杯芳烃衍生物分析及其色谱保留机理的量子化学研究
|
摘要
杯芳烃作为第三代主体分子，与环糊精和冠醚相比，更容易进行化学修饰，可广泛的应用于主-客体化学的研究与应用领域。利用主体分子的分子识别功能提高分离选择性是色谱分离材料研究的重要课题，杯芳烃在色谱分析领域的应用主要为流动相或背景电解液的添加剂和色谱固定相的制备。本论文主要包括苯甲酰基杯芳烃的合成、杯芳烃混合物的色谱分离研究和杯[4]芳烃键合硅胶色谱柱上色谱分离行为的量子化学研究等三部分内容：
1．合成了苯甲酰基杯[4，6，8]芳烃，并通过红外光谱、核磁共振、质谱和液相色谱验证了其结构和纯度。
2．分别在C18柱、CN RP柱、NH_2柱和LC-318柱上，对杯芳烃及其衍生物的色谱行为进行了比较研究。杯[4，6，8]芳烃在C18柱上10 min可达到基线分离；25-乙氧基杯[4]芳烃、杯[4]芳烃、对叔丁基杯[4]芳烃在C18柱上，采用甲醇-水梯度洗脱可达到基线分离；对叔丁基杯[4，6，8]芳烃在C18柱和LC-318柱上，使用乙腈／氯仿流动相，可以达到基线分离。
3．采用量子化学方法对多种物质在DBS4柱上的色谱行为进行了研究，发现DBS4固定相与被分离物之间的作用力不但有π-π作用、包结作用、疏水作用和范德华力，还存在与溶质体积相关的阻力，流动相对溶质的溶解作用也是影响色谱分离的重要因素。
As a typical representative of the third generation of supramolecules, calixarenes are more easily to be chemically modified than CDs and crowns. Calixarenes have being widely studied and applied in host-guest chemistry because their interactions between calixarenes and guests exist based on many kinds of modes and mechanisms. It is an important task to improve the separation selectivity of calixarene materials using the host molecule's recognition functions. In separation science, it has been widely used as the mobile phase additive, bonded stationary and capillary inner-wall modifier. This paper systemically introduced the synthesis of benzoyl hexahydroxy calixarene, the separation of calixarene derivatives and the quantum chemistry study of the separation behavior of the solutes on the calix[4]arene-bonded silica stationary phase. The summary of the thesis is as follows:
1. para-Benzoyl hexahydroxy clixarenes synthesized and characterized by IR, NMR and MS methods. The purity was determined with more than 98% by HPLC.
2. The separations of calixarene derivatives have been investigated using C18 column, CN RP column, NH_2 column and LC-318 column respectively. With C18 column and MeOH mobile phase, calix[4-8]arenes could be well baseline separated within 10min. Using C18 column, with a mobile phase of MeOH/H_20, 25-ethoxycalix[4]arene, calix[4]arene and p-tert-butylcalix[4]arene could be baseline separated with gradient elution. Using NH_2 column and MeCN mobile phase, p-tert-butylcalix[4-8]arenes were baseline separated within 10 min at 0.8 ml/min.
3. The quantumn chemistry study of the separation behavior of the analytes in the DBS4 has carried out. The results display that the interactions between DBS4 and solutes not only includeπ-πinteraction, inclusion interaction, hydrophobic interaction and van der waals forces, but also include the hindrance hindrance related to the volume size of solute molecules. The mobile phase solvent can affect chromatography separation through the analytes' solubility.
1．合成了苯甲酰基杯[4，6，8]芳烃，并通过红外光谱、核磁共振、质谱和液相色谱验证了其结构和纯度。
2．分别在C18柱、CN RP柱、NH_2柱和LC-318柱上，对杯芳烃及其衍生物的色谱行为进行了比较研究。杯[4，6，8]芳烃在C18柱上10 min可达到基线分离；25-乙氧基杯[4]芳烃、杯[4]芳烃、对叔丁基杯[4]芳烃在C18柱上，采用甲醇-水梯度洗脱可达到基线分离；对叔丁基杯[4，6，8]芳烃在C18柱和LC-318柱上，使用乙腈／氯仿流动相，可以达到基线分离。
3．采用量子化学方法对多种物质在DBS4柱上的色谱行为进行了研究，发现DBS4固定相与被分离物之间的作用力不但有π-π作用、包结作用、疏水作用和范德华力，还存在与溶质体积相关的阻力，流动相对溶质的溶解作用也是影响色谱分离的重要因素。
As a typical representative of the third generation of supramolecules, calixarenes are more easily to be chemically modified than CDs and crowns. Calixarenes have being widely studied and applied in host-guest chemistry because their interactions between calixarenes and guests exist based on many kinds of modes and mechanisms. It is an important task to improve the separation selectivity of calixarene materials using the host molecule's recognition functions. In separation science, it has been widely used as the mobile phase additive, bonded stationary and capillary inner-wall modifier. This paper systemically introduced the synthesis of benzoyl hexahydroxy calixarene, the separation of calixarene derivatives and the quantum chemistry study of the separation behavior of the solutes on the calix[4]arene-bonded silica stationary phase. The summary of the thesis is as follows:
1. para-Benzoyl hexahydroxy clixarenes synthesized and characterized by IR, NMR and MS methods. The purity was determined with more than 98% by HPLC.
2. The separations of calixarene derivatives have been investigated using C18 column, CN RP column, NH_2 column and LC-318 column respectively. With C18 column and MeOH mobile phase, calix[4-8]arenes could be well baseline separated within 10min. Using C18 column, with a mobile phase of MeOH/H_20, 25-ethoxycalix[4]arene, calix[4]arene and p-tert-butylcalix[4]arene could be baseline separated with gradient elution. Using NH_2 column and MeCN mobile phase, p-tert-butylcalix[4-8]arenes were baseline separated within 10 min at 0.8 ml/min.
3. The quantumn chemistry study of the separation behavior of the analytes in the DBS4 has carried out. The results display that the interactions between DBS4 and solutes not only includeπ-πinteraction, inclusion interaction, hydrophobic interaction and van der waals forces, but also include the hindrance hindrance related to the volume size of solute molecules. The mobile phase solvent can affect chromatography separation through the analytes' solubility.
引文
[1] A. Baeyer. Ueber die verbindungen der aldehyde mit den phenolen and aromatischen kohlenwas-serstoffen. Ber., 1872, 5: 1094-1100
[2] C. D. Gutsche, R. Muthukrishnan. Calixarenes. 1. analysis of the product mixtures produced by the base-catalyzed condensation of formaldehyde with pares-substituted phenols. J. Org. Chem., 1978, 43: 4905-4906
[3] R. S. Donald, K. Mariusz, P. K. Ram, H. W. William, C. D. Gutsche. Conformational characteristics of ethers and esters of p-tert-butylcalix[5]arene. J. Am. Chem. Soc., 1995, 117(2): 586-601
[4] V. Bohmer, G. Ferguson, M. Frings. 4,12,16,24-Tetrahydroxy calix[4]arene-methanol (1/2). Acta Crystallographica, Section C: Crystal Structure Commun. 1997, C53(9): 1293-1295
[5] S. Noa, E. B. Silvio. Proximal regioselectivity of the O,O'-dialkylation of tetrahydroxy ketocalix[4]arene. J. Org. Chem., 2005, 70(13): 5278-5282
[6] C. D. Gutsche, B. Dhawan, K. H. No, R. Muthukrishnan. Calixarenes. 4. the synthesis, characterization, and properties of the calixarenes from p-tert-butylphenol. J. Am. Chem. Soc., 1981, 103: 3782-3792
[7] B. T. Hayes, R. F. Hunter. Phenol-fon: naldehyde and allied resins Ⅵ. Rational synthesis of a 'cyclic' tetra-nuclear pcresolnovolak. J. Appl. Chem., 1958, 8: 743-748
[8] V. Bohmer. Calixarenes, macrocycles with (almost) unlimited possibilities. Angew. Chem. Int. Ed. Engl., 1995, 34: 713-745
[9] M. Hedidi, S. M. Hamdi, M. Tassadit. Microwave-assisted synthesis of calix[4]resorcinarenes. Tetrahedron, 2006, 62(24): 5652-5655
[10] 戈云，颜朝国．间苯二酚杯芳烃树枝醇类化合物的合成．有机化学，2005，25(4)：414-418
[11] 戈云，颜朝国．杯[4]间苯二酚芳烃Schiff碱衍生物的合成及其离子萃取性能．高等化学学报，2004，25(10)：1836-1839
[12] 吴萍，程爱民，汪浩，颜朝国．连苯三酚型杯芳烃及其酯类衍生物的合成．安徽大学学报，2005，29(6)：70-74
[13] G. Thorsten, I. Waldemar, A. Ceno, F. Roland, K. Sirpa, N. Christian, M. Jochen. Self-assembly of 2,8,14,20-tetraisobutyl-5,11,17,23-tetrahydroxyresorc[4]arene. Eur. J. Org. Chem., 1999, 9: 2257-2262
[14] L. Avram, Y. Cohen. Hexameric cap sules of L ipophilic Pyrogallolarene and Resorcinarerue in Solutions as Probed by Diffusion NMR: One HydroxylMakes the Pifference. Org. Lett., 2003, 5 (18): 3329-3332
[15] P. E. Georghiou, M. Ashram, Z. P. Li, S. G. Chaulk. Syntheses of Calix[4]naphthalenes Derived from 1-Naphthol. J. Org. Chem., 1995, 60(22): 7284-7289
[16] C. L. Zhang, Y. Jin, S. L. Gong. Syntheses and coordination properties of (thia)calix[4]arenes bearing single-quinolin-8-yl-oligooxyethylene pendant. J. Chem. Res., 2006, 9: 596-599
[17] B. Vandana, B. J. Nagendra, K. Manoj. Synthesis and binding studies of novel thiacalixpodands and bisthiacalixarenes having O,O″-dialkylated thiacalix-[4]are ne unit(s) of 1,3-alternate conformation. Tetrahedron Lett., 2007, 48(9): 1581-1585
[18] P. C. Carol, Y. Takehiko. 1,3-alternate- thiacalix[4]arene-based dimer: syn- thesis and inclusion behavior. Chem. Engineering Comm., 2006, 193(10): 1185-1193
[19] 顾金英，李延军，施宪法，计亮年．含硫杂杯芳烃的高聚物的合成、表征及对Pb2+的传输作用．高分子材料科学与上程，2006，22(4)：80-83
[20] 黄翠玉，杨发福，赵夏．硫杂杯[4]芳烃酰胺基硫脲衍生物的合成．合成化学，2006，14(3)：264-265
[21] N. Iki, H. Kumagai, N. Morohashi, K. Ejima, M. Hasegawa, S. Miyanari, S. Miyano. Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal Ions. Tetrahedron Lett., 1998, 39: 7559-7562
[22] F. Narumi, N. Iki, T. Suzuki, T. Onodera, S. Miyano. Syntheses of chirally modified thiacalix[4]-arenes with enantiomeric amines and their application to chiral stationary phases for gas chromatography. Enantiomer, 2000, 5(1): 83-93
[23] N. Iki, S. Miyano. Yhiacalixarenes. Novel host compounds with high versatility. Chem. Soc. Japan-Chem. & Industr. Chem. J., 2001, 11: 613-622
[24] N. Morohashi, R. Naito, N. Iki, S. Miyano. Synthesis of inherently chiral monosulfinyltrithiacalix[4]arenes by the oxidation of one of the bridging sulfurs of a tetrathiacalix[4]arene fixed in the 1,3-alternate conformation. Israel J. Chem., 2001, 41(4): 303-307
[25] J. Lang, H. Dvorakova, I. Bartosova, P. Lhotak, I. Stibor, R Hrabal. Conformational flexibility of a novel tetraethylether of thiacalix[4]arene. A comparison with the "classical" methylene-bridged compounds. Tetrahedron Lett., 1999, 40: 373-376
[26] 褚惠虹，王谨，潘志刚，胡晓钧，顾金英，施宪法．硫杂杯芳烃及其衍生物的合成与表征．有机化学，2003，23：1255-1259
[27] N. Morohashi, E Narumi, N. Iki, T. Hattori, S. Miyano. Thiacalixar-enes. chemical reviews, 2006, 106(12): 5291-5316
[28] V. Stastny, I. Stibor, H. Dvorakova, P. Lhotak. Synthesis of (thia)calix[4]arene oligomers: towards calixarene-based dendrimers. Tetrahedron, 2004, 60: 3383-3391
[29] 胡晓钧，王丽，任杰，施宪法．硫杂杯芳烃—类新型的分子受体化合物．化学通报，2004，2：90-95
[30] J. L. Sessler, P. J. Anzenbacher, K. Jursikova, H. Miyaji, J. W. Genge, N. A. Tvermoes, W. E. Allen, J. A. Shriver, P. A. Gale, V. Krat. Functionalized calix[4]pyrroles. Pure and Appl. Chem., 1998, 70(12): 2401-2408
[31] G. Cafeo, F. H. Kohnke, G. L. La Torre. Calix[6]pyrrole and hybrid calix [n] furan [m] pyrroles (n+m=6): Syntheses and Host-guest. J. Chem., 2002, 8 (14): 3148-3156
[32] N. M. Leonid, A. V. Miroslav, V. P. Vladimir, I. K. Vitaly, L. Januzh, A. S. Yury. Phosphorotropic rearrangement in synthesis of asymmetrically-substituted calix[4]-arenas. Chem. Comm., 1996, 69-72
[33] H. M. Chawla, K. S. Meena. Calix[n]arene-quinone interactions: Molecular recognition of 2,6-naphthoquinine by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41, 42-hexahy-droxycalix (6) arene. Tetrahedron, 1995, 51: 2709-2718
[34] Zhong C., Y. L. Zheng, F. C. Gong, S. Long, R Chen, X. C. He. Recognition of alkyl ketone molecules based on thickness-shear-mode acoustic sensors with calixarene derivatives. Microchemical J., 2007, 86(1): 1-9
[35] 张德华，吕鉴泉．芘冠醚双功能化杯[4]芳烃的合成与表征．化学试剂，2006，28(10)：627-628
[36] Agnihotri Pragati, Suresh Eringathodi, Paul Parimal, Ghosh Pushpito K. Synthesis, Crystal Structures, Cation-Binding Properties and the Influence of Intramolecular C-H…O Interactions on the Complexation Behaviour of a Family of Cone p-tert-Butylcalix [4]arene-crown-5 Compounds. Eur. J. Inorg. Chem., 2006, 17: 3369-3381
[37] 黄章杰，胡秋粉，杨光宇，尹家元．新显色剂8-[杯(4)芳烃偶氮]氨基喹啉的合成及其与金的 显色反应．分析实验室，2003，22(1)：75-77
[38] F. Karci, I. Sener, H. Deligoz. Azocalixarenes. 1: synthesis, characterization and investigation of the absorption spectra of substituted azocalix[4]arenas. Dyes and Pigments, 2003, 59: 53-61
[39] F. Karci, I. Sener, H. Deligoz. Azocalixarenes. 2: synthesis, characterization and investigation of the absorption spectra of azocalix[6]arenes containing chromogenic groups. Dyes and Pigments, 2004, 62: 131-140
[40] I. Sener, F. Karci, E. Kilic, H. Deligoz. Azocalixarenes. 3: synthesis and investigation of the absorption spectra of hetarylazo disperse dyes derived from calix[4]arene. Dyes and Pigments, 2004, 62: 141-148
[41] I. Sener, F. Karci, E. Kilic, H. Deligoz. Azocalixarenes. 4: synthesis, characterization and investigation of the absorption spectra of hetarylazo-substituted calix[6]arenas. Dyes and Pigments, 2004, 62: 149-157
[42] 钟志梅，姚俊学．杯芳烃磷酸酯为载体铅离子选择性膜电极的研究．分析化学(来稿摘登)，2006，34(4)：587
[43] S. Shinkai, T. Arimura, H. Satoh, O. Manabe. Chiral calixarene. J. Chem. Soc., Chem. Commun., 1987, 19: 1495-1496
[44] K. Ito, M. Noike, A. Kida, Y. Ohba. Syntheses of chiral homoazacalix[4]arenes incorporating amino acid residues: molecular recognition for racemic quaternary ammonium ions. J. Org. Chem., 2002, 67(21): 7519-7522
