薯莨色素的提取及对棉和真丝织物的染色性能研究
摘要
本文对从薯莨中提取薯莨色素的方法进行了优选,得到了提取的最佳工艺:70%丙酮溶液为提取剂,溶质和溶剂比1:5,60℃水浴中浸提3h。并且对提取的薯莨色素的pH、光照、温度和金属离子对其稳定性的影响进行了研究,结果表明,薯莨色素耐光性差,适宜避光保存;在70℃以下、酸碱为中性的条件下性质稳定;Fe2+和Zn2+对其稳定性的影响不大,但是Ti4+对其影响很大。
用提取的薯莨色素溶液对棉及真丝织物进行染色实验,通过测定K/S值及颜色特征值L*、a*、b*,确定了染色的最佳工艺,并且测定染色后织物的色牢度。结果表明,以铁离子为媒染剂,采用轧染法染色后的棉和真丝织物都能获得较好的染色深度,而以铝离子为媒染剂染色试样的颜色较浅,薯莨染色试样的水洗和摩擦牢度基本都符合要求,但日晒牢度差。薯莨染色对织物的抗紫外性能,服用性能和物理机械性能产生不同程度的影响,扫描电镜和X-射线衍射等测试表明,染色没有使棉和真丝的内部结构发生变化。
Extracting pigment from Diosorea Cirrhosa had been studied in the thesis,the best conditions of extracting were as follows: using 70%CH3COCH3, the ratio of solvent and solute 1:5,temperature 60℃and lasting for 3 hours. And the stability of pigment extracted from Diosorea Cirrhosa had also been researched including photostability, thermostability, pH, the existence of a variety of metal ion, the results show that: the pigment must be preserved without lights as the matter of poor photostability, it is stable under the condition of 70℃and neutral, it can maintain stability with the existence of Fe2+ and Zn2+, but it is impacted greatly with Ti4+.
The pigment which was extracted from Diosorea Cirrhosa was used to dye silk and cotton fabric, the best dyeing process was obtained according to K/S, L*,a*,b*,and the dyeing fastness was tested. The better dyeing performance was obtained with pad dyeing, using Fe2+ as the mordant, but it was not with Al3+.The washing and rubbing fastness of dyed fabrics meet the basic requirement. The treatment brought varying degrees of impact to the uv-resistant, comfort and physical properties of the fabric, the dyed fabrics were tested by scanning electron microscope and energy spectrum x-diffraction, it was found that the dyeing processing scarcely influenced the inner structure of silk and cotton.
用提取的薯莨色素溶液对棉及真丝织物进行染色实验,通过测定K/S值及颜色特征值L*、a*、b*,确定了染色的最佳工艺,并且测定染色后织物的色牢度。结果表明,以铁离子为媒染剂,采用轧染法染色后的棉和真丝织物都能获得较好的染色深度,而以铝离子为媒染剂染色试样的颜色较浅,薯莨染色试样的水洗和摩擦牢度基本都符合要求,但日晒牢度差。薯莨染色对织物的抗紫外性能,服用性能和物理机械性能产生不同程度的影响,扫描电镜和X-射线衍射等测试表明,染色没有使棉和真丝的内部结构发生变化。
Extracting pigment from Diosorea Cirrhosa had been studied in the thesis,the best conditions of extracting were as follows: using 70%CH3COCH3, the ratio of solvent and solute 1:5,temperature 60℃and lasting for 3 hours. And the stability of pigment extracted from Diosorea Cirrhosa had also been researched including photostability, thermostability, pH, the existence of a variety of metal ion, the results show that: the pigment must be preserved without lights as the matter of poor photostability, it is stable under the condition of 70℃and neutral, it can maintain stability with the existence of Fe2+ and Zn2+, but it is impacted greatly with Ti4+.
The pigment which was extracted from Diosorea Cirrhosa was used to dye silk and cotton fabric, the best dyeing process was obtained according to K/S, L*,a*,b*,and the dyeing fastness was tested. The better dyeing performance was obtained with pad dyeing, using Fe2+ as the mordant, but it was not with Al3+.The washing and rubbing fastness of dyed fabrics meet the basic requirement. The treatment brought varying degrees of impact to the uv-resistant, comfort and physical properties of the fabric, the dyed fabrics were tested by scanning electron microscope and energy spectrum x-diffraction, it was found that the dyeing processing scarcely influenced the inner structure of silk and cotton.
