褐煤腐殖酸肥料的养分缓释机理及其肥效研究
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摘要
随着现代化农业的不断发展,化肥在农业生产中的地位越来越重要,但由化肥的施用带来的问题也越来越多,尤其是较低的利用效率及其给环境、农产品等带来的系列危害越来越受到人们的重视,因此,各种缓效肥料的研究成为现阶段土壤学研究的热点问题之一。褐煤是一种重要的肥料基质,在我国已探明的保有储量就达1300多亿t。本试验采用室内试验同盆栽、大田试验相结合的方法,研究了不同处理方法对褐煤中腐殖酸含量及其特性的影响,并以活化前后的腐殖酸样品为吸附基质,探讨了其对N、P、K等养分离子的吸附特性。利用活化后腐殖酸的吸附特性制成腐殖酸缓效肥,以土肥混合法及大田淋溶的试验方法研究了该肥料中各养分离子的释放规律及硝酸盐的淋溶特性,并通过菠菜及杨树的盆栽试验探讨了腐殖酸缓效肥对作物产量、品质和土壤酶活性、养分及理化特性的影响,主要研究结果如下:
1. H3PO4和HCl处理能在一定程度上提高阳离子交换能力,但对腐殖酸含量及光学性质基本无影响。一定强度的HNO3能使腐殖酸含量增加25%以上,阳离子交换能力有了很大程度的提高,且其随硝酸强度的变化过程要明显滞后于腐殖酸含量的变化过程,光学性质发生了很大的变化。不同褐煤达到最佳处理效果的条件也不尽相同。
2.适宜的固液比例可提高铵单位吸附量;在试验pH(1.514.03)时,化学交换占主导地位,经硝酸处理后褐煤样品的分配系数Kd和吸附量Q明显大于未处理样品的Kd和Q。腐殖酸对铵氮的吸附等温式可用Freundlich等温曲线描述,其动力学吸附方程用Elovich方程拟合最佳。
3.未经硝酸处理的样品(S1)在pH为4.7时,对磷吸附量和分配系数有一最大值,而经硝酸处理后的样品(S2)随着pH的升高,吸附量和分配系数一直减小。且经硝酸处理后,样品对磷的单位吸附量和分配系数有了较大程度的降低。随平衡溶液浓度的升高,两样品对磷的单位吸附量也不断升高,其吸附规律可用Langmuir方程来加以描述,在第60min和90min时,两样品对磷的吸附基本达到吸附平衡,其吸附动力学可用Elovich和双常数方程进行拟合。
4.随着平衡溶液浓度的不断升高,褐煤腐殖酸对钾离子的单位吸附量不断增加。其吸附等温式可用Langmuir方程和Temkin方程来加以描述。S2对钾离子的吸附能力有了明显的提高,在适宜浓度条件下,其吸附量可提高41.1%。随pH的不断升高,S1和S2对钾离子吸附的分配系数逐渐增大,且pH的升高在一定程度上加快了吸附反应的速度。低pH时,两样品吸附能力差别不大,而高pH时,S2对钾离子的吸附能力远大于S1。其动力学吸附规律用Elovich方程描述最佳。在固液比例分别为0.04和0.06时,两样品对钾离子的吸附量达最大。
5.在投入养分量相等的条件下,化学肥料各养分离子的释放主要集中在前12 h,其释放量显著高于腐殖酸肥料,而在96h以后,腐殖酸肥料的释放量均要高于化学肥料。其中在氮肥释放过程中,NH4+是前期主要的释放形式,而随着时间不断延长,NO3--N成为主要的释放形式。腐殖酸肥料的施用能在一定程度上抑制NO3--N向地下迁移。
6.纯氮素处理的菠菜产量最高;腐殖酸肥料的施用显著改善了菠菜营养品质,降低菠菜体内硝酸盐含量,提高硝酸还原酶活性,增加Vc含量等。施用腐殖酸肥料N素利用率提高,增加了土壤速效磷的含量,促进了钾的消耗。自制的腐殖酸缓效肥料处理降低了土壤的pH,提高了土壤中蔗糖酶、碱性磷酸酶、多酚氧化酶的活性,同时降低土壤脲酶活性,但对过氧化氢酶活性影响不大。
Now, low N use efficiency and high environmental risk of chemical N fertilizer are worldwide concerned, which may be overcomed by using new slow-release fertilizers. So, the study on slow release fertilizer has very important practice meanings to the production in agriculture and forestry, etc. The brown coal is a kind of important raw material of the fertilizer and its reserve in our country is up to more than 130 billion tons. Simulative experiments, potted experiments and field experiments are used to study the effects of N、P、K concentration, equilibrium time and pH value on the adsorption of humic acid extracted from Shanxi brown coal. Humic acid fertilizer was manufactured through the adsorption characteristic. At the same time, release characteristic of N、P、K and the effect of this humic acid fertilizer on spinach and poplar were studied. The purpose of this research was to offer basic data for the production of humic acid slow-release fertilizers, the main results are as follows:
1. The effects of various kinds of inorganic acid on the content, cation exchange capacity and optics nature of humic acid in brown coal were studied .The results showed that the content and the optics nature were not affected by Phosphoric acid and Hydrochloric acid treatment ,but the cation exchange capacity can be increased to some extent .The content of humic acid can be increased by 25 per by suitable for intensity Nitric acid, The cation exchange capacity can be greatly increased and the optics characteristic was greatly changed too. The best conditions would be different to different brown coal.
2. With the increase of NH4+ concentration, adsorption capacity of NH4+ increased. The adsorption of NH4+ on humic acid could be well described by Freundlich equation and its kinetics adsorption fit Elovich equations best. Under the condition of pH lower than 7.04, pH increase of medium was great of advantage of NH4+ adsorption and could improve the velocity of adsorption reaction. Under the condition of pH lower than 4.03, physical adsorption was the dominant. However, under the condition of 4.03 3. pH increase of medium was of great disadvantage of P adsorption and could decrease the velocity of adsorption reaction. As to the sample one, the distribution coefficient and adsorption capacity were the maximum at pH being 4.7. Even the pH was higher, as to the second sample, the distribution coefficient and adsorption capacity weres decreased. Besides, the distribution coefficient and adsorption capacity of the experimental humic acid treated by nitric were significant lower than that of the brown coal without treated. With the increase of P concentration in the medium, adsorption capacity of P+ increased too. Adsorption capacity rose markedly in the beginning of the adsorption process, however, it slowed down later. Suitable ratio of solid to liquid could increase the unit adsorption. The adsorption of P on humic acid could be well described by Langmuir equation and its kinetics adsorption fit Elovich equations best.
4. pH increase of medium was of great advantage of K+ adsorption and could improve the velocity of adsorption reaction. Under the condition of pH<4.4, physical adsorption was the dominant. However, under the condition of 7.12 5. With equal-nutritional quantity, the release of chemistry fertilizer was main in the first and second time, which is significantly higher than humic acid fertilizer. However, the release of the humic acid fertilizer was higher than the chemical fertilize in the successive time. NH4+-N was the domination in ealier stage, while NO3--N was the main form latter. Applying humic acid fertilizers could refrain the leaching of NO3--N to some extent.
6. All fertilizer treatments were significantly out-weighted the CK and the treatment of N pure was the highest but was not significant all. With equal-nutritional quantity, humic acid fertilizer apparently decreased the NO3--N content and increased the content of Vc, soluble sugar and chlorophyll content. Compared with inorganic fertilizer, humic acid fertilizer increased N utilization and available P and comsumption K in soil. Humic acid fertilize reduced the pH, improved the activities of alkalinr phosphatase, invertase and polyphenol oxidase. At the same time it decreased the activities of urease, but there was no effect on the activities of catalase.