[45] W. C. Zhang, Y. S. Zheng, W. G. Wang, Q. Y. Zheng, Z. T. Huang. Syntheses of chiral calix[4]arene derivatives bearing amino acid residue. Chin. J. Chem., 2003, 21(7): 931-936
[46] S. S. Ben, R. Baudry, C. P. Felix, M. B. A. Giudicelli, R. J. Lamartine. Synthesis and structure of lower rim C-linked tetra-N-tosyl peptidocalix[4]arenes. Tetrahedron Lett., 2004, 45(41): 7801-7804
[47] G. Z. Zhang, Z. C. Li, M. Wang, J. Q. He, J. P. Cheng. Design and synthesis of novel amino acid-bearing macrocyclic calix[4]arenes. Synth. Comm. 2004, 34(19): 3615-3621
[48] H. Xu, G. R. Kinsel, J. Zhang, M. L. Li, D. M. Rudkevich. Calixarene amino acids; building blocks for calixarene peptides and peptide-dendrimers. Tetrahedron, 2003, 59(31): 5837-5848
[49] C. Gaeta, M. D. Rosa, M. Fruilo, A. Soriente, P. Neri. Synthesis of calix[4]arene derivatives bearing chiral pendant groups as ligands for enantioselective catalysis. Tetrahedron: Asymmetry, 2005, 16(13): 2333-2340
[50] G. Y. Qing, Y. B. He, Y. Zhao, C. G. Hu, S. Y. Liu, X. Yang. Calix[4]arene-based chromogenic chemosensor for the α-phenylglycine anion: synthesis and chiral recognition. Eur. J. Org. Chem., 2006, 6: 1574-1580
[51] I. I. Stoikov, S. A. Repejkov, I. S. Antipin, A. I. Konovalov. Lipophilic aminophosphonates and their calix[4]arene derivatives: synthesis and membrane transport of biorelevant species. Heteroatom Chem., 2000, 11(7): 518-527
[52] F. Liu, G. Y. Lu, W. J. He, J. Hu, Y. H. Mei, L. G. Zhu. Synthesis of calix[4]arene derivatives with alkyl guanidinium or chiral bicyclic guanidinium. Synthesis, 2001, 4: 607-611
[53] Y. B. He, Y. J. Xiao, L. Z. Meng, Z. Y. Zeng, X. J. Wu, C. T. Wu. New type chiral calix[4](aza)crowns: synthesis and chiral recognition. Tetrahedron Lett., 2002, 43(35): 6249-6253
[54] S. J. Kim, B. H. Kim. Syntheses and structural studies of calix[4]arene-nucleoside and calix[4]arene-oligonucleotide hybrids. Nucleic Acids Research, 2003, 31(11): 2725-2734
[55] 肖元晶，吴晓军，曾振亚，何永炳，孟令芝，吴成泰．一类新型四酰胺杯[4]氮杂冠醚的合成及阴离子识别研究．化学学报，2003，61(12)：1986-1990
[56] C. Sergiy, V. Andriy, M. Iryna, S. Alexander, K. Valery, L. Janusz, K. Vitaly. Calix[4]areneaminophos-phonic acids: asymmetric synthesis and enantioselective inhibition of an alkaline phosphatase. Org. Lett., 2006, 8(4): 549-552
[57] Y. B. He, J. F. Li, Y. J. Xiao, L. H. Wei, X. J. Wu, L. Z. Meng. Synthesis and chiral recognition of a new type of chiral calix[4]arene derivatives. Chin. J. Chem., 2003, 21: 83-86
[58] S. Cherenok, A. Vovk, I. Muravyova, A. Shivanyuk, V. Kukhar, J. Lipkowski, V. Kalchenko. Calix[4]arene-aminophosphonic acids: asymmetric synthesis and enantioselective inhibition of an alkaline phosphatase. Org. Lett., 2006, 8(4): 549-552
[59] 郑炎松，张春，梅付名，李光兴．杯[4]芳烃半冠醚的合成．华中科技大学学报(自然科学版)，2003，31(12)：114-116
[60] 郑炎松，张春．手性杯[4]芳烃氨基醇的合成及自组装．化学学报，2004，62(6)：537-539
[61] S. S. Ben, C. Felix, M. B. Giudicelli, F. Vocanson, M. Perrin, R. Lamartine. Synthesis, structure and anion binding properties of lower rim-hydroxy amide calix[4]arene derivatives. Tetrahedron Lett., 2005, 46(34): 5659-5663
[62] 孟令芝，梅功雄，何永炳，曾振亚，刘顺英．新型四酰胺杯[4]氮杂冠醚的合成及对阴离子的光化学传感性质研究．化学学报，2005，63(5)：16-420
[63] A. Sirit, E. Kocabas, S. Memon, A. Karakucuk, M. Yilmaz. Synthesis and metal ion recognition properties of a novel chiral calix[4](azoxa)crown-7. Supramol. Chem., 2005, 17(3): 251-256
[64] Y. S. Zheng, C. Zhang. Exceptional chiral recognition of racemic carboxylic acids by calix[4]arenes bearing optically pure, α,β-amino alcohol groups. Org. Lett., 2004, 6(8): 1189-1192
[65] S. A. Fernandes, F. F. Nachtigall, M. Lazzarotto, F. Y. Fujiwara, A. J. Marsaioli. Non-covalent synthesis' of a chiral host of calix[6]arene and enantiomeric discrimination. Magnetic Resonance in Chem., 2005, 43(5): 398-404
[66] U. Darbost, X. S. Zeng, M. Giorgi, I. Jabin. Optically pure calix[6]tris- ammoniums: syntheses and host-guest properties toward neutral guests. J. Org. Chem., 2005, 70(25): 10552-10560
[67] P. A. Reddy, C. D. Gutsche. Calixarenes. 32. reactions of calix[4]quinines. J. Org. Chem., 1993, 58(12): 3245-3251
[68] W. Verboom, P. J. Bodewes, G. Van Essen, P. Timmerman, G. J. V. Hummel, S. Harkema, D. N. Reinhoudt. A novel approach to inherently chiral calix[4]arenes by direct introduction of a substituent at the meta position. Tetrahedron, 1995, 51 (2): 499-512
[69] C. Dieleman, S. Steyer, C. Jeunesse, D. Matt. Diphosphines based on an inherently chiral calix[4]arene scaffold: Synthesis and use in enantioselective catalysis. J. Chem. Soc., Dalton Transactions, 2001, 17: 2508-2517
[70] M. T. Blanda, L. Edwards, R. Salazar, M. Boswell. Synthesis and characteri- zation of an inherently chiral calix[6]arene in the 1,4-alternate conformation. Tetrahedron Lette., 2006, 47(39): 7081-7084
[71] J. Luo, Q. Y. Zheng, C. F. Chen, Z. T. Huang. Synthesis and optical resolution of a series of inherently chiral calix[4]crowns with cone and partial cone conformations. Chem. Eur. J., 2005, 11(20): 5917-5928
[72] S. T. Ganjali, M. Shafai, M. Khosravi. Simple synthetic strategy to inherently chiral calix[4]arene by an asymmetric calix[4]quinone as a key intermediate. Acta Chim. Slovenica, 2002, 49(4): 903-908
[73] S. Y. Li, Q. Y. Zheng, C. F. Chen, Z. T. Huang. Fluorescent probes of D-(+)-gluconic acid δ5-lactone based on binary hosts of chiral calix[5]arene. Tetrahedron: Asymmetry, 2005, 16(16): 2816-2820
[74] 郑炎松．杯芳烃的配位性质．化学进展，1999，11(3)：275-285
[75] 陈淑华，李东红，袁立华，赵华明．杯芳烃类受体的分子识别作用研究进展．有机化学，1999，19(4)：339-347
[76] A. Arduini, B. Elisabetta, G. Giovanna, P. Andrea, S. Andrea. Recognition of guests bearing donor and acceptor hydrogen bonding groups by heteroditopic calix[4]arene receptors. Tetrahedron, 2003, 59(38): 7587-7594
[77] L. Zhang, Y. Zhang, H. B. Tao, X. J. Sun, Z. J. Guo, L. G. Zhu. Investigation of calix[4]arene-porphyrin and its palladium(Ⅱ) and zinc(Ⅱ) complexes at air/water interface and in langmuir-nlodgett film. Thin Solid Films, 2002, 413(1-2): 224-230
[78] 毛锋旺，胡晓钧，钱洪平，姚天明，施宪法．杯芳烃衍生物对K+和电子的耦合液膜传输．物理化学学报，2004，20(10)：1271-12741
[79] E. Akceylan, M. Yilmaz, R. A. Bartsch. Immobilization of cyclic alkyla- mine calix[4]arene derivatives on Merrifield resin: evaluation of extraction ability toward dichromate. J. Macromolecular Science, Part A: Pure and Applied Chemistry, 2006, 43(3):477-486
[80] X. J. Li, Z. R. Zeng, Y. Xu. A solid-phase microextraction fiber coated with diglycidyloxycalix[4]arene yields very high extraction selectivity and sensitivity during the analysis of chlorobenzenes in soil. Analytical and Bioanalytical Chemistry, 2006, 384(6): 1428-1437
[81] 孟冠华，王锦堂．杯芳烃的催化性质及其在有机反应中的应用．化工时刊，2003，17(7)：9-13
[82] 孟祥启，冯亚青，孟舒献，张宝．杯芳烃作为相转移催化剂用于四氟对苯二甲酸二甲酯的合成．化学试剂，2006，28(1)：5-7
[83] 赵芳，梁斌，刘道杰．杯芳烃催化剂的研究进展．信阳师范学院学报，2003，19(3)：364-367
[84] M. R. Yaftian, H. Abdollahi, R. Shokouhi. Ion binding properties of 5, 11,17,23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-bis(diphenylphosphinoylmethoxy)calix[4]a rene towards alkaline-earth cations. Chem. Anal., 2007, 52(1): 103-113
[85] M. R. Yaftian, S. Rayati, D. Emadi, D. Matt. A coated wire-type lead(Ⅱ) ion-selective electrode based on a phosphorylated calix[4]arene derivative. Anal. Sci., 2006, 22(8): 1075-1078
[86] L. X. Chen, J. Zhang, W. F. Zhao, X. W. He, Y. Liu. Double-armed calix[4]arene amide derivatives as ionophores for lead ion-selective electrodes. J. Electroanal. Chem., 2006, 589(1): 106-111
[87] 郑炎松，沈之荃．杯芳烃的催化性质．化学通报，1998，61(4)：27-32
[88] 王腾凤，杨世柱．杯芳烃催化剂在有机反应中的应用．化学试剂，2000，22(5)：274-278
[89] I. Vijaykumar, V. Francis, M. Claude, J. R. Nicole. Capacitive sensing of amino acids using caliraxene-coated silicon transducers. Electroanalysis, 2007, 19(4): 510-514
[90] P. Leyton, C. Domingo, S. C. Sanchez, M. V. Campos, G. F. Diaz, J. V. R. Garcia. Reflection-absorption IR and surface-enhanced IR spectroscopy of tetracarboethoxy t-butyl-calix[4]arene, as a host molecule with potential applications in sensor devices. Vibrational Spectroscopy, 2007, 43(2): 358-365
[91] 陈朗星，徐华，李一峻，何锡文．杯芳烃化学传感器的研究进展．分析化学，2000，28(2)：232-239
[92] 林琳，吴采樱．杯芳烃衍生物在分析化学中的应用．分析化学，1997，25(7)：850-856
[93] 李来生，达世禄，冯钰琦，刘敏．杯芳烃在液相色谱、毛细管电泳和电色谱中的应用进展．化学进展，2005，17(3)：523-530
[94] 狄晓威，何锡文，曾宪顺，邹本东．硒功能化杯芳烃载体银离子选择性膜电极的研究．分析化学，2004，32(4)：430-434
[95] F. J. Sr. Ludwiq, A. G. Jr. Bailie. Liquid chromatographic separation of p-alkylphenol-formaldehyde cyclic and linear oligomers. Anal. Chem., 1984, 56(12): 2081-2085
[96] F. J. Sr. Ludwiq, A. G. Jr. Bailie. Reversed-phase Liquid chromatographic separation of p-tert-butylphenol-formaldehyde linear and cyclic oligomers. Anal. Chem., 1986, 58(9): 2096-2072
[97] P. K. Zarzycki. Normal- and reversed-phase thin-layer chromatography of selected calixarenes and pyrene. J. Planar Chromatography-Modem TLC, 2001, 14(2): 113-118
[98] T. Jin, K. Monde. Synthesis and optical resolution of a fluorescent chiral calix[4] arene with two pyrene moieties forming an intramolecular excimer. Chem. Commun., 1998, 13: 1357-1358
[99] S. T. Pickard, W. H. Pirkle, M. Tabatabai, W. Vogt, V. Boehmer. Dissymmetric calix[4]arenes: Optical resolution of some conformationally fixed derivatives. Chirality, 1993, 5(5): 310-314
[100] K. Iwamoto, H. Shimizu, K. Araki, S. Shinkai. Syntheses and optical resolution of calix[4]arenes with molecular asymmetry. Systematic classification of all possible chiral isomers derivable from calix[4]arene. J. Am. Chem. Soc., 1993, 115(10): 3997-4006
[101] H. Otsuka, S. Shinkai. Definitive evidence for inhibition of calix[6]arene ring inversion obtained from a 1,3-xylenyl-bridged chiral calix[6]arene. J. Am. Chem. Sot., 1996, 118(18): 4271-4275
[102] J. Gloede, I. Keitel, B. Costisella, A. Kunath, M. Schneide. Inharent chirale 1,2-verbruckte calix[4]aren-diphosphate-Synthese, eigenschaften und isomerentrennung. Phosphorus, Sulfur and Silicon and Related Elements. 1996, 117: 67-88
[103] S. Pappalardo, S. Caccamese, L. Giunta. Stereoselective synthesis and optical resolution of chiral calix[4]arenes with mixed ligating functionalities. Tetrahedron Lett., 1991, 32(52): 7747-7750
[104] A. N. Francoise, C. Salvatore, F. Saowarux, P. Sebastiano, P. F. Melchiorre, P. Ada, P. Grazia. Synthesis, Optical resolution and complexation properties of inherently chiral monoalkylated p-tert-Butyl-(1,2)-calix[4]crown ethers. J. Org. Chem., 1997, 62(23): 8041-8048
[105] S. Caccamese, A. Notti, S. Pappalardo, M. F. Parisi, G. Principato. Inherently chrial α-picolyloxy-p-tert-butylcalix[5]arene crowm ethers: synthesis, structure proof and enantioselective HPLC resolution. Tetrahedron, 1999, 55: 5505-5514
[106] S. Caccamese, A. Bottino, F. Cunsolo, S. Parlato, P. Neri. Resolution of inherently chrial calyx[4]arenas with AABB and CDCD substitution patterms on the upper and lower rims, respectively. Teteahedron: Asymmetry, 2000, 11: 3103-3112
[107] S. Caccamese, A. Notti, S. Pappalardo, M. F. Parisi, G. Principato. Synthesis and host properties of (1,3)-p-tert-butylcalix[5]crown-6 derivatives incorporating the 1,1'-binaphthalene-2,2'-dioxy subunit. J. Inclusion Phenomena, 2000, 36(1): 67-78
[108] N. Morohashi, N. Iki, T. Onodera, C. Kabuto, S. Miyano. Novel molecular chriality in the calixarene family: formation of chrial disulfinyldithiacalix[4]arenas. Tetrahedron Lett., 2000, 41: 5093-5097
[109] 刘英，达世禄，陈远荫．C60键合硅胶液相色谱固定相的合成及其性能评价．色谱，1998，16(2)：115-117
[110] 冯钰锜，胡玉铃，李建森，刘英，达世禄，陈远荫．用C60键合硅胶固定相液相色谱分离杯芳烃及杯芳冠醚类化合物．分析测试学报，2000，19(2)：1-4
[111] Y. Saito, H. Ohta, H. Terasaki, Y. Katoh, H. Nagashima, K. Jinno, K. Itoh, R. D. Trengove, J. Harrowfield, S. F. Y. Li. Separation of calixarenes with a chemically bonded C60 silica stationary phase in microcolumn liquid chromatography. J. High Resolut. Chromatogr., 1996, 19(8): 475-477
[112] K. Jinno, K. Tanabe, Y. Saito, H. Nagashima, R. D. Trengove. Retention behavior of calixarenes with various C60 bonded silica phases in microcolumn liquid chromatography. Anal. Commun., 1997, 34(6): 175-177
[113] O. I. Kalchenko, J. Lipkowski, R. Nowakowski, V. I. Kalchenko, M. A. Visotsky, L. N. Markovsky. Studies on the behavior of some phosphorus-contained calix[n]arenes in reversed-phase high-performance liquid chromatography. J. Chromatogr. Sci., 1997, 35(2): 49-52.
