钴基合金用高效缓蚀清洗剂及其性能研究
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摘要
水基金属清洗剂主要是由表面活性剂和缓蚀剂组成，表面活性剂是具有非离子、阴离子或两性离子的表面活性物质，是由憎水基和亲水基两部分组成的化合物。采用表面活性剂复配技术开发的水基清洗剂适用范围广、去污能力强，适用于机械化自动清洗，可广泛用于金属加工业。
国内外对钴基合金清洗剂的钴析出问题研究较少，本文通过筛选出适用的表面活性剂进行复配，制备出新型的弱碱性、中性高效缓蚀清洗剂，能较好地抑制钴基合金中钴离子析出。研制的清洗剂不仅要求清洗效率很高，而且能抑制钴基合金中钴的析出。首先采用正交试验方法拟定配方，充分利用溶液的溶解力、溶质的pH值和表面活性剂的特性，同时加入功能性助剂，使清洗剂具有去污作用以外的多种功能，以增强和加大清洗剂的清洗能力，通过比较在不同清洗剂配方清洗后试样的清洗效率（CEF）及表面腐蚀形貌，确定了清洗剂的基本组成与清洗工艺。其次在配方中加入金属缓蚀剂，缓蚀试验筛选出清洗、缓蚀效果良好的复合缓蚀剂，通过改变其用量，筛选出添加最佳用量复合缓蚀剂后的清洗剂，能明显抑制试样中钴离子析出。最后采用柠檬酸-柠檬酸钠缓冲溶液调节清洗剂的pH值，最终确定清洗剂配方。
清洗试验中弱碱性和中性清洗剂对人工油污的CEF可达99.93%、99.74%，能彻底地清除金属表面的油污，达到ASTM G121-98与QB/T2117-95要求。缓蚀清洗剂缓蚀评价试验结果均表明，研制的两种清洗剂能减少钴基合金的腐蚀面积，明显抑制合金中Co~(2+)析出，缓蚀效果优良。通过对比研制的弱碱性、中性清洗剂与进口、国产清洗剂对钴基合金的清洗、浸泡、盐雾、电化学、SEM和能谱试验，表明研制的清洗剂的缓蚀效果更好，能更好抑制钴基合金中Co~(2+)析出，解决了清洗剂的钴析出问题。因此，本文研制的清洗剂使用方便，安全环保，符合新型高性能清洗剂的发展方向。
Water-based metal cleaning agents are mainly composed of surface active agent andcorrosion inhibitor. The surface active agents have nonionic, anionic and amphoteric ionsurfactant, which are composed of two compounds of the hydrophobic and hydrophilicgroups. The water-based cleaning agents use the complex surfactant technology todevelop widely applicable range and decontamination capability. They are suitable formechanized automatic cleaning that can be widely used in metal processing industry.
The research of cleaning agents about domestic and foreign literature oncobalt-base alloy precipitation problem is few. Through the screening out of suitablesurfactant, this article has prepared a new type of alkaline and neutral efficient cleaningagent, which can effectively inhibit cobalt ion precipitation of cobalt-base alloy. Thecleaning agent requires not only the high cleaning efficiency but also can better inhibitthe cobalt precipitation of cobalt-base alloy, so the formulation is also required to jointhe metal corrosion inhibitor. Firstly, this article use the orthogonal test method to drawup the formula, make full use of the solubility of the solution, the solute pH value andthe characteristics of surfactant additives. At the same time, it can have a variety offunctions of the cleaning agent beside the decontamination effect in order to enhanceand increase the cleaning ability, through the comparison’s CEF and surface corrosionmorphology of different cleaning formulations after cleaning. So it determines thecleaning agent composition and cleaning technology. Secondly in the corrosion inhibitorscreening test for good cleaning and corrosion inhibition effect of compound corrosioninhibitor, it can filter out to add optimum dosage of compound corrosion inhibitor intothe cleaning agent by changing the dosage, which can obviously inhibit the precipitationof cobalt ion on the surface of the sample. Finally using citric acid and sodium citratebuffer solution to regulate the cleaning agent of the pH value so that to ultimatelydetermine the cleaning formulations.
