配合物二碘三烯丙基硫脲合镉的合成与性质表征
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摘要
自从发现非线性光学现象以来,人们在新的非线性光学材料探索方面做了大量工作。金属有机配合物晶体材料结合了有机材料和无机材料的优点,通过改变金属有机配合物中心金属离子或配体,可以有效地调控、优化配合物的物理化学性质,在非线性光学领域吸引了众多研究者的目光。在所报道的金属有机配合物中,中心金属一般都选择IIB族金属,其中以烯丙基硫脲(简称AT)为配体的ATM'X型晶体具有较强的非线性光学效应,稳定的物化性质,可获得优质晶体,是一类性能优良的非线性光学材料。这类配合物的通式是ATM'X,其中M'=Cd、Hg, X=Cl、Br、Ⅰ等。
本文在参阅大量国内外文献的基础上介绍了非线性光学基本原理、非线性光学晶体材料的分类及应用,简述了金属有机配合物非线性光学晶体材料的发展情况。具体研究内容如下：
1、首次设计、合成、生长出了ATCI配合物新晶体。该晶体生长的最佳pH值在3-4之间,降温速率为0.1℃\天；选择的溶剂是蒸馏水和乙醇。
2、通过对ATCI晶体的元素分析确定了晶体的分子组成；进行了X射线衍射物相鉴定确定了ATCI晶体属于三方晶系,空间群是R3c；对晶体进行了光谱学、热学和非线性光学等性质的研究,结果表明配合物中S与Cd配位；二阶非线性光学效应测试显示ATCI晶体的效应与尿素相当。
3、对ATCC、ATCB、ATMC和ATCI这四种晶体进行了红外光谱、热学和粉末倍频效应等性质的比较研究,探讨了性质结构之间的内在规律性。结果表明,ATCI晶体与ATCC、ATCB、ATMC具有相似的性质,随着中心金属原子序数的增加,配合物材料的热稳定性提高,非线性光学效应变大。
本文研究对ATM'X型非线性光学晶体的生长、性能表征及应用有一定的指导意义,在探索新型配合物非线性光学材料方面具有重要的价值。
A lot of researches have been done since the first observation of nonlinear optical phenomenon. Organometallic complex materials have been attracting many researchers in the nonlinear optical field, because of its coordination compounds the merits of both inorganic and organic materials that the physical and chemical properties of the complex can be effectively dominated by changing the central ions and ligand. As reported in the organometallic materials, mostly have group IIB metals as center ions, Among them, metal-allylthiourea coordination compounds ATM'X type is prominent. ATM'X type crystal has strong NLO efficiency, deep UV cut-off wavelength and stable physicochemical properties as well as the crystal growth can be realized.The general formula of these coordination compound is ATM'X [where AT=(allylthiourea)=C4H8N2S, M'=Cd or Hg, X=Cl, Br orⅠ].
In this paper, the basic theory of nonlinear optics, the classification of nonlinear optical crystal materials and the application of nonlinear optical crystal materials were introduced and the development of organometallic complex optical materials, are reviewed on the basis of studying lots of literature at home and abroad. The summaries of compounds of this thesis are as follows:
1. The coordination crystal tri-allylthiourea cadmium iodide was synthesized and grown for the first time. The crystal growth optimal pH value is 3～4, Cooling rate is 0.1℃\day; Solvent is distilled water and ethanol.
2. The the element analysis of ATCI crystal, determine the molecular structure of this crystals. Through the powder X-ray content phase identification and Rietveld refinement determined the wafer ATCI crystal belong to trigonal system, belong to space group R3c; The spectroscopy, calorifics and NLO properties of the ATCI crystal. Some of the conclusions are: Complexes with Cd slots in S, ATCI shows powder SHG efficiency comparative to urea.
3. The structures and properties of the ATCC, ATCB, ATMC and ATCI crystal were systematically studied. Results show that ATCI crystals and ATCC, ATCB and ATMC are Similar properties. Along with the increase of central metal atom number, complexes material thermal stability improved, nonlinear optical effect greatens.
This paper will do help in study of the series of ATM'X type, both in their crystal growth, properties characterization and appliance. These studies are important for searching at novel coordination compound NLO materials.
本文在参阅大量国内外文献的基础上介绍了非线性光学基本原理、非线性光学晶体材料的分类及应用,简述了金属有机配合物非线性光学晶体材料的发展情况。具体研究内容如下：
1、首次设计、合成、生长出了ATCI配合物新晶体。该晶体生长的最佳pH值在3-4之间,降温速率为0.1℃\天；选择的溶剂是蒸馏水和乙醇。
2、通过对ATCI晶体的元素分析确定了晶体的分子组成；进行了X射线衍射物相鉴定确定了ATCI晶体属于三方晶系,空间群是R3c；对晶体进行了光谱学、热学和非线性光学等性质的研究,结果表明配合物中S与Cd配位；二阶非线性光学效应测试显示ATCI晶体的效应与尿素相当。
3、对ATCC、ATCB、ATMC和ATCI这四种晶体进行了红外光谱、热学和粉末倍频效应等性质的比较研究,探讨了性质结构之间的内在规律性。结果表明,ATCI晶体与ATCC、ATCB、ATMC具有相似的性质,随着中心金属原子序数的增加,配合物材料的热稳定性提高,非线性光学效应变大。
本文研究对ATM'X型非线性光学晶体的生长、性能表征及应用有一定的指导意义,在探索新型配合物非线性光学材料方面具有重要的价值。
A lot of researches have been done since the first observation of nonlinear optical phenomenon. Organometallic complex materials have been attracting many researchers in the nonlinear optical field, because of its coordination compounds the merits of both inorganic and organic materials that the physical and chemical properties of the complex can be effectively dominated by changing the central ions and ligand. As reported in the organometallic materials, mostly have group IIB metals as center ions, Among them, metal-allylthiourea coordination compounds ATM'X type is prominent. ATM'X type crystal has strong NLO efficiency, deep UV cut-off wavelength and stable physicochemical properties as well as the crystal growth can be realized.The general formula of these coordination compound is ATM'X [where AT=(allylthiourea)=C4H8N2S, M'=Cd or Hg, X=Cl, Br orⅠ].
In this paper, the basic theory of nonlinear optics, the classification of nonlinear optical crystal materials and the application of nonlinear optical crystal materials were introduced and the development of organometallic complex optical materials, are reviewed on the basis of studying lots of literature at home and abroad. The summaries of compounds of this thesis are as follows:
1. The coordination crystal tri-allylthiourea cadmium iodide was synthesized and grown for the first time. The crystal growth optimal pH value is 3～4, Cooling rate is 0.1℃\day; Solvent is distilled water and ethanol.
