新型Nd~（3+）掺杂无机近红外发光材料的制备及发光性能
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摘要
稀土Nd3+掺杂的近红外发光具有穿透深度大、线宽窄、背景小等特点,在生物分析标记物等方面有重要的应用前景。其应用的重要瓶颈是其近红外发光强度比较弱。通过敏化离子与Nd3+之间的能量传递是提高其近红外发光强度的重要方式。Eu2+具有4f→5d电偶极允许跃迁,可以高效地吸收激发光能量,并可能传递能量给Nd3+离子并敏化其发光。本文致力于研究Eu2+敏化的新型高效Nd3+掺杂近红外发光材料并探讨Eu2+对Nd3+近红外发光能量传递的机理。具体实验内容有：
用高温固相法制备了Ca2BO3Cl：Eu2+,Nd3+近红外发光材料,结果表明,Eu2+的掺入可提高Nd3+的近红外发光强度,Eu2+,Nd3+的掺杂量分别为0.03、0.05时,近红外发光最强。证明了Eu2+通过无辐射能量传递方式向Nd3+有效地传递了能量,对Nd3+近红外有很好的敏化作用。
用高温固相法制备了Ca3SiO4Cl2：Eu2+,Nd3+、Ca8Mg(SiO4)4Cl2：Eu2+,Nd3+发光材料,发现其中Eu2+对Nd3+的近红外发光存在敏化作用。研究了Eu2+、Nd3+的掺杂浓度对近红外发光性能的影响及相对强度变化的规律。考察了煅烧温度、煅烧时间对近红外发光性能的影响。在Ca8Mg(SiO4)4Cl2:Eu2+,Nd3+体系中,样品的近红外发光强度随着Eu2+的掺杂浓度的增大先增强后减弱,Eu2+的掺杂量为0.08时,近红外发光最强；Nd3+的掺杂浓度为0.10时,近红外发光最强。样品在煅烧温度为1100℃下煅烧3h,近红外发光最强。分析了Eu2+与Nd3+之间能量传递的机理：Eu2+具有4f→5d跃迁轨道,可以有效地吸收能量,并将能量转移到的Nd3+的能级上,发生能量传递,增强Nd3+的近红外发光。
用高温固相法制备了Sr4Si3O8Cl4：0.08Eu2+,0.08Nd3+发光材料,发现了该体系中Eu2+对Nd3+的近红外发光存在敏化作用,近红外发光强度提高了10倍左右,Eu2+向Nd3+的能量传递效率为19.7%。研究了Ca,Mg掺杂的Sr4Si3O8Cl4：0.08Eu2+,0.08Nd3+系列发光材料,随着Ca含量的增加,样品的近红外发光呈现逐渐增强的趋势。样品的近红外发光强度随着Mg含量的增加呈现逐渐减弱的趋势。
用固相法制备了LiSrPO4：Eu2+、LiCaPO4：Eu2+、KCaPO4：Eu2+、NaCaPO4：Eu2+系列的高效蓝色、绿色荧光粉,优化了各荧光粉的制备条件。其中,研究表明LiSrPO4：Eu2+随着掺杂量的变化出现不同的发光中心；LiCaPO4：Eu2+是一种新型高效蓝色荧光粉；掺杂少量的Y3+可提高KCaPO4：Eu2+荧光粉的发光强度。进一步研究了LiSrPO4：Eu2+,Nd3+、LiCaPO4：Eu2+,Nd3+、KCaPO4：Eu2+,Nd3+、NaCaPO4：Eu2+,Nd3+近红外发光材料,考察了不同Eu2+发射波长对Nd3+近红外发光的敏化效果；系统地研究了煅烧温度、煅烧时间、掺杂量等各因素对NaCaP04：Eu2+,Nd3+体系近红外发光材料的影响,分析探讨了ABP04体系中Eu2+-Nd3+之间的能量传递机理。
There is highly considerable attention on near-infrared(NIR) luminescence of Nd3+,due to its many advantages such as strong penetrability,narrow linewidth and free of background for biological analysis. However, the NIR luminescence intensity of Nd3+ doped in inorganic materials is still weak, which is difficiult for its application. It is an important way to enhance the luminescence intensity through the energy transfer between sensitizer and Nd3+. Eu2+ is an important sensitizer and activator with allowed 4f-5d electric dipole transition for luminescence, which is highly efficient absorb and emission and transfer the energy to other ionic. The passage contributes to prepare novel NIR luminescence materials doped Nd3+ and discusses the energy transfer mechanism between Eu2+ and Nd3+. The experiments as follows:
Near-infrared luminescence material Ca2BO3Cl:Eu2+,Nd3+ was synthesized by high temperature solid state method. All results show that near-infrared luminescence of Nd3+ could be greatly enhanced codope Eu2+. There is the greatest NIR luminescence when the concentration of Eu2+ and Nd3+ is 0.03、0.05, respectively. The nonradiation energy transfer from Eu2+to Nd3+ has been confirmed.
NIR luminescence phosphors Ca3SiO4Cl2:Eu2+,Nd3+、Ca8Mg(SiO4)4Cl2:Eu2+, Nd3+ were prepared by high temperature solid state method. It was found that Eu2+ has efficiently sensitized the NIR luminescence of Nd3+. The concentration of Eu2+ and Nd3+ effect on luminescence intensity was investigated and relationships between sintered temperature, sintered time and luminescence intensity were also studied. Such as Ca8Mg(SiO4)4Cl2:Eu2+,Nd3+, NIR luminescence intensity firstly increased with Eu2+ concentration, then reduced, the optimal concentration is 0.10. The phosphors sintered at 1100℃for 3 h give the strongest NIR luminescence intensity. The energy from Eu2+ efficiently excited transfer to the lever of Nd3+, the emission intensity of Nd3+ is greatly enhanced.
Phosphors Sr4Si3O8Cl4:0.08Eu2+,0.08Nd3+ were synthesized by high temperature solid state method. The NIR luminescence of Nd3+ could be efficiently sensitized by Eu2+, the emission intensity of Nd3+ enhanced 10 times, the energy transfer efficiency between Eu2+ and Nd3+ is 19.7%. Series phosphors codoped Ca2+ and Mg2+ in Sr4Si3O8Cl4:0.08Eu2+,0.08Nd3+ have been studied. NIR luminescence intensity increased with the Ca2+ concentration and reduced with the Mg2+ concentration.
Series efficient green or blue phosphors LiSrPO4:Eu2+、LiCaPO4:Eu2+、KCaPO4:Eu2+>、NaCaPO4:Eu2+ have been prepared by solid state method, the prepared conditions were optimization. Results show that there are two different emission centers in LiSrPO4:Eu2+ host with increased Eu2+ concentration. LiCaPO4:Eu2+ is a novel efficient blue-emitting phosphor. The emission intensity from KCaPO4:Eu2+ was enhanced by doping Y3+. Furthermore, NIR luminescence phosphors LiSrPO4:Eu2+,Nd3+、LiCaPO4:Eu2+,Nd3+、KCaPO4:Eu2+,Nd3+、NaCaPO4:Eu2+,Nd3+ have been studied. The effect of emission wavelength from Eu2+ on NIR luminescence of Nd3+ was investigated. The effects of sintered temperature, sintered time and concentration on NIR luminescence were also investigated. The energy transfer mechanism between Eu2+ and Nd3+ was discussed.