The washing test of weak alkaline and neutral cleaning agent on artificial oil CEFis up to99.93%and99.74%, they can thoroughly remove greasy dirt from the metalsurface, which have achieved the ASTM G121-98and QB/T2117-95requirements. Thetest’s results of the cleaning agent corrosion evaluation show that the two kinds ofcleaning agent can not only reduce the corrosion area of cobalt base alloy, but alsoinhibit the precipitation of Co~(2+), so their corrosion effect are very well. Through thecontrast of the cleaning, immersion, salt spray, electrochemistry, SEM and energyspectrum test of the weakly alkaline, neutral, import and domestic cleaning agent on cobalt-based alloy. It has also showed that the developed cleaning agent’s corrosioneffect is better. They can better inhibit Co~(2+)emission of cobalt base alloy, which solvethe cleaning agent cobalt precipitation problem. Therefore, this paper has developed twokinds of cleaning agent that the use is convenient, safe and environmental, whichconforms to the development direction of the new high performance cleaning agents.
国内外对钴基合金清洗剂的钴析出问题研究较少，本文通过筛选出适用的表面活性剂进行复配，制备出新型的弱碱性、中性高效缓蚀清洗剂，能较好地抑制钴基合金中钴离子析出。研制的清洗剂不仅要求清洗效率很高，而且能抑制钴基合金中钴的析出。首先采用正交试验方法拟定配方，充分利用溶液的溶解力、溶质的pH值和表面活性剂的特性，同时加入功能性助剂，使清洗剂具有去污作用以外的多种功能，以增强和加大清洗剂的清洗能力，通过比较在不同清洗剂配方清洗后试样的清洗效率（CEF）及表面腐蚀形貌，确定了清洗剂的基本组成与清洗工艺。其次在配方中加入金属缓蚀剂，缓蚀试验筛选出清洗、缓蚀效果良好的复合缓蚀剂，通过改变其用量，筛选出添加最佳用量复合缓蚀剂后的清洗剂，能明显抑制试样中钴离子析出。最后采用柠檬酸-柠檬酸钠缓冲溶液调节清洗剂的pH值，最终确定清洗剂配方。
清洗试验中弱碱性和中性清洗剂对人工油污的CEF可达99.93%、99.74%，能彻底地清除金属表面的油污，达到ASTM G121-98与QB/T2117-95要求。缓蚀清洗剂缓蚀评价试验结果均表明，研制的两种清洗剂能减少钴基合金的腐蚀面积，明显抑制合金中Co~(2+)析出，缓蚀效果优良。通过对比研制的弱碱性、中性清洗剂与进口、国产清洗剂对钴基合金的清洗、浸泡、盐雾、电化学、SEM和能谱试验，表明研制的清洗剂的缓蚀效果更好，能更好抑制钴基合金中Co~(2+)析出，解决了清洗剂的钴析出问题。因此，本文研制的清洗剂使用方便，安全环保，符合新型高性能清洗剂的发展方向。
Water-based metal cleaning agents are mainly composed of surface active agent andcorrosion inhibitor. The surface active agents have nonionic, anionic and amphoteric ionsurfactant, which are composed of two compounds of the hydrophobic and hydrophilicgroups. The water-based cleaning agents use the complex surfactant technology todevelop widely applicable range and decontamination capability. They are suitable formechanized automatic cleaning that can be widely used in metal processing industry.
