聚芳醚/纳米碳复合材料的制备及性能研究
|
摘要
纳米碳材料,如碳纳米管、石墨烯,因其独特的结构及优异的性能成为复合材料的理想填料。本论文将纳米碳引入到聚芳醚基体,从实现纳米单元在基体中的均匀分散及改善界面作用角度出发,立足于提高聚芳醚聚合物的基本性能,探索了复合材料的功能性,对一系列聚芳醚/纳米碳复合材料进行了研究。
首先采用熔融共混的方法制备了碳纳米管/聚醚醚酮复合材料,研究发现,经混酸处理的碳纳米管经磺化聚醚醚酮修饰后,与聚醚醚酮共混制得的复合材料界面性能有了很大改善,碳纳米管与树脂基体间的作用增强,力学性能提高,结晶温度表现为低含量时增加,高含量时降低。
碳纳米管具有优异的导电性能,是制备导电复合材料的理想导电剂。而碳纳米管完整的管结构,更有利于电子的传输。因此,与聚醚醚酮基体有较好相容性的聚醚砜包覆改性的碳纳米管,可以保持管结构完整性的同时促进碳纳米管在基体中的分散。研究发现,改性碳纳米管添加到一定量后,复合材料的体积电阻突降。当采用不同熔融指数的聚醚醚酮作为基体时,由于碳纳米管在熔体中分散难易程度的不同,使得复合材料的体积电阻不同。
碳纳米管的成本相对较高,大规模应用受到很大限制。近年来,可以通过石墨解离制备的石墨烯,因其不逊于碳纳米管的性能,低廉的成本,成为复合材料研究的热点。由于氧化石墨烯可以溶解在多种溶剂中,所以溶液成膜法是制备其复合材料的一种行之有效的方法。我们将化学方法制备的氧化石墨烯经磺化聚醚醚酮功能化后与聚醚砜溶液混合制备复合材料。研究表明,石墨烯的加入,提高了复合材料膜的力学性能。
石墨烯大的比表面积,高的导电率,成为新能源材料的理想选择。利用溶液成膜法制备了不同含量的磺化聚醚醚酮/氧化石墨烯复合材料。将高含量的氧化石墨烯的磺化聚醚醚酮复合膜还原后作为超级电容器的电极,与其他含量的磺化聚醚醚酮/氧化石墨烯复合膜组装成超级电容器,电化学测试表现出良好的双电层电容特性。
Oxidation carbon nanotubes were modified by SPEEK, PEEK composites with modified carbon nanotubes(f-CNTs) were prepared by melt blending. Mechanical properties of the composites were increased due to introduction of carbon nanotubes. Moreover, strong interfacial adhesion was shown between PEEK matrix and f-CNTs, the increment of mechanical properties is bigger.Carbon nanotubes play a role in action of heterogeneous nucleation, especially at lower content. Carbon nanotubes formed a bulk conglomeration at higher loading. The mobility of PEEK chains were inhibited , therefore, regular arrangement was influenced. Good dispersion of f-CNTs in the PEEK matrix also promoted nucleation.
However, the strong interfacial interaction restricted moving of PEEK chains. The crystallization rate obtained from isothermal crystallization kinetics can supported it. Functional carbon nanotubes were melt with PEEK for the conductive polymer composites. Carbon nanotubes were treated by PES. Node of carbon nanotubes were isolated, volume resistance of the composites were slowly decreased. Node of carbon nanotubes contacted gradually with increasing of carbon nanotubes, other nodes produced current by quantum-tunnel effect. Volume resistance was significantly reduced when the content near (or over) the percolation threshold. We also investigated the rheology of PEEK composites. Apparent viscosity increased with increasing of loading of carbon nanotubes. It made against the processing. Volume resistance was different while melt index was different at same loading of carbon nanotubes.
Graphene oxide was synthesized by chemical method.It was worth to modify the hydrophile sueface of graphene oxide for the composites blending with hydrophobic PES. SPEEK and PES have good compatibility because of similar molecular structure . The sulfonic group of SPEEK can interact with hydroxy group of graphene oxide. Graphene/PES composites were prepared by solution casting. Mechanical properties were increased with increasing of content.
Supercapacitors base on SPEEK/ graphene composite membranes were assembled. The content of oxygen was decreased after reduction comparing with graphene oxide. There were a lot of holes in the shurface and cross section, this could assist electrolyte ion soaked the graphene. Cyclic voltammograms shown a good performance of electrode, redox peak was not appearent. Galvanostatic charge-discharge curves exhibited isoceles triangle. We researched graphene oxide how to influence the electrochemical properties.
首先采用熔融共混的方法制备了碳纳米管/聚醚醚酮复合材料,研究发现,经混酸处理的碳纳米管经磺化聚醚醚酮修饰后,与聚醚醚酮共混制得的复合材料界面性能有了很大改善,碳纳米管与树脂基体间的作用增强,力学性能提高,结晶温度表现为低含量时增加,高含量时降低。
碳纳米管具有优异的导电性能,是制备导电复合材料的理想导电剂。而碳纳米管完整的管结构,更有利于电子的传输。因此,与聚醚醚酮基体有较好相容性的聚醚砜包覆改性的碳纳米管,可以保持管结构完整性的同时促进碳纳米管在基体中的分散。研究发现,改性碳纳米管添加到一定量后,复合材料的体积电阻突降。当采用不同熔融指数的聚醚醚酮作为基体时,由于碳纳米管在熔体中分散难易程度的不同,使得复合材料的体积电阻不同。
碳纳米管的成本相对较高,大规模应用受到很大限制。近年来,可以通过石墨解离制备的石墨烯,因其不逊于碳纳米管的性能,低廉的成本,成为复合材料研究的热点。由于氧化石墨烯可以溶解在多种溶剂中,所以溶液成膜法是制备其复合材料的一种行之有效的方法。我们将化学方法制备的氧化石墨烯经磺化聚醚醚酮功能化后与聚醚砜溶液混合制备复合材料。研究表明,石墨烯的加入,提高了复合材料膜的力学性能。
石墨烯大的比表面积,高的导电率,成为新能源材料的理想选择。利用溶液成膜法制备了不同含量的磺化聚醚醚酮/氧化石墨烯复合材料。将高含量的氧化石墨烯的磺化聚醚醚酮复合膜还原后作为超级电容器的电极,与其他含量的磺化聚醚醚酮/氧化石墨烯复合膜组装成超级电容器,电化学测试表现出良好的双电层电容特性。
Oxidation carbon nanotubes were modified by SPEEK, PEEK composites with modified carbon nanotubes(f-CNTs) were prepared by melt blending. Mechanical properties of the composites were increased due to introduction of carbon nanotubes. Moreover, strong interfacial adhesion was shown between PEEK matrix and f-CNTs, the increment of mechanical properties is bigger.Carbon nanotubes play a role in action of heterogeneous nucleation, especially at lower content. Carbon nanotubes formed a bulk conglomeration at higher loading. The mobility of PEEK chains were inhibited , therefore, regular arrangement was influenced. Good dispersion of f-CNTs in the PEEK matrix also promoted nucleation.
However, the strong interfacial interaction restricted moving of PEEK chains. The crystallization rate obtained from isothermal crystallization kinetics can supported it. Functional carbon nanotubes were melt with PEEK for the conductive polymer composites. Carbon nanotubes were treated by PES. Node of carbon nanotubes were isolated, volume resistance of the composites were slowly decreased. Node of carbon nanotubes contacted gradually with increasing of carbon nanotubes, other nodes produced current by quantum-tunnel effect. Volume resistance was significantly reduced when the content near (or over) the percolation threshold. We also investigated the rheology of PEEK composites. Apparent viscosity increased with increasing of loading of carbon nanotubes. It made against the processing. Volume resistance was different while melt index was different at same loading of carbon nanotubes.
Graphene oxide was synthesized by chemical method.It was worth to modify the hydrophile sueface of graphene oxide for the composites blending with hydrophobic PES. SPEEK and PES have good compatibility because of similar molecular structure . The sulfonic group of SPEEK can interact with hydroxy group of graphene oxide. Graphene/PES composites were prepared by solution casting. Mechanical properties were increased with increasing of content.
Supercapacitors base on SPEEK/ graphene composite membranes were assembled. The content of oxygen was decreased after reduction comparing with graphene oxide. There were a lot of holes in the shurface and cross section, this could assist electrolyte ion soaked the graphene. Cyclic voltammograms shown a good performance of electrode, redox peak was not appearent. Galvanostatic charge-discharge curves exhibited isoceles triangle. We researched graphene oxide how to influence the electrochemical properties.
引文
[1] H.W. Kroto., J. R. Heath, S. C. O'Brien, R. F.Curl, R. E.Smalley, C60: Buckminster fullerene[J], Nature,1985,318,162-163
[2] Sumio Iijima, Helical microtubules of graphitic carbon[J],Nature,354,1991, 56-58
[3] T. W. Ebbesen, P. M. Ajayan, Large-scale synthesis of carbon nanotubes[J], Nature,1992,358, 220-222
[4] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov ,Electric Field Effect in Atomically Thin Carbon Films[J],Science,2004,306,666-669
[5] A. K. Geim, K. S. Novoselov,The rise of graphene[J],Nat. Mater,2007,6, 183-191
[6] Mikhail I. Katsnelson,Graphene :carbon in two dimensions[J], Mater. Today, 2007,10,20-27
[7]成会明,纳米碳管制备、结构、物性及应用[M],化学工业出版社,2002,1-150
[8]王春,纳米金刚石、碳纳米管、石墨烯性能的第一原理研究[D],吉林大学博士学位论文,2009,1-11
[9] 0.Zhou,R. M. Fleming,D. W. Murphy, C. H. Chen,R. C. Haddon, A. P. Ramirez,S. H. Glarum,Defects in Carbon Nanostructures[J],Science,1994, 263,1744-1747
[10] S Amelinckx, A Lucas,P Lambin,Electron diffraction and microscopy of nanotubes[J],Rep. Prog. Phys. ,1999,62,1471–1524
[11]李海东,石墨烯纳米结构中的电子输运性质[D],吉林大学博士学位论文,2009,1-30
[12] Elena Stolyarova, Kwang Taeg Rim, Sunmin Ryu, Janina Maultzsch, Philip Kim, Louis E. Brus, Tony F. Heinz, Mark S. Hybertsen, George W. Flynn,High-resolution scanning tunneling microscopy imaging of mesoscopic graphene sheets on an insulating surface [J],PNAS,2007,104, 9209–9212
[13] Changgu Lee, Xiaoding Wei,Jeffrey W. Kysar,James Hone, Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J],Science, 2008,321,385-388
[14] Eric W. Wong,Paul E. Sheehan,Charles M. Lieber, Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes, Science,1997,277,1971-1975
[15] Nikolaos Tombros, Csaba Jozsa, Mihaita Popinciuc, Harry T. Jonkman,Bart J. van Wees, Electronic spin transport and spin precession in single graphene layers at room temperature[J],Nature, 2007, 448: 571-575
[16] K.S. Novoselov, Z. Jiang, Y. Zhang, S.V. Morozov, H.L. Stormer, U. Zeitler, J.C.Maan, G.S. Boebinger, P. Kim, A.K. Geim, Room-temperature quantum hall effect in graphene[J],Science, 2007, 315,1379-1379
[17] Robert F. Service,Carbon Sheets an Atom Thick Give Rise to Graphene Dreams[J],Science,2009,324, 875-877
[18] Kong J ,Zhou C,Yenilmez E,et al. Alkaline metal-doped n-type semiconducting nanotubes as quantum dots [J],Appl Phys Lett. 2000, 77,3977-3980
[19] Jiangtao Hu,Chemistry and physics in one dimension synthesis and properties of nanowires and nanotubes[J],ACC,Chem,Res,1999,32,435-44
[20] Baughman.RH; Zakhidov. AA,de Heer.WA, Carbon nanotubes-the route toward applications[J],Science,297,2002,787-792
[21] Yu, MF; Lourie,O; Dyer, MJ, et al.,Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load,Science,2000, 287,637-640
[22] Teri Wang Odom ,Atomic structure and electronic properties of single-walled carbon nanotubes[J],Nature,1998,391,62-64
[23] Grimes C.A., Mangle C., Kouzoudis D., et al. The 500MHz to 5.50GHz Complex Permittivity Spectra of Single-wall Carbon Nanotubes-loaded Polymer Composites[J],Chem. Phys. Lett. 2000, 319: 460-464.