1. H3PO4和HCl处理能在一定程度上提高阳离子交换能力,但对腐殖酸含量及光学性质基本无影响。一定强度的HNO3能使腐殖酸含量增加25%以上,阳离子交换能力有了很大程度的提高,且其随硝酸强度的变化过程要明显滞后于腐殖酸含量的变化过程,光学性质发生了很大的变化。不同褐煤达到最佳处理效果的条件也不尽相同。
2.适宜的固液比例可提高铵单位吸附量;在试验pH(1.51
3.未经硝酸处理的样品(S1)在pH为4.7时,对磷吸附量和分配系数有一最大值,而经硝酸处理后的样品(S2)随着pH的升高,吸附量和分配系数一直减小。且经硝酸处理后,样品对磷的单位吸附量和分配系数有了较大程度的降低。随平衡溶液浓度的升高,两样品对磷的单位吸附量也不断升高,其吸附规律可用Langmuir方程来加以描述,在第60min和90min时,两样品对磷的吸附基本达到吸附平衡,其吸附动力学可用Elovich和双常数方程进行拟合。
4.随着平衡溶液浓度的不断升高,褐煤腐殖酸对钾离子的单位吸附量不断增加。其吸附等温式可用Langmuir方程和Temkin方程来加以描述。S2对钾离子的吸附能力有了明显的提高,在适宜浓度条件下,其吸附量可提高41.1%。随pH的不断升高,S1和S2对钾离子吸附的分配系数逐渐增大,且pH的升高在一定程度上加快了吸附反应的速度。低pH时,两样品吸附能力差别不大,而高pH时,S2对钾离子的吸附能力远大于S1。其动力学吸附规律用Elovich方程描述最佳。在固液比例分别为0.04和0.06时,两样品对钾离子的吸附量达最大。
5.在投入养分量相等的条件下,化学肥料各养分离子的释放主要集中在前12 h,其释放量显著高于腐殖酸肥料,而在96h以后,腐殖酸肥料的释放量均要高于化学肥料。其中在氮肥释放过程中,NH4+是前期主要的释放形式,而随着时间不断延长,NO3--N成为主要的释放形式。腐殖酸肥料的施用能在一定程度上抑制NO3--N向地下迁移。
6.纯氮素处理的菠菜产量最高;腐殖酸肥料的施用显著改善了菠菜营养品质,降低菠菜体内硝酸盐含量,提高硝酸还原酶活性,增加Vc含量等。施用腐殖酸肥料N素利用率提高,增加了土壤速效磷的含量,促进了钾的消耗。自制的腐殖酸缓效肥料处理降低了土壤的pH,提高了土壤中蔗糖酶、碱性磷酸酶、多酚氧化酶的活性,同时降低土壤脲酶活性,但对过氧化氢酶活性影响不大。
Now, low N use efficiency and high environmental risk of chemical N fertilizer are worldwide concerned, which may be overcomed by using new slow-release fertilizers. So, the study on slow release fertilizer has very important practice meanings to the production in agriculture and forestry, etc. The brown coal is a kind of important raw material of the fertilizer and its reserve in our country is up to more than 130 billion tons. Simulative experiments, potted experiments and field experiments are used to study the effects of N、P、K concentration, equilibrium time and pH value on the adsorption of humic acid extracted from Shanxi brown coal. Humic acid fertilizer was manufactured through the adsorption characteristic. At the same time, release characteristic of N、P、K and the effect of this humic acid fertilizer on spinach and poplar were studied. The purpose of this research was to offer basic data for the production of humic acid slow-release fertilizers, the main results are as follows:
1. The effects of various kinds of inorganic acid on the content, cation exchange capacity and optics nature of humic acid in brown coal were studied .The results showed that the content and the optics nature were not affected by Phosphoric acid and Hydrochloric acid treatment ,but the cation exchange capacity can be increased to some extent .The content of humic acid can be increased by 25 per by suitable for intensity Nitric acid, The cation exchange capacity can be greatly increased and the optics characteristic was greatly changed too. The best conditions would be different to different brown coal.
2. With the increase of NH4+ concentration, adsorption capacity of NH4+ increased. The adsorption of NH4+ on humic acid could be well described by Freundlich equation and its kinetics adsorption fit Elovich equations best. Under the condition of pH lower than 7.04, pH increase of medium was great of advantage of NH4+ adsorption and could improve the velocity of adsorption reaction. Under the condition of pH lower than 4.03, physical adsorption was the dominant. However, under the condition of 4.03
4. pH increase of medium was of great advantage of K+ adsorption and could improve the velocity of adsorption reaction. Under the condition of pH<4.4, physical adsorption was the dominant. However, under the condition of 7.12
6. All fertilizer treatments were significantly out-weighted the CK and the treatment of N pure was the highest but was not significant all. With equal-nutritional quantity, humic acid fertilizer apparently decreased the NO3--N content and increased the content of Vc, soluble sugar and chlorophyll content. Compared with inorganic fertilizer, humic acid fertilizer increased N utilization and available P and comsumption K in soil. Humic acid fertilize reduced the pH, improved the activities of alkalinr phosphatase, invertase and polyphenol oxidase. At the same time it decreased the activities of urease, but there was no effect on the activities of catalase.
引文
安有恒,刘忠祥,王永芳.腐植酸类肥料在农业上的应用及其开发前景[J].甘肃农业科技,1994,(5):30-31
北京师范大学化学系.简明化学手册[M].北京:北京出版社,1980
曹文华,琚行松,赵红利.风化煤活性制备高纯腐殖酸的研究[J].唐山师范学院学报,2001,23(5):19-26
陈锦强,李明启.不同氮素营养对黄麻叶片的光合作用、光呼吸的影响及光呼吸与硝酸还原的关系[J].植物生理学报,1983,(3):251-259
陈铭,谭见安,孙富臣,等.湖南土壤对NO3--N和SO42-的吸附机理研究[J].环境化学,1993,(12):252-257
陈玉玲,曹敏,周燮.黄腐酸对冬小麦幼苗IAA、ABA水平的影响及作用机理的探讨[J].植物学通报,1999,16(5):587-590
陈子明.北京潮土NO3--N在土体中的移动特点及其淋失动态[J].植物营养与肥料学报, 1995,1(2):69-79
陈子明.氮素产量环境[M].北京:中国农业科技出版社,1996
成绍鑫,孙淑和,李善祥,等.腐殖酸和硝基腐殖酸的结构研究[J].燃料化学学报,1983,11(2):26-39
程东娟,刘树庆,王殿武,等.长期定位培肥对土壤酶活性及土壤养分动态变化影响[J].河北农业大学学报,2003,26(3):33-36
丁皓江,谢贻权,何福保.弹性和塑性力学中的有限单元法(修订本) [M].北京:机械工业出版社,1989,111-123
杜建军,廖宗文,毛小云,等.包膜控/缓释肥养分释放特性评价方法的研究[J].磷肥与复肥,2003,(18)2:11-13
范春杰,刘懿善,孟庆春,等.新型颗粒生物有机肥的生产工艺研究[J].齐齐哈尔大学学报,2002,18(3):22-24
范兴亮.新编肥料使用手册[M].中原农民出版社,1999
冯元琦.腐植酸类农药新技术[J].腐植酸,2003,(1):12
傅明华,戴朱恒,承友松,等.上海磷的土壤吸附特征及缓冲性能研究[J].土壤学报,1986,23(2):113-123
关松荫.土壤酶及其研究法[M].北京:农业出版社,1986
郭晓东,张雪芹,杨玲.甘肃省主要农业区土壤对磷的吸附与解吸特征[J].西北农业学报,1997,6(2):7-12
国家环保局编.水和废水监测分析方法[M].北京:中国环境科学出版社,1989
韩文质.腐植酸类肥料对土壤的改良作用及施用方法[J].甘肃农业科技,1997,(6):32-34
赫婧,颜丽,杨凯,等.不同来源腐殖酸的组成和性质的研究[J].土壤通报,2003,(4):343-345
胡红青,贺纪正,李学垣,等.有机酸对酸性土壤吸附磷的影响[J].华中农业大学学报,1997,16(1):37-42
胡红青,贺纪正,李学垣.多种有机酸共存多可变电荷土壤吸附磷德影响[J].植物营养与肥料学报,1999,15(2):122-128
黄彪,吴新华.粉煤灰活性炭处理六价铬废水的试验研究[J].环境科学进展,1998,2(6):77-80
姜建平,孙明强,严玉娟,等.腐植酸系列专用肥德开发与应用[J].磷肥与复肥,2001,16(2):70-71
蒋疆,王果,陈芳育.草炭溶解态有机物质与Pb2+、Zn2+络合稳定性研究[J].福建衣业学报,2002,17(2):125-127
劳家柽.土壤农化分析手册[M].北京:农业出版社,1988:465-475
李光林,魏世强,青长乐.铬在胡敏酸上的吸附动力学和热力学研究[J].土壤学报,2004, 41(1):74-80
李光林,魏世强,青长乐,等.铬在腐殖酸上的吸附与解吸特征研究[J].农业环境科学学报,2003,22(1):34-37
李克斌,刘维屏.重金属离子在腐殖酸上的吸附的研究[J].环境污染与防治,1997,19(1):9-11
李丽.硕士学位论文,风化煤腐殖酸与速效磷肥相互作用的研究[D].太原:中国科学院山西煤炭化学研究所,1999
李善祥.煤炭腐殖酸在农业领域的应用[J].农业环境保护,1996,15(3):136-138
李绪行,邵莉楣,殷蔚,等.黄腐酸和汪平酸对小麦种子萌发与幼苗生长及绿豆下胚轴生根的影响[J].植物学通报,1991,8(3):51-55
梁兰英.紫外分光光度法测定土壤中的硝态氮[J].甘肃环境研究与监测,2001,14(2):80-81
梁宗存,成绍鑫,武丽萍,等.煤中腐殖酸与尿素相互作用机理的研究[J].燃料化学学报,1999,27(2):176-181
梁宗存.煤中腐植酸与尿素反应机理及其产物的组成性质,学位论文[C]. 1997,13(2):233-238
刘翠霞,邓昌亮,徐海宁.龙口褐煤对废水中Cr(Ⅵ)的吸附与还原[J].化工环保,1996,16(6):337-340
刘满红,王如阳.凤鸣村腐殖酸和活性褐煤对Cr(Ⅵ)离子的吸附等温式[J].云南化工,2002,29(2):6-7
刘秀梅,张夫道,冯兆滨,等.风华煤腐殖酸对氮、磷、钾的吸附和解吸特性[J].植物营养与肥料学报,2005,11(5):641-646
卢静,朱琨,赵艳锋,等.腐殖酸在去除水体和土壤中有机污染的作用[J].环境科学与管理,2006,31(8): 151-154
陆欣,王申贵.煤炭腐植酸对石灰性土壤磷酸酶活性的影响[J].腐植酸,1989,(3):41-44
陆欣.煤炭腐植酸脲酶抑制剂应用效果研究[J].腐植酸,1994,(4):10-14
梅慧生,杨玉明,张淑远,等.腐植酸对植物生长的刺激作用[J].植物生理学报,1980,6(2):133-139
倪献智,许志华,曾蒲君.年轻煤硝酸氧解制备硝基腐殖酸的研究[J].煤炭转化,1996,19(2):80-86
彭正萍,门明新,薛世川,等.腐植酸复合肥对土壤养分转化和土壤酶活性的影响[J].河北农业大学学报,2005,28(4):1-4
彭正萍,薛世川,孙志梅.腐殖酸复合肥对油菜品质及生理指标的影响[J].河北农业大学学报,2001,24(1):24-27
全国农业技术推广服务中心.中国有机肥料资源[M].中国农业出版社,1999
任凤莲,宋鸽,孙丽勤.煤中总酸基的测定[J].湖南化工,2000,30(1):40-42
任祖淦,陈玉水,张逸清,等.有机无机肥料配施对土壤微生物和酶活性的影响[J].植物营养与肥料学报,1996,2(3):279-283.
