摘要
鄂尔多斯盆地是我国第二大含油气盆地,其上古生界天然气藏与阿尔伯达深盆气藏相比具有许多相似的特点,目前存在的关键问题是对该气藏的成藏机理和成藏模式认识不清。本研究对采集的鄂尔多斯盆地上古生界100多块储层样品和20多块源岩样品进行了详细地分析,利用所获得的流体包裹体信息结合盆地的沉积史与热史,对上古生界油气的运移及充注历史进行了详细的研究。在此基础上利用生烃动力学和同位素动力学方法对该气藏的成因以及成藏模式进行了研究与探讨。本研究取得如下主要成果与认识:
1.鄂尔多斯盆地上古生界储层中包裹体非常丰富,但个体较小,以无荧光包裹体为主,仅在东北部的低演化区域发育有少量蓝色荧光的石油包裹体。研究结果表明:气体包裹体含量以及气液两相包裹体的气液比,从南向北呈现出逐渐降低的规律。储层中三相包裹体以及沸腾包裹体的存在,说明在包裹体的形成过程中流体并非完全均一的流体。
2.建立起一种利用石油包裹体与同期盐水包裹体等容线方程计算包裹体捕获温度和捕获压力的新方法。利用该方法计算出鄂尔多斯盆地上古生界储层包裹体的捕获温度和捕获压力分别为85—145℃、22-32 Mpa。包裹体的捕获压力远小于其形成时地层的静水压力。包裹体的捕获温度和捕获压力均具有从南向北都逐渐降低的趋势。
3.结合区域地质背景资料,提出了应用流体包裹体捕获温度求取天然气藏形成时间的方法。据此方法的计算结果表明:鄂尔多斯盆地上古生界气藏最早于-150Ma左右(晚侏罗纪)在延安附近开始形成,随后气水界面逐渐向北推移;到-110Ma(晚白垩纪)该天然气藏最终形成。天然气的区域运移方向是由南向北。晚白垩纪后,由于构造运动的影响,气藏发生了小规模的迁移和调整。
4.热模拟实验结果及生烃动力学计算结果表明在盆地抬升的过程中,烃源岩仍有一定数量气体生成。气源岩生气结束的是晚白垩纪—晚第三纪,并具有东早西晚的特点。
5.碳同位素动力学计算结果表明鄂尔多斯盆地上古生界天然气甲烷碳同位素和本地区源岩演化存在明显的不一致性,天然气藏运聚模式属阶段累积,气源
摘要
区主要在盆地南部高成熟区域。
6.鄂尔多斯盆地上古生界天然气藏(主要指伊陕斜坡)的圈闭类型主要是
岩性气藏与深盆气藏,苏里格气田为深盆气藏,榆林气田与神木气田为岩性圈气
藏。
本研究成果对认识鄂尔多斯盆地晚古生界气藏的成藏规律提供了许多有价
值的信息,对于该区油气勘探研究与开发具有重要的指导意义。
The Ordos Basin is the second size basin rich in oil and gas in China mainland. The Upper Paleozoic gas reservoir in this basin has some similarities with the Alberta deep basin gas trap in Canada. The key problem for the gas pool is that the formation mechanism is not clear.
In this study, more than 100 reservoir sandstone samples and 20 source rock samples were taken from this basin and investigated by the combination method of geochemistry and geology, including fluid inclusion techniques, PVTsim software, thermal simulation experiments, hydrocarbon generation kinetics and carbon isotope kinetics. The following recognition and conclusion are obtained:
1. The fluid inclusions occurred in the Upper Paleozoic reservoir sandstones in Ordos Basin are abundant, with small size. Most of them are non- fluorescence, and only a small amount of blue fluorescence inclusions were found in the samples from the east area of the basin where the maturity of the source rocks is lower. The amount of gas inclusions and the ratios of liquid to gas in aqueous inclusions are decreasing from the south to the north in the basin. The present of the three-phase inclusions and boiling inclusions indicate that the fluids was not homogeneous when the inclusions formed.
2. A new method was suggested to calculate the trapping temperature and pressure of inclusion using the isochore equations of both petroleum inclusion and its coeval aqueous inclusions. The trapping temperature and pressure of aqueous inclusions occurred in the Upper Paleozoic reservoir sandstones are in the range of 85-145# and 22-32Mpa, respectively. The trapping pressures of inclusions are lower than the strata water static pressure when the inclusion was trapped. The trapping temperatures and pressures of the fluid inclusions are decreasing from the south to the north of the basin.
