磷酸三甲酯与醇、水混合体系的热力学研究
|
摘要
本文对磷酸三甲酯(TMP)与脂肪醇、水混合体系的热力学性质进行了研究。
用TAM Air恒温量热仪测量了{TMP+甲醇/乙醇/正丙醇/正丁醇}及{TMP+水}五个二元体系在298.15 K和常压下的超额混合焓H_m~E,实验结果用Redlich-Kister多元方程进行拟合,并考察了方程各项对体系焓值的贡献。
在{TMP+醇}二元系中,实验测定的混合焓值在实验浓度范围内均为正值,即混合过程为吸热效应,焓值变化体现一定的规律性,随着醇类物质碳原子个数的增加,超额混合焓值增大。对于{TMP+甲醇}体系,混合焓的最大值出现在X_(TMP)=0.30处,而其余三个体系的最大值出现在X_(TMP)=0.42处,体现了相对较好的对称性。{TMP+水}体系的超额混合焓在不同组成时均为负值,混合过程体现放热效应;混合物的红外光谱表明,TMP与醇分子、水分子之间形成了分子间氢键;对二元混合体系建立了热力学模型,考察了物理作用及化学作用对体系混合焓的贡献。
测量了{TMP+水+甲醇/乙醇}三元混合物在298.15K和常压下的超额混合焓H_m~E,采用经验公式对三元体系超额混合焓进行拟合,经最小二乘法求得拟合参数,得到了在298.15K时三元体系超额混合焓H_(m,123)~E与各组分组成之间的关系,并绘制了三元系的等焓图。
The thermodynamic properties of trimethyl phosphate mixed with n-alkanols or water have been investigated in this paper.
The excess molar enthalpies of binary mixtures for {Trimethyl Phosphate(TMP) + Methanol/Ethanol/Propan-1-ol/Butan-1-ol} were measured with a TAM Air Isothermal calorimeter at 298.15 K and atmospheric pressure.The experimental results have been correlated with the Redlish-Kister polynomial,and dissociated by the iterations of the Redlish-Kister polynomial.
The H_m~E for {xTMP+(1-x)Alkanol} are positive in the whole range of composition,which indiate that the mixing process are endothermic.There is some regularity with the excess molar enthalpies in that the alkanol molecule increases with the number of carbon atom.
When the x_((TMP))equals 0.30,the H_m~E value reaches maximum for {xTMP+(1-x)CH3OH},but for the other three systems,the maximum values appear when x_((TMP))=0.42,with a better symmetry.The H_m~E for {xTMP+(1-x)water} are negative in the whole range of composition,indiate that the mixing process are exothermic.IR spectra of the mixtures indicate the existence of hydrogen bonding between TMP and alkanols or water in the mixtures.The thermodynamic model for binary mixtures of {TMP+Methanol/Ethanol/Propan-1-ol/ Butan-1-ol/Water} provides the contributions of physical action and chemistry action.
The excess molar enthalpies of ternary mixtures for {x_1TMP+x_2CH_3OH+ (1-x_1-x_2)H_2O} and {x_1TMP+x_2C_2H_5OH+(1-x_1-x_2)H_2O} were measured on the same conditions;The experimental results have been correlated with the experiential equation;Constant H_(m.123)~E contours at 298.15 K are plotted by using the method of least-squares.
用TAM Air恒温量热仪测量了{TMP+甲醇/乙醇/正丙醇/正丁醇}及{TMP+水}五个二元体系在298.15 K和常压下的超额混合焓H_m~E,实验结果用Redlich-Kister多元方程进行拟合,并考察了方程各项对体系焓值的贡献。
在{TMP+醇}二元系中,实验测定的混合焓值在实验浓度范围内均为正值,即混合过程为吸热效应,焓值变化体现一定的规律性,随着醇类物质碳原子个数的增加,超额混合焓值增大。对于{TMP+甲醇}体系,混合焓的最大值出现在X_(TMP)=0.30处,而其余三个体系的最大值出现在X_(TMP)=0.42处,体现了相对较好的对称性。{TMP+水}体系的超额混合焓在不同组成时均为负值,混合过程体现放热效应;混合物的红外光谱表明,TMP与醇分子、水分子之间形成了分子间氢键;对二元混合体系建立了热力学模型,考察了物理作用及化学作用对体系混合焓的贡献。
测量了{TMP+水+甲醇/乙醇}三元混合物在298.15K和常压下的超额混合焓H_m~E,采用经验公式对三元体系超额混合焓进行拟合,经最小二乘法求得拟合参数,得到了在298.15K时三元体系超额混合焓H_(m,123)~E与各组分组成之间的关系,并绘制了三元系的等焓图。
The thermodynamic properties of trimethyl phosphate mixed with n-alkanols or water have been investigated in this paper.
The excess molar enthalpies of binary mixtures for {Trimethyl Phosphate(TMP) + Methanol/Ethanol/Propan-1-ol/Butan-1-ol} were measured with a TAM Air Isothermal calorimeter at 298.15 K and atmospheric pressure.The experimental results have been correlated with the Redlish-Kister polynomial,and dissociated by the iterations of the Redlish-Kister polynomial.
The H_m~E for {xTMP+(1-x)Alkanol} are positive in the whole range of composition,which indiate that the mixing process are endothermic.There is some regularity with the excess molar enthalpies in that the alkanol molecule increases with the number of carbon atom.
When the x_((TMP))equals 0.30,the H_m~E value reaches maximum for {xTMP+(1-x)CH3OH},but for the other three systems,the maximum values appear when x_((TMP))=0.42,with a better symmetry.The H_m~E for {xTMP+(1-x)water} are negative in the whole range of composition,indiate that the mixing process are exothermic.IR spectra of the mixtures indicate the existence of hydrogen bonding between TMP and alkanols or water in the mixtures.The thermodynamic model for binary mixtures of {TMP+Methanol/Ethanol/Propan-1-ol/ Butan-1-ol/Water} provides the contributions of physical action and chemistry action.
The excess molar enthalpies of ternary mixtures for {x_1TMP+x_2CH_3OH+ (1-x_1-x_2)H_2O} and {x_1TMP+x_2C_2H_5OH+(1-x_1-x_2)H_2O} were measured on the same conditions;The experimental results have been correlated with the experiential equation;Constant H_(m.123)~E contours at 298.15 K are plotted by using the method of least-squares.
