硼酸盐和氯硅酸盐荧光粉的制备与性能研究
摘要
本文以适合近紫外LED激发的荧光材料为研究对象,采用高温固相法合成了几种很有应用前景的LED用荧光材料。利用X射线粉末衍射(XRD)探索了合成材料的晶体结构。通过改变激活剂和共激活剂的掺杂浓度,借助于激发谱、发射谱、光度计等手段对材料的发光性能进行了详细的研究。结果如下：合成了绿色荧光粉Sr3B2O6:Tb3+,Li+,分析了碱土金属离子Li+作为电荷补偿剂对样品发光性能的影响,发现加入电荷补偿剂可以很大程度提高样品的发光亮度。制备了新型的CaBa2(BO3)2:Eu2+绿色荧光粉,其激发主峰值位于400nm,与近紫外LED管芯(350-410nm)匹配；当Eu2+浓度为0.02时,发光性能最好,Eu2+含量较大时,Eu2+之间共振能量传递增强,发生浓度猝灭现象。合成了Ca2Si03Cl2:Eu3+,Li+红色荧光粉,其激发主峰值与近紫外管芯(350-410nm)匹配；分析了碱土金属离子Li+作为电荷补偿剂及Eu3+含量对样品发光性能的影响。研究了Eu2+,Mn2+共激活的单一基质Ca10(Si2O7)3Cl2白色发光材料的发光性质。Eu2+中心形成峰值分别为426nm,523nm的特征宽带,而Eu2+中心向Mn2+中心的能量传递导致了峰值为585nm的发射,三个谱带叠加从而在单一基质中得到了白光；其激发光谱分布在250—450nm的波长范围,可以被InGaN管芯产生的350—410nm辐射有效激发。
In this paper, some kinds of phosphor used for near ultraviolet LED were fabricated by traditional high temperate solid stated method. Compare with Joint Committee on Powder Diffraction Standards, the crystal structure of the phosphors were studied. And the emission and excitation spectra of the phosphor were investigated, so that the luminescent properties of the phosphor can be explained. The chief contents are given as follows:The green phosphor Sr3B2O6:Tb3+,Li+ was prepared. The role of charge compensation of Li+ ions to the emission intensity was studied also. It was found that Li+ ions can enhance the intensity of the emissions well. A novel green-emitting phosphor CaBa2(BO3)2:Eu2+ was prepared. The excitation spectrum is a broad band and its main peak is at 400nm, which matches the emission of near ultraviolet light-emitting diodes (nUVLEDs). When the concentration of doped Eu2+ is 2%, the CaBa2(BO3)2:Eu2+ has the strongest emission intensity.The red phosphor Ca2SiO3Cl2:Eu3+, Li+ was fabricated by solid stated method. The excitation spectrum is coupled well with the emission of UVLEDs (350-410 nm). The effects of doped-Eu3+ concentration and charge compensations of Li+ on the emission intensity are also investigated. The luminescence properties of single white emitting phosphor Eu2+,Mn2+ co-activated Ca10(Si2O7)3Cl2 were studied. The emission peaks that located at 426 nm and 523 nm originated from the center of the Eu2+, while the 585 nm emission was attributed to the energy transfer from Eu2+ to Mn2+.White light could be obtained by mixing the three emission colors of blue (426nm), green (523 nm) and red (585 nm) in the single host. The excitation bands of the three emission colors were all extended from 250 nm to 450 nm. Phosphor can be excited effectively by InGaN chips in the range of 380-410 nm.