3. The Upper Paleozoic gas pool formed firstly in the Yanan area before 150Ma (Late Jurassic). With the migration of water-gas interface from the south to the north gradually, the gas-bearing area extended, and framework of the gas pool formed finally in 110Ma (the late Cretaceous). From the Late Cretaceous to present, the gas trap has been adjusted
because of the tectonic movement. Combining all kinds of information of inclusions with the geologic background, it is recognized that the regional migration of gas was from the south to north direction.
4. The results of the thermal simulation experiments and the kinetics calculation of hydrocarbon generation have shown that the source rock can generate a significant amount of gas in the process of tectonic uplifting. The gas generation of the source rocks in the basin ceased from the late Tertiary to the late Cretaceous, with the trend later in the west area and earlier in the east area.
5. The results of the carbon isotope kinetic have shown that the gas carbon isotope values in the Upper Paleozoic gas reservoirs areas not consistent with the maturity of the source rocks from the gas pool areas. The formation of the gas pools belong to stage accumulation model and the main source are in the south area with higher maturity.
6. There are two main types of gas trap in the Upper Paleozoic strata .One is lithological gas trap, and another is deep basin gas trap. The SuLiGe gas pool is a deep basin gas trap, and the YuLi and ShenMu gas pools are lithologyical gas traps.
The results have provided some important information on the formation of Upper Paleozoic gas pools, having great significance for further research and exploration of the Ordos Basin
引文
1. John A.Masters, Deep basin gas trap,Western Canada. AAPG 1979, 63 (2): 152-181
2. By mihael S.Wilson, Thaddeus S.Dyman, Vito F.Nuccio. Potential for deep basin-center gas accumulation in Hanna basin, Wyoming. USGS 2001, 1(6): 1-11
3. Barbara J.tilley, Brucee.nesbitt, Fred J. Longstffe. Thermal history of Alberta deep basin: Comparative study of fluid inclusion and vitrinite reflection and vitrinite reflectance data . AAPG 1989,73(5): 1206-1222
4. Brian hitchon, Geothermal gradients, hydrodynamics, and hydrocarbon occurrences, Alberta Canada. AAPG. 1984, 73(6):833-859
5.李熙哲,冉启贵,杨玉凤.鄂尔多斯盆地上古生界深盆气气水分布与压力特征.中国石油第二界深盆气研讨会内部材料.2000.7
7.魏新善,席胜利,孙六一.鄂尔多斯盆地上古生界深盆气成藏地质条件.中国石油第二界深盆气研讨会内部材料.2000.7
8.孙六一,范正平,杨奕华.鄂尔多斯盆地上古生界储层展布及其特征.中国石油第二界深盆气研讨会内部材料.2000.7
9. Stepen O. Moshier and Douglas W. Waples. Quantitative Evaluationof Lower Cretaceous Mannville Group as Source Rock for Alberta's O Sands. AAPG 1985, 69(2): 161-172
10. Stefen Bachu and J.R.Underschultz. Large-Scale Underpressuring in Mississippian-Cretaceous Succession, Southwester Alberta Basin, AAPG 1995, 79(7): 989-1004
11.D.H.Welte, W.Stoessinger, R.G.Schaefer.(胡征钦 译) 加拿大西部下深盆地天然气的生成和运移深盆地气田实例研究(埃尔姆沃斯) 中国石油天然气总公司情报研究所,1990.5:39-49
12.David G.Smith, Card E.Zorn, Robert M.Saeider,(吴永甫 译) 阿尔伯达西部和不列颠哥伦比亚东北部埃尔姆沃斯区深盆地及相邻区早白垩世古地理 深盆地气田实例研究(埃尔姆沃斯) 中国石油天然气总公司情报研究所,1990.5:88-123
13.Robert M.Gies,(李进 译) 阿尔伯达大型“深盆”气圈闭成因实例:卡多明组,深盆地气田实例研究(埃尔姆沃斯) 中国石油天然气总公司情报研究所,1990.5:124-149
14.T.Bdavis,(程守礼 译) 饱含气盆地中的地下压力分布—深盆地气田实例研究(埃尔姆
沃斯) 中国石油天然气总公司情报研究所,1990.5:201-217
15. Douglasi.Cant and Valerie G.Ethier. Lithology-Dependentic Control of Reservoir Properties of Congomerates,Falher Member, Elmworth Field, Alberta AAPG 1984, 68 (4) : 785-792
16. Andrew J. Wills and Thomas F.Moslow. Stratigraphic Setting of Transgressive Barrier-Island Reservoires with an Example from the Triassic Halfway Formation, Wembley Field,Alberta.Canda. AAPG 1994, 78(5) 684-702
17.戴金星,王庭斌,宋岩等.中国大中型天然气田形成条件与分布规律.地质出版社,1997
18.杨俊杰,裴锡古.中国天然气地质学(第四卷).鄂尔多斯盆地[M].北京:石油工业出版社,1996
19.沈平,徐永昌,王先彬等.气源岩和天然气地球化学特征及成气极力研究.甘肃科学技术出版社,1991
20.肖贤明.有机岩石学及其在油气评价中的应用.广东科学技术出版社,1992
21.周中毅,潘长春.沉积盆地古地温测定方法及其应用.广东科学技术出版社,1992
22.闵琪.深盆气藏与鄂尔多斯盆地[J].低渗透油气田,1998(2):1-6.
