5):23-27.
[69] Arunee Kongdee, Thomas Bechtold, Linda Teufel. Modification of cellulose fiber with silk sericin[J].Journal of Applied Polymer Science.2005,96(4):1421～1428.
[70] 罗伯特 D·布朗著. 最新仪器分析技术全书[M].化学工业出版社.
[71] Marte R L, Owens M L. Rapid determination of carbonyl content in acrylonitrile[J]. Anal Chem., 1956, (28):1312-1314.
[72] 钱军民,李旭祥. 高碘酸钠氧化纤维素的研究[J]. 现代化工,2001,21(7):27-30.
[73] Fabiana S, Attilio C. The Kinetics of periodate oxidation of carbohydrates: a calorimetric approach[ J]. Carbohydrate Research, 2000, (329):87～95.
[74] Ung J K, Shigenori K. Thermal decomposition of dialdehyde cellulose and its nitrogen containing derivatives[ J]. Thermochimica Acta, 2001, (369):79～85.
[75] 许云辉,林红,陈宇岳.选择性氧化棉纤维的聚集态结构[J].纺织学报,2006,27(11):1～5.
[76] 许云辉,黄晨,陈宇岳,等.棉纤维经胶原蛋白涂覆处理后的结构[J].纺织学报,2007,28(6):1～4.
[77] Stefano Tiziani, Fabiana Sussich, Attilio Cesaro. The Kinetics of periodate oxidation of carbohydrates 2. Polymeric substrates[J]. Carbohydrate Research, 2003, (338): 1083~1095.
[78] Hannes Sihtola. Chemical Properties of Modified Celluloses[J]. Macromolecular Chemistry and Physics, 1960,35(1):250-265.
[79] 李栋高,蒋蕙钧 编著.丝绸材料学[M].中国纺织出版社,1994.
[80] 朱宜等.扫描电镜图象的形成处理和显微分析[M].北京大学出版社.
[81] 李汝勤等.纤维和纺织品的测试原理与仪器[M].中国纺织大学出版社.
[82] 陈烯等.化学纤维实验教程[M].纺织工业出版社.
[83] 马礼敦.高等结构分析[M].复旦大学出版社.
[84] 潘志娟 主编.纤维材料近代测试技术[M].中国纺织出版社.
[85] Cuiyu Yin. Jianbo Li. Qun Xu.et al. Chemical modification of cotton cellulose in supercritical carbon dioxide:Synthesis and characterization of cellulose carbamate[J]. Carbohydrate Polymers. 2007, 67:147～154.
[86] 熊犍,叶君,梁文芷.二醛纤维素储能材料的研究[J].新能源,1998,20(4):9～12.
[87] 姚理荣,林红,陈宇岳.经胶原蛋白处理的氧化棉性状比较[J].苏州科技学院学报,2007,20(2):70～74.
[88] 张雨青.丝胶在功能性材料、纤维及织物上的应用[J].纺织学报,2002,23(3):243～245.
[89] 李辉芹.丝胶在纺织品整理中的应用[J].江苏丝绸,2005(3):9～11.
[90] 纤维学会志,2001(10).
[91] 何中琴 译,钱镇海 校.丝胶的再开发和在纤维上的应用[J].国外丝绸,2002(5):19～23.
[92] 野村正和等.纤维复合体[P]. 公开特许公报,1996:08-058006.
[93] 森一雄等.吸收性物品[P]. 公开特许公报,1997:09-322911.
[94] 陈丽华.超细纤维毛巾织物的结构和吸水性分析[J].针织工业,2005(6):59～60.
[95] 陈英 主编. 染整工艺实验教程[M]. 北京:中国纺织出版社,2004:2-26.
[96] 王健.丝胶整理剂对棉织物抗皱性能的影响[J].纺织科技进展,2005,(5):57-58.
[97] 潘福奎,潘廷松,王善元.利用丝胶改善棉织物洗后平整度的研究[J].青岛大学学报,2004,19(2):51～53.
[98] Fujie Kurroka, Akira Kurioka, Akir Aoki, et al. Fixation of sericin on cotton fabrio via crosslinking with citric acid[J].日蚕杂,2004(2,3):83～87.
[99] 金建平,乔海燕,邵卫东,等.织物丝胶/甲壳素改性舒适卫生整理技术研究[J].丝绸,2004(1):22～23.