In this paper, some kinds of phosphor used for near ultraviolet LED were fabricated by traditional high temperate solid stated method. Compare with Joint Committee on Powder Diffraction Standards, the crystal structure of the phosphors were studied. And the emission and excitation spectra of the phosphor were investigated, so that the luminescent properties of the phosphor can be explained. The chief contents are given as follows:The green phosphor Sr3B2O6:Tb3+,Li+ was prepared. The role of charge compensation of Li+ ions to the emission intensity was studied also. It was found that Li+ ions can enhance the intensity of the emissions well. A novel green-emitting phosphor CaBa2(BO3)2:Eu2+ was prepared. The excitation spectrum is a broad band and its main peak is at 400nm, which matches the emission of near ultraviolet light-emitting diodes (nUVLEDs). When the concentration of doped Eu2+ is 2%, the CaBa2(BO3)2:Eu2+ has the strongest emission intensity.The red phosphor Ca2SiO3Cl2:Eu3+, Li+ was fabricated by solid stated method. The excitation spectrum is coupled well with the emission of UVLEDs (350-410 nm). The effects of doped-Eu3+ concentration and charge compensations of Li+ on the emission intensity are also investigated. The luminescence properties of single white emitting phosphor Eu2+,Mn2+ co-activated Ca10(Si2O7)3Cl2 were studied. The emission peaks that located at 426 nm and 523 nm originated from the center of the Eu2+, while the 585 nm emission was attributed to the energy transfer from Eu2+ to Mn2+.White light could be obtained by mixing the three emission colors of blue (426nm), green (523 nm) and red (585 nm) in the single host. The excitation bands of the three emission colors were all extended from 250 nm to 450 nm. Phosphor can be excited effectively by InGaN chips in the range of 380-410 nm.
引文
[1]王海波,朱宪忠,任巨光.荧光粉涂敷法制白光LED前景广阔.[J].中国照明电器,2004,5：1-4.
[2]臧竞存,刘燕行.固体白光照明和稀土发光材料.中国科技论文在线,2005,1-5.
[3]王进.光转换白光LED研究.中国海洋大学.2005年1-3.
[4]杨笑卫(译).高亮度、全光色LED.[J].中国照明电器,2001,4：23-25.
[5]郝海涛.白光LED用荧光材料的制备及性能研究.太原理工大学硕士论文,2006,3-5.
[6]Maruska H.P., Tietjen.J.J. The preparation and properties of vapor-desited single-crystal-line GaN.[J].Applied Physics Letter,1969(15):327
[7]刘坚斌,李培咸,郝跃.高亮度GaN基蓝光与白光LED的研究进展.[J].量子电子学报,2005,22(10)：673-679.
[8]武毅.绿色光源—LED.[J]灯与照明,2005,30(2)：47-50.
[9]Werner K. Higher. visibility for LEDs.[J].IEEE Spectrum,1994,31(7):30-34.
[10]Lim M A, Park J K, Kim C H, Park H.D. Luminescence characteristics of green light emitting Ba2SiO4:Eu2+ phosphor.[J].Mater. Sci. Lett.,2003,22:1351-1353.
[11]蒋大鹏,赵成久,侯凤勤,刘学彦,范翊,张立功,褚明辉,申德振,范希武.白光发光二极管的制备技术及主要特性.[J].发光学报,2003,24(4)：385-389.
[12]YAO Guang-qing, DUAN Jie-fei, REN Min, YU Hai-dong, LIN Jian-hua, Preparation and Luminescence of Blue Light Conversion Material YAG:Ce.[J].Chinese Journal of luminescence., 2001,22(10):(Supp)21-23.
[13]孟继武,王燕辛,王晶,郑荣儿.光转换白光LEDs的研究.[J].光电子·激光,2003,14(6)：566-569.
[14]刘行仁,薛胜薜,黄德森,林秀华.白光LED的现状和问题.[J].光源与照明,2003,3：4-8.
[15]王少丽.《白光LED用硼酸盐荧光材料的合成及性能研究》.河北大学硕士学位论文.2008,1-2
[16]Yuexiao Pan, Mingmei Wu, Qiang Su.Tailored photoluminescence of YAG:Ce phosphor through various methods.[J]. Journal of Physics and Chemistry of Solids,2004,65:845-850.
[17]Qiang Li, Lian Gao, Dongsheng Yan. The crystal structure and spectra of nano-scale YAG:Ce3+.[J]. Materials Chemistry and Physics,2000,64:41-44.