23.张金亮,常象春,张金功.鄂尔多斯盆地上古生界深盆气藏研究[J].石油勘探与开发,2000(4)30-36.
24.李振铎,胡义军,谭芳.鄂尔多斯盆地上古生界深盆气研究.天然气工业,1998,18(3):10-16。
25.闵琪 刘孝汉 王欣等.鄂尔多斯盆地上古生界形成深盆气藏区域地质研究.低渗透油气田,1998,3(2):7-12
26.黄月明 黄建松 刘绥保 等.鄂尔多斯盆地上古生界低渗透致密砂岩储层研究.低渗透油气田,1998,3(2):24-28
27.马振芳,程启荣,周树勋.鄂尔多斯盆地上古生界低渗透气、水层重新判识.低渗透油气田,1998,3(2):29-31
28.闵琪,付今华,席胜利等.鄂尔多斯盆地上古生界天然气运聚特征.石油勘探与开发,2002 47(4)26-29
30.庞雄奇,金之钧,姜振学等.深盆气成藏门限及其物理模拟实验.天然气地球科学.2003,14(3):207-214
31.王振亮,陈荷立.鄂尔多斯盆地中部上古生界古流体动力分析.沉积学报.1998,16
(4):105-108
32.黄第藩,熊传武,杨俊杰等.鄂尔多斯盆地中部气田气源判识和天然气成因类型天然气工业.1996,41(17):1-5
33.王双明.鄂尔多斯盆地聚煤规律及煤炭资源评价 煤炭工业出版社 1996
34.罗启后,王世谦.四川盆地西部三叠系重点含气层系天然气富集条件研究.天然气工业.1996增刊
35.李一平.四川盆地已知大中型气田成藏条件研究.天然气工业 1996增刊
36.任战利.鄂尔多斯盆地热演化史与油气关系研究.石油学报.1996,17(1)
37.蒋国豪,胡瑞忠,方维萱.镜质体反射率(RO)推算古低温研究进展.地质地球化学.2001,29(4):40-45
38.任战利,赵重远.鄂尔多斯盆地古地温研究.沉积学报.1994,12(1):17-24
39.任战利.利用磷灰石裂变径迹研究鄂尔多斯盆地地热史.地球物理学报.1995,38(3):339-349
40.张金川,金之钧,庞雄奇.深盆气成藏条件及其内部特征.石油实验地质.2000,22(3):210-215
41.李克明.鄂尔多斯盆地北部晚古生代的深盆气气藏.石油与天然气地质.2002,23(3):190-194
42.廖鲁海,张厚福.陕甘宁盆地中部上古生界气藏盖层宏观封闭性研究.天然气工业.1998,18(3):4-6
43.马新华,王涛,庞雄奇等.深盆气藏的压力特征及成因机理.石油学报.2002,23(5):23-27
44.郑承光,范正平,侯云东等.鄂尔多斯盆地陕141井区上古生界气藏储层特征.天然气工业.1998,18(5)
45.耿安松,冯乔,张文正等.苏里格庙上古生界天然气成因类型及成藏机理研究报.中国科学院广州地球化学研究所,2001,12
46.黄第藩,熊传武,杨俊杰等.鄂尔多斯盆地中部气田气源判识.科学通报.1996,41(17) 1589-1592
47.郭英海,刘焕杰,权彪等.鄂尔多斯地区晚古生代沉积体系及古地理演化.沉积学报.1998,16(3)
48. John C.Hoppkins. Characterization of Reservoir Lithologies within Subunconformity Pool:
Pekisko Formatin ,Medicine River Field, Alberta.Canda AAPG 1999, 38(11): 855-1870
49. Scottl.Montgomery, James R.Wood, and Willam B.Harrison . Devonian Dundee Formation, Crystal Field, Michigan Basin: Recovery of Bypassed Oil Through Horizontal Drilling AAPG 1998, 82 (8): 1445-1462
50. Tommchika Tokunag, Tatsuro Mogi, Osamu Matsubara, et. Al. Buoyancy and Interfacial Force Effects on Two-Phase Displacement Patterns: An Exerimental Study 2000, 84(1): 65-74
51. Stefan Bachu and J.R.Underschultz. Large-Scale Underpressuring in the Mississippian-Cretaceous Succession, Southwestern Alberta Basin AAPG 1995, 79 (7): 589-605
52. Stefan Bachu. Flow of formation Water ,Aquifer Characteristics,and Their Relation to Hydrocarbon Accumulations,Northern Alberta Basin AAPG 1997, 81(5): 689-701
53.卢焕章,李秉伦 等.包裹体地球化学[M].北京:地质出版社,1990
54.刘斌,沈昆.流体包裹体热力学[M].北京:地质出版社,1999.