[114] O. I. Kalchenko, M. O. Tairov, M. O. Vysotsky, J. Lipkowski, V. I. Kalchenko. Optical resolution of phosphorus containing calix[4]arenes by additive RP HPLC method. Enantiomer, 2000, 5(3-4): 385-390
[115] S. J. Thibodeaux, P. M. Sanchez, Y. Zhang, S. A. Shamsi, I. M. Warner. Separation and identification of chiral N-acyl calix[4]arene amino acid derivatives by use of reversed-phase HPLC. Chromatographia, 1999, 49(3-4): 142-146
[116] B. F. Graham, J. M. Harrowfietd, R. D. Trengove, I. Rodriguez, S. F. Y. Li. Comparison of supercritical fluid chromatographic and high-performance liquid chromatographic separations of p-tert-butylcalixarenes. J. Chromatogr. Sci., 1997, 35:232
[117] S. F. Y. Li, B. F. Graham, R. D. Trengove. Liquid-chromatographic separation of calixarenes. J. Liq. Chromatogr. & Relat. Technol.. 1997, 20(8): 1197-1209
[118] C. Agena, C. Wolff, J. Mattay. First Synthesis, isolation and complete charac- terization of both enantiomers of inherently chiral resorc[4]arenes by monofunctionalization. Eur. J. Org. Chem. 2001, 15: 2977-2981
[119] G. McMahon, R. Wall, K. Nolan, D. Diamond. Characterisation of the ester-substituted products of the reaction of p-t-butyl calix[4]arene and ethyl bromoacetate using LC-UV-MS and LC-DAD. Talanta, 2002, 57(6): 1119-1132
[120] B. Schazmann, G. McMahon, K. Nolan, D. Diamond. Identification and recovery of an asymmetric calix[4]arene tetranitrile derivative using liquid chromatography and mass spectrometry. Supramolecular Chem., 2005, 17(5): 393-399
[121] C. K. Jankowski, M. -R. Van Calsteren, N. Aychet, J. F. Dozol, C. Moulin, C. Lamouroux. Study of the nitration of di-n-octylcrown-6 calix[4]arene using LC-MS, NMR, and molecular modelling. Canadian J. Chem. 2005, 83(8): 1098-1113
[122] Y. L. Zhang, I. M. Warner. Separation of water-soluble p-sulfonated calixarenes 4, 6 and 8 and 4-hydroxybenzene sulfonate by use of capillary zone electrophoresis. J. Chromatogr. A, 1994, 688: 293-300
[123] 韩珀．非水毛细管电泳的应用．郑州大学学士学位论文，2004
[124] C. G. Fu, A. L. Liu, Y. F. Zhao, L. Y. Zhang. Determination of sulfonated calixarenes by capillary electrophoresis with sample stacking enrichment. Lihua Jianyan, Huaxue Fence, 2005, 41(9): 658-660
[125] 沈家骢，孙俊奇．超分子科学研究进展．中国科学院院刊(学科发展)，2004，19(6)：420-424
[126] 闫有旺．化学学科的前沿-超分子化学．2003，11：32-33
[127] 谭倪．谈超分子化学与生物有机化学．怀化学院学报，2002，21(2)：31-33
[128] 张中强，涂华民，葛旭升．超分子化学的研究和进展．河北师范大学学报(自然科学版)，2006，30(4)：453-458
[129] 闫丽．超分子化学．世界科学，2003，4：6-8
[130] 张穗娟，李琼芳，李如芳．关于超分子化学．广东化工，2004，6：36-37
[131] 张希，沈家骢．超分子科学：认识物质世界的新层面．科学通报，2003，48(14)：1477-1478
[132] 胡伟光．无机化学，化工工业出版社，2002
[133] 夏泽吉．关于范德华力本质的定量探索．川东学刊，1997，7(2)：81-83
[134] K. Kazuo, M. Keiji. A new energy decomposition scheme for molecular interactions within the Hartree-Fock approximation. International J. Quantum Chem., 1976, 10(2): 325-340
[135] 孙得志，朱兰英，宋兴民．超分子化学选择性分子间力和若干化学研究领域．聊城师院学报(自然科学版)，1998，11(2)：27-33
[136] Y. Liu, L. Li, X. Y. Li, H. Y. Zhang, T. Wada, Y. Inoue. Synthesis of phosphoryl-tethered-cyclodextrins and their molecular and chiral recognition thermodynamics. J. Org. Chem., 2003, 68(9): 3646-3657
[137] J．M．Lehn，沈兴海．超分子化学-概念和展望，北京大学出版社，2002
[138] 许琳．分子间作用力对有机物物理性质的影响．雁北师院学报，1998，14(5)：22-24
[139] 王毓江，唐黎明．基于氢键作用结合的超分子聚合物．化学进展，2006，18(2-3)：308-316
[140] 张建合．疏水凝胶及疏水相互作用研究进展．信阳师范学院学报(自然科学版)，2004，17(2)：237-243
[141] J. Herzfeld. Understanding Hydrophobic Behavior. Science. 1991, 253: 88-90
[142] 李祥春，聂百胜．煤吸附水特性的研究．太原理工大学学报，2006，37(4)：417-419
[143] 沈晓春．色谱保留机理探索与研究．浙江大学硕士学位论文，2002
[144] A. Nicholls, K. A. Sharp and B. Honing. Protein Folding and Association: insights from the interfacial and thermodynamic properties of hydrocarbons. Protein, 1991, (11): 28-29
[145] 陈强，谭民裕，刘伟生．超分子中分子间弱相互作用力的研究方法概述，化学通报，2001，4：236-239
[146] C D. Gutsche, M. Iqbal, I. Alam. The interaction of calixarenes and amines. J. Am.Chem.Soc., 1987, 109: 4314-4320
[147] H. M. Chawla, K. M. Srinivas. Calix(n)arene-quinone interactions: molecular recognition of 2,6-naphthoquinone by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahydroxycalix (6) arene, Tetrahedron, 1995, 51 (9): 2709-2718
[148] 黄志兵，李来生，王宇晓，吴宇梅．荧光法研究对-二甲氨甲基-杯[8]芳烃与二苯胺磺酸钠包结作用．光谱学与光谱分析，2005，25(4)：591-593
[149] P. E. Georghiou, A. H. Tran, S. S. Stroud, D. W. Thompson. Supramolecular complexation studies of [60]fullerene with calyx[4]anphthalenes-a reinvestigation. Tetrahedron, 2006, 62(9): 2036-2044
[150] 唐波，马丽．生物相关物质-主客体识别超分子化学的分子光谱研究及其分析应用．山东师范大学硕士学位论文，2002，4
[151] S. M. Shuang, J. H. Pan, S. Y. Guo, M. Y. Cai, C. S. Liu. Camparative Study on the Inclusion complexation of rutin with cyclodextrin supramolecules. Chin. Chem. Lett., 1997, 8(9): 803-804
[152] L. F. Yao, Z. F. Luo, H. Y. Ma, Z. T. Pan. Spectroscopic study and application on the inclusion complexation of β-cyclodextrin with estradiol benzoate in aqueous solution. Wuhan Daxue Xuebao(Ziran Kexue Ban), 1997, 43(6): 706-710
[153] A. D. Qi, L. Li, Y. Liu. The binding ability and inclusion complexation behavior of curcumin with natural α-, β-, γ-Cyclodextrins and organoselenium-bridged bis(β-cyclodextrin)s. J. Chin. Phar. Sci., 2002, 12(1): 15-20
[154] Y. Liu, B. H. Han, Y. T. Chen. Inclusion complexation of acridine red dye by calixarenesulfonates and cyclodextrins: opposite fluorescent behavior, J. Org. Chem., 2000, 65 (19): 6227-6230
[155] 周叶红．环糊精和杯芳烃的包合特性及其在药物中的应用．山西大学硕士学位论文，2006
[156] 古俊，张勇，潘景浩．电化学方法研究环糊精与酮洛酚的包结行为．电化学，1998，4(4)：394-399
[157] 张霞，张清，赵迪思，罗川南，周长利．杯芳烃-硝基氯苯包络物的电化学行为研究．济南大学学报(自然科学版)，2005，19(1)：45-47
[158] Haino Takeharu, Yanase Manabu, Fukunaga Chigusa, Fukazawa Yoshimasa. Fullerene encapsulation with calyx[5]arenas. Tetrahedron, 2006, 62(9): 2025-2035
[159] 周稚仙，吴养洁，石雅琳．杯4芳烃衍生物的合成及其包合等性能的研究．郑州大学硕士学位论文，2002，6
[160] 王小萍，马麦霞，双少敏，张勇，潘景浩．薄层色谱法测定大黄类药物与环糊精的包结常数．分析化学研究简报，2002，30(1)：38-41
[161] 夏之宁，刘毅．分子竞争相互作用的HPLC和毛细管电泳法研究．重庆大学硕士学位论文，2004，4
[162] 朱维良，蒋华良，陈凯先，嵇汝运，曹阳．分子间相互作用的量子化学研究方法．化学进展．1999，11(3)：247-253
[163] 田国才，陶建民，李国宝．分子间相互作用的理论化学研究进展．云南师范大学学报，2002，22(1)：30-33
[164] W. l. Zhu, J. d. Guo, H. l. Jiang. IR spectrum and normal mode analysis of the anti-alzheimer's disease natural product huperzine a: a quantum chemistry density-functionaltheory (DFT) investigation. Science in China(Series B), 1998, 41 (6): 616-622
[165] 蒋华良，朱维良，谭小健，顾健德，陈建忠，林茂伟，陈凯先，嵇汝运．阳离子-π体系相互作用的理论研究-Ⅰ．铵离子-苯复合物构型及相互作用的密度泛函研究．中国科学(B辑)，1998，28(5)：403-409
[166] 朱维良，顾健德，蒋华良，陈建忠，刘东祥，林茂伟，陈凯先，嵇汝运，曹阳．抗早老性痴呆症天然产物石杉碱甲的红外光谱与简正分析-量子化学密度函数理论(DFT)研究．中国科学(B辑)，1998，28(4)：326-331
[167] 朱维良，蒋华良，谭小键，陈建忠，翟宇峰，顾健德，林茂伟，陈凯先，嵇汝运，曹阳．阳离子-π体系相互作用的理论研究-Ⅱ．铵离子-二苯复合物体系的密度泛函研究．化学学报，1999．57：852-859
[168] U. Cosentino, G. Moro, D. Pitea. Ab initio effective core potential calculations on lanthanide complexes: basis sets and electron correlation effects in the study of [Gd-(H2O)9]~(3+). Journal of Molecular Structure(Theochem), 1997, 392: 75-85
[169] M. C. Salazar, J. Paz, A. J. Hernandez. Ab initio test study of the N2…H2 and N2…He van der Waalsdimers. Journal of Molecular Structure (Theochem), 1999, 464: 183-189
[170] M. C. Salazar, J. L. Paz, A. J. Hernandez. Ab initio basis set study of the CO…He van der Waals interaction. Journal of Molecular Structure (Theochem), 1999, 493: 133-137
[171] A. N. Enyashin, Yu. N. Makurin, A. L. Ivanovskii. Ab initio study of dititanium end- ofullerenes: D5d- and D5h-Ti2@C80. Computational Materials Science, 2006, 36: 26-29
[172] X. Y. Ren, Z. Y. Liu, M. Q. Zhu. DFT studies on endohedral fullerene C-C60: C centers the C60 cage. J. Molecular Structure (Theochem), 2004, 710: 175-178
[173] M. I. Ogden, A. L. Rohl, J. D. Gale. An ab initio study of the influence of crystal packing on the host-guest interactions of calix[4]arene crystal structures. Chem. Commun., 2001, 18: 1626-1627
[174] J. I. Choe, S. K. Chang, S. Nanbu. Ab initio study of conformers of p-tert-butylcalix-[4]crown-6-ether complexed with alkyl ammonium cations. Bull. Korean Chem. Soc., 2002, 24(1): 75-80
[175] J. I. Choe, S. K. Chang, M. Satoshi. Ab initio study of conformers of p-tert-Butylcalix[5]arene derivative toward alkyl ammonium cations. Bull. Korean Chem. Soc., 2003, 23(6): 891-895
[176] J. I. Choe, S. H. Lee, D. S. Oh. Ab initio study of complexation behavior of p-tert-butylcalix-[5]arene derivative toward alkyl ammonium cations. Bull. Korean Chem. Soc., 2004, 25(2): 190-194
[177] J. I. Choe, S. H. Lee, D. S. Oh. Ab initio study of conformers of tetramethoxycalix[4]arenas. Bull. Korean Chem. Soc., 2004, 25(1): 55-58
[178] B. Thanaporn, P. Buncha, R. Vithaya. Protonation and energetical investigations of calix[4]-cyclen-benzo-crown-6 and its complexes with zinc and copper. Bull. Korean Chem. Soc., 2004, 25(6) : 819-822
[1] C. D. Gutsche, R. Muthukrishnan. Calixarenes. 1. analysis of the product mixtures produced by the base-catalyzed condensation of formaldehyde with pares-substituted phenols. J. Org. Chem., 1978, 43: 4905-4906
[2] 田振峰，郑炎松．手性杯芳烃的合成及性质．有机化学，2002，22(10)：702-709
[3] 胡晓钧，王丽，任杰，施宪法．硫杂杯芳烃—类新型的分子受体化合物．化学通报，2004，2(1)：90-95
[4] B. T. Hayes, R. F. Hunter. Phenol-formaldehyde and allied resins Ⅵ. rational synthesis of a 'cyclic' tetranuclear p-cresol novolak. J. Appl. Chem., 1958, 8: 743-748
[5] V. Bohmer. Calixarenes, macrocycles with (almost) unlimited possibilities. Angew. Chem. Int. Ed. Engl., 1995, 34: 713-745
[6] H. M. Chawla, K. S. Meena. Calix[n]arene-quinone interactions: molecular recognition of 2,6-naphthoquinine by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahy-droxy calix(6)arene. Tetrahedron, 1995, 51: 2709-2718
[7] N. Morohashi, R. Naito, N. Iki, S. Miyano. Syntheses of inherently chiral monosuifinylt-rithiacalix[4]arenes by the oxidation of one of the bridging sulfurs of a tetrathiacalix[4]- arene fixed in the 1,3-alternate conformation. Israel J. Chem., 2001, 41(4): 303-307
[8] F. Narumi, N. Iki, T. Suzuki, T. Onodera, S. Miyano. Syntheses of chirally modified thiacalix[4]arenes with enantiomeric amines and their application to chiral stationary phases for gas chromatography. Enantiomer, 2000, 5(1): 83-93
[9] Y. B. He, J. F. Li, Y. J. Xiao, L. H. Wei, X. J. Wu, L. Z. Meng. Synthesis and chiral recognition of a new type of chiral calix[4]arene derivatives. Chin. J. Chem., 2003, 21 (1): 83-86
[10] Y. Okada, Z. Miao, M. Akiba, J. Nishimura. Synthesis and characterization of chiral catenanes based on rigid calix[4]arene. Tetrahedron Lett., 2006, 47(16): 2699-2702
[11] Gaeta Carmine, Martino Marco, Neri Placido. Synthesis of the first examples of p-bromodienone and transannular spirodienone calixarene derivatives. Tetrahedron Lett., 2003, 44: 9155-9159
[12] 丁呈华．杯芳烃的合成及其色谱应用研究．郑州大学硕士学位论文，2006
[13] C. D. Gutsche, M. Iqbal. Pentacyclo[19,3.1.13,7.19,13,115,19]octacosa-1(25),3,5,7(28), 9,11, 13(27), 15,17,19(26),21,23-dodecanene-25,26,27,28-tetrol——5,11,17,23-tetrakis(1,1-diethylethyl). Org. Synth., 1990, 68: 234-237
[14] 李建森，陈远荫．对叔丁基杯[6]芳烃合成方法的改进．化学试剂，2000，22(3)：178-183
[15] C. D. Gutsche, B. Dhawan, M. Leonis, D. Stewart. Nonacyclo[43,3.1.13,7.19,13, 115,19, 121,25, 127,31,133,37,139,43]hexapentaconta-1 (49),3,5,7(56),9,11,13 (55), 15,17,19(54),21,23,25(53),27,29,31 (52),33,35,37(51),39,41,43 (50),45,47-tetracosaene-49,50,51,52,53,54,55,56-octo1——5,11,17,23,29,35,41,47-octakis(1,1-dimethylethyl). Org. Synth., 1990, 68: 243-246
