摘要
第一章:简要概述了修饰电极、碳纳米管、环糊精的基本内容,综述了近年来染料与环糊精相互作用的研究进展。
第二章:采用循环伏安法研究了活性艳橙K-7R在玻碳电极上的电化学行为。在0.2mol·L~(-1)(pH 7.0)Na_2HPO_4-KH_2PO_4缓冲液中,活性艳橙K-7R在-100 mV(vs.SCE)处有一对稳定、灵敏的氧化还原峰,其峰电流与浓度在1.0×10~(-7)~1.0×10~(-5)mol·L~(-1)范围内呈良好的线性关系,检测限为4.0×10~(-8)mol·L~(-1),RSD为2.61%。用“直线法”测定了活性艳橙K-7R与几种不同环糊精的包结比和包结常数,比较了包结能力,探讨了包结位点及影响包结能力大小的因素。
第三章:制备了MWNTs/Nafion修饰玻碳电极,详细研究了灿烂甲酚紫(BCV)在电极上的电化学行为。发现MWNTs/nafion复合膜可以较好的电催化BCV,BCV在修饰电极上发生了2电子2质子氧化还原反应。采用差示脉冲伏安法研究了BCV与γ-CD、HP-γ-CD的相互作用,计算了包结比和包结常数。此外,用分光光度法和~1HNMR法进一步证实了包结物的形成。结果表明,BCV可以在γ-CD空腔内形成H-聚集体。γ-CD和HP-γ-CD与该染料的二聚体均形成1:1的包结物,包结常数分别为2650 L·mol~(-1)和8040 L·mol~(-1),修饰环糊精的包结能力大于母体环糊精,说明体积匹配是包结物形成的决定性因素。
第四章:考察了甲基紫(MV)、乙基紫(EV)在MWNTs/Nafion修饰玻碳电极上的电化学行为。MV和EV在修饰电极上均发生了2电子2质子氧化还原反应,MV呈现出较EV强的电子转移能力;在溶液中,MV的扩散系数也略高于EV。采用差示脉冲伏安法研究了MV、EV与β-CD及其衍生物的相互作用,计算了包结比和包结常数。实验结果表明,各种环糊精对EV的包结能力均大于对MV的包结能力;MV、EV与各种环糊精的包结能力顺序均为:CM-β-CD>HP-β-CD>TM-β-CD>DM-β-CD>β-CD。包结常数的大小说明EV的分子尺寸更适于被β-CD包结。修饰环糊精的包结能力大于母体环糊精,说明体积匹配和疏水作用是包结物形成的决定性因素。而CM-β-CD显示出的强的包结能力则进一步证实静电作用对包合物的形成具有一定的贡献。
第五章:蓝色盐VB在酸性介质中易于聚合成二聚体或高聚体,在MWNTs/Nafion修饰玻碳电极表面发生2电子2质子的氧化还原反应。与环糊精形成包结物后,VB的扩散系数增加,导致峰电流增大,同时也阻碍了重氮盐分子的聚合。HP-β-CD、β-CD、HP-α-CD及α-CD与蓝色盐VB均形成1:1的包结物,不同的环糊精与VB的包结能力强弱次序为:HP-β-CD>β-CD>HP-α-CD>α-CD,而γ-CD空腔太大不适合包合VB。
Chapter 1:The fundamental contents of modified electrodes,carbon nanotubes and cyclodextrins were briefly introduced.The research progress of the interaction between dyes and cyclodextrins(CDs) in recent years was summarized in details.
Chapter 2:The electrochemical behavior of Reactive Brilliant Orange K-7R at glassy carbon electrode was studied by cyclic voltammetry method.The result showed that Reactive Brilliant Orange K-7R had a stable and sensitive oxidation-reduction peak at about-100mV in 0.2mol·L~(-1) Na_2HPO_4-KH_2PO_4 (pH 7.0) buffer solution.The peak current is proportional to the concentration in the range of 1.0×10~(-7)~1.0×10~(-5)mol·L~(-1).The limit of detection is 4.0×10~(-8) mol·L~(-1) and RSD is 2.61%.The corresponding inclusion ratio and inclusion constant were determined by "straight line method".The inclusion ability between the dye and different kinds of cyclodextrins was compared. Furthermore,the possible inclusion mechanism was proposed.
Chapter 3:MWNTs/Nafion modified GCE was fabricated and used to study the electrochemical behavior of Brilliant Cresyl violet(BCV).It was found that MWNTs/Nafion composite membrane was able to electrocatalyze BCV, and the redox of BCV involved two electrons and two protons.The inclusion interaction between BCV withγ-CD and HP-γ-CD were studied based on the differential pulse voltammetry(DPV) method.The inclusion ratio and inclusion constants were calculated.The formation inclusion complexes of BCV withγ-CD were further confirmed by UV-Vis and ~1HNMR spectrophotometry.The result showed that two BCV molecules could form H-aggregation in the cavity ofγ-CD.γ-CD and HP-γ-CD could form 1:1 inclusion complex with the dimmer of BCV,and the inclusion constants were 2650 L·mol~(-1) and 8040 L·mol~(-1),respectively.The inclusive ability of modifiedγ-CD was stronger than the nativeγ-CD,which further indicated the major factor was size matching in the progress of forming inclusior complex.
Chapter 4:The electrochemical behavior and the reaction mechanism of methyl violet(MV) and ethyl violet(EV) on the MWNTs/Nafion modified GCE were investigated in detail.The redox of MV and EV involved two electrons and two protons,and electron transfer ability and diffusion coefficient of MV were stronger than those of EV.The inclusion interaction of MV and EV withβ-CD and its derivatives were studied by DPV method, respectively.The inclusion ratios and inclusion constants were all calculated by "straight line method".The experimental showed thatβ-CD and its derivatives also presented stronger inclusion ability towards EV.The inclusion ability order of CDs is CM-β-CD>HP-β-CD>TM-β-CD>DM-β-CD>β-CD.The inclusion constants suggested that the molecular size of EV is more suitable for the cavity ofβ-CD.Inclusion capacity of modified CDs was greater than that of the native CDs,indicating the major factors affecting inclusive ability are size matching and hydrophobicity.However, CM-β-CD showed stronger inclusive ability,suggesting the charge interaction between CDs and guest had addtional contribution.
Chapter 5:In acid solution,Fast Blue Salt VB was easy to aggregate into dimer or high polymer,and exhibited two electrons and two protons redox process on the modified electrode.The diffusion coefficient of VB increased with the formation of inclusion complexes with CDs,and lead to the increase of the peak current.In addition,the formation of inclusion complexes prohibited the polymerization of diazonium salt molecules.VB could form 1:1 inclusion complexes with HP-β-CD,β-CD,HP-α-CD andα-CD with the inclusion ability order of HP-β-CD>β-CD>HP-α-CD>α-CD,andγ-CD was not suitable for inclusion due to the larger cavity.
引文
[1]YANG M L,KABULSKI J L,WOLLENBERG L,CHEN X,SUBRAMANIAN M,TRACY Y S,LEDERMAN D,GANNETT P M,WU N.Electrocatalytic drug metabolism by CYP2C9 bonded to a self-assembled monolayer-modified electrode[J].Drug Metab Dispos.,2009,37(4):892-899.
[2]TOMINAGA M,TAEMA Y,TANIGUCHI I.Electrocatalytic glucose oxidation at bimetallic gold-copper nanoparticle-modified carbon electrodes in alkaline solution[J].J.Electroanal.Chem.,2008,624(1-2):1-8.
[3]MAKGAE M E,KLINK M J,CROUCH A M.Performance of sol-gel Titanium Mixed Metal Oxide electrodes for electro-catalytic oxidation of phenol[J].Appl.Catal.B,2008,84(3-4):659-666.
[4]MAZLOUM ARDAKANI M,TALEAT Z,BEITOLLAHI H,SALAVATI-NIASARI M,MIRJALILI B B F,TAGHAVINIA N.Electrocatalytic oxidation and nanomolar determination of guanine at the surface of a molybdenum(Ⅵ) complex-TiO_2nanoparticle modified carbon paste electrode[J].J.Electroanal.Chem.,2008,624(1-2):73-78.