引文
[1]胡英.流体的分子热力学.北京:高等教育出版社,1983:310-459
[2]黄子卿.非电介质溶液理论导论.北京:科学出版社,1973:1-13
[3]童景山,高光华,刘裕品.化工热力学.北京:清华大学出版社,1995:225-229
[4]张平民主编.工科大学化学.长沙:湖南教育出版社,2002:278-279
[5]章丽辉,沈小燕,刘国杰.含醇溶液的热力学研究.化学学报,2002,60(1):617-621
[6]Dipl-Ing K Nolker,Dr.-Ing M Roth.Modified UNIFAC parameters for mixtureswith isocyanates.Chemical Engineering Science,1998,53:2395-2401
[7]Antonio M Peres,Eugenia A Macedo.Prediction of thermodynamic properties using a modified UNIFAC model:application to sugar industrial systems.FluidPhase Equilibriu.1999,158:391-399
[8]沈晓燕,刘国杰.二元液体混合物的过量体积模型.化工学报,2004,55(7):1041-1046
[9]陈海松,王文昌,王福安.关联二元体系超额混合焓的改进模型.化工学报,2005,56(5):757-762
[10]Pitzer K S,Peiper J C.Activity coefficient of aqueous NaHCO_3.Journal of Physical Chemisty,1980,84(19):2396-2398
[11]Renon H,Pransnutz J M.Local Compositions in Thermodynamic Excess Functions for liquid mixtures.AIChE Journal,1968,14(1):135-144
[12]Nagata I,Tamura K,Excess molar enthalpies of chlorobenzene +methanol,+acetonitrible,and +ethanol,and of(acetonitrile+chlorobenzens+methanol and+ethanol at 298.15 K.J.Chem.Thermodyn.,1986,18(1):39-44
[13]Heintz A,Kulikov D V,Verevkin Sergey P.Thermodynamic properties of mixtures containing ionic liquids.Activity coefficients at infinite dilution of polar solutes in 4-methyl-N-butyl-pyridinium tetrafluoroborate using gas-liquid chromatography.Journal of Chemical Thermodynamics,2002,34(7):1341-1347
[14]Browarzik D,Laux H,Rahimian I.Asphaltene flocculation in crude oil systems.Fluid Phase Equilibria,1999,154:285-300
[15]James C Young Jr,Jesse S Binford Jr,Scott W Campbell.Excess enthalpies of five pentanol isomer+n-heptane systems measured at 303.15 K and a model describing the behavior.Fluid Phase Equilibria,2003,209:255-264
[16]Satoru Kato,Daisuke Hoshino,Hidetaka Noritomi,Kunio Nagahama.Prediction of activity coefficients using UNIQUAC interaction parameters correlated with constant-temperature VLE data for alkane/alkane binaries.Fluid Phase Equilibria,2004,219:41-47
[17]Nagata I,Tamura K.Excess enthalpies for(methanol,or propan-l-ol+acetonitrile+propanone)at the temperature 298.15 K.J.Chem.Thermodyn.,1999,31:491-496
[18]Mehta S K,Chauhan R K,Tripathi A D.Excess molar enthalpies of mixtures of pyrrolidin-2-one with higher alkanols at the temperature 303.15 K.J.Chem.Thermodyn.,1998,30:1095-1101
[19]Goral M.Derivation of Wilson equation for GE from association models.Fluid Phase Equilibria,1995,106:11-16
[20]Rahmat Sadeghi.Extension of the segment-based Wilson and NRTL models for correlation of excess molar enthalpies of polymer solutions.J.Chem.Thermodynamics,2005,37:1013-1018
[21]Sander B,Frendenslund Aa,Rasmussen P.Calculation of vapour-liquid equilibria in mixed solvent/salt systems using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1171-1183
[22]Sander B,Rasmussen P,Frendenslund Aa.Calculation of vapour-liquid equilibria in nitric acid-water-nitrate salt systems using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1185-1195
[23]Sander B,Rasmussen P,Frendenslund Aa.Calculation of solid-liquid equilibria in aqueous of solid-liquid equilibria in aqueous solutions of nitrate salts using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1197-1202
[24]张香平,孙力,姚平经.扩展UNIQUAC方程求NH_3-CO_2-H_2O-Urea体系液相活度系数的新方法.高校化学工程学报,2002,16(4):355-360
[25]Nicolaisen H,Rasmussen P,Sφrensen J M.Correlation and prediction of mineral solubilities in the reciprocal salt system(Na~+,K~+)(Cl~-,SO_4~(2-))-H_2O at 0-100℃.Chem Eng Sci,1993,48(18):3149-3158
[26]Jiding Li,Kai Fischer,Jurgen Gmehling.Prediction of vapor-liquid equilibria for asymmetric systems at low and high pressures with the PSRK model.Fluid Phase Equilibria,1998,143:71-82
[27]Xiaohua Lu,Luzheng Zhang,Yanru Wang,et al.Simultaneous prediction of activity coefficients and enthalpy for aqueous electrolyte solutions at high temperatures.Fluid Phase Equilibria,1996,116:201-208
[28]温德才,刘义,赵儒铭等.量热技术在生命科学中的应用.自然杂志,1998.21:37-41
[29]陈则韶,葛新石,顾毓沁.量热技术和热物性测定.合肥:中国科学技术大学出版社,1990:1-4
[30]刘建红.发电厂凝汽器传热分析与节能途径.中国高新技术企业,2007,(9):78-79
[31]李祖光,高涵,厉刚等.吸热型碳氢燃料的量热研究.推进技术,1999,20(5):92-95
[32]张中良,刘伏明,刘漫红,王祯贞.电化学铜精炼过程中的热效应测试及某些相关的热力学研究.化学世界,1996,(S1)142-146
[33]于诚,许绛霞,李明.制碱生产过程溶液比热测定.纯碱工业,1996,(3):11-17
[34]周立幸,Y Grillet,J.Rowquerol.氢在氧化锌上吸附的量热学研究.科学通报,1995,(16):1532
[35]尉志武,高文颖.生物热化学研究进展.化学进展,2006,18(7/8):1049-1055
[36]梁毅,曲松生,刘义等.热动力学研究的新进展.化学通报,1998,(3):13-18
[37]董岁明,董延芳.酵母生长过程的热谱研究.西北建筑工程学院(自然科学版,2002,19(1:72-75
[38]谭志诚,邸友莹.近代低温绝热量热学的研究现状及发展前景.化学进展,2006,18(9):1234-1251
[39]俞志明.中国化工商品大全(上册).北京:中国物资出版社,1988:212
[40]丁彤,于秋华等.中国化工产品大全第三版(上卷).北京:化学工业出版社,2005:99-100
[41]于华,于令梅等.精细化工产品大全(下卷).北京:化学工业出版社,2005:71
[42]魏文德.有机化工原料大全(中卷).北京:化学工业出版社,1999:603-611
[43]王开毅,成本诚,舒万银.溶剂萃取化学.中南工业大学出版社,1991:51-58
[44]陈建.阻燃剂应用研究综述.化工中间体,2007,(10):25-28
[45]李秀瑜.阻燃剂的最新进展.河北化工,1998,(4):30-32.
[46]U K.Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.Chem Rev,2004,104:4400-4405.
[47]WANG X M,YAMADA C,NAITO H,et.al.High-concentration trimethyl phosphate-based nonflammable electrolytes with improved charge-discharge performance of a graphite anode for lithium-ion cells.J Electrochem Soc,2006,153(1):135-139.
[48]WANG Q S,SUN J H,YAO X L.4-Isopropyl phenyl diphenyl phosphate as flame-retardant additive for lithium-ion battery electrolyte.Electrochem Solid-State Lett,2005,8(9):467-470.
