Lyocell竹纤维素纤维的制备及结构与性能的研究
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摘要
Lyocell纤维生产工艺是将纤维素直接溶解在N-甲基吗啉-N-氧化物(NMMO)的水溶液中,并通过特殊的干湿法纺丝制备再生纤维素纤维的绿色工艺。该工艺具有生产流程简单、先进环保、产品性能好等特点,可望逐渐取代污染严重的传统纤维素纤维生产工艺即粘胶工艺。
迄今为止,Lyocell纤维的生产主要以木浆粕为原料,由于木材受到土地资源、生长周期等因素的影响,远远不能满足Lyocell纤维生产的需求。而我国是世界产竹大国,竹子分布十分广泛,成材迅速,2-3年即可实现连续砍伐使用,符合可持续发展的要求,再加之竹子的主要成分也是纤维素,若能用竹子作为原料生产Lyocell纤维素纤维,不仅提供了一种较为廉价的原料,还为竹子的利用开辟了一条新的途径。此外,以竹子为原料生产的竹纤维素纤维除具有普通纤维素纤维的优点外,还可能被赋予竹子本身所具有的凉爽、顺滑、清香、抑菌以及负离子效应等特性。
目前国内外主要采用粘胶工艺制备再生竹纤维素纤维,而有关以竹纤维素浆粕为原料,采用Lyocell工艺纺制竹纤维素纤维,至今尚无文献报道,因此,本论文将对这一领域进行探索性的研究。
本论文首先采用铜氨粘度法、凝胶渗透色谱法(GPC)法及FTIR法等手段对几种竹浆粕的聚合度、相对分子质量分布、α-纤维素含量及其主要化学组分进行了分析,并与木浆粕进行了对比。结果表明:竹浆粕与木浆粕主要成分都为纤维素,但竹浆粕中含有较多的木质素以及少量的木浆粕中没有的物质。造纸级竹浆粕与纤维级竹浆粕相比,其聚合度较大,相对分子质量分布较宽,半纤维素含量较高。对这二种竹浆粕在NMMO·H2O溶剂体系中的溶解研究进一步表明,纤维级竹浆粕的溶解性能较好,相比之下,造纸级竹浆粕溶解较困难,因此,这类竹浆粕不宜直接作为纺丝用原料。
本论文还采用哈克控制应力流变仪对不同聚合度的竹纤维素/NMMO·H2O溶液的动态及稳态流变性能进行了研究。结果发现,动态流变方法可以预测竹纤维素的相对分子质量及其分布;随着竹纤维素平均聚合度的增大,竹纤维素/NMMO·H2O溶液的流动曲线上移,出现切力变稀的临界剪切速率向低值方向移动,溶液的非牛顿指数n下降,粘流活化能Eη、结构粘度指数Δη和零切粘度η0增加;经一定条件碱处理的竹纤维素/NMMO·H2O溶液的流变性能受竹纤维素原料的聚合度、α-纤维素含量(或半纤维素含量)及杂质含量等因素的影响。
在上述研究基础上,本论文选择出了合适的纤维级竹纤维素浆粕,采用Lyocell工艺纺制出了Lyocell竹纤维素纤维,并探讨了纺丝工艺对Lyocell竹纤维素纤维结构与性能的影响,结果发现:随着纺丝原液浓度的适当增加,纤维的力学性能改善;喷头拉伸比的提高,有利于Lyocell竹纤维素纤维的结晶度及取向度增加,相应地纤维的初始模量和断裂强度增大,而纤度和断裂伸长率下降;在固定喷丝拉伸比的情况下,随着纺丝速度的升高,Lyocell竹纤维素纤维的晶区取向基本不变、非晶区取向及结晶度增加,强度和初始模量增大、断裂伸长减小,而纤度几乎没有变化;随着凝固浴温度的上升,所得Lyocell竹纤维素纤维的结晶度、晶区取向度和初始模量上升,而纤维非晶区取向度、总取向度和强度则略有下降。另外,气隙长度对所制得的Lyocell竹纤维素纤维的力学性能也有一定的影响,在本论文研究范围内,较合适的气隙长度为5cm。
与此同时,为了降低Lyocell竹纤维素纤维的制造成本,本论文还采用60Coγ射线对聚合度较高的造纸级竹浆粕进行辐照处理,以期获得可纺性好的Lyocell工艺用竹纤维素浆粕,并对辐照处理前后的竹纤维素的平均聚合度、相对分子质量分布及超分子结构进行了表征。结果表明,辐照处理对竹纤维素中的α-纤维素含量和相对分子质量及其分布均有影响:当辐照吸收剂量较小时,高能射线主要作用于高相对分子质量的竹纤维素,因此,竹纤维素的聚合度随吸收剂量的增加而迅速降低,但α-纤维素含量并无明显变化;当吸收剂量达到15kGy以上后,聚合度的下降趋势变缓,而α-纤维素含量逐渐降低;辐照处理后,高相对分子质量的竹纤维素分子数明显减少,相对分子质量分布变窄;此外,WAXD及FTIR的分析结果显示,辐照前后的竹纤维素的结晶变体都属于纤维素Ⅰ,且结晶度及晶粒尺寸也均无明显变化,表明在本研究的辐照吸收剂量范围内,经辐照的竹纤维素的结晶结构未被破坏。根据聚合度与吸收剂量之间的关系进一步推导出其G(s)值为0.94μmol·J-1,表明竹纤维素是一种比较容易辐照降解的聚合物,采用辐照方法处理竹纤维素是经济可行的。这种方法不仅解决了造纸级竹浆溶解困难、纺丝液浓度低的问题,而且使竹纤维素的可纺性明显改善,所制得的Lyocell竹纤维素纤维性能满足服用纤维的要求。
通过对Lyocell竹纤维素纤维服用性能与常规Lyocell纤维及粘胶法竹纤维素纤维的对比研究,发现Lyocell竹纤维与常规Lyocell纤维一样,具有光滑的表面及接近圆形的截面,易发生原纤化,其结晶度、强度和模量均远高于粘胶法竹纤维素纤维,湿态下力学性能损失也较小。另外,Lyocell竹纤维素纤维不仅吸湿性、染色性和抗原纤化能力均优于常规Lyocell纤维,还具有明显的负离子效应及天然抑菌性。采用KES织物风格仪对纤维面料的测试结果进一步显示,Lyocell竹纤维素纤维面料的滑爽度、柔软性、抗拉伸及抗压缩性能都比常规Lyocell纤维织物好,表明其具有较好的服用性能。