[5]李敏,朱秋芳,陈志敏.Mb-Collagen薄膜电极对O_2,H_2O_2的电化学催化[J].中北大学学报,2007,28(4):332-334.
[6]任旺,丁杰,张英.抗坏血酸在聚肉桂酸修饰电极上的电催化氧化[J].化学传感器,2008,28(3):58-61.
[7]卫应亮,张路平,邵晨,冯辉,李现利.碳纳米管修饰电极上沙丁胺醇电催化氧 化研究[J].电化学,2008,14(3):278-283.
[8]LIU Z Y,PAN K,LIU M,WANG M J,L(U|¨) Q,LI J H,BAI Y B,LI T J.Al_2O_3-coated SnO_2/TiO_2 composite electrode for the dye-sensitized solar cell[J].Electrochim.Acta,2005,50(13):2583-2589.
[9]NIAZOV T,SHLYAHOVSKY B,WILLNER I.Photoswitchable electrocatalysis and catalyzed chemiluminescence using photoisomerizable monolayer-functionalized surfaces and Pt nanoparticles[J].J.Am.Chem.Soc.,2007,129(20):6374-6375.
[10]CHENG X,ZHANG S,ZHANG H Y.Determination of carbohydrates by capillary zone electrophoresis with amperometric detection at a nano-nickel oxide modified carbon paste electrode[J].Food Chem.,2008,1011(2):830-835.
[11]BIAGIOTTI V,VALENTINI F,TAMBURRI E,TERRANOVA M L,MOSCONE D,PALLESCHI G.Synthesis and characterization of polymeric films and nanotubule nets used to assemble selective sensors for nitrite detection in drinking water[J].Sens.Actuators B,2007,122(1):236-242.
[12]王桂香,徐法君,刘道杰.化学修饰电极在选择性富集分离中的应用[J].冶金分析,2004,24(4):19-23.
[13]ZHANG L,ZHANG C H,LIAN J Y.Electrochemical synthesis of polyaniline nano-networks on p-aminobenzene sulfonic acid functionalized glassy carbon electrode:Its use for the simultaneous determination of ascorbic acid and uric acid[J].Biosens.Bioelectron.,2008,24(4):690-695.
[14]顾家山,何心伟,褚道葆.纳米TiO_2膜阴极电催化合成丁二酸的研究[J].安徽师范大学学报,2005,28(3):298-302.
[15]KUMAR S A,LO P H,CHEN S M.Electrochemical selective determination of ascorbic acid at redox active polymer modified electrode derived from direct blue 71[J].Biosens.Bioelectron.,2008,24(4):518-523.
[16]KOZLOWSKI C A,WALKOWIAK W,GIREK T.Modified cyclodextrin polymers as selective ion carriers for Pb(Ⅱ) separation across plasticized membranes[J].J Membrane Sci.,2008,310(1):312-320.
[17]NAKANISHI T,MATSUNAGA M,NAGASAKA M,ASAHI T,OSAKA T.Enantioselectivity of Redox Reaction of DOPA at the Gold Electrode Modified with a Self-Assembled Monolayer of Homocysteine[J].J.Am.Chem.Soc.,2006,128(41):13322-13323.
[18]董绍俊,车广礼,谢远武.化学修饰电极[M].科学出版社,1995,p16.
[19]MATEMADOMBO F,WESTBROEK P,NYOKONG T.Electroanalysis of thiocyanate using a novel glassy carbon electrode modified by aryl radicals and cobalt tetracarboxyphthalocyanine[J].Electrochim.Acta,2007,53(2):480-486.
[20]LIGAJ M,JASNOWSKA J,MUSIAL W G,FILIPIAK M.Covalent attachment of single-stranded DNA to carbon paste electrode modified by activated carboxyl groups[J].Electrochim.Acta,2006,51(24):5193-5198.
[21]BALLARIN B,CASSANI M C,SCAVETTA E,TONELLI D.Self-assembled gold nanoparticles modified ITO electrodes:The monolayer binder molecule effect[J].Electrochim.Acta,2008,53(27):8034-8044.
[22]MOCCELINI S K,FERNANDES S C,De CAMARGO T P,NEVES A,VIEIRA I C.Self-assembled monolayer of nickel(Ⅱ) complex and thiol on gold electrode for the determination of catechin[J].Talanta,2009,78(3):1063-1068.
[23]WANG F,LIU Q Y,WU Y J,YE B X.Langmuir-Blodgett film of p-tert-butylthiacalix[4]arene modified glassy carbon electrode as voltammetric sensor for the determination of Ag~+[J].J.Electroana.Chem.,2009,630(1-2):49-54.
[24]GLIGOR D,DILGIN Y,POPESCU I C,GORTON L.Poly-Phenothiazine Derivative-Modified Glassy Carbon Electrode for NADH Electrocatalytic Oxidation[J].Electrochim.Acta,2009,54(11):3124-3128.
[25]CUI K,SONG Y H,WANG L.Electrochemical and electrocatalytic behaviors of poly(ferrocenylsilane)/DNA modified glass carbon electrode[J].Electrochem.Commun.,2008,10(11):1712-1715.
[26]YANG G J,WANG C X,ZHANG R,WANG C Y,QU Q S,HU X Y.Poly(amidosulfonic acid) modified glassy carbon electrode for determination of isoniazid in pharmaceuticals[J].Bioelectrochemistry,2008,73(1):37-42.
[27]王炎英,牙禹,詹国庆,罗登柏,李春涯.色氨酸在聚茜素红膜修饰电极上的电化学行为[J].中南民族大学学报,2008,27(1):72-92.
[28]马艳蓉,高作宁.聚亚甲基蓝修饰金电极对过量抗坏血酸存在下尿酸的测定[J].分析测试学报,2008,27(2):139-142.
[29]林丽清,林新华,姚宏,陈敬华,李光文.聚伊文思蓝修饰电极对多巴胺和抗坏血酸的电分离及同时测定[J].2007,13(3):329-333.
[30]马伟,孙登明.聚L-苏氨酸修饰电极对多巴胺和肾上腺素的电催化氧化[J].物理化学学报,2007,23(3):332-336.
[31]张岩,吕鹏飞,李胜利.聚吖啶橙修饰电极上对苯二酚的电催化及分析应用[J].理化检验.化学分册,2006,42(9):726-728.
[32]郑莉.洛哌丁胺在碳纳米管碳糊电极上的伏安行为及其测定[J].分析测试学报,2009,28(1):93-95.
[33]KANNAN P,JOHN S A.Determination of nanomolar uric and ascorbic acids using enlarged gold nanoparticles modified electrode[J].Anal Biochem.,2009,386(1)65-72.
[34]HU H L,JIANG H,WANG X M,CHEN B A.Detection and distinguishability of leukemia cancer cells based on Au nanoparticles modified electrodes[J].Electrochem.Commun.,2008,10(8):1121-1124.
[35]王东田,魏杰,王芳,杨玉光,张忠林.用磷钼酸修饰甲醇燃料电池的铂电极[J].高校化学工程学报,2005,19(6):829-833.
[36]魏杰,许凯冬,王芳,杨玉光,张忠林.杂多酸修饰多晶铂电极的制备及其电催化性能的研究[J].材料科学与工艺,2006,14(6):666-966.
[37]张玲,郭文英,储海虹,屠一锋.纳米Pt-Au合金修饰电极对鲁米诺电化学发光的增敏研究[J].光谱学与光谱分析,2008,28(12):2785-2788.
[38]黄小清,李群芳,袁若.劳氏紫在DNA修饰的金电极上的电化学行为[J].西南师范大学学报,2008,33(5):59-63.
[39]时伟杰,艾仕云,李金焕,朱鲁生.基于树状高分子固定DNA的电化学生物传感器的研究[J].分析化学研究报告,2008,36(3):335-338.
[40]李业梅,戴月.血红素蛋白质.琼脂糖膜修饰电极的表征和电催化特性[J].分析试验室,2007,26(11):10-14.
[41]马建国,彭道锋,康文,包道龙.肾上腺素在聚氨基-β-环糊精修饰电极上的电化学行为[J].理化检验-化学分册,2007,43(1):1-7.
[42]IJIIMA S.Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58.