[16] C. D. Gutsche, Lee-Gin Lin. Calixarenes 12 The synthesis of functionalized calixarenes. Tetrahedron, 1986, 42(6): 1633-1640
[17] W. Y. Chen, J. Lu, Z. X. Shen, J. P. Lang, L. F. Zhang, Y. W. Zhang. Chiral ferrocenyl amino alcohols: preparation and application as catalysts in the enantioselective reduction of ketones using NaBH_4/I_2. Chin. J. Chem., 2003, 21(2): 192-195
[18] W. Y. Chen, J. Lu, Z. X. Shen, Y. W. Zhang. Catalytic enantioselective reduction of prochiral ketones with chirai ferrocenyl amino alcohols. Chin. J. Chem., 2004, 22(3): 306-309
[19] B. Thierry, C. Jerome, B. Stephanie. Chiral ferrocenyl amino alcohols as catalysts for the enantioselective borane reduction of ketones. Tetrahedron: Asymmetry, 2002, 13: 1241-1243
[20] P. Angela, P. Sonia. Screening of chiral ferrocenyl amino alcohols as ligands for ruthenium-catalysed transfer hydrogenation of ketones. Tetrahedron: Asymmetry, 2003, 14: 597-602
[21] Z. T. Huang, G. Q. Wang. Friedel-grafts reaction ofcalixarenes. Chem. Ber., 1994, 127: 519-523
[22] K. Satish, H. M. Chawla, R. Varadarajan. A one-step, one-pot synthesis of p-acyl calix[n]arenas. Tetrahedron Lett., 2002, 43(14): 2495-2498
[1] Y. Haino, M. Yanase, C. Fukunaga, Y. Fukazawa. Fullerene encapsulation with calix[5]arenas. Tetrahedron, 2006, 62(9): 2025-2035
[2] W. F. Nijenhuis, E. G. Buitenhuis, J. F. De, E. J. R. Sudholter, D. N. Reinhoudt. Calixcrowns as selective potassium cation carriers in supported liquid membranes. J. Am. Chem. Soc. 1991, 113(21): 7963-7968
[3] H. M. Dong, H. Zheng, S. J. Wang, B. X. Ye. Chemically modified electrode with LB film of calixarene and its recognition property. Huaxue Tongbao, 2006, 69: 127-129
[4] A. Wei. Calixarene-encapsulated nanoparticles: self-assembly into functional nanomaterials. Chem. Commun, 2006, 15: 1581-1591
[5] J. H. Lee, G. Kim, M. C. Oh. Polymeric waveguide bio sensors with bragg gratings. Han' guk Kwanghak Hoechi, 2006, 17: 54-59
[6] M. Benounis, R. N. Jaffrezic, H. Halouani, R. Lamartine. Detection of heavy metals by an optical fiber sensor with a sensitive cladding including a new chromogenic calyx[4]arene molecule. Material Science & Engineering, C: Biomimetic and Supramolecular Systems, 2006(2-3), 26: 364-368
[7] 林琳，吴采樱．杯芳烃衍生物在分析化学中的应用．分析化学，1997，25：850-856
[8] T. Zhao, X. B. Hu, J. K. Cheng, Lu X. B.. Use of calix[4]arene to separate positional isomers in capillary electrophoresis. Anal. Chim. Acta, 1998, 358(3): 263-268
[9] T. Sokolieβ, U. Menyes, R. Ulrich, T. Jira. Separation of cis- and trans-isomers of thioxanthene and dibenz[b,e]oxepin derivatives on calixarene- and resorcinarene- bonded high-performance liquid chromatography stationary phases. J. Chromatogr. A, 2002, 948(1-2): 309-319
[10] X. J. Wu, H. X. Liu, H. Liu, S. S. Zhang, P. R. Haddad. Preparation and characterization of p-tert-butylcalix[8]arene bonded capillaries for open-tubular capillary electrochromatography. Anal. Chim. Acta, 2003, 478(2): 191-197
[11] S. Seyhan, O. Ozbayrak, N. Demirel, M. Merdivan, N. Pirinccioglu. Chiral separation of amino acids by chiral octamide derivatives of calixarenes derived from resorcinol by impregnation on a polymeric support. Tetrahedron: Asymmetry. 2005, 16(22): 3735-3738
[12] M. Liu, L. S. Li, S. L. Da, Y. Q. Feng. High performance liquid chromatography with cyclodextrin and calixarene macrocycle bonded silica stationary phases for separation of steroids. Talanta, 2005, 66(2): 479-486
[13] F. J. Ludwiq, A. G. Bailie. Liquid chromatographic separation of p-alkylphenol- formaldehyde cyclic and linear oligomers. Anal. Chem., 1984, 56: 2081-2085
[14] P. K. Zarzycki. Normal-and reversed-phase thin-layer chromatography of selected calixarenes and pyrene. J. Planar Chromatogr. -Modem TLC, 2001, 14: 113-118
[15] F. J. Ludwig, A. G. Bailie. Reversed-phase liquid chromatographic separation of p-tertbutylphenol-formaldehyde linear and cyclic oligomers. Anal. Chem., 1986, 58:2096-2097
[16] Y. Saito, H. Ohta, H. Terasaki, Y. Katoh, H. Nagashima, K. Jinno, K. ltoh, R. D. Trengove, J. Harrowfield, S. F. Y. Li, Separation of calixarenes with a chemically bonded C60 silica stationary phase in microcolumn liquid chromatography. JHRC, 1996, 19(8): 475-477
[17] A. Bianco, F. Gasparrini, M. Maggini, D. Misiti, A. Polese, M. Prato, G. Scorrano, C. Toniolo, C. Villani. Molecular recognition by a silica-bound fullerene derivative. J. Am. Chem. Soc., 1997, 119(32): 7550-7554
[18] Y. Liu, Y. Q. Feng, S. L. Da, Y. Y. Cben. Preparation and evaluation of C60 bonded silica phase for high performance liquid chromatography. J. Chromatogr. A, 1998, 16(2) : 115-117
[19] Y. Q. Feng, Y. L. Hu, J. S. Li, Y. Liu, S. L. Da, Y. Y. Chen. Separation of calixarenes and calixcrowns with a C60 bonded silica stationary phase in normal-phase liquid chromatography. Chin. J. Instrum. Anal., 2000, 19(1): 1-4
[20] O. I. Kalchenko, J. Lipkowski, R. Nowakowski, V. I. Kalchenko, M. A. Visotsky, L. N. Markovsky. Studies on the behavior of some phosphorus-contained calix[n]arenes in reversed-phase high-performance liquid chromatography. J. Chromatogr. Sci., 1997, 35(2): 49-52
[21] S. J. Thibodeaux, P. M. Sanchez, Y. Zhang, S. A. Shamsi, I. M. Warner. Separation and identification of chiral N-acyl calix[4]arene amino acid derivatives by use of reversed-phase HPLC. Chromatographia, 1999, 49(3/4): 142-146
[22] B. F. Graham, J. M. Harrowfield, R. D. Trengove, I. Rodriguez, S. F. Y. Li. Comparison of supercritical fluid chromatographic and high-performance liquid chromatographic separations of p-tert-butylcalix[n]arenes. J. Chromatogr. Sci., 1997, 35: 232-236
[23] I. Rodriguez, S. F. Y. Li, B. F. Graham, R. D. Trengove. Liquid chromatographic separation of calixarenes. Journal of Liquid Chromatography & Related Technologies, 1997, 20(8): 1197-1209
[24] S. Caccamese, Pappalardo and Sebastiano. Direct separation of cone-shaped tri-O-alkylated chiral calix[4]arenes by enantioselective HPLC. Chirality, 1993, 5: 159-163
[25] N. Morohashi, N. Iki, T. Onodera. Novel molecular chirality in the calixarene family: formation of chiral disulfinyldithiacalix[4]arenes via partial oxidation of two adjacent sulfides of tetrathiacalix[4]arene. Tetrahedron Lett., 2000, 41: 5093-5097
[26] S. Caccamese, A. Notti, S. Pappalardo. Inherently chiral a-(picolyloxy)-p-tert-butylcalix-[5]arene crown ethers: synthesis, structure proof, and enantioselective HPLC resolution. Tetrahedron, 1999, 55: 5505-5514
[27] S. Caccamese, A. Bottino, F. Cunsolo. Resolution of inherently chiral calix[4]arenes with AABB and CDCD substitution patterns on the upper and lower rims, respectively. Tetrahedron: Asymmetry, 2000, 11: 3103-3112
[28] Y. L. Zhang, I. M. Warner. Separation of water-soluble p-sulfonated calixarenes 4, 6 and 8 and 4-hydroxybenzene sulfonate by use of capillary zone electrophoresis. J. Chromatogr. A, 1994, 688(1+2): 293-300
[29] I. Rodriguez, H. K. Lee, S. E Y. Li. Capillary electrophoresis separation ofp-sulfonated calix[n]arenes, n=4, 6, 8. Talanta, 1998, 45: 683-691
[30] K. Oshita, T. Takayangagi, M. Oshima. Complex formation analysis of water-soluble calixarenes by capillary zone electrophoresis. J. Chromatogr. A, 2001, 934: 113-122
[31] 傅崇岗，刘爱林，赵艳芳，张立云．样品堆积富集毛细管电泳测定磺化杯芳烃．理化检验-化学分册，2005，41：658-660
[32] 韩珀．非水毛细管电泳的应用．郑州大学学士毕业论文，2004
[33] C. D. Gutsche, M. Iqbal. Pentacyclo[19,3.1.13,7.19,13,115,19]octacosa-1(25),3,5, 7(28),9,11, 13(27),15,17,19(26),21,23-dodecanene-25,26,27,28-tetrol——5,11,17,23-tetrakis(1,1-diethylethyl). Org. Synth., 1990, 68: 234-237
[34] 李建森，陈远荫．对叔丁基杯[6]芳烃合成方法的改进．化学试剂，2000，22(3)：178-183
[35] C. D. Gutsche, B. Dhawan, M. Leonis, D. Stewart. Nonacyclo [43,3.1.13,7.19,13, 115,19, 121,25, 127,31,133,37, 139,43]hexapentaconta-1(49),3,5,7(56),9,11,13(55), 15,17,19(54),21,23,25(53),27,29,31 (52),33,35,37(51),39,41,43(50),45,47-tetracosaene-49,50,51,52,53,54,55,56-octol-5,11,17,23,29,35,4 1,47-octakis(1,1-dimethylethyl). Org. Synth., 1990, 68: 243-246
[36] C. D. Gutsche, L. G. Lin. Calixarenes 12 the synthesis of functionalized calixarenes. Tetrahedron, 1986, 42(6): 1633-1640
[1] G. Liu, X. Y. Pang, R. F. Li. The study about adsorption heat on 5A molecular sievewith reverse gas chromatogram. Guangxi Sciences, 2006, 13(1): 37-39
[2] Y. Y. Zhou, Q. Lu, C. Liu, S. K. She, L. Wang. Spectrofluorimetric study on the inclusion interaction between lomefloxacin and p-sulfonated calix[4]arene and its analytical application. Spectrochimica Acta Part A, 2006, 64(3): 748-756
[3] D. Namor, A. F. Danil, J. Wang, I. Orellana, V. Gomez, F. J. Sueros, D. A. Tanaka. Pacheco. thermodynamic and electrochemical aspects of p-tert-butylcalix(n)arenes (n=4,6,8) and their interactions with amines. J. Inclusion Phenomena and Molecular Recognition in Chem., 1994, 19(1-4): 371-387
[4] F. Sansone, S. Barboso, A. Csanati, D. Sciotto, R. Ungaro. A new chiral rigid cone water soluble peptidocalix[4]arene and its inclusion complexes with α-amino acids and aromatic ammonium cations. Tetrahedron Lett., 1999, 40(25): 4741-4744
[5] 李来生，黄志兵，刘旭，王宇晓．高效液相色谱法研究水溶性杯[8]芳烃与二苯胺磺酸钠的相互作用．分析化学研究简报，2005，23(4)：509-511
[6] 赵邦屯，张衡益，刘育．杯芳烃的配位热力学研究进展．洛阳师范学院学报，2003，5：30-38
[7] 施介华，江峰，严巍，王纪康，王桂林．烃类化合物在不同色谱柱上的定量结构-保留相关性研究．分析化学研究报告，2005，33(2)：181-186
[8] 薄涛，杨学东，贡素萱，李克安，刘虎威．毛细管区带电泳分离山酮类化合物的结构、电泳迁移定量关系研究．色谱，2003，21(6)：535-540
[9] 张燕玲，郭亦然，王耘，乔延江．化合物色谱保留参数与其三维结构关系的研究．色谱，2005，23(3)：223-228
[10] 陈景文，杨丽红，王连生．苯砜基环烷酸酯类化合物的分子结构与色谱保留的定量关系．分析化学研究简报，1997，25(2)：189-192
[11] 郄毅巍，李江波，曹维良，张敬畅，刘华．环醇和酯的定量结构一保留关系的研究．北京化工大学学报，2003，30f3)：85-88
[12] J. Jiskra, H. A. Claessens, C. A. Cramers, R. Kaliszan. Quantitative structure-retention relationships in comparative studiesof behavior of stationary phases under high-performance liquidchromatography and capillary electrochromatography conditions. J. Chromatogr. A, 2002, 977(2): 193-206
[13] B. Tomasz, K. Roman. Predictive approaches to gradient retention based on analyte structural descriptors from calculation chemistry. J. Chromatogr. A, 2003, 987(1-2): 29-37
[14] F. Ruggieri, A. D. Archivio, G. Carlucci, P. Mazzeo. Application of artificial neural networks for prediction of retention factorsof triazine herbicides in reversed-phase liquid chromatography. J. Chromatogr. A, 2005, 1076(1-2): 163-169
[15] R Mnuk, L. Feltl. Gas chromatographic study of the inclusion properties of calixarenes Ⅰ. p-tert.-Butylcalix[4]arene in a micropacked column. J. Chromatogr. A, 1995,696(1): 101-112
[16] P. Mnuk, L. Feltl, V. Schuring. Gas chromatographic study of the inclusion properties of calixarenes Ⅱ. Selective properties of cyclic tetra- to octamers derived from phenol, and some provlems associated with the use of calixarenes in capillary gas chromatography. J. Chromatogr. A, 1996, 732(1): 63-74
[17] 张兵，商志才，赵文娜，邹建卫，胡桂香，俞庆森．5-芳基乙内酰脲类化合物QSERR研究．物理化学学报，2003，19(10)：938-943
[18] 张青，赵洪霞，陈吉平，梁鑫淼．多氯联苯的正辛醇-空气分配系数与气相色谱保留参数的关联．色谱，2005，23(5)：441-444