用高温固相法制备了Ca2BO3Cl：Eu2+,Nd3+近红外发光材料,结果表明,Eu2+的掺入可提高Nd3+的近红外发光强度,Eu2+,Nd3+的掺杂量分别为0.03、0.05时,近红外发光最强。证明了Eu2+通过无辐射能量传递方式向Nd3+有效地传递了能量,对Nd3+近红外有很好的敏化作用。
用高温固相法制备了Ca3SiO4Cl2：Eu2+,Nd3+、Ca8Mg(SiO4)4Cl2：Eu2+,Nd3+发光材料,发现其中Eu2+对Nd3+的近红外发光存在敏化作用。研究了Eu2+、Nd3+的掺杂浓度对近红外发光性能的影响及相对强度变化的规律。考察了煅烧温度、煅烧时间对近红外发光性能的影响。在Ca8Mg(SiO4)4Cl2:Eu2+,Nd3+体系中,样品的近红外发光强度随着Eu2+的掺杂浓度的增大先增强后减弱,Eu2+的掺杂量为0.08时,近红外发光最强；Nd3+的掺杂浓度为0.10时,近红外发光最强。样品在煅烧温度为1100℃下煅烧3h,近红外发光最强。分析了Eu2+与Nd3+之间能量传递的机理：Eu2+具有4f→5d跃迁轨道,可以有效地吸收能量,并将能量转移到的Nd3+的能级上,发生能量传递,增强Nd3+的近红外发光。
用高温固相法制备了Sr4Si3O8Cl4：0.08Eu2+,0.08Nd3+发光材料,发现了该体系中Eu2+对Nd3+的近红外发光存在敏化作用,近红外发光强度提高了10倍左右,Eu2+向Nd3+的能量传递效率为19.7%。研究了Ca,Mg掺杂的Sr4Si3O8Cl4：0.08Eu2+,0.08Nd3+系列发光材料,随着Ca含量的增加,样品的近红外发光呈现逐渐增强的趋势。样品的近红外发光强度随着Mg含量的增加呈现逐渐减弱的趋势。
用固相法制备了LiSrPO4：Eu2+、LiCaPO4：Eu2+、KCaPO4：Eu2+、NaCaPO4：Eu2+系列的高效蓝色、绿色荧光粉,优化了各荧光粉的制备条件。其中,研究表明LiSrPO4：Eu2+随着掺杂量的变化出现不同的发光中心；LiCaPO4：Eu2+是一种新型高效蓝色荧光粉；掺杂少量的Y3+可提高KCaPO4：Eu2+荧光粉的发光强度。进一步研究了LiSrPO4：Eu2+,Nd3+、LiCaPO4：Eu2+,Nd3+、KCaPO4：Eu2+,Nd3+、NaCaPO4：Eu2+,Nd3+近红外发光材料,考察了不同Eu2+发射波长对Nd3+近红外发光的敏化效果；系统地研究了煅烧温度、煅烧时间、掺杂量等各因素对NaCaP04：Eu2+,Nd3+体系近红外发光材料的影响,分析探讨了ABP04体系中Eu2+-Nd3+之间的能量传递机理。
There is highly considerable attention on near-infrared(NIR) luminescence of Nd3+,due to its many advantages such as strong penetrability,narrow linewidth and free of background for biological analysis. However, the NIR luminescence intensity of Nd3+ doped in inorganic materials is still weak, which is difficiult for its application. It is an important way to enhance the luminescence intensity through the energy transfer between sensitizer and Nd3+. Eu2+ is an important sensitizer and activator with allowed 4f-5d electric dipole transition for luminescence, which is highly efficient absorb and emission and transfer the energy to other ionic. The passage contributes to prepare novel NIR luminescence materials doped Nd3+ and discusses the energy transfer mechanism between Eu2+ and Nd3+. The experiments as follows:
Near-infrared luminescence material Ca2BO3Cl:Eu2+,Nd3+ was synthesized by high temperature solid state method. All results show that near-infrared luminescence of Nd3+ could be greatly enhanced codope Eu2+. There is the greatest NIR luminescence when the concentration of Eu2+ and Nd3+ is 0.03、0.05, respectively. The nonradiation energy transfer from Eu2+to Nd3+ has been confirmed.
NIR luminescence phosphors Ca3SiO4Cl2:Eu2+,Nd3+、Ca8Mg(SiO4)4Cl2:Eu2+, Nd3+ were prepared by high temperature solid state method. It was found that Eu2+ has efficiently sensitized the NIR luminescence of Nd3+. The concentration of Eu2+ and Nd3+ effect on luminescence intensity was investigated and relationships between sintered temperature, sintered time and luminescence intensity were also studied. Such as Ca8Mg(SiO4)4Cl2:Eu2+,Nd3+, NIR luminescence intensity firstly increased with Eu2+ concentration, then reduced, the optimal concentration is 0.10. The phosphors sintered at 1100℃for 3 h give the strongest NIR luminescence intensity. The energy from Eu2+ efficiently excited transfer to the lever of Nd3+, the emission intensity of Nd3+ is greatly enhanced.
Phosphors Sr4Si3O8Cl4:0.08Eu2+,0.08Nd3+ were synthesized by high temperature solid state method. The NIR luminescence of Nd3+ could be efficiently sensitized by Eu2+, the emission intensity of Nd3+ enhanced 10 times, the energy transfer efficiency between Eu2+ and Nd3+ is 19.7%. Series phosphors codoped Ca2+ and Mg2+ in Sr4Si3O8Cl4:0.08Eu2+,0.08Nd3+ have been studied. NIR luminescence intensity increased with the Ca2+ concentration and reduced with the Mg2+ concentration.
Series efficient green or blue phosphors LiSrPO4:Eu2+、LiCaPO4:Eu2+、KCaPO4:Eu2+>、NaCaPO4:Eu2+ have been prepared by solid state method, the prepared conditions were optimization. Results show that there are two different emission centers in LiSrPO4:Eu2+ host with increased Eu2+ concentration. LiCaPO4:Eu2+ is a novel efficient blue-emitting phosphor. The emission intensity from KCaPO4:Eu2+ was enhanced by doping Y3+. Furthermore, NIR luminescence phosphors LiSrPO4:Eu2+,Nd3+、LiCaPO4:Eu2+,Nd3+、KCaPO4:Eu2+,Nd3+、NaCaPO4:Eu2+,Nd3+ have been studied. The effect of emission wavelength from Eu2+ on NIR luminescence of Nd3+ was investigated. The effects of sintered temperature, sintered time and concentration on NIR luminescence were also investigated. The energy transfer mechanism between Eu2+ and Nd3+ was discussed.
引文
[1]李建宇.稀土发光材料及其应用[M].化学工业出版社,2003：6.
[2]孙家跃,杜海燕,胡文祥.固体发光材料[M].化学工业出版社,2005：25.
[3]肖志国.半导体照明发光材料及应用[M].化学工业出版社,2008：1.
[4]Su Fuhai, Ma Baoshan, Ding Kun, Li Guohua, Wang Shaopeng, Chen Wei, Alan G. Joly, David E. McCready. Luminescence temperature and pressure studies of Zn2SiO4 phosphors doped with Mn2+ and Eu3+ ions [J]. Journal of Luminescence,2006,116:117-126.