[43]HAMADA N,SAWADA S I,OSHIYAMA A.New one-dimensional conductors:Graphitic Microtubules[J].Phys.Rev.Lett.,1992,68(10):1579-1581.
[44]AJAYAN P M,EBBESEN T W.Nanometer-size tubes of carbon[J].Rep.Prog.Phys.,1997,60(10):1025-1062.
[45]顾军渭,张广成,王文志.碳纳米管的制备技术研究进展[J].纳米科技,2004,1(5):53-58.
[46]朱华.碳纳米管的制备方法研究进展[J].江苏陶瓷,2008,41(4):20-22.
[47]罗国安,王宗花,王义明.生物兼容性电极构置及应用[M].科学出版社,2006,p89.
[48]TSANG S C,CHEN Y K,HARRIS P J E,GREEN M L H.A simple chemical method of opening and filling carbon nanotunes[J].Narure,1994,372:159-162.
[49]LAGO R M,TSANG S C,LU K L,CHEN Y K,GREEN M L H.Filling carbon nanotubes with small palladium metal crystallites:the effect of surface acid groups[J].J.Chem.Soc.,Chem.Commun.,1995,13:1355-1356.
[50]肖奇,王平华,司知蠢.碳纳米管共价功能化[J].化学进展,2007,19(1):101-106.
[51]王宗花,赵凯,陈相康,李延辉.共价功能化碳纳米管的应用研究进展[J].化学研究,2009,20(1):104-108.
[52]毛蕾蕾,王宗花.碳纳米管的非共价功能化研究进展[J].现代化工,2006,26(2):29-32.
[53]孟令杰,伏传龙,路庆华.碳纳米管的功能化研究[J].自然科学进展,2009,19(2):148-157.
[54]WANG J,MUSAMEH M,LIN Y.Solubilization of Carbon Nanotubes by Nafion toward the Preparation of Amperometric Biosensors[J].J.Am.Chem.Soc.,2003,125(9):2408-2409.
[55]任春艳,蒋海燕,于曙光.Nafion修饰铂电极测定天然海水中一氧化氮[J].分析化学研究简报,2006,34(4):514-516.
[56]陈艳玲,郭锋,范畴,谭华.Nafion-1,10-二氮杂菲修饰玻碳电极及其在钌的伏安分析中的应用[J].理化检验.化学分册,2008,38(1):13-18.
[57]SHAHROKHIAN S,ZARE-MEHRJARDI H R.Application of thionine-nafion supported on multi-walled carbon nanotube for preparation of a modified electrode in simultaneous voltammetric detection of dopamine and ascorbic acid[J].Electrochim.Acta,2007,52(22):6310-6317.
[58]LIL,ZHANG Y M,DRILLET J F,DITTMEYER R,J(U|¨)TTNER K M.Preparation and characterization of Pt direct deposition on polypyrrole modified Nafion composite membranes for direct methanol fuel cell applications[J].Chem.Eng.J.,2007,133(1-3):113-119.
[59]LIN Z Y,CHEN J H,CHEN G N.An ECL biosensor for glucose based on carbon-nanotube/Nafion film modified glass carbon electrode[J].Electrochim.Acta,2008,53(5):2396-2401.
[60]BRITTON P J,SANTHANAM K S V,AJAYAN P M.Carbon nanotube eleetrode for oxidation of dopamine[J].Bioelectrochem.Bioenerg.,1996,41(1):121-125.
[61]LIU C Y,BARD A J,WUDL F,WEITZ I,HEATH J R.Electrochemical characterization of films of single-walled carbon nanotubes and their possible use as supercapacitors[J].Electrochem.Solid State Lett.,1999,2(11):577-578.
[62]KONG J,FRANKLIN N R,ZHOU C W,ET AL.Nanotube molecular wires as chemical sensors[J].Science,2000,287(5453):622-625.
[63]WANG J X,LI M X,SHI Z J,LI N Q,GU Z N.Electrocatalytic oxidation of 3,4-dihydroxyphenylacetic acid at a glassy carbon electrode modified with single-wall carbon nanotubes[J].Electrochim.Acta,2001,47:651-657.
[64]WANG J X,LI M X,SHI Z J,LI N Q,GU Z N.Investigation of the electrocatalytic behavior of single-wall carbon nanotube films on an Au electrode[J].Microchem.J.,2002,73:325-333.
[65]MUSAMEH M,WANG J,MERKOCI A,LIN Y H.Low-potential stable NADH detection at carbon nanotube modified glassy carbon electrodes[J].Electrochem.Commun.,2002,4(10):743-746.
[66]罗红霞,施祖进,李南强,顾镇南,庄乾坤.羧基化单层碳纳米管修饰电极的电化学表征及其电催化作用[J].高等学校化学学报,2000,21(9):1372-1374.
[67]WANG J X,LI M X,SHI Z J,LI NQ,GU Z N.Direct Electrochemistry of Cytochrome c at a Glassy Carbon Electrode Modified with Single-Wall Carbon Nanotubes[J].Anal.Chem.,2002,74:1993-1997.
[68]XU J Z,ZHU J J,WU Q,HU Z,CHEN H Y.An amperometric biosensor based on the coimmobilization of horseradish peroxidase and methylene blue on a carbon nanotubes modified electrode[J].Electroanalysis,2003,15(3):219-224.
[69]王宗花,刘军,颜流水.羧基化碳纳米管嵌入石墨修饰电极对多巴胺和抗坏血酸的电催化[J].分析化学,2002,30(9):1053-1057.
[70]AJAYAN P M,STEPHAN O,COLLIEX C,TRAUTH D.Aligned Carbon Nanotube Arrays Formed by Cutting a Polymer Resin-Nanotube Composite[J].Science,1994,265:1212-1214.
[71]丁中华,康天放,郝玉翠,张雁.碳纳米管/壳聚糖修饰电极的制备及其对NADH的电催化氧化[J].化学研究与应用,2008,20(4):74-77.
[72]李丽花,徐琴,王海燕,胡效亚.普鲁士蓝-多壁碳纳米管复合材料修饰电极测定过氧化氢[J].分析化学,2007,35(6):835-838
[73]WANG G,XU J J,CHEN H Y.Interfacing cytochrome c to electrodes with a DNA-carbon nanotube composite film[J].Electrochem.Commun.,2002,4(6):506-509.
[74]肖素芳,王宗花,罗国安,王义明.L-半胱氨酸在环糊精复合碳纳米管电极上的伏安测定[J].高等学校化学学报,2004,25(10):1833-1835.
[75]ZHANG M N,GONG K P,ZHANG H W,MAO L Q.Layer-by-layer assembled carbon nanotubes for selective determination of dopamine in the presence of ascorbic acid[J].Biosens.Bioelectron.,2005,20(7):1270-1276.
[76]ZENG J X,WEI W Z,WU L,LIU X Y,LIU K,LI Y.Fabrication of poly(toluidine blue O)/carbon nanotube composite nanowires and its stable low-potential detection of NADH[J].J.Electroanal.Chem.,2006,595(2):152-160.
[77]ZHU.Y H,ZHANG Z L,ZHAO W,PANG D W.Voltammetric behavior and determination ofphenylephrine at a glassy carbon electrode modified with multi-wall carbon nanotubes[J].Sens.Actuators B,2006,119(1):308-314.
[78]LI H H,ZHANG Z L,SHEN X C,ZHANG M X,PANG D W.Glassy carbon electrodes modified with DNA-partly-wrapped single-walled carbon nanotubes[J].Electrochem.Commun.,2007,9:2729-2733.
[79]ZHANG X H,WANG S M,JIA L,XU Z X,ZENG Y.An electrochemical sensor for determination of calcium dobesilate based on PoPD/MWNTs composite film modified glassy carbon electrode[J].J.Biochem.Biophys.Methods,2007,70(6):1203-1209.
[80]TSAI Y C,HUANG J D,CHIU C C.Amperometric ethanol biosensor based on poly (vinyl alcohol)-multiwalled carbon nanotube-alcohol dehydrogenase biocomposite[J].Biosen.Bioelectron.,2007,22:3051-3056.
[81]KANG S Z,CUI Z Y,MU J.Electrochemical behavior of sodium cholate and deoxycholate on an electrode modified with multi-walled carbon nanotubes(MWNTs)linked up with cyclodextrin[J].Diamond Relat.Mater.,2007,16:12-15.
