纳米碳纤维在元素形态分析中的应用研究
|
摘要
随着现代环境科学、生命科学等学科的发展,人们发现元素的毒性与其存在形态密切相关,仅测量体系中元素的总量已不能满足研究该元素在体系中的生理、毒理作用的需要,因此提出了元素形态分析的概念。元素形态分析一般需要采用分离富集技术进行样品预处理,然后用高灵敏度的检测仪器进行测定。
固相萃取作为一种常用的分离富集技术,具有较高的富集倍数、选择性好、有机溶剂消耗量少、能处理小体积样品、可重复使用吸附材料、操作简单、易于实现自动化等优点,在样品前处理中得到了广泛的应用。固相萃取中吸附材料的选择非常重要,直接关系到方法的灵敏度和选择性。因此,寻找新的吸附材料一直是分析科学研究领域中的一个热点问题。纳米碳纤维作为一种新型的纳米碳材料,具有较高的比表面积、表面能和表面结合能等,对许多金属离子具有较强的吸附能力,是一种颇具潜力的分离富集材料。
电感耦合等离子体质谱法(ICP-MS)作为一种痕量、超痕量元素分析技术,具有检出限低、精密度高、分析速度快、线性范围宽和多元素同时测定等优点,在环境、食品、临床、生物、材料等领域里获得了广泛的应用。本论文的研究目的是,用纳米碳纤维作为固相吸附材料,以电感耦合等离子体质谱为检查手段,系统地研究了纳米碳纤维对铬、锰、砷三种元素不同价态的吸附性能、主要影响因素及其相关规律性,并将所建立的方法用于生物和环境样品中相关元素的形态分析。主要研究内容概括如下:
(1)以纳米碳纤维为吸附剂,将微柱分离富集与ICP-MS联用,对Cr(Ⅲ)和Cr(Ⅵ)的吸附行为进行了研究,考察了影响吸附的主要因素,建立了Cr(Ⅲ)和Cr(Ⅵ)分析的新方法。
(2)将微柱分离富集与ICP-MS联用,探讨了纳米碳纤维对Mn(Ⅱ)和Mn(Ⅶ)的吸附行为,考察了pH值、洗脱剂、共存离子等因素对吸附的影响,并用所建立的方法测定了实际样品中的Mn(Ⅱ)和Mn(Ⅶ)。
(3)用纳米碳纤维作为吸附剂,以ICP-MS作为检测手段,研究了纳米碳纤维在APDC存在下对As(Ⅲ)和As(Ⅴ)的吸附行为,考察了影响吸附的主要因素,并将所建立的方法应用于实际样品中As(Ⅲ)和As(Ⅴ)的分析。
With the development of environmental science and biological science, there is an increasing demand for the information about speciation because the different chemical forms of an element have different effects on human health, the environment and the ecosystems. Therefore, the separation and determination of elemental species is of great importance. In general, in order to obtain the data about the chemical form of elements, the separation and preconcentration are usually required before analysis by instruments.
Solid phase extraction(SPE) as a separation and preconcentration technique has become increasingly popular in the pretreatment of samples due to its advantages of simple to operate, high preconcentration factor, low consumption of organic solvents, rapid phase separation and the ability of combination with different detection techniques. The choice of adsorbents for SPE is very important as it is decisive and direct factor that affects analytical sensitivity and selectivity. Therefore, it has still been an interesting research field to find new and effective adsorbents nowadays. Carbon nanofibers(CNFs), as a novel and interesting carbon material, have very attractive features:small size, large specific surface area, excellent mechanical strength, highly chemical stability, and unique electrical property. Their surface properties can be modified through different treatments to satisfy special needs. These make them a promising candidate as adsorbers for solid phase extraction.
As is well know, inductively coupled plasma mass spectrometry (ICP-MS) has become one of the most appropriate techniques for the determination of trace/ultra-trace elements due to its low detection limits, super high sensitivity, broad dynamic linear range and rapid multi-element detection capability. The aim of this dissertation is to use a microcolumn packed with CNFs coupled to inductively coupled plasma mass spectrometry (ICP-MS) for the speciation analysis of elements in real samples. The major contents are described as follows:
(1) The adsorption characteristics of Cr(Ⅲ) and Cr(Ⅵ) on CNFs were investigated systematically. Based on the obtained results,a novel method was developed for the speciation of chromium by a microcolumn packed with CNFs as adsorbent coupled with ICP-MS. The proposed method has been applied to the determination of the chromium in certified materials, and chromium species in water samples with satisfactory results.
(2) The adsorption behaviors of Mn(Ⅱ) and Mn(Ⅶ) on CNFs under dynamic conditions were studied systematically. The main factors influencing preconcentration and determination of the analytes have been examined in detail. A novel method with carbon nanofibers(CNFs) as a solid phase extraction adsorbent for the preconcentration and determination of Mn(Ⅱ) and Mn(Ⅶ) was developed by inductively coupled plasma mass spectrometry (ICP-MS) detection.
(3) A new method for the separation/preconcentration of As(Ⅲ) and As(Ⅴ) with a microcolumn packed with carbon nanofibers is described for the determination by inductively coupled plasma mass spectrometry in the presence of APDC. The effects of pH, sample flow rate and volume, elution solution and interfering ions on the adsorption of analytes were examined in detail. The proposed method was applied to the determination of As(Ⅲ) and As(Ⅴ) in real samples with good results.
固相萃取作为一种常用的分离富集技术,具有较高的富集倍数、选择性好、有机溶剂消耗量少、能处理小体积样品、可重复使用吸附材料、操作简单、易于实现自动化等优点,在样品前处理中得到了广泛的应用。固相萃取中吸附材料的选择非常重要,直接关系到方法的灵敏度和选择性。因此,寻找新的吸附材料一直是分析科学研究领域中的一个热点问题。纳米碳纤维作为一种新型的纳米碳材料,具有较高的比表面积、表面能和表面结合能等,对许多金属离子具有较强的吸附能力,是一种颇具潜力的分离富集材料。
电感耦合等离子体质谱法(ICP-MS)作为一种痕量、超痕量元素分析技术,具有检出限低、精密度高、分析速度快、线性范围宽和多元素同时测定等优点,在环境、食品、临床、生物、材料等领域里获得了广泛的应用。本论文的研究目的是,用纳米碳纤维作为固相吸附材料,以电感耦合等离子体质谱为检查手段,系统地研究了纳米碳纤维对铬、锰、砷三种元素不同价态的吸附性能、主要影响因素及其相关规律性,并将所建立的方法用于生物和环境样品中相关元素的形态分析。主要研究内容概括如下:
(1)以纳米碳纤维为吸附剂,将微柱分离富集与ICP-MS联用,对Cr(Ⅲ)和Cr(Ⅵ)的吸附行为进行了研究,考察了影响吸附的主要因素,建立了Cr(Ⅲ)和Cr(Ⅵ)分析的新方法。
(2)将微柱分离富集与ICP-MS联用,探讨了纳米碳纤维对Mn(Ⅱ)和Mn(Ⅶ)的吸附行为,考察了pH值、洗脱剂、共存离子等因素对吸附的影响,并用所建立的方法测定了实际样品中的Mn(Ⅱ)和Mn(Ⅶ)。
(3)用纳米碳纤维作为吸附剂,以ICP-MS作为检测手段,研究了纳米碳纤维在APDC存在下对As(Ⅲ)和As(Ⅴ)的吸附行为,考察了影响吸附的主要因素,并将所建立的方法应用于实际样品中As(Ⅲ)和As(Ⅴ)的分析。
With the development of environmental science and biological science, there is an increasing demand for the information about speciation because the different chemical forms of an element have different effects on human health, the environment and the ecosystems. Therefore, the separation and determination of elemental species is of great importance. In general, in order to obtain the data about the chemical form of elements, the separation and preconcentration are usually required before analysis by instruments.
Solid phase extraction(SPE) as a separation and preconcentration technique has become increasingly popular in the pretreatment of samples due to its advantages of simple to operate, high preconcentration factor, low consumption of organic solvents, rapid phase separation and the ability of combination with different detection techniques. The choice of adsorbents for SPE is very important as it is decisive and direct factor that affects analytical sensitivity and selectivity. Therefore, it has still been an interesting research field to find new and effective adsorbents nowadays. Carbon nanofibers(CNFs), as a novel and interesting carbon material, have very attractive features:small size, large specific surface area, excellent mechanical strength, highly chemical stability, and unique electrical property. Their surface properties can be modified through different treatments to satisfy special needs. These make them a promising candidate as adsorbers for solid phase extraction.
As is well know, inductively coupled plasma mass spectrometry (ICP-MS) has become one of the most appropriate techniques for the determination of trace/ultra-trace elements due to its low detection limits, super high sensitivity, broad dynamic linear range and rapid multi-element detection capability. The aim of this dissertation is to use a microcolumn packed with CNFs coupled to inductively coupled plasma mass spectrometry (ICP-MS) for the speciation analysis of elements in real samples. The major contents are described as follows:
(1) The adsorption characteristics of Cr(Ⅲ) and Cr(Ⅵ) on CNFs were investigated systematically. Based on the obtained results,a novel method was developed for the speciation of chromium by a microcolumn packed with CNFs as adsorbent coupled with ICP-MS. The proposed method has been applied to the determination of the chromium in certified materials, and chromium species in water samples with satisfactory results.
(2) The adsorption behaviors of Mn(Ⅱ) and Mn(Ⅶ) on CNFs under dynamic conditions were studied systematically. The main factors influencing preconcentration and determination of the analytes have been examined in detail. A novel method with carbon nanofibers(CNFs) as a solid phase extraction adsorbent for the preconcentration and determination of Mn(Ⅱ) and Mn(Ⅶ) was developed by inductively coupled plasma mass spectrometry (ICP-MS) detection.
(3) A new method for the separation/preconcentration of As(Ⅲ) and As(Ⅴ) with a microcolumn packed with carbon nanofibers is described for the determination by inductively coupled plasma mass spectrometry in the presence of APDC. The effects of pH, sample flow rate and volume, elution solution and interfering ions on the adsorption of analytes were examined in detail. The proposed method was applied to the determination of As(Ⅲ) and As(Ⅴ) in real samples with good results.