[24] Li N, Huang Y, Du F et al Electromagnetic Interference (EMI)Shielding of Single-Walled Carbon Nanotube Epoxy Composites[J],Nano Lett.,6, 2006, 111-1145
[25] Ma C M., Huang Y L, Kuan H C,et al .Preparation and Electromagnetic Interference shielding characteristics of novel carbon-nantubes /siloxane (urea urethane) nanocomposites[J],J. Polym. Sci., Part B: Polym. Phys., 2005, 43, 345–358
[26]郭平生,碳纳米材料化学气相沉积制备及其场发射显示器研究[D],华东师范大学博士学位毕业论文2006,14-30
[27] Michael J. O’Connell ,Carbon Nanotubes Properties and Applications[M], CRC Press, 2006,83-119
[28] Yury Gogotsi, Carbon Nanomaterials[M],CRC Press, 2006,255-316
[29] C.N.R.Rao, Kanishka Biswas, K. S. Subrahmanyam, A. Govindaraj, Graphene, the new nanocarbon[J],J. Mater. Chem., 2009, 19, 2457–2469
[30]杨全红,唐致远,新型储能材料———石墨烯的储能特性及其前景展望[J],电源技术,2009,33,241-244
[31] Journet C, Maser WK, Bernier P, Loisear A, et al. Large-scale production of single-walled carbon nanotubes by the electric-arctechnique[J],Nature 1997, 388,756-758
[32] Rinzler AG ,Liu J, Dai H, Nikolaev P, Huffman CB, et al. Large-scale purification of single-wall carbon nanotubes:process,product,and characterization[J],Appl Phys A 1998,67(1):29-37
[33] Dai HJ, Wong W, Lu Y, Fan S. Lieber. Synthesis and characterization of carbide nanorods [J],Nature,1995;375:769-772
[34] Endo M, Takeuchi K, KoboriK,Takahashi K, Kroto HW, Sarkar A. Pyrolytic Carbon nanotubes from vapor-grow carbon fibers [J].Carbon,1995, 33,873-881
[35] Tao Tang, Xuecheng Chen, Xiaoyu Meng, Hui Chen,and Yaping Ding, Synthesis of Multiwalled Carbon Nanotubes by Catalytic Combustion of Polypropylene[J],Angew. Chem. Int. Ed. 2005,44,1517–1520
[36]唐涛等,一种碳纳米管材料的制备方法[P],中国专利:CN 1600683A.
[37]唐涛等,燃烧聚烯烃合成碳纳米管的方法[P],中国专利:CN 1636868A.
[38]唐涛等,镍氧化物催化燃烧聚烯烃合成碳纳米管及复合物的方法[P],中国专利:CN 1699154A.
[39]唐涛等,聚烯烃催化裂解制备氢气和碳纳米管[P],中国专利:CN 1760114A.
[40] Keun Soo Kim,Yue Zhao,Houk Jang, Sang Yoon Lee, Jong Min Kim, Kwang S. Kim, Jong-Hyun Ahn, Philip Kim, Jae-Young Choi,Byung Hee Hong,Large-scale pattern growth of graphene films for stretchabletransparent electrodes [J].Nature,2009,457, 706-710
[41] B. C. Brodie, On the atomic weight of graphite, Phil. Trans. Roy. Soc., 1859,149,249-259
[42] L. Staudenmaier, Verfahren Zur Darstellung Der Graphitsaure, Ber. Dtsh. Chem.Ges., 1898, 31,1481-1499
[43] Hummers, W. S. ,Offeman, R. E. ,Preparation of graphite oxide.[J], J. Am. Chem. Soc.,1958,80,1339
[44] Jian Chen; Mark A. Hamon; Hui Hu; Yongsheng Chen; Apparao M. Rao; Peter C. Eklund; Robert C. Haddon, Solution Properties of Single-Walled Carbon Nanotubes[J],Science, 282, 95-98.
[45] Yuehe Lin, Fang Lu, Joseph Wang, Disposable Carbon Nanotube Modified Screen-Printed Biosensor for Amperometric Detection of Organophosphorus Pesticides and Nerve Agents[J],Electroanalysis, 2004,145-149
[46] Jie Liu, Andrew G. Rinzler, Hongjie Dai, Jason H. Hafner, R. Kelley Bradley, Peter J. Boul, Adrian Lu, Terry Iverson, Konstantin Shelimov, Chad B. Huffman, Fernando Rodriguez-Macias, Young-Seok Shon, T. Randall Lee, Daniel T. Colbert, and Richard E. Smalley, Fullerene Pipes[J], Science,1998,280, 1253-1256
[47] E.T. Mickelson , C.B. Huffman , A.G. Rinzler , R.E. Smalley , R.H. Hauge,J.L. Margrave,Fluorination of single-wall carbon nanotubes[J] , Chem. Phys. Lett.,1998,296,188–194
[48] B. Katherine Price and James M. Tour,Functionalization of Single-Walled Carbon Nanotubes“On Water”,[J]. J Am. Chem. Soc. 2006, 128, 12899-12904
[49] Jay R. Lomeda, Condell D. Doyle, Dmitry V. Kosynkin, Wen-Fang Hwang, andJames M. Tour, Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets[J], J. Am. Chem. Soc. 2008, 130, 16201–16206
[50] Chen R J,Zhang Y G,Dai H J et al, Nocovalent Sidewall Functionalzation of Single-Walled Carbon Nanotubes for Protein Immobilization[J], J.Am.Chem.Soc.,2001,123,3838-383
[51] Zhuang Liu, Joshua T. Robinson, Xiaoming Sun, and Hongjie Dai,PEGylated Nanographene Oxide for Delivery of Water-InsolubleCancer Drugs[J] J. Am. Chem. Soc. 2008, 130, 10876–10877
[52] Michael J. O Connell, Peter Boul, Lars M. Ericson,Chad Huffman, Yuhuang Wang, Erik Haroz, Cynthia Kuper, Jim Tour, Kevin D. Ausman and Richard E. Smalley, Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping[J],Chem. Phys. Lett,2001 342, 265-271
[53] Wei-De Zhang,In Yee Phang, and Tianxi Liu , Growth of Carbon Nanotubes on Clay: Unique Nanostructured Filler for High-Performance Polymer Nanocomposites[J],Adv. Mater. 2006, 18, 73–77
[54] M.F.DeRiccardis ,D.Carbone,Th.DikonimosMakris,R.Giorgi,N.Lisi,E.Salernitano, Anchorage of carbon nanotubes grown on carbon fibres[J],Carbon 44 (2006) 671–674
[55] Pulickel M.Ajayan and James M.Tour, Nanotubes composites[J], Nature,2007,447,1066-1068
[56] Haggenmueller R, Gommans HH, Rinzler AG, Fischer JE, Winey KI. Aligned single-wall carbon nanotubes in composites by melt processing methods[J],Chem .Phys .Lett. 2000;330:219-225.
[57] Jun’ichi Masuda,John M. Torkelson,Dispersion and Major Property Enhancements in Polymer/Multiwall Carbon Nanotube Nanocomposites via Solid-State Shear Pulverization Followed by Melt Mixing[J], Macromolecules 2008, 41, 5974-5977
[58] Potschke P, Fornes TD,; Paul DR. Dielectric spectroscopy on melt processed polycarbonate-multiwalled carbon nanotube composites[J], Polymer,2002,43,3247-3255
[59] Fangming Du, John.E. Fischer, Karen I. Winey,Coagulation Method for Preparing Single-Walled Carbon Nanotube/Poly(methyl methacrylate) Composites and Their Modulus, Electrical Conductivity, and Thermal Stability[J],J. Polym. Sci., Part B: Polym. Phys., 2003, 41,3333–3338
[60] T. Ramanathan, A.A.Abdala, S.Stankovich, D.A.Dikin, M.Herrera-Alonso,R.D.Piner, D.H.Adamson, H.C.Schniepp, X.Chen, R.S.Ruoff, S.T.Nguyen,I.A.Aksay, R.K.Prud’Homme, L.C.Brinson,Functionalized graphene sheets for polymer nanocomposites[J],Nature nanotechnology, 2008,3,327-331
[61] Chang-Eui Hong, Joong-Hee Lee, Prashantha Kalappa, Suresh G.Advani,Effects of oxidative conditions on properties of multi-walled carbon nanotubes in polymer nanocomposites [J],Compos. Sci. Technol., 2007,67 ,1027–1034
[62] S. Kanagaraj , Fa′tima R. Varanda, Tatiana V. Zhil’tsova, Mo′nica S.A. Oliveira,Jose′A.O. Simo?es,Mechanical properties of high density polyethylene/carbon nanotube composites[J],Compos.Sci. Technol.,2207, 67,3071–3077
[63] Sasha Stankovich, Dmitriy A. Dikin, Geoffrey H. B. Dommett, Kevin M. Kohlhaas, Eric J. Zimney, Eric A. Stach, Richard D. Piner, SonBinh T. Nguyen,Rodney S.Ruoff,Graphene-based composite materials[J],Nature, 2006,442,282-286
[64] P. M. Ajayan, O. Stephan, C. Colliex, D. Trauth,Aligned Carbon Nanotube Arrays Formed by Cutting a Polymer Resin-Nanotube Composite[J] , Science,1994,265, 1212-1214.