阮建云,马立锋,石元值,等.茶园上壤对氟的吸附与解吸特性[J].茶叶科学,2001,21(2):161-165
芮旻,高乃云,徐斌,等.水中腐殖酸对高级氧化联用技术去除饮用水中内分泌干扰物(DMP)的影响[J].环境科学,2006,27(12): 2495-2501
沈明珠.蔬菜硝酸盐累积的研究[J].园艺学报,1982,9(1):42-47
宋茜萍.腐植酸的开发与应用[J].中国化工,1998,(5):49-50
苏玲,林咸永,章永松,等.水稻土淹水过程中不同土层铁形态德变化及对磷吸附解吸特征的影响[J].浙江大学学报(农业与生命科学版),2001,27(2):124-128
孙克刚,张桂兰,姚健,等.长期不同施肥对潮土中NO3--N累积及作物产量的影响[J].土壤通报,1999,30(6):262-264
孙明强,姜建平,王为民.腐殖酸包裹型长效尿素在水稻土上应用效果研究[J].腐殖酸,2000,(3):23-27
孙瑞莲,赵秉强,朱鲁生,等.长期定位施肥对土壤酶活性的影响及其调控土壤肥力的作用[J].植物营养与肥料学报,2003,9(4):406-410
唐周斌,李晓明,赵嘉平. PGPR菌剂及可溶性腐植酸对经济果林生长的影响[J].山西林业科技,2003(4):1-6
陶著.煤化学[M].冶金工业出版社,1984
汪建飞,李增流,李春泉.土壤NH4+吸附特征的研究[J].安徽农业技术师范学院学报,1998,12(3):1-4
王丹丽,董晓丹,王恩德.针铁矿对重金属离子的吸附作用[J].黄金,2002,23(2):44-46
王国学.腐植酸肥料改土增产效果研究[J].腐植酸,1993,(4):38-40
王建琪,吴文辉,冯大明.电子能谱学引论[M].北京:国防工业出版社,1992
王如阳,王泓,许红波,等.寻甸褐煤腐殖酸对Ni(Ⅱ)的吸附性能试验[J].云南化工,2000,27(3):9-12
王如阳,王泓等.褐煤腐殖酸对Cr(Ⅵ)离子的吸附特性试验[J].云南民族学院学报(自然版),1999,(4):41-44
王树会,张红艳.不同腐植酸用量对烤烟生长及产质的影响[J].中国农学通报,2007,23(1):289-291
王天立.腐植酸的胶体性质,全国第二次腐植酸化学学术讨论会论文集,中国化学会,1981:177-183
王天立.黄腐酸在农业上的应用[J].腐植酸,1992,(1):14
王小岗,凌道盛,徐兴.三维退化梁单元及在扭转问题中的应用[J].固体力学学报,1999,20:245-248
魏景云.褐煤不同处理方法制成的腐殖酸复合肥料增效作用[J].内蒙古农牧学院学报,1998,19(4):74-79
文启孝,张晓华,杜丽娟,等.太湖地区主要土壤中的NH4+及其有效性[J].土壤学报,1998,25(1):22-30
吴玉光.化肥使用指南[M].中国农业出版社,2000
武汉大学等五校编.分析化学[M].北京:人民教育出版社,1978.17-21
谢鹏,蒋剑敏,熊毅.我国几种主要土壤胶体的NH4+吸附特征[J].土壤学报,1998,25(2):175-183
熊又升,陈明亮,喻永熹,等.包膜控释肥料的研究进展[J].湖北农业科学,2000,5:40-42
徐传忠.生产有机-无机复混肥原料腐殖酸的选择及质量指标的测定[J].磷肥与复肥,2006,21(3):45-46
徐明岗.土壤离子吸附[J].土壤肥料,1997(5) :3-7
许秀成,李菂萍,王好斌.包裹型缓释/控制释放肥料专题报告[J].磷肥与复肥,2000,15(3):1-6
薛继澄.保护地栽培蔬菜生理障碍的土壤因子与对策[J].土壤肥料,1991(1):4-9
薛青武、陈培元.灌浆期土壤干旱条件下氮素营养对小麦旗叶光合作用的影响[J].干旱地区农业研究,1989(3):86-93
薛青武.灌浆期土壤干旱条件下氮素营养对小麦旗叶光合作用的影响[J].干旱地区农业研究,1989(3):86-93
薛泉宏,尉庆丰,高彦,等.陕西省几种代表性土壤NH4+吸附、解吸动力学特征研究[J].土壤学报,1996,33(5):130-137
薛世川,韩建民,刘东臣,等.棉用腐殖酸复合肥施用量与机理的研究[J].河北农业大学学报,1998,21(4):21-27
薛泰麟.从土壤脲酶性质的角度探讨尿素合理施用的途径[J].中国农业科学,1991,24(4):61-68
闫娥,孙文风.土壤腐殖质的分析化学性状研究现状[J].青海大学学报(自然科学版),2000,18(5):17-22
闫双堆,卜玉山,刘利军,等.不同腐殖酸物质对土壤中汞的固定作用及植物吸收的影响[J].环境科学学报,2007,27(1):101-105
严昶升主编,土壤肥力研究法[M].农业出版社,1988,274-276
严玉娟,张晓健,孙明强,等.水稻应用腐殖酸包裹型长效尿素效果研究[J].腐殖酸,2001(1):14-16
杨新全,冯锋,宋长青,等.主要农田生态系统氮素行为与氮肥高效利用研究[J].植物营养与肥料学报,2003,9(3):373-376
杨学云,王采绒,戴万红,等.娄土硝酸盐淋失的渗漏池研究[J].西北农业学报,1999,8(6):122-125
叶柄,王虹.应用Langmuir等温式解释我国东北某些土壤对磷酸离子的吸附作用[J].土壤学报,1984,21(1):21-28
于淑芳,杨力,张玉兰,等.长期施肥对土壤腐殖质组成的影响[J].土壤通报,2002,33(3):165-167
于蜀宜,李剑华.用陶土吸附处理含镍废水的处理[J].化工环保,1998,(4):199-202
于天仁,季国亮,丁昌璞.可变电荷土壤的电化学[M].北京:科学出版社,1996,39-134
余贵芬,青长乐,牟树森.汞在腐殖酸上德吸附与解吸特征[J].环境科学学报,2001,21(5):601-606
袁新民,王周琼.硝态氮的淋洗及其影响因素[J].干旱区研究,2000,17(4):46-51
岳廷盛,程家安,马沛岚.褐煤腐殖酸基本性能研究[J].兰州大学学报(自然科学版),1995,31(2):82-85
岳廷盛,唐涤,窦富全.泥炭中腐殖酸含量提高方法研究[J].腐殖酸,1993(2):25-28
岳廷盛,张汉文,王玉琨.褐煤中腐植酸对65Zn2+的吸附与交换[J].铀矿冶,1996,15(4):76-79
岳延盛,解箐雅. NH4+在褐煤腐殖酸中的物理吸附与化学交换[J].铀矿冶,1997,16:62-65
张春兰.氮素形态和和NO3--N和NH4+-N对菠菜生长和品质的影响[J].南京农业大学学报,1990 ,13(3):70-74
张福锁.土壤与植物营养研究新动态(第二卷) [M].中国农业出版社,1995,42-75
张福珠,熊先哲,戴同顺.应用15N研究土壤-植物系统中氮素淋失动态[J].环境科学,1984,8(1):21-24
张怀成,王在峰,李建义,等.褐煤经磺化及碱化处理对重金属离子的吸附性能研究[J].环境化学,1996,18(5):482-487
张梁国,章申.农田氮素淋失进展[J].土壤,1998,6:291-297
张民,杨越超,宋付朋,等.包膜控释肥料研究与产业化开发[J].化肥工业,2005,32(2):7-13
张庆忠,陈欣,沈善敏,等.农田土壤硝酸盐累积与淋失研究进展[J].应用生态学报,2002,13(2):233-238
张淑霞.胡萝卜鲜、干重变化与需肥规律的研究[J].河北农业技术师范学院学报,1997,11(4):30-35
张学才,张德祥.我国德腐植酸资源及其工农业利用[J].中国煤炭,26(12):13-18
张泽丽,王照雄.缓释肥料在水稻土中施用效果研究[J].四川农业大学学报,1995,13(3):259-265
肇溥敏,王宝中.腐殖酸类物质与尿素的复合效应及其对脉酶活性的抑制作用[J].土壤通报,1993,24 (3):135-136
郑剑英.施用氮、磷肥对作物体内养分含量的影响[J].西北植物学报,1996,16(6):56-61
郑平.煤炭腐殖酸的生产和应用[M].北京:化学工业出版社,1991,59-62
郑圣先.控释肥料提高N素利用率作用及对水稻效应的研究[J].植物营养与肥料学报,2001,7(1):11-16
郑兴耗,温贤芳.氮素施用量对土壤硝态氮形成动力学的影响[J].核农学报,1995,9(增刊):41-48
中国科学院山西煤炭化学研究所,北京化工学院.北京农业大学学报,植酸类肥料[M].北京:科学出版社,1979,151-152
周礼恺.土壤酶学[M].北京:科学出版社,1987
周延刚,王瑛.陕西焦坪低变质烟煤硝酸氧解制取硝基腐植酸研究[J].煤炭科学技术,27(3):189-21
朱坚果.硝态氮污染与展望[J].土壤学报,1995,35(增刊):62-69
Addiscott T M. A sample computer model for leaching in structured soils[J]. Soil Sci., 1977,28:554-563.
Akkanen J, Penttinen S, Haitzer Ml. Bioavailablity of atrazine pyrene and benzopyrene in European river waters[J]. Chemosphere, 2001, 45(4): 453-462
Alfassi Z B. On the precipitation of salts/complexes of trivalent cations with humic acid[J]. Journal of Radio analytical and Nuclear Chemistry, 2004, 262 (1): 77-81
Ayuso M, Hernandez Z T, Garcia C A. Comparatives study of the effect on barley growth of humic substances extracted from municipal wastes and from traditional organic materials[J]. Sci. Food Agric. 1996,72(4):493-500
Bergstrom L F, Kirchmann H. Leaching of total nitrogen from nitrogen-15-labelled poultrymanure and inorganic nitrogen fertilizer[J]. J Environ. Qual.,1999,28:1283-1290.