引文
[1]Templeton D.M.,Ariese F.,Cornelis R. etc.Guidelines for terms related to chemical speciation and fractionation of elements.Definitions,structural aspects, and methodological approaches (IUPAC Recommendations 2000). Pure Appl. Chem., 2000, 72:1453-1470.
[2]陈文君,吴政宙,卢志琴.液液萃取-分光光度法测定三溴苯酚中铁.理化检验-化学分册,2006,42(10):859-859.
[3]武宇红,孟哲,廖询等.液液萃取饮料中甲苯GC/MS测定方法的研究.河北农业大学学报,2006,29(5):57-59.
[4]郁建栓.固相萃取-气相色谱/质谱法测定地面水中半挥发性有机物.岩矿测试,2006,25(4):331-333.
[5]Nilgun Tokman, Suleyman Akman. Determination of bismuth and cadmium after solid-phase extraction with chromosorb-107 in a syringe.Analytica Chimica Acta, 2004, 519(1):87-91.
[6]Franco A. Bertolino, Angel A. J. Torriero, Eloy Salinas etc. Speciation analysis of selenium in natural water using square-wave voltammetry after preconcentration on activated carbon. Analytica Chimica Acta, 2006, 572:32-38
[7]王海林,钱沙华,汪玉庭等.交联壳聚糖富集分离冷原子吸收分光光度法测定环境水样中痕量无机汞.分析化学研究学报,1997,25(8):893-897
[8]Santha V., Ketavarapu Yathavakilla, Monika Shah etc. Speciation ofcationic selenium compounds in Brassica juncea leaves by strong cation-exchange chromatography with inductively coupled plasma mass spectrometry. Journal of Chromatography A, 2005, 1100(2):153-159.
[9] Kristina Hennebrüder, Rainer Wennrich, Jürgen Mattusch etc. Determination of gadolinium in river water by SPE preconcentration and ICP-MS. Talanta, 2004, 63(2):309-316.
[10]张彦斌,程忠洲,李华.硫脲树脂富集-电感耦合等离子体质谱法测定地质样品中的超痕量金、银、铂、钯.分析试验室,2006,25(7):105-108.
[11]苏耀东,郝冰冰,秦立俊等.8-羟基喹啉快速共沉淀分离富集原子吸收光谱法测定啤酒中的Cu和Pb.光谱学与光谱分析, 2007, 3(27):589-591.
[12]殷忠,黄培林,李雪春.用硝酸铋共沉淀分离富集的火焰原子吸收法测定酱油中微量铅的方法研究.现代预防医学,2007,34(1):117-119.
[13]赵可江,王新军,赵亮等.偕胺肟基纤维对金属离子选择吸附性能研究.黄金,2008,29(1):52-56.
[14]王照丽,肖新峰,罗娅君等.螯合树脂浓缩柱预富集低压离子色谱分光光度法测定海水中痕量铅.分析测试学报,2007,26(2):221-224.
[15]朱永春,李丹,岳爽等.超声波-微分脉冲伏安法测定超痕量铜.分析化学研究简报,2006,34(5):721-724.
[16]王玉宝,陈玉静,唐清华等.离子交换纤维分离富集催化光度法测定痕量铬(Ⅵ).理化检验-化学分册,2007,43(12):1085-1087.
[17]胡瑜,杨亚玲,胡礼鸣等.阳离子树脂微柱-孔雀石绿分光光度法测化妆品中的铅.分析试验室,2007,26:165-167.
[18]付颖,王常波,叶非.固相微萃取技术在农药残留分析中的应用.理化检验-化学分册,2006,42(10):865-870.
[19] Mester Z., Sturgeon R., Pawliszyn J.. Review Solid phase microextraction as a tool for trace element speciation. Spectrochim.Acta, 2001, 56B:233-260.
[20]杨骥,郭锐,彭娟等.应用活性炭纤维型固相微萃取器定量分析化妆品中的甲醇.环境化学,2005,24(5):620-621.
[21] Dimitra A.L., Triantafyllos A.A., Liquid-phase micro-extraction techniques in pesticide residue analysis. Biochemical and Biophysical Methods, 2007, 70(2):195-228.
[22]张红,陈玲,陈皓等.液相微萃取技术及其在环境水样预处理中的应用.环境监测管理与技术,2004,16(6):8-11.
[23]Clàudia Fontàs, Núria Pont, Manuela Hidalgo etc. Separation and preconcentration of Cd(II) from chloride solutions using supported liquid membranes systems. Desalination, 2006, 200(3):114-116.
[24] Leyre Irigoyen, Carlos Moreno, Carolina Mendiguchía etc. Application of liquid membranes to sample preconcentration for the spectrometric determination of cadmium in seawater. Journal of Membrane Science, 2006, 274 (1):169-172.
[25]Farhadi K.,Teimouri G.. Flame atomic absorption determination of palladium in solutions after preconcentration using octadecyl silica membrane disks modified by thioridazine·HCl. Talanta, 2005, 65(4): 925-929.
[26]王仁才,欧阳建文,成智涛等.超临界流体萃取技术在果实功效成分提取中的应用.湖南农业大学学报:自然科学版,2006,32(2):225-228.
[27]金春英,林金清,李雯君.超临界流体萃取技术在中药提取中的应用与发展趋势.化学工程与装备,2006,6:48-51.
[28]周丽屏,郭璇华.超临界流体萃取技术及其应用.现代仪器,2006,4:18-21.
[29]黄焱,秦炜,戴猷元.浊点萃取技术及其在分离过程中的应用.现代化工,2006,26:307-311.
[30]黄晖,陈培珍.浊点萃取技术在痕量金属离子测定中的应用.三明高等专科学校学报,2004,21(4):66-71.
[31]Lemos V.A., da Fran?a R.S., Moreira B.O.. Cloud point extraction for Co and Ni determination in water samples by flame atomic absorption spectrometry. Separation and Purification Technology, 2007, 54(3): 349-354.
[32]Coelho L.M.,Arruda M.A.. Preconcentration procedure using cloud point extraction in the presence of electrolyte for cadmium determination by flame atomic absorption spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(5):743-748.
[33] Marcos A. B., Roy E. B., Sergio L.C. Ferreira.. Statistical design-principal component analysis optimization of a multiple response procedure using cloud point extraction and simultaneous determination of metals by ICP -OES. Analytica Chimica Acta, 2006, 580(2):251-257.
[34]彭岚,谈明光,李玉兰等.微波辅助萃取-液质联用技术测定底泥砷、硒的化学形态.分析实验室,2006,25(5):10-14.
[35]Liang Pei, Liu Rui. Speciation analysis of inorganic arsenic in water samples by immobilized nanometer titanium dioxide separation and graphite furnace atomic absorption spectrometric determination. Anal. Chim. Acta, 2007, 602:32-36.
[36]梁沛、李春香、秦勇超等.纳米二氧化钛分离富集和ICP-AES测定水样中Cr (Ⅲ)/Cr (Ⅵ).分析科学学报,2000,l6(4):300-303.
[37]谷学新,邹洪,朱若华.分析化学中的分离技术.分析试验室,2001,20(3):96-98.
[38]曹华丽,闫永胜,赵干卿等.离子交换树脂预浓集薄层树脂相分光光度法测定水中铬(Ⅵ)和铬(Ⅲ).冶金分析,2006,26(5):72-74.
[39]唐索寒,朱祥坤.AGMP-1阴离子交换树脂元素分离方法研究.高校地质学报,2006,12(3):398-403.
[40]Zhu Yanbei, Itoh Akihide, Eiji Fujimori etc. Determination of rare earth elements in seawater by ICP -MS after preconcentration with a chelating resin -packed minicolumn. Journal of Alloys and Compounds, 2006, 408(2):985-988.
[41] Dwinna Rahmi, Zhu Yanbei, Eiji Fujimori etc. Multielement determination of trace metals in seawater by ICP -MS with aid of down-sized chelating resin-packed minicolumn for preconcentration. Talanta, 2007, 72(2):600-606.
[42] Wu Yiwei, Jiang Zucheng, Hu Bin.Speciation of vanadium in water with quinine modified resin micro-column separation/preconcentration and their determination by fluorination assisted electrothermal vaporization(FETV)–inductively coupled plasma optical emission spectrometry ( ICP -OES). Talanta, 2005, 67(4):854-861.
[43] Katarina Rosi Ketrin, Toshio Takayanagi, Mitsuko Oshima etc. Synthesis of a chitosan-based chelating resin and its application to the selective concentration and ultratrace determination of silver in environmental water samples. Analytica Chimica Acta, 2006, 558(2): 246-253.
[44]李正罡,王义,张敏.DCS-偶氮胂树脂相分光光度法测定牧草中的微量稀土.稀土,2001,22(5):40-41.
[45]江放明,周方钦等.聚乙烯-双硫腙复膜树脂分离富集/原子吸收法测定地质样品中的痕量金.分析科学学报,2006,22(1):34-36.
[46]马桂云,孙开进,王京平等.双硫腙负载树脂对铅和镉的吸附性能研究.化学世界,2006,12:726-729.
[47]张凯,鲍长利,李增文等.双硫腙螯合形成树脂分离富集地质样品中的微量金、铂、钯及其测定.分析化学,1997,25(4):404-407.
[48]Ferreira S.L.C., Brito C.F., Dantas A.F.. Nickel determination in saline matrices by ICP-AES after sorption on Amberlite XAD-2 loaded with PAN. Talanta,1999, 48:1173-1177.
[49] Molodovan Z., Vladscu L.. Preparation, characterization and metal sorption studies of a Chrome-Azuro-S-loade danion-exchange resin. Talanta, 1996, 43:1573-1577.
[50]郭嘉,陈延林,罗晔等.新型离子交换纤维的应用研究及展望.高科丝纤谁与应用,2005,30(6):35-38.
[51]Wen Bei, Shan Xiaoquan, Lian Jun. Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry. Talanta, 2002, 56(4):681-687.
[52]张华,逯阳,肖长发.载双硫腙螯合纤维制备及富集重金属离子研究.离子交换与吸附,2005,21 (5):468-473.