2. The the element analysis of ATCI crystal, determine the molecular structure of this crystals. Through the powder X-ray content phase identification and Rietveld refinement determined the wafer ATCI crystal belong to trigonal system, belong to space group R3c; The spectroscopy, calorifics and NLO properties of the ATCI crystal. Some of the conclusions are: Complexes with Cd slots in S, ATCI shows powder SHG efficiency comparative to urea.
3. The structures and properties of the ATCC, ATCB, ATMC and ATCI crystal were systematically studied. Results show that ATCI crystals and ATCC, ATCB and ATMC are Similar properties. Along with the increase of central metal atom number, complexes material thermal stability improved, nonlinear optical effect greatens.
This paper will do help in study of the series of ATM'X type, both in their crystal growth, properties characterization and appliance. These studies are important for searching at novel coordination compound NLO materials.
引文
1.张克从,王希敏.非线性光学晶体材料科学[M].北京：科学出版社,2005：397-403
2.黄昆,韩汝琦.固体物理学[M].北京：高等教育出版社,1988
3.张玉龙,唐磊.人工晶体[M].北京：化学工业出版社,2005：44-59
4. Yuan Duorong,ZhangNan,Tao Xutang,Xu Dong,Jiang Minhua, Shao Zongshu. Study oncrystal Growth and Properties of a New Highly Efficient NLO material-Organometallic complex Tri-allylthiourea Mercury Chloride(ATMC)[J],Chinese Science Bulletin,1991, 36(16):1401-1404
5. Zhang Nan,Jiang Minhua,Yuan Duorong,Xu Dong,Yu Wentao,Tao Xutang.Study on thegrowth and properties of ATCC Crystal[J], Chinese Science Bulletin,1990,35(08): 646-649
6. Yuan Duorong,Zhang Nan,Tao Xutang, Jiang Minhua.A New Nonlinear optical Material-organ metallic complex tri-allylthiourea mercury chloride[J], Chinese Phys.Lett., 1990,07 (07):334-336
7. Zhan Nan, Jiang Min Hua,Yuan Duo Rong.A new nonlinear optical, materiae-organometalli complex tri-allythiourea cadmium chloride[J],Chin.Phys.Lett.,1989(6):280
8. Julien Zaeearo,Nathalie Sanz,EstelleBotzung APPert, PatrieeL.Baldeck, Alain Ibanez. organic nanocrystals grown in sol-gel matrices:a new type of hybrid material for optics nucleation et croissance confinee de nanocristaux organiquesenmatrices sol-gel:unnouveau type de materiaux organo-mineraux pour l'optique [J],C.R.Physique2002,3(4):463-478
9.胡安,章维益。固体物理学[M].北京：高等教育出版社,2005
10.蔡正千.热分析[M].北京：高等教育出版社,1993：74-83
11.刘粤惠,刘平安.X射线衍射分析原理与应用[M].北京：化学工业出版社,2003：83-120
12.祁景玉.X射线结构分析[M].上海：同济大学出版社.2003：87-98
13.N.布洛姆伯根.非线性光学[M].北京：科学出版社,1987：26
14.闵乃本.晶体生长的物理基础[M].上海：上海科学技术出版社,1982：433-436
15.王英华.X光衍射技术基础[M].北京：原子能出版社,1993：263-267
16.胡女丹.金属有机配合物非线性光学材料研究进展[J],六盘水师范高等专科学校学报,2010,22(6)：25-30
17.胡晓琴,胡拖平,许玉敏.金属-有机配合物的合成及其研究进展[J],广州化工, 2011,39(1)：13-15
18.邢光彩,蒋民华,邵宗书,许东.络合物型非线性光学新晶体—二氯二硫脲合镉(BTCC)[J],中国激光,1987,14(5)：302-308
19.邵宗书,邢光彩,蒋民华.粉末倍频效应—一种探索非线性光学晶体材料的有效方法[J],山东大学学报(自然科学版),1987,22(04)：118-123
20.杨俊涛,罗时军.二氯二硫脲合镉晶体的电子结构与光学性质的研究[J],湖北汽车工业学院学报,2010,24(1)：50-54
21.邢光彩,邵宗书,蒋民华.BTCC和KTP晶体倍频系数的测量[J],山东大学学报(自然科学版),1987,22(04)：107-117
22.张囡,蒋民华,袁多荣,许东,于文涛,陶绪堂.一种全新的金属络合物非线性倍频材料—TCC晶体的生长及性能研究[J],科学通报,1989：154-1156
23.张良辅,丁涪江,赵可清,杨立梅,王春燕,李莉[J],成都：合成化学,1997,5：(1)：17-27
24.张克从,张乐潓.晶体生长科学与技术(下)[M].北京：科学出版社,1997：374-442
25.杜文风,罗时军,尿素晶体的线性和非线性光学性质的从头算研究[J],湖北汽车工业学院学报,2008,22(2)：52-56
26.D.Amilan Jose,Ajeet Singh,Amitava Das and Bishwajit Ganguly. A density functionalst-udy to wards the preferential binding of anions to urea and thiourea[J], Elsevier. Tetrahedron Letters,48(2007):3695-3698
27.袁多荣,张囡,于文涛,许东,陶绪堂,蒋民华.非线性光学新晶体—二溴三丙烯基硫脲合镉[J],中国激光,1990,17(6)：332-335
28. Li Shengli, Yu Jianhua,Yang Jie,et al. Syntheses and Characterizations Of several new supramolecular coordination compounds[J], Journal of Anhui University Natural Science Edition,2007,31(6):62-65
29. Hou Wenbao,Xu Dong,Yuan Duorong,Liu Mingguo,ZhangNan,Tao Xutang, Sun Suoying, Jiang Minhua.Investigations on Tri-allylthiourea Mercury Bromide (ATMB)Crystal Growth[J],Cryst.Res.Technol,1994(7):939-944
30. Zhang Nan,Jiang Minhua,Yuan Duorong,Xu Dong,Tao Xutang,Shao Zongshu.The Quality and Performance of the Organometallic Complex Nonlinear Optical Material Tri-allylthiourea Cadmium Chloride[J],Journal of Crystal Growth,1990,102:581-584
31. Hou Wenbao,Xu Dong,Yuan Duorong,Liu Mingguo,ZhangNan,Tao Xutang, Sun Suoying, Jiang Minhua.A New Organometallic nonlinear optical material-Triallylthiourea mercury bromide(ATMB) crystal:growth and structure[J], Journalof Crystal Growth,1993, 133:71-74