[18]LED散热问题的解决方案,太阳能商情网,2008-7-7.
[19]徐叙熔,苏勉曾《发光学与发光材料》.北京：化学工业出版社,2004,第1版：53-55.
[20]田晶.《近紫外光LED芯片用荧光粉的制备与性能研究》.河北大学硕士学位论文.2008,6-7
[21]Kottaisamy M., Rao RP., Avudaithai M., Srinivasan LK. Sundaram V., Jagannathan R. On the formation of flux grown Y2O2S-Eu3+ red phosphor.[J]. J. Electrochem. Soc.1995,142(9):3205-3209.
[22]张若桦,申泮文.稀土元素化学.[M].天津：科技出版社,1987.
[23]《固体发光》编写组.固体发光.[M].安徽：中国科技大学出版社,1976.
[24]孙家跃等.固体发光材料.[M].北京：化学工业出版社,2003：7.
[25]Yuji Uchida, Tatsumi Setomotoa, Tsunemasa Taguchia, Yoshinori Nakagawa,Kazuto Miyazakib. Characteristics of high-efficient InGaN-based white LED lighting. [J].Pro.SPIE.,2000,4079:120-126.
[26]孙晓园,张家骅,张霞.新一代白光LED照明用一种适于近紫外光激发的单一白光荧光粉.[J].发光学报,2005,26(3)：404-406.
[27]刘洁,孙家跃,石春山.与LED匹配的白光发射荧光体的研究进展.[J].化学通报,2005,6：417-424.
[28]尹长安,赵成久,刘学彦,侯凤勤,郑岩,卢景贵,蒋大鹏,申德振.白光LED的最新进展.[J].发光学报,2000,21(4)：380-382.
[29]中国科学院吉林物理所等,固体发光,中国科技大学,1976,4.
[30]李旭.《白光LED用荧光粉的性能和制备》.河北大学硕士学位论文.2006,2-3.
[31]臧竞存,刘燕行.固体白光照明和稀土发光材料.中国科技论文在线.2005,1-5.
[32]杨广伟.《磷酸盐稀土荧光材料的制备及性能研究》.2008,8-9.
[33]Jun-Ho Yum, Seok-Soon Kim, Yung-Eun Sung. Y3Al5O12:Ce0.05 phosphor coatings on a flexible substrate for use in white light-emitting diodes. [J].Colloids and Surfaces A:physicochem. Eng. Aspects,2004,251:203-207.
[34]王健,瞿存德,高正中.稀土硼酸盐黄色荧光粉的合成[J].北京化工大学学报.1998,25(4)：81-84.
[35]高玮,古宏晨.阴极射线管用Y2O2S:Eu红粉的市场、生产和研究[J].稀土学报,1998,19(4)：66-69.
[36]YU Xi-Bin,YANG Liang-Zhun,YANG Shi-Ping, et al.. SrZnO2:Eu3+, Li+长波紫外激发红光荧光体的合成及发光性能研究[J]J.Rare Earths,2005,23(5):533-536.
[37]Lianhua Tian, Byung-Yong Yu, Chong-Hong Pyun, et al. New red phosphors BaZr(BO3)2 and SrAl2B2O7 doped with Eu3+ for PDP applications. Solid State Commun.2004,129:43-46.
[38]D.S. Thakare, S.K. Omanwar, S.V. Moharil, S.M. Dhopte, P.L. Muthal, V.K. Kondawar.Combustion synthesis of borate phosphors. [J]. Optical Materials,2007,29(12):1731-1735.
[39]Fang Ying, Zhuang Weidong, Sun Yimin, et al. Luminescence Properties of Eu2+ and Mn2+ Co-Doped Ca8Mg(Si04) 4C12. [J]. J Rare Earth,2004,22 (1):122-125.
[40]Zhiping Yang, Xu Li, Xingmin LI, et al. Synthesis of red-emitting phosphors Ca1-xSrxS:Eu2+ used in white light emitting diodes by combustion[J]. Journal of the chinese ceramic society,2006,34(8): 966-969.