[49]HYUNG Y E,VISSERS D R,AMINE K.Flame-retardant additives for lithium-ion batteries.J Power Sources,2003,:119-121
[50]周代营,左晓希,谭春林等.TEP和TPP用作锂离子蓄电池电解液阻燃剂的研究.电源技术,2007,31(9):387-689
[51]冯祥明,郑金云,石秋芝等.阻燃剂TCPP与锂离子电池负极材料的相性.电池,2007,37(5):336-338
[52]Schulz W W,Burger L L,Nabratil J D.Aapplication of Tributylphosphate in nuclear Fuel Processing.Science and Technology of Tributylphosphate,CRC Press,1990.3-10
[53]孙永霞,周祖铭.磷酸三丁酯从硝酸介质中萃取铀(Ⅳ)和钍(Ⅳ)的动力学研究.核科学与工程,1996,16(1):62-67
[54]Jassim T N,Persson G,Liljenzin J O.Co-extraction of Pertechnetate With Zirconium(Ⅳ)in the TBP-nitric Acid System.Solvent Extr.Ion.Exch.,1984,(7/8):1079-1092
[55]马晓龙,伍明霞.络合萃取法处理含苯胺工业废水.江苏化工,2001,29(1):42-44
[56]杨义燕,杨天雪,戴模元.磷酸三丁酯(TBP)对苯酚的络合萃取.环境化学,1995,(14):410-416
[57]秦炜,王升,梅帆等.苯甲酸生产废水的处理与资源化.环境化学,2004,25(4):78-81
[58]Erkey C,Supercritical carbon dioxide extraction of metals from aqueous solutions:a review.Journal of Supercritical Fluids,2000,17:259-287
[59]Wai C M,Wang S F,Evaluation of dithiocarbamates and β-diketones as chelating agents in supercritical fluid extraction of Cd,Pb,and Hg from solid samples.Talanta,1996,43:2083-2091
[60]Wang J,Marshall W D.Recovery of metals from aqueous media by extraction with supercritical carbon dioxide.Anal.Chem.,1994,66(10):1658-1663
[61]Lin Y,Wai C M.Supercritical fluid extraction of lanthanides with fluorinated β-diketones and tributyl phosphate.Anal.Chem.,1994,66(13):1971-1975
[62]Lin Y,Wai C M,Jean F M,et al.Supercritical fluid extraction of thorium and uranium from solid and liquid materials with fluorinatedβ-diketones and tributyl phosphate.Environ.Sci.Technol.,1994,28:1190-1198
[63]张镜澄.超临界流体萃取.北京,化学工业出版社,2000:12-13
[64]王仁安,胡云翔,许志明等.超临界流体萃取分馏法分离石油重质油.石油学报(石油加工),1997,(1):53-59
[65]Joanna Shaofen Wang,Jamie Herman,Youichi Enokida,Chien M Wai.Dissolution of organid acids in supercritical CO_2 using a CO_2-philic Lewis base carrier.Journal of Supercritical Fluids,2005,36:98-105
[66]陈能林.溶剂手册,北京:化学工业出版社,2002:686-689
[67]Guo-guang Niu,Yu-chun Xie,Jian-feng Lou,et al.Isolation and purification of glycyrrhizic acid with solvent extraction.Separation and Purification Technology,2005,44:189-196
[68]Naddaka,Vladimir;Saeed,Shadi;Montviliski,Dionne;Arad,Oded;Kaspi,Joseph.Europe patent,EP1484321,2004-12-08
[69]储成林,林萍华,董寅生等.磷酸钙系生物陶瓷纳米粉体的制备方法.中国专利,CN 200410013917.1,2004-12-29
[70]萧耀南,李春成,张栋等.聚酰胺共聚物/粘土纳米复合材料及其制各方法和用途.中国专利,CN200610007296.5,2006-02-17
[71]Nakayama,Isao.Water -system fire extinguishers.Japan patent,JP53115600,1978-10-09
[72]Nakayama,Isao;Tanaka,Chiharu.Fire-extinguishing agent.Japan patent,JP 51076900,1976-07-03
[73]Matsumura,Kazuyuki;Yamamoto,Akira.Water -based flame retardants and fireproofed wood.Japan patent,JP 2003253123.A,2003-09-10
[74]Kim,Yongho;Park,Chea-Yong;Kim,Hakwon.Theoretical Studies for Trimethyl Phosphate Complexes with HNO3 and Water as a CO2-Soluble Extractant. Industrial & Engineering Chemistry Research, 2005, 44(10):3389-3395.
[75] Prihoda, J.; Hala, J. Solvent extraction of hafnium. Part XXVIII.Extraction of hafnium(IV) with N-benzoyl-N-phenylhydroxylamine from water -trimethyl phosphate and water -hexamethylphosphortriamide solutions. Purkynianae Brunensis , 1982, 12(6): 277-282.
[76] Crea, Joseph; Lincoln, Stephen F. First coordination sphere of aluminum(III), gallium(III), and indium(III) in trimethyl phosphate. Proton magnetic resonance study.Inorganic Chemistry , 1972,11(5): 1131-1132.
[77] Bacaloni, Alessandro; Cucci, Francesca; Guarino, Chiara; Nazzari, Manuela;Samperi, Roberto. Occurrence of Organophosphorus Flame Retardant and Plasticizers in Three Volcanic Lakes of Central Italy. Environmental Science & Technology ,2008, 42(6): 1898-1903.
[78]Sankaran, K.; Vidya, V.; Viswanathan, K. S.; George, Lisa; Singh, Surjit.Trimethyl Phosphate-Water Interaction: A Matrix-Isolation Infrared and ab Initio Study. Journal of Physical Chemistry A 1998, (102): 2944—2953.
[79] Bertoluzza, A.; Bonora, S.; Fini, G.; Morelli, M. A. Infrared and Raman studies of hydrogen bonding in organophosphorus compounds-proton donors. I.Journal of Spectroscopy , 1987, 32(5): 107-114.
[80]Yarkov, A. V.; Raevskii, O. A. Analysis of the conformational structure of trimethyl phosphate in aqueous solutions. Zhurnal Obshchei Khimii, 1985,55(1): 50-53.
[81] Landgren M, McEachern D, Olofsson Q, et al. Evaluation of Excess Enthalpy from Flow-calorimetric Measurements of Enthalpies of Dilution Using Local Approximation by polynomials, J. Chem. Thermodyn. 1978,10: 847—854
[82] Battler J R, Rowley R L, Excess enthalpies between 293 and 323K for constituent binaries of ternary mixtures exhibiting partial misability. J. Chem.Thermodyn., 1985,17(8): 719-732
[83] Letcher T M, Naicker P K, Excess molar enthalpies and excess molar volumes of(an alkanol +a nitrile compound) at T= 298.15 K and p= 0.1 MPa, J.Chem.Thermodyn. 2001, 33: 1035-1047
[84] Kimura T, Matsushita T, Momoki M, et al. Excess enthalpies of {CH_3(CH_2)_nOH,n=3-12}+methyl methylthiomethyl sulfoxide or dimethyl sulfoxideat 298.15 K . Thermochimica Acta, 2004,424: 83—90
[85]Park S B,Kim J S,Lee H,Excess molar enthalpies of(propylene carbonate +an alcohol).J.Chem.Thermodyn,1999,31(10):1265-1271
[86]Nagata I,Tamura K,Excess molar enthalpies of chlorobenzene +methanol,+acetonitrible,and +ethanol,and of(acetonitrile+chlorobenzens+methanol and+ethanol at 298.15 K.J.Chem.Thermodyn.,1986,18(1):39-44
[87]Pederson M J,Kay W B,Hershey H C,Excess enthalpies heat capacities,andexcess heat capacities as a function of temperature in liquid mixtures of enthanol+toluene,ethanol+hexamethyldisiloxane,and hexamethyldisiloxane +toluene.J.Chem.Thermodyn.,1975,7(12):1107-1118
[88]Kertes,A.S.,Tsimering,L.Enthalpies of mixing and solution in trialkylphosphate-water systems.Journal of Physical Chemistry,1977,81(2):120-125.