32. X.L.Yu,Y.Sun,W.B.Hou,S.J.Zhang,Zh.X.Cheng.Interface kinetics and crystal growth mechanism of a new organometallic coordination compound:triallylthiourea mercury bromide[J],ELSEVIER. Journal of Crystal Growth,182(1997):428-433
33. E.Budevski,V.Bostanov,G,Staikov,Ann.Rev.Mater[J],Sci.10(1980)85
34. V.Venkataramanana,S.Maheswarana,J.N.Sherwoodb,H.L.Bhata.Crystal growth and phys-ical characterization of the semiorganic bis(thiourea) cadmium chloride[J], ELSEVIER. Journal of Crystal Growth,179(1997):605-610
35. W.B.Hou,Z.H.Yang,M.G.Liu,D.R.Yuan,D.Xu,N.Zhang,W.T.Yu,Y.H.Bing,S.Y.Sun, Ther-mal properties of a new organometallic nonlinear opticalmaterial, triallylthiourea mercury bromide [J],Materiala Letters 18(1994):207-210
36. W.B.Hou,M.H.Jiang,D.R.Yuan, Xu Dong,N.Zhang,M.G.Liu,X.T Tao.THE PREPARA-TION AND CHARACTERIZATION OF A NEW ORGANOMETALLIC NONLINEAR OPTICAL---TRI-ALLYLTHIOUREA MERCURY BROMIDE(ATMB) CRYSTAL [J], Mat.Res.Bull., Vol,1993(28):645-653
37. Dong Xu,Wen-Tao Yu,Xin-Qiang Wang,Duo-Rong Yuan,Meng-kai Lu,Ping Yang,Shi-Yi Guo,Fan-Qing Meng,Min-Hua Jiang. Zinc mercury thiocyanate(ZMTC)[J],Acta Cryst,1999(C55):1203-1205
38. Celia Marcos,Jose M,Victor Adovasio,Manuel Prieto,Santiago Garcia-Granda.Bis-(thiourea) cadmium Halides[J], Acta Crysty,1998(C54):1225-1229
39.袁多荣,张囡,陶绪堂,许东,于文涛,邵宗书,蒋民华.一组新型络合物晶体结构与光学性能的研究*[J],光学学报,1993,13(05)：456-460
40.蒋民华,许东,邢光彩.一类潜在的非线性光学材料—金属有机络合物[J],人工晶体,1985,14：3-4
41.袁多荣,陶绪堂,许东.高效有机非线性光学材料——二氯二丙烯基硫脲合汞晶体的生长和性能研究[J],科学通报,1991,36(02)：151-153
42.袁多荣,张囡,陶绪堂,许东,蒋民华,邵宗书。高效有机非线性光学材料—二氯三丙烯基硫脲合汞晶体的生长和性能研究’[J],科学通报,1990,2：151-153
43.孙海清,王淑峰.IIB族金属-硫脲配合物非线性光学晶体的研究进展[J],山东科技大学学报(自然科学版),2009,28(1)：55-57
44.袁多荣,张囡,于文涛.非线性光学新材料—二休三烯丙基硫脲[J],中国激光, 1990,17(06)：332-335
45.王莉,何飞,陈亚娟,阎吉祥,李家泽,吴世康,姜永才,张晓红.高效有机非线性光学材料特性的光谱分析[J],激光与红外,2004,34(05)：379-381
46. M.Oussaid, P.Becker,and C.Carabatos-Nedelec, Raman and Infrared Spectra of Bis(Thiourea)Zinc Chloride Zn[CS(NH2)]2Cl2 Single Crystal[J], Phys. Stat.Sol.(b),1998, 207:499-507
47. J.M.Alia, H.G.M.Edwards, M.D.Stoev, A systematic FT-Raman spectroscopic study of twelve bis-thiourea complexes, A(TU)2B2(A=Zn, Cd, Hg; B=Cl, Br, I, SCN) Spectrochim[J], Acta A,1999,55:2423
48. Ginson P.Joseph, K.Rajarajan, M.Vimalan, S.Selvakumar, S.M.Ravi Kumar J.Madhavan, P.Sagayaraj. Spectroscopic, thermal and mechanical behavior of allylthiourea cadmium chloride single crystals[J],ELSEVIER. Materials Research Bulletin,42(2007):2040-2047
49. H.Q.Sun,D.R.Yuan,X.Q. Wang,Y.Q.Lu,Z.H. Sun, X.C. Wei, X.L. Duan, C.N. Luan, M.K.Lu,D.Xu.Growth and thermal properties of tri-allylthiourea cadmium chloride(ATCC) crystal [J], Journal of Cryst Growth,256(2003):183
50. R.Perumal, S.Moorthy Babu. Growth and characterization of an organometallic nonlinear optical material tri-allylthiourea cadmium chloride(ATCC)[J], ELSEVIER.Materials Chemistry and Physics,107(2008):23-27
51. M.Lydia Caroline,S.Vasudevan. Growth and characterization of bis thiourea cadmium iodide:A semiorganic single crystal[J], ELSEVIER. Materials Chemistry and Physics,2008:5
52. K.Selvaraju,R.Valluvan,S.Kumararaman. Growth and characterization of a new metal-organic crystal:Potassium thiourea iodide[J], ELSEVIER.Materials Letters,60(2006):3130-3132
53. H.Q.Sun,D.R.Yuan,X.Q.Wang,X.F.Cheng,C.R.Gong,M.Zhou,H.Y.Xu,X.C.Wei, C.N.Luan, et.al.A novel metal-organic coordination complex crystal:tri-allylthiourea zinc chloride(ATZC)[J], Crystal Research and Technology,2005,40(9):882-886
54. P.A.Angeli Mary and S.Dhanuskodi.Growth and Characterization of a New Nonlinear Optical Crystal:Bis Thiourea Zinc Chloride[J], Cryst.Res.Technol.,2001,36:1231-1237
55. X.L.Duan, D.R YuanX.Q.Wang,X.F.Cheng,Z.H.Yang,S.Y.Guo,H.Q.Sun.Preparation and characterzation of nonlinear optical crystal materials:cadmium mercury thiocyanate and its lewis base adducts[J], Crysty.Res Technol..37(2002):446
56. Wang Xinqing,Xu Dong,et.al.Growth and characterization of the organometallic nonlinear optical crystal:manganese mercury thiocyanate (MMTC)[J], Mater. Res. Bull., 36(2001):879
57. K.Sangwal.Kinetic effects of impurities on the growth of single crystals from solutions[J], Journal of Crystal Growth,203(1999):197-212
58.孙海清.IIB族金属有机配合物非线性光学新材料的研究[D],山东济南：山东大学,2005
59.侯印春,潘守膺.非线性光学晶体及其应用[J]人工晶体学报,1990,19(04)：356-362
60. Sun Haiqing,Yuan Duorong,Yu Wentao,Wang Xinqing Liu Liqiang.Zinc cadmium selenocyanate and cadmium Mercury selenocyanate[J], Acta Crystallogr E,2006,62:88-90