[41]Woan-Jen Yang, Teng-Ming Chen. White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes.[J]. Applied Physics Letters,2006,88(10):101903.
[42]乔彬,张中太,唐子龙,张俊英,王晓欣.Eu2+,Mn2+共激活碱土镁硅酸盐基红色荧光粉的发光性能.[J].中国稀土学报,2003,21(2)：192-195.
[43]Chun-Kuei Chang and Teng-Ming Chen. Sr3B2O6:Ce3+,Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2007,91:081902.
[44]董岩,蒋建清,肖睿,刘刚,陈会东,于金.(Y,Gd) BO3:Eu3+荧光粉的合成及粒度控制.[J].中国稀土学报,2004,2(2)：201.205.
[45]林海,刘行仁,许武亮Ca8M(Si04)4Cl2(M=Mg,Zn)中Ce3+的发光性质.[J].硅酸盐报,1997,25,(14)：494-498.
[46]孙家跃,夏志国,杜海燕.用碱土氯硅酸盐基稀土光致发光材料的研究.[J].国外建材科技,2004,25(4)：11-13.
[47]Zeng Q H, Hiroaki T, Kiichirou E,tanamachi N, Zhang S. Ba5Si04Cl6:Eu2+:An intense blue emission phosphor under vacuum ultraviolet and near-ultraviolet excitation.[J]. Appl. Phys. Lett.,2006,88:051906-1-051906-3.
[48]Liu J,Lian H Z,Sun J Y,shi chun shan. Characterization and properties of green emitting Ca3Si04Cl2:Eu2+ power phosphor for white light emitting diodes.[J].Chem. Lett.,2005,34(10): 1340-1341.
[49]Shi Shikao, Wang Jiye. Combustion synthesis of Eu3+ activated Y3Al5O12 phosphor nanoparticles.[J]. Journal of Alloys and Compounds,2001,327:82-86.
[50]N. Taghavinia, G. Lerondel, H. Makino, et al. Blue- and red-emitting phosphor nanoparticles embedded in a porous matrix.[J]. Thin Solid Films,2006,503:190-195.
[51]Hongmei Yang, Jianxin Shi, Menglian Gong, et al. Synthesis and photoluminescence of Eu3+-or Tb3+-doped Mg2SiO4 nanoparticles prepared by a combined novel approach.[J]. Journal of Luminescence,2006,118:257-264.
[52]Akira Komeno, Kazuyoshi Uematsu, Kenji Toda, et al. VUV properties of Eu-doped alkaline earth magnesium silicate.[J]. Journal of Alloys and Compounds,2006,408-412:871-874.
[53]Zhengliang Wang, Hongbin Liang, Jing Wang, et al. Red-light-emitting diodes fabricated by near-ultraviolet InGaN chips with molybdate phosphors.[J]. Applied Physics Letters,2006,89:071921
[54]O. Ozuna, G. A. Hirata, J. McKittrick. Luminescence enhancement in Eu3+-doped α- and γ-Al2O3 produced by pressure-assisted low-temperature combustion synthesis. [J]. Applied Physics Letters, 2004,84(8):1296-1298.
[55]D. Haranath, Harish Chander, Pooja Sharma, et al. Enhanced luminescence of Y3Al5O12:Ce3+ nanophosphor for white lightemitting diodes.[J]. Applied Physics Letters,2006,89:173118.
[56]Sho Abe, Kazuyoshi Uematsu, Kenji Toda, et al. Luminescent properties of red long persistence phosphors, BaMg2Si2O7:Eu2+, Mn2+.[J]. Journal of Alloys and Compounds,2006,408-412:911-914.
[57]徐光青,郑治祥,汤文明Mn2+、Ce3+共掺杂Zn2 SiO4材料的溶胶-凝胶法制备及光学性能研究[J].合肥工业大学学报(自然科学版),2006,29(4).
[58]Yu-Ho Won, Ho Seong Jang, Won Bin Im, et al. Tunable full-color-emitting La0.827Al11.9Ol9.09: Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes[J]. Applied Physics Letters, 2006,89:231909.