Binay K S, Narendra S R. Comparative sorption equilibriumstudies of toxic phenols On fly ash and impregnated fly ash[J]. J Chem. Tech. Biotechnol.,1994,61:307-317
Boyd G E. The exchange adsorption of ions from aqueous solutions by organic zeolites kineties [J]. Am. Chem. Soc. 1947,69:28-38
Brennan R F, Bolland M D, Jeffery R. C. Phosphorus adsorptlon by a range of Western soils related to soil properties[J] .Commun Soil Sci. Plant Anal, 1994,25:(15-16):2785-2795
California Fertilizer Association . West Fertilizer Handbook Second Horticulture Edition[M]. Interstate Publishers ,Inc,1998,147
Christian A E. Adsorption of iron by a Nigerian brown coal [J]. Fuel ,1994,14(2):132-135.
Cookson W R. Rowarth J S. Cameron K C. The effect of sutumn applied 15N-labelled fertilizer on nitrate leaching in a cultivated soil during winter[J]. Nutri cycling in agroecosystems, 2000,56:99-107
Cordon M K, John F P. Equilibrium parameters for the sorption of copper Cadmium and Zinc ions onto peat[J]. Chem. Tech Biotechnol,1997,69:309-320
Datta A, Sanyal S K, Saha S. A study on natural and synthetic humic acids and their complexing ability towards cadmium[J]. Plant and Soil, 2001, 235: 115-125,
Dean L A. Fixation of soil phosphorus[J]. Adv. Agron, 1949,1:391-411.
Ding G, Novak J M, Amarasiriwardena D, et al. Soil oeganic matter characteristics as affected by tillage management[J]. Soil Sci. Soc. Am. 2002,66:421-429
Donnell R W. The auxin-like effects of humic preparations from leonardite[J]. Soil Sci. 1973,116(2):106-149
Frimmel F H. Humic substances and their role in the environment[J]. John and Sons, 1988:173-179
Gardner B R, Roth R. L. Midrib nitrate concentration as a meansfor nitro-gen needs of Broccoli[J]. J of Plant Nutri, 1989,12(1):111-125
GlannoplitiS G. N. Ries S. Superoxide dismutase:Purification and quantiative relationship with water-soluble protein in seedlings[J]. Plant Physiol,1997,(59):309
Gunasekara A S, Simpson M J, Xing B. Identificationand characterization of sorption domains in soil organic matter using struccturally modified humic acids. Environ[J].. Sci.Technol.,2003,37:852-858
Gunasekara A S, Xing B. Sorption and adsorption of naphthalene by soil orgnic matter: Importance of aromatic and aliphatic components[J]. Environ. Qual. 2003,32:240-246
Haitzer M, Burnison B, Hoss S. Effects of quality and contact time of dissolved organic matter on bioconcentration of benzopyrene in the nematode caenorhabditis elegans[J]. Environ Toxicol Chem, 1999, 18(3): 459-465
Haitzer M, Burnison B, Hoss S. Effects of quality and contact time of dissolved organic matter on bioconcentration of benzopyrene in the nematode caenorhabditis elegans[J]. Environ Toxicol Chem, 1999, 18(3): 459-465
Hansen E M, Djurhuus P. Nitrate leaching as affected by long-term N fertilization on a coarse sand[J]. Soil use and management, 1996, 12:199-204
Havis R N, Alberts E E. Nutrient leaching from field-decomposed corn and sovbean residue under simulated rainfall[J]. Soil Sci. Soc. Am. J, 1993,56:211-218
Havlin J L. westfall D g. Potassium release kinetics and plant response in calcareous soils[J]. Soil Sci. Soc, Am. J. 1985:49:365-370
Joanna Cieslewicz, Slawomir S. Gonet. Properties of humic acids as biomarkets of lake catchment management[J]. Aquatic Sciences. 2004, 66: 178-184
Kang S H. Amarasiriwardena D, Veneman P L, et al. Characterization of ten sequentially extrated humic acids and a humin from a soil in western Massachusetts[J]. Soil Sci. 2003, 168: 880-887
Kay C M, Porter J F. Equilibrium parameters for the sorption of copper, Cadmium and zinc irons onto peat[J]. Chem. Teach Bio Technol. 1997, 69: 309-320
Kiniburgh D G, Syers J K. Specific adsorption of trace amount of Ca and Sr by hydrous oxides of iron and alum in ium [J]. Water Research 1994, 22(3):19-22
Lahav O, Green M. Ammonium Removai using lon Exchange and Biologica Regeneration [J]. Water Research 1998, 32(7):9-11
Li H X, Zhang X M, Liu Y J. Soil components affecting phosphate sorption parameters of acid paddy soils in Guangdong province[J]. Pedosphere, 2000,10:317-321
Liu X B, Han X Z, Song C, et al. Soil organic caebon dynamics in blank soil of China of humic substances by solid-state carbon-13 nuclear magnetic resonance[J]. Soil Sci. Soc. Am.J. 2000,64:873-884
Malcolm R L, Mac C P. Transactions of the 14th intemational congress of Soil[J]. Science 1990,(1):490-491