[5]Kirikova N.Yu., Kirm M., Krupa J.C.,Makhov V.N.,Negodin E.,Gesland J.Y.. Low-temperature high-resolution VUV spectroscopy of Ce3+ doped LiYF4, LiLuF4 and LuF3 crystals [J]. Journal of Luminescence,2004,110:135-145.
[6]吴雪艳,尤洪鹏,曾小青,洪广言,金昌弘,卞锺洪,庾炳容,朴哲熙.共沉淀法合成稀土正磷酸盐(La,Gd)PO4：RE3+(RE=Eu,Tb)及其真空紫外光谱特性[J].高等学校化学学报,2003,24：1-4.
[7]Nazarov M.V., Jeon D.Y., Kang J.H., Popovici E.J., Muresan L.E., Zamoryanskaya M.V. Tsukerblat B.S.. Luminescence properties of europium-terbium double activated calcium tungstate phosphor [J]. Solid State Communications,2004,131:307-311.
[8]Yang Hongmei, Shi Jianxin, Gong Menglian, K.W. Cheah. Synthesis and photoluminescence of Eu3+ or Tb3+ doped Mg2SiO4 nanoparticles prepared by a combined novel approach [J]. Journal of Luminescence,2006,118:257-264.
[9]Neeraj S.,Kijima N.,Cheetham A.K. Novel red phosphors for solid-state lighting:the system NaM (WO4)2-x(MoO4)2x:Eu3+(M= Gd, Y, Bi) [J]. Chemical Physics Letters,2004,387:2-6.
[10]Wu Jianping, David Newman, Ian V.F. Viney. Study on relationship of luminescence in CaS:Eu, Sm and dopants concentration [J].Journal of Luminescence,2002,99:237-245.
[11]Sun Xiaolin, Hong Guangyan, Zhang Guilan, Tang Guoqing, Chen Wenju. The luminescence properties of CaS:Eu2+ excited by pico-second laser pulse [J]. Journal of Luminescence,2001,92:307-310.
[12]Jong Su Kim, Yun Hyung Park, Sun Myung Kim, Jin Chul Choi, Hong Lee Park.Temperature-dependent emission spectra of M2SiO4:Eu2+(M=Ca, Sr, Ba) phosphors for green and greenish white LEDs [J].Solid State Communications,2005,133:445-448.
[13]Haranath D, Harish Chander, Pooja Sharma, Sukhvir Singh. Enhanced luminescence of Y3Al5O12:Ce3+ nanophosphor for white light emitting Diodes [J]. Applied physics letters, 2006,89:173118.
[14]肖志国.半导体照明发光材料及应用[M].化学工业出版社,2008：1
[15]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：186.
[16]Wei-Hsiang Hsu, Meng-Huei Sheng, Ming-Shyong Tsai. Preparation of Eu-activated strontium orthosilicate (Sr1.95SiO4:Eu0.05) phosphor by a sol-gel method and its luminescent properties [J].J. Alloys and Compounds,2009,467:491-495.
[17]杨志平,王少丽,杨广伟,等.绿色荧光粉NaCaPO4：Tb3+的制备与发光特性[J].发光学报,2008,29(1)：81-84.
[18]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：188.
[19]Yizhu Lei, Qi Zou, Dehai Du. Energy transfer between Ce3+ and Eu2+ in doped KSrPO4 [J]. Applied Physics A,2009,97:635-639.
[20]毛智勇,王达建,马亮,陆启飞,刘凌云,李雪征,刘艳花.近紫外光激发的Ba3MgSi2O8：Eu2+,Mn2+全色荧光材料的发光性质的研究[J].天津理工大学学报,2008,24(6)：9-12.
[21]钟丹,胡小野,李振华,李永秀.镨和镱掺杂Ba2SiO4：Eu2+荧光材料的合成与发光性能[J].中国稀土学报,2009,27(1)：36-39.
[22]Z.C.Wu, J.X.Shi, J Wang, M.L.Gong, Q Su. A novel Blue-emitting phosphor LiSrPO4:Eu2+ for White LEDs [J]. Journal of Solid State Chemistry,2006,179:2356-2360.
[23]J.Liu, Z.C.Wu, M.L.Gong. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes [J]. Applied Physics B,2008,93:583-587.
[24]Yu-Sheng Tang, Shu-Fen Hu. Thermally stable luminescence of blue KSrPO4:Eu2+ phosphor for White light UV light-emitting diodes [J].Applied Physics Letters,2007,90: 151108.
[25]Ting-Shi Chan, Yao-Min Liu, Ru-Shi Liu. Combinatiorial Search for Green and Blue Phosphors of High Thermal Stabilities under UV Excitation based on the KSr1-x-yPO_4:Tbx3+, Euy2+ system [J]. Journal of Combinatorial Chemistry,2008,10: 847-850.
[26]Q. ZHANG, J. WANG, M. ZHANG, Q, Su. Tunable bluish green to yellowish green Ca2 (1-x)Sr2xAl2SiO7:Eu2+ Phosphors for Potential LED Application [J]. Applied Physics B 2008, 92:195-198.
[27]Wen Pan, Guiling Ning. Synthesis and luminescence properties of Sr3MgSi2O8:Eu2+, Dy3+ by a novel silica-nanocoating method [J].Sensors and Actuator A,2007,139:318-322.
[28]W.J.Park, M.K. Jung, S.M. Kang, T. Masaki, D.H. Yoon. Synthesis and photoluminescence characterization of Ca3Si2O7:Eu2+ as a potential green-emitting white LED phosphor [J]. Journal of Physics and Chemistry of Solids,2008,69:1505-1508.
[29]Xinmin Zhang, Boowon Park, Namisk Choi, Jongsu Kim, GC.Kim, J.H.Yoo.A novel blue-emitting Sr3Al2O5Cl2:Ce3+, Li+ phosphor for near UV-excited white-light-emitting diodes [J].Materials Letters,2009,63:700-702.
[30]Xu Jun, Su Liangbi, Li Hongjun. High quantum fluorescence yield of Er3+ at 1.5 μm in an Yb3+, Ce3+ -codoped CaF2crystal [J].Optical Materials,2007,29:932-935.
[31]Kawamaura Y., Wada Y., Iwamuro M., Kitamura T.. Near-infrared electroluminescence from ytterbium (Ⅲ) complex, Chem. Lett,2000:280-281
[32]Meng J.X., Li K.F.,Yuan J.Near-IR luminescence and photophysics of Yb-Porphyrinate complexes [J].Chem. Phys.Lett.,2000,332:313-318.
[33]Sharma Y.K.,Surana S.S.L.,Singh R.K. Spectral studies of erbium doped soda lime silicate glasses in visible and near infrared regions [J].Optical Materials,2007,29:598-604.
[34]Christof Strohhofer, Albert Polman. Enhancement of Er3+-I13/2 population in Y2O3 by energy transfer to Ce3+[J]. Optical Materials,2001,17:445-451.
[35]Masayuki Nishi, Setsuhisa Tanabe, Masashi Inoue. Optical-telecommunication-band fluorescence properties of Er3+-doped YAG nanocrystals synthesized by glycothermal method [J].Optical Materials,2005,27:655-662.
[36]Veasey D.L.,Funk D.S.,Sanford N.A.,Hayden J.S.Arrays of distributed-Bragg-reflector waveguide lasers at 1536nm Yb/Er codoped phosphate glass [J].Appl.Phys. Lett.,1999,74: 789-791.