[19] M. Muller, W. Kordel. Comparison of screening methods for the estimation of adsorption coefficients on soil. Chemosphere, 1996, 32(12): 2493-2504
[20] G. Bazylak, L. J. Nagels. A novel potentiometric approach for detection of beta-adrenergics and beta-adrenolytics in high-performance liquid chromatography. Farmaco, 2003, 58(8): 591-603
[21] W. Du, G. S. Yang, X. Q. Wang, S. L.Yuan, L. Zhou, D. Xu, C. P. Liu. Enantioseparation of 15 organic phosphonate esters on the cellulose tris(3,5-dimethylphenyl carbamate) chiral stationary phase by HPLC. Talanta, 2003, 60: 1187-1195
[22] 王晓荣，堵锡华．~mB对气相色谱保留指数的QSPR研究．南京工业大学报，2002，24(3)：31-37
[23] 颜冬云，蒋欣，赵振华，余贵芬，谷成刚．运用QSPR预测有机磷农药的色谱保留值．环境化学，2006，25(2)：220-224
[24] B. T. Luke. Comparison of different data set screening methods for use in QSAR/QSPR generation studies. J. Molecular Structure (Theochem), 2000, 507: 229-238
[25] B. T. Luke. Comparison of three different QSAR/QSPR generation techniques. J. Molecular Structure (Theochem), 1999, 468 (1-2): 13-20
[26] J. W. Chen, Q. G. Huang, L. S. Wang, H. M. Hu, Z. Zhang. Using aml hamiltonian and factor analysis in prediction of partition properties for phenylthio,phenylsulfinyl and phenylsulfonyl acetates. Chemosphere, 1996, 33(12): 2565-2575
[27] A. Dominik, H. J. Roth, K. D. Schierbaum, W. Goepel. Supramolecular complexes based on calixarenes: force field calculations and applications for chemical sensors. Supramolecular Sci., 1994, 1(11): 11-19
[28] M. C. Salazar, J. L. Paz, A. J. Hernandez. Ab initio basis set study of the CO...He van der waais interaction. J. Molecular Structure (Theochem), 1999, 493: 133-137
[29] M. C. Salazar, J. Paz, A. J. Hernandez. Ab initio test study of the N_2...H_2 and N_2...He van der waals dimmers. J. Molecular Structure (Theochem), 1999, 464: 183-189
[30] 缪方明，宿秀梅，齐强．β-环糊精-三乙醇胺超分子体系的量子化学从头计算研究．天津师范大学学报(自然学报)，2003，23(1)：1-3
[31] 沈晓春，朱龙华，张树生．量子化学方法在色谱分析中的应用．中国计量学院学报，2003，14(1)： 296-299
[32] 李丹妮，练鸿振，康玉芬，缪强．量子化学计算预测高效液相色谱键合相的保留机理．分析科学学报，2005，21(6)：591-595
[33] 沈晓春，陈平，郭伟强，冷桃花，董明利．用毛细管电泳方法分离有机酸的研究．浙江大学学报，2002，29(6)：679-684
[34] K. Takenaka, Y. Obora, L. H. Jiang. Solid-state and solution structures of calix[4]arene tetramethyl ethercontaining four diphenylphosphino moieties at the upper rim. Bull. Chem. Soc. Jpn., 2001, 74: 1709-1715
[35] 李勇，郑衍昭，郭金梁，宋心琦．杯[4]芳烃的构象间转换机理的CNDO／2法研究．物理化学学报，1995，11(7)：627-631
[36] G. Nemethy, H. A. Scheraga. The structure of water and hydrophobic bonding in proteins. Ⅲ. the thermodynamic properties of hydrophobic bonds in proteins. J. Physical Chem., 1962, 66: 1773-1789
[37] P. D. Ross, S. Subramanian. Thermodynamics of protein association reactions: forces contributing to stability. Biochem., 1981, 20(11): 3096-3102
[2] C. D. Gutsche, R. Muthukrishnan. Calixarenes. 1. analysis of the product mixtures produced by the base-catalyzed condensation of formaldehyde with pares-substituted phenols. J. Org. Chem., 1978, 43: 4905-4906
[3] R. S. Donald, K. Mariusz, P. K. Ram, H. W. William, C. D. Gutsche. Conformational characteristics of ethers and esters of p-tert-butylcalix[5]arene. J. Am. Chem. Soc., 1995, 117(2): 586-601
[4] V. Bohmer, G. Ferguson, M. Frings. 4,12,16,24-Tetrahydroxy calix[4]arene-methanol (1/2). Acta Crystallographica, Section C: Crystal Structure Commun. 1997, C53(9): 1293-1295
[5] S. Noa, E. B. Silvio. Proximal regioselectivity of the O,O'-dialkylation of tetrahydroxy ketocalix[4]arene. J. Org. Chem., 2005, 70(13): 5278-5282
[6] C. D. Gutsche, B. Dhawan, K. H. No, R. Muthukrishnan. Calixarenes. 4. the synthesis, characterization, and properties of the calixarenes from p-tert-butylphenol. J. Am. Chem. Soc., 1981, 103: 3782-3792
[7] B. T. Hayes, R. F. Hunter. Phenol-fon: naldehyde and allied resins Ⅵ. Rational synthesis of a 'cyclic' tetra-nuclear pcresolnovolak. J. Appl. Chem., 1958, 8: 743-748
[8] V. Bohmer. Calixarenes, macrocycles with (almost) unlimited possibilities. Angew. Chem. Int. Ed. Engl., 1995, 34: 713-745
[9] M. Hedidi, S. M. Hamdi, M. Tassadit. Microwave-assisted synthesis of calix[4]resorcinarenes. Tetrahedron, 2006, 62(24): 5652-5655
[10] 戈云，颜朝国．间苯二酚杯芳烃树枝醇类化合物的合成．有机化学，2005，25(4)：414-418
[11] 戈云，颜朝国．杯[4]间苯二酚芳烃Schiff碱衍生物的合成及其离子萃取性能．高等化学学报，2004，25(10)：1836-1839
[12] 吴萍，程爱民，汪浩，颜朝国．连苯三酚型杯芳烃及其酯类衍生物的合成．安徽大学学报，2005，29(6)：70-74
[13] G. Thorsten, I. Waldemar, A. Ceno, F. Roland, K. Sirpa, N. Christian, M. Jochen. Self-assembly of 2,8,14,20-tetraisobutyl-5,11,17,23-tetrahydroxyresorc[4]arene. Eur. J. Org. Chem., 1999, 9: 2257-2262
[14] L. Avram, Y. Cohen. Hexameric cap sules of L ipophilic Pyrogallolarene and Resorcinarerue in Solutions as Probed by Diffusion NMR: One HydroxylMakes the Pifference. Org. Lett., 2003, 5 (18): 3329-3332
[15] P. E. Georghiou, M. Ashram, Z. P. Li, S. G. Chaulk. Syntheses of Calix[4]naphthalenes Derived from 1-Naphthol. J. Org. Chem., 1995, 60(22): 7284-7289
[16] C. L. Zhang, Y. Jin, S. L. Gong. Syntheses and coordination properties of (thia)calix[4]arenes bearing single-quinolin-8-yl-oligooxyethylene pendant. J. Chem. Res., 2006, 9: 596-599
[17] B. Vandana, B. J. Nagendra, K. Manoj. Synthesis and binding studies of novel thiacalixpodands and bisthiacalixarenes having O,O″-dialkylated thiacalix-[4]are ne unit(s) of 1,3-alternate conformation. Tetrahedron Lett., 2007, 48(9): 1581-1585
[18] P. C. Carol, Y. Takehiko. 1,3-alternate- thiacalix[4]arene-based dimer: syn- thesis and inclusion behavior. Chem. Engineering Comm., 2006, 193(10): 1185-1193
[19] 顾金英，李延军，施宪法，计亮年．含硫杂杯芳烃的高聚物的合成、表征及对Pb2+的传输作用．高分子材料科学与上程，2006，22(4)：80-83
[20] 黄翠玉，杨发福，赵夏．硫杂杯[4]芳烃酰胺基硫脲衍生物的合成．合成化学，2006，14(3)：264-265
[21] N. Iki, H. Kumagai, N. Morohashi, K. Ejima, M. Hasegawa, S. Miyanari, S. Miyano. Selective oxidation of thiacalix[4]arenes to the sulfinyl- and sulfonylcalix[4]arenes and their coordination ability to metal Ions. Tetrahedron Lett., 1998, 39: 7559-7562
[22] F. Narumi, N. Iki, T. Suzuki, T. Onodera, S. Miyano. Syntheses of chirally modified thiacalix[4]-arenes with enantiomeric amines and their application to chiral stationary phases for gas chromatography. Enantiomer, 2000, 5(1): 83-93
[23] N. Iki, S. Miyano. Yhiacalixarenes. Novel host compounds with high versatility. Chem. Soc. Japan-Chem. & Industr. Chem. J., 2001, 11: 613-622
[24] N. Morohashi, R. Naito, N. Iki, S. Miyano. Synthesis of inherently chiral monosulfinyltrithiacalix[4]arenes by the oxidation of one of the bridging sulfurs of a tetrathiacalix[4]arene fixed in the 1,3-alternate conformation. Israel J. Chem., 2001, 41(4): 303-307
[25] J. Lang, H. Dvorakova, I. Bartosova, P. Lhotak, I. Stibor, R Hrabal. Conformational flexibility of a novel tetraethylether of thiacalix[4]arene. A comparison with the "classical" methylene-bridged compounds. Tetrahedron Lett., 1999, 40: 373-376
[26] 褚惠虹，王谨，潘志刚，胡晓钧，顾金英，施宪法．硫杂杯芳烃及其衍生物的合成与表征．有机化学，2003，23：1255-1259
[27] N. Morohashi, E Narumi, N. Iki, T. Hattori, S. Miyano. Thiacalixar-enes. chemical reviews, 2006, 106(12): 5291-5316
[28] V. Stastny, I. Stibor, H. Dvorakova, P. Lhotak. Synthesis of (thia)calix[4]arene oligomers: towards calixarene-based dendrimers. Tetrahedron, 2004, 60: 3383-3391
[29] 胡晓钧，王丽，任杰，施宪法．硫杂杯芳烃—类新型的分子受体化合物．化学通报，2004，2：90-95
[30] J. L. Sessler, P. J. Anzenbacher, K. Jursikova, H. Miyaji, J. W. Genge, N. A. Tvermoes, W. E. Allen, J. A. Shriver, P. A. Gale, V. Krat. Functionalized calix[4]pyrroles. Pure and Appl. Chem., 1998, 70(12): 2401-2408
[31] G. Cafeo, F. H. Kohnke, G. L. La Torre. Calix[6]pyrrole and hybrid calix [n] furan [m] pyrroles (n+m=6): Syntheses and Host-guest. J. Chem., 2002, 8 (14): 3148-3156
[32] N. M. Leonid, A. V. Miroslav, V. P. Vladimir, I. K. Vitaly, L. Januzh, A. S. Yury. Phosphorotropic rearrangement in synthesis of asymmetrically-substituted calix[4]-arenas. Chem. Comm., 1996, 69-72
[33] H. M. Chawla, K. S. Meena. Calix[n]arene-quinone interactions: Molecular recognition of 2,6-naphthoquinine by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41, 42-hexahy-droxycalix (6) arene. Tetrahedron, 1995, 51: 2709-2718
[34] Zhong C., Y. L. Zheng, F. C. Gong, S. Long, R Chen, X. C. He. Recognition of alkyl ketone molecules based on thickness-shear-mode acoustic sensors with calixarene derivatives. Microchemical J., 2007, 86(1): 1-9
[35] 张德华，吕鉴泉．芘冠醚双功能化杯[4]芳烃的合成与表征．化学试剂，2006，28(10)：627-628
[36] Agnihotri Pragati, Suresh Eringathodi, Paul Parimal, Ghosh Pushpito K. Synthesis, Crystal Structures, Cation-Binding Properties and the Influence of Intramolecular C-H…O Interactions on the Complexation Behaviour of a Family of Cone p-tert-Butylcalix [4]arene-crown-5 Compounds. Eur. J. Inorg. Chem., 2006, 17: 3369-3381
[37] 黄章杰，胡秋粉，杨光宇，尹家元．新显色剂8-[杯(4)芳烃偶氮]氨基喹啉的合成及其与金的 显色反应．分析实验室，2003，22(1)：75-77
[38] F. Karci, I. Sener, H. Deligoz. Azocalixarenes. 1: synthesis, characterization and investigation of the absorption spectra of substituted azocalix[4]arenas. Dyes and Pigments, 2003, 59: 53-61
[39] F. Karci, I. Sener, H. Deligoz. Azocalixarenes. 2: synthesis, characterization and investigation of the absorption spectra of azocalix[6]arenes containing chromogenic groups. Dyes and Pigments, 2004, 62: 131-140
[40] I. Sener, F. Karci, E. Kilic, H. Deligoz. Azocalixarenes. 3: synthesis and investigation of the absorption spectra of hetarylazo disperse dyes derived from calix[4]arene. Dyes and Pigments, 2004, 62: 141-148
[41] I. Sener, F. Karci, E. Kilic, H. Deligoz. Azocalixarenes. 4: synthesis, characterization and investigation of the absorption spectra of hetarylazo-substituted calix[6]arenas. Dyes and Pigments, 2004, 62: 149-157
[42] 钟志梅，姚俊学．杯芳烃磷酸酯为载体铅离子选择性膜电极的研究．分析化学(来稿摘登)，2006，34(4)：587
[43] S. Shinkai, T. Arimura, H. Satoh, O. Manabe. Chiral calixarene. J. Chem. Soc., Chem. Commun., 1987, 19: 1495-1496
[44] K. Ito, M. Noike, A. Kida, Y. Ohba. Syntheses of chiral homoazacalix[4]arenes incorporating amino acid residues: molecular recognition for racemic quaternary ammonium ions. J. Org. Chem., 2002, 67(21): 7519-7522
[45] W. C. Zhang, Y. S. Zheng, W. G. Wang, Q. Y. Zheng, Z. T. Huang. Syntheses of chiral calix[4]arene derivatives bearing amino acid residue. Chin. J. Chem., 2003, 21(7): 931-936
[46] S. S. Ben, R. Baudry, C. P. Felix, M. B. A. Giudicelli, R. J. Lamartine. Synthesis and structure of lower rim C-linked tetra-N-tosyl peptidocalix[4]arenes. Tetrahedron Lett., 2004, 45(41): 7801-7804
[47] G. Z. Zhang, Z. C. Li, M. Wang, J. Q. He, J. P. Cheng. Design and synthesis of novel amino acid-bearing macrocyclic calix[4]arenes. Synth. Comm. 2004, 34(19): 3615-3621
[48] H. Xu, G. R. Kinsel, J. Zhang, M. L. Li, D. M. Rudkevich. Calixarene amino acids; building blocks for calixarene peptides and peptide-dendrimers. Tetrahedron, 2003, 59(31): 5837-5848
[49] C. Gaeta, M. D. Rosa, M. Fruilo, A. Soriente, P. Neri. Synthesis of calix[4]arene derivatives bearing chiral pendant groups as ligands for enantioselective catalysis. Tetrahedron: Asymmetry, 2005, 16(13): 2333-2340
[50] G. Y. Qing, Y. B. He, Y. Zhao, C. G. Hu, S. Y. Liu, X. Yang. Calix[4]arene-based chromogenic chemosensor for the α-phenylglycine anion: synthesis and chiral recognition. Eur. J. Org. Chem., 2006, 6: 1574-1580