The research of cleaning agents about domestic and foreign literature oncobalt-base alloy precipitation problem is few. Through the screening out of suitablesurfactant, this article has prepared a new type of alkaline and neutral efficient cleaningagent, which can effectively inhibit cobalt ion precipitation of cobalt-base alloy. Thecleaning agent requires not only the high cleaning efficiency but also can better inhibitthe cobalt precipitation of cobalt-base alloy, so the formulation is also required to jointhe metal corrosion inhibitor. Firstly, this article use the orthogonal test method to drawup the formula, make full use of the solubility of the solution, the solute pH value andthe characteristics of surfactant additives. At the same time, it can have a variety offunctions of the cleaning agent beside the decontamination effect in order to enhanceand increase the cleaning ability, through the comparison’s CEF and surface corrosionmorphology of different cleaning formulations after cleaning. So it determines thecleaning agent composition and cleaning technology. Secondly in the corrosion inhibitorscreening test for good cleaning and corrosion inhibition effect of compound corrosioninhibitor, it can filter out to add optimum dosage of compound corrosion inhibitor intothe cleaning agent by changing the dosage, which can obviously inhibit the precipitationof cobalt ion on the surface of the sample. Finally using citric acid and sodium citratebuffer solution to regulate the cleaning agent of the pH value so that to ultimatelydetermine the cleaning formulations.
The washing test of weak alkaline and neutral cleaning agent on artificial oil CEFis up to99.93%and99.74%, they can thoroughly remove greasy dirt from the metalsurface, which have achieved the ASTM G121-98and QB/T2117-95requirements. Thetest’s results of the cleaning agent corrosion evaluation show that the two kinds ofcleaning agent can not only reduce the corrosion area of cobalt base alloy, but alsoinhibit the precipitation of Co~(2+), so their corrosion effect are very well. Through thecontrast of the cleaning, immersion, salt spray, electrochemistry, SEM and energyspectrum test of the weakly alkaline, neutral, import and domestic cleaning agent on cobalt-based alloy. It has also showed that the developed cleaning agent’s corrosioneffect is better. They can better inhibit Co~(2+)emission of cobalt base alloy, which solvethe cleaning agent cobalt precipitation problem. Therefore, this paper has developed twokinds of cleaning agent that the use is convenient, safe and environmental, whichconforms to the development direction of the new high performance cleaning agents.
引文
[1]李仁琼.功能梯度硬质合金的研究现状和发展前景[J].硬质合金,2003,20(3),177～181.
[2]钱开友，王兴庆，何宝山等.碳含量对纳米硬质合金组织和性能的影响.上海大学学报（自然科学版），2002，8(5)：433～436.
[3] Li Z X, Cao C X. Intersection Mechanism of Deformation Twins withαPlateinγ-TiAl Alloy Deformted at Room Temperature[J]. Rare Metal Materials andEngineering,2003,32(2):95～98.
[4] Kissi M, Bouklah M, Hammouti B, et al. Establishment of equivalent circuits fromelectrochemical impedance spectroscopy study of corrosion inhibition of steel bypyrazine in sulphuric acidic solution[J]. Applied Surface Science,2006,252(12):4190～4197.
[5][5]Rosliza R, Senin H B, Wan W B. Electrochemical properties and corrosioninhibition of AA6061in tropical seawater[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,312(2/3):185～189.
[6] Satpati A K, Ravindran P V. Electrochemical study of the inhibition of corrosion ofstainless steel by1,2,3-benzotriazole in acidicmedia[J]. Materials Chemistry andPhysics,2008,109(2/3):352～359.
[7]张圣麟.常温除油清洗剂的制备与应用[J].材料保护，2003，36(10)：52～53.
[8]徐宝财，韩富，周雅文.工业清洗剂配方与工艺[M].北京化学工业出版社，2008，1(3)：34～38.
[9]王雨，郑晓宇，马玉华.含阴/非双子表面活性剂的金属清洗剂的性能研究[J].金属热处理，2006，31(9)：95～97.
[10]魏竹波，周继维，姚瑶.金属清洗技术[M].北京化学工业出版社，2003，6(2)：148～151.
[11] Yair E E, David S. Review on copper chemical mechanical polishing and post-CMPcleaning in ultra large system integrated(ULSI)-An electrochemical perspective[J].Electrochimica Acta,2007(52):1825～1838.