[37]Nagamatsu K.,Nagaoka S.,Higashihata M. Influence of Yb3+ and Ce3+ codoping on fluorescence characteristics of Er3+-doped fluoride glass under 980 nm excitation[J]. Optical Materials,2004,27:337-342.
[38]Simondi-Teisseire B., Viana B., Vivien D.,Lejus A.M. Yb3+ to Er3+ energy transfer and rate-equations formalism in the eye safe laser material Yb:Er:Ca2Al2SiO7 [J]. Opt. Mater., 1996,6:267-274.
[39]Meng J X.,Li K F, Yuan J, et al. Chem. Phys.Lett.,2000,332:313.
[40]Bok Yeop Ahn, Sang IL Seok, Suk-In Hong, Jae-Seok Oh, Ha-Kyun Jung, Woon Jin Chung. Optical properties of organic/inorganic nanocomposite sol-gel films containing LaPO4:Er, Yb nanocrystals [J].Optical Materials,2006,28:374-379.
41] MENG Jian-xin, CHEN Da-zhi, QI Jian-ying, et al.Chinese Journal of Luminescence,2002, 23(1):49-51.
[42]Van Der Tol, Eric B, Van Ramesdonk et al. Chem. Eru. J.,1998,4(11):2315.
[43]Martinus W, Hofstraat H V et al.Chem. Phys. Lett.,1997,276(3,4):196.
[44]孟建新,邓朝霞,陈大志,冯德雄.稀土-铬蓝黑R配合物体系的近红外发光研究[J].光谱学与光谱分析,2004,24(5)：582-584.
[45]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：125-128.
[46]徐叙瑢,苏勉曾.发光学与发光材料[M].化学工业出版社,2004：597-601.
[47]Vaqueiro P, Lopequea M A. Influence of Complexing Agents and pH on Yttrium-Iron Garnet Synthesized by the Sol-Gel Method [J].Chem. Mater.,1997,9:2836-2841.
[48]C.J. Kim, M.S.Kwon. Effects of precursors in ethanol-based sol-gel synthesis of Zn2SiO4:Mn2+phosphor [J]. J. Mater. Sci.,2006,41:6138-3141.
[49]张中太.张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：133.
[50]肖志国.半导体照明发光材料及应用[M].化学工业出版社.2008：77-78.
[51]Li Jiguang, Ikegami T, Lee Jongheun. Co-precipitation synthesis and sintering of yttrium aluminum garnet (YAG) powders:the effect of precipitant [J]. J. Eur. Ceram. Soc,2000,20: 2395-2405.
[52]郭旺,卢铁城,仝世红,张颖.共沉淀法制备纯相钇铝石榴石(YAG)纳米粉体中的若干影响因素[J].功能材料,2006,37：66-69.
[53]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：136.
[54]蔡子龙,孟建新,刘敏,时朝璞,刘应亮.共沉淀法制备长余辉发光材料CaWO4：Eu3+的研究[J].稀土,2008,29(3)：10-13.
[55]张茂峰,孟建新,刘应亮,满石清.LaF3：Eu3+纳米粒子的水热法制备及发光性质研究[J].中国稀土学报,2005,23(5)：564-567.
[56]张茂峰,孟建新,时朝璞,刘应亮,满石清.LaF3纳米线的低温溶剂热法制备及形成机理[J].无机化学学报,2006,(10)：1883-1886.
[57]Meng J X, Zhang M F, Liu Y L, Man S Q. Hydrothermal preparation and luminescence of LaF3:Eu3+ nanoparticles [J].Spectrochimic Acta A,2007,66(1):81-85
[58]张茂峰,孟建新,刘应亮,满石清.水热法制备LaF3：Ce,Tb纳米荧光粉及发光性质研究[J].光谱学与光谱分析,2007,(2)：232-235.
[59]Ning Xue, Xiaoping Fan, Zhiyu Wang, Minquan Wang. Synthesis process and the luminescence properties of rare earth doped NaLa (WO4)2 nanoparticles [J].Journal of Physics and Chemistry of Solids,2008,69:1891-1896.
[60]Feng Wang, Xiaoping Fan, Daibo Pi, Zhiyu Wang, Minquan Wang. Hydrothermal synthesis and luminescence behavior of rare-earth-doped NaLa(WO4)2 powders [J]. Journal of Solid State of chemistry,2005,178:825-830.
[61]綦艳,孟建新.纳米LaP04：Eu的凝胶网格法制备及发光特性[J].发光学报,2006,(3)：397-400.
[62]綦艳,孟建新,刘敏.纳米LaP04：Ce,Tb的明胶网格沉淀法制备及发光研究[J].稀土,2006,(1)：15-18.
[63]Yuexiao Pan, Mingmei Wu, Qiang Su. Comparative investigation on synthesis and photoluminescence of YAG:Ce phosphor [J].Materials science and engineering B,2004, 106:251-256.
[64]程永亮,宋武林,谢长生.燃烧法制备氧化物纳米材料的研究进展[J].材料导报,2007,17(7)：70-72.
[65]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：138-144.
[66]J.X Meng, K.W.Chean, Z.P SHI et al. Intense 1540 nm emission from Er doped Ce:YAG phosphor [J]. Appl. Phys. Lett.,2007,91:151107.
[67]J.X Meng, J.Q.LI, Z.P SHI, et al. Efficient energy transfer for Ce to Nd in Nd/ Ce codoped yttrium aluminum garnet [J].Appl. Phys. Lett.,2008,93:221908.
[68]杨建龙,李友芬,吴纪颖.Eu2+,Tb3+共掺3／2-莫来石发光特性及Eu2+→Tb3+的能量传递[J].科学通报,2009,54(5)：569-573.
[69]杨志平,杨广伟,王少丽,等.Eu2+,Mn2+在BaZnP2O7中的发光及Eu2+→Mn2+能量传递[J].物理学报,57(1)：581-585.
[70]赵秋香,陈大志,孟建新.Yb-邻菲啰啉-曙红三元配合物近红外发光测定Yb3+[J].分析实验室,2004,23(3)：46-49.
[71]W.J.Yang, T.M.Chen, White-light generation and energy transfer in SrZn2(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2006,88: 101903.
[72]J. Liu, Z.Wu, M.Gong. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes [J]. Applied Physics B,2008,93:583-587.
[73]Z.C. Wu, JXShi, J.Wang, M.L.Gong, Q.Su. A novel of blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs [J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[74]Yu-Sheng Tang, Shu-Fen Hu. Thermally stable luminescence of blue KSrPO4:Eu2+ phosphor for White light UV light-emitting diodes [J]. Applied Physics Letters,2007,90: 151108.
[75]孙家跃,杜海燕,胡文祥,等.固体发光材料[M].北京：化学工业出版社,2003：156.
[1]Kosketalo T, Leskela M. Niinsto L [J].Mat. Res. Bull,1985,20:265.
[2]常树岚,郭风瑜,孙寅官.Ca2B2O5中Ce3+、Mn2+的发光与能量传递[J].高等学校化学学报,1992,13(9)：1257-1259.
[3]郭风瑜,常树岚.Ca3La3(BO3)5中Ce3+、pb2+、Mn2+的光致发光和能量传递[J].中国稀土学报,1990,18(3)：229-232.
[4]常树岚,吴基石,盖同祥.以M3La3(BO3)5为基质的光致发光材料的合成[J].延边大学学报(自然科学版),1993,19(4)：42-44.