Lyocell process is a simple and environmental-friendly process for the production of regenerated cellulose fiber.It adopts N-methylmorpholine-N-oxide monohydrate (NMMO·H_2O),a non-toxic solvent,to directly dissolve cellulose and then uses a dry-jet wet spinning method to spin the fiber.In the process,no derivatization,such as alkalization and xanthation in the case of viscose fibers,is required.Furthermore, Lyocell fibers are distinguished by high crystallinity,high degree of orientation,and well-oriented amorphous regions,resulting in a very high dry and wet tensile strength, a high wet modulus and high loop tenacity.
Due to the restriction of wood resource in China,using wood as main raw material of Lyocell fiber could not meet demand for Lyocell fiber.However,bamboo resource is abundant in our country.If Lyocell fibers could be made from bamboo,it not only provides a cheap material for Lyocell fiber but also exploits a new application of bamboo.Moreover,compared to the fibers from cotton and wood,bamboo cellulose fiber made from bamboo has significantly different properties,such as good drapability,good dyeing property,soft,cool,comfortable feelings,and lustrous looking,etc.
So far,regenerated bamboo cellulose fiber was prepared by viscose process at home and abroad.Lyocell Fibers made from bamboo cellulose has not been reported yet. Hence,exploratory researches on bamboo Lyocell fiber were done in this paper.
Firstly,the bamboo pulps were analyzed and characterized by viscosimetry method, gel permeation chromatography(GPC) and Fourier transform infrared spectroscopy (FTIR) and the results were compared with wood pulp.It was found from the FTIR spectra that bamboo pulp was mainly consist of cellulose,same as wood pulp,but contained higher lignin than wood pulp and a little unknown substances which didn't exist in wood pulp,the paper grade bamboo pulp had higher DP,broader MWD and higher content of hemicellulose than that of fiber grade bamboo pulp.Furthermore,the study of bamboo pulp with different DP dissolved in NMMO·H_2O showed that the dissolving property of the paper grade bamboo pulp with high DP exhibited more inferior than that of the fiber grade bamboo pulp.Therefore,the paper grade bamboo pulp could not be directly used as raw material for producing Lyocell fiber.