[53]杨秀政.多胺螯合纤维预富集FAAS对水体中铅的形态分析.分析试验室,2007,26(1):102-104.
[54]Tang bo,Zhang hui, Wang yan. On-line separation, preconcentration and determination of trace amounts of gold in mineral sample by flow injection catalytic kinetic spectrofluorimetry . Analytica Chimica Acta, 2004, 525(2):305-311.
[55]李慧芝,赵淑英.聚酰胺分离富集催化动力学电位法测定痕量钯.分析科学学报,2005,21(6):652-654.
[56]解文秀,李慧芝,韩斌.聚酰胺分离富集发射光谱法同时测定金、铂和钯.光谱实验室,2005,22(1):62-65.
[57]李承元,李蓉,赵刚等.负载泡沫塑料富集发射光谱测定化探样品中痕量金、铂、钯.黄金,2005,26(12):48-50.
[58]林智辉,王英滨,黄文辉.聚氨酯泡沫塑料富集-电感耦合等离子体质谱法测定地质样品中痕量铂和钯.理化检验-化学分册,2005,41(5):321-323.
[59]Lemos V.A., Santos M.S., Santos E.S etc. Application of polyurethane foam as a sorbent for trace metal preconcentration-a review. SpectrochimicaActa Part B: Atomic Spectroscopy, 2007, 62(1):4-12.
[60]王丽敏,宋闯,金晶.熔融萘萃取铁(Ⅱ)-4,7-二苯基-1,10-菲啰啉-四苯硼酸盐三元络合物光度法测定铁.分析试验室,2004,23 (9) :48-50.
[61] Sharma R.K.. Solid-phase extraction of trace metal ions using low-melting extractants. Microchem. J., 1995, 51:289-311.
[62]范哲锋,杜黎明.微晶萘固相萃取ICP-AES法测定地质样品中的痕量铟.分析试验室,2000,19(3):63-64.
[63] Fan Zhefeng, Hu Bin, Jiang Zucheng. Speciation analysis of vanadium in natural water samples by electrothermal vaporization inductively coupled plasma optical emission spectrometry after separation/preconcentration with thenoyltrifluoroacetone immobilized on microcrystalline naphthalene. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(1):65-71.
[64]Xiong Chaomei, Jiang Zucheng, Hu Bin. Speciation of dissolved Fe(II) and Fe(III) in environmental water samples by micro-column packed with N-benzoyl-N-phenylhydroxylamine loaded on microcrystalline naphthalene and determination by electrothermal vaporization inductively coupled plasma-optical emission spectrometry. Analytica Chimica Acta, 2006, 559(1):113-119.
[65]Zhu Xiangbing, Chang Xijun, Cui Yuemei etc. Solid-phase extraction of trace Cu(II) Fe(III) and Zn(II) with silica gel modified with curcumin from biological and natural water samples by ICP-OES. Microchemical Journal,2007, 86(2):189-194.
[66]Chang Xijun, Jiang Na, Zheng Hong etc. Solid-phase extraction of iron(III) with an ion-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique. Talanta, 2007, 71(1):38-43.
[67]樊静,秦玉霞,冯素玲等.二苯卡巴腙键合硅胶的制备及对废水中重金属的分离与富集.分析化学,2005,33(8):1151-1154.
[68]杨朝勇,吴熙鸿等.碳18键合硅胶柱-流动注射-电感耦合等离子体质谱联用技术及其在海水分析中的应用.分析化学,2001,29(3),283-286.
[69]Dressler V.L., Pozebon D., Curtius A. J.. Determination of Ag, Te, U and Au in waters and in biologicalsamples by FI–ICP-MS following on-line preconcentration. Anal.Chim.Acta, 2001, 438:235-244.
[70]叶映雪.流动注射固相预富集原子吸收光谱法测定铁和钴.光谱实验室,2000,17(4):459-462.
[71]张俊刚.可控孔径多孔玻璃微珠的研制及其吸附性能的研究:[硕士学位论文].吉林长春:长春理工大学,2002.
[72]Amarildo Otavio Martins, Edson Luiz da Silva, Eduardo Carasek etc. Chelating resin from functionalization of chitosan with complexing agent 8-hydroxyquinoline: application for metal ions on line preconcentration system. Analytica Chimica Acta, 2004, 521(2):157-162.
[73]Ebru Birlik, Arzu Ers?z, Adil Denizli. Preconcentration of copper using double-imprinted polymer via solid phase extraction. Analytica Chimica Acta, 2006, 565(2),145-151.
[74]Tang Y.W.,Chen B.R.,Mo S,J.. Separation and preconcentration ofultratrace lead in biological organisms and its determination by graphite furnace atomic absorption spectrometry. Talanta, 1996, 43:761-765.
[75]纪志永,李鑫钢,孙津生.炭材料在水污染修复领域的应用研究.材料导报,2006,20(7):84-87.
[76]王爱霞,郭黎平,张宏.活性炭微柱在线流动注射预富集-火焰原子吸收快速顺序测定铜、钴、镍、镉、铅的研究.分析化学,2005,33(3):385-388.
[77]吴惠明,李锦文,陈永亨.活性炭吸附分离-8-羟基喹啉紫外分光光度法测定铊.化学试剂,2006,28(9):547-548.
[78] Takara E. A., Pasini-Cabello S. D., Cerutti S. etc. On-line preconcentration/determination of copper in parenteral solutions using activated carbon by inductively coupled plasma optical emission spectrometry. Journal of Pharmaceutical and Biomedical Analysis, 2005, 39(3):735-739.
[79] Mehrorang Ghaedi, Farshid Ahmadi, Ardeshir Shokrollahi. Simultaneous preconcentration and determination of copper, nickel, cobalt and lead ions content by flame atomic absorption spectrometry. Journal of Hazardous Materials, 2007, 142(1):272-278.
[80]Barbara Miku?a, Bo?ena Puzio. Determination of trace metals by ICP-OES in plant materials after preconcentration of 1,10-phenanthroline complexes on activated carbon. Talanta, 2007, 71(1):136-140.
[81]李永贵,赵苗,梁继.国内活性炭纤维的应用研究与开发.纺织学报,2006,27(6):100-103.
[82]杨健松,李玉峰,赖奇.膨胀石墨的研究与开发利用.攀枝花学院学报:综合版,2006,23(6):99-102.
[83]Filho N.L.D., Gushikem Y.,Polito W.L.. 2-Mercaptobenzothiazole clay as matrix for sorption and preconcentration of some heavy metals from aqueous solution. Anal.Chim.Acta, 1995, 306:167-172.
[84]Towler P.H., Smith J,D.,Dixon D.R.. Magnetic recovery of radium, lead and polonium from seawater samples after preconcentration on a magnetic adsorbent of manganese dioxide coated magnetite. Anal. Chim. Acta, 1996, 328:53-59.
[85] Hiraide M.,Iwasawa J., Kawaguchi H.. Collection of trace heavy metals complexed with ammonium pyrrolidinedithiocarbamate on surfactant-coated alumina sorbents. Talanta, 1997, 44:231-237.
[86]黄志英,李惕川,齐振光.流动注射在线预浓集原子吸收光谱分析废水中的Cd~(2+)、Fe~(3+)、Zn~(2+).离子交换与吸附,1996,12:27-33.
[87]张兆春,刘振学,牛富玲.活性矸对硫、氟、铬阴离子吸附的研究.环境科学,1996,15(5):415-419.
[88]李永宏,王尚义,郑玉霞.浅谈对富勒烯的认识及应用.内蒙古石油化工,2006,32(8):16-17.
[89]Barbara A.Le?niewska, Iwona Godlewska.The study of applicability of dithiocarbamate-coated fullerene C60 for preconcentration of palladium for graphite furnace atomic absorption spectrometric determination in environmental samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(3):377-384.
[90] Pereira M.G., Pereira-Filho E.R., Berndt H..Determination of cadmium and lead at low levels by using preconcentration at fullerene coupled to thermospray flame furnace atomic absorption spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 2004, 59(4):515-521.
[91]Mu?oz J.,Gallego M., Valcárcel M.. Speciation analysis of mercury and tin compounds in water and sediments by gas chromatography–mass spectrometry following preconcentration on C60 fullerene. Analytica Chimica Acta, 2005, 548(1):66-72.
[92]Adriano Francisco Barbosa,Mariana Gava Segatelli,Arnaldo César Pereira,etc. Solid-phase extraction system for Pb (II) ions enrichment based on multiwall carbon nanotubes coupled on-line to flame atomic absorption spectrometry. Talanta, 2007, 71( 4):1512-1519.
[93]刘艳.纳米材料在痕量元素分离富集及形态分析中的应用:[硕士学位论文].湖北武汉:华中师范大学,2005.
[94]赵稼祥.纳米碳纤维及其应用.纤维复合材料,2003,20(4):48-50.
[95]Chen Shizhong, Xiao Mingfa, Lu Dengbu etc.Use of a microcolumn packed with modified carbon nanofibers coupled with inductively coupled plasma mass spectrometry for simultaneous on-line preconcentration and determination of trace rare earth elements in biological samples. Rapid Communication in Mass Spectrometry, 2007, 21:2524-2528.
[96]Chen Shizhong, Xiao Mingfa, Lu Dengbu etc.Preconcentration and separation of gold and palladium in geological samples via solid-Phase extraction on carbon nanofibers prior to sample analysis by ICP-MS.Atomic Spectroscopy, 2007, 28(3):90-94.
[97]肖亚兵,钱沙华等.纳米二氧化钛对砷(Ⅲ)和砷(Ⅴ)吸附性能的研究.分析科学学报,2003,19(2):172-174.
[98] Beard H.C., Lyerlyl A.. Separation of arsenic fromantimony and bismuth by solvent extraction. Anal. Chem, 1961, 33(12):1781-1782.
[99]Zhang X., Vanderbiesen V., Cubber A.D. . Accumulation of arsenic species in serumof patients with chronic renaldisease. Clin. Chem., 1996, 42(8):1231-1237.