引文
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[2]成都科学技术大学等.制革化学及工艺学[M].北京:轻工业出版社,1982.
[3]张文德.植物鞣质化学及鞣料[M].北京:轻工业出版社,1985.
[4]张力平,孙天霞等.植物多酚的研究现状及发展前景[J].林业科学,2005,6:159-162.
[5]狄莹,石碧.植物多酚在化妆品中的应用[J].日用化学工业,1998,3:20-23.
[6]王建新.天然活性化妆品[M].北京:中国轻工业出版社,1997.
[7]宋立江,狄莹,石碧.植物多酚研究与利用的意义及发展趋势[J].化学进展,2000,12(2):161-170.
[8]Wheatley M.Use of tannins in adhensive application[J].Plant polyphenols,1992,Plenum press.
[9]Haslame L,Cai Y. Traditional herbal medicines-the role of polyplenols[J].Plant medica,55:1-3.
[10]石碧,狄莹等.从植物单宁的利用看以植物原料的精细化工的发展[J].化工学报,1998,49:43-50.
[11]黄占华,方桂珍.植物单宁的应用及研究进展[J].林产化工通讯,2005,39(5):39-41.
[12]何强,姚开等.植物单宁的营养学特性[J].林产化学与工业,2001,21(1):80-85.
[13]Shay Y S, Ephraim P L,Ishak N. Antioxidant and eicosanoid enzyme inhibiton properties of pomegranate seed oil and fermented juice flavonoids[J].Journal of ethnopharmacology,1996,66(1):11-17.
[14]Wang B, Lai Y F,Gideon M. Differential inhibition of enkaryote protein kinases by condenced tannins[J].Phytochemistry,1996,43(2):359-365.
[15]石碧,狄莹.植物多酚[M].北京:科学出版社,2000.
[16] 吴浩亮.漫话莨纱绸[J].丝绸,1999,16(7):41~42.
[17] 刘玉明,靳小青,黄宝康,沈越. 薯莨及其易混品的鉴别研究[J].时珍国医国药,2006,17(9):1626~1627.
[18] 程金友,何金鹭,宋健. 红药子与混淆品薯莨鬼灯檠的性状及理化鉴别[J].时珍国医国药,1998,9(5):447.
[19] 肖尊琰. 研究报告选集[M]. 北京: 中国林业出版社,1986.
[20]中国科学植物研究所.中国经济植物志[M].北京:科学出版社,1961.
[21] 肖培根,连文琰.中国植物原色图鉴,1 版[M].北京:中国农业出版社,1999:574.
[22] 黎碧娜,何鸣,杨辉荣.薯莨色素的提取和性能研究[J].广东工学院学报,1994,11:74~80.
[23] 熊晓燕,陈曼群,黎碧娜.从薯莨中提取单宁的最佳工艺条件研究[J].广东工业大学学报,1998,15(4):35~39.
[24] 黎碧娜,何鸣,杨辉荣.从野生植物薯莨中提取抗氧化成分的研究[J].现代化工,1996,(6):26~28.
[25] 黄瑞松,苏青,黄永灵,丘记珍.均匀设计法优选薯莨的提取工艺条件[J].华西药学杂志.2003,18(3):199~210.
[26]谢珍珍,傅月华等.红曲色素提取的研究[J].中国粮油学报,1995,10(3):29-32.
[27]胡隆基,白东江,杨海宁.甘薯红色素稳定性研究[J].食品与发酵工业,1993,2:39-43.
[28]Z Czochanska , L Y Foo , R H Newman. Polymetic proanthocyandins. Stereochemistry,strucural units and molecular weight.J.C.S.PerkinⅠ,1980:2278-2286.
[29]顾人霞.中国林业会林产化学化工学会树木提取物化学与利用学术讨论会论文[J].1986.
[30]L Y Foo. Proanthocyanidins: Gross chemical structures by infrared spectra. Phytochemistry,1981,20(6):1397-1402.
[31]程万里.天然染料姜黄对真丝织物的染色性能研究[J].印染助剂,2002,19(1):31-34.