[59]Junxi Wan, Zhenghua Wang, Xiangying Chen, et al. Controlled synthesis and relationship between luminescent properties and shape/crystal structure of Zn2SiO4:Mn2+ phosphor.[J]. Journal of Luminescence,2006,121:32-38.
[60]姚光庆,张亮,苏勉曾.Eu2+和Mn2+在Sr3MgSi2O8中的光致发光研究.[J].高等学校化学报1997,18(1)：1-5.
[61]郭常新,李碧琳.纳米ZnS:Mn荧光粉的余辉研究[J].发光学报,2001,22(3)：223.
[2]臧竞存,刘燕行.固体白光照明和稀土发光材料.中国科技论文在线,2005,1-5.
[3]王进.光转换白光LED研究.中国海洋大学.2005年1-3.
[4]杨笑卫(译).高亮度、全光色LED.[J].中国照明电器,2001,4：23-25.
[5]郝海涛.白光LED用荧光材料的制备及性能研究.太原理工大学硕士论文,2006,3-5.
[6]Maruska H.P., Tietjen.J.J. The preparation and properties of vapor-desited single-crystal-line GaN.[J].Applied Physics Letter,1969(15):327
[7]刘坚斌,李培咸,郝跃.高亮度GaN基蓝光与白光LED的研究进展.[J].量子电子学报,2005,22(10)：673-679.
[8]武毅.绿色光源—LED.[J]灯与照明,2005,30(2)：47-50.
[9]Werner K. Higher. visibility for LEDs.[J].IEEE Spectrum,1994,31(7):30-34.
[10]Lim M A, Park J K, Kim C H, Park H.D. Luminescence characteristics of green light emitting Ba2SiO4:Eu2+ phosphor.[J].Mater. Sci. Lett.,2003,22:1351-1353.
[11]蒋大鹏,赵成久,侯凤勤,刘学彦,范翊,张立功,褚明辉,申德振,范希武.白光发光二极管的制备技术及主要特性.[J].发光学报,2003,24(4)：385-389.
[12]YAO Guang-qing, DUAN Jie-fei, REN Min, YU Hai-dong, LIN Jian-hua, Preparation and Luminescence of Blue Light Conversion Material YAG:Ce.[J].Chinese Journal of luminescence., 2001,22(10):(Supp)21-23.
[13]孟继武,王燕辛,王晶,郑荣儿.光转换白光LEDs的研究.[J].光电子·激光,2003,14(6)：566-569.
[14]刘行仁,薛胜薜,黄德森,林秀华.白光LED的现状和问题.[J].光源与照明,2003,3：4-8.
[15]王少丽.《白光LED用硼酸盐荧光材料的合成及性能研究》.河北大学硕士学位论文.2008,1-2
[16]Yuexiao Pan, Mingmei Wu, Qiang Su.Tailored photoluminescence of YAG:Ce phosphor through various methods.[J]. Journal of Physics and Chemistry of Solids,2004,65:845-850.
[17]Qiang Li, Lian Gao, Dongsheng Yan. The crystal structure and spectra of nano-scale YAG:Ce3+.[J]. Materials Chemistry and Physics,2000,64:41-44.
[18]LED散热问题的解决方案,太阳能商情网,2008-7-7.
[19]徐叙熔,苏勉曾《发光学与发光材料》.北京：化学工业出版社,2004,第1版：53-55.
[20]田晶.《近紫外光LED芯片用荧光粉的制备与性能研究》.河北大学硕士学位论文.2008,6-7
[21]Kottaisamy M., Rao RP., Avudaithai M., Srinivasan LK. Sundaram V., Jagannathan R. On the formation of flux grown Y2O2S-Eu3+ red phosphor.[J]. J. Electrochem. Soc.1995,142(9):3205-3209.
[22]张若桦,申泮文.稀土元素化学.[M].天津：科技出版社,1987.
[23]《固体发光》编写组.固体发光.[M].安徽：中国科技大学出版社,1976.