Mantinez M T, Romero C, Gavilan J M. Characteristics of HA-Ca complexes prepared from lignite humic acids[J]. Fuel. 1983, 62(8):956-958
Marcelo J, Kevin J . Disaggregation kinetics of a peat humic acid : mechanism and pH effects[J]. Environmental. Science. Technology. 2002, 36: 5100-5105
Martin E T. Controlled-release Stabilized Fertilizer in Agriculture[M]. International Fertilizer Industry Association, 1997,61
Matis K A. Zouboulis A I. Sorption of as by goethite particles and study of their flocculation[J]. water Air and Soil Pollution 1998,104(8):33-45
Nandakumar R, Saravanan A, Singaram P, et al. Effect of lignite humic acid on soil nutrient availability at different growth stages of rice grown on vertisols and alfisols[J]. Acta Agronomica Hungarica, 2004, 152(3): 227-235
Ortega E, Cheese C, Knight J. et al. Properties of Alkali active clinoptilolite[J]. Cement and Concrete Research ,2000 , 30: 1641-1646
Ouki S K, Neufeld R D. Use of activated carbon for the recovery of chromium from industrial waste watters[J]. J Chem. Tech. Biotechnol., 1997, 70:3-8
Patter J W, Allen H E, Scala J J. Carbonate heavy metals pollutants[J]. J. Water pollut. 2001,(12):2 397
Pinton R, Varanini Z, Vizzotto G. Soil humic substances effect transport propertise of tonoplast resicles isolated from Oat roots[J]. Plant and Soil. 1992, 142:203-210
Sanders J R, Mcgrath S P. Experimental measurements and computer predictions of copper complex formation by soluble soil organic matter[J]. Environ. Pollu. 1988,49:63-76
Sarah P, Landels C E H. Marketing Research Controlled Release Fertilber[A]. The Chemical Economics Handbook—SRI International[M]. 1994
Schniter M, Khan S U. Humic substances in the environment[M]. New ork:Marcel Dekker,Inc, 1972, 138-142
Sensi N, Rizzi F R, Acquafredda. Fraction dimension of humic acids in aqueous suspensions as a function of pH and time[J]. Soil Sci. Am. J. 1996,60:1773-1780.
Sposito G. Sorption of trace metals by humic materials in soils and waters CRC Crit[J]. Rev. Environ. Ctrl., 1986,16:193-227
Stenberg M, Aronsson H, Linden B, et al. Soil mineral nitrogen and nitrate leaching losses in soil tillage systems combined with a catch crop[J]. Soil and tillage research, 1999,50:115-125.
Syers J K, Iskandar I K. Soil phosphor Chemistry[M] ,1981,571-599
Thorup R M, Mehich A. Retetion of potassium ,meta and orthophosphate by soils and minerals[J] .Soils Sci ,1961 ,91:38-43
Torstensson G, Aronsson H. Nitrogen leaching and crop availability in manured catch crop systemin Sweden[J]. Nutri cycling in agroecosystems,2000,56:139-122
Trenkel M E. Controlled release and stabilized fertilizers in agriculture. IFA, Paris, 1997 Tsutsuki K. Characterization of humic-metal complexes in a buried volcanic ash soil profile and a peat soil[J]. Soil sci. plant Nutr,1992,38(2):297-306
Varanini Z,Pinton R, Debiasi M G. Low Molecular Weight Humic Substances Stimulate H+-ATPase Activity of Plasma Membrane resides Isolated from Oat (Avena Satival L.) Roots[J]. Plant and Soil. 1993,153:61-69
Vaughan D A. Possible Mechanism for Humic acid Action on Cell Elongation in Root Segments of pisum sativum under Aseptic Conditions[J]. Soil Biol. Biochem. 1974,6:241-247
Vaughan D, Linehan D J, The Growth of Wheat Plants in Humic Acid Solution under Axenic Condition[J]. Plant and Soil. 1976,44:445-449
Vaughan D, Ord B G. Uptake and incorporation of 14C- Labeled Soil Organic Matter by Roots of pisum sativum[J]. Exp. Bot. 1981, 32(129):684-687
Viaraghavan T. Use of peat in pollution control[J]. Environ-mental Studies. 1991,37:163-169
Von O B, Kordel W, Klein W, Sorption of nonpolar and polar compounds to soils: processes, measurement an dexperience with the applicability of the modified OECD-guideline[J]. Chemosphere,1991,22:285-304
Wahlberg O, Aren S. Studies of fluvic and humic acids 1.determination of the steady states for slow processes in 0.1M NaCl aqueous solution[J].Acita. chem..Scand,1996,50:561-566
Wang D Y, Qing C L. Effect of humic acid on transport and Transformation of Mercury in soil-plant systems[J].Water, air and soil pollution. 1997,95:35-43
Williams A, Xing B, Veneman P. Effect of cultivation on soil organic matter and aggregatedstability[J]. Pedosphere. 2005,15(2):255-262
Wu J, Laird D A, Thompson M L. Sorption and desorption of copper on soil clay component[J]. Journal of Environmental Quality. 1999,28(1):334-338
Xing B S, Liu J D, Liu X B, et al. Extraction and characterization of humic acids and humin fractions from a black soil of China[J]. Pedosphere, 2005,15(1) : 1-8