[51] I. I. Stoikov, S. A. Repejkov, I. S. Antipin, A. I. Konovalov. Lipophilic aminophosphonates and their calix[4]arene derivatives: synthesis and membrane transport of biorelevant species. Heteroatom Chem., 2000, 11(7): 518-527
[52] F. Liu, G. Y. Lu, W. J. He, J. Hu, Y. H. Mei, L. G. Zhu. Synthesis of calix[4]arene derivatives with alkyl guanidinium or chiral bicyclic guanidinium. Synthesis, 2001, 4: 607-611
[53] Y. B. He, Y. J. Xiao, L. Z. Meng, Z. Y. Zeng, X. J. Wu, C. T. Wu. New type chiral calix[4](aza)crowns: synthesis and chiral recognition. Tetrahedron Lett., 2002, 43(35): 6249-6253
[54] S. J. Kim, B. H. Kim. Syntheses and structural studies of calix[4]arene-nucleoside and calix[4]arene-oligonucleotide hybrids. Nucleic Acids Research, 2003, 31(11): 2725-2734
[55] 肖元晶，吴晓军，曾振亚，何永炳，孟令芝，吴成泰．一类新型四酰胺杯[4]氮杂冠醚的合成及阴离子识别研究．化学学报，2003，61(12)：1986-1990
[56] C. Sergiy, V. Andriy, M. Iryna, S. Alexander, K. Valery, L. Janusz, K. Vitaly. Calix[4]areneaminophos-phonic acids: asymmetric synthesis and enantioselective inhibition of an alkaline phosphatase. Org. Lett., 2006, 8(4): 549-552
[57] Y. B. He, J. F. Li, Y. J. Xiao, L. H. Wei, X. J. Wu, L. Z. Meng. Synthesis and chiral recognition of a new type of chiral calix[4]arene derivatives. Chin. J. Chem., 2003, 21: 83-86
[58] S. Cherenok, A. Vovk, I. Muravyova, A. Shivanyuk, V. Kukhar, J. Lipkowski, V. Kalchenko. Calix[4]arene-aminophosphonic acids: asymmetric synthesis and enantioselective inhibition of an alkaline phosphatase. Org. Lett., 2006, 8(4): 549-552
[59] 郑炎松，张春，梅付名，李光兴．杯[4]芳烃半冠醚的合成．华中科技大学学报(自然科学版)，2003，31(12)：114-116
[60] 郑炎松，张春．手性杯[4]芳烃氨基醇的合成及自组装．化学学报，2004，62(6)：537-539
[61] S. S. Ben, C. Felix, M. B. Giudicelli, F. Vocanson, M. Perrin, R. Lamartine. Synthesis, structure and anion binding properties of lower rim-hydroxy amide calix[4]arene derivatives. Tetrahedron Lett., 2005, 46(34): 5659-5663
[62] 孟令芝，梅功雄，何永炳，曾振亚，刘顺英．新型四酰胺杯[4]氮杂冠醚的合成及对阴离子的光化学传感性质研究．化学学报，2005，63(5)：16-420
[63] A. Sirit, E. Kocabas, S. Memon, A. Karakucuk, M. Yilmaz. Synthesis and metal ion recognition properties of a novel chiral calix[4](azoxa)crown-7. Supramol. Chem., 2005, 17(3): 251-256
[64] Y. S. Zheng, C. Zhang. Exceptional chiral recognition of racemic carboxylic acids by calix[4]arenes bearing optically pure, α,β-amino alcohol groups. Org. Lett., 2004, 6(8): 1189-1192
[65] S. A. Fernandes, F. F. Nachtigall, M. Lazzarotto, F. Y. Fujiwara, A. J. Marsaioli. Non-covalent synthesis' of a chiral host of calix[6]arene and enantiomeric discrimination. Magnetic Resonance in Chem., 2005, 43(5): 398-404
[66] U. Darbost, X. S. Zeng, M. Giorgi, I. Jabin. Optically pure calix[6]tris- ammoniums: syntheses and host-guest properties toward neutral guests. J. Org. Chem., 2005, 70(25): 10552-10560
[67] P. A. Reddy, C. D. Gutsche. Calixarenes. 32. reactions of calix[4]quinines. J. Org. Chem., 1993, 58(12): 3245-3251
[68] W. Verboom, P. J. Bodewes, G. Van Essen, P. Timmerman, G. J. V. Hummel, S. Harkema, D. N. Reinhoudt. A novel approach to inherently chiral calix[4]arenes by direct introduction of a substituent at the meta position. Tetrahedron, 1995, 51 (2): 499-512
[69] C. Dieleman, S. Steyer, C. Jeunesse, D. Matt. Diphosphines based on an inherently chiral calix[4]arene scaffold: Synthesis and use in enantioselective catalysis. J. Chem. Soc., Dalton Transactions, 2001, 17: 2508-2517
[70] M. T. Blanda, L. Edwards, R. Salazar, M. Boswell. Synthesis and characteri- zation of an inherently chiral calix[6]arene in the 1,4-alternate conformation. Tetrahedron Lette., 2006, 47(39): 7081-7084
[71] J. Luo, Q. Y. Zheng, C. F. Chen, Z. T. Huang. Synthesis and optical resolution of a series of inherently chiral calix[4]crowns with cone and partial cone conformations. Chem. Eur. J., 2005, 11(20): 5917-5928
[72] S. T. Ganjali, M. Shafai, M. Khosravi. Simple synthetic strategy to inherently chiral calix[4]arene by an asymmetric calix[4]quinone as a key intermediate. Acta Chim. Slovenica, 2002, 49(4): 903-908
[73] S. Y. Li, Q. Y. Zheng, C. F. Chen, Z. T. Huang. Fluorescent probes of D-(+)-gluconic acid δ5-lactone based on binary hosts of chiral calix[5]arene. Tetrahedron: Asymmetry, 2005, 16(16): 2816-2820
[74] 郑炎松．杯芳烃的配位性质．化学进展，1999，11(3)：275-285
[75] 陈淑华，李东红，袁立华，赵华明．杯芳烃类受体的分子识别作用研究进展．有机化学，1999，19(4)：339-347
[76] A. Arduini, B. Elisabetta, G. Giovanna, P. Andrea, S. Andrea. Recognition of guests bearing donor and acceptor hydrogen bonding groups by heteroditopic calix[4]arene receptors. Tetrahedron, 2003, 59(38): 7587-7594
[77] L. Zhang, Y. Zhang, H. B. Tao, X. J. Sun, Z. J. Guo, L. G. Zhu. Investigation of calix[4]arene-porphyrin and its palladium(Ⅱ) and zinc(Ⅱ) complexes at air/water interface and in langmuir-nlodgett film. Thin Solid Films, 2002, 413(1-2): 224-230
[78] 毛锋旺，胡晓钧，钱洪平，姚天明，施宪法．杯芳烃衍生物对K+和电子的耦合液膜传输．物理化学学报，2004，20(10)：1271-12741
[79] E. Akceylan, M. Yilmaz, R. A. Bartsch. Immobilization of cyclic alkyla- mine calix[4]arene derivatives on Merrifield resin: evaluation of extraction ability toward dichromate. J. Macromolecular Science, Part A: Pure and Applied Chemistry, 2006, 43(3):477-486
[80] X. J. Li, Z. R. Zeng, Y. Xu. A solid-phase microextraction fiber coated with diglycidyloxycalix[4]arene yields very high extraction selectivity and sensitivity during the analysis of chlorobenzenes in soil. Analytical and Bioanalytical Chemistry, 2006, 384(6): 1428-1437
[81] 孟冠华，王锦堂．杯芳烃的催化性质及其在有机反应中的应用．化工时刊，2003，17(7)：9-13
[82] 孟祥启，冯亚青，孟舒献，张宝．杯芳烃作为相转移催化剂用于四氟对苯二甲酸二甲酯的合成．化学试剂，2006，28(1)：5-7
[83] 赵芳，梁斌，刘道杰．杯芳烃催化剂的研究进展．信阳师范学院学报，2003，19(3)：364-367
[84] M. R. Yaftian, H. Abdollahi, R. Shokouhi. Ion binding properties of 5, 11,17,23-tetra-tert-butyl-25,27-bis(diethylcarbamoylmethoxy)-26,28-bis(diphenylphosphinoylmethoxy)calix[4]a rene towards alkaline-earth cations. Chem. Anal., 2007, 52(1): 103-113
[85] M. R. Yaftian, S. Rayati, D. Emadi, D. Matt. A coated wire-type lead(Ⅱ) ion-selective electrode based on a phosphorylated calix[4]arene derivative. Anal. Sci., 2006, 22(8): 1075-1078
[86] L. X. Chen, J. Zhang, W. F. Zhao, X. W. He, Y. Liu. Double-armed calix[4]arene amide derivatives as ionophores for lead ion-selective electrodes. J. Electroanal. Chem., 2006, 589(1): 106-111
[87] 郑炎松，沈之荃．杯芳烃的催化性质．化学通报，1998，61(4)：27-32
[88] 王腾凤，杨世柱．杯芳烃催化剂在有机反应中的应用．化学试剂，2000，22(5)：274-278
[89] I. Vijaykumar, V. Francis, M. Claude, J. R. Nicole. Capacitive sensing of amino acids using caliraxene-coated silicon transducers. Electroanalysis, 2007, 19(4): 510-514
[90] P. Leyton, C. Domingo, S. C. Sanchez, M. V. Campos, G. F. Diaz, J. V. R. Garcia. Reflection-absorption IR and surface-enhanced IR spectroscopy of tetracarboethoxy t-butyl-calix[4]arene, as a host molecule with potential applications in sensor devices. Vibrational Spectroscopy, 2007, 43(2): 358-365
[91] 陈朗星，徐华，李一峻，何锡文．杯芳烃化学传感器的研究进展．分析化学，2000，28(2)：232-239
[92] 林琳，吴采樱．杯芳烃衍生物在分析化学中的应用．分析化学，1997，25(7)：850-856
[93] 李来生，达世禄，冯钰琦，刘敏．杯芳烃在液相色谱、毛细管电泳和电色谱中的应用进展．化学进展，2005，17(3)：523-530
[94] 狄晓威，何锡文，曾宪顺，邹本东．硒功能化杯芳烃载体银离子选择性膜电极的研究．分析化学，2004，32(4)：430-434
[95] F. J. Sr. Ludwiq, A. G. Jr. Bailie. Liquid chromatographic separation of p-alkylphenol-formaldehyde cyclic and linear oligomers. Anal. Chem., 1984, 56(12): 2081-2085
[96] F. J. Sr. Ludwiq, A. G. Jr. Bailie. Reversed-phase Liquid chromatographic separation of p-tert-butylphenol-formaldehyde linear and cyclic oligomers. Anal. Chem., 1986, 58(9): 2096-2072
[97] P. K. Zarzycki. Normal- and reversed-phase thin-layer chromatography of selected calixarenes and pyrene. J. Planar Chromatography-Modem TLC, 2001, 14(2): 113-118
[98] T. Jin, K. Monde. Synthesis and optical resolution of a fluorescent chiral calix[4] arene with two pyrene moieties forming an intramolecular excimer. Chem. Commun., 1998, 13: 1357-1358
[99] S. T. Pickard, W. H. Pirkle, M. Tabatabai, W. Vogt, V. Boehmer. Dissymmetric calix[4]arenes: Optical resolution of some conformationally fixed derivatives. Chirality, 1993, 5(5): 310-314
[100] K. Iwamoto, H. Shimizu, K. Araki, S. Shinkai. Syntheses and optical resolution of calix[4]arenes with molecular asymmetry. Systematic classification of all possible chiral isomers derivable from calix[4]arene. J. Am. Chem. Soc., 1993, 115(10): 3997-4006
[101] H. Otsuka, S. Shinkai. Definitive evidence for inhibition of calix[6]arene ring inversion obtained from a 1,3-xylenyl-bridged chiral calix[6]arene. J. Am. Chem. Sot., 1996, 118(18): 4271-4275
[102] J. Gloede, I. Keitel, B. Costisella, A. Kunath, M. Schneide. Inharent chirale 1,2-verbruckte calix[4]aren-diphosphate-Synthese, eigenschaften und isomerentrennung. Phosphorus, Sulfur and Silicon and Related Elements. 1996, 117: 67-88
[103] S. Pappalardo, S. Caccamese, L. Giunta. Stereoselective synthesis and optical resolution of chiral calix[4]arenes with mixed ligating functionalities. Tetrahedron Lett., 1991, 32(52): 7747-7750
[104] A. N. Francoise, C. Salvatore, F. Saowarux, P. Sebastiano, P. F. Melchiorre, P. Ada, P. Grazia. Synthesis, Optical resolution and complexation properties of inherently chiral monoalkylated p-tert-Butyl-(1,2)-calix[4]crown ethers. J. Org. Chem., 1997, 62(23): 8041-8048
[105] S. Caccamese, A. Notti, S. Pappalardo, M. F. Parisi, G. Principato. Inherently chrial α-picolyloxy-p-tert-butylcalix[5]arene crowm ethers: synthesis, structure proof and enantioselective HPLC resolution. Tetrahedron, 1999, 55: 5505-5514
[106] S. Caccamese, A. Bottino, F. Cunsolo, S. Parlato, P. Neri. Resolution of inherently chrial calyx[4]arenas with AABB and CDCD substitution patterms on the upper and lower rims, respectively. Teteahedron: Asymmetry, 2000, 11: 3103-3112
[107] S. Caccamese, A. Notti, S. Pappalardo, M. F. Parisi, G. Principato. Synthesis and host properties of (1,3)-p-tert-butylcalix[5]crown-6 derivatives incorporating the 1,1'-binaphthalene-2,2'-dioxy subunit. J. Inclusion Phenomena, 2000, 36(1): 67-78
[108] N. Morohashi, N. Iki, T. Onodera, C. Kabuto, S. Miyano. Novel molecular chriality in the calixarene family: formation of chrial disulfinyldithiacalix[4]arenas. Tetrahedron Lett., 2000, 41: 5093-5097
[109] 刘英，达世禄，陈远荫．C60键合硅胶液相色谱固定相的合成及其性能评价．色谱，1998，16(2)：115-117
[110] 冯钰锜，胡玉铃，李建森，刘英，达世禄，陈远荫．用C60键合硅胶固定相液相色谱分离杯芳烃及杯芳冠醚类化合物．分析测试学报，2000，19(2)：1-4
[111] Y. Saito, H. Ohta, H. Terasaki, Y. Katoh, H. Nagashima, K. Jinno, K. Itoh, R. D. Trengove, J. Harrowfield, S. F. Y. Li. Separation of calixarenes with a chemically bonded C60 silica stationary phase in microcolumn liquid chromatography. J. High Resolut. Chromatogr., 1996, 19(8): 475-477
[112] K. Jinno, K. Tanabe, Y. Saito, H. Nagashima, R. D. Trengove. Retention behavior of calixarenes with various C60 bonded silica phases in microcolumn liquid chromatography. Anal. Commun., 1997, 34(6): 175-177
[113] O. I. Kalchenko, J. Lipkowski, R. Nowakowski, V. I. Kalchenko, M. A. Visotsky, L. N. Markovsky. Studies on the behavior of some phosphorus-contained calix[n]arenes in reversed-phase high-performance liquid chromatography. J. Chromatogr. Sci., 1997, 35(2): 49-52.