[100]陈历程,张勇.微量元素硒的研究现状及其食品强化.食品科学,2002,23(10):134-137.
[101]黄峙.食品硒源的生物学研究进展.食品科学,2001,22(5):90-94.
[102]刘国珍,金泽祥.汞的形态分析进展.理化检验-化学分册,2000,36(1):38-41.
[103]郑徽,金银龙.汞的毒性效应及作用机制研究进展.卫生研究,2006,35(5):663-666.
[104] Morita Y., Kobayashi T., Kuroiwa T. etc. Study on simultaneous speciation of arsenicand antimony by HPLC–ICP-MS. Talanta, 2007, 73:81–86.
[105]Ronkart S.N., Laurent V., Carbonnelle P. etc. Speciation of five arsenic species (arsenite, arsenate, MMAAV, DMAAV and AsBet) in different kind of water by HPLC-ICP-MS. Chemosphere, 2007, 66:738-745.
[106]Duarte F.A., Pereira J.S.F., Mesko M.F. etc. Evaluation of liquid chromatography inductively coupled plasma massspectrometry for arsenicspeciation in water from industrialtreatment of shale. Spectrochimica Acta Part B, 2007, 62: 978-984.
[107] Nina Ulrich. Speciation of antimony(Ⅲ), antimony(Ⅴ) and trimethylstiboxide by ion chromatography with inductively coupled plasma atomic emssion spectrometric and mass spectrometric detection. Anal.Chim.Acta, 1998, 359:245-253.
[108]Li Feng, Wang Dongdong, Yan Xiuping etc. Speciation analysis of inorganic arsenic by microchip capillaryelectrophoresis coupled with hydride generation atomic fluorescence spectrometry. Journal of Chromatography A, 2005, 1081:232-237.
[109]顾文奎,慕毓,陈文杰.气相色谱及其联用技术在环境有机锡化合物分析中的应用.环境与健康杂志,2006,23(5):478-480.
[110]赵亮,朱霞石,封克等.纳米二氧化钛分离/富集-石墨原子吸收光谱法测定环境样品中痕量镉.分析化学(FENXIHUAXUE)研究简报,2006,34:S223-S226.
[111]罗津新.TBP萃淋树脂分离GFAAS法测定水与废水中的铬(Ⅲ)和铬(Ⅵ).中国环境监测,1999,15(4):36-38.
[112]叶映雪.流动注射固相萃取预富集原子吸收光谱测定铁的价态.分析测试技术与仪器,2000,6(1):31-33.
[113]姜健生.交联壳聚糖在锑形态分析中的应用.分析测试学报,1998,17(4):1-4.
[114]吴旭,翁明,肖亚兵等.纳米二氧化钛富集石墨炉原子吸收光谱法测定环境水样中痕量锑.分析科学学报,2004,20(4):376-380.
[115]孔庆安,吴奇藩,林罗发等.活性氧化铝富集火焰原子吸收法测定铬(Ⅲ)和铬(Ⅵ).分析测试学报,1996,15(4):74-76.
[116]李顺兴,钱沙华.固氮蓝藻分离富集石墨炉原子吸收光谱法测定痕量铬(Ⅲ)和铬(Ⅵ).分析科学学报,1995,11(1):42-46.
[117]喻德忠,邹菁,艾军.纳米二氧化锆对砷(Ⅲ)和砷(Ⅴ)的吸附性质研究.武汉化工学院学报,2004,26(3):21-24.
[118] Coelho N.M.M., Coelho L.M., Lima E.S. etc. Determination of arsenic compounds in beverages by high-performance liquid chromatography-inductively coupled plasma mass spectrometry. Talanta, 2005, 66:818-822.
[119]Hirata S., Honda K., Shikino O. etc. Determination of chromium(III) and total chromium in seawater by on-line column preconcentration inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B, 2000, 55:1089-1099.
[120]袁东星等.流动注射小柱预富集-石墨炉原子吸收联用分析茶汤和水样中不同形态的铝.厦门大学学报,1998,37(1):80-87.
[121]李玉珍,陈德勋.环境样品中铝的形态分析.岩矿测试,1999,18(4):241-245.
[122]Abollino O., Aceto M., Sarzanini C., Mentasti E.. The retention of metal species by different solid sorbents mechanisms for heavy metal speciation by sequential three column uptake. Anal.Chim.Acta, 2000, 411:223-237.
[123]罗明标,毕树平.阳离子交换树脂分离-铝试剂分光光度法测定土壤中铝形态.分析科学学报,2004,20(2):113-116.
[124]吴庆梅,康清蓉,郑坚等.连续流动冷原子吸收光谱法测定鱼体中总汞、无机汞和有机汞.光谱实验室,2007,24(2):103-105.
[125] Robles L.C., Feo J.C.,Aller A.J., Selective preconcentration of phenyl-mercury by living Escherichia coli and its determination by cold vapour atomic absorption spectrometry. Anal.Chim.Acta, 2000, 423:255-263.
[126]黄国清,彭珊珊.食用花卉中微量元素Fe的可溶性有机态和无机态研究.食品工业科技,2004,20(2):113-116.
[127]Bardy M., Bonhomme C., Fritsch E.. Al speciation in tropical podzols of the upper Amazon Basin: A solid-state 27Al MAS and MQMAS NMR study. Geochimica et Cosmochimica Acta. 2007, 71: 3211-3222.
[128]张勇,唐元洪,裴立宅等.纳米碳纤维的批量制备和应用.高科技纤维与应用,2005,30(2):20-25.
[129]余雯,刘日利,潘春旭.热氧化法制备ZnO纳米针的微结构与场发射性质研究.电子显微学报,2006,25(B08):40-41.
[130]陈东,陈廉,刘实等.新型复合材料Mg/ MWNTs的储放氢性能.中国有色金属学报,2003,13(4):850-855.
[131]朱相丽.纳米复合材料的研究进展.新材料产业,2006,11,57-60.
[132]陈煜,唐亚文,周益民等.碳纳米管作燃料电池催化剂载体的研究进展.电池,2006,36(1):71-73.
[133]祝宁宁.硫化铅纳米颗粒标记DNA电化学探针研究.上海师范大学学报(自然科学版),2004,33(2):65-69.
[134]赵稼祥.纳米碳纤维及其应用.高科技纤维与应用,2003,28(2):7-10.
[135]于立岩,张乾,崔作林.螺旋纳米碳纤维的制备与表征.高等学校化学学报,2005,26(1):5-8.
[136]顾书英,朱立华,藤新荣.纳米碳纤维的制备及应用.材料导报,2004, 18(4):86-88.
[137]张勇,唐元洪,裴立宅.纳米碳纤维制备方法的研究进展.炭材料科学与工艺,2005,15(1):33-37.
[138]曾艳.柱分离富集/等离子体质谱痕量元素及形态分析:[硕士学位论文].湖北武汉:武汉大学,2004.
[139]陈松涛,闫永胜,徐婉珍等.纳米TiO2预分离/富集FAAS法同时测定Cr (Ⅲ)和Cr (Ⅵ)的研究.光谱学与光谱分析,2007,5:1018-1020.
[140]张春丽,宋恩军,张东.纳米钛酸锶钡分离原子吸收法测定铬酸盐转化膜中铬形态.电镀与精饰, 2007,5:48-51.
[141]Liang Pei, Shi Taqing, Lu Hanbing etc. Speciation of Cr (Ⅲ) and Cr (Ⅵ) by nanometer titanium dioxide micro-column and inductively coupled plasma atomic emission spectrometry. Spectrochimica Acta PartB: Atomic Spectroscopy, 2003, 58 (9):1709-1714.
[142] Jimmy C.Yu, Wu Xiu-Juan, Chen ZuLiang. Separation and determination of Cr(III) by titanium dioxide-filled column and inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 2001, 436:59-67.
[143]梁沛,江祖成,胡斌等.纳米二氧化钛材料对稀土络合物吸附性能的研究.中国稀土学报,2002,20(4):311-314.
[144]Hu Jing, Irene M.C.Lo, Chen Guohua. Performance and mechanism of chromate(VI) adsorption byδ-FeOOH-coated maghemite (γ-Fe2O3) nanoparticles. Separation and Purification Technology, 2007, 58:76-82.
[145]Suna Y.C.,Chen Y.J., Tsai Y.N.. Determination of urinary arsenic species using an on-line nano-TiO2 photooxidation device coupled with microbore LC and hydride generation-ICP-MS system. Microchemical Journal, 2007, 86:140-145.
[146] Cui Yuemei, Chang Xijun, Zhu Xiangbing etc. Nanometer SiO2 modified with 5-sulfosalicylic acid as selective solid-phase extractant for Fe (III) determination by ICP-AES from biological and natural water samples. Microchemical Journal, 2007, 86:23-28.
[147]刘二保,梁建功,韩素琴等.铬的形态分析研究与进展.理化检验-化学分册,2003,39(6):368-371.
[148]李艳廷,李方.环境中无机铬形态分析研究进展.化学研究与应用,2000,12(5):476-481.
[149] Ibrahim Narin, Ayse Kars,Mustafa Soylak. A novel solid phase extraction procedure on Amberlite XAD-1180 for speciation of Cr(III), Cr(VI) and total chromium in environmental and pharmaceutical samples. Journal of Hazardous Materials, 2008, 150: 453-458.
[150] Sadhan Pramanik, Sourav Dey, Pabitra Chattopadhyay. A new chelating resin containing azophenolcarboxylate functionality: synthesis, characterization and application to chromium speciation in wastewater. Analytica Chimica Acta, 2007, 584:469-476.
[151] Amauri A.Meneg′ario,Patricia Smichowski,Griselda Polla.On-line preconcentration and speciation analysis of Cr(III) and Cr(VI)using baker’s yeast cells immobilised on controlled pore glass. Analytica Chimica Acta, 2005, 546:244-250.
[152] Balarama Krishna M.V., Chandrasekaran K.,Sarva V. Rao etc. Speciation of Cr (III) and Cr (VI) in waters using immobilized moss and determination by ICP-MS and FAAS. Talanta, 2005, 65:135-143.