[65] M.C. Paiva, B. Zhou, K.A.S. Fernando, Y. Lin, J.M. Kennedy, Y.-P. Sun,Mechanical and morphological characterization of polymer–carbon nanocomposites from functionalized carbon nanotubes[J] ,Carbon,2004,42,2849–2854
[66] S.L. Ruan, P. Gao, X.G. Yang, T.X. Yu,Toughening high performance ultrahigh molecular weight polyethylene using multiwalled carbon nanotubes,Polymer ,2003;44:5643-5654.
[67] Jeong-Ho Ko, Jin-Hae Chang,Properties of Ultrahigh-Molecular-Weight Polyethylene Nanocomposite Films Containing Different Functionalized Multiwalled Carbon Nanotubes[J] ,Polym. Eng. Sci. ,2009,2168-2178
[68] Silvia Villar-Rodil, Juan. I. Paredes, Amelia Mart?′nez-Alonso ,Juan. M. D. Tascon,Preparation of graphene dispersions and graphene-polymer composites in organic media[J] ,J. Mater. Chem., 2009, 19, 3591–3593
[69] Mohammad A. Rafiee, Javad Rafiee, Iti Srivastava, Zhou Wang, Huaihe Song,Zhong-Zhen Yu, and Nikhil Koratkar, Fracture and Fatigue in Graphene Nanocomposites[J], Small,2010, 6, No. 2, 179–183
[70] Carlos Velasco-Santos, Ana L. Mart?′nez-Herna′ndez, Frank T. Fisher,Rodney Ruoff, Victor M. Castan o,Improvement of Thermal and Mechanical Properties of Carbon Nanotube Composites through ChemicalFunctionalization[J] ,Chem. Mater. 2003, 15, 4470-4475
[71] Duc Anh Nguyen,Yu Rok Lee,Anjanapura V Raghu,HanMo Jeong,CheolMin Shin,Byung Kyu Kim,Morphological and physical properties of athermoplastic polyurethane reinforced with functionalized graphene sheet[J] ,Polym Int. 2009; 58: 412–417
[72] Huating Hu, Xianbao Wang, Jingchao Wang, Li Wan, Fangming Liu, Han Zheng, Rong Chen, Chunhui Xu,Preparation and properties of graphene nanosheets-polystyrene nanocomposites via in situ emulsion polymerization [J] ,Chem. Phys. Lett. ,2010,484,247–253
[73] Bonner W H.[P] USA patent 3065205,1962.
[74] Rose J B.[P] USA patent 4320224,1976.
[75] Rose J B.[P] Britian patent 1558671,1976.
[76] Rose J B.[P] Britian patent 1414422,1975.
[77] Rose J B.[P] Britian patent 1414423,1975.
[78] Rose J B.[P] Britian patent 1414424,1975.
[79] http://www.jusep.com.cn/cpjs.html
[80] M.Rama Rao,V.L.Rao,T.S.Radhakrishnan,S.Ramachandran.Synthesis、characterization and thermal degradation studies of poly(ether ether ketone)copolymers[J].Polymer,1992,33,2834-2839
[81] Ming Chen ,Jang-Yang Chen. Analysis of Crystallization Kinetics of Poly(ether ether ketone)[J].J.Polym.Sci,PartB:Polym.phys,1998,36 1348-1355.
[82]田爱国,纳米氧化铝粉体填充增强聚醚醚酮复合材料及其性能研究[D],上海材料研究所硕士学位论文,2002,1-30
[83]陶国源,聚醚醚酮应用实例(下)[J],塑料制造,2006,46-51
[84] http://www.victrex.com
[85] Bhanu Nandan, L. D. Kandpal, G. N. Mathur,Poly(ether ether ketone) /Poly(aryl ether sulfone) Blends:Relationships Between Morphology and Mechanical Properties[J],J. Appl. Polym. Sci., 2003, 90,2887–2905
[86] R. Gensler, Ph. B6guelin , C. J. G. Plummer , H.-H. Kausch , H. Miinstedt,Tensile behaviour and fracture toughness of poly(ether ether ketone)/poly(ether imide) blends[J],Polym. Bull.,1996,37, 111-118
[87] Alain M. Jonas, Dimitri A. Ivanov, and Do Y. Yoon,The SemicrystallineMorphology of Poly(ether?ether?ketone) Blends with Poly(ether?imide) [J] ,Macromolecules 1998, 31, 5352-5362
[88] Yong Sung Chun, Heon Sang Lee, Hyun Chul Jung, Woo Nyon Kim,Thermal Properties of Melt-Blended Poly(ether ether ketone) and Poly(ether imide)[J] ,J. Appl. Polym. Sci., 1999,72, 733–739
[89] Anjum Saleem, Lars Frormann, Azhar Iqbal , High Performance Thermoplastic Composites: Study on the Mechanical, Thermal, and Electrical Resistivity Properties of Carbon Fiber-Reinforced Polyetheretherketone and Poly ether sulphone [J],Polym. Compos, 2007,785-796
[90] R. A. Crick, D.C.Leach, P.J.Meakin, D.R.Moore,Interlaminar fracture morphology of carbon fibre/PEEK composites[J],J.Mater. Sci,1987, 22,2094-2104
[91] Chi-Cherng Jeng, Ming Chen,Flexural failure mechanisms in injection -moulded carbon fibre/PEEK composites[J],Compos.Sci. Technol.,2000, 60,1863-1872
[92] M.S. Abu Bakar , P. Cheang , K.A. Khor,Tensile properties and microstructural analysis of spheroidized hydroxyapatite/poly(etherether ketone) biocomposites[J] ,Mater. Sci. Eng. A,2003,345, 55-/63
[93] R.K. Goyal , A.N. Tiwari , U.P. Mulik , Y.S. Negi, Effect of aluminum nitride on thermomechanical properties of high performance PEEK[J], Composites: Part A 38 (2007) 516–524
[94] R. K. Goyal,A. N. Tiwari,U. P. Mulik,Y. S. Negi, Study on Microhardness, Dynamic Mechanical, andTribological Properties of PEEK/Al2O3 Composites[J], J. Appl. Polym. Sci,2008, 110, 3379–3387
[95] Y.H. Lai , M.C. Kuo , J.C. Huang, M. Chen,On the PEEK composites reinforced by surface-modified nano-silica[J],Mater. Sci. Eng. A,2007, 458,158–169
[96] Pan Guoliang, Guo Qiang, Tian Aiguo, He Zhiqiang,Mechanical behaviors of Al2O3 nanoparticles reinforced polyetheretherketone[J] , Mater. Sci. Eng.A,2008, 492 ,383–391
[97] Jan Sandler, Philipp Werner, Milo S.P. Shaffer, Vitaly Demchuk, Volker Altsta¨dt,Alan H. Windle,Carbon-nanofibre-reinforced poly(ether etherketone) composites[J] ,Composites: Part A,2002,33,1033–1039
[98] J.Sandler,A.H.Windle,P.Werner,V.Altsta¨DT,M.V.ES,M.S.P.Shaffer,Carbon-nanofibre-reinforced poly(ether ether ketone) fibres[J],J. Mater. Sci,2003,38,2135– 2141
[99] Philipp Werner, Volker Altst¨adt, Romy Jaskulk, Olaf Jacobs,Jan K.W. Sandler, Milo S.P. Shaffer, Alan H. Windle,Tribological behaviour of carbon-nanofibre-reinforcedpoly(etheretherketone)[J] ,Wear,2004,257,1006–1014
[100] Philipp Werner, Raquel Verdejo, Frank W?llecke,Volker Altst?dt, Jan K. W. Sandler,Milo S. P. Shaffer,Carbon Nanofibers Allow Foaming of Semicrystalline Poly(ether ether ketone)[J],Adv. Mater. 2005,17,2864–2869
[101] Raquel Verdejo ,Philipp Werner ,Jan Sandler,Volker Altsta¨dt ,M. S. P. Shaffer,Morphology and properties of injection-moulded carbon- nanofibre poly(etheretherketone) foams[J],J Mater Sci ,2009,44,1427–1434
[102] Li Song, Hui Zhang, Zhong Zhang, Sishen Xie,Processing and performance improvements of SWNT paper reinforced PEEK nanocomposites [J],Composites: Part A,2007,38,388–392
[103] Fei Deng, Toshio Ogasawara, Nobuo Takeda,Tensile properties at different temperature and observation of micro deformation of carbon nanotubes–poly(ether ether ketone) composites[J],Compos. Sci. Technol. , 2007,67,2959–2964
[104] Ana M. D?′ez-Pascual, Mohammed Naffakh, Maria′n A. Go′mez, Carlos Marco,Gary Ellis,M. Teresa Mart?′nez, Alejandro Anso′n, Jose′M. Gonza′lez-Dom?′nguez,Yadienka Mart?′nez-Rubi, Benoit Simard,Development and characterization of PEEK/carbon nanotube Composites [J],Carbon, 2009,47,079–3090
[105] A M.D′?ez-Pascual,M Naffakh,M A.G′omez, C.Marco,G Ellis,J M Gonz′alez-Dom′?nguez,A Ans′on,M T Mart′?nez,Y Mart′?nez-Rubi, B Simard,B Ashrafi,The influence of a compatibilizer on the thermal and dynamic mechanical properties of PEEK/carbon nanotube Composites[J], Nanotechnology,2009,20,315707,1-13
[106] Se-Jin Oh, Hwa-Jeong Lee,Dong-Ki Keum, Seong-Woo Lee,David H. Wang,Soo-Young Park,Loon-Seng Tan,Jong-Beom Baek,Multiwalledcarbon nanotubes and nanofibers grafted with polyetherketones in mild and viscous polymeric acid[J],Polymer,2006,47,1132–1140
[107] Ja-Young Choi,Sang-Wook Han, Wan-Soo Huh,Loon-Seng Tan, Jong-Beom Baek,In situ grafting of carboxylic acid-terminated hyperbranched poly(ether-ketone) to the surface of carbon nanotubes[J] , Polymer, 2007,48,4034-4040
[108] Ja-Young Choi,Se-Jin Oh,Hwa-Jeong Lee,David H. Wang,Loon-Seng Tan,Jong-Beom Baek,In-Situ Grafting of Hyperbranched Poly(ether ketone)s onto Multiwalled Carbon Nanotubes via the A3+B2 Approach [J] ,Macromolecules 2007, 40, 4474-4480
[109] In-Yup Jeon,Loon-Seng Tan,Jong-Beom Baek,Nanocomposites Derived from In Situ Grafting of Linear and Hyperbranched Poly(ether-ketone)s Containing Flexible Oxyethylene Spacers onto the Surface of Multiwalled Carbon Nanotubes[J],J. Appl. Polym. Sci: Part A: Polymer Chemistry, 2008,46, 3471–3481