61. X.Q.Wang,D.Xu,M.K.Lu,D.R.Yuan,S.G.Li,G.W.Lu,H.Q.Sun.et.al.,Physicochemical behav-eior of nonlinear optical crystal CdHg(SCN)4[J], J.Cryst.Growth,247(2003):432
62. X.Q. Wang,D. Xu,M.K. Lu,D.R.Yuan,X.Yin,G.H. Zhang,C.F. Song,S.Y Guo. Crystal Growth and Physical Properties of UV Nonlinear Optical Crystal Zinc Cadmium Thiocyanate, Zncd(SCN)4[J], Chem.Phys.Lett.,346(2001):393
63. X.N. Jiang, D. Xu, D.R. Yuan, W.T. Yu, M.K. Lu, S.Y. Guo, G.H. Zhang, Q. Fang. Synthesis, structure and properties of tetrakis (thiourea) mercury (Ⅱ) tetrakis (thiocyanato-N)zinc(Ⅱ)[J], Chin.Chem. Lett.,12(2001):279
64. J.G. Bergman Jr, S.K. Kurtz. Nonlinear optical materials[J], Materials Science and Engineering,1970,5(05):235-250
65. C.K. Lakshmanaperumal, A. Arulchakkaravarthi, N. Balamurugan, P.Santhanaraghavan, P. Ramasamy. Synthesis, crystal growth and characterization of novel NLO material: 4-Hydroxy benzal Dehyde-N-Methyl-4-stilbazolium tosylate[J], Journal of Crystal Growth.:2004,265(1-2):260-265
66. X.Q.Wang, D. Xu, D.R. Yuan, Y.P. Tian,W.T. Yu, S.Y. Sun, Z.H. Yang, Q.Fang, M.K. Lu, Y.X. Yan, F.Q. Meng, S.Y. Guo, G.H. Zhang, M.H. Jiang. Synthesis, Structure and properties of a new nonlinear optical material:zinc cadmium terathiocyanate[J], Mater. Res. Bull.:34(1999)2003
67. R. Rajasekaran,P. M. Ushasree, R. Jayavel, P. Ramasamy. Growth and characterization of zinc thiourea chloride (ZTC):a semiorganic nonlinear optical crystal[J], Journal of Crystal Growth,2001,299(1-4):563-567
68. X.Q. Wang,D. Xu,Y.T. Chowb,G.H. Zhang,M.K. Lu,D.R. Yuana,H.P. Chanb, H.Q. Sun,Y.L Geng,C.K. Chow,Q. Ren,P.L. Chu. Effects of pH and hydrogen-bonding on the growth and characterization of ZnCd(SCN)4[J], Journal of Crystal Growth,2004,267(1-2):263-269
69.王新强.双金属硫氰酸配合物晶体的生长和性质研究[D],山东济南：山东大学,2005
70.宁红霞.络合物型非线性光学晶体—ZCTC透光性能的研究[D].山东济南：山东大学,2002
71. Han Ye,Yao Shuyu,Sun Haiqing, Zhang Weiwei. Evaluation of the degree of crystallization in glass-ceramics by dielectric constant measurements[J], Advanced Materials Research, 2009,79(82):2279-2282
72.秦金贵,刘道玉.有机和金属有机非线性光学晶体材料[J],化学通报,1990,(10)：23-30
73. Kittipchal P,Peruta R L A,Koreuo Wski G M,et al.In-situ Poling and synthesis of NLO Chromophore—bearing Polyurethanes for second Harmonic Generation[J],Polymer Chemistry,1993,31:1365-1375
74. Xue Dongfeng,Zhou Shihong,Zhang Siyuan.Progress in the Study of Inorganic Nonlinear Optical Materials[J], Chemical Researches,1998,9(2):1-5
75. Zhang Liangfu,Ding Fujiang,Zhao Keqing,Yang Limei,WangChunyan,Li Li.Nonlinear Optical Characteristics of Organometallic Complexes[J],HE CHENG HUA XUE,1997,5(1):17-26
76. Jiang Minhua.The development of functional crystal materials[J], Journal of functional materials,2004,35,11-20
77. Sheng Yu,Zhang Wengong.Review of Organometal Nonlinear OPtieal Materials[J], Journal of functional materials,1995,26(01):1-12
78. V.Venkataramanan,G.Dhanaraj,V.K.Wadhawan,J.N.Shrewood,H.L.Bhat. Crystal growth and defects characterization of zinc tris(thiourea) Sulfate:a novel metalorganic nonlinear optical crystal[J],J.Cryst.Growth,1990,102:581-584
79. P.M. Ushasree,R. Muralidharan,R. Jayavel.P. Ramasamy. Growth of bis(thiourea) cadmium chloride single crystals-a potential NLO materials of organometallic complex[J], J. Cryst. Growth.2000,218,365-371
80. R.Valluvan, K.Selvaraju, S.Kumararaman. Growth and characterization Of sulphamic acid single crystals:A nonlinear optical material [J], Materials Chemistry and Physics,2006, 97:81-84
81. Ginson P.Joseph, J.Philip,K.Rajasekar, A. Joseph A. Pragasam, K. Tamilasaran, S.M. RaviKumar, P.Sagayaraj.Growth and characterization of an organometallic nonlinear optical crystal of manganese mercury thiocyanate(MMTC)[J], Journal of Crystal Growth,2006,296:51-57
82. J.Qin,C.Dai,D.Liu, C.Dai, C.Chen,B.Wu, C.Yang,C.Zhan. Influence of the molecular configuration on second-order optical properties of coordination compounds[J], Coord. Chem.Rev,1999,188:23-34
83. H.L.Sun,C.H.Ye,X.Y.Wang,J.R.Li,S.Gao,K.B.Yu.Lanthanide contraction and pH value controlled structural change in a series of rare earth complexes with p-aminobenzoic acid[J], Journal of Molecular Structure,2004,702:77-83
84.李南.新型非线性光学晶体ZnBi2B2O7的生长与性质研究[D],北京：中国科学院理化技术研究所,2009
85.薛海萍.碘酸盐非线性光学晶体材料的生长及其结构分析[D],北京：北京工业大学,2006
86.李真一.新型红外非线性光学晶体CsGeBr3的研究[D],山东青岛：山东科技大学,2006