[32]徒晓茜,王祥荣.桑葚色素对真丝织物的染色性能研究[J].印染助剂,2007,3:15-18.
[33]路艳华,程万里,陈宇岳.高粱红天然染料对棉织物的染色性能研究[J].印染助剂,2005,11:27-30.
[34]周家伟,程万里.环氧交联剂 EH 对苏木植物染料的固色作用[J].纺织学报,2006,4:39-43.
[35]张建波,朱平等.棉织物的天然染料媒染工艺研究[J].印染,2005,16:8-11.
[36]慈云祥.分析化学中心的配位化合物[M].北京:北京大学出版社,1996.
[37] 张祥麟,康衡. 配位化学[M].长沙:中南工业大学出版社, 1986.
[38]金斗满,朱文祥.配位化学研究方法[M].北京:科学出版社,1996.
[39]孙为银.配位化学[M].北京:化学工业出版社,2004.
[41]陈英.染整工艺实验教程[M].北京:中国纺织出版社,2004.
[42]赵涛.染整工艺学教程[M].北京:中国纺织出版社,2004.
[43]吴雄英.纺织品抗紫外线辐射性能测试方法比较[J].印染,2001,2:38-40.
[44]李平,王煜等.抗紫外织物测试结果的统计分析[J].印染,2001,5:44-46.
[45] 邵苏秀,安玉山.抗紫外线纺织品的研究与评价[J].江苏纺织,2005,6:25-27.
[46] 张秀红,姜连仁.抗紫外纺织品概述[J].中国科技信息,2006,5:70.
[47] 朱慧敏,陈志.天然产物抗紫外线的研究进展[J].青海科技,2007,1:49-51.
[48]代雪梅,顾平.真丝织物透湿性的影响因素分析[J].江苏丝绸,2005,5:1-3.
[49] 陈雁,潘志娟.真丝材料热湿舒适性的研究[J].苏州丝绸工学院学报.2001,21(1):10-14.
[50] 黄素平.真丝织物的服用舒适性能[J].广西纺织科技.2000,29(2):41-43.
[51]郭维婵,杨斌.夏季织物服用性能探讨[J].丝绸,1997,8:43-46.
[52]姚穆,周锦芳等.纺织材料学[M].北京:纺织工业出版社,1997.
[2]成都科学技术大学等.制革化学及工艺学[M].北京:轻工业出版社,1982.
[3]张文德.植物鞣质化学及鞣料[M].北京:轻工业出版社,1985.
[4]张力平,孙天霞等.植物多酚的研究现状及发展前景[J].林业科学,2005,6:159-162.
[5]狄莹,石碧.植物多酚在化妆品中的应用[J].日用化学工业,1998,3:20-23.
[6]王建新.天然活性化妆品[M].北京:中国轻工业出版社,1997.
[7]宋立江,狄莹,石碧.植物多酚研究与利用的意义及发展趋势[J].化学进展,2000,12(2):161-170.
[8]Wheatley M.Use of tannins in adhensive application[J].Plant polyphenols,1992,Plenum press.
[9]Haslame L,Cai Y. Traditional herbal medicines-the role of polyplenols[J].Plant medica,55:1-3.
[10]石碧,狄莹等.从植物单宁的利用看以植物原料的精细化工的发展[J].化工学报,1998,49:43-50.
[11]黄占华,方桂珍.植物单宁的应用及研究进展[J].林产化工通讯,2005,39(5):39-41.
[12]何强,姚开等.植物单宁的营养学特性[J].林产化学与工业,2001,21(1):80-85.
[13]Shay Y S, Ephraim P L,Ishak N. Antioxidant and eicosanoid enzyme inhibiton properties of pomegranate seed oil and fermented juice flavonoids[J].Journal of ethnopharmacology,1996,66(1):11-17.
[14]Wang B, Lai Y F,Gideon M. Differential inhibition of enkaryote protein kinases by condenced tannins[J].Phytochemistry,1996,43(2):359-365.
[15]石碧,狄莹.植物多酚[M].北京:科学出版社,2000.
[16] 吴浩亮.漫话莨纱绸[J].丝绸,1999,16(7):41~42.
[17] 刘玉明,靳小青,黄宝康,沈越. 薯莨及其易混品的鉴别研究[J].时珍国医国药,2006,17(9):1626~1627.