[82]YOGESWARAN U,THIAGRAJAN S,CHEN S M.Nanocomposite of functionalized multiwall carbon nanotubes with nafion,nano platinum,and nano gold biosensing film for simultaneous determination of ascorbic acid,epinephrine,and uric acid[J].Anal Biochem.,2007,365(1):122-131.
[83]SUN D,XIE X F,CAI Y P,ZHANG J H,WU K B.Voltammetric determination of Cd~(2+)based bifunctionality of single-walled carbon nanotubes-Nafion film[J].Anal.Chim.Acta,2007,581(1):27-31.
[84]吴韶华,聂法慧,张玉明.核黄素在多壁碳纳米管修饰印刷电极上电化学行为及吸附溶出分析[J].福州大学学报,2008,36(6):888-892.
[85]李晓霞,申丽华,王姝,漆红兰.多壁碳纳米管修饰电极上阿替洛尔电化学行为的研究及其测定[J].分析实验室,2008,27(6):1-4.
[86]LUO L Q,ZOU X L,DING Y P,WU Q S.Derivative voltammetric direct simultaneous determination of nitrophenol isomers at a carbon nanotube modified electrode[J].Sens.Actuators B,2008,135(1):61-65.
[87]SIMS M J,LI Q,KACHOOSANGI R T,WILDGOOSE G G,COMPTON R G.Using multiwalled carbon nanotube modified electrodes for the adsorptive striping voltammetric determination of hesperidin[J].Electrochim.Acta,2009,54(22):5030-5034.
[88]CHOI A,JEONG H,KIM S,JO S,JEON S.Electrocatalytic reduction of dioxygen by cobalt porphyrin-modified glassy carbon electrode with single-walled carbon nanotubes and nafion in aqueous solutions[J].Electrochim.Acta,2008,53:2579-2584.
[89]GOYAL R N,GUPTA V K,CHATTERJEE S.Simultaneous determination of adenosine and inosine using single-wall carbon nanotubes modified pyrolytic graphite electrode[J].Talanta,2008,76(3):662-668.
[90]ZHANG Y Z,ZHANG K Y,MA H Y.Electrochemical DNA biosensor based on silver nanoparticles/poly(3-(3-pyridyl)3 acrylic acid)/carbon nanotubes modified electrode[J].Anal.Biochem.,2009,387(1):13-19.
[91]MENG L,WU P,CHEN G X,CAI C X,SUN Y M,YUAN Z H.Low potential detection of glutamate based on the electrocatalytic oxidation of NADH at thionine/single-walled carbon nanotubes composite modified electrode[J].Biosen.Bioelectron.,2009,24(6):1751-1756.
[92]RADOI A,COMPAGNONE D,VALCARCEL M A,PLACIDI P,MATERAZZI S,MOSCONE D,PALLESCHI G.Detection of NADH via electrocatalytic oxidation at single-wall carbon nanotubes modified with variamine blue[J].Electrochim.Acta,2008,53(5):2161-2169.
[93]SHOBHA JEYKUMARI D R,RAMAPRABHU S,SRIMAN NRAYANAN S.A.thionine functionalized multiwalled carbon nanotube modified electrode for the determination of hydrogen peroxide[J].Carbon,2007,45(6):1340-1353.
[94]DU P,LIU S N,WU P,CAI C X.Single-walled carbon nanobubes functionalized with poly(nile blue A)and their application to dehydrogenase-based biosensors[J].Electrochim.Acta,2007,53(4):1811-1823.
[95]徐红艳,吴华强,徐冬梅,王谦宜.碳纳米管负载纳米Ni修饰电极及碱液中电氧化甲醇[J].应用化学,2007,24(5):503-506.
[96]时巧翠,王素芬,侯海祥,孙戎.纳米碳管负载铂的修饰电极对H_2O_2的测定[J].分析试验室,2008,27(1):20-22.
[97]SAENGER W.Cyclodextrin inclusion compounds in research and industry[J].Angew.Chem.Int.Ed.Engl.,1980,19:344-362.
[98]刘育,尤长城,张衡益.超分子化学-合成受体的分子识别与组装[M].天津,南开大学出版社,2001,p170.
[99]SZEJTLI J.Introduction and general overview of cyclodextrin chemistry[J].Chem.Rev.,1998,98:1743-1753.
[100]SZEJTLI J.Downstream processing using cyclodextrins.TIBTRCH,1989,7:171-174.
[101]SZEJTLI J.Cyclodextrin Techoology,Kluwer,Dordrecht,1988,p12.
[102]GELB R I,SCHWARTZ L M,CARDELINO B,FUHRMAN H S,JOHNSON R F,LAUFER D A.Binding mechanisms in cyclohexaamylose complexes[J].J.Am. Chem.Soc.,1981,103(7):1750-1757.
[103]徐筱杰,陈丽蓉,化学及生物体系中的分子识别[J].化学进展,1996,8(3):189.
[104]AMATORE C,BURIEZ O,LABBIE E,VERPEAUX J N.Supramolecular effects of cyclodextrins on the electrochemical reduction and reactivity of aromatic carbonyl compounds[J].J.Electroanal.Chem.,2008,621(2):134-145.
[105]JADHAV G S,VAVIA P R.Physicochemical in silico and in vivo evaluation of a danazol-β-cyclodextrin complex[J].Int.J.Pharm.,2008,352(1-2):5-16.
[106]王海名,宋乐新,滕传峰,柏雷.紫外-可见光谱法研究β-环糊精对短链脂肪胺及其Cu(Ⅱ)、Ni(Ⅱ)配合物的包合行为[J].无机化学学报,2008,24(1):1-9.
[107]谢文磊,为河,冯光柱.紫外光谱法研究β-环糊精与卵磷脂的包结作用[J].光谱学与光谱分析,2001,21(5):707-709.
[108]LEON-RODRIGUEZ L M D,BASUIL-TOBIAS D A.Testing the possibility of using UV-vis spectrophotometric techniques to determine non-absorbing analytes by inclusion complex competition in cyclodextrins[J].Anal.Chim.Acta,2005,543(1-2):282-290.
[109]DIAS K,NIKOLAOU S,GIOVANI W F D.Synthesis and spectral investigateon of Al(Ⅲ)catechin/β-cyclodextrin and Al(Ⅲ)quercetin/β-cyclodextrin inclusion compounds[J].Spectrochim.Acta,Part A,2008,70(1):154-161.
[110]CAIRO P,ORTUSO F,ALCARO S,FONTANANOVA E,TOCCI E,DRIOLI E.β-Cyclodextrin interactions with three drugs used in inflammatory pathologies:An experimental and theoretical study[J].Chem.Phys.Lett.,2008,454(4-6):374-381.
[111]TEMERK Y M,IBRAHIM M S,KOTB M.Voltammetric and spectroscopic studies on binding of antitumor Morin,Morin-Cu complex and Morin-β-cyclodextrin with DNA[J].Spectrochim.Acta,Part A,2009,71(5):1830-1836.
[112]PASTOR I,MARINO A D,MENDICUTI E Complexes of dihexyl 2,6-naphthalenedi-carboxylate with α-and β-cyclodextrins:Fluorescence and molecular modeling[J].J.Photochem.Photobiol.A,2005,173(3):238-247.
[113]SERNA L,MARINO A D,MENDICUTI E Inclusion complexes of a bichromophoric diester containing anthracene and naphthalene groups with α-and β-cyclodextrins:thermodynamics and molecular mechanics[J].Spectrochim.Acta,PartA,2005,61(8):1945-1954.
[114]ABDEL-SHAFI A A,AL-SHIHRY S S.Fluorescence enhancement of 1-napthol-5-sulfonate by forming inclusion complex with β-cyclodextrin in aqueous solution[J].Spectrochim.Acta,Part A,2008,72(3):533-537.
[115]GORNAS P,NEUNERT G,BACZYNSKI K,POLEWSKI K.Beta-cyclodextrin complexes with chlorogenic and caffeic acids from coffee brew:Spectroscopic,thermodynamic and molecular modelling study[J].Food Chem.,2008,114(1):190-196.