[114] O. I. Kalchenko, M. O. Tairov, M. O. Vysotsky, J. Lipkowski, V. I. Kalchenko. Optical resolution of phosphorus containing calix[4]arenes by additive RP HPLC method. Enantiomer, 2000, 5(3-4): 385-390
[115] S. J. Thibodeaux, P. M. Sanchez, Y. Zhang, S. A. Shamsi, I. M. Warner. Separation and identification of chiral N-acyl calix[4]arene amino acid derivatives by use of reversed-phase HPLC. Chromatographia, 1999, 49(3-4): 142-146
[116] B. F. Graham, J. M. Harrowfietd, R. D. Trengove, I. Rodriguez, S. F. Y. Li. Comparison of supercritical fluid chromatographic and high-performance liquid chromatographic separations of p-tert-butylcalixarenes. J. Chromatogr. Sci., 1997, 35:232
[117] S. F. Y. Li, B. F. Graham, R. D. Trengove. Liquid-chromatographic separation of calixarenes. J. Liq. Chromatogr. & Relat. Technol.. 1997, 20(8): 1197-1209
[118] C. Agena, C. Wolff, J. Mattay. First Synthesis, isolation and complete charac- terization of both enantiomers of inherently chiral resorc[4]arenes by monofunctionalization. Eur. J. Org. Chem. 2001, 15: 2977-2981
[119] G. McMahon, R. Wall, K. Nolan, D. Diamond. Characterisation of the ester-substituted products of the reaction of p-t-butyl calix[4]arene and ethyl bromoacetate using LC-UV-MS and LC-DAD. Talanta, 2002, 57(6): 1119-1132
[120] B. Schazmann, G. McMahon, K. Nolan, D. Diamond. Identification and recovery of an asymmetric calix[4]arene tetranitrile derivative using liquid chromatography and mass spectrometry. Supramolecular Chem., 2005, 17(5): 393-399
[121] C. K. Jankowski, M. -R. Van Calsteren, N. Aychet, J. F. Dozol, C. Moulin, C. Lamouroux. Study of the nitration of di-n-octylcrown-6 calix[4]arene using LC-MS, NMR, and molecular modelling. Canadian J. Chem. 2005, 83(8): 1098-1113
[122] Y. L. Zhang, I. M. Warner. Separation of water-soluble p-sulfonated calixarenes 4, 6 and 8 and 4-hydroxybenzene sulfonate by use of capillary zone electrophoresis. J. Chromatogr. A, 1994, 688: 293-300
[123] 韩珀．非水毛细管电泳的应用．郑州大学学士学位论文，2004
[124] C. G. Fu, A. L. Liu, Y. F. Zhao, L. Y. Zhang. Determination of sulfonated calixarenes by capillary electrophoresis with sample stacking enrichment. Lihua Jianyan, Huaxue Fence, 2005, 41(9): 658-660
[125] 沈家骢，孙俊奇．超分子科学研究进展．中国科学院院刊(学科发展)，2004，19(6)：420-424
[126] 闫有旺．化学学科的前沿-超分子化学．2003，11：32-33
[127] 谭倪．谈超分子化学与生物有机化学．怀化学院学报，2002，21(2)：31-33
[128] 张中强，涂华民，葛旭升．超分子化学的研究和进展．河北师范大学学报(自然科学版)，2006，30(4)：453-458
[129] 闫丽．超分子化学．世界科学，2003，4：6-8
[130] 张穗娟，李琼芳，李如芳．关于超分子化学．广东化工，2004，6：36-37
[131] 张希，沈家骢．超分子科学：认识物质世界的新层面．科学通报，2003，48(14)：1477-1478
[132] 胡伟光．无机化学，化工工业出版社，2002
[133] 夏泽吉．关于范德华力本质的定量探索．川东学刊，1997，7(2)：81-83
[134] K. Kazuo, M. Keiji. A new energy decomposition scheme for molecular interactions within the Hartree-Fock approximation. International J. Quantum Chem., 1976, 10(2): 325-340
[135] 孙得志，朱兰英，宋兴民．超分子化学选择性分子间力和若干化学研究领域．聊城师院学报(自然科学版)，1998，11(2)：27-33
[136] Y. Liu, L. Li, X. Y. Li, H. Y. Zhang, T. Wada, Y. Inoue. Synthesis of phosphoryl-tethered-cyclodextrins and their molecular and chiral recognition thermodynamics. J. Org. Chem., 2003, 68(9): 3646-3657
[137] J．M．Lehn，沈兴海．超分子化学-概念和展望，北京大学出版社，2002
[138] 许琳．分子间作用力对有机物物理性质的影响．雁北师院学报，1998，14(5)：22-24
[139] 王毓江，唐黎明．基于氢键作用结合的超分子聚合物．化学进展，2006，18(2-3)：308-316
[140] 张建合．疏水凝胶及疏水相互作用研究进展．信阳师范学院学报(自然科学版)，2004，17(2)：237-243
[141] J. Herzfeld. Understanding Hydrophobic Behavior. Science. 1991, 253: 88-90
[142] 李祥春，聂百胜．煤吸附水特性的研究．太原理工大学学报，2006，37(4)：417-419
[143] 沈晓春．色谱保留机理探索与研究．浙江大学硕士学位论文，2002
[144] A. Nicholls, K. A. Sharp and B. Honing. Protein Folding and Association: insights from the interfacial and thermodynamic properties of hydrocarbons. Protein, 1991, (11): 28-29
[145] 陈强，谭民裕，刘伟生．超分子中分子间弱相互作用力的研究方法概述，化学通报，2001，4：236-239
[146] C D. Gutsche, M. Iqbal, I. Alam. The interaction of calixarenes and amines. J. Am.Chem.Soc., 1987, 109: 4314-4320
[147] H. M. Chawla, K. M. Srinivas. Calix(n)arene-quinone interactions: molecular recognition of 2,6-naphthoquinone by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahydroxycalix (6) arene, Tetrahedron, 1995, 51 (9): 2709-2718
[148] 黄志兵，李来生，王宇晓，吴宇梅．荧光法研究对-二甲氨甲基-杯[8]芳烃与二苯胺磺酸钠包结作用．光谱学与光谱分析，2005，25(4)：591-593
[149] P. E. Georghiou, A. H. Tran, S. S. Stroud, D. W. Thompson. Supramolecular complexation studies of [60]fullerene with calyx[4]anphthalenes-a reinvestigation. Tetrahedron, 2006, 62(9): 2036-2044
[150] 唐波，马丽．生物相关物质-主客体识别超分子化学的分子光谱研究及其分析应用．山东师范大学硕士学位论文，2002，4
[151] S. M. Shuang, J. H. Pan, S. Y. Guo, M. Y. Cai, C. S. Liu. Camparative Study on the Inclusion complexation of rutin with cyclodextrin supramolecules. Chin. Chem. Lett., 1997, 8(9): 803-804
[152] L. F. Yao, Z. F. Luo, H. Y. Ma, Z. T. Pan. Spectroscopic study and application on the inclusion complexation of β-cyclodextrin with estradiol benzoate in aqueous solution. Wuhan Daxue Xuebao(Ziran Kexue Ban), 1997, 43(6): 706-710
[153] A. D. Qi, L. Li, Y. Liu. The binding ability and inclusion complexation behavior of curcumin with natural α-, β-, γ-Cyclodextrins and organoselenium-bridged bis(β-cyclodextrin)s. J. Chin. Phar. Sci., 2002, 12(1): 15-20
[154] Y. Liu, B. H. Han, Y. T. Chen. Inclusion complexation of acridine red dye by calixarenesulfonates and cyclodextrins: opposite fluorescent behavior, J. Org. Chem., 2000, 65 (19): 6227-6230
[155] 周叶红．环糊精和杯芳烃的包合特性及其在药物中的应用．山西大学硕士学位论文，2006
[156] 古俊，张勇，潘景浩．电化学方法研究环糊精与酮洛酚的包结行为．电化学，1998，4(4)：394-399
[157] 张霞，张清，赵迪思，罗川南，周长利．杯芳烃-硝基氯苯包络物的电化学行为研究．济南大学学报(自然科学版)，2005，19(1)：45-47
[158] Haino Takeharu, Yanase Manabu, Fukunaga Chigusa, Fukazawa Yoshimasa. Fullerene encapsulation with calyx[5]arenas. Tetrahedron, 2006, 62(9): 2025-2035
[159] 周稚仙，吴养洁，石雅琳．杯4芳烃衍生物的合成及其包合等性能的研究．郑州大学硕士学位论文，2002，6
[160] 王小萍，马麦霞，双少敏，张勇，潘景浩．薄层色谱法测定大黄类药物与环糊精的包结常数．分析化学研究简报，2002，30(1)：38-41
[161] 夏之宁，刘毅．分子竞争相互作用的HPLC和毛细管电泳法研究．重庆大学硕士学位论文，2004，4
[162] 朱维良，蒋华良，陈凯先，嵇汝运，曹阳．分子间相互作用的量子化学研究方法．化学进展．1999，11(3)：247-253
[163] 田国才，陶建民，李国宝．分子间相互作用的理论化学研究进展．云南师范大学学报，2002，22(1)：30-33
[164] W. l. Zhu, J. d. Guo, H. l. Jiang. IR spectrum and normal mode analysis of the anti-alzheimer's disease natural product huperzine a: a quantum chemistry density-functionaltheory (DFT) investigation. Science in China(Series B), 1998, 41 (6): 616-622
[165] 蒋华良，朱维良，谭小健，顾健德，陈建忠，林茂伟，陈凯先，嵇汝运．阳离子-π体系相互作用的理论研究-Ⅰ．铵离子-苯复合物构型及相互作用的密度泛函研究．中国科学(B辑)，1998，28(5)：403-409
[166] 朱维良，顾健德，蒋华良，陈建忠，刘东祥，林茂伟，陈凯先，嵇汝运，曹阳．抗早老性痴呆症天然产物石杉碱甲的红外光谱与简正分析-量子化学密度函数理论(DFT)研究．中国科学(B辑)，1998，28(4)：326-331
[167] 朱维良，蒋华良，谭小键，陈建忠，翟宇峰，顾健德，林茂伟，陈凯先，嵇汝运，曹阳．阳离子-π体系相互作用的理论研究-Ⅱ．铵离子-二苯复合物体系的密度泛函研究．化学学报，1999．57：852-859
[168] U. Cosentino, G. Moro, D. Pitea. Ab initio effective core potential calculations on lanthanide complexes: basis sets and electron correlation effects in the study of [Gd-(H2O)9]~(3+). Journal of Molecular Structure(Theochem), 1997, 392: 75-85
[169] M. C. Salazar, J. Paz, A. J. Hernandez. Ab initio test study of the N2…H2 and N2…He van der Waalsdimers. Journal of Molecular Structure (Theochem), 1999, 464: 183-189
[170] M. C. Salazar, J. L. Paz, A. J. Hernandez. Ab initio basis set study of the CO…He van der Waals interaction. Journal of Molecular Structure (Theochem), 1999, 493: 133-137
[171] A. N. Enyashin, Yu. N. Makurin, A. L. Ivanovskii. Ab initio study of dititanium end- ofullerenes: D5d- and D5h-Ti2@C80. Computational Materials Science, 2006, 36: 26-29
[172] X. Y. Ren, Z. Y. Liu, M. Q. Zhu. DFT studies on endohedral fullerene C-C60: C centers the C60 cage. J. Molecular Structure (Theochem), 2004, 710: 175-178
[173] M. I. Ogden, A. L. Rohl, J. D. Gale. An ab initio study of the influence of crystal packing on the host-guest interactions of calix[4]arene crystal structures. Chem. Commun., 2001, 18: 1626-1627
[174] J. I. Choe, S. K. Chang, S. Nanbu. Ab initio study of conformers of p-tert-butylcalix-[4]crown-6-ether complexed with alkyl ammonium cations. Bull. Korean Chem. Soc., 2002, 24(1): 75-80
[175] J. I. Choe, S. K. Chang, M. Satoshi. Ab initio study of conformers of p-tert-Butylcalix[5]arene derivative toward alkyl ammonium cations. Bull. Korean Chem. Soc., 2003, 23(6): 891-895
[176] J. I. Choe, S. H. Lee, D. S. Oh. Ab initio study of complexation behavior of p-tert-butylcalix-[5]arene derivative toward alkyl ammonium cations. Bull. Korean Chem. Soc., 2004, 25(2): 190-194
[177] J. I. Choe, S. H. Lee, D. S. Oh. Ab initio study of conformers of tetramethoxycalix[4]arenas. Bull. Korean Chem. Soc., 2004, 25(1): 55-58
[178] B. Thanaporn, P. Buncha, R. Vithaya. Protonation and energetical investigations of calix[4]-cyclen-benzo-crown-6 and its complexes with zinc and copper. Bull. Korean Chem. Soc., 2004, 25(6) : 819-822
[1] C. D. Gutsche, R. Muthukrishnan. Calixarenes. 1. analysis of the product mixtures produced by the base-catalyzed condensation of formaldehyde with pares-substituted phenols. J. Org. Chem., 1978, 43: 4905-4906
[2] 田振峰，郑炎松．手性杯芳烃的合成及性质．有机化学，2002，22(10)：702-709
[3] 胡晓钧，王丽，任杰，施宪法．硫杂杯芳烃—类新型的分子受体化合物．化学通报，2004，2(1)：90-95
[4] B. T. Hayes, R. F. Hunter. Phenol-formaldehyde and allied resins Ⅵ. rational synthesis of a 'cyclic' tetranuclear p-cresol novolak. J. Appl. Chem., 1958, 8: 743-748
[5] V. Bohmer. Calixarenes, macrocycles with (almost) unlimited possibilities. Angew. Chem. Int. Ed. Engl., 1995, 34: 713-745
[6] H. M. Chawla, K. S. Meena. Calix[n]arene-quinone interactions: molecular recognition of 2,6-naphthoquinine by 5,11,17,23,29,35-hexa-tert-butyl-37,38,39,40,41,42-hexahy-droxy calix(6)arene. Tetrahedron, 1995, 51: 2709-2718
[7] N. Morohashi, R. Naito, N. Iki, S. Miyano. Syntheses of inherently chiral monosuifinylt-rithiacalix[4]arenes by the oxidation of one of the bridging sulfurs of a tetrathiacalix[4]- arene fixed in the 1,3-alternate conformation. Israel J. Chem., 2001, 41(4): 303-307
[8] F. Narumi, N. Iki, T. Suzuki, T. Onodera, S. Miyano. Syntheses of chirally modified thiacalix[4]arenes with enantiomeric amines and their application to chiral stationary phases for gas chromatography. Enantiomer, 2000, 5(1): 83-93
[9] Y. B. He, J. F. Li, Y. J. Xiao, L. H. Wei, X. J. Wu, L. Z. Meng. Synthesis and chiral recognition of a new type of chiral calix[4]arene derivatives. Chin. J. Chem., 2003, 21 (1): 83-86
[10] Y. Okada, Z. Miao, M. Akiba, J. Nishimura. Synthesis and characterization of chiral catenanes based on rigid calix[4]arene. Tetrahedron Lett., 2006, 47(16): 2699-2702
[11] Gaeta Carmine, Martino Marco, Neri Placido. Synthesis of the first examples of p-bromodienone and transannular spirodienone calixarene derivatives. Tetrahedron Lett., 2003, 44: 9155-9159
[12] 丁呈华．杯芳烃的合成及其色谱应用研究．郑州大学硕士学位论文，2006
[13] C. D. Gutsche, M. Iqbal. Pentacyclo[19,3.1.13,7.19,13,115,19]octacosa-1(25),3,5,7(28), 9,11, 13(27), 15,17,19(26),21,23-dodecanene-25,26,27,28-tetrol——5,11,17,23-tetrakis(1,1-diethylethyl). Org. Synth., 1990, 68: 234-237
[14] 李建森，陈远荫．对叔丁基杯[6]芳烃合成方法的改进．化学试剂，2000，22(3)：178-183
[15] C. D. Gutsche, B. Dhawan, M. Leonis, D. Stewart. Nonacyclo[43,3.1.13,7.19,13, 115,19, 121,25, 127,31,133,37,139,43]hexapentaconta-1 (49),3,5,7(56),9,11,13 (55), 15,17,19(54),21,23,25(53),27,29,31 (52),33,35,37(51),39,41,43 (50),45,47-tetracosaene-49,50,51,52,53,54,55,56-octo1——5,11,17,23,29,35,41,47-octakis(1,1-dimethylethyl). Org. Synth., 1990, 68: 243-246
[16] C. D. Gutsche, Lee-Gin Lin. Calixarenes 12 The synthesis of functionalized calixarenes. Tetrahedron, 1986, 42(6): 1633-1640
[17] W. Y. Chen, J. Lu, Z. X. Shen, J. P. Lang, L. F. Zhang, Y. W. Zhang. Chiral ferrocenyl amino alcohols: preparation and application as catalysts in the enantioselective reduction of ketones using NaBH_4/I_2. Chin. J. Chem., 2003, 21(2): 192-195
[18] W. Y. Chen, J. Lu, Z. X. Shen, Y. W. Zhang. Catalytic enantioselective reduction of prochiral ketones with chirai ferrocenyl amino alcohols. Chin. J. Chem., 2004, 22(3): 306-309
[19] B. Thierry, C. Jerome, B. Stephanie. Chiral ferrocenyl amino alcohols as catalysts for the enantioselective borane reduction of ketones. Tetrahedron: Asymmetry, 2002, 13: 1241-1243
[20] P. Angela, P. Sonia. Screening of chiral ferrocenyl amino alcohols as ligands for ruthenium-catalysed transfer hydrogenation of ketones. Tetrahedron: Asymmetry, 2003, 14: 597-602
[21] Z. T. Huang, G. Q. Wang. Friedel-grafts reaction ofcalixarenes. Chem. Ber., 1994, 127: 519-523
[22] K. Satish, H. M. Chawla, R. Varadarajan. A one-step, one-pot synthesis of p-acyl calix[n]arenas. Tetrahedron Lett., 2002, 43(14): 2495-2498