[110] David H. Wang, Peter Mirau, Bing Li, Christopher Y. Li, Jong-Beom Baek, Loon-Seng Tan,Solubilization of Carbon Nanofibers with a Covalently Attached Hyperbranched Poly(ether ketone)[J] ,Chem. Mater. 2008, 20, 1502–1515
[111]李先锋,磺化聚芳醚酮类质子交换膜材料的结构与性能研究[D],吉林大学博士学位论文,2006,1-33
[112] P. Sivaraman, V.R. Hande, V.S. Mishra, Ch. Srinivasa Rao, A.B. Samui, All-solid supercapacitor based on polyaniline and sulfonated poly(ether ether ketone), J. Power Sources,2003, 124 ,351–354
[113] P. Sivaraman, R.K. Kushwaha, K. Shashidhara, V.R. Hande, A.P. Thakur,A.B. Samui, M.M. Khandpekar,All solid supercapacitor based on polyaniline and crosslinked sulfonated poly[ether ether ketone][J], Electrochim. Acta ,2010,55 ,2451–2456
[114] Rapee Gosalawit, Suwabun Chirachanchai, Sergey Shishatskiy, Suzana P. Nunes,Sulfonated montmorillonite/sulfonated poly(ether ether ketone) (SMMT/SPEEK) nanocomposite membrane for direct methanol fuel cells (DMFCs)[J],J. Membr. Sci.,2008,323,337–346
[115] Seung-Hee Park,Jin-Soo Park,Sung-Dae Yim,Seok-Hee Park,Young-MooLee,Chang-Soo Kim,Preparation of organic/inorganic composite membranes using two types of polymer matrix via a sol–gel process[J],J. Power Sources,2008,181,259–266
[116]李会巧,超级电容器及其相关材料的研究[D],复旦大学博士学位论文,2008,2-6
[117] Dong-Won Kim, Jang Myoun Ko, Wan Ju Kim, Jong Huy Kim, Study on the electrochemical characteristics of quasi-solid-state electric double layer capacitors assembled with sulfonated poly(ether ether ketone)[J], J. Power Sources,2006, 163 ,300–303
[118] Wan Ju Kim, Dong-Won Kim, Sulfonated poly(ether ether ketone) membranes for electric double layer capacitors[J],Electrochimica Acta,2008, 53,4331–4335
[119] M. Lai,J. Liu,Thrmal and dynamic mechanical properties of PES/PPS blends,Journal of Thermal Analysis and Calorimetry, 2004,77,935–945
[120] M. Garc?′a, J. I. Eguiaza′bal, J. Naza′bal, Reinforced Poly(ether sulfone) Materials by Blending with a Semiaromatic Liquid Crystalline Copolyester [J], Journal of Applied Polymer Science, 2004, 91, 52–59
[121] M. Garc?′a, J.I. Eguiaza′bal, J. Naza′bal, Two scale reinforcement in hybrid composites based on poly(ether sulfone), glass fiber and liquid crystalline polymer[J], Compos. Sci. Technol .2003,63, 2163–2170
[122] G. M. Wu,J. M. Schultz,Processing and Properties of Solution Impregnated Carbon Fiber Reinforced Poly ether sulfone Composites[J],Polym. Compos., 2000, 21,223-230
[123] J. Bijwe, S. Awtade B.K. Satapathy, A. Ghosh, Influence of concentration of aramid fabric on abrasive wear performance of polyethersulfone composites[J], Tribology Letters,2004,17,187-194
[124] J. Bijwe, S. Awtade , A. Ghosh, Influence of orientation and volume fraction of Aramid fabric on abrasive wear performance of polyethersulfone composites[J], Wear ,2006,260 ,401–411
[125] Sadhan C.Jana,Sachin Jain,Dispersion of nanofillers in high performance polymers using reactive solvents as processing aids[J],Polymer,2001, 42,6897-6905
[126] Guiping Wu, Shuying Gan, Longzhe Cui, Youyi Xu,Preparation andcharacterization of PES/TiO2 composite membranes[J],Appl.Surf. Sci,2008,254,7080–7086
[1] Gan Lin Hwang,Yeong-Tarng,Kuo Chu Shieh, Efficient load transfer to polymer-grafted multiwalled carbon nanotubes in polymer composites[J]. Adv. Funct. Mater. 2004;14:487-491
[2] Rowan Blake, Jonathan N. Coleman, Michele T. Byrne, Joseph E. McCarthy,Tatiana S. Perova,Werner J. Blau,Antonio Fonseca,Janos B. Nagy and Yurii K. Gun’ko. Reinforcement of poly(vinyl chloride) and polystyrene using chlorinated polypropylene grafted carbon nanotubes[J]. J. Mater. Chem. 2006; 16: 4206–4213
[3] Anton A. Koval’chuk, Vitaliy G. Shevchenko, Alexander N. Shchegolikhin,Polina M. Nedorezova, Alla N. Klyamkina, and Alexander M. Aladyshev.Effect of Carbon Nanotube Functionalization on the structural and mechanical properties of polypropylene/MWCNT composites[J]. Macromolecules,2008; 41:7536-7542
[4] Hye Jin Yoo, Yong Chae Jung, Jae Whan Cho. Effect of interaction between poly(ethylene terephthalate) and carbon nanotubes on the morphology and properties of their nanocomposites[J], J. Polym. Sci: Part B: Polymer Physics,2008,46,900–910
[5] Jian Chen, Mark A. Hamon, Hui Hu, Yongsheng Chen,Apparao M. Rao, Peter C. Eklund, Robert C. Haddon. Solution properties of single-walled carbon nanotubes. Science,1998,282,95-98
[6] Douglas B. Mawhinney, Viktor Naumenko, Anya Kuznetsova, John T. Yates, J. Liu, and R. E. Smalley. Infrared spectral evidence for the etching of carbon nanotubes: ozone oxidation at 298 K[J]. J. Am. Chem. Soc. 2000,122(10),2383–2384
[7] Bing Zhou, Xiangbo Ji, Ye Sheng, Lifeng Wang, Zhenhua Jiang. Mechanical and thermal properties of poly-ether ether ketone reinforced with CaCO3. Eur. Polym. J.2004; 40:2357–2363
[8]周兵,CaCO3/PEEK复合材料的制备与性能研究[D],吉林大学博士学位论文,2004,46
[9] J Jin, M Song, F Pan.A DSC study of effect of carbon nanotubes on crystallisation behaviour of poly(ethylene oxide)[J]. Thermochimica Acta ,2007; 456:25–31
[10] H Meng, GX Sui, PF Fang, R Yang. Effects of acid- and diamine-modified MWNTs on the mechanical properties and crystallization behavior of polyamide 6[J]. Polymer,2008,49,610-620
[11] Jinghui Yang , Tao Xu , Ai Lu, Qin Zhang, Hong Tan , Qiang Fu, Preparation and properties of poly (p-phenylene sulfide)/multiwall carbon nanotube composites obtained by melt compounding[J].Compos. Sci. Technol 2009,69,147-153
[12] M.A. Lo′pez Manchado, L. Valentini b, J. Biagiotti, J.M. Kenny. Thermal and mechanical properties of single-walled carbon nanotubes–polypropylene composites prepared by melt processing[J]. Carbon,2005, 43,1499–1505
[13] Biao Wang, Guangping Sun, Jingjiang Liu, Xiaofeng He,Jing Li. Crystallization behavior of carbon nanotubes-filled polyamide 1010[J]. J. Appl. Polym. Sci,2006,100,3794–3800
[14]李娟,碳纳米管/尼龙6复合材料的结构与性能研究[D],浙江大学博士学位论文,2006,108-120
[15]赵焱,聚醚醚酮(PEEK)/有机化蒙脱土(OMMT)复合材料的制备及性能研究[D],吉林大学博士学位论文,2009,54-59
[16] Melvin Avrami. Kinetics of phase changⅡ,Transformation-time relations for radom distribution of nucei [J]. J. Chem. Phys. 1940;8:212-224
[1]赵择卿,陈小立,高分子材料导电和抗静电技术及应用[M],中国纺织出版社,2006,391
[2]熊佳,导电复合材料的制备及其性能的研究,西北工业大学硕士学位论文[D],2005,3
[3]杨波,炭黑/聚丙烯导电复合材料的电性能和形态研究[D],四川大学硕士学位论文[D],2007,5
[4] Stenger-Smith.J.D,Intrinsically electrically conducting polymers Synthesis, characterization, and their application [J].Prog Polym Sci,1998, 23,57-79
[5] R. M. Scarisbrick. Electrically conducting mixtures [J] J. Phys. D: Appl. Phys,1973,6,2098-2110
[6] C.Rajagopal,M.Satyam.Studies on electrical conductivity of insulator-conductor composites [J] J Appl. Phys., 1978, 49, 5536
[7] S. Miyauchi. The conduction mechanism of polymer-filler particles [J]. J. Appl. Polym. Sci,1985, 30, 2743
[8] Xianqiang Pei,Yan Li ,Qihua Wang, Xiaojun Sun, Effects of atomic oxygen irradiation on the surface properties of phenolphthalein poly(ether sulfone)[J], Appl. Surf. Sci. 255 (2009) 5932–5934
[9] Jiachun Feng , Guian Wen ,Wei Huang , En-Tang Kang ,Koon Gee Neoh, Influence of oxygen plasma treatment on poly(ether sulphone) films[J], Polym. Degrad. Stab ,2006,91, 12-20
[10] S.M. Kang, S.G. Yoon , D.H. Yoon, Surface treatment of polycarbonate and polyethersulphone for SiNx thin film deposition[J], Thin Solid Films,2008,516, 1405–1409
[11] Jinghui Yang, Tao Xu , Ai Lu, Qin Zhang, Hong Tan, Qiang Fu, Preparation and properties of poly (p-phenylene sulfide)/multiwall carbon nanotube composites obtained by melt compounding[J], Compos. Sci. Technol, 2009,69,147–153
[1] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, A. A. Firsov ,Electric Field Effect in Atomically Thin Carbon Films[J], Science,2004,306,666-669
[2] Matthew J. Allen,Vincent C. Tung, Richard B. Kaner, Honeycomb Carbon: A Review of Graphene[J], Chem. Rev. 2010, 110, 132–145