[89]Kedrina N.N,Semenov,L.B.,Gaile,A.Heats of mixing of hydrocarbons in polar solvents.USSR.Avail.SPSTL.Deposited Doc.1981
[90]Sitnyakovskii I.B.;Gaile,A.A.;Semenov,L.V.;Koldobskaya,L.L.;Chupyra,O.S,Intermolecular interactions in dilute solutions of methanol in non-electrolytes.Zhurnal Obshchei Khimii,1991,61(11):2405-2410.
[91]Frederick D.Rossini.Experimental Thermochemisty:Measurement of Heats of Reaction.Pennsylvania:Carnegie Institute of Technology,1956:239-250
[92]朱之轮.微机在Tian-Calvert型微热量热计中的应用.电子技术参考,1989,(2):28-36
[93]Kubaschewski O,Alcock C B.冶金热化学.北京:冶金工业出版社,1985:79-138
[94]刘红丽.磷酸三丁酯与醇、水混合体系的热力学性质研究:[硕士学位论文].长沙:中南大学,2006
[95]Donald D.Wagmank,William H.Evans,Vivian B.Parker,etl.The NBS tables of chemical properties.J.Phys.Chem.Ref.Date,1982,11(2):2-328
[96]Fenby,David V.Thermodynamic study of deuterium exchange in water +methanol systems.Journal of the Chemical Society,Faraday Transactions 1:Physical Chemistry in Condensed Phases,1978,74(7):1768-1775.
[97]Marongiu,Bruno;Ferino,Italo;Monaci,Roberto;Solinas,Vincenzo;Torrazza,Sergio.Thermodynamic properties of aqueous non-electrolyte mixtures.Alkanols+water systems.Journal of Molecular Liquids,1984,28(4):229-247
[98]Battler,John R.;Rowley,Richard L.Excess enthalpies between 293 and 323 Kfor constituent binaries of ternary mixtures exhibiting partial miscibility. Journal of Chemical Thermodynamics ,1985, 17(8): 719—732.
[99] Igor Reva, Alcides Simao, Rui Fausto. Conformational Properties of trimethyl phosphate monomer. Chemical Physics Lettets, 2005, 406: 126— 136
[100] Evans, David P.; Davies, Walter C; Jones, Wm. J. Lower trialkyl-orthophosphates. I. Journal of the Chemical Society, 1930:1310—1313.
[101] Connor, T. H. The mutagenicity of trimethyl phosphate. Mutation Research, Reviews in Genetic Toxicology, 1979, 65(2):121 — 131.
[102] Epstein, Samuel S.; Bass, Willa; Arnold, Elsie; Bishop, Yvonne.Mutagenicity of trimethylphosphate in mice. Science, 1970 ,(168): 584—586.
[103] Hanna, P. J.; Kerr, J. B. Antifertility activity of trimethylphosphate in male rats. Experientia, 1981,(37): 999—1001.
[104] Streck, Roman; Barnes, Austin J.; Herrebout, Wouter A.; van der Veken,Benjamin J. Conformational behavior of trimethyl phosphate studied by infrared spectroscopy. Journal of Molecular Structure, 1996,( 376): 277—287.
[105] George, Lisa; Sankaran, K.; Viswanathan, K. S.; Mathews, C. K.Matrix-isolation infrared spectroscopy of hydrogen-bonded complexes of triethyl phosphate with H2O, D2O, and methanol. Applied Spectroscopy, 1994, (48): 801—807.
[106]. Eaton, Graham; Harris, Lorraine; Patel, Kiran; Symons, Martyn C. R.Infrared and nuclear magnetic resonance spectroscopic studies on the solvation of trimethyl phosphate and dimethyl methylphosphonate. Journal of the Chemical Society, Faraday Transactions, 1992, (88): 3527—3531.
[107] Oberhammer, H.. Molecular structure of phosphorus compounds. I.Trimethyl phosphate. Zeitschrift fuer Naturforschung, Teil A: Astrophysik, Physik und Physikalische Chemie, 1973, (28):1140-1144.
[108] Raevskii, O. A.; Vereshchagin, A. N.; Khalitov, F. G. Conformations of trimethyl phosphate and trimethyl thiophosp hate. Izvestiya Akademii Nauk SSSR,Seriya Khimicheskaya, 1972, (2): 353-358.
[109] Becker, U.; Wessels, V.; Turky, G.; Ghoneim, A.; Stockhausen, M.Dielectric relaxation of trimethylphosphate in its pure liquid state and in mesitylene solution. Zeitschrift fuer Physikalische Chemie (Munich), 1995, (191): 251-258.
[110] George, Lisa; Viswanathan, K. S.; Singh, Surjit. Ab Initio Study of Trimethyl Phosphate: Conformational Analysis, Dipole Moments, Vibrational Frequencies, and Barriers for Conformer Interconversion. Journal of Physical Chemistry A,1997,(101):2459-2464.
[111]Tekin,Nalan;Cebe,Mustafa.Solvents effect on infrared spectra of trimethyl phosphate in organic solvents.Vibrational Spectroscopy,2004,36(1),129-133.
[112]Roman Streck,Austin J.Bames,Solvent effects on infrared,13C and 31P NMR spectra of trimethyl phosphate.Part 1.Single solvent systems Spectrochimica Acta PartA,1999(55):1049-1057
[113]K.Sankaran,V.Vidya,and K.S.Viswanathan Trimethyl Phosphate-Water Interaction:A Matrix-Isolation Infrared and ab Initio Study.J.Phys.Chem.A,1998,102,2944-2953
[114]H.L.Liu,S.J.Liu,Z.L.Xiao et al.Excess molar enthalpies of binary mixtures for(tributyl phosphate + ethanol/methanol)at 298.15 K.Journal of Thermal Analysis and Calorimetry,2006,(83):541-544.
[115]S.J.Liu,H.L.Liu,Q.Y Chen et al.Molar excess enthalpies of mixtures of [tributyl phosphate+{CH3(CH2)nOH(n=0 to 3)}]at 298.15K.Journal of Chemical Thermaodynamics,2007,(39):412-416
[116]刘红丽,刘士军,肖忠良等,磷酸三丁酯与醇二元混合体系的热力学研究.物理化学通报,2007(23):124-128.