[116]SHANMUGAM M,RAMESH D,NAGALAKSHMI V,KAVITHA R,RAJAMOHAN R,STALIN T.Host-guest interaction of I-tyrosine with β-cyclodextrin[J].Spectrochim.Acta,Part A 2008,71(1):125-132.
[117]MARCONI G,MONTI S,MANOLI F,ESPOSTI A D,MAYER B.A circular dichroism and structural study of the inclusion complex artemisinin-β-cyclodextrin[J].Chem.Phys.Lett.,2004,383(5-6):566-571.
[118]ABOU-ZIED O K.A spectroscopic study of the inclusion of azulene by β-and γ-cyclodextrins[J].Spectrochim.Acta,Part A,2005,62(1-3):245-251.
[119]ZIELENKIEWICZ W,MARCINOWICZ A,POZNANSKI J,CHERENOK S,KALCHENKO V.Complexation of isoleucine by phosphorylated calix[4]arene in methanol followed by calorimetry,NMR and UV-VIS spectroscopies,and molecular modeling methods[J].J.Mol.Liq.,2005,121(1):8-14.
[120]ALI S M,ASMAT F,MAHESHWARI A.NMR spectroscopy of inclusion complex of D-(-)-chloramphenicol with β-cyclodextrin in aqueous solution[J].IL Farmaco,2004,59(10):835-838.
[121]DANEL C,AZAROUAL N,BRUNEL A,LANNOY D,VERMEERSCH G,ODOU P,VACCHER C.Study of the complexation of risperidone and 9-hydroxyrisperidone with cyclodextrin hosts using affinity capillary electrophoresis and 1H NMR spectroscopy[J].J.Chromatogr.A,2008,1215(1-2):185-193.
[122]陈国华,夏之宁,郭宝元,廖凤霞,刘芬妮.氯苯那敏与β-环糊精相互作用的电化学表征[J].重庆大学学报,2003,26(6):109-115.
[123]LIU Y,PAN J H,WEI Y L,ZHANG Y.Electroanalytical method of TCPP and its supramolecular system with cyclodextrins[J].Talanta,2004,63(3):581-584.
[124] GU J, PAN J H. Determination of the cyclodextrin inclusion constant with the constant current coulometric titration method[J]. Talanta, 1999, 50(1): 35-39.
[125] OSELLA D, CARRETTA A, NERVI C, RAVERA M, GOBETTO R. Inclusion complexes of ferrocenes and β-cyclodextrin. Critical appraisal of the electrochemical evaluation of formation constants[J]. Organometallics, 2000, 19(14): 2791-2797.
[126] ALARCON-ANGELES G, PEREZ-LOPEZ B, PALOMAR-PARDAVE M, RAMIREZ-SILVA M T, ALEGRET S, MERKOCI A. Enhanced host-guest electrochemical recognition of dopamine using cyclodextrin in the presence of carbon nanotubes[J]. Carbon, 2008, 46(6): 898-906.
[127] LI Y Q, GUO Y J, LI X F, PAN J H. Electrochemical studies of determination of Basic Brown G and its interaction with cyclodextrins[J]. Dyes Pigments, 2007, 74(1): 67-72.
[128] OLEA-AZAR C, ABARCA B, NORAMBUENA E, OPAZO L, JULLIAN C, VALENCIA S, BALLESTEROS R, CHADLAOUI M. ESR, electrochemical and cyclodextrin-inclusion studies of triazolopyridyl pyridyl ketones and dipyridyl ketones derivatives [J]. Spectrochim Acta A Mol Biomol Spectrosc, 2008, 71(2): 703-709.
[129] QUAN Z, SONG Y, SAULSBERRY A, SHENG Y, LIU Y M. Capillary electrophoresis for diastereomers of (R/S)-tetrahydroisoquinoline-3-carboxylic acid derivatized with (R)-4-nitro-7-(3-aminopyrrolidin-1-yl)-2,1,3-benzoxadiazole: effect of molecular geometries[J]. J. Chromatogr. Sci., 2005, 43(3): 121-125.
[130] ELBASHIR A A, SULIMAN F E O, SAAD B, ABOUL-ENEIN H Y. Determination of aminoglutethimide enantiomers in pharmaceutical formulations by capillary electrophoresis using methylated-β-cyclodextrin as a chiral selector and computational calculation for their respective inclusion complexes[J]. Talanta, 2009, 77(4): 1388-1393.
[131] WANG E J, LIAN Z X, CAI J W. The crystal structure of the 1:1 inclusion complex of P-cyclodextrin with benzamide[J]. Carbohyd. Res., 2007,342(5): 767-771.
[132] DI TULLIO A, REALE S, DE ANGELIS F. Molecular recognition by mass spectrometry[J].J Mass Spectrom,2005,40(7):845-865.
[133]TONG L H,PANG Z Z,YI Y.Inclusion Complexes of α-and β-cyclodextrin with α-lipoic[J].J.Inclusion Phenom.Mol.Recognit.,1995,23:119-126.
[134]任维衡,罗冬冬,王凯,马庆苓.β-环糊精与柠檬醛及紫罗兰酮包和物的研究[J].湖北化工,1997,4:11-12.
[135]苏柘僮,杨明,吴品江,许润春,高亚男,欧水平.胆酸-羟丙基-β-环糊精包合物的制备王艺及相溶解度研究[J].中成药,2009,31(3):380-382.
[136]ARAUJO M V G D,VIEIRA E K B,LAZARO G S,CONEGERO L D S,FERREIRA O P,ALMEIDA L E,BARRETO L S,COSTA N B,GIMENEZ I F.Inclusion complexes of pyrimethamine in 2-hydroxypropyl-b-cyclodextrin:Characterization,phase solubility and molecular modeling[J].Bioorgan.Med.Chem.,2007,15(17):5752-5759.
[137]IKEDA H,MURAYAMA T,UENO A.Skeleton-selective fluorescent chemosensor based on cyclodextrin bearing a 4-amino-7-nitrobenz-2-oxa-1,3-diazole moiety[J].Org.Biomol.Chem.,2005,3:4262-4267.
[138]AOYAGI T,NAKAMURA A,IKEDA H,IKEDA T,MIHARA H,UENO A.Alizarin Yellow-modified β-Cyclodextrin as a Guest-Responsive Absorption Change Sensor[J].Anal Chem.,1997,69:659-663.
[139]UENO A,IKEDA A,IKEDA H,IKEDA T,TODA F.Fluorescent cyclodextrins responsive to molecules and metal ions.Fluorescence properties and inclusion phenomena of N~α-Dansyl-L-lysine-β-cyclodextrin and monensin-incorporated N~α-Dansyl-L-lysine-β-cyclodextrin[J].J Org.Chem.,1999,64:382-387.
[140]邱文革,李宗锋,孟胜男.环糊精与卟啉键合的新型超分子[J].化学世界,2007,2:114-117.
[141]张华承,郝爱友,申健.环糊精-杯芳烃偶合体系研究进展及前景展望[J].有机化学,2008,28(6):954-963.
[142]RONG D,D'SOUZA V T.A convenient method for functionalization of the 2-position of cyclodextrins[J].Tetrahedron Lett.,1990,31(30):4275-4278.
[143]尤长城,刘育.超分子体系中的分子识别研究[J].高等学校化学学报,2000,21(2):249-251.
[144]申刚义,杨新玲,凌云.新型超分子化合物桥联β-环糊精合成研究进展[J].化 学通报,2003,4:235-240.
[145]LIU Y,YOU C C,CHEN Y,WADA T,INOUE Y.Molecular Recognition Studies on Supramolecular Systems.25.Inclusion Complexation by OrganoseleniumBridged Bis(β-cyclodextrin)s and Their Platinum(Ⅳ)Complexes[J].J.Org.Chem.,1999,64(21):7781-7787.
[146]陈湧,迟恒,刘育.均苯三酰胺桥联三环糊精/Zn~(2+)金刚烷衍生物三元超分子体系的合成及其羧肽酶A模拟研究[J].化学学报,2008,66(1):91-96.
[147]SZEJTLI J,Cyclodextrin Technology[M].Kluwer Dordrecht,1988,p314.
[148]谭静,姜子涛.环糊精及其衍生物在食品领域中的应用[J].食品研究与开发,2008,29(11):178-181.