Bamboo cellulose/NMMO·H_2O solutions were prepared by dissolving bamboo celluloses with different DP in NMMO·H_2O and the rheological behaviors of these solutions were investigated with HAAKE RS150L rheometer.The results showed that bamboo cellulose spinning dopes were shear thinning fluids.With the increase of the average degree of polymerization of bamboo cellulose pulps,the flow curves moved upward,the critical shear rate and the non-Newtonian index(n) decreased,while the apparent viscosity,the viscous flow activation energy,the zero shear viscosity and the structural viscosity index increased.With the increase of temperature,the apparent viscosity decreased,the non-Newtonian index increased.Moreover,the rheological behaviors of the alkali treated bamboo cellulose/NMMO·H_2O solutions were affected by the average degree of polymerization of bamboo cellulose,the content of hemicellulose and impurity in the pulp.In addition,the comparison of the results from theological data and GPC showed that it was feasible to predict the MW and MWD of cellulose by using rheological method.
On basis of aforementioned investigations,the fiber grade bamboo pulp was preferentially selected as raw material for preparing bamboo Lyoccell fiber,bamboo Lyocell fiber was preparing with this pulp by Lyocell process in our laboratory and the influence of spinning parameters on structure and property of bamboo cellulose fiber were systemically investigated.The results showed that the spin parameters had greatly effected on the structures and properties of bamboo Lyocell fiber.Firstly,the mechanical property of the fiber enhanced with the increase of the cellulose concentration in spinning dope.Secondly,the crystallinity and orientation of bamboo Lyocell fiber increased and accordingly the tensile strength and initial modulus increased with the increase of draw down ratio,whereas the linear density and elongation at break decreased with the increase of draw down ratio.When the draw ratio was kept constant,the higher the spinning speed,the higher the orientation in amorphous region and crystallinity,the higher the tensile strength and initial modulus will be,while the orientation in crystalline region and the linear density were not changed basically.In addition,the crystallinity,orientation in crystalline region and initial modulus increased and the orientation in amorphous region,total orientation and tensile strength slightly decreased with the increase of the temperature of coagulation bath.Moreover,the gap length also affects the mechnical properties of the fiber and the optimum gap length is 5 cm.
Generally speaking,paper grade bamboo pulp has high molecular weight,it is difficult to be dissolved in N-methylmorpholine-N-oxide monohydrate(NMMO·H_2O). In order to reduce its molecular weight,improve its dissolving property in NMMO·H_2O and obtain the cheap bamboo pulp with good spinnability for Lyocell process,the paper grade bamboo pulp was irradiated in air by ~(60)Coγ-ray,then the molecular weight(MW) and the molecular weight distribution(MWD) of the irradiated bamboo cellulose were measured by viscosimetry and gel permeation chromatography (GPC),and the crystalline structure was studied by Fourier transform infrared spectroscopy(FTIR) and wide angle X-ray diffraction(WAXD).The results showed that the average degree of polymerization((?)) of the irradiated bamboo cellulose decreased and its MWD became narrow continuously with the increase of absorbed dose,the most significant degradation of the bamboo cellulose took place in the range of the absorbed dose up to 15kGy.However,the results from WAXD and FTIR showed that the crystalline structure such as crystallinity and crystalline form did not change obviously,and this implies that the crystalline structures of the bamboo cellulose were not destroyed in our case.It could be deduced from the relationship between(?) and absorbed doses(D) that G(s) of the bamboo cellulose was 0.94μmol·J~(-1),which indicated that the bamboo cellulose was easily degraded by ~(60)Coγ-ray radiation. Therefore,it was possible economically to degrade the bamboo cellulose by irradiation. Furthermore,it was found from spinning experiment that the dissolving property and the spinnability of the irradiated bamboo cellulose was remarkably improved and that the fiber made from the bamboo cellulose could be applied in apparel industry.
The comparison of the wear behavior of bamboo Lyocell fiber and the other regenerated cellulose fiber was carried out.The results showed that the bamboo Lyocell fiber had many similarities in structure and properties compared with the conventional Lyocell fiber,such as smooth surface,approximate circular cross section, and easy fibrillation,its crystallinity,tensile strength and initial modulus are higher than the bamboo viscose fiber,its ratio of wet tensile strength to dry tensile strength is higher than that of bamboo viscose fiber,and its hygroscopic,dyeing and anti-fibrillation property all are better than conventional Lyocell fiber.Furthermore, the bamboo Lyocell fiber also has excellent negative ion effect and nature antibacterial property.The handle of the fabrics weaved with bamboo lyocell fiber and wood lyocell fiber respectively were evaluated by KES system,the results showed that the former had better wear performance,such as fluffy,slippery,tender and has a good sense of seeing as well as good hanging ability.