[12] Bernard M C, Gabrielli C, Joiret S, et a1. Investigations on the corrosion of copperpatterns in the course of the “post-CMP cleaning” of integrated electronicmicrocircuits in oxalic acid aqueous solutions[J]. Electrochimica Acta,2007(53):1325～1335.
[13] Ha G Y. Method of production WC/Co cemented carbide using grain growthinhibitor．The United States: US2002043130.2002-04-18.
[14] Naheed Bukhari. Cobalt transport through triethanolamine cyclohexanonesupported liquid membranes[J]. Journal of Membrane Science,2004,234(1/2):157～165.
[15]魏铭，朱焱.无磷水基金属清洗剂的研制[J].材料保护，2007，40(4)：30～31．
[16]左理胜，肖礼祥，姜建平，等.油垢清洗剂的研究与应用[J].石油化工腐蚀与防护，2009，26(3)：16～18.
[17]杨亚莉.水基型油污清洗剂的配方设计[J].大众科技，2009，8(3)：114～116.
[18]罗胜铁，沈丽，魏利滨，等.一种环境友好型水基多功能油污清洗剂的研制[J].清洗世界，2009，3(25)：11～15.
[19]杨文奎.企业实施ODS清洗改造项目对替代清洗剂的要求和质量认定方法[J].洗净技术，2004，5～57.
[20]孟冬华.水基清洗剂在表面处理中的应用[J].材料保护，2003，36(7)：57.
[21]李薇薇，刘玉岭，李广福.一种新型的LDC清洗剂[J].电子工业技术，2005，26(l)：35～40.
[22] Jin X M, Wang F. Influence of antirusting agent on the cobalt leaching of thecemented carbide tools[J]. Key Engineering Materials,2009,(407/408):317～320.
[23] Zhang H Q, Jin X M, Hou S. Study on inhibition effect of borax on cobalt-Fromcemented carbide tools[J]. Tool Engineering,2008,42(1):55～57.
[24]秦国治，田至明.工业清洗及应用实例[M].北京化学工业出版社.2003.
[25]傅乐峰，寿建平.高效水基金属脱脂剂的研究[J].表面技术，2001，30(3)：12.
[26]肖进新，赵振国.表面活性剂应用原理[M].北京化学工业出版社.2003.
[27]詹益腾，梁国柱.酸性除油与碱性除油的互补作用[J].电镀与环保，2002，22(2)：29～31.
[28]朱机灵，商剑锋，李小松，等.设备清洗剂的研制及应用[J].炼油技术与工程，2005，35(1)：29～32.
[29]周江萍.新型高效、防锈环保型金属清洗剂的研制[J].江西化工，2003，6(2)：77～78.
[30]赵会明，母泽亮.清洗机专用清洗剂的研制及应用仁[J].表面技术，2001，30(l)：46～48.
[31]刘玉岭，李薇薇，檀柏梅.微电子工艺中的清洗技术现况与展望[J].河北工业大学学报，2002，31(6)：11～17.
[32]傅乐峰，寿建平.高效水基金属脱脂剂的研究[J].表面技术，2001，30(3)：12.
[33]陈洁.高效水基金属清洗剂的研制[J].腐蚀与防护，2001，22(12)：54～56.
[34]孙高翔.水基金属清洗剂的清洗机理[J].洗净技术，2004，2(l)：27～28.
[35]王能友.一种高效印刷机清洗剂[J].材料与设备，2005(2)：27.
[36]吴小芳，石亚菊.ZW-1清洗剂的研制及应用[J].工业水处理，2004，24(11)：45～47.
[37]郝建军，王立军，安成强.环保型脱脂剂的研制[J].沈阳理工大学学报，2005，24(1)：50～52.
[38]张春梅.循环冷却水系统化学清洗配方的研究[J].石化科技，2001，24(l)：48～51.
[39]张好强，贾晓鸣，高筠.油酸添加剂对硬质合金刀具钴浸出的抑制作用[J].河北理工学院学报，2005，2：29～31．
[40]杨宏.油酸在水基金属加工液中的应用研究[J].润滑与密封，2004(9)：71～72.