55. T.Shepherd, A.H.Rankin, D.H.M.Alderdon. A Practical Guide to Fluid Inclusion Studies[M]. USA: chapman ε Hall NEW YORK, 1985.
56. Rick C. Tobin and Brenda L.Claxon. Multidisciplinary Thermal Maturity Studies Using Vitrinite Reflectance and Fluid Inclusion Microthermometry : A New Calibration of Old Techniques. AAPG. 2000, 84 (10): 1647-1665
57. A.C.Aplin, G.Macleod, S.R.Larter, K.S.Pedersen, H.Sorensen, T.Bbbth. Combined use of Confocal Laser Microscopy and PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions. Marine and Petrolum geology, 1999, 16(8): 98-101.
58. A.C.Aplin, S.R.Larter, M.A.Bigge, G,Macleod, et,al. PVTX history of the North sea's Judy oilfield[J]. Journal of Geochemical Exploration, 2000, 60-70: 641~644.
59. J.Parnell, P.F.Carey, B.Monson. Fluid inclusion constraints on temperatures of petroleum migration from authigenic quartz in bitumen vein, Chemical Geology. 1996,129: 217-226.
60. D.Middleton, J.Parnell, P.Carey, G.Xu. Reconstruction of fluid migration history in Northwest Ireland using fluid inclusion studies, Journal of Geochemical Exploration 2000, 69~70: 673-677.
61. Karsten Michael and Stefan Bachu. Fluids and pressure distributins in the foreland-basin succession in the west-centeral part of the Alberta basin, Canada: Evidence for permeability barriers and hydrocarbon generation and migration. AAPG. 2001, 85(7): 1231-1252
62. Carlos Rossi, Robert H. Goldstein, Andrea Ceriani, et,al. Fliud inclusions record thermal and fluid evolution in reservoir sandstones, Khatatba Formation, Western Desert, Egypt: A case for fluid injection. AAPG. 2002, 86 (10): 1773-1779
63. R.Thiery, J.Pirononl, F.Walgenwitz et al. PIT: a new modeling tool for the characterization of hydrocarbon fluid inclusions from volumetric and microthermometric measurements. Journal of Geochemical Exploration. 2000, 69-70:701-704
64. Liu D. H, Xiao X. M, Mi J.K, et al. Determination of trapping pressure and temperature of petroleum inclusions using PVT simulation software - a case study of Lower Ordovician carbonates from the Lunnan Low Uplift, Tarim Basin. Marine and Petroleum Geology. 2003, 8
65. E.L.Rowan, M.B.Goldhaber, and J.R.Hatch. Regional fluid flow as a factor in the thermal history of the Illinois basin: constraints from fluid inclusions and the maturity of Pennsylvanian coals. AAPG. 2002, 8 (2) 1458-1472
66. Stratigraphic setting of transgressive barrier-island reservoir with an example from the Triassic halfway Formation, Wembley field, Alberta, Canada. AAPG. 994, 78 (5): 775-791
67. Simon C.George, Tim E.Ruble, Adriana Dutkiewicz, et,al. Assessing the maturity of oil trapped in fluid inclusions using molecular geochemistry data and visually-determined fluorescence colours. Applied geochemistry. 2001, 16: 451-473
68. Volker luders, Bernhard Prcejus, Peter Halbach. Fluid inclusion and sutfur isotpe study in probable modern analogue Kuroko-type ores from the JADE hydrothermal field. Chemical geology. 2001, 173:45-58
69. J. PARNELL, P. F. CAREY, B. Monson. Fluid inclusion constraints on temperatures of petroleum migration from authigenic quartz in bitumen veins. Chemical geology. 1996, 129:217-226