[3] Eun-Young Choi, Tae Hee Han,Jihyun Hong,Ji Eun Kim,Sun Hwa Lee, Hyun Wook Kima, Sang Ouk Kim, Noncovalent functionalization of graphene with end-functional polymers[J], J. Mater. Chem., 2010, 20, 1907–1912
[4] Ming Fang, Kaigang Wang, Hongbin Lu, Yuliang Yang, Steven Nutt, Single-layer graphene nanosheets with controlled grafting of polymer chains[J], J. Mater. Chem., 2010, 20, 1982–1992
[5] DW Boukhvalov and M I Katsnelson, Chemical functionalization of graphene[J], J. Phys. Condens. Matter ,2009,21, 344205,1-12
[6] Dongyu Cai, Kamal Yusoh , Mo Song, The mechanical properties and morphology of a graphite oxide,nanoplatelet/polyurethane composite[J], Nanotechnology, 2009,20,085712,1-5
[7] Dongyu Cai ,Mo Song,A simple route to enhance the interface between graphite oxide nanoplatelets and a semi-crystalline polymer for stress transfer[J], Nanotechnology ,2009,20,315708,1-6
[8] Xin Zhao, Qinghua Zhang, Dajun Chen, Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites[J] Macromolecules , 2010, 43, 2357–2363
[9] Hummers, W. S. ,Offeman, R. E. ,Preparation of graphite oxide.[J],J. Am. Chem. Soc.,1958,80,1339
[10] Wei Gao,Lawrence B. Alemany, Lijie Ci, Pulickel M. Ajayan, New insights into the structure and reduction of graphite oxide[J], Nature Chemistry ,2009, 1, 403–408
[11] Meyer.Jannik.C.,Geim.A.K.,Katsnelson.M.I.,Novoselov.K.S.,Booth,T.J.,Roth.S.,The structure of suspended graphene sheets[J], Nature,2007,446,60-63
[12] Zou H, Xu W, Zhang Q, et al. Effect of alkylammonium salt on the dispersion and properties of Poly(p-phenylene sulfide)/clay nanocomposites via melt intercalation[J],.Journal of Applied Polymer Science,2006,99,1724
[13]赵焱,聚醚醚酮(PEEK)/有机化蒙脱土(OMMT)复合材料的制备及其性能研究[D],吉林大学博士学位论文,2008,40-60
[1] B.E.康维著,陈艾等译,电化学超级电容器[M],化学工业出版社,2005,556-615
[2] Mehrdad Ehsani,Yimin Gao等著,倪匡正等译,现代电动汽车、混合动力电动车和燃料电池车-基本原理、理论和设计[M],机械工业出版社,2008,267-283
[3] Kim.J.H.,Myung S.T., Yoo C.S.,Kang S.G.et al ,Comparative study of LiNi0.5Mn1.5O4-delta and LiNi0.5Mn1.5O4 cathodes having two crystallographic structures:Fd(3)over-barm and p4(3)32[J], Chem.Mater., 2004,16,906
[4] Zhang L.L, Zhao X.S, Carbon-based materials as supercapacitor electrodes[J], Chem. Soc. Rev., 2009, 38, 2520–2531
[5] Meryl D. Stoller, Sungjin Park, Yanwu Zhu, Jinho An, and Rodney S. Ruoff, Graphene-Based Ultracapacitors[J],Nano letter,2008,8,498-3502
[6] Yan Wang,Zhiqiang Shi,Yi Huang,Yanfeng Ma, Chengyang Wang,Mingming Chen,Yongsheng Chen, Supercapacitor Devices Based on Graphene Materials[J], J. Phys. Chem. C 2009, 113, 13103–13107
[7] S R C Vivekchand, Chandra Sekhar Rout, K S Subrahmanyam,A Govindaraj,C N R Rao, Graphene-based electrochemical supercapacitors[J], J. Chem. Sci.,2008,120, 9–13
[8]袁国辉,电化学电容器[M],化学工业出版社,2006,23-120
[9]殷金玲,凝胶聚合物电解质超级电容器的研究[D],哈尔滨工程大学2007,2-30
[10] S. J. Park, K. S. Lee, G. Bozoklu, Graphene oxide papers modified by divalent ions-Enhancing mechanical properties via chemical cross-linking, ACS Nano,2008, 23:572~578
[11] Kim W.J, Kim D.W., Sulfonated poly(ether ether ketone) membranes or electric double layer capacitors[J], Electrochimica Acta,2008,53, 4331–4335
[2] Sumio Iijima, Helical microtubules of graphitic carbon[J],Nature,354,1991, 56-58
[3] T. W. Ebbesen, P. M. Ajayan, Large-scale synthesis of carbon nanotubes[J], Nature,1992,358, 220-222
[4] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov ,Electric Field Effect in Atomically Thin Carbon Films[J],Science,2004,306,666-669
[5] A. K. Geim, K. S. Novoselov,The rise of graphene[J],Nat. Mater,2007,6, 183-191
[6] Mikhail I. Katsnelson,Graphene :carbon in two dimensions[J], Mater. Today, 2007,10,20-27
[7]成会明,纳米碳管制备、结构、物性及应用[M],化学工业出版社,2002,1-150
[8]王春,纳米金刚石、碳纳米管、石墨烯性能的第一原理研究[D],吉林大学博士学位论文,2009,1-11
[9] 0.Zhou,R. M. Fleming,D. W. Murphy, C. H. Chen,R. C. Haddon, A. P. Ramirez,S. H. Glarum,Defects in Carbon Nanostructures[J],Science,1994, 263,1744-1747
[10] S Amelinckx, A Lucas,P Lambin,Electron diffraction and microscopy of nanotubes[J],Rep. Prog. Phys. ,1999,62,1471–1524
[11]李海东,石墨烯纳米结构中的电子输运性质[D],吉林大学博士学位论文,2009,1-30
[12] Elena Stolyarova, Kwang Taeg Rim, Sunmin Ryu, Janina Maultzsch, Philip Kim, Louis E. Brus, Tony F. Heinz, Mark S. Hybertsen, George W. Flynn,High-resolution scanning tunneling microscopy imaging of mesoscopic graphene sheets on an insulating surface [J],PNAS,2007,104, 9209–9212
[13] Changgu Lee, Xiaoding Wei,Jeffrey W. Kysar,James Hone, Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene[J],Science, 2008,321,385-388
[14] Eric W. Wong,Paul E. Sheehan,Charles M. Lieber, Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes, Science,1997,277,1971-1975
[15] Nikolaos Tombros, Csaba Jozsa, Mihaita Popinciuc, Harry T. Jonkman,Bart J. van Wees, Electronic spin transport and spin precession in single graphene layers at room temperature[J],Nature, 2007, 448: 571-575
[16] K.S. Novoselov, Z. Jiang, Y. Zhang, S.V. Morozov, H.L. Stormer, U. Zeitler, J.C.Maan, G.S. Boebinger, P. Kim, A.K. Geim, Room-temperature quantum hall effect in graphene[J],Science, 2007, 315,1379-1379
[17] Robert F. Service,Carbon Sheets an Atom Thick Give Rise to Graphene Dreams[J],Science,2009,324, 875-877
[18] Kong J ,Zhou C,Yenilmez E,et al. Alkaline metal-doped n-type semiconducting nanotubes as quantum dots [J],Appl Phys Lett. 2000, 77,3977-3980
[19] Jiangtao Hu,Chemistry and physics in one dimension synthesis and properties of nanowires and nanotubes[J],ACC,Chem,Res,1999,32,435-44
[20] Baughman.RH; Zakhidov. AA,de Heer.WA, Carbon nanotubes-the route toward applications[J],Science,297,2002,787-792
[21] Yu, MF; Lourie,O; Dyer, MJ, et al.,Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load,Science,2000, 287,637-640
[22] Teri Wang Odom ,Atomic structure and electronic properties of single-walled carbon nanotubes[J],Nature,1998,391,62-64
[23] Grimes C.A., Mangle C., Kouzoudis D., et al. The 500MHz to 5.50GHz Complex Permittivity Spectra of Single-wall Carbon Nanotubes-loaded Polymer Composites[J],Chem. Phys. Lett. 2000, 319: 460-464.
[24] Li N, Huang Y, Du F et al Electromagnetic Interference (EMI)Shielding of Single-Walled Carbon Nanotube Epoxy Composites[J],Nano Lett.,6, 2006, 111-1145
[25] Ma C M., Huang Y L, Kuan H C,et al .Preparation and Electromagnetic Interference shielding characteristics of novel carbon-nantubes /siloxane (urea urethane) nanocomposites[J],J. Polym. Sci., Part B: Polym. Phys., 2005, 43, 345–358
[26]郭平生,碳纳米材料化学气相沉积制备及其场发射显示器研究[D],华东师范大学博士学位毕业论文2006,14-30
[27] Michael J. O’Connell ,Carbon Nanotubes Properties and Applications[M], CRC Press, 2006,83-119
[28] Yury Gogotsi, Carbon Nanomaterials[M],CRC Press, 2006,255-316
[29] C.N.R.Rao, Kanishka Biswas, K. S. Subrahmanyam, A. Govindaraj, Graphene, the new nanocarbon[J],J. Mater. Chem., 2009, 19, 2457–2469
[30]杨全红,唐致远,新型储能材料———石墨烯的储能特性及其前景展望[J],电源技术,2009,33,241-244
[31] Journet C, Maser WK, Bernier P, Loisear A, et al. Large-scale production of single-walled carbon nanotubes by the electric-arctechnique[J],Nature 1997, 388,756-758
[32] Rinzler AG ,Liu J, Dai H, Nikolaev P, Huffman CB, et al. Large-scale purification of single-wall carbon nanotubes:process,product,and characterization[J],Appl Phys A 1998,67(1):29-37
[33] Dai HJ, Wong W, Lu Y, Fan S. Lieber. Synthesis and characterization of carbide nanorods [J],Nature,1995;375:769-772
[34] Endo M, Takeuchi K, KoboriK,Takahashi K, Kroto HW, Sarkar A. Pyrolytic Carbon nanotubes from vapor-grow carbon fibers [J].Carbon,1995, 33,873-881
[35] Tao Tang, Xuecheng Chen, Xiaoyu Meng, Hui Chen,and Yaping Ding, Synthesis of Multiwalled Carbon Nanotubes by Catalytic Combustion of Polypropylene[J],Angew. Chem. Int. Ed. 2005,44,1517–1520
[36]唐涛等,一种碳纳米管材料的制备方法[P],中国专利:CN 1600683A.
[37]唐涛等,燃烧聚烯烃合成碳纳米管的方法[P],中国专利:CN 1636868A.
[38]唐涛等,镍氧化物催化燃烧聚烯烃合成碳纳米管及复合物的方法[P],中国专利:CN 1699154A.
[39]唐涛等,聚烯烃催化裂解制备氢气和碳纳米管[P],中国专利:CN 1760114A.