87.洪海平,王业斌,林绮,周淑琴,金祥凤.无机非线性材料的探索[J],化学通报,1994,10：18-20
88. Frazier C.C,Harvey M.A, Coeketham M.P,et al.Second-harmonic Generation in Transition-metal-organic Compounds[J], J.Phys.Chem,1986,90:5703-5706
89. S.B.Monaeo,L.E.Davis,S.P.Velsko,F.T.Wng,D.Eimeri. Synthesis and Characterization of chemical analogs of L-arginine phosphate[J],J.Cryst. Growth,1987,85:252-255
90. F.zhang,D.Shen,G.shen,X. Wang.Growth and characterization of non-liner optical crystal Cd3Zn3B4O12[J],Materials Research Bulletin,2008,43:3188-3194
91.李莉.金属有机磷类配合物二阶非线性光学材料的合成、结构与性质研究[D],山东济南：山东大学,2009
92. S.Lin,Z.Sun,B.Wu,C.Chen.The nonlinear optical characteristics of a LiB3O5 crystal[J], J. Appl.Phys,1990,67:634-638
93. H.Jiang,D.Li,K.Zhang,H.Liu,J.Wang.Optical and thermal properties of Nonlinear optical crystal LaCaO(BO3)3[J], Chemical Physics Letters,2003,372:788-793
94. K.Wostyn,K, Binnemans,K.Claysand,A.Persoons. Molecular First HyPerpolarizability Data for Lanthanate Complexes Containing the Hemicyanine Chromophore[J], J.Phys.Chem.B2001,105:5169-5173
95. Chang Xin-an,Zang Hegui,Chen Xue-an,Xiao,Weiqiang,Hou Lin,Hao Xiuhong. Study on Crystal Growth of Metall organic Coordination Compound-Zinc Tris(thiourea) Sulfate[J], JOURNAL OF SYNTHETIC CRYSTALS,36(4):780-783
96.牛睿祺.非线性光学晶体的制备及性能研究与单分子磁体的制备及性能研究[D],北京：北京工业大学,2007
97. K.Xu, P.Loiseau.Growth and characterization of a nonlinear borate optical crystal: BaNaB9O15[J],Journal of Crystal Growth,2009,311:389-393
98. G.H. Hsiue,R.H. Lee,R.J. Jeng.A New Class of organic-Inorganic Sol-Gel Materials for Second-Order Nonlinear optics[J],Chem.Mater,1997,9:883-888
99. G.H. Hsiue,R.H. Lee,R.J. Jeng. Thermally Stable organic-Inorganic Sol-Gel Materials for Second-Order Nonlinear Optics[J], Macromol.Symp,2000,156:163-170
100. TAO Xutang,Jiang Minhua,Xu Dong,et al.Structure,growth and optical properties of nonlinear optical crystal Cd(NH2NHCSNH2)Cl2·H2O[J],Journal of Synthetic Crystals, 1987,16(1):28-32
101. KURTZ S K,PERRY T T.A powder technique for the evaluation of nonlinear optical materials [J], Journal of Applied Physics,1968,39(08):3978-3813.
102.王晓洋.非线性光学晶体—缺之不可的功能材料[J],中国建材,2001,05：82-83
103.吴林,赵波.非线性光学和非线性光学材料[J],大学化学,2002,17(06)：21-28
104.封继康.非线性光学材料的分子设计研究[J],化学学报,2005,63(14)：1245-1256
105. Shiyi Guo,Duorong Yuan,Dong Xu,Guanghui Zhang,Suoying Sun,Fanqing Meng, Xinqiang Wang,Xuening Jiang,Minhua Jiang.Growth of cadmium mercury thiocyanate dimethyl-sulphoxide single crystal for laser frequency doubling, Progress in Crystal Growth and Characterization of Materials,40(2000)75
106. X.Q. Wang,D. Xu,M.K. Lu,D.R. Yuan,G.H. Zhang,S.X. Xu,S.Y Guo, X.N.Jiang, et al.Growth and propertiees of UV nonlinear optical crystal:ZnCd(SCN)4, Mater.Res.Bull.,36(2001)1287
2.黄昆,韩汝琦.固体物理学[M].北京：高等教育出版社,1988
3.张玉龙,唐磊.人工晶体[M].北京：化学工业出版社,2005：44-59
4. Yuan Duorong,ZhangNan,Tao Xutang,Xu Dong,Jiang Minhua, Shao Zongshu. Study oncrystal Growth and Properties of a New Highly Efficient NLO material-Organometallic complex Tri-allylthiourea Mercury Chloride(ATMC)[J],Chinese Science Bulletin,1991, 36(16):1401-1404
5. Zhang Nan,Jiang Minhua,Yuan Duorong,Xu Dong,Yu Wentao,Tao Xutang.Study on thegrowth and properties of ATCC Crystal[J], Chinese Science Bulletin,1990,35(08): 646-649
6. Yuan Duorong,Zhang Nan,Tao Xutang, Jiang Minhua.A New Nonlinear optical Material-organ metallic complex tri-allylthiourea mercury chloride[J], Chinese Phys.Lett., 1990,07 (07):334-336
7. Zhan Nan, Jiang Min Hua,Yuan Duo Rong.A new nonlinear optical, materiae-organometalli complex tri-allythiourea cadmium chloride[J],Chin.Phys.Lett.,1989(6):280
8. Julien Zaeearo,Nathalie Sanz,EstelleBotzung APPert, PatrieeL.Baldeck, Alain Ibanez. organic nanocrystals grown in sol-gel matrices:a new type of hybrid material for optics nucleation et croissance confinee de nanocristaux organiquesenmatrices sol-gel:unnouveau type de materiaux organo-mineraux pour l'optique [J],C.R.Physique2002,3(4):463-478
9.胡安,章维益。固体物理学[M].北京：高等教育出版社,2005
10.蔡正千.热分析[M].北京：高等教育出版社,1993：74-83
11.刘粤惠,刘平安.X射线衍射分析原理与应用[M].北京：化学工业出版社,2003：83-120
12.祁景玉.X射线结构分析[M].上海：同济大学出版社.2003：87-98
13.N.布洛姆伯根.非线性光学[M].北京：科学出版社,1987：26
14.闵乃本.晶体生长的物理基础[M].上海：上海科学技术出版社,1982：433-436
15.王英华.X光衍射技术基础[M].北京：原子能出版社,1993：263-267
16.胡女丹.金属有机配合物非线性光学材料研究进展[J],六盘水师范高等专科学校学报,2010,22(6)：25-30
17.胡晓琴,胡拖平,许玉敏.金属-有机配合物的合成及其研究进展[J],广州化工, 2011,39(1)：13-15
18.邢光彩,蒋民华,邵宗书,许东.络合物型非线性光学新晶体—二氯二硫脲合镉(BTCC)[J],中国激光,1987,14(5)：302-308