[117]Sitnyakovskii,I.B.;Gaile,A.A.;Semenov,L.V.;Koldobskaya,L.L.;Chupyra,O.S.ntermolecular interactions in dilute solutions of methanol in non-electrolytes.Zhurnal Obshchei Khimii,1991,(61):2405-2410.
[118]Reddy K V R,Rambabu K,Krishnaiah A,et al.Excess enthalpies of binary mixtures containing Methyl Cellosolve and aliphalic alcohols.Fluid Phase Equilibria,1995,103:251-256
[119]Sipowska J T,Ott J B,Lemon L R,et al.Excess enthalpies and excess volumes for(butane+ethanol)at the temperatures(298.15,323.15,and 348.15)K and the pressures(5,10,and 15)MPa.J.Chem.Eng.Data,1995,27:1355-1364
[120]Asprion N,Hasse H,Maurer G..Application of IR-spectroscopy in thermodynamic investigations of associating solution.Fluid Phase Equilibria.,2003,205:195-214
[121]Asprion N,Hasse H,Maurer G.Thermodynamic and IR spectroscopic studies of solutions with simultaneous association and solvation,Fluid Phase Equilibria.,2003,208:23-51
[122]Metha S K,Chauhan R.K,Triphati A D.Excess molar enthalpies of mixtures of pyrrolidin-2-one with methanol,or ethanol,or propan-l-ol,or butan-l-ol,or pentan-l-ol at the temperature 303.15K,J.Chem.Thermodyn.,1997,29:353-358
[123]K.Sankaran,K.Sundararajan,K.S.Viswanathan,Trimethyl phosphate —CCl4 interaction:experimental and computational evidence for Cl...O interactions,J.Molecular Structure,2002(609):177-185
[124]傅献彩,沈文霞,姚天扬.物理化学(第四版),北京:高等教育出版社,2002:154-156
[125]何凤姣,无机化学,北京:科学出版社,2002:7-12
[126]Heinz,A.A new theoretical approach for predicting excess properties of alkanol/alkane mixtures.Ber.Bunsenges.Phys.Chem.1985,89,172-181.
[127]Panayiotou C.G.Thermodynamics of alkanol-alkane mixtures.J.Phys.Chem.1988,92(10):2960-2969
[128]徐云蕾,俞春芳,黑恩成等.液体内压的预测和新溶解度参数值.化工学报,2000,51(3):407-413
[129]王海燕,曾艳丽,孟令鹏等.有关氢键理论研究的现状及前景.河北师范大学学报(自然科学版),2005,29(2):177-181
[130]朱亮亮,滕启文,吴师等.氢键复合物自组装性质的研究.化学进展,2006,18(6):708-714
[131]Ding-Yu Peng,George C Benson,Benjamin C Y Lu.Excess enthalpies of cyclohexane + n-hexane +(n-octane or n-dodecane)ternary mixture at 298.15 K.Fluid Phase Equilibria,2000,171:105-113
[132]John W Morris,Patrick J Mulvey,Michael M Abbott,et al.Excess thermodynamics functions for ternary systems Ⅰ acetone-chloroform-methanol at 50℃.Journal of Chemical and Engineering Data,1975,20(4):403-405
[133]M.J.Costigan,L.J.Hodges,K.N.Marsh et al.J.Chem,1980(33),2103-2118
[2]黄子卿.非电介质溶液理论导论.北京:科学出版社,1973:1-13
[3]童景山,高光华,刘裕品.化工热力学.北京:清华大学出版社,1995:225-229
[4]张平民主编.工科大学化学.长沙:湖南教育出版社,2002:278-279
[5]章丽辉,沈小燕,刘国杰.含醇溶液的热力学研究.化学学报,2002,60(1):617-621
[6]Dipl-Ing K Nolker,Dr.-Ing M Roth.Modified UNIFAC parameters for mixtureswith isocyanates.Chemical Engineering Science,1998,53:2395-2401
[7]Antonio M Peres,Eugenia A Macedo.Prediction of thermodynamic properties using a modified UNIFAC model:application to sugar industrial systems.FluidPhase Equilibriu.1999,158:391-399
[8]沈晓燕,刘国杰.二元液体混合物的过量体积模型.化工学报,2004,55(7):1041-1046
[9]陈海松,王文昌,王福安.关联二元体系超额混合焓的改进模型.化工学报,2005,56(5):757-762
[10]Pitzer K S,Peiper J C.Activity coefficient of aqueous NaHCO_3.Journal of Physical Chemisty,1980,84(19):2396-2398
[11]Renon H,Pransnutz J M.Local Compositions in Thermodynamic Excess Functions for liquid mixtures.AIChE Journal,1968,14(1):135-144
[12]Nagata I,Tamura K,Excess molar enthalpies of chlorobenzene +methanol,+acetonitrible,and +ethanol,and of(acetonitrile+chlorobenzens+methanol and+ethanol at 298.15 K.J.Chem.Thermodyn.,1986,18(1):39-44
[13]Heintz A,Kulikov D V,Verevkin Sergey P.Thermodynamic properties of mixtures containing ionic liquids.Activity coefficients at infinite dilution of polar solutes in 4-methyl-N-butyl-pyridinium tetrafluoroborate using gas-liquid chromatography.Journal of Chemical Thermodynamics,2002,34(7):1341-1347
[14]Browarzik D,Laux H,Rahimian I.Asphaltene flocculation in crude oil systems.Fluid Phase Equilibria,1999,154:285-300
[15]James C Young Jr,Jesse S Binford Jr,Scott W Campbell.Excess enthalpies of five pentanol isomer+n-heptane systems measured at 303.15 K and a model describing the behavior.Fluid Phase Equilibria,2003,209:255-264
[16]Satoru Kato,Daisuke Hoshino,Hidetaka Noritomi,Kunio Nagahama.Prediction of activity coefficients using UNIQUAC interaction parameters correlated with constant-temperature VLE data for alkane/alkane binaries.Fluid Phase Equilibria,2004,219:41-47
[17]Nagata I,Tamura K.Excess enthalpies for(methanol,or propan-l-ol+acetonitrile+propanone)at the temperature 298.15 K.J.Chem.Thermodyn.,1999,31:491-496
[18]Mehta S K,Chauhan R K,Tripathi A D.Excess molar enthalpies of mixtures of pyrrolidin-2-one with higher alkanols at the temperature 303.15 K.J.Chem.Thermodyn.,1998,30:1095-1101
[19]Goral M.Derivation of Wilson equation for GE from association models.Fluid Phase Equilibria,1995,106:11-16
[20]Rahmat Sadeghi.Extension of the segment-based Wilson and NRTL models for correlation of excess molar enthalpies of polymer solutions.J.Chem.Thermodynamics,2005,37:1013-1018
[21]Sander B,Frendenslund Aa,Rasmussen P.Calculation of vapour-liquid equilibria in mixed solvent/salt systems using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1171-1183
[22]Sander B,Rasmussen P,Frendenslund Aa.Calculation of vapour-liquid equilibria in nitric acid-water-nitrate salt systems using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1185-1195