[41]吴松，崔淑玲.DH-1新型水基除油剂的研制[J].表面技术，2005，34(4)：34～36.
[42]喻冬秀，文秀芳，杨卓如，等.无磷水基金属清洗剂的研制[J].电镀与环保，2004，24(1)：28～30.
[43]俞红，季德霖.HR-2型水基金属清洗剂的研制及应用[J].安徽化工，2003(6)：21～23.
[44]连建肖，张秀玲，杨桥，等.抑制硬质合金中金属W、Co水解的复合防锈剂的研究[J].硬质合金，2010，27(3)：153~157.
[45]李薇薇，刘玉岭，李广福.一种新型的LDC清洗剂[J].电子工业技术，2005，26(l)：35～40.
[46] Tsann R L. Experimental design and performance analys of TiN-coated carbide toolin face milling stainless steel[J]. Journal of Materials Processing Technology,2002,127:1～7.
[47] Harris T K, Brookes E J, Taylor C J. The effect of temperature on the hardness ofpolycrystalline cubic boron nitride cutting tool materials[J]. International Journal ofRefractory Metals﹠Hard Materials,2004,22:105～110.
[48]陈旭俊.工业清洗剂及清洗技术[M].北京化学工业出版社．2002.
[49]朱机灵，商剑锋，李小松，等.设备清洗剂的研制及应用[J].炼油技术与工程，2005，35(1)：29～32.
[50]周江萍.新型高效、防锈环保型金属清洗剂的研制[J].江西化工，2003，6(2)：77～78.
[51]李玉香，刘建强，肖洪池.液晶显示屏的非ODS清洗技术研究[J]．洗净技术,2003(5):24～27.
[52]王能友.一种高效印刷机清洗剂[J]．材料与设备，2005，2(2)：27.
[53]郝建军，王立军，安成强.环保型脱脂剂的研制[J]．沈阳理工大学学报．2005，24(1)：50～52.
[54]张圣麟.常温除油清洗剂的制备与应用[J]．材料保护，2003，36(10)：52～53.
[55]黄高山，汪蓉蓉.不锈钢抛光用低温高效超声波除蜡清洗剂的研制[J]．电镀与涂饰，2005，24(5)：16～18.
[56]吴松，崔淑玲.DH-1新型水基除油剂的研制[J]．表面技术，2005，34(4)：22～24.
[57] Ruhr R, Levitt M D, Richardson E H. Alkaline Metal Cleaner[P]．WO:03029393,2003-04-10.
[58] Sebabhattin G, Bernd F. Recovery of cobalt Powder and Tungsten carbide fromcemented carbide Scrap/Part I: Kinetics of cobalt Acid leaching [J]．ERZMETALL,2004,(3):143～147.
[59]弓宁满.“三合一”清洗剂的研制与应用[J]．腐蚀与防护，2004，25(4)：178～181.
[60]赵春芝.铝塑板生产中表面处理带来的污染及其治理[J]．2006，39(1)：74～76.
[61]陈金如，林美金.金属水剂清洗技术在设备维修中的应用[J]．今日印刷，2005(3)：75.
[62]孙丽媛，程秀芳.金属表面常温除油新工艺的研究[J]．表面技术，2003，32(2)：53～54.
[63] Yin L. Influence of microstructure on ultra precision grinding of cementedcarbides[J]．International Journal of Machine Tools and Manufacture,2004，44(5)：533～543.
[64] Ishikawa. Influence of EDM on the wear characteristics of WC-Co cementedcarbide[J]．Journal of Japanese Society of Tribologists,2003,48(11):928～935.
[65]周德民，程烨.常温除油剂的研制[J]．材料保护，2004，37(10)：45～46.
[66]于占峰．预磷化电镀锌钢板粉末喷涂前处理工艺[J]．电镀与精饰，2005，27(1)：29～34.
[67] JB/T4323.1-1999,水基金属清洗剂[S].