迄今为止,Lyocell纤维的生产主要以木浆粕为原料,由于木材受到土地资源、生长周期等因素的影响,远远不能满足Lyocell纤维生产的需求。而我国是世界产竹大国,竹子分布十分广泛,成材迅速,2-3年即可实现连续砍伐使用,符合可持续发展的要求,再加之竹子的主要成分也是纤维素,若能用竹子作为原料生产Lyocell纤维素纤维,不仅提供了一种较为廉价的原料,还为竹子的利用开辟了一条新的途径。此外,以竹子为原料生产的竹纤维素纤维除具有普通纤维素纤维的优点外,还可能被赋予竹子本身所具有的凉爽、顺滑、清香、抑菌以及负离子效应等特性。
目前国内外主要采用粘胶工艺制备再生竹纤维素纤维,而有关以竹纤维素浆粕为原料,采用Lyocell工艺纺制竹纤维素纤维,至今尚无文献报道,因此,本论文将对这一领域进行探索性的研究。
本论文首先采用铜氨粘度法、凝胶渗透色谱法(GPC)法及FTIR法等手段对几种竹浆粕的聚合度、相对分子质量分布、α-纤维素含量及其主要化学组分进行了分析,并与木浆粕进行了对比。结果表明:竹浆粕与木浆粕主要成分都为纤维素,但竹浆粕中含有较多的木质素以及少量的木浆粕中没有的物质。造纸级竹浆粕与纤维级竹浆粕相比,其聚合度较大,相对分子质量分布较宽,半纤维素含量较高。对这二种竹浆粕在NMMO·H2O溶剂体系中的溶解研究进一步表明,纤维级竹浆粕的溶解性能较好,相比之下,造纸级竹浆粕溶解较困难,因此,这类竹浆粕不宜直接作为纺丝用原料。
本论文还采用哈克控制应力流变仪对不同聚合度的竹纤维素/NMMO·H2O溶液的动态及稳态流变性能进行了研究。结果发现,动态流变方法可以预测竹纤维素的相对分子质量及其分布;随着竹纤维素平均聚合度的增大,竹纤维素/NMMO·H2O溶液的流动曲线上移,出现切力变稀的临界剪切速率向低值方向移动,溶液的非牛顿指数n下降,粘流活化能Eη、结构粘度指数Δη和零切粘度η0增加;经一定条件碱处理的竹纤维素/NMMO·H2O溶液的流变性能受竹纤维素原料的聚合度、α-纤维素含量(或半纤维素含量)及杂质含量等因素的影响。
在上述研究基础上,本论文选择出了合适的纤维级竹纤维素浆粕,采用Lyocell工艺纺制出了Lyocell竹纤维素纤维,并探讨了纺丝工艺对Lyocell竹纤维素纤维结构与性能的影响,结果发现:随着纺丝原液浓度的适当增加,纤维的力学性能改善;喷头拉伸比的提高,有利于Lyocell竹纤维素纤维的结晶度及取向度增加,相应地纤维的初始模量和断裂强度增大,而纤度和断裂伸长率下降;在固定喷丝拉伸比的情况下,随着纺丝速度的升高,Lyocell竹纤维素纤维的晶区取向基本不变、非晶区取向及结晶度增加,强度和初始模量增大、断裂伸长减小,而纤度几乎没有变化;随着凝固浴温度的上升,所得Lyocell竹纤维素纤维的结晶度、晶区取向度和初始模量上升,而纤维非晶区取向度、总取向度和强度则略有下降。另外,气隙长度对所制得的Lyocell竹纤维素纤维的力学性能也有一定的影响,在本论文研究范围内,较合适的气隙长度为5cm。
与此同时,为了降低Lyocell竹纤维素纤维的制造成本,本论文还采用60Coγ射线对聚合度较高的造纸级竹浆粕进行辐照处理,以期获得可纺性好的Lyocell工艺用竹纤维素浆粕,并对辐照处理前后的竹纤维素的平均聚合度、相对分子质量分布及超分子结构进行了表征。结果表明,辐照处理对竹纤维素中的α-纤维素含量和相对分子质量及其分布均有影响:当辐照吸收剂量较小时,高能射线主要作用于高相对分子质量的竹纤维素,因此,竹纤维素的聚合度随吸收剂量的增加而迅速降低,但α-纤维素含量并无明显变化;当吸收剂量达到15kGy以上后,聚合度的下降趋势变缓,而α-纤维素含量逐渐降低;辐照处理后,高相对分子质量的竹纤维素分子数明显减少,相对分子质量分布变窄;此外,WAXD及FTIR的分析结果显示,辐照前后的竹纤维素的结晶变体都属于纤维素Ⅰ,且结晶度及晶粒尺寸也均无明显变化,表明在本研究的辐照吸收剂量范围内,经辐照的竹纤维素的结晶结构未被破坏。根据聚合度与吸收剂量之间的关系进一步推导出其G(s)值为0.94μmol·J-1,表明竹纤维素是一种比较容易辐照降解的聚合物,采用辐照方法处理竹纤维素是经济可行的。这种方法不仅解决了造纸级竹浆溶解困难、纺丝液浓度低的问题,而且使竹纤维素的可纺性明显改善,所制得的Lyocell竹纤维素纤维性能满足服用纤维的要求。
通过对Lyocell竹纤维素纤维服用性能与常规Lyocell纤维及粘胶法竹纤维素纤维的对比研究,发现Lyocell竹纤维与常规Lyocell纤维一样,具有光滑的表面及接近圆形的截面,易发生原纤化,其结晶度、强度和模量均远高于粘胶法竹纤维素纤维,湿态下力学性能损失也较小。另外,Lyocell竹纤维素纤维不仅吸湿性、染色性和抗原纤化能力均优于常规Lyocell纤维,还具有明显的负离子效应及天然抑菌性。采用KES织物风格仪对纤维面料的测试结果进一步显示,Lyocell竹纤维素纤维面料的滑爽度、柔软性、抗拉伸及抗压缩性能都比常规Lyocell纤维织物好,表明其具有较好的服用性能。