[5]常树岚.四硼酸镁光致发光材料的性能研究[J].延边大学学报(自然科学版),1994,20(3)：43-46.
[6]常树岚,郭明申,韩长友,孙尚梅.掺杂pb2+、Mn2+的SrB6O10发光材料的探讨[J].延边大学学报(自然科学版),1996,22(1)：16-19.
[7]曾庆华,裴治武,王树彬,等.SrB6010：Sm2+的高分辨光谱研究[J].中国稀土学报,1998,第八届全国发光学术会议稀土离子发光专辑：1021-1023.
[8]高勇,石春山,李德成.在SrB6O10中Tb和Eu的发光[J].科学通报,1996,41(17)：1575.
[9]Woo-Seuk Song, Yong-Seog Kim, and Heesun Yang. Yellow-emitting phosphor of Sr3B2O6:Eu2+ for application to white light-emitting diodes [J]. Materials Chemistry and Physics,2009,117:500-503.
[10]Chun-Kuei Chang and Teng-Ming Chen. Sr3B2O6:Ce3+, Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2007,91:081902.
[11]Zhiguo Xia, Haiyan Dub, Jiayue Sunb, Daimei Chen, Xuefeng Wang. A novel blue-emitting Ca2B5O9Br:Eu2+phosphor prepared by a microwave calcination route [J]. Materials Chemistry and Physics,2010,119:7-10.
[12]YANG Zhi-ping, WANG Shao-li, YANG Guang-wei, et al. Luminescent properties of Ca2BO3Cl:Eu2+yellow-emitting phosphor for white-emitting diodes [J].Materials Letters, 2007,61:5258-5260.
[13]F.Xiao, Y.N.Xue, Q.Y.Zhang. Ca2BO3Cl:Ce3+, Eu2+:A potential tunable yellow-white-blue-emitting phosphors for white light-emitting diodes [J]. Physica B, 2009,404:3743-3747.
[14]Qiuhong Zhang, Jing Wang, Gongguo Zhang, Qiang Su. UV photo harvesting and enhanced near-infrared emission in novel quantum cutting Ca2BO3Cl:Ce3+, Tb3+, Yb3+[J]. Journal of Materials Chemistry,2009,19:7088-7092.
[15]CHEUNG H C.in Topics in Fluorescence Spectroscopy [M].New York:Kluwer 2002,2: 130.
[1]赵惠玲,刘世香,王明文,李文军.Sr8Si4O12Cl8：Eu3+,M3+(M3+=Bi3+,Gd3+)中的敏化发光[J].2007,35(5)：611-615.
[2]Jie Liu, Hongzhou Lian, Jiayue Sun, Chunshan Shi.Characterization and Properties of Green Emitting Ca3SiO4Cl:Eu2+ Powder Phosphor for White Light-emitting Diodes [J]. 2005,34(10):1340-1341.
[3]张明荣,刘波,朱正和.Eu2+在新型基质Ca8Mg(SiO4)4Cl2的光致发光[J].1993,14(13)：265-269.
[4]Jing Wang, Zongmiao Liu, Weijia Ding, Qiang Su. Luminescent Properties of (Ca1-xSrx)3SiO4(Cl1-yFy)2:Eu2+ Phosphors and Their Application for White LED[J].Int. J. Appl. Ceram. Technol,2009,6 (4):447-452.
[5]Fang Ying, Zhang Weidong, Cui Xiangzhong, Hu Yunsheng, Huang Xiaowei.Study on Ca8Mg(SiO4)4Cl2:Eu2+ Doped with Sr2+[J]. Journal of Rare Earths,2006,24(12):145-148.
[6]方英,叶信宇.Ca8Mg(SiO4)4Cl2：Eu2+,Mn2+绿色荧光粉的光谱性质[J].江西师范大学学报(自然科学版),2008,32(3)：273-276.
[7]Fang Ying, Zhang Weidong, Hu Yunsheng, Ye Xinyu, Huang Xiaowei. Luminescent Properties of Green Phosphors Ca8Mg(SiO4)4Cl2:Eu2+,Dy3+ for LED Application [J].2007, 25(5):574-576.
[8]CHEUNG H C. in Topics in Fluorescence Spectroscopy [M].New York:Kluwer 2002,2: 130.
[1]赵惠玲,刘世香,王明文,李文军.Sr8Si4O12Cl8：Eu3+,M3+(M3+=Bi3+,Gd3+)中的敏化发光[J],2007,35(5)：611-615.
[2]孙家跃,夏志国,杜海燕.(Sr,Ca)4Si3O8Cl4基质中Eu2+的发光特性研究[J].光谱学与光谱分析,2005,25(11)：1760-1763.
[3]Xia Zhiguo, Sun Jiayue, Du Haiyan. Study on Luminescence Properties and Crystal-Lattice Environment of Eu2+ in Sr4-xMgxSi3O8Cl4:Eu2+ Phosphor [J]. Journal of Rare earths,2004, 22(3):370-374.
[4]常树岚,路趁霄.CBC：Ce／Tb的光谱特性及CBC、Ce、Tb间的能量传递[J].稀有金属材料与工程,2008,37(9)：1592-1596.
[1]Wei-Hsiang Hsu, Meng-Huei Sheng, Ming-Shyong Tsai.Preparation of Eu-activated strontium orthosilicate (Sr1.95SiO4:Eu0.05) phosphor by a sol-gel method and its luminescent properties [J]. J. Alloys and Compounds.2009,467:491-495.
[2]杨志平,王少丽,杨广伟,等.绿色荧光粉NaCaP04：Tb3+的制备与发光特性[J].发光学报,2008,29(1)：81-84.
[3]Xinguo Zhang, Fangxiang Zhou, Jianxin Shi, et al. Sr3.5Mg0.5Si3O8Cl4:Eu2+ bluish-green emitting phosphor for NUV-based LED [J].Materials Letters,2009,63:852-854.
[4]Yang Zhi-Ping, Liu Yu-Feng. Preparation and luminescence characteristics of Eu2+ activated Ca3SiO5 green-emitting phosphor [J].ACTA PHYSIC A SINICA,2006,55(9): 4946-4950.
[5]Weijia Ding, Jing Wang, Mei Zhang, Qiu hong Zhang, Qiang Su. Luminescence Properties of new Ca10(Si2O7)3Cl2:Eu2+ Phosphor [J]. Chemical Physics Letters,2007,435:301-305.
[6]Zhanchao Wu, Menglian Gong, Jianxin Shi, Gang Wang, and Qiang Su.Dibarium Magnesium Diphosphate Yellow Phosphor Applied in InGaN-based LEDs [J].Chemistry Letters,2007,36(3):410-411.
[7]黄世华,楼立人.严懋勋教授和能量传递研究,发光学报[J].2008,29(4)：646-650.
[8]傅丹,郭培民,王稼国,陈德来,刑西平.蓝粉光谱特征对三基色荧光灯光色影响的色度学模拟计算[J].中国照明电器,2002,7：5-9.
[2]孙家跃,杜海燕,胡文祥.固体发光材料[M].化学工业出版社,2005：25.
[3]肖志国.半导体照明发光材料及应用[M].化学工业出版社,2008：1.
[4]Su Fuhai, Ma Baoshan, Ding Kun, Li Guohua, Wang Shaopeng, Chen Wei, Alan G. Joly, David E. McCready. Luminescence temperature and pressure studies of Zn2SiO4 phosphors doped with Mn2+ and Eu3+ ions [J]. Journal of Luminescence,2006,116:117-126.