[153] Zhang Nan, Jibrin Sabo Suleiman, He Man etc. Chromium (III)-imprinted silica gel for speciation analysis of chromium in environmental water samples with ICP-MS detection. Talanta, 2008, 75: 536-543.
[154]张勇,唐元洪,裴立宅等.纳米碳纤维的批量制备与应用.高科技纤维与应用,2005,30(2):20-25.
[155]唐天地,陈久岭,李永丹.碳纳米纤维在浓硝酸-浓硫酸溶液中表面氧化对其负载的Pd-Pt催化剂颗粒分散状态的影响.高等学校化学学报,2006,27(1):129-133.
[156]肖明发,陈世忠,战锡林等.纳米碳纤维分离富集电感耦合等离子体质谱法测定地质样品中痕量Au.光谱学与光谱分析, 2008, 28(2):444-446.
[157] Angel Maquleira, Hayat A.M. Elmahadi, Rosa Puchades. Immobilized cyanobacteria for on-line tracemetal enrichment by flow injection atomic absorption. Anal. Chem., 1994, 350:387.
[158]Bernhard Michalke. Manganese speciation using capillaryelectrophoresis–ICP-mass spectrometry. Journal of Chromatography A, 2004, 1050:69-76.
[159] Mercedes Quintana, Alkisti D. Klouda, Maria Ochsenk-uhn-Petropoulou etc.Size characterization of manganese species from liver extracts using size exclusion chromatography inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 2005, 554: 130-135.
[160]王艳华,许梓荣.锰的生物学作用及螯合锰在畜牧生产上的研究与应用.饲料博览,2002,1:15-17.
[161]Staden J.F.van, Mulaudzi L.V., StefanR.I.. Speciation of Mn(II) and Mn(VII) by on-line spectrophotometric sequential injection analysis. Analytica Chimica Acta, 2003, 499:129-137.
[162] Mercedes Quintana, Alkisti D. Klouda, Andrew Gondikas etc. Analysis of size characterized manganese species from liver extracts using capillary zone electrophoresis coupled to inductively coupled plasma mass spectrometry (CZE-ICP-MS). Analytica Chimica Acta, 2006, 573-574:172-180.
[163]薛爱芳,钱沙华,黄淦泉.交联壳聚糖富集分离火焰原子吸收法测定环境样品中微量锰.环境科学与技术,2000,4:32-34.
[164]吴旺喜,金泽祥,刘汉东等.土壤中锰的形态分析方法研究.理化检验-化学分册,2003,39(2);99-101.
[165]刘桂华,汪丽.HPLC-ICP-MS在紫菜中砷形态分析的应用.分析测试学报,2002,21(4):88-90.
[166]Wang Ruohyun, Hsu Yingling, Chang Lanfang etc. Speciation analysis of arsenic and selenium compounds in environmental and biological samples by ion chromatography–inductively coupled plasma dynamic reaction cell mass spectrometer. Analytica Chimica Acta, 2007, 590:239-244.
[167]Mary Kate Donais, Rob Hery, Tom Rettberg. Chromium speciation using an automated liquid handling system witn inductively coupled plasma-mass spectrometric detection. Talanta, 1999, 49:1045-1050.
[168] B’Hymer C., Caruso J.A.. Selenium speciation analysis using inductively coupled plasma-mass spectrometry. Journal of Chromatography A, 2006, 1114:1-20.
[169]杨仕清,张怀武.纳米材料科学的研究现状和展望.电子科技导报,1995,11:2-5.
[170]刘演兵,韩恒斌.砷形态分析方法研究进展.环境科学进展,1994,2(4):1-14.
[171]张普敦,许国旺,魏复盛.砷形态分析方法进展.分析化学评述与进展,2001,29(8):971-977.
[172]杨瑞瑛,朱旭萍.APDC-CCl4对As(Ⅲ)和As(Ⅴ)的萃取行为研究.核化学与放射化学,1997,19(2):61-64.
[173]吴少尉,史建波.HPLC-HG-AFS测定As(Ⅲ)和As(Ⅴ)的方法研究.湖北民族学院学报(自然科学版),2003,21(4):54-56.
[174]Chen Zuliang, Kazi Farzana Akter, Mohammad Mahmudur Rahman. The separation of arsenic species in soils and plant tissues by anion-exchange chromatography with in ductively coupled mass spectrometry using variousmobile phases. Microchemical Journal, Available online 1 November 2007.
[175] Daniel Sa′nchez-Rodas, Jose′Luis Go′mez-Ariza, Inmaculada Gira′ldez. Arsenic speciation in river and estuarine waters from southwest Spain. Science of the Total Environment, 2005, 345:207-217.
[176]Zhang Liang, Yukitoki Morita, Akio Sakuragawa. Inorganic speciation of As(III,V), Se(IV,VI) and Sb(III,V) in natural water with GF-AAS using solid phase extraction technology. Talanta, 2007, 72: 723-729.
[177]Kritsana Jitmanee, Mitsuko Oshima, Shoji Motomizu. Speciation of arsenic(III) and arsenic(V) by inductively coupled plasma-atomic emission spectrometry coupled with preconcentration system. Talanta, 2005, 66:529-533.
[2]陈文君,吴政宙,卢志琴.液液萃取-分光光度法测定三溴苯酚中铁.理化检验-化学分册,2006,42(10):859-859.
[3]武宇红,孟哲,廖询等.液液萃取饮料中甲苯GC/MS测定方法的研究.河北农业大学学报,2006,29(5):57-59.
[4]郁建栓.固相萃取-气相色谱/质谱法测定地面水中半挥发性有机物.岩矿测试,2006,25(4):331-333.
[5]Nilgun Tokman, Suleyman Akman. Determination of bismuth and cadmium after solid-phase extraction with chromosorb-107 in a syringe.Analytica Chimica Acta, 2004, 519(1):87-91.
[6]Franco A. Bertolino, Angel A. J. Torriero, Eloy Salinas etc. Speciation analysis of selenium in natural water using square-wave voltammetry after preconcentration on activated carbon. Analytica Chimica Acta, 2006, 572:32-38
[7]王海林,钱沙华,汪玉庭等.交联壳聚糖富集分离冷原子吸收分光光度法测定环境水样中痕量无机汞.分析化学研究学报,1997,25(8):893-897
[8]Santha V., Ketavarapu Yathavakilla, Monika Shah etc. Speciation ofcationic selenium compounds in Brassica juncea leaves by strong cation-exchange chromatography with inductively coupled plasma mass spectrometry. Journal of Chromatography A, 2005, 1100(2):153-159.
[9] Kristina Hennebrüder, Rainer Wennrich, Jürgen Mattusch etc. Determination of gadolinium in river water by SPE preconcentration and ICP-MS. Talanta, 2004, 63(2):309-316.
[10]张彦斌,程忠洲,李华.硫脲树脂富集-电感耦合等离子体质谱法测定地质样品中的超痕量金、银、铂、钯.分析试验室,2006,25(7):105-108.
[11]苏耀东,郝冰冰,秦立俊等.8-羟基喹啉快速共沉淀分离富集原子吸收光谱法测定啤酒中的Cu和Pb.光谱学与光谱分析, 2007, 3(27):589-591.
[12]殷忠,黄培林,李雪春.用硝酸铋共沉淀分离富集的火焰原子吸收法测定酱油中微量铅的方法研究.现代预防医学,2007,34(1):117-119.
[13]赵可江,王新军,赵亮等.偕胺肟基纤维对金属离子选择吸附性能研究.黄金,2008,29(1):52-56.
[14]王照丽,肖新峰,罗娅君等.螯合树脂浓缩柱预富集低压离子色谱分光光度法测定海水中痕量铅.分析测试学报,2007,26(2):221-224.
[15]朱永春,李丹,岳爽等.超声波-微分脉冲伏安法测定超痕量铜.分析化学研究简报,2006,34(5):721-724.
[16]王玉宝,陈玉静,唐清华等.离子交换纤维分离富集催化光度法测定痕量铬(Ⅵ).理化检验-化学分册,2007,43(12):1085-1087.
[17]胡瑜,杨亚玲,胡礼鸣等.阳离子树脂微柱-孔雀石绿分光光度法测化妆品中的铅.分析试验室,2007,26:165-167.
[18]付颖,王常波,叶非.固相微萃取技术在农药残留分析中的应用.理化检验-化学分册,2006,42(10):865-870.
[19] Mester Z., Sturgeon R., Pawliszyn J.. Review Solid phase microextraction as a tool for trace element speciation. Spectrochim.Acta, 2001, 56B:233-260.
[20]杨骥,郭锐,彭娟等.应用活性炭纤维型固相微萃取器定量分析化妆品中的甲醇.环境化学,2005,24(5):620-621.
[21] Dimitra A.L., Triantafyllos A.A., Liquid-phase micro-extraction techniques in pesticide residue analysis. Biochemical and Biophysical Methods, 2007, 70(2):195-228.
[22]张红,陈玲,陈皓等.液相微萃取技术及其在环境水样预处理中的应用.环境监测管理与技术,2004,16(6):8-11.
[23]Clàudia Fontàs, Núria Pont, Manuela Hidalgo etc. Separation and preconcentration of Cd(II) from chloride solutions using supported liquid membranes systems. Desalination, 2006, 200(3):114-116.
[24] Leyre Irigoyen, Carlos Moreno, Carolina Mendiguchía etc. Application of liquid membranes to sample preconcentration for the spectrometric determination of cadmium in seawater. Journal of Membrane Science, 2006, 274 (1):169-172.
[25]Farhadi K.,Teimouri G.. Flame atomic absorption determination of palladium in solutions after preconcentration using octadecyl silica membrane disks modified by thioridazine·HCl. Talanta, 2005, 65(4): 925-929.
[26]王仁才,欧阳建文,成智涛等.超临界流体萃取技术在果实功效成分提取中的应用.湖南农业大学学报:自然科学版,2006,32(2):225-228.
[27]金春英,林金清,李雯君.超临界流体萃取技术在中药提取中的应用与发展趋势.化学工程与装备,2006,6:48-51.
[28]周丽屏,郭璇华.超临界流体萃取技术及其应用.现代仪器,2006,4:18-21.