[68]刘程，米裕长．表面活性剂性质理论与应用[M]．北京北京工业大学出版社，2003.
[69]前野纯．使用准水基清洗剂的最新洗净实例[J]．电子工业专用设备，2004(9)：13～22.
[70] JB/T4323.2-1999,水基金属清洗剂试验方法[S].
[71]陶蕾，郑书忠，秦立娟，等．电化学测试技术在缓蚀剂缓蚀行为研究中的应用[J]．工业水处理，2010，30(8)：1～5.
[72]刘福国，杜敏．新型复配缓蚀剂对G105钢在NaCl溶液中缓蚀行为的影响[J]．金属学报，2007，43(9)：989～993.
[73] Hu D P, He B S, Kong D H. Influence of Cr addition on corrosion resistance ofWC-based cemented carbide[J]. Corrosion&Protection,2006,27(8):382～386.
[74] Jia X M, Wang Fei. Influence of antirusting agent on the cobalt leaching of thecemented carbide tool[J]. Key Engineering Materials,2009,(407/408):317～320.
[2]钱开友，王兴庆，何宝山等.碳含量对纳米硬质合金组织和性能的影响.上海大学学报（自然科学版），2002，8(5)：433～436.
[3] Li Z X, Cao C X. Intersection Mechanism of Deformation Twins withαPlateinγ-TiAl Alloy Deformted at Room Temperature[J]. Rare Metal Materials andEngineering,2003,32(2):95～98.
[4] Kissi M, Bouklah M, Hammouti B, et al. Establishment of equivalent circuits fromelectrochemical impedance spectroscopy study of corrosion inhibition of steel bypyrazine in sulphuric acidic solution[J]. Applied Surface Science,2006,252(12):4190～4197.
[5][5]Rosliza R, Senin H B, Wan W B. Electrochemical properties and corrosioninhibition of AA6061in tropical seawater[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2008,312(2/3):185～189.
[6] Satpati A K, Ravindran P V. Electrochemical study of the inhibition of corrosion ofstainless steel by1,2,3-benzotriazole in acidicmedia[J]. Materials Chemistry andPhysics,2008,109(2/3):352～359.
[7]张圣麟.常温除油清洗剂的制备与应用[J].材料保护，2003，36(10)：52～53.
[8]徐宝财，韩富，周雅文.工业清洗剂配方与工艺[M].北京化学工业出版社，2008，1(3)：34～38.
[9]王雨，郑晓宇，马玉华.含阴/非双子表面活性剂的金属清洗剂的性能研究[J].金属热处理，2006，31(9)：95～97.
[10]魏竹波，周继维，姚瑶.金属清洗技术[M].北京化学工业出版社，2003，6(2)：148～151.
[11] Yair E E, David S. Review on copper chemical mechanical polishing and post-CMPcleaning in ultra large system integrated(ULSI)-An electrochemical perspective[J].Electrochimica Acta,2007(52):1825～1838.
[12] Bernard M C, Gabrielli C, Joiret S, et a1. Investigations on the corrosion of copperpatterns in the course of the “post-CMP cleaning” of integrated electronicmicrocircuits in oxalic acid aqueous solutions[J]. Electrochimica Acta,2007(53):1325～1335.
[13] Ha G Y. Method of production WC/Co cemented carbide using grain growthinhibitor．The United States: US2002043130.2002-04-18.
[14] Naheed Bukhari. Cobalt transport through triethanolamine cyclohexanonesupported liquid membranes[J]. Journal of Membrane Science,2004,234(1/2):157～165.
[15]魏铭，朱焱.无磷水基金属清洗剂的研制[J].材料保护，2007，40(4)：30～31．
[16]左理胜，肖礼祥，姜建平，等.油垢清洗剂的研究与应用[J].石油化工腐蚀与防护，2009，26(3)：16～18.
[17]杨亚莉.水基型油污清洗剂的配方设计[J].大众科技，2009，8(3)：114～116.
[18]罗胜铁，沈丽，魏利滨，等.一种环境友好型水基多功能油污清洗剂的研制[J].清洗世界，2009，3(25)：11～15.