[23]Sander B,Rasmussen P,Frendenslund Aa.Calculation of solid-liquid equilibria in aqueous of solid-liquid equilibria in aqueous solutions of nitrate salts using an extended UNIQUAC equation.Chemical Engineering Science,1986,41(5):1197-1202
[24]张香平,孙力,姚平经.扩展UNIQUAC方程求NH_3-CO_2-H_2O-Urea体系液相活度系数的新方法.高校化学工程学报,2002,16(4):355-360
[25]Nicolaisen H,Rasmussen P,Sφrensen J M.Correlation and prediction of mineral solubilities in the reciprocal salt system(Na~+,K~+)(Cl~-,SO_4~(2-))-H_2O at 0-100℃.Chem Eng Sci,1993,48(18):3149-3158
[26]Jiding Li,Kai Fischer,Jurgen Gmehling.Prediction of vapor-liquid equilibria for asymmetric systems at low and high pressures with the PSRK model.Fluid Phase Equilibria,1998,143:71-82
[27]Xiaohua Lu,Luzheng Zhang,Yanru Wang,et al.Simultaneous prediction of activity coefficients and enthalpy for aqueous electrolyte solutions at high temperatures.Fluid Phase Equilibria,1996,116:201-208
[28]温德才,刘义,赵儒铭等.量热技术在生命科学中的应用.自然杂志,1998.21:37-41
[29]陈则韶,葛新石,顾毓沁.量热技术和热物性测定.合肥:中国科学技术大学出版社,1990:1-4
[30]刘建红.发电厂凝汽器传热分析与节能途径.中国高新技术企业,2007,(9):78-79
[31]李祖光,高涵,厉刚等.吸热型碳氢燃料的量热研究.推进技术,1999,20(5):92-95
[32]张中良,刘伏明,刘漫红,王祯贞.电化学铜精炼过程中的热效应测试及某些相关的热力学研究.化学世界,1996,(S1)142-146
[33]于诚,许绛霞,李明.制碱生产过程溶液比热测定.纯碱工业,1996,(3):11-17
[34]周立幸,Y Grillet,J.Rowquerol.氢在氧化锌上吸附的量热学研究.科学通报,1995,(16):1532
[35]尉志武,高文颖.生物热化学研究进展.化学进展,2006,18(7/8):1049-1055
[36]梁毅,曲松生,刘义等.热动力学研究的新进展.化学通报,1998,(3):13-18
[37]董岁明,董延芳.酵母生长过程的热谱研究.西北建筑工程学院(自然科学版,2002,19(1:72-75
[38]谭志诚,邸友莹.近代低温绝热量热学的研究现状及发展前景.化学进展,2006,18(9):1234-1251
[39]俞志明.中国化工商品大全(上册).北京:中国物资出版社,1988:212
[40]丁彤,于秋华等.中国化工产品大全第三版(上卷).北京:化学工业出版社,2005:99-100
[41]于华,于令梅等.精细化工产品大全(下卷).北京:化学工业出版社,2005:71
[42]魏文德.有机化工原料大全(中卷).北京:化学工业出版社,1999:603-611
[43]王开毅,成本诚,舒万银.溶剂萃取化学.中南工业大学出版社,1991:51-58
[44]陈建.阻燃剂应用研究综述.化工中间体,2007,(10):25-28
[45]李秀瑜.阻燃剂的最新进展.河北化工,1998,(4):30-32.
[46]U K.Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.Chem Rev,2004,104:4400-4405.
[47]WANG X M,YAMADA C,NAITO H,et.al.High-concentration trimethyl phosphate-based nonflammable electrolytes with improved charge-discharge performance of a graphite anode for lithium-ion cells.J Electrochem Soc,2006,153(1):135-139.
[48]WANG Q S,SUN J H,YAO X L.4-Isopropyl phenyl diphenyl phosphate as flame-retardant additive for lithium-ion battery electrolyte.Electrochem Solid-State Lett,2005,8(9):467-470.
[49]HYUNG Y E,VISSERS D R,AMINE K.Flame-retardant additives for lithium-ion batteries.J Power Sources,2003,:119-121
[50]周代营,左晓希,谭春林等.TEP和TPP用作锂离子蓄电池电解液阻燃剂的研究.电源技术,2007,31(9):387-689
[51]冯祥明,郑金云,石秋芝等.阻燃剂TCPP与锂离子电池负极材料的相性.电池,2007,37(5):336-338
[52]Schulz W W,Burger L L,Nabratil J D.Aapplication of Tributylphosphate in nuclear Fuel Processing.Science and Technology of Tributylphosphate,CRC Press,1990.3-10
[53]孙永霞,周祖铭.磷酸三丁酯从硝酸介质中萃取铀(Ⅳ)和钍(Ⅳ)的动力学研究.核科学与工程,1996,16(1):62-67
[54]Jassim T N,Persson G,Liljenzin J O.Co-extraction of Pertechnetate With Zirconium(Ⅳ)in the TBP-nitric Acid System.Solvent Extr.Ion.Exch.,1984,(7/8):1079-1092
[55]马晓龙,伍明霞.络合萃取法处理含苯胺工业废水.江苏化工,2001,29(1):42-44
[56]杨义燕,杨天雪,戴模元.磷酸三丁酯(TBP)对苯酚的络合萃取.环境化学,1995,(14):410-416
[57]秦炜,王升,梅帆等.苯甲酸生产废水的处理与资源化.环境化学,2004,25(4):78-81
[58]Erkey C,Supercritical carbon dioxide extraction of metals from aqueous solutions:a review.Journal of Supercritical Fluids,2000,17:259-287
[59]Wai C M,Wang S F,Evaluation of dithiocarbamates and β-diketones as chelating agents in supercritical fluid extraction of Cd,Pb,and Hg from solid samples.Talanta,1996,43:2083-2091
[60]Wang J,Marshall W D.Recovery of metals from aqueous media by extraction with supercritical carbon dioxide.Anal.Chem.,1994,66(10):1658-1663
[61]Lin Y,Wai C M.Supercritical fluid extraction of lanthanides with fluorinated β-diketones and tributyl phosphate.Anal.Chem.,1994,66(13):1971-1975
[62]Lin Y,Wai C M,Jean F M,et al.Supercritical fluid extraction of thorium and uranium from solid and liquid materials with fluorinatedβ-diketones and tributyl phosphate.Environ.Sci.Technol.,1994,28:1190-1198
[63]张镜澄.超临界流体萃取.北京,化学工业出版社,2000:12-13
[64]王仁安,胡云翔,许志明等.超临界流体萃取分馏法分离石油重质油.石油学报(石油加工),1997,(1):53-59
[65]Joanna Shaofen Wang,Jamie Herman,Youichi Enokida,Chien M Wai.Dissolution of organid acids in supercritical CO_2 using a CO_2-philic Lewis base carrier.Journal of Supercritical Fluids,2005,36:98-105
[66]陈能林.溶剂手册,北京:化学工业出版社,2002:686-689
[67]Guo-guang Niu,Yu-chun Xie,Jian-feng Lou,et al.Isolation and purification of glycyrrhizic acid with solvent extraction.Separation and Purification Technology,2005,44:189-196
[68]Naddaka,Vladimir;Saeed,Shadi;Montviliski,Dionne;Arad,Oded;Kaspi,Joseph.Europe patent,EP1484321,2004-12-08
[69]储成林,林萍华,董寅生等.磷酸钙系生物陶瓷纳米粉体的制备方法.中国专利,CN 200410013917.1,2004-12-29
[70]萧耀南,李春成,张栋等.聚酰胺共聚物/粘土纳米复合材料及其制各方法和用途.中国专利,CN200610007296.5,2006-02-17
[71]Nakayama,Isao.Water -system fire extinguishers.Japan patent,JP53115600,1978-10-09
[72]Nakayama,Isao;Tanaka,Chiharu.Fire-extinguishing agent.Japan patent,JP 51076900,1976-07-03
[73]Matsumura,Kazuyuki;Yamamoto,Akira.Water -based flame retardants and fireproofed wood.Japan patent,JP 2003253123.A,2003-09-10
[74]Kim,Yongho;Park,Chea-Yong;Kim,Hakwon.Theoretical Studies for Trimethyl Phosphate Complexes with HNO3 and Water as a CO2-Soluble Extractant. Industrial & Engineering Chemistry Research, 2005, 44(10):3389-3395.