[1] Y. Haino, M. Yanase, C. Fukunaga, Y. Fukazawa. Fullerene encapsulation with calix[5]arenas. Tetrahedron, 2006, 62(9): 2025-2035
[2] W. F. Nijenhuis, E. G. Buitenhuis, J. F. De, E. J. R. Sudholter, D. N. Reinhoudt. Calixcrowns as selective potassium cation carriers in supported liquid membranes. J. Am. Chem. Soc. 1991, 113(21): 7963-7968
[3] H. M. Dong, H. Zheng, S. J. Wang, B. X. Ye. Chemically modified electrode with LB film of calixarene and its recognition property. Huaxue Tongbao, 2006, 69: 127-129
[4] A. Wei. Calixarene-encapsulated nanoparticles: self-assembly into functional nanomaterials. Chem. Commun, 2006, 15: 1581-1591
[5] J. H. Lee, G. Kim, M. C. Oh. Polymeric waveguide bio sensors with bragg gratings. Han' guk Kwanghak Hoechi, 2006, 17: 54-59
[6] M. Benounis, R. N. Jaffrezic, H. Halouani, R. Lamartine. Detection of heavy metals by an optical fiber sensor with a sensitive cladding including a new chromogenic calyx[4]arene molecule. Material Science & Engineering, C: Biomimetic and Supramolecular Systems, 2006(2-3), 26: 364-368
[7] 林琳，吴采樱．杯芳烃衍生物在分析化学中的应用．分析化学，1997，25：850-856
[8] T. Zhao, X. B. Hu, J. K. Cheng, Lu X. B.. Use of calix[4]arene to separate positional isomers in capillary electrophoresis. Anal. Chim. Acta, 1998, 358(3): 263-268
[9] T. Sokolieβ, U. Menyes, R. Ulrich, T. Jira. Separation of cis- and trans-isomers of thioxanthene and dibenz[b,e]oxepin derivatives on calixarene- and resorcinarene- bonded high-performance liquid chromatography stationary phases. J. Chromatogr. A, 2002, 948(1-2): 309-319
[10] X. J. Wu, H. X. Liu, H. Liu, S. S. Zhang, P. R. Haddad. Preparation and characterization of p-tert-butylcalix[8]arene bonded capillaries for open-tubular capillary electrochromatography. Anal. Chim. Acta, 2003, 478(2): 191-197
[11] S. Seyhan, O. Ozbayrak, N. Demirel, M. Merdivan, N. Pirinccioglu. Chiral separation of amino acids by chiral octamide derivatives of calixarenes derived from resorcinol by impregnation on a polymeric support. Tetrahedron: Asymmetry. 2005, 16(22): 3735-3738
[12] M. Liu, L. S. Li, S. L. Da, Y. Q. Feng. High performance liquid chromatography with cyclodextrin and calixarene macrocycle bonded silica stationary phases for separation of steroids. Talanta, 2005, 66(2): 479-486
[13] F. J. Ludwiq, A. G. Bailie. Liquid chromatographic separation of p-alkylphenol- formaldehyde cyclic and linear oligomers. Anal. Chem., 1984, 56: 2081-2085
[14] P. K. Zarzycki. Normal-and reversed-phase thin-layer chromatography of selected calixarenes and pyrene. J. Planar Chromatogr. -Modem TLC, 2001, 14: 113-118
[15] F. J. Ludwig, A. G. Bailie. Reversed-phase liquid chromatographic separation of p-tertbutylphenol-formaldehyde linear and cyclic oligomers. Anal. Chem., 1986, 58:2096-2097
[16] Y. Saito, H. Ohta, H. Terasaki, Y. Katoh, H. Nagashima, K. Jinno, K. ltoh, R. D. Trengove, J. Harrowfield, S. F. Y. Li, Separation of calixarenes with a chemically bonded C60 silica stationary phase in microcolumn liquid chromatography. JHRC, 1996, 19(8): 475-477
[17] A. Bianco, F. Gasparrini, M. Maggini, D. Misiti, A. Polese, M. Prato, G. Scorrano, C. Toniolo, C. Villani. Molecular recognition by a silica-bound fullerene derivative. J. Am. Chem. Soc., 1997, 119(32): 7550-7554
[18] Y. Liu, Y. Q. Feng, S. L. Da, Y. Y. Cben. Preparation and evaluation of C60 bonded silica phase for high performance liquid chromatography. J. Chromatogr. A, 1998, 16(2) : 115-117
[19] Y. Q. Feng, Y. L. Hu, J. S. Li, Y. Liu, S. L. Da, Y. Y. Chen. Separation of calixarenes and calixcrowns with a C60 bonded silica stationary phase in normal-phase liquid chromatography. Chin. J. Instrum. Anal., 2000, 19(1): 1-4
[20] O. I. Kalchenko, J. Lipkowski, R. Nowakowski, V. I. Kalchenko, M. A. Visotsky, L. N. Markovsky. Studies on the behavior of some phosphorus-contained calix[n]arenes in reversed-phase high-performance liquid chromatography. J. Chromatogr. Sci., 1997, 35(2): 49-52
[21] S. J. Thibodeaux, P. M. Sanchez, Y. Zhang, S. A. Shamsi, I. M. Warner. Separation and identification of chiral N-acyl calix[4]arene amino acid derivatives by use of reversed-phase HPLC. Chromatographia, 1999, 49(3/4): 142-146
[22] B. F. Graham, J. M. Harrowfield, R. D. Trengove, I. Rodriguez, S. F. Y. Li. Comparison of supercritical fluid chromatographic and high-performance liquid chromatographic separations of p-tert-butylcalix[n]arenes. J. Chromatogr. Sci., 1997, 35: 232-236
[23] I. Rodriguez, S. F. Y. Li, B. F. Graham, R. D. Trengove. Liquid chromatographic separation of calixarenes. Journal of Liquid Chromatography & Related Technologies, 1997, 20(8): 1197-1209
[24] S. Caccamese, Pappalardo and Sebastiano. Direct separation of cone-shaped tri-O-alkylated chiral calix[4]arenes by enantioselective HPLC. Chirality, 1993, 5: 159-163
[25] N. Morohashi, N. Iki, T. Onodera. Novel molecular chirality in the calixarene family: formation of chiral disulfinyldithiacalix[4]arenes via partial oxidation of two adjacent sulfides of tetrathiacalix[4]arene. Tetrahedron Lett., 2000, 41: 5093-5097
[26] S. Caccamese, A. Notti, S. Pappalardo. Inherently chiral a-(picolyloxy)-p-tert-butylcalix-[5]arene crown ethers: synthesis, structure proof, and enantioselective HPLC resolution. Tetrahedron, 1999, 55: 5505-5514
[27] S. Caccamese, A. Bottino, F. Cunsolo. Resolution of inherently chiral calix[4]arenes with AABB and CDCD substitution patterns on the upper and lower rims, respectively. Tetrahedron: Asymmetry, 2000, 11: 3103-3112
[28] Y. L. Zhang, I. M. Warner. Separation of water-soluble p-sulfonated calixarenes 4, 6 and 8 and 4-hydroxybenzene sulfonate by use of capillary zone electrophoresis. J. Chromatogr. A, 1994, 688(1+2): 293-300
[29] I. Rodriguez, H. K. Lee, S. E Y. Li. Capillary electrophoresis separation ofp-sulfonated calix[n]arenes, n=4, 6, 8. Talanta, 1998, 45: 683-691
[30] K. Oshita, T. Takayangagi, M. Oshima. Complex formation analysis of water-soluble calixarenes by capillary zone electrophoresis. J. Chromatogr. A, 2001, 934: 113-122
[31] 傅崇岗，刘爱林，赵艳芳，张立云．样品堆积富集毛细管电泳测定磺化杯芳烃．理化检验-化学分册，2005，41：658-660
[32] 韩珀．非水毛细管电泳的应用．郑州大学学士毕业论文，2004
[33] C. D. Gutsche, M. Iqbal. Pentacyclo[19,3.1.13,7.19,13,115,19]octacosa-1(25),3,5, 7(28),9,11, 13(27),15,17,19(26),21,23-dodecanene-25,26,27,28-tetrol——5,11,17,23-tetrakis(1,1-diethylethyl). Org. Synth., 1990, 68: 234-237
[34] 李建森，陈远荫．对叔丁基杯[6]芳烃合成方法的改进．化学试剂，2000，22(3)：178-183
[35] C. D. Gutsche, B. Dhawan, M. Leonis, D. Stewart. Nonacyclo [43,3.1.13,7.19,13, 115,19, 121,25, 127,31,133,37, 139,43]hexapentaconta-1(49),3,5,7(56),9,11,13(55), 15,17,19(54),21,23,25(53),27,29,31 (52),33,35,37(51),39,41,43(50),45,47-tetracosaene-49,50,51,52,53,54,55,56-octol-5,11,17,23,29,35,4 1,47-octakis(1,1-dimethylethyl). Org. Synth., 1990, 68: 243-246
[36] C. D. Gutsche, L. G. Lin. Calixarenes 12 the synthesis of functionalized calixarenes. Tetrahedron, 1986, 42(6): 1633-1640
[1] G. Liu, X. Y. Pang, R. F. Li. The study about adsorption heat on 5A molecular sievewith reverse gas chromatogram. Guangxi Sciences, 2006, 13(1): 37-39
[2] Y. Y. Zhou, Q. Lu, C. Liu, S. K. She, L. Wang. Spectrofluorimetric study on the inclusion interaction between lomefloxacin and p-sulfonated calix[4]arene and its analytical application. Spectrochimica Acta Part A, 2006, 64(3): 748-756
[3] D. Namor, A. F. Danil, J. Wang, I. Orellana, V. Gomez, F. J. Sueros, D. A. Tanaka. Pacheco. thermodynamic and electrochemical aspects of p-tert-butylcalix(n)arenes (n=4,6,8) and their interactions with amines. J. Inclusion Phenomena and Molecular Recognition in Chem., 1994, 19(1-4): 371-387
[4] F. Sansone, S. Barboso, A. Csanati, D. Sciotto, R. Ungaro. A new chiral rigid cone water soluble peptidocalix[4]arene and its inclusion complexes with α-amino acids and aromatic ammonium cations. Tetrahedron Lett., 1999, 40(25): 4741-4744
[5] 李来生，黄志兵，刘旭，王宇晓．高效液相色谱法研究水溶性杯[8]芳烃与二苯胺磺酸钠的相互作用．分析化学研究简报，2005，23(4)：509-511
[6] 赵邦屯，张衡益，刘育．杯芳烃的配位热力学研究进展．洛阳师范学院学报，2003，5：30-38
[7] 施介华，江峰，严巍，王纪康，王桂林．烃类化合物在不同色谱柱上的定量结构-保留相关性研究．分析化学研究报告，2005，33(2)：181-186
[8] 薄涛，杨学东，贡素萱，李克安，刘虎威．毛细管区带电泳分离山酮类化合物的结构、电泳迁移定量关系研究．色谱，2003，21(6)：535-540
[9] 张燕玲，郭亦然，王耘，乔延江．化合物色谱保留参数与其三维结构关系的研究．色谱，2005，23(3)：223-228
[10] 陈景文，杨丽红，王连生．苯砜基环烷酸酯类化合物的分子结构与色谱保留的定量关系．分析化学研究简报，1997，25(2)：189-192
[11] 郄毅巍，李江波，曹维良，张敬畅，刘华．环醇和酯的定量结构一保留关系的研究．北京化工大学学报，2003，30f3)：85-88
[12] J. Jiskra, H. A. Claessens, C. A. Cramers, R. Kaliszan. Quantitative structure-retention relationships in comparative studiesof behavior of stationary phases under high-performance liquidchromatography and capillary electrochromatography conditions. J. Chromatogr. A, 2002, 977(2): 193-206
[13] B. Tomasz, K. Roman. Predictive approaches to gradient retention based on analyte structural descriptors from calculation chemistry. J. Chromatogr. A, 2003, 987(1-2): 29-37
[14] F. Ruggieri, A. D. Archivio, G. Carlucci, P. Mazzeo. Application of artificial neural networks for prediction of retention factorsof triazine herbicides in reversed-phase liquid chromatography. J. Chromatogr. A, 2005, 1076(1-2): 163-169
[15] R Mnuk, L. Feltl. Gas chromatographic study of the inclusion properties of calixarenes Ⅰ. p-tert.-Butylcalix[4]arene in a micropacked column. J. Chromatogr. A, 1995,696(1): 101-112
[16] P. Mnuk, L. Feltl, V. Schuring. Gas chromatographic study of the inclusion properties of calixarenes Ⅱ. Selective properties of cyclic tetra- to octamers derived from phenol, and some provlems associated with the use of calixarenes in capillary gas chromatography. J. Chromatogr. A, 1996, 732(1): 63-74
[17] 张兵，商志才，赵文娜，邹建卫，胡桂香，俞庆森．5-芳基乙内酰脲类化合物QSERR研究．物理化学学报，2003，19(10)：938-943
[18] 张青，赵洪霞，陈吉平，梁鑫淼．多氯联苯的正辛醇-空气分配系数与气相色谱保留参数的关联．色谱，2005，23(5)：441-444
[19] M. Muller, W. Kordel. Comparison of screening methods for the estimation of adsorption coefficients on soil. Chemosphere, 1996, 32(12): 2493-2504
[20] G. Bazylak, L. J. Nagels. A novel potentiometric approach for detection of beta-adrenergics and beta-adrenolytics in high-performance liquid chromatography. Farmaco, 2003, 58(8): 591-603
[21] W. Du, G. S. Yang, X. Q. Wang, S. L.Yuan, L. Zhou, D. Xu, C. P. Liu. Enantioseparation of 15 organic phosphonate esters on the cellulose tris(3,5-dimethylphenyl carbamate) chiral stationary phase by HPLC. Talanta, 2003, 60: 1187-1195
[22] 王晓荣，堵锡华．~mB对气相色谱保留指数的QSPR研究．南京工业大学报，2002，24(3)：31-37
[23] 颜冬云，蒋欣，赵振华，余贵芬，谷成刚．运用QSPR预测有机磷农药的色谱保留值．环境化学，2006，25(2)：220-224
[24] B. T. Luke. Comparison of different data set screening methods for use in QSAR/QSPR generation studies. J. Molecular Structure (Theochem), 2000, 507: 229-238
[25] B. T. Luke. Comparison of three different QSAR/QSPR generation techniques. J. Molecular Structure (Theochem), 1999, 468 (1-2): 13-20
[26] J. W. Chen, Q. G. Huang, L. S. Wang, H. M. Hu, Z. Zhang. Using aml hamiltonian and factor analysis in prediction of partition properties for phenylthio,phenylsulfinyl and phenylsulfonyl acetates. Chemosphere, 1996, 33(12): 2565-2575
[27] A. Dominik, H. J. Roth, K. D. Schierbaum, W. Goepel. Supramolecular complexes based on calixarenes: force field calculations and applications for chemical sensors. Supramolecular Sci., 1994, 1(11): 11-19
[28] M. C. Salazar, J. L. Paz, A. J. Hernandez. Ab initio basis set study of the CO...He van der waais interaction. J. Molecular Structure (Theochem), 1999, 493: 133-137
[29] M. C. Salazar, J. Paz, A. J. Hernandez. Ab initio test study of the N_2...H_2 and N_2...He van der waals dimmers. J. Molecular Structure (Theochem), 1999, 464: 183-189
[30] 缪方明，宿秀梅，齐强．β-环糊精-三乙醇胺超分子体系的量子化学从头计算研究．天津师范大学学报(自然学报)，2003，23(1)：1-3
[31] 沈晓春，朱龙华，张树生．量子化学方法在色谱分析中的应用．中国计量学院学报，2003，14(1)： 296-299
[32] 李丹妮，练鸿振，康玉芬，缪强．量子化学计算预测高效液相色谱键合相的保留机理．分析科学学报，2005，21(6)：591-595
[33] 沈晓春，陈平，郭伟强，冷桃花，董明利．用毛细管电泳方法分离有机酸的研究．浙江大学学报，2002，29(6)：679-684
[34] K. Takenaka, Y. Obora, L. H. Jiang. Solid-state and solution structures of calix[4]arene tetramethyl ethercontaining four diphenylphosphino moieties at the upper rim. Bull. Chem. Soc. Jpn., 2001, 74: 1709-1715
[35] 李勇，郑衍昭，郭金梁，宋心琦．杯[4]芳烃的构象间转换机理的CNDO／2法研究．物理化学学报，1995，11(7)：627-631
[36] G. Nemethy, H. A. Scheraga. The structure of water and hydrophobic bonding in proteins. Ⅲ. the thermodynamic properties of hydrophobic bonds in proteins. J. Physical Chem., 1962, 66: 1773-1789
[37] P. D. Ross, S. Subramanian. Thermodynamics of protein association reactions: forces contributing to stability. Biochem., 1981, 20(11): 3096-3102