Xing B, Liu X, Liu J, et al. Physical and chemical characteristics of a typical Mollisol in china. Commun[J]. Soil Sci. Plant Anal. 2004,35:1829-1838
Xu J M, Yuan K W. Dissolution and fraction of calcium-bound and iron and aluminum-bound humus in soils[J]. Pedosphere, 1993,3:45-80
Yang C M, Wang M C, Lu Y F, et al. Humic substances affect the activity of chlorophyllase[J]. Journal of Chemical Ecology, 2004, 30(5): 1057-1065
Zorpas A, Constantinides T, Mysside A. G. Heavy metals uptake by natural zeolite and metals [J]. Soils Sci.,1978,81:31-33
北京师范大学化学系.简明化学手册[M].北京:北京出版社,1980
曹文华,琚行松,赵红利.风化煤活性制备高纯腐殖酸的研究[J].唐山师范学院学报,2001,23(5):19-26
陈锦强,李明启.不同氮素营养对黄麻叶片的光合作用、光呼吸的影响及光呼吸与硝酸还原的关系[J].植物生理学报,1983,(3):251-259
陈铭,谭见安,孙富臣,等.湖南土壤对NO3--N和SO42-的吸附机理研究[J].环境化学,1993,(12):252-257
陈玉玲,曹敏,周燮.黄腐酸对冬小麦幼苗IAA、ABA水平的影响及作用机理的探讨[J].植物学通报,1999,16(5):587-590
陈子明.北京潮土NO3--N在土体中的移动特点及其淋失动态[J].植物营养与肥料学报, 1995,1(2):69-79
陈子明.氮素产量环境[M].北京:中国农业科技出版社,1996
成绍鑫,孙淑和,李善祥,等.腐殖酸和硝基腐殖酸的结构研究[J].燃料化学学报,1983,11(2):26-39
程东娟,刘树庆,王殿武,等.长期定位培肥对土壤酶活性及土壤养分动态变化影响[J].河北农业大学学报,2003,26(3):33-36
丁皓江,谢贻权,何福保.弹性和塑性力学中的有限单元法(修订本) [M].北京:机械工业出版社,1989,111-123
杜建军,廖宗文,毛小云,等.包膜控/缓释肥养分释放特性评价方法的研究[J].磷肥与复肥,2003,(18)2:11-13
范春杰,刘懿善,孟庆春,等.新型颗粒生物有机肥的生产工艺研究[J].齐齐哈尔大学学报,2002,18(3):22-24
范兴亮.新编肥料使用手册[M].中原农民出版社,1999
冯元琦.腐植酸类农药新技术[J].腐植酸,2003,(1):12
傅明华,戴朱恒,承友松,等.上海磷的土壤吸附特征及缓冲性能研究[J].土壤学报,1986,23(2):113-123
关松荫.土壤酶及其研究法[M].北京:农业出版社,1986
郭晓东,张雪芹,杨玲.甘肃省主要农业区土壤对磷的吸附与解吸特征[J].西北农业学报,1997,6(2):7-12
国家环保局编.水和废水监测分析方法[M].北京:中国环境科学出版社,1989
韩文质.腐植酸类肥料对土壤的改良作用及施用方法[J].甘肃农业科技,1997,(6):32-34
赫婧,颜丽,杨凯,等.不同来源腐殖酸的组成和性质的研究[J].土壤通报,2003,(4):343-345
胡红青,贺纪正,李学垣,等.有机酸对酸性土壤吸附磷的影响[J].华中农业大学学报,1997,16(1):37-42
胡红青,贺纪正,李学垣.多种有机酸共存多可变电荷土壤吸附磷德影响[J].植物营养与肥料学报,1999,15(2):122-128
黄彪,吴新华.粉煤灰活性炭处理六价铬废水的试验研究[J].环境科学进展,1998,2(6):77-80
姜建平,孙明强,严玉娟,等.腐植酸系列专用肥德开发与应用[J].磷肥与复肥,2001,16(2):70-71
蒋疆,王果,陈芳育.草炭溶解态有机物质与Pb2+、Zn2+络合稳定性研究[J].福建衣业学报,2002,17(2):125-127
劳家柽.土壤农化分析手册[M].北京:农业出版社,1988:465-475
李光林,魏世强,青长乐.铬在胡敏酸上的吸附动力学和热力学研究[J].土壤学报,2004, 41(1):74-80
李光林,魏世强,青长乐,等.铬在腐殖酸上的吸附与解吸特征研究[J].农业环境科学学报,2003,22(1):34-37
李克斌,刘维屏.重金属离子在腐殖酸上的吸附的研究[J].环境污染与防治,1997,19(1):9-11
李丽.硕士学位论文,风化煤腐殖酸与速效磷肥相互作用的研究[D].太原:中国科学院山西煤炭化学研究所,1999
李善祥.煤炭腐殖酸在农业领域的应用[J].农业环境保护,1996,15(3):136-138
李绪行,邵莉楣,殷蔚,等.黄腐酸和汪平酸对小麦种子萌发与幼苗生长及绿豆下胚轴生根的影响[J].植物学通报,1991,8(3):51-55
梁兰英.紫外分光光度法测定土壤中的硝态氮[J].甘肃环境研究与监测,2001,14(2):80-81
梁宗存,成绍鑫,武丽萍,等.煤中腐殖酸与尿素相互作用机理的研究[J].燃料化学学报,1999,27(2):176-181
梁宗存.煤中腐植酸与尿素反应机理及其产物的组成性质,学位论文[C]. 1997,13(2):233-238
刘翠霞,邓昌亮,徐海宁.龙口褐煤对废水中Cr(Ⅵ)的吸附与还原[J].化工环保,1996,16(6):337-340
刘满红,王如阳.凤鸣村腐殖酸和活性褐煤对Cr(Ⅵ)离子的吸附等温式[J].云南化工,2002,29(2):6-7
刘秀梅,张夫道,冯兆滨,等.风华煤腐殖酸对氮、磷、钾的吸附和解吸特性[J].植物营养与肥料学报,2005,11(5):641-646
卢静,朱琨,赵艳锋,等.腐殖酸在去除水体和土壤中有机污染的作用[J].环境科学与管理,2006,31(8): 151-154
陆欣,王申贵.煤炭腐植酸对石灰性土壤磷酸酶活性的影响[J].腐植酸,1989,(3):41-44
陆欣.煤炭腐植酸脲酶抑制剂应用效果研究[J].腐植酸,1994,(4):10-14
梅慧生,杨玉明,张淑远,等.腐植酸对植物生长的刺激作用[J].植物生理学报,1980,6(2):133-139
倪献智,许志华,曾蒲君.年轻煤硝酸氧解制备硝基腐殖酸的研究[J].煤炭转化,1996,19(2):80-86
彭正萍,门明新,薛世川,等.腐植酸复合肥对土壤养分转化和土壤酶活性的影响[J].河北农业大学学报,2005,28(4):1-4
彭正萍,薛世川,孙志梅.腐殖酸复合肥对油菜品质及生理指标的影响[J].河北农业大学学报,2001,24(1):24-27
全国农业技术推广服务中心.中国有机肥料资源[M].中国农业出版社,1999
任凤莲,宋鸽,孙丽勤.煤中总酸基的测定[J].湖南化工,2000,30(1):40-42
任祖淦,陈玉水,张逸清,等.有机无机肥料配施对土壤微生物和酶活性的影响[J].植物营养与肥料学报,1996,2(3):279-283.
阮建云,马立锋,石元值,等.茶园上壤对氟的吸附与解吸特性[J].茶叶科学,2001,21(2):161-165
芮旻,高乃云,徐斌,等.水中腐殖酸对高级氧化联用技术去除饮用水中内分泌干扰物(DMP)的影响[J].环境科学,2006,27(12): 2495-2501
沈明珠.蔬菜硝酸盐累积的研究[J].园艺学报,1982,9(1):42-47
宋茜萍.腐植酸的开发与应用[J].中国化工,1998,(5):49-50
苏玲,林咸永,章永松,等.水稻土淹水过程中不同土层铁形态德变化及对磷吸附解吸特征的影响[J].浙江大学学报(农业与生命科学版),2001,27(2):124-128
孙克刚,张桂兰,姚健,等.长期不同施肥对潮土中NO3--N累积及作物产量的影响[J].土壤通报,1999,30(6):262-264
孙明强,姜建平,王为民.腐殖酸包裹型长效尿素在水稻土上应用效果研究[J].腐殖酸,2000,(3):23-27
孙瑞莲,赵秉强,朱鲁生,等.长期定位施肥对土壤酶活性的影响及其调控土壤肥力的作用[J].植物营养与肥料学报,2003,9(4):406-410
唐周斌,李晓明,赵嘉平. PGPR菌剂及可溶性腐植酸对经济果林生长的影响[J].山西林业科技,2003(4):1-6
陶著.煤化学[M].冶金工业出版社,1984
汪建飞,李增流,李春泉.土壤NH4+吸附特征的研究[J].安徽农业技术师范学院学报,1998,12(3):1-4
王丹丽,董晓丹,王恩德.针铁矿对重金属离子的吸附作用[J].黄金,2002,23(2):44-46
王国学.腐植酸肥料改土增产效果研究[J].腐植酸,1993,(4):38-40
王建琪,吴文辉,冯大明.电子能谱学引论[M].北京:国防工业出版社,1992
王如阳,王泓,许红波,等.寻甸褐煤腐殖酸对Ni(Ⅱ)的吸附性能试验[J].云南化工,2000,27(3):9-12
王如阳,王泓等.褐煤腐殖酸对Cr(Ⅵ)离子的吸附特性试验[J].云南民族学院学报(自然版),1999,(4):41-44
王树会,张红艳.不同腐植酸用量对烤烟生长及产质的影响[J].中国农学通报,2007,23(1):289-291
王天立.腐植酸的胶体性质,全国第二次腐植酸化学学术讨论会论文集,中国化学会,1981:177-183
王天立.黄腐酸在农业上的应用[J].腐植酸,1992,(1):14
王小岗,凌道盛,徐兴.三维退化梁单元及在扭转问题中的应用[J].固体力学学报,1999,20:245-248
魏景云.褐煤不同处理方法制成的腐殖酸复合肥料增效作用[J].内蒙古农牧学院学报,1998,19(4):74-79
文启孝,张晓华,杜丽娟,等.太湖地区主要土壤中的NH4+及其有效性[J].土壤学报,1998,25(1):22-30
吴玉光.化肥使用指南[M].中国农业出版社,2000
武汉大学等五校编.分析化学[M].北京:人民教育出版社,1978.17-21
谢鹏,蒋剑敏,熊毅.我国几种主要土壤胶体的NH4+吸附特征[J].土壤学报,1998,25(2):175-183