[19]杨文奎.企业实施ODS清洗改造项目对替代清洗剂的要求和质量认定方法[J].洗净技术，2004，5～57.
[20]孟冬华.水基清洗剂在表面处理中的应用[J].材料保护，2003，36(7)：57.
[21]李薇薇，刘玉岭，李广福.一种新型的LDC清洗剂[J].电子工业技术，2005，26(l)：35～40.
[22] Jin X M, Wang F. Influence of antirusting agent on the cobalt leaching of thecemented carbide tools[J]. Key Engineering Materials,2009,(407/408):317～320.
[23] Zhang H Q, Jin X M, Hou S. Study on inhibition effect of borax on cobalt-Fromcemented carbide tools[J]. Tool Engineering,2008,42(1):55～57.
[24]秦国治，田至明.工业清洗及应用实例[M].北京化学工业出版社.2003.
[25]傅乐峰，寿建平.高效水基金属脱脂剂的研究[J].表面技术，2001，30(3)：12.
[26]肖进新，赵振国.表面活性剂应用原理[M].北京化学工业出版社.2003.
[27]詹益腾，梁国柱.酸性除油与碱性除油的互补作用[J].电镀与环保，2002，22(2)：29～31.
[28]朱机灵，商剑锋，李小松，等.设备清洗剂的研制及应用[J].炼油技术与工程，2005，35(1)：29～32.
[29]周江萍.新型高效、防锈环保型金属清洗剂的研制[J].江西化工，2003，6(2)：77～78.
[30]赵会明，母泽亮.清洗机专用清洗剂的研制及应用仁[J].表面技术，2001，30(l)：46～48.
[31]刘玉岭，李薇薇，檀柏梅.微电子工艺中的清洗技术现况与展望[J].河北工业大学学报，2002，31(6)：11～17.
[32]傅乐峰，寿建平.高效水基金属脱脂剂的研究[J].表面技术，2001，30(3)：12.
[33]陈洁.高效水基金属清洗剂的研制[J].腐蚀与防护，2001，22(12)：54～56.
[34]孙高翔.水基金属清洗剂的清洗机理[J].洗净技术，2004，2(l)：27～28.
[35]王能友.一种高效印刷机清洗剂[J].材料与设备，2005(2)：27.
[36]吴小芳，石亚菊.ZW-1清洗剂的研制及应用[J].工业水处理，2004，24(11)：45～47.
[37]郝建军，王立军，安成强.环保型脱脂剂的研制[J].沈阳理工大学学报，2005，24(1)：50～52.
[38]张春梅.循环冷却水系统化学清洗配方的研究[J].石化科技，2001，24(l)：48～51.
[39]张好强，贾晓鸣，高筠.油酸添加剂对硬质合金刀具钴浸出的抑制作用[J].河北理工学院学报，2005，2：29～31．
[40]杨宏.油酸在水基金属加工液中的应用研究[J].润滑与密封，2004(9)：71～72.
[41]吴松，崔淑玲.DH-1新型水基除油剂的研制[J].表面技术，2005，34(4)：34～36.
[42]喻冬秀，文秀芳，杨卓如，等.无磷水基金属清洗剂的研制[J].电镀与环保，2004，24(1)：28～30.
[43]俞红，季德霖.HR-2型水基金属清洗剂的研制及应用[J].安徽化工，2003(6)：21～23.
[44]连建肖，张秀玲，杨桥，等.抑制硬质合金中金属W、Co水解的复合防锈剂的研究[J].硬质合金，2010，27(3)：153~157.
[45]李薇薇，刘玉岭，李广福.一种新型的LDC清洗剂[J].电子工业技术，2005，26(l)：35～40.
[46] Tsann R L. Experimental design and performance analys of TiN-coated carbide toolin face milling stainless steel[J]. Journal of Materials Processing Technology,2002,127:1～7.