[24]孙家跃等.固体发光材料.[M].北京：化学工业出版社,2003：7.
[25]Yuji Uchida, Tatsumi Setomotoa, Tsunemasa Taguchia, Yoshinori Nakagawa,Kazuto Miyazakib. Characteristics of high-efficient InGaN-based white LED lighting. [J].Pro.SPIE.,2000,4079:120-126.
[26]孙晓园,张家骅,张霞.新一代白光LED照明用一种适于近紫外光激发的单一白光荧光粉.[J].发光学报,2005,26(3)：404-406.
[27]刘洁,孙家跃,石春山.与LED匹配的白光发射荧光体的研究进展.[J].化学通报,2005,6：417-424.
[28]尹长安,赵成久,刘学彦,侯凤勤,郑岩,卢景贵,蒋大鹏,申德振.白光LED的最新进展.[J].发光学报,2000,21(4)：380-382.
[29]中国科学院吉林物理所等,固体发光,中国科技大学,1976,4.
[30]李旭.《白光LED用荧光粉的性能和制备》.河北大学硕士学位论文.2006,2-3.
[31]臧竞存,刘燕行.固体白光照明和稀土发光材料.中国科技论文在线.2005,1-5.
[32]杨广伟.《磷酸盐稀土荧光材料的制备及性能研究》.2008,8-9.
[33]Jun-Ho Yum, Seok-Soon Kim, Yung-Eun Sung. Y3Al5O12:Ce0.05 phosphor coatings on a flexible substrate for use in white light-emitting diodes. [J].Colloids and Surfaces A:physicochem. Eng. Aspects,2004,251:203-207.
[34]王健,瞿存德,高正中.稀土硼酸盐黄色荧光粉的合成[J].北京化工大学学报.1998,25(4)：81-84.
[35]高玮,古宏晨.阴极射线管用Y2O2S:Eu红粉的市场、生产和研究[J].稀土学报,1998,19(4)：66-69.
[36]YU Xi-Bin,YANG Liang-Zhun,YANG Shi-Ping, et al.. SrZnO2:Eu3+, Li+长波紫外激发红光荧光体的合成及发光性能研究[J]J.Rare Earths,2005,23(5):533-536.
[37]Lianhua Tian, Byung-Yong Yu, Chong-Hong Pyun, et al. New red phosphors BaZr(BO3)2 and SrAl2B2O7 doped with Eu3+ for PDP applications. Solid State Commun.2004,129:43-46.
[38]D.S. Thakare, S.K. Omanwar, S.V. Moharil, S.M. Dhopte, P.L. Muthal, V.K. Kondawar.Combustion synthesis of borate phosphors. [J]. Optical Materials,2007,29(12):1731-1735.
[39]Fang Ying, Zhuang Weidong, Sun Yimin, et al. Luminescence Properties of Eu2+ and Mn2+ Co-Doped Ca8Mg(Si04) 4C12. [J]. J Rare Earth,2004,22 (1):122-125.
[40]Zhiping Yang, Xu Li, Xingmin LI, et al. Synthesis of red-emitting phosphors Ca1-xSrxS:Eu2+ used in white light emitting diodes by combustion[J]. Journal of the chinese ceramic society,2006,34(8): 966-969.
[41]Woan-Jen Yang, Teng-Ming Chen. White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes.[J]. Applied Physics Letters,2006,88(10):101903.
[42]乔彬,张中太,唐子龙,张俊英,王晓欣.Eu2+,Mn2+共激活碱土镁硅酸盐基红色荧光粉的发光性能.[J].中国稀土学报,2003,21(2)：192-195.
[43]Chun-Kuei Chang and Teng-Ming Chen. Sr3B2O6:Ce3+,Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2007,91:081902.
[44]董岩,蒋建清,肖睿,刘刚,陈会东,于金.(Y,Gd) BO3:Eu3+荧光粉的合成及粒度控制.[J].中国稀土学报,2004,2(2)：201.205.