[5]Kirikova N.Yu., Kirm M., Krupa J.C.,Makhov V.N.,Negodin E.,Gesland J.Y.. Low-temperature high-resolution VUV spectroscopy of Ce3+ doped LiYF4, LiLuF4 and LuF3 crystals [J]. Journal of Luminescence,2004,110:135-145.
[6]吴雪艳,尤洪鹏,曾小青,洪广言,金昌弘,卞锺洪,庾炳容,朴哲熙.共沉淀法合成稀土正磷酸盐(La,Gd)PO4：RE3+(RE=Eu,Tb)及其真空紫外光谱特性[J].高等学校化学学报,2003,24：1-4.
[7]Nazarov M.V., Jeon D.Y., Kang J.H., Popovici E.J., Muresan L.E., Zamoryanskaya M.V. Tsukerblat B.S.. Luminescence properties of europium-terbium double activated calcium tungstate phosphor [J]. Solid State Communications,2004,131:307-311.
[8]Yang Hongmei, Shi Jianxin, Gong Menglian, K.W. Cheah. Synthesis and photoluminescence of Eu3+ or Tb3+ doped Mg2SiO4 nanoparticles prepared by a combined novel approach [J]. Journal of Luminescence,2006,118:257-264.
[9]Neeraj S.,Kijima N.,Cheetham A.K. Novel red phosphors for solid-state lighting:the system NaM (WO4)2-x(MoO4)2x:Eu3+(M= Gd, Y, Bi) [J]. Chemical Physics Letters,2004,387:2-6.
[10]Wu Jianping, David Newman, Ian V.F. Viney. Study on relationship of luminescence in CaS:Eu, Sm and dopants concentration [J].Journal of Luminescence,2002,99:237-245.
[11]Sun Xiaolin, Hong Guangyan, Zhang Guilan, Tang Guoqing, Chen Wenju. The luminescence properties of CaS:Eu2+ excited by pico-second laser pulse [J]. Journal of Luminescence,2001,92:307-310.
[12]Jong Su Kim, Yun Hyung Park, Sun Myung Kim, Jin Chul Choi, Hong Lee Park.Temperature-dependent emission spectra of M2SiO4:Eu2+(M=Ca, Sr, Ba) phosphors for green and greenish white LEDs [J].Solid State Communications,2005,133:445-448.
[13]Haranath D, Harish Chander, Pooja Sharma, Sukhvir Singh. Enhanced luminescence of Y3Al5O12:Ce3+ nanophosphor for white light emitting Diodes [J]. Applied physics letters, 2006,89:173118.
[14]肖志国.半导体照明发光材料及应用[M].化学工业出版社,2008：1
[15]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：186.
[16]Wei-Hsiang Hsu, Meng-Huei Sheng, Ming-Shyong Tsai. Preparation of Eu-activated strontium orthosilicate (Sr1.95SiO4:Eu0.05) phosphor by a sol-gel method and its luminescent properties [J].J. Alloys and Compounds,2009,467:491-495.
[17]杨志平,王少丽,杨广伟,等.绿色荧光粉NaCaPO4：Tb3+的制备与发光特性[J].发光学报,2008,29(1)：81-84.
[18]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：188.
[19]Yizhu Lei, Qi Zou, Dehai Du. Energy transfer between Ce3+ and Eu2+ in doped KSrPO4 [J]. Applied Physics A,2009,97:635-639.
[20]毛智勇,王达建,马亮,陆启飞,刘凌云,李雪征,刘艳花.近紫外光激发的Ba3MgSi2O8：Eu2+,Mn2+全色荧光材料的发光性质的研究[J].天津理工大学学报,2008,24(6)：9-12.
[21]钟丹,胡小野,李振华,李永秀.镨和镱掺杂Ba2SiO4：Eu2+荧光材料的合成与发光性能[J].中国稀土学报,2009,27(1)：36-39.
[22]Z.C.Wu, J.X.Shi, J Wang, M.L.Gong, Q Su. A novel Blue-emitting phosphor LiSrPO4:Eu2+ for White LEDs [J]. Journal of Solid State Chemistry,2006,179:2356-2360.
[23]J.Liu, Z.C.Wu, M.L.Gong. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes [J]. Applied Physics B,2008,93:583-587.
[24]Yu-Sheng Tang, Shu-Fen Hu. Thermally stable luminescence of blue KSrPO4:Eu2+ phosphor for White light UV light-emitting diodes [J].Applied Physics Letters,2007,90: 151108.
[25]Ting-Shi Chan, Yao-Min Liu, Ru-Shi Liu. Combinatiorial Search for Green and Blue Phosphors of High Thermal Stabilities under UV Excitation based on the KSr1-x-yPO_4:Tbx3+, Euy2+ system [J]. Journal of Combinatorial Chemistry,2008,10: 847-850.
[26]Q. ZHANG, J. WANG, M. ZHANG, Q, Su. Tunable bluish green to yellowish green Ca2 (1-x)Sr2xAl2SiO7:Eu2+ Phosphors for Potential LED Application [J]. Applied Physics B 2008, 92:195-198.
[27]Wen Pan, Guiling Ning. Synthesis and luminescence properties of Sr3MgSi2O8:Eu2+, Dy3+ by a novel silica-nanocoating method [J].Sensors and Actuator A,2007,139:318-322.
[28]W.J.Park, M.K. Jung, S.M. Kang, T. Masaki, D.H. Yoon. Synthesis and photoluminescence characterization of Ca3Si2O7:Eu2+ as a potential green-emitting white LED phosphor [J]. Journal of Physics and Chemistry of Solids,2008,69:1505-1508.
[29]Xinmin Zhang, Boowon Park, Namisk Choi, Jongsu Kim, GC.Kim, J.H.Yoo.A novel blue-emitting Sr3Al2O5Cl2:Ce3+, Li+ phosphor for near UV-excited white-light-emitting diodes [J].Materials Letters,2009,63:700-702.
[30]Xu Jun, Su Liangbi, Li Hongjun. High quantum fluorescence yield of Er3+ at 1.5 μm in an Yb3+, Ce3+ -codoped CaF2crystal [J].Optical Materials,2007,29:932-935.
[31]Kawamaura Y., Wada Y., Iwamuro M., Kitamura T.. Near-infrared electroluminescence from ytterbium (Ⅲ) complex, Chem. Lett,2000:280-281
[32]Meng J.X., Li K.F.,Yuan J.Near-IR luminescence and photophysics of Yb-Porphyrinate complexes [J].Chem. Phys.Lett.,2000,332:313-318.
[33]Sharma Y.K.,Surana S.S.L.,Singh R.K. Spectral studies of erbium doped soda lime silicate glasses in visible and near infrared regions [J].Optical Materials,2007,29:598-604.
[34]Christof Strohhofer, Albert Polman. Enhancement of Er3+-I13/2 population in Y2O3 by energy transfer to Ce3+[J]. Optical Materials,2001,17:445-451.
[35]Masayuki Nishi, Setsuhisa Tanabe, Masashi Inoue. Optical-telecommunication-band fluorescence properties of Er3+-doped YAG nanocrystals synthesized by glycothermal method [J].Optical Materials,2005,27:655-662.