Lyocell process is a simple and environmental-friendly process for the production of regenerated cellulose fiber.It adopts N-methylmorpholine-N-oxide monohydrate (NMMO·H_2O),a non-toxic solvent,to directly dissolve cellulose and then uses a dry-jet wet spinning method to spin the fiber.In the process,no derivatization,such as alkalization and xanthation in the case of viscose fibers,is required.Furthermore, Lyocell fibers are distinguished by high crystallinity,high degree of orientation,and well-oriented amorphous regions,resulting in a very high dry and wet tensile strength, a high wet modulus and high loop tenacity.
Due to the restriction of wood resource in China,using wood as main raw material of Lyocell fiber could not meet demand for Lyocell fiber.However,bamboo resource is abundant in our country.If Lyocell fibers could be made from bamboo,it not only provides a cheap material for Lyocell fiber but also exploits a new application of bamboo.Moreover,compared to the fibers from cotton and wood,bamboo cellulose fiber made from bamboo has significantly different properties,such as good drapability,good dyeing property,soft,cool,comfortable feelings,and lustrous looking,etc.
So far,regenerated bamboo cellulose fiber was prepared by viscose process at home and abroad.Lyocell Fibers made from bamboo cellulose has not been reported yet. Hence,exploratory researches on bamboo Lyocell fiber were done in this paper.
Firstly,the bamboo pulps were analyzed and characterized by viscosimetry method, gel permeation chromatography(GPC) and Fourier transform infrared spectroscopy (FTIR) and the results were compared with wood pulp.It was found from the FTIR spectra that bamboo pulp was mainly consist of cellulose,same as wood pulp,but contained higher lignin than wood pulp and a little unknown substances which didn't exist in wood pulp,the paper grade bamboo pulp had higher DP,broader MWD and higher content of hemicellulose than that of fiber grade bamboo pulp.Furthermore,the study of bamboo pulp with different DP dissolved in NMMO·H_2O showed that the dissolving property of the paper grade bamboo pulp with high DP exhibited more inferior than that of the fiber grade bamboo pulp.Therefore,the paper grade bamboo pulp could not be directly used as raw material for producing Lyocell fiber.