19.邵宗书,邢光彩,蒋民华.粉末倍频效应—一种探索非线性光学晶体材料的有效方法[J],山东大学学报(自然科学版),1987,22(04)：118-123
20.杨俊涛,罗时军.二氯二硫脲合镉晶体的电子结构与光学性质的研究[J],湖北汽车工业学院学报,2010,24(1)：50-54
21.邢光彩,邵宗书,蒋民华.BTCC和KTP晶体倍频系数的测量[J],山东大学学报(自然科学版),1987,22(04)：107-117
22.张囡,蒋民华,袁多荣,许东,于文涛,陶绪堂.一种全新的金属络合物非线性倍频材料—TCC晶体的生长及性能研究[J],科学通报,1989：154-1156
23.张良辅,丁涪江,赵可清,杨立梅,王春燕,李莉[J],成都：合成化学,1997,5：(1)：17-27
24.张克从,张乐潓.晶体生长科学与技术(下)[M].北京：科学出版社,1997：374-442
25.杜文风,罗时军,尿素晶体的线性和非线性光学性质的从头算研究[J],湖北汽车工业学院学报,2008,22(2)：52-56
26.D.Amilan Jose,Ajeet Singh,Amitava Das and Bishwajit Ganguly. A density functionalst-udy to wards the preferential binding of anions to urea and thiourea[J], Elsevier. Tetrahedron Letters,48(2007):3695-3698
27.袁多荣,张囡,于文涛,许东,陶绪堂,蒋民华.非线性光学新晶体—二溴三丙烯基硫脲合镉[J],中国激光,1990,17(6)：332-335
28. Li Shengli, Yu Jianhua,Yang Jie,et al. Syntheses and Characterizations Of several new supramolecular coordination compounds[J], Journal of Anhui University Natural Science Edition,2007,31(6):62-65
29. Hou Wenbao,Xu Dong,Yuan Duorong,Liu Mingguo,ZhangNan,Tao Xutang, Sun Suoying, Jiang Minhua.Investigations on Tri-allylthiourea Mercury Bromide (ATMB)Crystal Growth[J],Cryst.Res.Technol,1994(7):939-944
30. Zhang Nan,Jiang Minhua,Yuan Duorong,Xu Dong,Tao Xutang,Shao Zongshu.The Quality and Performance of the Organometallic Complex Nonlinear Optical Material Tri-allylthiourea Cadmium Chloride[J],Journal of Crystal Growth,1990,102:581-584
31. Hou Wenbao,Xu Dong,Yuan Duorong,Liu Mingguo,ZhangNan,Tao Xutang, Sun Suoying, Jiang Minhua.A New Organometallic nonlinear optical material-Triallylthiourea mercury bromide(ATMB) crystal:growth and structure[J], Journalof Crystal Growth,1993, 133:71-74
32. X.L.Yu,Y.Sun,W.B.Hou,S.J.Zhang,Zh.X.Cheng.Interface kinetics and crystal growth mechanism of a new organometallic coordination compound:triallylthiourea mercury bromide[J],ELSEVIER. Journal of Crystal Growth,182(1997):428-433
33. E.Budevski,V.Bostanov,G,Staikov,Ann.Rev.Mater[J],Sci.10(1980)85
34. V.Venkataramanana,S.Maheswarana,J.N.Sherwoodb,H.L.Bhata.Crystal growth and phys-ical characterization of the semiorganic bis(thiourea) cadmium chloride[J], ELSEVIER. Journal of Crystal Growth,179(1997):605-610
35. W.B.Hou,Z.H.Yang,M.G.Liu,D.R.Yuan,D.Xu,N.Zhang,W.T.Yu,Y.H.Bing,S.Y.Sun, Ther-mal properties of a new organometallic nonlinear opticalmaterial, triallylthiourea mercury bromide [J],Materiala Letters 18(1994):207-210
36. W.B.Hou,M.H.Jiang,D.R.Yuan, Xu Dong,N.Zhang,M.G.Liu,X.T Tao.THE PREPARA-TION AND CHARACTERIZATION OF A NEW ORGANOMETALLIC NONLINEAR OPTICAL---TRI-ALLYLTHIOUREA MERCURY BROMIDE(ATMB) CRYSTAL [J], Mat.Res.Bull., Vol,1993(28):645-653
37. Dong Xu,Wen-Tao Yu,Xin-Qiang Wang,Duo-Rong Yuan,Meng-kai Lu,Ping Yang,Shi-Yi Guo,Fan-Qing Meng,Min-Hua Jiang. Zinc mercury thiocyanate(ZMTC)[J],Acta Cryst,1999(C55):1203-1205
38. Celia Marcos,Jose M,Victor Adovasio,Manuel Prieto,Santiago Garcia-Granda.Bis-(thiourea) cadmium Halides[J], Acta Crysty,1998(C54):1225-1229
39.袁多荣,张囡,陶绪堂,许东,于文涛,邵宗书,蒋民华.一组新型络合物晶体结构与光学性能的研究*[J],光学学报,1993,13(05)：456-460
40.蒋民华,许东,邢光彩.一类潜在的非线性光学材料—金属有机络合物[J],人工晶体,1985,14：3-4
41.袁多荣,陶绪堂,许东.高效有机非线性光学材料——二氯二丙烯基硫脲合汞晶体的生长和性能研究[J],科学通报,1991,36(02)：151-153
42.袁多荣,张囡,陶绪堂,许东,蒋民华,邵宗书。高效有机非线性光学材料—二氯三丙烯基硫脲合汞晶体的生长和性能研究’[J],科学通报,1990,2：151-153
43.孙海清,王淑峰.IIB族金属-硫脲配合物非线性光学晶体的研究进展[J],山东科技大学学报(自然科学版),2009,28(1)：55-57
44.袁多荣,张囡,于文涛.非线性光学新材料—二休三烯丙基硫脲[J],中国激光, 1990,17(06)：332-335
45.王莉,何飞,陈亚娟,阎吉祥,李家泽,吴世康,姜永才,张晓红.高效有机非线性光学材料特性的光谱分析[J],激光与红外,2004,34(05)：379-381
46. M.Oussaid, P.Becker,and C.Carabatos-Nedelec, Raman and Infrared Spectra of Bis(Thiourea)Zinc Chloride Zn[CS(NH2)]2Cl2 Single Crystal[J], Phys. Stat.Sol.(b),1998, 207:499-507
47. J.M.Alia, H.G.M.Edwards, M.D.Stoev, A systematic FT-Raman spectroscopic study of twelve bis-thiourea complexes, A(TU)2B2(A=Zn, Cd, Hg; B=Cl, Br, I, SCN) Spectrochim[J], Acta A,1999,55:2423
48. Ginson P.Joseph, K.Rajarajan, M.Vimalan, S.Selvakumar, S.M.Ravi Kumar J.Madhavan, P.Sagayaraj. Spectroscopic, thermal and mechanical behavior of allylthiourea cadmium chloride single crystals[J],ELSEVIER. Materials Research Bulletin,42(2007):2040-2047
49. H.Q.Sun,D.R.Yuan,X.Q. Wang,Y.Q.Lu,Z.H. Sun, X.C. Wei, X.L. Duan, C.N. Luan, M.K.Lu,D.Xu.Growth and thermal properties of tri-allylthiourea cadmium chloride(ATCC) crystal [J], Journal of Cryst Growth,256(2003):183