[45]林海,刘行仁,许武亮Ca8M(Si04)4Cl2(M=Mg,Zn)中Ce3+的发光性质.[J].硅酸盐报,1997,25,(14)：494-498.
[46]孙家跃,夏志国,杜海燕.用碱土氯硅酸盐基稀土光致发光材料的研究.[J].国外建材科技,2004,25(4)：11-13.
[47]Zeng Q H, Hiroaki T, Kiichirou E,tanamachi N, Zhang S. Ba5Si04Cl6:Eu2+:An intense blue emission phosphor under vacuum ultraviolet and near-ultraviolet excitation.[J]. Appl. Phys. Lett.,2006,88:051906-1-051906-3.
[48]Liu J,Lian H Z,Sun J Y,shi chun shan. Characterization and properties of green emitting Ca3Si04Cl2:Eu2+ power phosphor for white light emitting diodes.[J].Chem. Lett.,2005,34(10): 1340-1341.
[49]Shi Shikao, Wang Jiye. Combustion synthesis of Eu3+ activated Y3Al5O12 phosphor nanoparticles.[J]. Journal of Alloys and Compounds,2001,327:82-86.
[50]N. Taghavinia, G. Lerondel, H. Makino, et al. Blue- and red-emitting phosphor nanoparticles embedded in a porous matrix.[J]. Thin Solid Films,2006,503:190-195.
[51]Hongmei Yang, Jianxin Shi, Menglian Gong, et al. Synthesis and photoluminescence of Eu3+-or Tb3+-doped Mg2SiO4 nanoparticles prepared by a combined novel approach.[J]. Journal of Luminescence,2006,118:257-264.
[52]Akira Komeno, Kazuyoshi Uematsu, Kenji Toda, et al. VUV properties of Eu-doped alkaline earth magnesium silicate.[J]. Journal of Alloys and Compounds,2006,408-412:871-874.
[53]Zhengliang Wang, Hongbin Liang, Jing Wang, et al. Red-light-emitting diodes fabricated by near-ultraviolet InGaN chips with molybdate phosphors.[J]. Applied Physics Letters,2006,89:071921
[54]O. Ozuna, G. A. Hirata, J. McKittrick. Luminescence enhancement in Eu3+-doped α- and γ-Al2O3 produced by pressure-assisted low-temperature combustion synthesis. [J]. Applied Physics Letters, 2004,84(8):1296-1298.
[55]D. Haranath, Harish Chander, Pooja Sharma, et al. Enhanced luminescence of Y3Al5O12:Ce3+ nanophosphor for white lightemitting diodes.[J]. Applied Physics Letters,2006,89:173118.
[56]Sho Abe, Kazuyoshi Uematsu, Kenji Toda, et al. Luminescent properties of red long persistence phosphors, BaMg2Si2O7:Eu2+, Mn2+.[J]. Journal of Alloys and Compounds,2006,408-412:911-914.
[57]徐光青,郑治祥,汤文明Mn2+、Ce3+共掺杂Zn2 SiO4材料的溶胶-凝胶法制备及光学性能研究[J].合肥工业大学学报(自然科学版),2006,29(4).
[58]Yu-Ho Won, Ho Seong Jang, Won Bin Im, et al. Tunable full-color-emitting La0.827Al11.9Ol9.09: Eu2+,Mn2+ phosphor for application to warm white-light-emitting diodes[J]. Applied Physics Letters, 2006,89:231909.
[59]Junxi Wan, Zhenghua Wang, Xiangying Chen, et al. Controlled synthesis and relationship between luminescent properties and shape/crystal structure of Zn2SiO4:Mn2+ phosphor.[J]. Journal of Luminescence,2006,121:32-38.
[60]姚光庆,张亮,苏勉曾.Eu2+和Mn2+在Sr3MgSi2O8中的光致发光研究.[J].高等学校化学报1997,18(1)：1-5.
[61]郭常新,李碧琳.纳米ZnS:Mn荧光粉的余辉研究[J].发光学报,2001,22(3)：223.