[29]黄焱,秦炜,戴猷元.浊点萃取技术及其在分离过程中的应用.现代化工,2006,26:307-311.
[30]黄晖,陈培珍.浊点萃取技术在痕量金属离子测定中的应用.三明高等专科学校学报,2004,21(4):66-71.
[31]Lemos V.A., da Fran?a R.S., Moreira B.O.. Cloud point extraction for Co and Ni determination in water samples by flame atomic absorption spectrometry. Separation and Purification Technology, 2007, 54(3): 349-354.
[32]Coelho L.M.,Arruda M.A.. Preconcentration procedure using cloud point extraction in the presence of electrolyte for cadmium determination by flame atomic absorption spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(5):743-748.
[33] Marcos A. B., Roy E. B., Sergio L.C. Ferreira.. Statistical design-principal component analysis optimization of a multiple response procedure using cloud point extraction and simultaneous determination of metals by ICP -OES. Analytica Chimica Acta, 2006, 580(2):251-257.
[34]彭岚,谈明光,李玉兰等.微波辅助萃取-液质联用技术测定底泥砷、硒的化学形态.分析实验室,2006,25(5):10-14.
[35]Liang Pei, Liu Rui. Speciation analysis of inorganic arsenic in water samples by immobilized nanometer titanium dioxide separation and graphite furnace atomic absorption spectrometric determination. Anal. Chim. Acta, 2007, 602:32-36.
[36]梁沛、李春香、秦勇超等.纳米二氧化钛分离富集和ICP-AES测定水样中Cr (Ⅲ)/Cr (Ⅵ).分析科学学报,2000,l6(4):300-303.
[37]谷学新,邹洪,朱若华.分析化学中的分离技术.分析试验室,2001,20(3):96-98.
[38]曹华丽,闫永胜,赵干卿等.离子交换树脂预浓集薄层树脂相分光光度法测定水中铬(Ⅵ)和铬(Ⅲ).冶金分析,2006,26(5):72-74.
[39]唐索寒,朱祥坤.AGMP-1阴离子交换树脂元素分离方法研究.高校地质学报,2006,12(3):398-403.
[40]Zhu Yanbei, Itoh Akihide, Eiji Fujimori etc. Determination of rare earth elements in seawater by ICP -MS after preconcentration with a chelating resin -packed minicolumn. Journal of Alloys and Compounds, 2006, 408(2):985-988.
[41] Dwinna Rahmi, Zhu Yanbei, Eiji Fujimori etc. Multielement determination of trace metals in seawater by ICP -MS with aid of down-sized chelating resin-packed minicolumn for preconcentration. Talanta, 2007, 72(2):600-606.
[42] Wu Yiwei, Jiang Zucheng, Hu Bin.Speciation of vanadium in water with quinine modified resin micro-column separation/preconcentration and their determination by fluorination assisted electrothermal vaporization(FETV)–inductively coupled plasma optical emission spectrometry ( ICP -OES). Talanta, 2005, 67(4):854-861.
[43] Katarina Rosi Ketrin, Toshio Takayanagi, Mitsuko Oshima etc. Synthesis of a chitosan-based chelating resin and its application to the selective concentration and ultratrace determination of silver in environmental water samples. Analytica Chimica Acta, 2006, 558(2): 246-253.
[44]李正罡,王义,张敏.DCS-偶氮胂树脂相分光光度法测定牧草中的微量稀土.稀土,2001,22(5):40-41.
[45]江放明,周方钦等.聚乙烯-双硫腙复膜树脂分离富集/原子吸收法测定地质样品中的痕量金.分析科学学报,2006,22(1):34-36.
[46]马桂云,孙开进,王京平等.双硫腙负载树脂对铅和镉的吸附性能研究.化学世界,2006,12:726-729.
[47]张凯,鲍长利,李增文等.双硫腙螯合形成树脂分离富集地质样品中的微量金、铂、钯及其测定.分析化学,1997,25(4):404-407.
[48]Ferreira S.L.C., Brito C.F., Dantas A.F.. Nickel determination in saline matrices by ICP-AES after sorption on Amberlite XAD-2 loaded with PAN. Talanta,1999, 48:1173-1177.
[49] Molodovan Z., Vladscu L.. Preparation, characterization and metal sorption studies of a Chrome-Azuro-S-loade danion-exchange resin. Talanta, 1996, 43:1573-1577.
[50]郭嘉,陈延林,罗晔等.新型离子交换纤维的应用研究及展望.高科丝纤谁与应用,2005,30(6):35-38.
[51]Wen Bei, Shan Xiaoquan, Lian Jun. Separation of Cr(III) and Cr(VI) in river and reservoir water with 8-hydroxyquinoline immobilized polyacrylonitrile fiber for determination by inductively coupled plasma mass spectrometry. Talanta, 2002, 56(4):681-687.
[52]张华,逯阳,肖长发.载双硫腙螯合纤维制备及富集重金属离子研究.离子交换与吸附,2005,21 (5):468-473.
[53]杨秀政.多胺螯合纤维预富集FAAS对水体中铅的形态分析.分析试验室,2007,26(1):102-104.
[54]Tang bo,Zhang hui, Wang yan. On-line separation, preconcentration and determination of trace amounts of gold in mineral sample by flow injection catalytic kinetic spectrofluorimetry . Analytica Chimica Acta, 2004, 525(2):305-311.
[55]李慧芝,赵淑英.聚酰胺分离富集催化动力学电位法测定痕量钯.分析科学学报,2005,21(6):652-654.
[56]解文秀,李慧芝,韩斌.聚酰胺分离富集发射光谱法同时测定金、铂和钯.光谱实验室,2005,22(1):62-65.
[57]李承元,李蓉,赵刚等.负载泡沫塑料富集发射光谱测定化探样品中痕量金、铂、钯.黄金,2005,26(12):48-50.
[58]林智辉,王英滨,黄文辉.聚氨酯泡沫塑料富集-电感耦合等离子体质谱法测定地质样品中痕量铂和钯.理化检验-化学分册,2005,41(5):321-323.
[59]Lemos V.A., Santos M.S., Santos E.S etc. Application of polyurethane foam as a sorbent for trace metal preconcentration-a review. SpectrochimicaActa Part B: Atomic Spectroscopy, 2007, 62(1):4-12.
[60]王丽敏,宋闯,金晶.熔融萘萃取铁(Ⅱ)-4,7-二苯基-1,10-菲啰啉-四苯硼酸盐三元络合物光度法测定铁.分析试验室,2004,23 (9) :48-50.
[61] Sharma R.K.. Solid-phase extraction of trace metal ions using low-melting extractants. Microchem. J., 1995, 51:289-311.
[62]范哲锋,杜黎明.微晶萘固相萃取ICP-AES法测定地质样品中的痕量铟.分析试验室,2000,19(3):63-64.
[63] Fan Zhefeng, Hu Bin, Jiang Zucheng. Speciation analysis of vanadium in natural water samples by electrothermal vaporization inductively coupled plasma optical emission spectrometry after separation/preconcentration with thenoyltrifluoroacetone immobilized on microcrystalline naphthalene. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(1):65-71.
[64]Xiong Chaomei, Jiang Zucheng, Hu Bin. Speciation of dissolved Fe(II) and Fe(III) in environmental water samples by micro-column packed with N-benzoyl-N-phenylhydroxylamine loaded on microcrystalline naphthalene and determination by electrothermal vaporization inductively coupled plasma-optical emission spectrometry. Analytica Chimica Acta, 2006, 559(1):113-119.
[65]Zhu Xiangbing, Chang Xijun, Cui Yuemei etc. Solid-phase extraction of trace Cu(II) Fe(III) and Zn(II) with silica gel modified with curcumin from biological and natural water samples by ICP-OES. Microchemical Journal,2007, 86(2):189-194.
[66]Chang Xijun, Jiang Na, Zheng Hong etc. Solid-phase extraction of iron(III) with an ion-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique. Talanta, 2007, 71(1):38-43.
[67]樊静,秦玉霞,冯素玲等.二苯卡巴腙键合硅胶的制备及对废水中重金属的分离与富集.分析化学,2005,33(8):1151-1154.
[68]杨朝勇,吴熙鸿等.碳18键合硅胶柱-流动注射-电感耦合等离子体质谱联用技术及其在海水分析中的应用.分析化学,2001,29(3),283-286.
[69]Dressler V.L., Pozebon D., Curtius A. J.. Determination of Ag, Te, U and Au in waters and in biologicalsamples by FI–ICP-MS following on-line preconcentration. Anal.Chim.Acta, 2001, 438:235-244.
[70]叶映雪.流动注射固相预富集原子吸收光谱法测定铁和钴.光谱实验室,2000,17(4):459-462.
[71]张俊刚.可控孔径多孔玻璃微珠的研制及其吸附性能的研究:[硕士学位论文].吉林长春:长春理工大学,2002.
[72]Amarildo Otavio Martins, Edson Luiz da Silva, Eduardo Carasek etc. Chelating resin from functionalization of chitosan with complexing agent 8-hydroxyquinoline: application for metal ions on line preconcentration system. Analytica Chimica Acta, 2004, 521(2):157-162.
[73]Ebru Birlik, Arzu Ers?z, Adil Denizli. Preconcentration of copper using double-imprinted polymer via solid phase extraction. Analytica Chimica Acta, 2006, 565(2),145-151.
[74]Tang Y.W.,Chen B.R.,Mo S,J.. Separation and preconcentration ofultratrace lead in biological organisms and its determination by graphite furnace atomic absorption spectrometry. Talanta, 1996, 43:761-765.
[75]纪志永,李鑫钢,孙津生.炭材料在水污染修复领域的应用研究.材料导报,2006,20(7):84-87.
[76]王爱霞,郭黎平,张宏.活性炭微柱在线流动注射预富集-火焰原子吸收快速顺序测定铜、钴、镍、镉、铅的研究.分析化学,2005,33(3):385-388.
[77]吴惠明,李锦文,陈永亨.活性炭吸附分离-8-羟基喹啉紫外分光光度法测定铊.化学试剂,2006,28(9):547-548.