[75] Prihoda, J.; Hala, J. Solvent extraction of hafnium. Part XXVIII.Extraction of hafnium(IV) with N-benzoyl-N-phenylhydroxylamine from water -trimethyl phosphate and water -hexamethylphosphortriamide solutions. Purkynianae Brunensis , 1982, 12(6): 277-282.
[76] Crea, Joseph; Lincoln, Stephen F. First coordination sphere of aluminum(III), gallium(III), and indium(III) in trimethyl phosphate. Proton magnetic resonance study.Inorganic Chemistry , 1972,11(5): 1131-1132.
[77] Bacaloni, Alessandro; Cucci, Francesca; Guarino, Chiara; Nazzari, Manuela;Samperi, Roberto. Occurrence of Organophosphorus Flame Retardant and Plasticizers in Three Volcanic Lakes of Central Italy. Environmental Science & Technology ,2008, 42(6): 1898-1903.
[78]Sankaran, K.; Vidya, V.; Viswanathan, K. S.; George, Lisa; Singh, Surjit.Trimethyl Phosphate-Water Interaction: A Matrix-Isolation Infrared and ab Initio Study. Journal of Physical Chemistry A 1998, (102): 2944—2953.
[79] Bertoluzza, A.; Bonora, S.; Fini, G.; Morelli, M. A. Infrared and Raman studies of hydrogen bonding in organophosphorus compounds-proton donors. I.Journal of Spectroscopy , 1987, 32(5): 107-114.
[80]Yarkov, A. V.; Raevskii, O. A. Analysis of the conformational structure of trimethyl phosphate in aqueous solutions. Zhurnal Obshchei Khimii, 1985,55(1): 50-53.
[81] Landgren M, McEachern D, Olofsson Q, et al. Evaluation of Excess Enthalpy from Flow-calorimetric Measurements of Enthalpies of Dilution Using Local Approximation by polynomials, J. Chem. Thermodyn. 1978,10: 847—854
[82] Battler J R, Rowley R L, Excess enthalpies between 293 and 323K for constituent binaries of ternary mixtures exhibiting partial misability. J. Chem.Thermodyn., 1985,17(8): 719-732
[83] Letcher T M, Naicker P K, Excess molar enthalpies and excess molar volumes of(an alkanol +a nitrile compound) at T= 298.15 K and p= 0.1 MPa, J.Chem.Thermodyn. 2001, 33: 1035-1047
[84] Kimura T, Matsushita T, Momoki M, et al. Excess enthalpies of {CH_3(CH_2)_nOH,n=3-12}+methyl methylthiomethyl sulfoxide or dimethyl sulfoxideat 298.15 K . Thermochimica Acta, 2004,424: 83—90
[85]Park S B,Kim J S,Lee H,Excess molar enthalpies of(propylene carbonate +an alcohol).J.Chem.Thermodyn,1999,31(10):1265-1271
[86]Nagata I,Tamura K,Excess molar enthalpies of chlorobenzene +methanol,+acetonitrible,and +ethanol,and of(acetonitrile+chlorobenzens+methanol and+ethanol at 298.15 K.J.Chem.Thermodyn.,1986,18(1):39-44
[87]Pederson M J,Kay W B,Hershey H C,Excess enthalpies heat capacities,andexcess heat capacities as a function of temperature in liquid mixtures of enthanol+toluene,ethanol+hexamethyldisiloxane,and hexamethyldisiloxane +toluene.J.Chem.Thermodyn.,1975,7(12):1107-1118
[88]Kertes,A.S.,Tsimering,L.Enthalpies of mixing and solution in trialkylphosphate-water systems.Journal of Physical Chemistry,1977,81(2):120-125.
[89]Kedrina N.N,Semenov,L.B.,Gaile,A.Heats of mixing of hydrocarbons in polar solvents.USSR.Avail.SPSTL.Deposited Doc.1981
[90]Sitnyakovskii I.B.;Gaile,A.A.;Semenov,L.V.;Koldobskaya,L.L.;Chupyra,O.S,Intermolecular interactions in dilute solutions of methanol in non-electrolytes.Zhurnal Obshchei Khimii,1991,61(11):2405-2410.
[91]Frederick D.Rossini.Experimental Thermochemisty:Measurement of Heats of Reaction.Pennsylvania:Carnegie Institute of Technology,1956:239-250
[92]朱之轮.微机在Tian-Calvert型微热量热计中的应用.电子技术参考,1989,(2):28-36
[93]Kubaschewski O,Alcock C B.冶金热化学.北京:冶金工业出版社,1985:79-138
[94]刘红丽.磷酸三丁酯与醇、水混合体系的热力学性质研究:[硕士学位论文].长沙:中南大学,2006
[95]Donald D.Wagmank,William H.Evans,Vivian B.Parker,etl.The NBS tables of chemical properties.J.Phys.Chem.Ref.Date,1982,11(2):2-328
[96]Fenby,David V.Thermodynamic study of deuterium exchange in water +methanol systems.Journal of the Chemical Society,Faraday Transactions 1:Physical Chemistry in Condensed Phases,1978,74(7):1768-1775.
[97]Marongiu,Bruno;Ferino,Italo;Monaci,Roberto;Solinas,Vincenzo;Torrazza,Sergio.Thermodynamic properties of aqueous non-electrolyte mixtures.Alkanols+water systems.Journal of Molecular Liquids,1984,28(4):229-247
[98]Battler,John R.;Rowley,Richard L.Excess enthalpies between 293 and 323 Kfor constituent binaries of ternary mixtures exhibiting partial miscibility. Journal of Chemical Thermodynamics ,1985, 17(8): 719—732.
[99] Igor Reva, Alcides Simao, Rui Fausto. Conformational Properties of trimethyl phosphate monomer. Chemical Physics Lettets, 2005, 406: 126— 136
[100] Evans, David P.; Davies, Walter C; Jones, Wm. J. Lower trialkyl-orthophosphates. I. Journal of the Chemical Society, 1930:1310—1313.