[149]王水兴,郭勇,许杨.大环糊精及其在食品工业应用前瞻[J].食品与机械,2006,22(2):113-116.
[150]童林荟.环糊精化学-基础与应用[M].北京,科学出版社.2001:p360-376.
[151]刘鄂湖,蔡光明,夏新华,熊晗辉,朱海升.羟丙基-β-环糊精增溶难溶性药物研究进展[J].药学专论,2007,16(8):25-27.
[152]张桂枝,肖曙光,靳双星.环糊精包合物在药物制剂中的应用[J].郑州牧业工程高等专科学校学报,2007,27(2):29-46.
[153]吕正检,王建华,徐世荣.环糊精及其衍生物在口服给药制剂中的应用[J].医药导报,2006,25(8):806-807.
[154]LIU F,LIANG H L,XU K H,TONG L L,TANG B.Supramolecular interaction of ethylenediamine linked β-cyclodextrin dimer and berberine hydrochloride by spectrofluorimetry and its analytical application[J].Talanta,2007,74(1):140-145.
[155]ANSELMI C,CENTINI M,MAGGIORE M,GAGGELLI N,ANDREASSI M,BUONOCORE A,BERETTA G,FACINO R M.Non-covalent inclusion of ferulic acid with α-cyclodextrin improves photo-stability and delivery:NMR and modeling studies[J].J.Pharmaceut.Biomed.,2008,46(4):645-652.
[156]RAJABI O,TAYYARI F,SALARI R,TAYYARI S F.Study of interaction of spironolactone with hydroxypropyl-β-cyclodextrin in aqueous solution and in solid state[J].J.Mol.Struct.,2008,878(1-3):78-83.
[157]LI S.Cyclodextrins and their applications in analytical chemistry[J].Chem.Rev.,1992,92:1457-1470.
[158]SCHLATTER A,KUNDA M K,WOGGON W D.Enantioselective reduction of aromatic and aliphatic ketones catalyzed by ruthenium complexes attached to beta-cyclodextrin[J].Angew.Chem.Int.Ed,2004,43(48):6731-6734.
[159]SZEMAN J,GANZLER K,SALGOA,SZEJTLI J.Effect of the degree of substitution of cyclodextrin derivatives on chiral separations by high-performance liquid chromatography and capillary electrophoresis[J].J.Chromatogr.A,1996,728(1-2):423-431.
[160]KRZEK J,STAREK M,JELONKIEWICZ D.RP-TLC Determination of S(+)and R(-)Ibuprofen in drugs with the application of chiral mobile phase and UV densitometric detection[J].Chromatographia,2005,62(11-12):653-657.
[161]BLYSHAK L A,ROSSI T M,PATONAY G,WARNER I M.Cyclodextrin-modified solvent extraction for polynuclear aromatic hydrocarbons[J].Anal Chem.,1988,60(19):2127-2131.
[162]李海丰,王光辉,于荣,邓南圣.环糊精在环境治理中的应用研究进展[J].环境污染与防治,2007,29(11):844-847.
[163]张慧容,彭浩,贺红武.环糊精在农药中的研究及其应用[J].农药,2008,47(8):406-411.
[164]PACIONI N L,VEGLIA A V.Determination of poorly fluorescent carbamate pesticides in water,bendiocarb and promecarb,using cyclodextrin nanocavities and related media[J].Anal.Chim.Acta,2007,583(1):63-71.
[165]陈丽,王潮霞.环糊精改性聚酰胺纤维的机械和物理化学性能[J].国外丝绸,2008.3:9-14.
[166]陈丽,王潮霞.环糊精在纺织品加工中的应用[J].印染助剂,2009,26(3):6-9.
[167]环糊精衍生物在化妆品中的应用[J].科技开发动态,2004,8:58-59.
[168]BOCHOT A,TRICHARD L,LE BAS G,ALPHANDARY H,GROSSIORD J L,DUCHENE D,FATTAL E.α-Cyclodextrin/oil beads:An innovative selfassembling system[J].Int.J.Pharm.,2007,339(1-2):121-129.
[169]何海兰.染料,精细化工产品手册[M].化学工业出版社.2004.
[170]郑庆东,姚祖光.多烯和花菁染料分子设计及其非线性光学性质研究进展[J].化学研究,2000,11(1):55-64.
[171]周诗娟,樊增禄.还原染料的电化学还原及其染色[J].河北纺织,2008,2: 61-67.
[172]CHEN J G,CHEN C Y,WU S J,LI J Y,WU C G,HO K C.On the photophysical and electrochemical studies of dye-sensitized solar cells with the new dye CYC-B1[J].Sol.Energy Mater.Sol.Cells,2008,92(12):1723-1727.
[173]KIM J J,CHOI H,LEE J W,KANG M S,SONG K,KANG S O,KO J.A polymer gel electrolyte to achieve≥6%power conversion efficiency with a novel organic dye incorporating a low-band-gap chromophore[J].J.Mater.Chem.,2008,18:5223-5229.
[174]WANG Z S,CUI Y,DAN-OH Y,KASADA C,SHINPO A,HARA K.Molecular Design of Coumarin Dyes for Stable and Efficient Organic Dye-Sensitized Solar Cells[J].J.Phys.Chem.,2008,112(43):17011-17017.
[175]傅妮娜,王红,张华山.近红外荧光探针及其在生物分析中的应用进展[J].分析科学学报,2008,24(2):233-239.
[176]WOLLERT H G,MULLEJANS B,BEHOLZ S,ECKEL L.Intraoperative visualization of coronary artery fistula using medical dye[J].Thorac Cardiov.Surg.,1997,45(6):287-294.
[177]赵红莉,袁慧慧,蓝闽波.菁染料在荧光探针及光动力疗法中的应用[J].感光科学与光化学,2003,21(3):212-222.
[178]LIU Y,LI B,YOU C C,WADA T,INOUE Y.Molecular Recognition Studies on Supramolecular Systems.Molecular Recognition of Dyes by Organoselenium -Bridged Bis(β-cyclodextrin)s[J].J.Org.Chem.,2001,66(1):225-232.
[179]LIU Y,HAN B H,CHEN Y T.Molecular recognition and complexation thermodnamics of dye guest molecules by modified cyclodextrins and calixarnesulfonates[J].J.Phys.Chem.B,2002,1116(18):4678-4687.
[180]LIU Y,LI L,ZHANG H Y,LIANG P,WANG H.Inclusion complexation behavior of dyestuff guest molecules by a bridged bis(cyclomaltoheptaose)[bis (β-cyclodex-trin)]with a pyromellitic acid diamide tether[J].Carbohyd.Res.,2003,338(17):1751-1757.
[181]LIU Y,LI X Q,CHEN Y,GUAN X D.Spectrophotometric Study of Selective Binding Behaviors of Dye Molecules by Pyridineand Bipyridine-Modified α-Cyclodextrin Derivatives with a Functional Tether in Aqueous Solution[J].J. Phys.Chem.B,2004,108(50):19541-19549.
[182]LIU Y,LI C J,GUO D S,PAN Z H,LI Z.A comparative study of complexation of beta-cyclodextrin,calix[4]arenesulfonate and cucurbit[7]uril with dye guests:Fluorescence behavior and binding ability[J].Supramol.Chem.,2007,19(7):517-523.
[183]ZHANG G M,SHUANG S M,DONG C,PAN J H.Study on the interaction of methylene blue with cyclodextrin derivatives by absorption and fluorescence spectroscopy[J].Spectrochim.Acta,Part A,2003,59(13):2935-2941.
[184]王茹林,张国梅,杨郁,双少敏,潘景浩.亚甲蓝与中性及电荷型β-环糊精的包和特性[J].分析化学,2003,31(2):205-207.
[185]杨华,赵曙辉,李兰,侯书雅.紫外.可见光谱法研究β-环糊精与分散染料的包合作用[J].染料与染色,2006,43(2):40-43.
[186]ZHU X S,SUN J,WU J.Study on the inclusion interactions of β-cyclodextrin and itS derivative with dyes by spectrofluorimetry and its analytical application[J].Talanta,2007,72(1):237-242.