Bamboo cellulose/NMMO·H_2O solutions were prepared by dissolving bamboo celluloses with different DP in NMMO·H_2O and the rheological behaviors of these solutions were investigated with HAAKE RS150L rheometer.The results showed that bamboo cellulose spinning dopes were shear thinning fluids.With the increase of the average degree of polymerization of bamboo cellulose pulps,the flow curves moved upward,the critical shear rate and the non-Newtonian index(n) decreased,while the apparent viscosity,the viscous flow activation energy,the zero shear viscosity and the structural viscosity index increased.With the increase of temperature,the apparent viscosity decreased,the non-Newtonian index increased.Moreover,the rheological behaviors of the alkali treated bamboo cellulose/NMMO·H_2O solutions were affected by the average degree of polymerization of bamboo cellulose,the content of hemicellulose and impurity in the pulp.In addition,the comparison of the results from theological data and GPC showed that it was feasible to predict the MW and MWD of cellulose by using rheological method.
On basis of aforementioned investigations,the fiber grade bamboo pulp was preferentially selected as raw material for preparing bamboo Lyoccell fiber,bamboo Lyocell fiber was preparing with this pulp by Lyocell process in our laboratory and the influence of spinning parameters on structure and property of bamboo cellulose fiber were systemically investigated.The results showed that the spin parameters had greatly effected on the structures and properties of bamboo Lyocell fiber.Firstly,the mechanical property of the fiber enhanced with the increase of the cellulose concentration in spinning dope.Secondly,the crystallinity and orientation of bamboo Lyocell fiber increased and accordingly the tensile strength and initial modulus increased with the increase of draw down ratio,whereas the linear density and elongation at break decreased with the increase of draw down ratio.When the draw ratio was kept constant,the higher the spinning speed,the higher the orientation in amorphous region and crystallinity,the higher the tensile strength and initial modulus will be,while the orientation in crystalline region and the linear density were not changed basically.In addition,the crystallinity,orientation in crystalline region and initial modulus increased and the orientation in amorphous region,total orientation and tensile strength slightly decreased with the increase of the temperature of coagulation bath.Moreover,the gap length also affects the mechnical properties of the fiber and the optimum gap length is 5 cm.
Generally speaking,paper grade bamboo pulp has high molecular weight,it is difficult to be dissolved in N-methylmorpholine-N-oxide monohydrate(NMMO·H_2O). In order to reduce its molecular weight,improve its dissolving property in NMMO·H_2O and obtain the cheap bamboo pulp with good spinnability for Lyocell process,the paper grade bamboo pulp was irradiated in air by ~(60)Coγ-ray,then the molecular weight(MW) and the molecular weight distribution(MWD) of the irradiated bamboo cellulose were measured by viscosimetry and gel permeation chromatography (GPC),and the crystalline structure was studied by Fourier transform infrared spectroscopy(FTIR) and wide angle X-ray diffraction(WAXD).The results showed that the average degree of polymerization((?)) of the irradiated bamboo cellulose decreased and its MWD became narrow continuously with the increase of absorbed dose,the most significant degradation of the bamboo cellulose took place in the range of the absorbed dose up to 15kGy.However,the results from WAXD and FTIR showed that the crystalline structure such as crystallinity and crystalline form did not change obviously,and this implies that the crystalline structures of the bamboo cellulose were not destroyed in our case.It could be deduced from the relationship between(?) and absorbed doses(D) that G(s) of the bamboo cellulose was 0.94μmol·J~(-1),which indicated that the bamboo cellulose was easily degraded by ~(60)Coγ-ray radiation. Therefore,it was possible economically to degrade the bamboo cellulose by irradiation. Furthermore,it was found from spinning experiment that the dissolving property and the spinnability of the irradiated bamboo cellulose was remarkably improved and that the fiber made from the bamboo cellulose could be applied in apparel industry.
The comparison of the wear behavior of bamboo Lyocell fiber and the other regenerated cellulose fiber was carried out.The results showed that the bamboo Lyocell fiber had many similarities in structure and properties compared with the conventional Lyocell fiber,such as smooth surface,approximate circular cross section, and easy fibrillation,its crystallinity,tensile strength and initial modulus are higher than the bamboo viscose fiber,its ratio of wet tensile strength to dry tensile strength is higher than that of bamboo viscose fiber,and its hygroscopic,dyeing and anti-fibrillation property all are better than conventional Lyocell fiber.Furthermore, the bamboo Lyocell fiber also has excellent negative ion effect and nature antibacterial property.The handle of the fabrics weaved with bamboo lyocell fiber and wood lyocell fiber respectively were evaluated by KES system,the results showed that the former had better wear performance,such as fluffy,slippery,tender and has a good sense of seeing as well as good hanging ability.
引文
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