[101] Connor, T. H. The mutagenicity of trimethyl phosphate. Mutation Research, Reviews in Genetic Toxicology, 1979, 65(2):121 — 131.
[102] Epstein, Samuel S.; Bass, Willa; Arnold, Elsie; Bishop, Yvonne.Mutagenicity of trimethylphosphate in mice. Science, 1970 ,(168): 584—586.
[103] Hanna, P. J.; Kerr, J. B. Antifertility activity of trimethylphosphate in male rats. Experientia, 1981,(37): 999—1001.
[104] Streck, Roman; Barnes, Austin J.; Herrebout, Wouter A.; van der Veken,Benjamin J. Conformational behavior of trimethyl phosphate studied by infrared spectroscopy. Journal of Molecular Structure, 1996,( 376): 277—287.
[105] George, Lisa; Sankaran, K.; Viswanathan, K. S.; Mathews, C. K.Matrix-isolation infrared spectroscopy of hydrogen-bonded complexes of triethyl phosphate with H2O, D2O, and methanol. Applied Spectroscopy, 1994, (48): 801—807.
[106]. Eaton, Graham; Harris, Lorraine; Patel, Kiran; Symons, Martyn C. R.Infrared and nuclear magnetic resonance spectroscopic studies on the solvation of trimethyl phosphate and dimethyl methylphosphonate. Journal of the Chemical Society, Faraday Transactions, 1992, (88): 3527—3531.
[107] Oberhammer, H.. Molecular structure of phosphorus compounds. I.Trimethyl phosphate. Zeitschrift fuer Naturforschung, Teil A: Astrophysik, Physik und Physikalische Chemie, 1973, (28):1140-1144.
[108] Raevskii, O. A.; Vereshchagin, A. N.; Khalitov, F. G. Conformations of trimethyl phosphate and trimethyl thiophosp hate. Izvestiya Akademii Nauk SSSR,Seriya Khimicheskaya, 1972, (2): 353-358.
[109] Becker, U.; Wessels, V.; Turky, G.; Ghoneim, A.; Stockhausen, M.Dielectric relaxation of trimethylphosphate in its pure liquid state and in mesitylene solution. Zeitschrift fuer Physikalische Chemie (Munich), 1995, (191): 251-258.
[110] George, Lisa; Viswanathan, K. S.; Singh, Surjit. Ab Initio Study of Trimethyl Phosphate: Conformational Analysis, Dipole Moments, Vibrational Frequencies, and Barriers for Conformer Interconversion. Journal of Physical Chemistry A,1997,(101):2459-2464.
[111]Tekin,Nalan;Cebe,Mustafa.Solvents effect on infrared spectra of trimethyl phosphate in organic solvents.Vibrational Spectroscopy,2004,36(1),129-133.
[112]Roman Streck,Austin J.Bames,Solvent effects on infrared,13C and 31P NMR spectra of trimethyl phosphate.Part 1.Single solvent systems Spectrochimica Acta PartA,1999(55):1049-1057
[113]K.Sankaran,V.Vidya,and K.S.Viswanathan Trimethyl Phosphate-Water Interaction:A Matrix-Isolation Infrared and ab Initio Study.J.Phys.Chem.A,1998,102,2944-2953
[114]H.L.Liu,S.J.Liu,Z.L.Xiao et al.Excess molar enthalpies of binary mixtures for(tributyl phosphate + ethanol/methanol)at 298.15 K.Journal of Thermal Analysis and Calorimetry,2006,(83):541-544.
[115]S.J.Liu,H.L.Liu,Q.Y Chen et al.Molar excess enthalpies of mixtures of [tributyl phosphate+{CH3(CH2)nOH(n=0 to 3)}]at 298.15K.Journal of Chemical Thermaodynamics,2007,(39):412-416
[116]刘红丽,刘士军,肖忠良等,磷酸三丁酯与醇二元混合体系的热力学研究.物理化学通报,2007(23):124-128.
[117]Sitnyakovskii,I.B.;Gaile,A.A.;Semenov,L.V.;Koldobskaya,L.L.;Chupyra,O.S.ntermolecular interactions in dilute solutions of methanol in non-electrolytes.Zhurnal Obshchei Khimii,1991,(61):2405-2410.
[118]Reddy K V R,Rambabu K,Krishnaiah A,et al.Excess enthalpies of binary mixtures containing Methyl Cellosolve and aliphalic alcohols.Fluid Phase Equilibria,1995,103:251-256
[119]Sipowska J T,Ott J B,Lemon L R,et al.Excess enthalpies and excess volumes for(butane+ethanol)at the temperatures(298.15,323.15,and 348.15)K and the pressures(5,10,and 15)MPa.J.Chem.Eng.Data,1995,27:1355-1364
[120]Asprion N,Hasse H,Maurer G..Application of IR-spectroscopy in thermodynamic investigations of associating solution.Fluid Phase Equilibria.,2003,205:195-214
[121]Asprion N,Hasse H,Maurer G.Thermodynamic and IR spectroscopic studies of solutions with simultaneous association and solvation,Fluid Phase Equilibria.,2003,208:23-51
[122]Metha S K,Chauhan R.K,Triphati A D.Excess molar enthalpies of mixtures of pyrrolidin-2-one with methanol,or ethanol,or propan-l-ol,or butan-l-ol,or pentan-l-ol at the temperature 303.15K,J.Chem.Thermodyn.,1997,29:353-358
[123]K.Sankaran,K.Sundararajan,K.S.Viswanathan,Trimethyl phosphate —CCl4 interaction:experimental and computational evidence for Cl...O interactions,J.Molecular Structure,2002(609):177-185
[124]傅献彩,沈文霞,姚天扬.物理化学(第四版),北京:高等教育出版社,2002:154-156
[125]何凤姣,无机化学,北京:科学出版社,2002:7-12
[126]Heinz,A.A new theoretical approach for predicting excess properties of alkanol/alkane mixtures.Ber.Bunsenges.Phys.Chem.1985,89,172-181.
[127]Panayiotou C.G.Thermodynamics of alkanol-alkane mixtures.J.Phys.Chem.1988,92(10):2960-2969
[128]徐云蕾,俞春芳,黑恩成等.液体内压的预测和新溶解度参数值.化工学报,2000,51(3):407-413
[129]王海燕,曾艳丽,孟令鹏等.有关氢键理论研究的现状及前景.河北师范大学学报(自然科学版),2005,29(2):177-181
[130]朱亮亮,滕启文,吴师等.氢键复合物自组装性质的研究.化学进展,2006,18(6):708-714
[131]Ding-Yu Peng,George C Benson,Benjamin C Y Lu.Excess enthalpies of cyclohexane + n-hexane +(n-octane or n-dodecane)ternary mixture at 298.15 K.Fluid Phase Equilibria,2000,171:105-113
[132]John W Morris,Patrick J Mulvey,Michael M Abbott,et al.Excess thermodynamics functions for ternary systems Ⅰ acetone-chloroform-methanol at 50℃.Journal of Chemical and Engineering Data,1975,20(4):403-405
[133]M.J.Costigan,L.J.Hodges,K.N.Marsh et al.J.Chem,1980(33),2103-2118