50. R.Perumal, S.Moorthy Babu. Growth and characterization of an organometallic nonlinear optical material tri-allylthiourea cadmium chloride(ATCC)[J], ELSEVIER.Materials Chemistry and Physics,107(2008):23-27
51. M.Lydia Caroline,S.Vasudevan. Growth and characterization of bis thiourea cadmium iodide:A semiorganic single crystal[J], ELSEVIER. Materials Chemistry and Physics,2008:5
52. K.Selvaraju,R.Valluvan,S.Kumararaman. Growth and characterization of a new metal-organic crystal:Potassium thiourea iodide[J], ELSEVIER.Materials Letters,60(2006):3130-3132
53. H.Q.Sun,D.R.Yuan,X.Q.Wang,X.F.Cheng,C.R.Gong,M.Zhou,H.Y.Xu,X.C.Wei, C.N.Luan, et.al.A novel metal-organic coordination complex crystal:tri-allylthiourea zinc chloride(ATZC)[J], Crystal Research and Technology,2005,40(9):882-886
54. P.A.Angeli Mary and S.Dhanuskodi.Growth and Characterization of a New Nonlinear Optical Crystal:Bis Thiourea Zinc Chloride[J], Cryst.Res.Technol.,2001,36:1231-1237
55. X.L.Duan, D.R YuanX.Q.Wang,X.F.Cheng,Z.H.Yang,S.Y.Guo,H.Q.Sun.Preparation and characterzation of nonlinear optical crystal materials:cadmium mercury thiocyanate and its lewis base adducts[J], Crysty.Res Technol..37(2002):446
56. Wang Xinqing,Xu Dong,et.al.Growth and characterization of the organometallic nonlinear optical crystal:manganese mercury thiocyanate (MMTC)[J], Mater. Res. Bull., 36(2001):879
57. K.Sangwal.Kinetic effects of impurities on the growth of single crystals from solutions[J], Journal of Crystal Growth,203(1999):197-212
58.孙海清.IIB族金属有机配合物非线性光学新材料的研究[D],山东济南：山东大学,2005
59.侯印春,潘守膺.非线性光学晶体及其应用[J]人工晶体学报,1990,19(04)：356-362
60. Sun Haiqing,Yuan Duorong,Yu Wentao,Wang Xinqing Liu Liqiang.Zinc cadmium selenocyanate and cadmium Mercury selenocyanate[J], Acta Crystallogr E,2006,62:88-90
61. X.Q.Wang,D.Xu,M.K.Lu,D.R.Yuan,S.G.Li,G.W.Lu,H.Q.Sun.et.al.,Physicochemical behav-eior of nonlinear optical crystal CdHg(SCN)4[J], J.Cryst.Growth,247(2003):432
62. X.Q. Wang,D. Xu,M.K. Lu,D.R.Yuan,X.Yin,G.H. Zhang,C.F. Song,S.Y Guo. Crystal Growth and Physical Properties of UV Nonlinear Optical Crystal Zinc Cadmium Thiocyanate, Zncd(SCN)4[J], Chem.Phys.Lett.,346(2001):393
63. X.N. Jiang, D. Xu, D.R. Yuan, W.T. Yu, M.K. Lu, S.Y. Guo, G.H. Zhang, Q. Fang. Synthesis, structure and properties of tetrakis (thiourea) mercury (Ⅱ) tetrakis (thiocyanato-N)zinc(Ⅱ)[J], Chin.Chem. Lett.,12(2001):279
64. J.G. Bergman Jr, S.K. Kurtz. Nonlinear optical materials[J], Materials Science and Engineering,1970,5(05):235-250
65. C.K. Lakshmanaperumal, A. Arulchakkaravarthi, N. Balamurugan, P.Santhanaraghavan, P. Ramasamy. Synthesis, crystal growth and characterization of novel NLO material: 4-Hydroxy benzal Dehyde-N-Methyl-4-stilbazolium tosylate[J], Journal of Crystal Growth.:2004,265(1-2):260-265
66. X.Q.Wang, D. Xu, D.R. Yuan, Y.P. Tian,W.T. Yu, S.Y. Sun, Z.H. Yang, Q.Fang, M.K. Lu, Y.X. Yan, F.Q. Meng, S.Y. Guo, G.H. Zhang, M.H. Jiang. Synthesis, Structure and properties of a new nonlinear optical material:zinc cadmium terathiocyanate[J], Mater. Res. Bull.:34(1999)2003
67. R. Rajasekaran,P. M. Ushasree, R. Jayavel, P. Ramasamy. Growth and characterization of zinc thiourea chloride (ZTC):a semiorganic nonlinear optical crystal[J], Journal of Crystal Growth,2001,299(1-4):563-567
68. X.Q. Wang,D. Xu,Y.T. Chowb,G.H. Zhang,M.K. Lu,D.R. Yuana,H.P. Chanb, H.Q. Sun,Y.L Geng,C.K. Chow,Q. Ren,P.L. Chu. Effects of pH and hydrogen-bonding on the growth and characterization of ZnCd(SCN)4[J], Journal of Crystal Growth,2004,267(1-2):263-269
69.王新强.双金属硫氰酸配合物晶体的生长和性质研究[D],山东济南：山东大学,2005
70.宁红霞.络合物型非线性光学晶体—ZCTC透光性能的研究[D].山东济南：山东大学,2002
71. Han Ye,Yao Shuyu,Sun Haiqing, Zhang Weiwei. Evaluation of the degree of crystallization in glass-ceramics by dielectric constant measurements[J], Advanced Materials Research, 2009,79(82):2279-2282
72.秦金贵,刘道玉.有机和金属有机非线性光学晶体材料[J],化学通报,1990,(10)：23-30
73. Kittipchal P,Peruta R L A,Koreuo Wski G M,et al.In-situ Poling and synthesis of NLO Chromophore—bearing Polyurethanes for second Harmonic Generation[J],Polymer Chemistry,1993,31:1365-1375
74. Xue Dongfeng,Zhou Shihong,Zhang Siyuan.Progress in the Study of Inorganic Nonlinear Optical Materials[J], Chemical Researches,1998,9(2):1-5
75. Zhang Liangfu,Ding Fujiang,Zhao Keqing,Yang Limei,WangChunyan,Li Li.Nonlinear Optical Characteristics of Organometallic Complexes[J],HE CHENG HUA XUE,1997,5(1):17-26