70. Lung-Chuan Kou. Gas exsolution during fluid migration and its relation to overpressure and petroleum. Marine and Petroleum Geology. 1997, 14 (3) :221-229
71. Svetlana Grishina, Jacques Pironon. Organic inclusion in salt. Part 3. oil and gas inclusions in
Cambrian evaporite deposit from East Siberia. A contribution to the understanding of nitrogen genration in evaporates. Organic geochemistry. 1998, 28 (5): 297-310
72. Jan Kihle. Adaptation of fluorescence excitation-emission mocro-spectroscopy for characterization of single hydrocarbon fluid inclusions. Organic geochemistry. 1995, 23 (11): 1029-1042
73. Tim E.Ruble, Simon C.George, Mark Lisk, et.al. Grganic compounds trapped in aqueous fluid inclusions. Organic geochemistry. 1998, 29(1-3): 195-205
74. Steven J.O'Connor. Hydrcarbon-water interracial tension values at reservoir conditions: Inconsistencies in the technical literature and the impact on maximum oil and gas column height calculations. AAPG. 2000, 84(10): 1537-1541
75.米敬奎,肖贤明,刘德汉等.鄂尔多斯盆地上古生界储层中包裹体最小捕获压力的PVTsim模拟 地球化学 2002,31(4):402-406
76.米敬奎,肖贤明,刘德汉等.利用储层流体包裹体的PVT特征模拟计算天然气藏形成古压力.中国科学(D),2003,35(7)
77.肖贤明,刘祖发,宋之光等.应用储层流体包裹体信息研究天然气藏的成藏时间.科学通报,2002,47(12):957~960
78.邹艳荣,杨起,刘大锰.华北晚古生代煤二次生烃的动力学模式[J].地球科学—中国地质大学学报 1999.24(2) 189-190
79. ZOU YanRong , YNAG Qi , LIU DaMeng et al. Maturity Control on the Patterns of Hyrocarbon Regeneraton from Coal [J]. Earth science, 2000, 74 (2) : 370-373.
80.米敬奎,肖贤明,刘德汉等.利用流体包裹体信息研究油气的运移规律.石油学报.2003,24(9):46-51
81.赵重远.石油地质学.北京:地质出版社,1979
82.施继锡.包裹体作为天然气运移判别标志的研究.石油与天然气地质.1991,12(2):185-194
83.施继锡,余孝顺.碳酸盐岩中包裹体有机质特征与非常规油气评价.矿物学报,1996,16(2):105-107
84.周雯雯.珠三凹陷有机包裹体特征及其在油源和油气运移分析中的应用.中国海上油气地质,2001,14(5):324-331
85.郝石生,张振英.天然气在地层水中的溶解度变化特征及地质意义.石油学报,
1993,14(2):12-22
86.叶素娟,姜亮.从有机包裹体特征探讨油气运移时间.矿物岩石.2001,21(6):38-41
87.付少英,彭平安,张文正等.用镜质体反射率和包裹体研究鄂尔多斯盆地气藏中气水界面的迁移.石油学报,2003,24(3)
88.米敬奎,杨孟达,刘新华.鄂尔多斯盆地抬升后源岩是否生气的实验模拟.湖南科技大学学报.2003,18(2):1-5
89.刘金钟,唐永春.用干酪根生烃动力学方法预测甲烷生烃量之一例.科学通报.1998,43(11):1187-1191
90.熊永强,耿安松,王云鹏等.干酪根二次生烃动力学模拟实验研究.中国科学(D).2001,31(4):315-320
91.付少英,彭平安,张文正等.鄂尔多斯盆地上古生界煤的生烃动力学研究.中国科学(D).2002,32(10):812-818
92.刘金钟.干酪根生烃动力学研究及地质应用.有机地球化学研究新进展(第八届全国有机地球化学会议论文集).石油工业出版社 2002,343-351
93.邹艳荣,帅燕华,孔枫等.甲烷碳同位素演化的数学模型与演化.天然气地球科学.2003,14(2):92-96
94.Melodye A R, George E C, Chung H M.利用天然气的碳同位素比值建立热成因起模型.天然气地球科学.2002,13(5-6):19-26
95. Bernhard Cramer, Eckhard Faber, Peter Gerling, et al. Reaction kinetics of stable carbon isotope in natural gas-insights from dry, open system pyrolysis experiments. Energy and Fuels. 2001, 15:517-532
96. Francois Lorant, Francois Behar, Mireille Vandenbroucke. Methane generation from methylated aromatics: Kineic study and carbon isotope modeling. Energy and Fuels. 2000, 14:1143-1155
97. M.Mastalerz, A.Schimmemann. Isotopically exchangeable organic hydrogen in coal relates to thermal maturity and maceral composition. Organic geochemistry. 2002, 33:921-931
98. Y.Tang, J.K.Perry, P.D.Jenden, et al. Mathematical modeling of stable carbon isotope ratio in natural gases. Geochimica et Cosmochimica Acta. 2000, 64(15): 2673-2687
99. Ulrich Berner, Eckhard Faber and Wolfgang Stahl. Mathematical simulation of the carbon isotopic fraction between huminitic coals and related methane. Chemical Geology.