[40] Keun Soo Kim,Yue Zhao,Houk Jang, Sang Yoon Lee, Jong Min Kim, Kwang S. Kim, Jong-Hyun Ahn, Philip Kim, Jae-Young Choi,Byung Hee Hong,Large-scale pattern growth of graphene films for stretchabletransparent electrodes [J].Nature,2009,457, 706-710
[41] B. C. Brodie, On the atomic weight of graphite, Phil. Trans. Roy. Soc., 1859,149,249-259
[42] L. Staudenmaier, Verfahren Zur Darstellung Der Graphitsaure, Ber. Dtsh. Chem.Ges., 1898, 31,1481-1499
[43] Hummers, W. S. ,Offeman, R. E. ,Preparation of graphite oxide.[J], J. Am. Chem. Soc.,1958,80,1339
[44] Jian Chen; Mark A. Hamon; Hui Hu; Yongsheng Chen; Apparao M. Rao; Peter C. Eklund; Robert C. Haddon, Solution Properties of Single-Walled Carbon Nanotubes[J],Science, 282, 95-98.
[45] Yuehe Lin, Fang Lu, Joseph Wang, Disposable Carbon Nanotube Modified Screen-Printed Biosensor for Amperometric Detection of Organophosphorus Pesticides and Nerve Agents[J],Electroanalysis, 2004,145-149
[46] Jie Liu, Andrew G. Rinzler, Hongjie Dai, Jason H. Hafner, R. Kelley Bradley, Peter J. Boul, Adrian Lu, Terry Iverson, Konstantin Shelimov, Chad B. Huffman, Fernando Rodriguez-Macias, Young-Seok Shon, T. Randall Lee, Daniel T. Colbert, and Richard E. Smalley, Fullerene Pipes[J], Science,1998,280, 1253-1256
[47] E.T. Mickelson , C.B. Huffman , A.G. Rinzler , R.E. Smalley , R.H. Hauge,J.L. Margrave,Fluorination of single-wall carbon nanotubes[J] , Chem. Phys. Lett.,1998,296,188–194
[48] B. Katherine Price and James M. Tour,Functionalization of Single-Walled Carbon Nanotubes“On Water”,[J]. J Am. Chem. Soc. 2006, 128, 12899-12904
[49] Jay R. Lomeda, Condell D. Doyle, Dmitry V. Kosynkin, Wen-Fang Hwang, andJames M. Tour, Diazonium Functionalization of Surfactant-Wrapped Chemically Converted Graphene Sheets[J], J. Am. Chem. Soc. 2008, 130, 16201–16206
[50] Chen R J,Zhang Y G,Dai H J et al, Nocovalent Sidewall Functionalzation of Single-Walled Carbon Nanotubes for Protein Immobilization[J], J.Am.Chem.Soc.,2001,123,3838-383
[51] Zhuang Liu, Joshua T. Robinson, Xiaoming Sun, and Hongjie Dai,PEGylated Nanographene Oxide for Delivery of Water-InsolubleCancer Drugs[J] J. Am. Chem. Soc. 2008, 130, 10876–10877
[52] Michael J. O Connell, Peter Boul, Lars M. Ericson,Chad Huffman, Yuhuang Wang, Erik Haroz, Cynthia Kuper, Jim Tour, Kevin D. Ausman and Richard E. Smalley, Reversible water-solubilization of single-walled carbon nanotubes by polymer wrapping[J],Chem. Phys. Lett,2001 342, 265-271
[53] Wei-De Zhang,In Yee Phang, and Tianxi Liu , Growth of Carbon Nanotubes on Clay: Unique Nanostructured Filler for High-Performance Polymer Nanocomposites[J],Adv. Mater. 2006, 18, 73–77
[54] M.F.DeRiccardis ,D.Carbone,Th.DikonimosMakris,R.Giorgi,N.Lisi,E.Salernitano, Anchorage of carbon nanotubes grown on carbon fibres[J],Carbon 44 (2006) 671–674
[55] Pulickel M.Ajayan and James M.Tour, Nanotubes composites[J], Nature,2007,447,1066-1068
[56] Haggenmueller R, Gommans HH, Rinzler AG, Fischer JE, Winey KI. Aligned single-wall carbon nanotubes in composites by melt processing methods[J],Chem .Phys .Lett. 2000;330:219-225.
[57] Jun’ichi Masuda,John M. Torkelson,Dispersion and Major Property Enhancements in Polymer/Multiwall Carbon Nanotube Nanocomposites via Solid-State Shear Pulverization Followed by Melt Mixing[J], Macromolecules 2008, 41, 5974-5977
[58] Potschke P, Fornes TD,; Paul DR. Dielectric spectroscopy on melt processed polycarbonate-multiwalled carbon nanotube composites[J], Polymer,2002,43,3247-3255
[59] Fangming Du, John.E. Fischer, Karen I. Winey,Coagulation Method for Preparing Single-Walled Carbon Nanotube/Poly(methyl methacrylate) Composites and Their Modulus, Electrical Conductivity, and Thermal Stability[J],J. Polym. Sci., Part B: Polym. Phys., 2003, 41,3333–3338
[60] T. Ramanathan, A.A.Abdala, S.Stankovich, D.A.Dikin, M.Herrera-Alonso,R.D.Piner, D.H.Adamson, H.C.Schniepp, X.Chen, R.S.Ruoff, S.T.Nguyen,I.A.Aksay, R.K.Prud’Homme, L.C.Brinson,Functionalized graphene sheets for polymer nanocomposites[J],Nature nanotechnology, 2008,3,327-331
[61] Chang-Eui Hong, Joong-Hee Lee, Prashantha Kalappa, Suresh G.Advani,Effects of oxidative conditions on properties of multi-walled carbon nanotubes in polymer nanocomposites [J],Compos. Sci. Technol., 2007,67 ,1027–1034
[62] S. Kanagaraj , Fa′tima R. Varanda, Tatiana V. Zhil’tsova, Mo′nica S.A. Oliveira,Jose′A.O. Simo?es,Mechanical properties of high density polyethylene/carbon nanotube composites[J],Compos.Sci. Technol.,2207, 67,3071–3077
[63] Sasha Stankovich, Dmitriy A. Dikin, Geoffrey H. B. Dommett, Kevin M. Kohlhaas, Eric J. Zimney, Eric A. Stach, Richard D. Piner, SonBinh T. Nguyen,Rodney S.Ruoff,Graphene-based composite materials[J],Nature, 2006,442,282-286
[64] P. M. Ajayan, O. Stephan, C. Colliex, D. Trauth,Aligned Carbon Nanotube Arrays Formed by Cutting a Polymer Resin-Nanotube Composite[J] , Science,1994,265, 1212-1214.
[65] M.C. Paiva, B. Zhou, K.A.S. Fernando, Y. Lin, J.M. Kennedy, Y.-P. Sun,Mechanical and morphological characterization of polymer–carbon nanocomposites from functionalized carbon nanotubes[J] ,Carbon,2004,42,2849–2854
[66] S.L. Ruan, P. Gao, X.G. Yang, T.X. Yu,Toughening high performance ultrahigh molecular weight polyethylene using multiwalled carbon nanotubes,Polymer ,2003;44:5643-5654.
[67] Jeong-Ho Ko, Jin-Hae Chang,Properties of Ultrahigh-Molecular-Weight Polyethylene Nanocomposite Films Containing Different Functionalized Multiwalled Carbon Nanotubes[J] ,Polym. Eng. Sci. ,2009,2168-2178
[68] Silvia Villar-Rodil, Juan. I. Paredes, Amelia Mart?′nez-Alonso ,Juan. M. D. Tascon,Preparation of graphene dispersions and graphene-polymer composites in organic media[J] ,J. Mater. Chem., 2009, 19, 3591–3593
[69] Mohammad A. Rafiee, Javad Rafiee, Iti Srivastava, Zhou Wang, Huaihe Song,Zhong-Zhen Yu, and Nikhil Koratkar, Fracture and Fatigue in Graphene Nanocomposites[J], Small,2010, 6, No. 2, 179–183
[70] Carlos Velasco-Santos, Ana L. Mart?′nez-Herna′ndez, Frank T. Fisher,Rodney Ruoff, Victor M. Castan o,Improvement of Thermal and Mechanical Properties of Carbon Nanotube Composites through ChemicalFunctionalization[J] ,Chem. Mater. 2003, 15, 4470-4475
[71] Duc Anh Nguyen,Yu Rok Lee,Anjanapura V Raghu,HanMo Jeong,CheolMin Shin,Byung Kyu Kim,Morphological and physical properties of athermoplastic polyurethane reinforced with functionalized graphene sheet[J] ,Polym Int. 2009; 58: 412–417
[72] Huating Hu, Xianbao Wang, Jingchao Wang, Li Wan, Fangming Liu, Han Zheng, Rong Chen, Chunhui Xu,Preparation and properties of graphene nanosheets-polystyrene nanocomposites via in situ emulsion polymerization [J] ,Chem. Phys. Lett. ,2010,484,247–253
[73] Bonner W H.[P] USA patent 3065205,1962.
[74] Rose J B.[P] USA patent 4320224,1976.
[75] Rose J B.[P] Britian patent 1558671,1976.
[76] Rose J B.[P] Britian patent 1414422,1975.
[77] Rose J B.[P] Britian patent 1414423,1975.
[78] Rose J B.[P] Britian patent 1414424,1975.
[79] http://www.jusep.com.cn/cpjs.html
[80] M.Rama Rao,V.L.Rao,T.S.Radhakrishnan,S.Ramachandran.Synthesis、characterization and thermal degradation studies of poly(ether ether ketone)copolymers[J].Polymer,1992,33,2834-2839
[81] Ming Chen ,Jang-Yang Chen. Analysis of Crystallization Kinetics of Poly(ether ether ketone)[J].J.Polym.Sci,PartB:Polym.phys,1998,36 1348-1355.