[187]赵焱,杨自明,朱洪友,顾娟,王宇飞.一种新型芳香二胺桥联β-环糊精对染料的分子识别[J].物理化学学报,2007,23(3):394-398.
[188]ZHANG Q F,JIANG Z T,GUO Y X,LI R.Complexation study of brilliant cresyl blue with β-cyclodextrin and its derivatives by UV-vis and fluorospectrometry[J].Spectrochim.Acta,Part A,2008,69(1):65-70.
[189]田威,范晓东,刘涛,刘郁杨,孙乐,姜敏,黄怡.壳层悬挂β-环糊精单元的两亲性超支化聚合物的分子包合与识别行为[J].高等学校化学学报,2009,30(3):632-637.
[190]ZHANG H R,CHEN G,WANG L,DING L,TIAN Y,J1N W Q,ZHANG H Q.Study on the inclusion complexes of cyclodextrin and sulphonated azo dyes by electrospray ionization mass spectrometry[J].Int.J.Mass Spectrom.,2006,252(1):1-10.
[191]郭玉晶,潘景浩,郭春花,郑红莲.甲基绿的电化学行为及其与环糊精形成超分子体系的研究[J].电化学,2003,9(3):363-367.
[192]郭玉晶,潘景浩,王慧.线性扫描伏安法研究茜素红及茜素红-环糊精超分子体系[J].分析化学,2003,31(12):1533.
[193]郭玉晶,潘景浩.邻氯酚红的电化学行为及其与环糊精超分子体系的研究[J].分析科学学报,2004,20(1):32-34.
[194]GUO Y J,PAN J H,JING W J.Determination of Orange Ⅱand the supramolecular system of Orange Ⅱwith cyclodextrins by polarography[J].Dyes Pigments,2004,63(1):65-70.
[195]芦飞,潘景浩,王英特,郭玉晶.酸性深蓝5R的极谱分析方法及其与环糊精超分子体系的研究[J].电化学,2005,11(1):105-109.
[196]GUO Y J,PAN J H,LI X M,LU F.Elecroanalytical method of Acid red 1 and its supramolecular system with cyclodextrins[J].Dyes Pigments,2006,70(1):27-30.
[197]LI Y Q,GUO Y J,PAN J H.Electrochemical study on determination reactive red 15and its interaction with cyclodextrins[J].J.Incl.Phenom.Macro.,2006,56(1-2):237-241.
[198]RAJ C R,RAMARAJ R.Electrochemistry and photoelectrochemistry of phenothiazine dye-β-CD inclusion complexes[J].J.Electroanal.Chem.,1996,405(1-2):141-147.
[199]邱红娟,龚蕴玉,徐敏,李淑华,王慧珍.β-环糊精对阳离子染料染色性能的影响[J].丝绸,2001,10:26-27.
[200]邱红娟,许敏,龚蕴玉,王惠珍.环糊精的性质及在染整加工上的应用[J].四川丝绸,2001,4:26-30.
[201]刘守奎,董振礼,候继强.β-环糊精对分散染料上染聚酯超细纤维染色性能的影响[J].印染助剂,2004,21(3):32-34.
[202]黄建洪,傅科杰.浅谈超分子染色助剂研究[J].上海丝绸,2004,2:21-24.
[203]邱红娟.β-环糊精的匀染作用研究[J].印染,2008,4:13-16.
[204]BUSCHMANN H J等著,何中琴译.环糊精在纺织品加工上的应用汇[J].丝绸技术,1999,7(3):45-48.
[205]王俊华,王峰,蔡再生.改性β-环糊精的应用研究[J].毛纺科技,2008,3:23-26.
[206]王兰英,黄怡,张小刚,徐玲,张祖训.β-环糊精对菁染料光稳定性的影响[J].应用化学,2003,20(3):215-218.
[207]SAVARINO P,VISCARDI G,QUAGLIOTTO P,MONTONERI E,BARNI E.Reactivity and effects of cyclodextrins in textile dyeing[J].Dyes Pigments,1999,42(2):143-147.
[208]SAVARINO P,PICCININI P,MONTONERI E,VISCARDI G,QUAGLIOTTO P,BARNI E.Effects of additives on the dyeing of nylon-6 with dyes containing hydrophobic and hydrophilic moieties[J].Dyes Pigments,2000,47(1-2):177-188.
[209]SAVARINO P,PARLARTI S,BUSCAINO R,PICCININI P,BAROLO C,MONTONERI E.Effects of additives on the dyeing of polyamide fibres.Part Ⅱ:Methyl-β-cyclodextrin[J].Dyes Pigments,2006,69(1-2):7-12.
[210]史丽颖,龙家杰,陆同庆.β-环糊精对阳离子染料的移染作用研究[J].毛纺科技,2004.5:17-20.
[211]CRINI G.Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment[J].Prog.Polym.Sci.,2005,30(1):38-70.
[212]CR1NI G,PEINDY H N,GIMBERT F,ROBERT C.Removal of C.I.Basic Green 4(Malachite Green)from aqueous solutions by adsorption using cyclodextrin-based adsorbent:Kinetic and equilibrium studies[J].Sep.Purif.Technol.,2007,53(1):97-110.
[213]OZMEN E Y,SEZGIN M,YILMAZ A,YILMAZ M.Synthesis of β-cyclodextrin and starch based polymers for sorption of azo dyes from aqueous solutions[J].Bioresour.Technol.,2008,99(3):526-531.
[1]何海兰.染料[M].北京:化学工业出版社,2004:p408.
[2]古俊,常雁,潘景浩.环糊精的实际应用进展[J]应用化学,1996,13(4):5.
[3]龙家杰,王惠珍.弱酸深蓝5R染料的β-CD包和作用研究[J].印染,2002,28(7):4-6
[4]潘云芳.β-环糊精在涤棉织物分散/活性染料一浴一步法中的应用[J].印染助剂,2004,21(5):42-48.
[5]王潮霞,陈水林.β-环糊精对双活性基染料染色性能的影响[J].2005,22:1-4.
[6]李有琴,潘景浩,郭玉晶,芦飞,张红芬.活性艳红K-2G与环糊精相互作用的极谱伏安法研究[J].分析实验室,2006,25(1):9-12.
[7]李有琴,郭玉晶,潘景浩.活性艳红K-2BP与环糊精相互作用的电化学研究[J].分析科学学报,2006,22(4):421-424.
[8]BARD A J,FAULKNER L R.Electrochemical methods-Fundamentals and applications[M],Wiley,New York,1980,p.222.
[9]童林荟,申宝剑.超分子化学研究中的物理方法[M].科学出版社,2004:p287.
[10]李南强,高小霞.钒极谱催化波的研究I-钒-磷酸盐体系中过氧化氢极谱催化波的研究.分析化学[J],1973,1(4):40.
[11]刘育,尤长城,张衡益.超分子化学[M],南开大学出版社,2001:p193.
[1]项生昌.环糊精在电化学中的应用[J].大学化学,2000,15(6):30-34.
[2]谭静,姜子涛.环糊精及其衍生物在食品领域中的应用[J].食品研究与开发,2008,29(11):178-181.
[3]孙宏元,郝爱友,尹明静,张华承,申健.环糊精在绿色有机合成中的应用[J].化学进展,2008,20(11):1694-1698.
[4]路平,邓南圣.β-环糊精在二氧化钛对偶氮染料光催化脱色中的应用[J].水处理技术,2005,31(1):35-37.
[5]黄怡,范晓东.环糊精在药物控制释放系统中的应用研究进展[J].化学研究与进展,2005,17:715-719.
[6]张国梅,双少敏,钞建宾,潘景浩.环糊精超分子化学在生命科学研究中的新进展[J].分析科学学报,2005,21(2):200-204.
[7]DAVIS M E,BELLOQ N C.Cyclodextrin containing polymers for gene delivery[J].J.Incl.Phenom.Macro.,2002,44:17-22.
[8]MARTIN DEL VALLE E M.Cyclodextrins and theirs uses:a review[J].Process Biochem.,2004,39:1033-1046.
[9]龙家杰,王惠珍.弱酸深蓝5R染料的β-CD包和作用研究[J].印染,2002,28(7):4-6
[10]王蕾,殷亚辉.环糊精整理织物的技术开发[J].印染,2004,8:47-49.