76. Jiang Minhua.The development of functional crystal materials[J], Journal of functional materials,2004,35,11-20
77. Sheng Yu,Zhang Wengong.Review of Organometal Nonlinear OPtieal Materials[J], Journal of functional materials,1995,26(01):1-12
78. V.Venkataramanan,G.Dhanaraj,V.K.Wadhawan,J.N.Shrewood,H.L.Bhat. Crystal growth and defects characterization of zinc tris(thiourea) Sulfate:a novel metalorganic nonlinear optical crystal[J],J.Cryst.Growth,1990,102:581-584
79. P.M. Ushasree,R. Muralidharan,R. Jayavel.P. Ramasamy. Growth of bis(thiourea) cadmium chloride single crystals-a potential NLO materials of organometallic complex[J], J. Cryst. Growth.2000,218,365-371
80. R.Valluvan, K.Selvaraju, S.Kumararaman. Growth and characterization Of sulphamic acid single crystals:A nonlinear optical material [J], Materials Chemistry and Physics,2006, 97:81-84
81. Ginson P.Joseph, J.Philip,K.Rajasekar, A. Joseph A. Pragasam, K. Tamilasaran, S.M. RaviKumar, P.Sagayaraj.Growth and characterization of an organometallic nonlinear optical crystal of manganese mercury thiocyanate(MMTC)[J], Journal of Crystal Growth,2006,296:51-57
82. J.Qin,C.Dai,D.Liu, C.Dai, C.Chen,B.Wu, C.Yang,C.Zhan. Influence of the molecular configuration on second-order optical properties of coordination compounds[J], Coord. Chem.Rev,1999,188:23-34
83. H.L.Sun,C.H.Ye,X.Y.Wang,J.R.Li,S.Gao,K.B.Yu.Lanthanide contraction and pH value controlled structural change in a series of rare earth complexes with p-aminobenzoic acid[J], Journal of Molecular Structure,2004,702:77-83
84.李南.新型非线性光学晶体ZnBi2B2O7的生长与性质研究[D],北京：中国科学院理化技术研究所,2009
85.薛海萍.碘酸盐非线性光学晶体材料的生长及其结构分析[D],北京：北京工业大学,2006
86.李真一.新型红外非线性光学晶体CsGeBr3的研究[D],山东青岛：山东科技大学,2006
87.洪海平,王业斌,林绮,周淑琴,金祥凤.无机非线性材料的探索[J],化学通报,1994,10：18-20
88. Frazier C.C,Harvey M.A, Coeketham M.P,et al.Second-harmonic Generation in Transition-metal-organic Compounds[J], J.Phys.Chem,1986,90:5703-5706
89. S.B.Monaeo,L.E.Davis,S.P.Velsko,F.T.Wng,D.Eimeri. Synthesis and Characterization of chemical analogs of L-arginine phosphate[J],J.Cryst. Growth,1987,85:252-255
90. F.zhang,D.Shen,G.shen,X. Wang.Growth and characterization of non-liner optical crystal Cd3Zn3B4O12[J],Materials Research Bulletin,2008,43:3188-3194
91.李莉.金属有机磷类配合物二阶非线性光学材料的合成、结构与性质研究[D],山东济南：山东大学,2009
92. S.Lin,Z.Sun,B.Wu,C.Chen.The nonlinear optical characteristics of a LiB3O5 crystal[J], J. Appl.Phys,1990,67:634-638
93. H.Jiang,D.Li,K.Zhang,H.Liu,J.Wang.Optical and thermal properties of Nonlinear optical crystal LaCaO(BO3)3[J], Chemical Physics Letters,2003,372:788-793
94. K.Wostyn,K, Binnemans,K.Claysand,A.Persoons. Molecular First HyPerpolarizability Data for Lanthanate Complexes Containing the Hemicyanine Chromophore[J], J.Phys.Chem.B2001,105:5169-5173
95. Chang Xin-an,Zang Hegui,Chen Xue-an,Xiao,Weiqiang,Hou Lin,Hao Xiuhong. Study on Crystal Growth of Metall organic Coordination Compound-Zinc Tris(thiourea) Sulfate[J], JOURNAL OF SYNTHETIC CRYSTALS,36(4):780-783
96.牛睿祺.非线性光学晶体的制备及性能研究与单分子磁体的制备及性能研究[D],北京：北京工业大学,2007
97. K.Xu, P.Loiseau.Growth and characterization of a nonlinear borate optical crystal: BaNaB9O15[J],Journal of Crystal Growth,2009,311:389-393
98. G.H. Hsiue,R.H. Lee,R.J. Jeng.A New Class of organic-Inorganic Sol-Gel Materials for Second-Order Nonlinear optics[J],Chem.Mater,1997,9:883-888
99. G.H. Hsiue,R.H. Lee,R.J. Jeng. Thermally Stable organic-Inorganic Sol-Gel Materials for Second-Order Nonlinear Optics[J], Macromol.Symp,2000,156:163-170
100. TAO Xutang,Jiang Minhua,Xu Dong,et al.Structure,growth and optical properties of nonlinear optical crystal Cd(NH2NHCSNH2)Cl2·H2O[J],Journal of Synthetic Crystals, 1987,16(1):28-32
101. KURTZ S K,PERRY T T.A powder technique for the evaluation of nonlinear optical materials [J], Journal of Applied Physics,1968,39(08):3978-3813.
102.王晓洋.非线性光学晶体—缺之不可的功能材料[J],中国建材,2001,05：82-83
103.吴林,赵波.非线性光学和非线性光学材料[J],大学化学,2002,17(06)：21-28
104.封继康.非线性光学材料的分子设计研究[J],化学学报,2005,63(14)：1245-1256
105. Shiyi Guo,Duorong Yuan,Dong Xu,Guanghui Zhang,Suoying Sun,Fanqing Meng, Xinqiang Wang,Xuening Jiang,Minhua Jiang.Growth of cadmium mercury thiocyanate dimethyl-sulphoxide single crystal for laser frequency doubling, Progress in Crystal Growth and Characterization of Materials,40(2000)75
106. X.Q. Wang,D. Xu,M.K. Lu,D.R. Yuan,G.H. Zhang,S.X. Xu,S.Y Guo, X.N.Jiang, et al.Growth and propertiees of UV nonlinear optical crystal:ZnCd(SCN)4, Mater.Res.Bull.,36(2001)1287