[18] 程金友,何金鹭,宋健. 红药子与混淆品薯莨鬼灯檠的性状及理化鉴别[J].时珍国医国药,1998,9(5):447.
[19] 肖尊琰. 研究报告选集[M]. 北京: 中国林业出版社,1986.
[20]中国科学植物研究所.中国经济植物志[M].北京:科学出版社,1961.
[21] 肖培根,连文琰.中国植物原色图鉴,1 版[M].北京:中国农业出版社,1999:574.
[22] 黎碧娜,何鸣,杨辉荣.薯莨色素的提取和性能研究[J].广东工学院学报,1994,11:74~80.
[23] 熊晓燕,陈曼群,黎碧娜.从薯莨中提取单宁的最佳工艺条件研究[J].广东工业大学学报,1998,15(4):35~39.
[24] 黎碧娜,何鸣,杨辉荣.从野生植物薯莨中提取抗氧化成分的研究[J].现代化工,1996,(6):26~28.
[25] 黄瑞松,苏青,黄永灵,丘记珍.均匀设计法优选薯莨的提取工艺条件[J].华西药学杂志.2003,18(3):199~210.
[26]谢珍珍,傅月华等.红曲色素提取的研究[J].中国粮油学报,1995,10(3):29-32.
[27]胡隆基,白东江,杨海宁.甘薯红色素稳定性研究[J].食品与发酵工业,1993,2:39-43.
[28]Z Czochanska , L Y Foo , R H Newman. Polymetic proanthocyandins. Stereochemistry,strucural units and molecular weight.J.C.S.PerkinⅠ,1980:2278-2286.
[29]顾人霞.中国林业会林产化学化工学会树木提取物化学与利用学术讨论会论文[J].1986.
[30]L Y Foo. Proanthocyanidins: Gross chemical structures by infrared spectra. Phytochemistry,1981,20(6):1397-1402.
[31]程万里.天然染料姜黄对真丝织物的染色性能研究[J].印染助剂,2002,19(1):31-34.
[32]徒晓茜,王祥荣.桑葚色素对真丝织物的染色性能研究[J].印染助剂,2007,3:15-18.
[33]路艳华,程万里,陈宇岳.高粱红天然染料对棉织物的染色性能研究[J].印染助剂,2005,11:27-30.
[34]周家伟,程万里.环氧交联剂 EH 对苏木植物染料的固色作用[J].纺织学报,2006,4:39-43.
[35]张建波,朱平等.棉织物的天然染料媒染工艺研究[J].印染,2005,16:8-11.
[36]慈云祥.分析化学中心的配位化合物[M].北京:北京大学出版社,1996.
[37] 张祥麟,康衡. 配位化学[M].长沙:中南工业大学出版社, 1986.
[38]金斗满,朱文祥.配位化学研究方法[M].北京:科学出版社,1996.
[39]孙为银.配位化学[M].北京:化学工业出版社,2004.
[41]陈英.染整工艺实验教程[M].北京:中国纺织出版社,2004.
[42]赵涛.染整工艺学教程[M].北京:中国纺织出版社,2004.
[43]吴雄英.纺织品抗紫外线辐射性能测试方法比较[J].印染,2001,2:38-40.
[44]李平,王煜等.抗紫外织物测试结果的统计分析[J].印染,2001,5:44-46.
[45] 邵苏秀,安玉山.抗紫外线纺织品的研究与评价[J].江苏纺织,2005,6:25-27.
[46] 张秀红,姜连仁.抗紫外纺织品概述[J].中国科技信息,2006,5:70.
[47] 朱慧敏,陈志.天然产物抗紫外线的研究进展[J].青海科技,2007,1:49-51.
[48]代雪梅,顾平.真丝织物透湿性的影响因素分析[J].江苏丝绸,2005,5:1-3.
[49] 陈雁,潘志娟.真丝材料热湿舒适性的研究[J].苏州丝绸工学院学报.2001,21(1):10-14.
[50] 黄素平.真丝织物的服用舒适性能[J].广西纺织科技.2000,29(2):41-43.
[51]郭维婵,杨斌.夏季织物服用性能探讨[J].丝绸,1997,8:43-46.
[52]姚穆,周锦芳等.纺织材料学[M].北京:纺织工业出版社,1997.