[11]CRINI G,PEINDY H N,GIMBERT F,ROBERT C.Removal of C.I.Basic Green 4(Malachite Green)from aqueous solutions by adsorption using cyclodextrin-based adsorbent:Kinetic and equilibrium studies[J].Sep.Purif.TechnoL,2007,53(1):97-110.
[12]CRINI G.Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment[J].Prog.Polym.Sci.,2005,30(1):38-70.
[13]TETSUO K,MAKOTO T,AKIKO M.Phenolphthalein-Modified beta-Cyclodextrin as a Molecule-Responsive Colorless-to-Color Change Indicator[J].J.Org.Chem.,1998,63(24):8729-8735.
[14]季维,费学宁,杨少斌.作为生物探针的噻唑橙类化合物的合成及光谱性质研究[J].天津理工大学学报,2007,23(3):8-12.
[15]高峰,章丽,卞桂荣,王伦.光谱法研究灿烂甲酚蓝与DNA的相互作用[J].光谱学与光谱分析,2005,25(11):1843-1845.
[16]韩吉林,陈洪渊,高鸿.生物分子电催化研究(I)-电子传递媒介体甲酚固紫电化学行为的研究[J].化学学报,1993,51:568-574.
[17]韩吉林,陈洪渊,高鸿.生物分子电催化研究(Ⅱ)-血红蛋白在甲酚固紫修饰石墨电极上的电催化[J].化学学报,1993,51:683-689.
[18]韩吉林,经卫,高鸿.生物分子电催化研究(Ⅲ)--血红蛋白在甲酚固紫修饰碳糊电极上的电催化[J].化学学报,1993,14:332-333.
[19]ZHANG Q F,JIANG Z T,GUO Y X,LI R.Complexation study of brilliant cresyl blue with β-cyclodextrin and its derivatives by UV-vis and fluorospectrometry[J].Spectrochimica Acta Part A,2008,69:65-70.
[20]WANG J X,LI M X,SHI Z J,LI N Q,GU Z N.Direct electrochemistry of cytochrome c at a glassy carbon electrode modified with single-wall carbon nanotubes[J].Anal.Chem.,2002,74:1993-1997.
[21]SHOBHA JEYKUMARI D R,RAMAPRABHU S,SRIMAN NRAYANAN S.A thionine functionalized multiwalled carbon nanotube modified electrode for the determination of hydrogen peroxide[J].Carbon,2007,45:1340-1353.
[22]董绍俊,车广礼,谢远武.化学修饰电极(修订版)[M].北京,科学出版社.2003,p319.
[23]TSANG S C,CHEN Y K,HARRIS P J F,GREEN M L H.A simple chemical method of opening and filling carbon nanotubes[J].Nature,1994,372:159-162.
[24]BARD A J,FAULKNER L R.Electrochemical methods-Fundamentals and applications[M],Wiley,New York,1980,p.222.
[25]ANTONOV L,GERGOV G,PETROV V,KUBISTA M,NYGREN J.UV-Vis spectroscopic and chemometric study on the aggregation of ionic dyes in water[J].Talanta,1999,49:99-106.
[26]童林荟,申宝剑.超分子化学研究中的物理方法[M].科学出版社,2004:P287.
[27]李南强,高小霞.钒极谱催化波的研究I.钒-磷酸盐体系中过氧化氢极谱催化波的研究[J].分析化,1971,1(4):40-48.
[28]李南强,高小霞.钒极谱催化波的研究Ⅱ.钒在苦杏仁酸底液中氯酸盐极谱催化波的研究[J].分析化,1974,2(6):459-461.
[29]刘育,尤长城,张衡益.超分子化学[M].天津:南开大学出版社.2001,p193.
[1]世界染料品种[M],2000,p575.
[2]古俊,常雁,潘景浩.环糊精的实际应用进展[J].应用化学,1996,13(4):5.
[3]王春梅.环糊精在染整加工中的应用[J].丝绸,2005,12:35-37.
[4]龙家杰.β-环糊精在阳离子染料染色中的应用研究[J].印染助剂,2003,20(1):31-35.
[5]龙家杰,王惠珍,陈霞.β-环糊精对阳离子染料的包合作用[J].纺织学报,2002,23(4):33-35.
[6]邱红娟.β-环糊精与阳离子黄X-6G包合的光谱分析[J].印染助剂,2003,20(3):51-22.
[7]邱红娟,伍天荣.解析β-环糊精与阳离子蓝X-GRRL的包合[J].南通纺织职业技术学院学报,2002,2(4):1-3.
[8]王中慧,潘景浩,用电化学分析法研究碱性染料与β-环糊精的包结作用[J].分析化学研究报告,2004,32(7):889-892.
[9]BARD A J,FAULKNER L R.Electrochemical Methods Fundamentals and Applications[M],New York:John Wiley and Sons;1980,p223.
[10]丁世家,张祖训。线性变位极谱法研究(XV)--铜(Ⅱ)-L-肾上腺素配位吸附波[J].高等学校化学学报,1991,12(5):598-601.
[11]ANSON F C.Application of Potentiostatic Current Integration to the Study of the Adsorption of Cobalt(Ⅲ)-(Ethylenedinitrilo(tetraacetate) on Mercury Electrodes[J].Anal.Chem.,1964,36:932-934.
[12]LAVIRON E.General expression of the linear potential sweep voltammogram in the case of diffusionless electrochemical systems[J].J.Electroanal.Chem.,1979,101:19-28.
[13]李南强,高小霞.钒极谱催化波的研究I.钒-磷酸盐体系中过氧化氢极谱催化波的研究[J].分析化学,1971,1(4):40-48.
[14]李南强,高小霞.钒极谱催化波的研究Ⅱ.钒在苦杏仁酸底液中氯酸盐极谱催化波的研究[J].分析化学,1974,2(6):459-461.
[15]ZHANG G M,SHUANG S M,DONG C,PAN J H.Study on the interaction of methylene blue with cyclodextrin derivatives by absorption and fluorescence spectroscopy[J].Spectrochimica Acta PartA,2003,59:2935-2941.
[1]何海兰.染料[M].北京,化学工业出版社,2004,p170.
[2]徐伟亮,王晓东.蓝色盐VB和快磺素的可见-紫外定量测定法[J].理化检验-化学分册,2000,36(10):462-463.
[3]王兰英,黄怡,张小刚,徐玲,张祖训.β-环糊精对菁染料光稳定性的影响[J].应用化学,2003,20(3):215-218.
[4]邱红娟,龚蕴玉,许敏,李淑华,王惠珍.β-环糊精对阳离子染料染色性能的影响[J].丝绸,2001,10:26-27.
[5]邱红娟.β-环糊精的匀染作用研究[J].印染,2008,4:13-16.
[6]WANG J,LIU G D,JAN M R.Ultrasensitive Electrical Biosensing of Proteins and DNA:Carbon-Nanotube Derived Amplification of the Recognition and Transduction Events[J].J.Am.Chem.Soc(Communication),2004,126:3010-3011.
[7]BARD A J,FAULKNER L R.Electrochemical methods-Fundamentals and applications[M],Wiley,New York,1980,p222.
[8]LAFORGUE A,ADDOU T,BELANGER D.Characterization of the deposition of organic molecules at the surface of gold by the electrochemical reduction of aryldiazonium cations[J].Langmuir,2005,21:6855-6865.
[9]童林荟,申宝剑.超分子化学研究中的物理方法[M].科学出版社,2004:p287.
[10]ANSON F C.Application of Potentiostatic Current Integration to the Study of the Adsorption of Cobalt(Ⅲ)-(Ethylenedinitfilo(tetraacetate) on Mercury Electrodes[J].Anal Chem.,1964;36:932-934.
[11]李南强,高小霞.钒极谱催化波的研究I.钒-磷酸盐体系中过氧化氢极谱催化波的研究[J].分析化学,1971,1(4):40-48.
[12]李南强,高小霞.钒极谱催化波的研究Ⅱ.钒在苦杏仁酸底液中氯酸盐极谱催化波的研究[J].分析化学,1974,2(6):459-461.
[13]刘育,尤长城,张衡益.超分子化学[M].天津:南开大学出版社.2001,p194.