1992, 94:315-39
100. Ulrich Berner, Eckhard Fabe, Georg Scheeder, et al. Primary cracking of algal and landplant kerogens: kinetic models of isotope variations in methane, ethane and propane. Chemical Geology. 1995, 126:233-245
101.Cramer B, Faber E, Gerling P, et al.天然气稳定碳同位素反应动力学研究.天然气地球科学.2002,13(5-6):8-18
102.何自新,付金华,席胜利等.苏里格大气田成藏地质特征.石油学报.2003,24(2):6-12
103.李文厚,屈红军,魏红红等.苏里格庙地区晚古生代层序地层学研究.地层学杂志.2003,27(1):41-44
104.刘建仪,唐海,郭平等.苏里格气田类型判别实验研究.天然气工业.2003,23(2):75-78
105.解国爱,张庆龙,郭令智.鄂尔多斯盆地西缘和南缘古生代前陆盆地及中央古隆起成因与油气分布.石油学报.2003,24(2):18-24
106.邸领军,张东阳,王红科.鄂尔多斯盆地喜山构造运动与油气成藏.石油学报.2003,24(2):34-37
107.张新建,刘新刚,王鑫峰.鄂尔多斯盆地富县探区上古生界深盆气藏条件.新疆石油地质.2003,24(2):127-129
108.朱蓉,楼章华,金爱民等.鄂尔多斯盆地上古生界深盆气藏流体特征及成藏过程分析.地质科学,2003,38(1):31-43
109.耿安松,熊永强,冯乔等.鄂尔多斯盆地和四川盆地川东复杂低渗气田勘探技术研究,“十五”国家重大科技攻关项目成果报告.广州:2003.9
110.冯乔,张文正,耿安松等.苏里格庙上古生界天然气成因类型及成藏机理研究报告.广州:2001.12
111.陈晋阳,郑海飞,曾贻善.流体包裹体的拉曼光谱分析进展.矿物岩石地球化学通报.2002,21(2):133-138
112.庞雄奇,金之钧,姜振学等.深盆气成藏门限及其物理模拟实验.天然气地球科学.2003,14(3):207-214
113. Michael S. Wilson, Thaddeus S. Dyman, Vito F. Nuccio. Potenial for deep basin-centered gas accumulation in Hanna Basin, Wyoming. USGS 2002.
114. Crawford, M.L. Phase equilibria in aqueous fluid inclusion. In:Mineral. Assoc. Can. Short Course Handbook, 1981,6:75-100.
115.魏国齐,陈孟晋.鄂尔多斯盆地和四川盆地川东复杂低渗气田成藏规律研究与勘探目标评选研究报告.中国石油勘探开发研究院廊坊分院天然气研究所.2003.8
116.冯乔,张文正.苏里格庙上古生界天然气成因类型及成藏机理研究报告.长庆油田勘探研究院、中国科学院广州地球化学研究所,2001.12
117.杨俊杰,汤显明,傅锁堂.鄂尔多斯盆地上古生界天然气圈闭类型及气藏序列.天然气地质研究.1992,石油工业出版社
118.王启军,陈建渝.油气地球化学.1988,中国地质大学出版社