[78] Takara E. A., Pasini-Cabello S. D., Cerutti S. etc. On-line preconcentration/determination of copper in parenteral solutions using activated carbon by inductively coupled plasma optical emission spectrometry. Journal of Pharmaceutical and Biomedical Analysis, 2005, 39(3):735-739.
[79] Mehrorang Ghaedi, Farshid Ahmadi, Ardeshir Shokrollahi. Simultaneous preconcentration and determination of copper, nickel, cobalt and lead ions content by flame atomic absorption spectrometry. Journal of Hazardous Materials, 2007, 142(1):272-278.
[80]Barbara Miku?a, Bo?ena Puzio. Determination of trace metals by ICP-OES in plant materials after preconcentration of 1,10-phenanthroline complexes on activated carbon. Talanta, 2007, 71(1):136-140.
[81]李永贵,赵苗,梁继.国内活性炭纤维的应用研究与开发.纺织学报,2006,27(6):100-103.
[82]杨健松,李玉峰,赖奇.膨胀石墨的研究与开发利用.攀枝花学院学报:综合版,2006,23(6):99-102.
[83]Filho N.L.D., Gushikem Y.,Polito W.L.. 2-Mercaptobenzothiazole clay as matrix for sorption and preconcentration of some heavy metals from aqueous solution. Anal.Chim.Acta, 1995, 306:167-172.
[84]Towler P.H., Smith J,D.,Dixon D.R.. Magnetic recovery of radium, lead and polonium from seawater samples after preconcentration on a magnetic adsorbent of manganese dioxide coated magnetite. Anal. Chim. Acta, 1996, 328:53-59.
[85] Hiraide M.,Iwasawa J., Kawaguchi H.. Collection of trace heavy metals complexed with ammonium pyrrolidinedithiocarbamate on surfactant-coated alumina sorbents. Talanta, 1997, 44:231-237.
[86]黄志英,李惕川,齐振光.流动注射在线预浓集原子吸收光谱分析废水中的Cd~(2+)、Fe~(3+)、Zn~(2+).离子交换与吸附,1996,12:27-33.
[87]张兆春,刘振学,牛富玲.活性矸对硫、氟、铬阴离子吸附的研究.环境科学,1996,15(5):415-419.
[88]李永宏,王尚义,郑玉霞.浅谈对富勒烯的认识及应用.内蒙古石油化工,2006,32(8):16-17.
[89]Barbara A.Le?niewska, Iwona Godlewska.The study of applicability of dithiocarbamate-coated fullerene C60 for preconcentration of palladium for graphite furnace atomic absorption spectrometric determination in environmental samples. Spectrochimica Acta Part B: Atomic Spectroscopy, 2005, 60(3):377-384.
[90] Pereira M.G., Pereira-Filho E.R., Berndt H..Determination of cadmium and lead at low levels by using preconcentration at fullerene coupled to thermospray flame furnace atomic absorption spectrometry. Spectrochimica Acta Part B: Atomic Spectroscopy, 2004, 59(4):515-521.
[91]Mu?oz J.,Gallego M., Valcárcel M.. Speciation analysis of mercury and tin compounds in water and sediments by gas chromatography–mass spectrometry following preconcentration on C60 fullerene. Analytica Chimica Acta, 2005, 548(1):66-72.
[92]Adriano Francisco Barbosa,Mariana Gava Segatelli,Arnaldo César Pereira,etc. Solid-phase extraction system for Pb (II) ions enrichment based on multiwall carbon nanotubes coupled on-line to flame atomic absorption spectrometry. Talanta, 2007, 71( 4):1512-1519.
[93]刘艳.纳米材料在痕量元素分离富集及形态分析中的应用:[硕士学位论文].湖北武汉:华中师范大学,2005.
[94]赵稼祥.纳米碳纤维及其应用.纤维复合材料,2003,20(4):48-50.
[95]Chen Shizhong, Xiao Mingfa, Lu Dengbu etc.Use of a microcolumn packed with modified carbon nanofibers coupled with inductively coupled plasma mass spectrometry for simultaneous on-line preconcentration and determination of trace rare earth elements in biological samples. Rapid Communication in Mass Spectrometry, 2007, 21:2524-2528.
[96]Chen Shizhong, Xiao Mingfa, Lu Dengbu etc.Preconcentration and separation of gold and palladium in geological samples via solid-Phase extraction on carbon nanofibers prior to sample analysis by ICP-MS.Atomic Spectroscopy, 2007, 28(3):90-94.
[97]肖亚兵,钱沙华等.纳米二氧化钛对砷(Ⅲ)和砷(Ⅴ)吸附性能的研究.分析科学学报,2003,19(2):172-174.
[98] Beard H.C., Lyerlyl A.. Separation of arsenic fromantimony and bismuth by solvent extraction. Anal. Chem, 1961, 33(12):1781-1782.
[99]Zhang X., Vanderbiesen V., Cubber A.D. . Accumulation of arsenic species in serumof patients with chronic renaldisease. Clin. Chem., 1996, 42(8):1231-1237.
[100]陈历程,张勇.微量元素硒的研究现状及其食品强化.食品科学,2002,23(10):134-137.
[101]黄峙.食品硒源的生物学研究进展.食品科学,2001,22(5):90-94.
[102]刘国珍,金泽祥.汞的形态分析进展.理化检验-化学分册,2000,36(1):38-41.
[103]郑徽,金银龙.汞的毒性效应及作用机制研究进展.卫生研究,2006,35(5):663-666.
[104] Morita Y., Kobayashi T., Kuroiwa T. etc. Study on simultaneous speciation of arsenicand antimony by HPLC–ICP-MS. Talanta, 2007, 73:81–86.
[105]Ronkart S.N., Laurent V., Carbonnelle P. etc. Speciation of five arsenic species (arsenite, arsenate, MMAAV, DMAAV and AsBet) in different kind of water by HPLC-ICP-MS. Chemosphere, 2007, 66:738-745.
[106]Duarte F.A., Pereira J.S.F., Mesko M.F. etc. Evaluation of liquid chromatography inductively coupled plasma massspectrometry for arsenicspeciation in water from industrialtreatment of shale. Spectrochimica Acta Part B, 2007, 62: 978-984.
[107] Nina Ulrich. Speciation of antimony(Ⅲ), antimony(Ⅴ) and trimethylstiboxide by ion chromatography with inductively coupled plasma atomic emssion spectrometric and mass spectrometric detection. Anal.Chim.Acta, 1998, 359:245-253.
[108]Li Feng, Wang Dongdong, Yan Xiuping etc. Speciation analysis of inorganic arsenic by microchip capillaryelectrophoresis coupled with hydride generation atomic fluorescence spectrometry. Journal of Chromatography A, 2005, 1081:232-237.
[109]顾文奎,慕毓,陈文杰.气相色谱及其联用技术在环境有机锡化合物分析中的应用.环境与健康杂志,2006,23(5):478-480.
[110]赵亮,朱霞石,封克等.纳米二氧化钛分离/富集-石墨原子吸收光谱法测定环境样品中痕量镉.分析化学(FENXIHUAXUE)研究简报,2006,34:S223-S226.
[111]罗津新.TBP萃淋树脂分离GFAAS法测定水与废水中的铬(Ⅲ)和铬(Ⅵ).中国环境监测,1999,15(4):36-38.
[112]叶映雪.流动注射固相萃取预富集原子吸收光谱测定铁的价态.分析测试技术与仪器,2000,6(1):31-33.
[113]姜健生.交联壳聚糖在锑形态分析中的应用.分析测试学报,1998,17(4):1-4.
[114]吴旭,翁明,肖亚兵等.纳米二氧化钛富集石墨炉原子吸收光谱法测定环境水样中痕量锑.分析科学学报,2004,20(4):376-380.
[115]孔庆安,吴奇藩,林罗发等.活性氧化铝富集火焰原子吸收法测定铬(Ⅲ)和铬(Ⅵ).分析测试学报,1996,15(4):74-76.
[116]李顺兴,钱沙华.固氮蓝藻分离富集石墨炉原子吸收光谱法测定痕量铬(Ⅲ)和铬(Ⅵ).分析科学学报,1995,11(1):42-46.
[117]喻德忠,邹菁,艾军.纳米二氧化锆对砷(Ⅲ)和砷(Ⅴ)的吸附性质研究.武汉化工学院学报,2004,26(3):21-24.
[118] Coelho N.M.M., Coelho L.M., Lima E.S. etc. Determination of arsenic compounds in beverages by high-performance liquid chromatography-inductively coupled plasma mass spectrometry. Talanta, 2005, 66:818-822.
[119]Hirata S., Honda K., Shikino O. etc. Determination of chromium(III) and total chromium in seawater by on-line column preconcentration inductively coupled plasma mass spectrometry. Spectrochimica Acta Part B, 2000, 55:1089-1099.
[120]袁东星等.流动注射小柱预富集-石墨炉原子吸收联用分析茶汤和水样中不同形态的铝.厦门大学学报,1998,37(1):80-87.
[121]李玉珍,陈德勋.环境样品中铝的形态分析.岩矿测试,1999,18(4):241-245.
[122]Abollino O., Aceto M., Sarzanini C., Mentasti E.. The retention of metal species by different solid sorbents mechanisms for heavy metal speciation by sequential three column uptake. Anal.Chim.Acta, 2000, 411:223-237.
[123]罗明标,毕树平.阳离子交换树脂分离-铝试剂分光光度法测定土壤中铝形态.分析科学学报,2004,20(2):113-116.
[124]吴庆梅,康清蓉,郑坚等.连续流动冷原子吸收光谱法测定鱼体中总汞、无机汞和有机汞.光谱实验室,2007,24(2):103-105.
[125] Robles L.C., Feo J.C.,Aller A.J., Selective preconcentration of phenyl-mercury by living Escherichia coli and its determination by cold vapour atomic absorption spectrometry. Anal.Chim.Acta, 2000, 423:255-263.
[126]黄国清,彭珊珊.食用花卉中微量元素Fe的可溶性有机态和无机态研究.食品工业科技,2004,20(2):113-116.