[36]Veasey D.L.,Funk D.S.,Sanford N.A.,Hayden J.S.Arrays of distributed-Bragg-reflector waveguide lasers at 1536nm Yb/Er codoped phosphate glass [J].Appl.Phys. Lett.,1999,74: 789-791.
[37]Nagamatsu K.,Nagaoka S.,Higashihata M. Influence of Yb3+ and Ce3+ codoping on fluorescence characteristics of Er3+-doped fluoride glass under 980 nm excitation[J]. Optical Materials,2004,27:337-342.
[38]Simondi-Teisseire B., Viana B., Vivien D.,Lejus A.M. Yb3+ to Er3+ energy transfer and rate-equations formalism in the eye safe laser material Yb:Er:Ca2Al2SiO7 [J]. Opt. Mater., 1996,6:267-274.
[39]Meng J X.,Li K F, Yuan J, et al. Chem. Phys.Lett.,2000,332:313.
[40]Bok Yeop Ahn, Sang IL Seok, Suk-In Hong, Jae-Seok Oh, Ha-Kyun Jung, Woon Jin Chung. Optical properties of organic/inorganic nanocomposite sol-gel films containing LaPO4:Er, Yb nanocrystals [J].Optical Materials,2006,28:374-379.
41] MENG Jian-xin, CHEN Da-zhi, QI Jian-ying, et al.Chinese Journal of Luminescence,2002, 23(1):49-51.
[42]Van Der Tol, Eric B, Van Ramesdonk et al. Chem. Eru. J.,1998,4(11):2315.
[43]Martinus W, Hofstraat H V et al.Chem. Phys. Lett.,1997,276(3,4):196.
[44]孟建新,邓朝霞,陈大志,冯德雄.稀土-铬蓝黑R配合物体系的近红外发光研究[J].光谱学与光谱分析,2004,24(5)：582-584.
[45]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：125-128.
[46]徐叙瑢,苏勉曾.发光学与发光材料[M].化学工业出版社,2004：597-601.
[47]Vaqueiro P, Lopequea M A. Influence of Complexing Agents and pH on Yttrium-Iron Garnet Synthesized by the Sol-Gel Method [J].Chem. Mater.,1997,9:2836-2841.
[48]C.J. Kim, M.S.Kwon. Effects of precursors in ethanol-based sol-gel synthesis of Zn2SiO4:Mn2+phosphor [J]. J. Mater. Sci.,2006,41:6138-3141.
[49]张中太.张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：133.
[50]肖志国.半导体照明发光材料及应用[M].化学工业出版社.2008：77-78.
[51]Li Jiguang, Ikegami T, Lee Jongheun. Co-precipitation synthesis and sintering of yttrium aluminum garnet (YAG) powders:the effect of precipitant [J]. J. Eur. Ceram. Soc,2000,20: 2395-2405.
[52]郭旺,卢铁城,仝世红,张颖.共沉淀法制备纯相钇铝石榴石(YAG)纳米粉体中的若干影响因素[J].功能材料,2006,37：66-69.
[53]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：136.
[54]蔡子龙,孟建新,刘敏,时朝璞,刘应亮.共沉淀法制备长余辉发光材料CaWO4：Eu3+的研究[J].稀土,2008,29(3)：10-13.
[55]张茂峰,孟建新,刘应亮,满石清.LaF3：Eu3+纳米粒子的水热法制备及发光性质研究[J].中国稀土学报,2005,23(5)：564-567.
[56]张茂峰,孟建新,时朝璞,刘应亮,满石清.LaF3纳米线的低温溶剂热法制备及形成机理[J].无机化学学报,2006,(10)：1883-1886.
[57]Meng J X, Zhang M F, Liu Y L, Man S Q. Hydrothermal preparation and luminescence of LaF3:Eu3+ nanoparticles [J].Spectrochimic Acta A,2007,66(1):81-85
[58]张茂峰,孟建新,刘应亮,满石清.水热法制备LaF3：Ce,Tb纳米荧光粉及发光性质研究[J].光谱学与光谱分析,2007,(2)：232-235.
[59]Ning Xue, Xiaoping Fan, Zhiyu Wang, Minquan Wang. Synthesis process and the luminescence properties of rare earth doped NaLa (WO4)2 nanoparticles [J].Journal of Physics and Chemistry of Solids,2008,69:1891-1896.
[60]Feng Wang, Xiaoping Fan, Daibo Pi, Zhiyu Wang, Minquan Wang. Hydrothermal synthesis and luminescence behavior of rare-earth-doped NaLa(WO4)2 powders [J]. Journal of Solid State of chemistry,2005,178:825-830.
[61]綦艳,孟建新.纳米LaP04：Eu的凝胶网格法制备及发光特性[J].发光学报,2006,(3)：397-400.
[62]綦艳,孟建新,刘敏.纳米LaP04：Ce,Tb的明胶网格沉淀法制备及发光研究[J].稀土,2006,(1)：15-18.
[63]Yuexiao Pan, Mingmei Wu, Qiang Su. Comparative investigation on synthesis and photoluminescence of YAG:Ce phosphor [J].Materials science and engineering B,2004, 106:251-256.
[64]程永亮,宋武林,谢长生.燃烧法制备氧化物纳米材料的研究进展[J].材料导报,2007,17(7)：70-72.
[65]张中太,张俊英.无机光致发光材料及应用[M].化学工业出版社,2005：138-144.
[66]J.X Meng, K.W.Chean, Z.P SHI et al. Intense 1540 nm emission from Er doped Ce:YAG phosphor [J]. Appl. Phys. Lett.,2007,91:151107.
[67]J.X Meng, J.Q.LI, Z.P SHI, et al. Efficient energy transfer for Ce to Nd in Nd/ Ce codoped yttrium aluminum garnet [J].Appl. Phys. Lett.,2008,93:221908.
[68]杨建龙,李友芬,吴纪颖.Eu2+,Tb3+共掺3／2-莫来石发光特性及Eu2+→Tb3+的能量传递[J].科学通报,2009,54(5)：569-573.
[69]杨志平,杨广伟,王少丽,等.Eu2+,Mn2+在BaZnP2O7中的发光及Eu2+→Mn2+能量传递[J].物理学报,57(1)：581-585.
[70]赵秋香,陈大志,孟建新.Yb-邻菲啰啉-曙红三元配合物近红外发光测定Yb3+[J].分析实验室,2004,23(3)：46-49.
[71]W.J.Yang, T.M.Chen, White-light generation and energy transfer in SrZn2(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2006,88: 101903.
[72]J. Liu, Z.Wu, M.Gong. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes [J]. Applied Physics B,2008,93:583-587.
[73]Z.C. Wu, JXShi, J.Wang, M.L.Gong, Q.Su. A novel of blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs [J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[74]Yu-Sheng Tang, Shu-Fen Hu. Thermally stable luminescence of blue KSrPO4:Eu2+ phosphor for White light UV light-emitting diodes [J]. Applied Physics Letters,2007,90: 151108.
[75]孙家跃,杜海燕,胡文祥,等.固体发光材料[M].北京：化学工业出版社,2003：156.
[1]Kosketalo T, Leskela M. Niinsto L [J].Mat. Res. Bull,1985,20:265.
[2]常树岚,郭风瑜,孙寅官.Ca2B2O5中Ce3+、Mn2+的发光与能量传递[J].高等学校化学学报,1992,13(9)：1257-1259.