熊又升,陈明亮,喻永熹,等.包膜控释肥料的研究进展[J].湖北农业科学,2000,5:40-42
徐传忠.生产有机-无机复混肥原料腐殖酸的选择及质量指标的测定[J].磷肥与复肥,2006,21(3):45-46
徐明岗.土壤离子吸附[J].土壤肥料,1997(5) :3-7
许秀成,李菂萍,王好斌.包裹型缓释/控制释放肥料专题报告[J].磷肥与复肥,2000,15(3):1-6
薛继澄.保护地栽培蔬菜生理障碍的土壤因子与对策[J].土壤肥料,1991(1):4-9
薛青武、陈培元.灌浆期土壤干旱条件下氮素营养对小麦旗叶光合作用的影响[J].干旱地区农业研究,1989(3):86-93
薛青武.灌浆期土壤干旱条件下氮素营养对小麦旗叶光合作用的影响[J].干旱地区农业研究,1989(3):86-93
薛泉宏,尉庆丰,高彦,等.陕西省几种代表性土壤NH4+吸附、解吸动力学特征研究[J].土壤学报,1996,33(5):130-137
薛世川,韩建民,刘东臣,等.棉用腐殖酸复合肥施用量与机理的研究[J].河北农业大学学报,1998,21(4):21-27
薛泰麟.从土壤脲酶性质的角度探讨尿素合理施用的途径[J].中国农业科学,1991,24(4):61-68
闫娥,孙文风.土壤腐殖质的分析化学性状研究现状[J].青海大学学报(自然科学版),2000,18(5):17-22
闫双堆,卜玉山,刘利军,等.不同腐殖酸物质对土壤中汞的固定作用及植物吸收的影响[J].环境科学学报,2007,27(1):101-105
严昶升主编,土壤肥力研究法[M].农业出版社,1988,274-276
严玉娟,张晓健,孙明强,等.水稻应用腐殖酸包裹型长效尿素效果研究[J].腐殖酸,2001(1):14-16
杨新全,冯锋,宋长青,等.主要农田生态系统氮素行为与氮肥高效利用研究[J].植物营养与肥料学报,2003,9(3):373-376
杨学云,王采绒,戴万红,等.娄土硝酸盐淋失的渗漏池研究[J].西北农业学报,1999,8(6):122-125
叶柄,王虹.应用Langmuir等温式解释我国东北某些土壤对磷酸离子的吸附作用[J].土壤学报,1984,21(1):21-28
于淑芳,杨力,张玉兰,等.长期施肥对土壤腐殖质组成的影响[J].土壤通报,2002,33(3):165-167
于蜀宜,李剑华.用陶土吸附处理含镍废水的处理[J].化工环保,1998,(4):199-202
于天仁,季国亮,丁昌璞.可变电荷土壤的电化学[M].北京:科学出版社,1996,39-134
余贵芬,青长乐,牟树森.汞在腐殖酸上德吸附与解吸特征[J].环境科学学报,2001,21(5):601-606
袁新民,王周琼.硝态氮的淋洗及其影响因素[J].干旱区研究,2000,17(4):46-51
岳廷盛,程家安,马沛岚.褐煤腐殖酸基本性能研究[J].兰州大学学报(自然科学版),1995,31(2):82-85
岳廷盛,唐涤,窦富全.泥炭中腐殖酸含量提高方法研究[J].腐殖酸,1993(2):25-28
岳廷盛,张汉文,王玉琨.褐煤中腐植酸对65Zn2+的吸附与交换[J].铀矿冶,1996,15(4):76-79
岳延盛,解箐雅. NH4+在褐煤腐殖酸中的物理吸附与化学交换[J].铀矿冶,1997,16:62-65
张春兰.氮素形态和和NO3--N和NH4+-N对菠菜生长和品质的影响[J].南京农业大学学报,1990 ,13(3):70-74
张福锁.土壤与植物营养研究新动态(第二卷) [M].中国农业出版社,1995,42-75
张福珠,熊先哲,戴同顺.应用15N研究土壤-植物系统中氮素淋失动态[J].环境科学,1984,8(1):21-24
张怀成,王在峰,李建义,等.褐煤经磺化及碱化处理对重金属离子的吸附性能研究[J].环境化学,1996,18(5):482-487
张梁国,章申.农田氮素淋失进展[J].土壤,1998,6:291-297
张民,杨越超,宋付朋,等.包膜控释肥料研究与产业化开发[J].化肥工业,2005,32(2):7-13
张庆忠,陈欣,沈善敏,等.农田土壤硝酸盐累积与淋失研究进展[J].应用生态学报,2002,13(2):233-238
张淑霞.胡萝卜鲜、干重变化与需肥规律的研究[J].河北农业技术师范学院学报,1997,11(4):30-35
张学才,张德祥.我国德腐植酸资源及其工农业利用[J].中国煤炭,26(12):13-18
张泽丽,王照雄.缓释肥料在水稻土中施用效果研究[J].四川农业大学学报,1995,13(3):259-265
肇溥敏,王宝中.腐殖酸类物质与尿素的复合效应及其对脉酶活性的抑制作用[J].土壤通报,1993,24 (3):135-136
郑剑英.施用氮、磷肥对作物体内养分含量的影响[J].西北植物学报,1996,16(6):56-61
郑平.煤炭腐殖酸的生产和应用[M].北京:化学工业出版社,1991,59-62
郑圣先.控释肥料提高N素利用率作用及对水稻效应的研究[J].植物营养与肥料学报,2001,7(1):11-16
郑兴耗,温贤芳.氮素施用量对土壤硝态氮形成动力学的影响[J].核农学报,1995,9(增刊):41-48
中国科学院山西煤炭化学研究所,北京化工学院.北京农业大学学报,植酸类肥料[M].北京:科学出版社,1979,151-152
周礼恺.土壤酶学[M].北京:科学出版社,1987
周延刚,王瑛.陕西焦坪低变质烟煤硝酸氧解制取硝基腐植酸研究[J].煤炭科学技术,27(3):189-21
朱坚果.硝态氮污染与展望[J].土壤学报,1995,35(增刊):62-69
Addiscott T M. A sample computer model for leaching in structured soils[J]. Soil Sci., 1977,28:554-563.
Akkanen J, Penttinen S, Haitzer Ml. Bioavailablity of atrazine pyrene and benzopyrene in European river waters[J]. Chemosphere, 2001, 45(4): 453-462
Alfassi Z B. On the precipitation of salts/complexes of trivalent cations with humic acid[J]. Journal of Radio analytical and Nuclear Chemistry, 2004, 262 (1): 77-81
Ayuso M, Hernandez Z T, Garcia C A. Comparatives study of the effect on barley growth of humic substances extracted from municipal wastes and from traditional organic materials[J]. Sci. Food Agric. 1996,72(4):493-500
Bergstrom L F, Kirchmann H. Leaching of total nitrogen from nitrogen-15-labelled poultrymanure and inorganic nitrogen fertilizer[J]. J Environ. Qual.,1999,28:1283-1290.
Binay K S, Narendra S R. Comparative sorption equilibriumstudies of toxic phenols On fly ash and impregnated fly ash[J]. J Chem. Tech. Biotechnol.,1994,61:307-317
Boyd G E. The exchange adsorption of ions from aqueous solutions by organic zeolites kineties [J]. Am. Chem. Soc. 1947,69:28-38
Brennan R F, Bolland M D, Jeffery R. C. Phosphorus adsorptlon by a range of Western soils related to soil properties[J] .Commun Soil Sci. Plant Anal, 1994,25:(15-16):2785-2795
California Fertilizer Association . West Fertilizer Handbook Second Horticulture Edition[M]. Interstate Publishers ,Inc,1998,147
Christian A E. Adsorption of iron by a Nigerian brown coal [J]. Fuel ,1994,14(2):132-135.
Cookson W R. Rowarth J S. Cameron K C. The effect of sutumn applied 15N-labelled fertilizer on nitrate leaching in a cultivated soil during winter[J]. Nutri cycling in agroecosystems, 2000,56:99-107
Cordon M K, John F P. Equilibrium parameters for the sorption of copper Cadmium and Zinc ions onto peat[J]. Chem. Tech Biotechnol,1997,69:309-320
Datta A, Sanyal S K, Saha S. A study on natural and synthetic humic acids and their complexing ability towards cadmium[J]. Plant and Soil, 2001, 235: 115-125,
Dean L A. Fixation of soil phosphorus[J]. Adv. Agron, 1949,1:391-411.