[47] Harris T K, Brookes E J, Taylor C J. The effect of temperature on the hardness ofpolycrystalline cubic boron nitride cutting tool materials[J]. International Journal ofRefractory Metals﹠Hard Materials,2004,22:105～110.
[48]陈旭俊.工业清洗剂及清洗技术[M].北京化学工业出版社．2002.
[49]朱机灵，商剑锋，李小松，等.设备清洗剂的研制及应用[J].炼油技术与工程，2005，35(1)：29～32.
[50]周江萍.新型高效、防锈环保型金属清洗剂的研制[J].江西化工，2003，6(2)：77～78.
[51]李玉香，刘建强，肖洪池.液晶显示屏的非ODS清洗技术研究[J]．洗净技术,2003(5):24～27.
[52]王能友.一种高效印刷机清洗剂[J]．材料与设备，2005，2(2)：27.
[53]郝建军，王立军，安成强.环保型脱脂剂的研制[J]．沈阳理工大学学报．2005，24(1)：50～52.
[54]张圣麟.常温除油清洗剂的制备与应用[J]．材料保护，2003，36(10)：52～53.
[55]黄高山，汪蓉蓉.不锈钢抛光用低温高效超声波除蜡清洗剂的研制[J]．电镀与涂饰，2005，24(5)：16～18.
[56]吴松，崔淑玲.DH-1新型水基除油剂的研制[J]．表面技术，2005，34(4)：22～24.
[57] Ruhr R, Levitt M D, Richardson E H. Alkaline Metal Cleaner[P]．WO:03029393,2003-04-10.
[58] Sebabhattin G, Bernd F. Recovery of cobalt Powder and Tungsten carbide fromcemented carbide Scrap/Part I: Kinetics of cobalt Acid leaching [J]．ERZMETALL,2004,(3):143～147.
[59]弓宁满.“三合一”清洗剂的研制与应用[J]．腐蚀与防护，2004，25(4)：178～181.
[60]赵春芝.铝塑板生产中表面处理带来的污染及其治理[J]．2006，39(1)：74～76.
[61]陈金如，林美金.金属水剂清洗技术在设备维修中的应用[J]．今日印刷，2005(3)：75.
[62]孙丽媛，程秀芳.金属表面常温除油新工艺的研究[J]．表面技术，2003，32(2)：53～54.
[63] Yin L. Influence of microstructure on ultra precision grinding of cementedcarbides[J]．International Journal of Machine Tools and Manufacture,2004，44(5)：533～543.
[64] Ishikawa. Influence of EDM on the wear characteristics of WC-Co cementedcarbide[J]．Journal of Japanese Society of Tribologists,2003,48(11):928～935.
[65]周德民，程烨.常温除油剂的研制[J]．材料保护，2004，37(10)：45～46.
[66]于占峰．预磷化电镀锌钢板粉末喷涂前处理工艺[J]．电镀与精饰，2005，27(1)：29～34.
[67] JB/T4323.1-1999,水基金属清洗剂[S].
[68]刘程，米裕长．表面活性剂性质理论与应用[M]．北京北京工业大学出版社，2003.
[69]前野纯．使用准水基清洗剂的最新洗净实例[J]．电子工业专用设备，2004(9)：13～22.
[70] JB/T4323.2-1999,水基金属清洗剂试验方法[S].
[71]陶蕾，郑书忠，秦立娟，等．电化学测试技术在缓蚀剂缓蚀行为研究中的应用[J]．工业水处理，2010，30(8)：1～5.
[72]刘福国，杜敏．新型复配缓蚀剂对G105钢在NaCl溶液中缓蚀行为的影响[J]．金属学报，2007，43(9)：989～993.
[73] Hu D P, He B S, Kong D H. Influence of Cr addition on corrosion resistance ofWC-based cemented carbide[J]. Corrosion&Protection,2006,27(8):382～386.
[74] Jia X M, Wang Fei. Influence of antirusting agent on the cobalt leaching of thecemented carbide tool[J]. Key Engineering Materials,2009,(407/408):317～320.