[82]田爱国,纳米氧化铝粉体填充增强聚醚醚酮复合材料及其性能研究[D],上海材料研究所硕士学位论文,2002,1-30
[83]陶国源,聚醚醚酮应用实例(下)[J],塑料制造,2006,46-51
[84] http://www.victrex.com
[85] Bhanu Nandan, L. D. Kandpal, G. N. Mathur,Poly(ether ether ketone) /Poly(aryl ether sulfone) Blends:Relationships Between Morphology and Mechanical Properties[J],J. Appl. Polym. Sci., 2003, 90,2887–2905
[86] R. Gensler, Ph. B6guelin , C. J. G. Plummer , H.-H. Kausch , H. Miinstedt,Tensile behaviour and fracture toughness of poly(ether ether ketone)/poly(ether imide) blends[J],Polym. Bull.,1996,37, 111-118
[87] Alain M. Jonas, Dimitri A. Ivanov, and Do Y. Yoon,The SemicrystallineMorphology of Poly(ether?ether?ketone) Blends with Poly(ether?imide) [J] ,Macromolecules 1998, 31, 5352-5362
[88] Yong Sung Chun, Heon Sang Lee, Hyun Chul Jung, Woo Nyon Kim,Thermal Properties of Melt-Blended Poly(ether ether ketone) and Poly(ether imide)[J] ,J. Appl. Polym. Sci., 1999,72, 733–739
[89] Anjum Saleem, Lars Frormann, Azhar Iqbal , High Performance Thermoplastic Composites: Study on the Mechanical, Thermal, and Electrical Resistivity Properties of Carbon Fiber-Reinforced Polyetheretherketone and Poly ether sulphone [J],Polym. Compos, 2007,785-796
[90] R. A. Crick, D.C.Leach, P.J.Meakin, D.R.Moore,Interlaminar fracture morphology of carbon fibre/PEEK composites[J],J.Mater. Sci,1987, 22,2094-2104
[91] Chi-Cherng Jeng, Ming Chen,Flexural failure mechanisms in injection -moulded carbon fibre/PEEK composites[J],Compos.Sci. Technol.,2000, 60,1863-1872
[92] M.S. Abu Bakar , P. Cheang , K.A. Khor,Tensile properties and microstructural analysis of spheroidized hydroxyapatite/poly(etherether ketone) biocomposites[J] ,Mater. Sci. Eng. A,2003,345, 55-/63
[93] R.K. Goyal , A.N. Tiwari , U.P. Mulik , Y.S. Negi, Effect of aluminum nitride on thermomechanical properties of high performance PEEK[J], Composites: Part A 38 (2007) 516–524
[94] R. K. Goyal,A. N. Tiwari,U. P. Mulik,Y. S. Negi, Study on Microhardness, Dynamic Mechanical, andTribological Properties of PEEK/Al2O3 Composites[J], J. Appl. Polym. Sci,2008, 110, 3379–3387
[95] Y.H. Lai , M.C. Kuo , J.C. Huang, M. Chen,On the PEEK composites reinforced by surface-modified nano-silica[J],Mater. Sci. Eng. A,2007, 458,158–169
[96] Pan Guoliang, Guo Qiang, Tian Aiguo, He Zhiqiang,Mechanical behaviors of Al2O3 nanoparticles reinforced polyetheretherketone[J] , Mater. Sci. Eng.A,2008, 492 ,383–391
[97] Jan Sandler, Philipp Werner, Milo S.P. Shaffer, Vitaly Demchuk, Volker Altsta¨dt,Alan H. Windle,Carbon-nanofibre-reinforced poly(ether etherketone) composites[J] ,Composites: Part A,2002,33,1033–1039
[98] J.Sandler,A.H.Windle,P.Werner,V.Altsta¨DT,M.V.ES,M.S.P.Shaffer,Carbon-nanofibre-reinforced poly(ether ether ketone) fibres[J],J. Mater. Sci,2003,38,2135– 2141
[99] Philipp Werner, Volker Altst¨adt, Romy Jaskulk, Olaf Jacobs,Jan K.W. Sandler, Milo S.P. Shaffer, Alan H. Windle,Tribological behaviour of carbon-nanofibre-reinforcedpoly(etheretherketone)[J] ,Wear,2004,257,1006–1014
[100] Philipp Werner, Raquel Verdejo, Frank W?llecke,Volker Altst?dt, Jan K. W. Sandler,Milo S. P. Shaffer,Carbon Nanofibers Allow Foaming of Semicrystalline Poly(ether ether ketone)[J],Adv. Mater. 2005,17,2864–2869
[101] Raquel Verdejo ,Philipp Werner ,Jan Sandler,Volker Altsta¨dt ,M. S. P. Shaffer,Morphology and properties of injection-moulded carbon- nanofibre poly(etheretherketone) foams[J],J Mater Sci ,2009,44,1427–1434
[102] Li Song, Hui Zhang, Zhong Zhang, Sishen Xie,Processing and performance improvements of SWNT paper reinforced PEEK nanocomposites [J],Composites: Part A,2007,38,388–392
[103] Fei Deng, Toshio Ogasawara, Nobuo Takeda,Tensile properties at different temperature and observation of micro deformation of carbon nanotubes–poly(ether ether ketone) composites[J],Compos. Sci. Technol. , 2007,67,2959–2964
[104] Ana M. D?′ez-Pascual, Mohammed Naffakh, Maria′n A. Go′mez, Carlos Marco,Gary Ellis,M. Teresa Mart?′nez, Alejandro Anso′n, Jose′M. Gonza′lez-Dom?′nguez,Yadienka Mart?′nez-Rubi, Benoit Simard,Development and characterization of PEEK/carbon nanotube Composites [J],Carbon, 2009,47,079–3090
[105] A M.D′?ez-Pascual,M Naffakh,M A.G′omez, C.Marco,G Ellis,J M Gonz′alez-Dom′?nguez,A Ans′on,M T Mart′?nez,Y Mart′?nez-Rubi, B Simard,B Ashrafi,The influence of a compatibilizer on the thermal and dynamic mechanical properties of PEEK/carbon nanotube Composites[J], Nanotechnology,2009,20,315707,1-13
[106] Se-Jin Oh, Hwa-Jeong Lee,Dong-Ki Keum, Seong-Woo Lee,David H. Wang,Soo-Young Park,Loon-Seng Tan,Jong-Beom Baek,Multiwalledcarbon nanotubes and nanofibers grafted with polyetherketones in mild and viscous polymeric acid[J],Polymer,2006,47,1132–1140
[107] Ja-Young Choi,Sang-Wook Han, Wan-Soo Huh,Loon-Seng Tan, Jong-Beom Baek,In situ grafting of carboxylic acid-terminated hyperbranched poly(ether-ketone) to the surface of carbon nanotubes[J] , Polymer, 2007,48,4034-4040
[108] Ja-Young Choi,Se-Jin Oh,Hwa-Jeong Lee,David H. Wang,Loon-Seng Tan,Jong-Beom Baek,In-Situ Grafting of Hyperbranched Poly(ether ketone)s onto Multiwalled Carbon Nanotubes via the A3+B2 Approach [J] ,Macromolecules 2007, 40, 4474-4480
[109] In-Yup Jeon,Loon-Seng Tan,Jong-Beom Baek,Nanocomposites Derived from In Situ Grafting of Linear and Hyperbranched Poly(ether-ketone)s Containing Flexible Oxyethylene Spacers onto the Surface of Multiwalled Carbon Nanotubes[J],J. Appl. Polym. Sci: Part A: Polymer Chemistry, 2008,46, 3471–3481
[110] David H. Wang, Peter Mirau, Bing Li, Christopher Y. Li, Jong-Beom Baek, Loon-Seng Tan,Solubilization of Carbon Nanofibers with a Covalently Attached Hyperbranched Poly(ether ketone)[J] ,Chem. Mater. 2008, 20, 1502–1515
[111]李先锋,磺化聚芳醚酮类质子交换膜材料的结构与性能研究[D],吉林大学博士学位论文,2006,1-33
[112] P. Sivaraman, V.R. Hande, V.S. Mishra, Ch. Srinivasa Rao, A.B. Samui, All-solid supercapacitor based on polyaniline and sulfonated poly(ether ether ketone), J. Power Sources,2003, 124 ,351–354
[113] P. Sivaraman, R.K. Kushwaha, K. Shashidhara, V.R. Hande, A.P. Thakur,A.B. Samui, M.M. Khandpekar,All solid supercapacitor based on polyaniline and crosslinked sulfonated poly[ether ether ketone][J], Electrochim. Acta ,2010,55 ,2451–2456
[114] Rapee Gosalawit, Suwabun Chirachanchai, Sergey Shishatskiy, Suzana P. Nunes,Sulfonated montmorillonite/sulfonated poly(ether ether ketone) (SMMT/SPEEK) nanocomposite membrane for direct methanol fuel cells (DMFCs)[J],J. Membr. Sci.,2008,323,337–346
[115] Seung-Hee Park,Jin-Soo Park,Sung-Dae Yim,Seok-Hee Park,Young-MooLee,Chang-Soo Kim,Preparation of organic/inorganic composite membranes using two types of polymer matrix via a sol–gel process[J],J. Power Sources,2008,181,259–266
[116]李会巧,超级电容器及其相关材料的研究[D],复旦大学博士学位论文,2008,2-6
[117] Dong-Won Kim, Jang Myoun Ko, Wan Ju Kim, Jong Huy Kim, Study on the electrochemical characteristics of quasi-solid-state electric double layer capacitors assembled with sulfonated poly(ether ether ketone)[J], J. Power Sources,2006, 163 ,300–303
[118] Wan Ju Kim, Dong-Won Kim, Sulfonated poly(ether ether ketone) membranes for electric double layer capacitors[J],Electrochimica Acta,2008, 53,4331–4335
[119] M. Lai,J. Liu,Thrmal and dynamic mechanical properties of PES/PPS blends,Journal of Thermal Analysis and Calorimetry, 2004,77,935–945
[120] M. Garc?′a, J. I. Eguiaza′bal, J. Naza′bal, Reinforced Poly(ether sulfone) Materials by Blending with a Semiaromatic Liquid Crystalline Copolyester [J], Journal of Applied Polymer Science, 2004, 91, 52–59
[121] M. Garc?′a, J.I. Eguiaza′bal, J. Naza′bal, Two scale reinforcement in hybrid composites based on poly(ether sulfone), glass fiber and liquid crystalline polymer[J], Compos. Sci. Technol .2003,63, 2163–2170
[122] G. M. Wu,J. M. Schultz,Processing and Properties of Solution Impregnated Carbon Fiber Reinforced Poly ether sulfone Composites[J],Polym. Compos., 2000, 21,223-230
[123] J. Bijwe, S. Awtade B.K. Satapathy, A. Ghosh, Influence of concentration of aramid fabric on abrasive wear performance of polyethersulfone composites[J], Tribology Letters,2004,17,187-194
[124] J. Bijwe, S. Awtade , A. Ghosh, Influence of orientation and volume fraction of Aramid fabric on abrasive wear performance of polyethersulfone composites[J], Wear ,2006,260 ,401–411