Ding G, Novak J M, Amarasiriwardena D, et al. Soil oeganic matter characteristics as affected by tillage management[J]. Soil Sci. Soc. Am. 2002,66:421-429
Donnell R W. The auxin-like effects of humic preparations from leonardite[J]. Soil Sci. 1973,116(2):106-149
Frimmel F H. Humic substances and their role in the environment[J]. John and Sons, 1988:173-179
Gardner B R, Roth R. L. Midrib nitrate concentration as a meansfor nitro-gen needs of Broccoli[J]. J of Plant Nutri, 1989,12(1):111-125
GlannoplitiS G. N. Ries S. Superoxide dismutase:Purification and quantiative relationship with water-soluble protein in seedlings[J]. Plant Physiol,1997,(59):309
Gunasekara A S, Simpson M J, Xing B. Identificationand characterization of sorption domains in soil organic matter using struccturally modified humic acids. Environ[J].. Sci.Technol.,2003,37:852-858
Gunasekara A S, Xing B. Sorption and adsorption of naphthalene by soil orgnic matter: Importance of aromatic and aliphatic components[J]. Environ. Qual. 2003,32:240-246
Haitzer M, Burnison B, Hoss S. Effects of quality and contact time of dissolved organic matter on bioconcentration of benzopyrene in the nematode caenorhabditis elegans[J]. Environ Toxicol Chem, 1999, 18(3): 459-465
Haitzer M, Burnison B, Hoss S. Effects of quality and contact time of dissolved organic matter on bioconcentration of benzopyrene in the nematode caenorhabditis elegans[J]. Environ Toxicol Chem, 1999, 18(3): 459-465
Hansen E M, Djurhuus P. Nitrate leaching as affected by long-term N fertilization on a coarse sand[J]. Soil use and management, 1996, 12:199-204
Havis R N, Alberts E E. Nutrient leaching from field-decomposed corn and sovbean residue under simulated rainfall[J]. Soil Sci. Soc. Am. J, 1993,56:211-218
Havlin J L. westfall D g. Potassium release kinetics and plant response in calcareous soils[J]. Soil Sci. Soc, Am. J. 1985:49:365-370
Joanna Cieslewicz, Slawomir S. Gonet. Properties of humic acids as biomarkets of lake catchment management[J]. Aquatic Sciences. 2004, 66: 178-184
Kang S H. Amarasiriwardena D, Veneman P L, et al. Characterization of ten sequentially extrated humic acids and a humin from a soil in western Massachusetts[J]. Soil Sci. 2003, 168: 880-887
Kay C M, Porter J F. Equilibrium parameters for the sorption of copper, Cadmium and zinc irons onto peat[J]. Chem. Teach Bio Technol. 1997, 69: 309-320
Kiniburgh D G, Syers J K. Specific adsorption of trace amount of Ca and Sr by hydrous oxides of iron and alum in ium [J]. Water Research 1994, 22(3):19-22
Lahav O, Green M. Ammonium Removai using lon Exchange and Biologica Regeneration [J]. Water Research 1998, 32(7):9-11
Li H X, Zhang X M, Liu Y J. Soil components affecting phosphate sorption parameters of acid paddy soils in Guangdong province[J]. Pedosphere, 2000,10:317-321
Liu X B, Han X Z, Song C, et al. Soil organic caebon dynamics in blank soil of China of humic substances by solid-state carbon-13 nuclear magnetic resonance[J]. Soil Sci. Soc. Am.J. 2000,64:873-884
Malcolm R L, Mac C P. Transactions of the 14th intemational congress of Soil[J]. Science 1990,(1):490-491
Mantinez M T, Romero C, Gavilan J M. Characteristics of HA-Ca complexes prepared from lignite humic acids[J]. Fuel. 1983, 62(8):956-958
Marcelo J, Kevin J . Disaggregation kinetics of a peat humic acid : mechanism and pH effects[J]. Environmental. Science. Technology. 2002, 36: 5100-5105
Martin E T. Controlled-release Stabilized Fertilizer in Agriculture[M]. International Fertilizer Industry Association, 1997,61
Matis K A. Zouboulis A I. Sorption of as by goethite particles and study of their flocculation[J]. water Air and Soil Pollution 1998,104(8):33-45
Nandakumar R, Saravanan A, Singaram P, et al. Effect of lignite humic acid on soil nutrient availability at different growth stages of rice grown on vertisols and alfisols[J]. Acta Agronomica Hungarica, 2004, 152(3): 227-235
Ortega E, Cheese C, Knight J. et al. Properties of Alkali active clinoptilolite[J]. Cement and Concrete Research ,2000 , 30: 1641-1646
Ouki S K, Neufeld R D. Use of activated carbon for the recovery of chromium from industrial waste watters[J]. J Chem. Tech. Biotechnol., 1997, 70:3-8
Patter J W, Allen H E, Scala J J. Carbonate heavy metals pollutants[J]. J. Water pollut. 2001,(12):2 397
Pinton R, Varanini Z, Vizzotto G. Soil humic substances effect transport propertise of tonoplast resicles isolated from Oat roots[J]. Plant and Soil. 1992, 142:203-210
Sanders J R, Mcgrath S P. Experimental measurements and computer predictions of copper complex formation by soluble soil organic matter[J]. Environ. Pollu. 1988,49:63-76
Sarah P, Landels C E H. Marketing Research Controlled Release Fertilber[A]. The Chemical Economics Handbook—SRI International[M]. 1994
Schniter M, Khan S U. Humic substances in the environment[M]. New ork:Marcel Dekker,Inc, 1972, 138-142
Sensi N, Rizzi F R, Acquafredda. Fraction dimension of humic acids in aqueous suspensions as a function of pH and time[J]. Soil Sci. Am. J. 1996,60:1773-1780.
Sposito G. Sorption of trace metals by humic materials in soils and waters CRC Crit[J]. Rev. Environ. Ctrl., 1986,16:193-227
Stenberg M, Aronsson H, Linden B, et al. Soil mineral nitrogen and nitrate leaching losses in soil tillage systems combined with a catch crop[J]. Soil and tillage research, 1999,50:115-125.
Syers J K, Iskandar I K. Soil phosphor Chemistry[M] ,1981,571-599
Thorup R M, Mehich A. Retetion of potassium ,meta and orthophosphate by soils and minerals[J] .Soils Sci ,1961 ,91:38-43
Torstensson G, Aronsson H. Nitrogen leaching and crop availability in manured catch crop systemin Sweden[J]. Nutri cycling in agroecosystems,2000,56:139-122
Trenkel M E. Controlled release and stabilized fertilizers in agriculture. IFA, Paris, 1997 Tsutsuki K. Characterization of humic-metal complexes in a buried volcanic ash soil profile and a peat soil[J]. Soil sci. plant Nutr,1992,38(2):297-306
Varanini Z,Pinton R, Debiasi M G. Low Molecular Weight Humic Substances Stimulate H+-ATPase Activity of Plasma Membrane resides Isolated from Oat (Avena Satival L.) Roots[J]. Plant and Soil. 1993,153:61-69
Vaughan D A. Possible Mechanism for Humic acid Action on Cell Elongation in Root Segments of pisum sativum under Aseptic Conditions[J]. Soil Biol. Biochem. 1974,6:241-247
Vaughan D, Linehan D J, The Growth of Wheat Plants in Humic Acid Solution under Axenic Condition[J]. Plant and Soil. 1976,44:445-449
Vaughan D, Ord B G. Uptake and incorporation of 14C- Labeled Soil Organic Matter by Roots of pisum sativum[J]. Exp. Bot. 1981, 32(129):684-687
Viaraghavan T. Use of peat in pollution control[J]. Environ-mental Studies. 1991,37:163-169
Von O B, Kordel W, Klein W, Sorption of nonpolar and polar compounds to soils: processes, measurement an dexperience with the applicability of the modified OECD-guideline[J]. Chemosphere,1991,22:285-304
Wahlberg O, Aren S. Studies of fluvic and humic acids 1.determination of the steady states for slow processes in 0.1M NaCl aqueous solution[J].Acita. chem..Scand,1996,50:561-566
Wang D Y, Qing C L. Effect of humic acid on transport and Transformation of Mercury in soil-plant systems[J].Water, air and soil pollution. 1997,95:35-43
Williams A, Xing B, Veneman P. Effect of cultivation on soil organic matter and aggregatedstability[J]. Pedosphere. 2005,15(2):255-262
Wu J, Laird D A, Thompson M L. Sorption and desorption of copper on soil clay component[J]. Journal of Environmental Quality. 1999,28(1):334-338
Xing B S, Liu J D, Liu X B, et al. Extraction and characterization of humic acids and humin fractions from a black soil of China[J]. Pedosphere, 2005,15(1) : 1-8
Xing B, Liu X, Liu J, et al. Physical and chemical characteristics of a typical Mollisol in china. Commun[J]. Soil Sci. Plant Anal. 2004,35:1829-1838
Xu J M, Yuan K W. Dissolution and fraction of calcium-bound and iron and aluminum-bound humus in soils[J]. Pedosphere, 1993,3:45-80
Yang C M, Wang M C, Lu Y F, et al. Humic substances affect the activity of chlorophyllase[J]. Journal of Chemical Ecology, 2004, 30(5): 1057-1065
Zorpas A, Constantinides T, Mysside A. G. Heavy metals uptake by natural zeolite and metals [J]. Soils Sci.,1978,81:31-33