[3]郭风瑜,常树岚.Ca3La3(BO3)5中Ce3+、pb2+、Mn2+的光致发光和能量传递[J].中国稀土学报,1990,18(3)：229-232.
[4]常树岚,吴基石,盖同祥.以M3La3(BO3)5为基质的光致发光材料的合成[J].延边大学学报(自然科学版),1993,19(4)：42-44.
[5]常树岚.四硼酸镁光致发光材料的性能研究[J].延边大学学报(自然科学版),1994,20(3)：43-46.
[6]常树岚,郭明申,韩长友,孙尚梅.掺杂pb2+、Mn2+的SrB6O10发光材料的探讨[J].延边大学学报(自然科学版),1996,22(1)：16-19.
[7]曾庆华,裴治武,王树彬,等.SrB6010：Sm2+的高分辨光谱研究[J].中国稀土学报,1998,第八届全国发光学术会议稀土离子发光专辑：1021-1023.
[8]高勇,石春山,李德成.在SrB6O10中Tb和Eu的发光[J].科学通报,1996,41(17)：1575.
[9]Woo-Seuk Song, Yong-Seog Kim, and Heesun Yang. Yellow-emitting phosphor of Sr3B2O6:Eu2+ for application to white light-emitting diodes [J]. Materials Chemistry and Physics,2009,117:500-503.
[10]Chun-Kuei Chang and Teng-Ming Chen. Sr3B2O6:Ce3+, Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes [J]. Applied Physics Letters,2007,91:081902.
[11]Zhiguo Xia, Haiyan Dub, Jiayue Sunb, Daimei Chen, Xuefeng Wang. A novel blue-emitting Ca2B5O9Br:Eu2+phosphor prepared by a microwave calcination route [J]. Materials Chemistry and Physics,2010,119:7-10.
[12]YANG Zhi-ping, WANG Shao-li, YANG Guang-wei, et al. Luminescent properties of Ca2BO3Cl:Eu2+yellow-emitting phosphor for white-emitting diodes [J].Materials Letters, 2007,61:5258-5260.
[13]F.Xiao, Y.N.Xue, Q.Y.Zhang. Ca2BO3Cl:Ce3+, Eu2+:A potential tunable yellow-white-blue-emitting phosphors for white light-emitting diodes [J]. Physica B, 2009,404:3743-3747.
[14]Qiuhong Zhang, Jing Wang, Gongguo Zhang, Qiang Su. UV photo harvesting and enhanced near-infrared emission in novel quantum cutting Ca2BO3Cl:Ce3+, Tb3+, Yb3+[J]. Journal of Materials Chemistry,2009,19:7088-7092.
[15]CHEUNG H C.in Topics in Fluorescence Spectroscopy [M].New York:Kluwer 2002,2: 130.
[1]赵惠玲,刘世香,王明文,李文军.Sr8Si4O12Cl8：Eu3+,M3+(M3+=Bi3+,Gd3+)中的敏化发光[J].2007,35(5)：611-615.
[2]Jie Liu, Hongzhou Lian, Jiayue Sun, Chunshan Shi.Characterization and Properties of Green Emitting Ca3SiO4Cl:Eu2+ Powder Phosphor for White Light-emitting Diodes [J]. 2005,34(10):1340-1341.
[3]张明荣,刘波,朱正和.Eu2+在新型基质Ca8Mg(SiO4)4Cl2的光致发光[J].1993,14(13)：265-269.
[4]Jing Wang, Zongmiao Liu, Weijia Ding, Qiang Su. Luminescent Properties of (Ca1-xSrx)3SiO4(Cl1-yFy)2:Eu2+ Phosphors and Their Application for White LED[J].Int. J. Appl. Ceram. Technol,2009,6 (4):447-452.
[5]Fang Ying, Zhang Weidong, Cui Xiangzhong, Hu Yunsheng, Huang Xiaowei.Study on Ca8Mg(SiO4)4Cl2:Eu2+ Doped with Sr2+[J]. Journal of Rare Earths,2006,24(12):145-148.
[6]方英,叶信宇.Ca8Mg(SiO4)4Cl2：Eu2+,Mn2+绿色荧光粉的光谱性质[J].江西师范大学学报(自然科学版),2008,32(3)：273-276.
[7]Fang Ying, Zhang Weidong, Hu Yunsheng, Ye Xinyu, Huang Xiaowei. Luminescent Properties of Green Phosphors Ca8Mg(SiO4)4Cl2:Eu2+,Dy3+ for LED Application [J].2007, 25(5):574-576.
[8]CHEUNG H C. in Topics in Fluorescence Spectroscopy [M].New York:Kluwer 2002,2: 130.
[1]赵惠玲,刘世香,王明文,李文军.Sr8Si4O12Cl8：Eu3+,M3+(M3+=Bi3+,Gd3+)中的敏化发光[J],2007,35(5)：611-615.
[2]孙家跃,夏志国,杜海燕.(Sr,Ca)4Si3O8Cl4基质中Eu2+的发光特性研究[J].光谱学与光谱分析,2005,25(11)：1760-1763.
[3]Xia Zhiguo, Sun Jiayue, Du Haiyan. Study on Luminescence Properties and Crystal-Lattice Environment of Eu2+ in Sr4-xMgxSi3O8Cl4:Eu2+ Phosphor [J]. Journal of Rare earths,2004, 22(3):370-374.
[4]常树岚,路趁霄.CBC：Ce／Tb的光谱特性及CBC、Ce、Tb间的能量传递[J].稀有金属材料与工程,2008,37(9)：1592-1596.
[1]Wei-Hsiang Hsu, Meng-Huei Sheng, Ming-Shyong Tsai.Preparation of Eu-activated strontium orthosilicate (Sr1.95SiO4:Eu0.05) phosphor by a sol-gel method and its luminescent properties [J]. J. Alloys and Compounds.2009,467:491-495.
[2]杨志平,王少丽,杨广伟,等.绿色荧光粉NaCaP04：Tb3+的制备与发光特性[J].发光学报,2008,29(1)：81-84.
[3]Xinguo Zhang, Fangxiang Zhou, Jianxin Shi, et al. Sr3.5Mg0.5Si3O8Cl4:Eu2+ bluish-green emitting phosphor for NUV-based LED [J].Materials Letters,2009,63:852-854.
[4]Yang Zhi-Ping, Liu Yu-Feng. Preparation and luminescence characteristics of Eu2+ activated Ca3SiO5 green-emitting phosphor [J].ACTA PHYSIC A SINICA,2006,55(9): 4946-4950.
[5]Weijia Ding, Jing Wang, Mei Zhang, Qiu hong Zhang, Qiang Su. Luminescence Properties of new Ca10(Si2O7)3Cl2:Eu2+ Phosphor [J]. Chemical Physics Letters,2007,435:301-305.
[6]Zhanchao Wu, Menglian Gong, Jianxin Shi, Gang Wang, and Qiang Su.Dibarium Magnesium Diphosphate Yellow Phosphor Applied in InGaN-based LEDs [J].Chemistry Letters,2007,36(3):410-411.
[7]黄世华,楼立人.严懋勋教授和能量传递研究,发光学报[J].2008,29(4)：646-650.
[8]傅丹,郭培民,王稼国,陈德来,刑西平.蓝粉光谱特征对三基色荧光灯光色影响的色度学模拟计算[J].中国照明电器,2002,7：5-9.