[125] Sadhan C.Jana,Sachin Jain,Dispersion of nanofillers in high performance polymers using reactive solvents as processing aids[J],Polymer,2001, 42,6897-6905
[126] Guiping Wu, Shuying Gan, Longzhe Cui, Youyi Xu,Preparation andcharacterization of PES/TiO2 composite membranes[J],Appl.Surf. Sci,2008,254,7080–7086
[1] Gan Lin Hwang,Yeong-Tarng,Kuo Chu Shieh, Efficient load transfer to polymer-grafted multiwalled carbon nanotubes in polymer composites[J]. Adv. Funct. Mater. 2004;14:487-491
[2] Rowan Blake, Jonathan N. Coleman, Michele T. Byrne, Joseph E. McCarthy,Tatiana S. Perova,Werner J. Blau,Antonio Fonseca,Janos B. Nagy and Yurii K. Gun’ko. Reinforcement of poly(vinyl chloride) and polystyrene using chlorinated polypropylene grafted carbon nanotubes[J]. J. Mater. Chem. 2006; 16: 4206–4213
[3] Anton A. Koval’chuk, Vitaliy G. Shevchenko, Alexander N. Shchegolikhin,Polina M. Nedorezova, Alla N. Klyamkina, and Alexander M. Aladyshev.Effect of Carbon Nanotube Functionalization on the structural and mechanical properties of polypropylene/MWCNT composites[J]. Macromolecules,2008; 41:7536-7542
[4] Hye Jin Yoo, Yong Chae Jung, Jae Whan Cho. Effect of interaction between poly(ethylene terephthalate) and carbon nanotubes on the morphology and properties of their nanocomposites[J], J. Polym. Sci: Part B: Polymer Physics,2008,46,900–910
[5] Jian Chen, Mark A. Hamon, Hui Hu, Yongsheng Chen,Apparao M. Rao, Peter C. Eklund, Robert C. Haddon. Solution properties of single-walled carbon nanotubes. Science,1998,282,95-98
[6] Douglas B. Mawhinney, Viktor Naumenko, Anya Kuznetsova, John T. Yates, J. Liu, and R. E. Smalley. Infrared spectral evidence for the etching of carbon nanotubes: ozone oxidation at 298 K[J]. J. Am. Chem. Soc. 2000,122(10),2383–2384
[7] Bing Zhou, Xiangbo Ji, Ye Sheng, Lifeng Wang, Zhenhua Jiang. Mechanical and thermal properties of poly-ether ether ketone reinforced with CaCO3. Eur. Polym. J.2004; 40:2357–2363
[8]周兵,CaCO3/PEEK复合材料的制备与性能研究[D],吉林大学博士学位论文,2004,46
[9] J Jin, M Song, F Pan.A DSC study of effect of carbon nanotubes on crystallisation behaviour of poly(ethylene oxide)[J]. Thermochimica Acta ,2007; 456:25–31
[10] H Meng, GX Sui, PF Fang, R Yang. Effects of acid- and diamine-modified MWNTs on the mechanical properties and crystallization behavior of polyamide 6[J]. Polymer,2008,49,610-620
[11] Jinghui Yang , Tao Xu , Ai Lu, Qin Zhang, Hong Tan , Qiang Fu, Preparation and properties of poly (p-phenylene sulfide)/multiwall carbon nanotube composites obtained by melt compounding[J].Compos. Sci. Technol 2009,69,147-153
[12] M.A. Lo′pez Manchado, L. Valentini b, J. Biagiotti, J.M. Kenny. Thermal and mechanical properties of single-walled carbon nanotubes–polypropylene composites prepared by melt processing[J]. Carbon,2005, 43,1499–1505
[13] Biao Wang, Guangping Sun, Jingjiang Liu, Xiaofeng He,Jing Li. Crystallization behavior of carbon nanotubes-filled polyamide 1010[J]. J. Appl. Polym. Sci,2006,100,3794–3800
[14]李娟,碳纳米管/尼龙6复合材料的结构与性能研究[D],浙江大学博士学位论文,2006,108-120
[15]赵焱,聚醚醚酮(PEEK)/有机化蒙脱土(OMMT)复合材料的制备及性能研究[D],吉林大学博士学位论文,2009,54-59
[16] Melvin Avrami. Kinetics of phase changⅡ,Transformation-time relations for radom distribution of nucei [J]. J. Chem. Phys. 1940;8:212-224
[1]赵择卿,陈小立,高分子材料导电和抗静电技术及应用[M],中国纺织出版社,2006,391
[2]熊佳,导电复合材料的制备及其性能的研究,西北工业大学硕士学位论文[D],2005,3
[3]杨波,炭黑/聚丙烯导电复合材料的电性能和形态研究[D],四川大学硕士学位论文[D],2007,5
[4] Stenger-Smith.J.D,Intrinsically electrically conducting polymers Synthesis, characterization, and their application [J].Prog Polym Sci,1998, 23,57-79
[5] R. M. Scarisbrick. Electrically conducting mixtures [J] J. Phys. D: Appl. Phys,1973,6,2098-2110
[6] C.Rajagopal,M.Satyam.Studies on electrical conductivity of insulator-conductor composites [J] J Appl. Phys., 1978, 49, 5536
[7] S. Miyauchi. The conduction mechanism of polymer-filler particles [J]. J. Appl. Polym. Sci,1985, 30, 2743
[8] Xianqiang Pei,Yan Li ,Qihua Wang, Xiaojun Sun, Effects of atomic oxygen irradiation on the surface properties of phenolphthalein poly(ether sulfone)[J], Appl. Surf. Sci. 255 (2009) 5932–5934
[9] Jiachun Feng , Guian Wen ,Wei Huang , En-Tang Kang ,Koon Gee Neoh, Influence of oxygen plasma treatment on poly(ether sulphone) films[J], Polym. Degrad. Stab ,2006,91, 12-20
[10] S.M. Kang, S.G. Yoon , D.H. Yoon, Surface treatment of polycarbonate and polyethersulphone for SiNx thin film deposition[J], Thin Solid Films,2008,516, 1405–1409
[11] Jinghui Yang, Tao Xu , Ai Lu, Qin Zhang, Hong Tan, Qiang Fu, Preparation and properties of poly (p-phenylene sulfide)/multiwall carbon nanotube composites obtained by melt compounding[J], Compos. Sci. Technol, 2009,69,147–153
[1] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, A. A. Firsov ,Electric Field Effect in Atomically Thin Carbon Films[J], Science,2004,306,666-669
[2] Matthew J. Allen,Vincent C. Tung, Richard B. Kaner, Honeycomb Carbon: A Review of Graphene[J], Chem. Rev. 2010, 110, 132–145
[3] Eun-Young Choi, Tae Hee Han,Jihyun Hong,Ji Eun Kim,Sun Hwa Lee, Hyun Wook Kima, Sang Ouk Kim, Noncovalent functionalization of graphene with end-functional polymers[J], J. Mater. Chem., 2010, 20, 1907–1912
[4] Ming Fang, Kaigang Wang, Hongbin Lu, Yuliang Yang, Steven Nutt, Single-layer graphene nanosheets with controlled grafting of polymer chains[J], J. Mater. Chem., 2010, 20, 1982–1992
[5] DW Boukhvalov and M I Katsnelson, Chemical functionalization of graphene[J], J. Phys. Condens. Matter ,2009,21, 344205,1-12
[6] Dongyu Cai, Kamal Yusoh , Mo Song, The mechanical properties and morphology of a graphite oxide,nanoplatelet/polyurethane composite[J], Nanotechnology, 2009,20,085712,1-5
[7] Dongyu Cai ,Mo Song,A simple route to enhance the interface between graphite oxide nanoplatelets and a semi-crystalline polymer for stress transfer[J], Nanotechnology ,2009,20,315708,1-6
[8] Xin Zhao, Qinghua Zhang, Dajun Chen, Enhanced Mechanical Properties of Graphene-Based Poly(vinyl alcohol) Composites[J] Macromolecules , 2010, 43, 2357–2363
[9] Hummers, W. S. ,Offeman, R. E. ,Preparation of graphite oxide.[J],J. Am. Chem. Soc.,1958,80,1339
[10] Wei Gao,Lawrence B. Alemany, Lijie Ci, Pulickel M. Ajayan, New insights into the structure and reduction of graphite oxide[J], Nature Chemistry ,2009, 1, 403–408
[11] Meyer.Jannik.C.,Geim.A.K.,Katsnelson.M.I.,Novoselov.K.S.,Booth,T.J.,Roth.S.,The structure of suspended graphene sheets[J], Nature,2007,446,60-63
[12] Zou H, Xu W, Zhang Q, et al. Effect of alkylammonium salt on the dispersion and properties of Poly(p-phenylene sulfide)/clay nanocomposites via melt intercalation[J],.Journal of Applied Polymer Science,2006,99,1724
[13]赵焱,聚醚醚酮(PEEK)/有机化蒙脱土(OMMT)复合材料的制备及其性能研究[D],吉林大学博士学位论文,2008,40-60
[1] B.E.康维著,陈艾等译,电化学超级电容器[M],化学工业出版社,2005,556-615
[2] Mehrdad Ehsani,Yimin Gao等著,倪匡正等译,现代电动汽车、混合动力电动车和燃料电池车-基本原理、理论和设计[M],机械工业出版社,2008,267-283
[3] Kim.J.H.,Myung S.T., Yoo C.S.,Kang S.G.et al ,Comparative study of LiNi0.5Mn1.5O4-delta and LiNi0.5Mn1.5O4 cathodes having two crystallographic structures:Fd(3)over-barm and p4(3)32[J], Chem.Mater., 2004,16,906
[4] Zhang L.L, Zhao X.S, Carbon-based materials as supercapacitor electrodes[J], Chem. Soc. Rev., 2009, 38, 2520–2531
[5] Meryl D. Stoller, Sungjin Park, Yanwu Zhu, Jinho An, and Rodney S. Ruoff, Graphene-Based Ultracapacitors[J],Nano letter,2008,8,498-3502
[6] Yan Wang,Zhiqiang Shi,Yi Huang,Yanfeng Ma, Chengyang Wang,Mingming Chen,Yongsheng Chen, Supercapacitor Devices Based on Graphene Materials[J], J. Phys. Chem. C 2009, 113, 13103–13107
[7] S R C Vivekchand, Chandra Sekhar Rout, K S Subrahmanyam,A Govindaraj,C N R Rao, Graphene-based electrochemical supercapacitors[J], J. Chem. Sci.,2008,120, 9–13
[8]袁国辉,电化学电容器[M],化学工业出版社,2006,23-120
[9]殷金玲,凝胶聚合物电解质超级电容器的研究[D],哈尔滨工程大学2007,2-30
[10] S. J. Park, K. S. Lee, G. Bozoklu, Graphene oxide papers modified by divalent ions-Enhancing mechanical properties via chemical cross-linking, ACS Nano,2008, 23:572~578
[11] Kim W.J, Kim D.W., Sulfonated poly(ether ether ketone) membranes or electric double layer capacitors[J], Electrochimica Acta,2008,53, 4331–4335