[127]Bardy M., Bonhomme C., Fritsch E.. Al speciation in tropical podzols of the upper Amazon Basin: A solid-state 27Al MAS and MQMAS NMR study. Geochimica et Cosmochimica Acta. 2007, 71: 3211-3222.
[128]张勇,唐元洪,裴立宅等.纳米碳纤维的批量制备和应用.高科技纤维与应用,2005,30(2):20-25.
[129]余雯,刘日利,潘春旭.热氧化法制备ZnO纳米针的微结构与场发射性质研究.电子显微学报,2006,25(B08):40-41.
[130]陈东,陈廉,刘实等.新型复合材料Mg/ MWNTs的储放氢性能.中国有色金属学报,2003,13(4):850-855.
[131]朱相丽.纳米复合材料的研究进展.新材料产业,2006,11,57-60.
[132]陈煜,唐亚文,周益民等.碳纳米管作燃料电池催化剂载体的研究进展.电池,2006,36(1):71-73.
[133]祝宁宁.硫化铅纳米颗粒标记DNA电化学探针研究.上海师范大学学报(自然科学版),2004,33(2):65-69.
[134]赵稼祥.纳米碳纤维及其应用.高科技纤维与应用,2003,28(2):7-10.
[135]于立岩,张乾,崔作林.螺旋纳米碳纤维的制备与表征.高等学校化学学报,2005,26(1):5-8.
[136]顾书英,朱立华,藤新荣.纳米碳纤维的制备及应用.材料导报,2004, 18(4):86-88.
[137]张勇,唐元洪,裴立宅.纳米碳纤维制备方法的研究进展.炭材料科学与工艺,2005,15(1):33-37.
[138]曾艳.柱分离富集/等离子体质谱痕量元素及形态分析:[硕士学位论文].湖北武汉:武汉大学,2004.
[139]陈松涛,闫永胜,徐婉珍等.纳米TiO2预分离/富集FAAS法同时测定Cr (Ⅲ)和Cr (Ⅵ)的研究.光谱学与光谱分析,2007,5:1018-1020.
[140]张春丽,宋恩军,张东.纳米钛酸锶钡分离原子吸收法测定铬酸盐转化膜中铬形态.电镀与精饰, 2007,5:48-51.
[141]Liang Pei, Shi Taqing, Lu Hanbing etc. Speciation of Cr (Ⅲ) and Cr (Ⅵ) by nanometer titanium dioxide micro-column and inductively coupled plasma atomic emission spectrometry. Spectrochimica Acta PartB: Atomic Spectroscopy, 2003, 58 (9):1709-1714.
[142] Jimmy C.Yu, Wu Xiu-Juan, Chen ZuLiang. Separation and determination of Cr(III) by titanium dioxide-filled column and inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 2001, 436:59-67.
[143]梁沛,江祖成,胡斌等.纳米二氧化钛材料对稀土络合物吸附性能的研究.中国稀土学报,2002,20(4):311-314.
[144]Hu Jing, Irene M.C.Lo, Chen Guohua. Performance and mechanism of chromate(VI) adsorption byδ-FeOOH-coated maghemite (γ-Fe2O3) nanoparticles. Separation and Purification Technology, 2007, 58:76-82.
[145]Suna Y.C.,Chen Y.J., Tsai Y.N.. Determination of urinary arsenic species using an on-line nano-TiO2 photooxidation device coupled with microbore LC and hydride generation-ICP-MS system. Microchemical Journal, 2007, 86:140-145.
[146] Cui Yuemei, Chang Xijun, Zhu Xiangbing etc. Nanometer SiO2 modified with 5-sulfosalicylic acid as selective solid-phase extractant for Fe (III) determination by ICP-AES from biological and natural water samples. Microchemical Journal, 2007, 86:23-28.
[147]刘二保,梁建功,韩素琴等.铬的形态分析研究与进展.理化检验-化学分册,2003,39(6):368-371.
[148]李艳廷,李方.环境中无机铬形态分析研究进展.化学研究与应用,2000,12(5):476-481.
[149] Ibrahim Narin, Ayse Kars,Mustafa Soylak. A novel solid phase extraction procedure on Amberlite XAD-1180 for speciation of Cr(III), Cr(VI) and total chromium in environmental and pharmaceutical samples. Journal of Hazardous Materials, 2008, 150: 453-458.
[150] Sadhan Pramanik, Sourav Dey, Pabitra Chattopadhyay. A new chelating resin containing azophenolcarboxylate functionality: synthesis, characterization and application to chromium speciation in wastewater. Analytica Chimica Acta, 2007, 584:469-476.
[151] Amauri A.Meneg′ario,Patricia Smichowski,Griselda Polla.On-line preconcentration and speciation analysis of Cr(III) and Cr(VI)using baker’s yeast cells immobilised on controlled pore glass. Analytica Chimica Acta, 2005, 546:244-250.
[152] Balarama Krishna M.V., Chandrasekaran K.,Sarva V. Rao etc. Speciation of Cr (III) and Cr (VI) in waters using immobilized moss and determination by ICP-MS and FAAS. Talanta, 2005, 65:135-143.
[153] Zhang Nan, Jibrin Sabo Suleiman, He Man etc. Chromium (III)-imprinted silica gel for speciation analysis of chromium in environmental water samples with ICP-MS detection. Talanta, 2008, 75: 536-543.
[154]张勇,唐元洪,裴立宅等.纳米碳纤维的批量制备与应用.高科技纤维与应用,2005,30(2):20-25.
[155]唐天地,陈久岭,李永丹.碳纳米纤维在浓硝酸-浓硫酸溶液中表面氧化对其负载的Pd-Pt催化剂颗粒分散状态的影响.高等学校化学学报,2006,27(1):129-133.
[156]肖明发,陈世忠,战锡林等.纳米碳纤维分离富集电感耦合等离子体质谱法测定地质样品中痕量Au.光谱学与光谱分析, 2008, 28(2):444-446.
[157] Angel Maquleira, Hayat A.M. Elmahadi, Rosa Puchades. Immobilized cyanobacteria for on-line tracemetal enrichment by flow injection atomic absorption. Anal. Chem., 1994, 350:387.
[158]Bernhard Michalke. Manganese speciation using capillaryelectrophoresis–ICP-mass spectrometry. Journal of Chromatography A, 2004, 1050:69-76.
[159] Mercedes Quintana, Alkisti D. Klouda, Maria Ochsenk-uhn-Petropoulou etc.Size characterization of manganese species from liver extracts using size exclusion chromatography inductively coupled plasma mass spectrometry. Analytica Chimica Acta, 2005, 554: 130-135.
[160]王艳华,许梓荣.锰的生物学作用及螯合锰在畜牧生产上的研究与应用.饲料博览,2002,1:15-17.
[161]Staden J.F.van, Mulaudzi L.V., StefanR.I.. Speciation of Mn(II) and Mn(VII) by on-line spectrophotometric sequential injection analysis. Analytica Chimica Acta, 2003, 499:129-137.
[162] Mercedes Quintana, Alkisti D. Klouda, Andrew Gondikas etc. Analysis of size characterized manganese species from liver extracts using capillary zone electrophoresis coupled to inductively coupled plasma mass spectrometry (CZE-ICP-MS). Analytica Chimica Acta, 2006, 573-574:172-180.
[163]薛爱芳,钱沙华,黄淦泉.交联壳聚糖富集分离火焰原子吸收法测定环境样品中微量锰.环境科学与技术,2000,4:32-34.
[164]吴旺喜,金泽祥,刘汉东等.土壤中锰的形态分析方法研究.理化检验-化学分册,2003,39(2);99-101.
[165]刘桂华,汪丽.HPLC-ICP-MS在紫菜中砷形态分析的应用.分析测试学报,2002,21(4):88-90.
[166]Wang Ruohyun, Hsu Yingling, Chang Lanfang etc. Speciation analysis of arsenic and selenium compounds in environmental and biological samples by ion chromatography–inductively coupled plasma dynamic reaction cell mass spectrometer. Analytica Chimica Acta, 2007, 590:239-244.
[167]Mary Kate Donais, Rob Hery, Tom Rettberg. Chromium speciation using an automated liquid handling system witn inductively coupled plasma-mass spectrometric detection. Talanta, 1999, 49:1045-1050.
[168] B’Hymer C., Caruso J.A.. Selenium speciation analysis using inductively coupled plasma-mass spectrometry. Journal of Chromatography A, 2006, 1114:1-20.
[169]杨仕清,张怀武.纳米材料科学的研究现状和展望.电子科技导报,1995,11:2-5.
[170]刘演兵,韩恒斌.砷形态分析方法研究进展.环境科学进展,1994,2(4):1-14.
[171]张普敦,许国旺,魏复盛.砷形态分析方法进展.分析化学评述与进展,2001,29(8):971-977.
[172]杨瑞瑛,朱旭萍.APDC-CCl4对As(Ⅲ)和As(Ⅴ)的萃取行为研究.核化学与放射化学,1997,19(2):61-64.
[173]吴少尉,史建波.HPLC-HG-AFS测定As(Ⅲ)和As(Ⅴ)的方法研究.湖北民族学院学报(自然科学版),2003,21(4):54-56.
[174]Chen Zuliang, Kazi Farzana Akter, Mohammad Mahmudur Rahman. The separation of arsenic species in soils and plant tissues by anion-exchange chromatography with in ductively coupled mass spectrometry using variousmobile phases. Microchemical Journal, Available online 1 November 2007.
[175] Daniel Sa′nchez-Rodas, Jose′Luis Go′mez-Ariza, Inmaculada Gira′ldez. Arsenic speciation in river and estuarine waters from southwest Spain. Science of the Total Environment, 2005, 345:207-217.
[176]Zhang Liang, Yukitoki Morita, Akio Sakuragawa. Inorganic speciation of As(III,V), Se(IV,VI) and Sb(III,V) in natural water with GF-AAS using solid phase extraction technology. Talanta, 2007, 72: 723-729.
[177]Kritsana Jitmanee, Mitsuko Oshima, Shoji Motomizu. Speciation of arsenic(III) and arsenic(V) by inductively coupled plasma-atomic emission spectrometry coupled with preconcentration system. Talanta, 2005, 66:529-533.