键合型强荧光稀土聚合物的设计合成与性能研究
|
摘要
稀土聚合物由于兼具稀土离子发光强度高、色纯度高和高分子材料优良的加工性能等优点而倍受瞩目。以化学键结合的形式将稀土配合物与聚合物连结在一起,生成的键合型的稀土聚合物,可以使稀土配合物均匀地分布在聚合物基体中,在稀土含量较高时仍具有优良的荧光性能,而且其荧光强度随稀土离子含量的增加而增强,呈现出线性递增的现象。目前,多数研究利用丙烯酸与稀土的键合作用将C=C双键引入到稀土配合物中,再与甲基丙烯酸甲酯、苯乙烯等烯类单体共聚,制得键合型的稀土高分子复合材料。但应当指出,这些键合型的复合材料中,丙烯酸类配体对稀土离子的荧光发射贡献不明显,但是却占用了稀土离子的一部分配位数,明显影响了材料的荧光性能。本文旨在通过多功能配体的设计来合成具有高荧光强度的稀土聚合物,发展高性能稀土聚合物发光材料的合成与制备方法。论文的主要内容如下：
1)针对邻菲罗啉和8-羟基喹啉配体具有刚性大、吸光系数大、配位能力强等特点,设计合成了基于这两种物质的多功能配体——5-丙烯酰胺基-1,10-邻菲罗啉(Aphen)和5-丙烯酰氧乙氧基甲基-8-羟基喹啉(Hamq),并对合成工艺进行了优化。分别实验考察了两种配体的荧光发射光谱及低温磷光光谱,发现两者都具有具有较强的向稀土离子能量转移的趋势,它们的最低三重态能级分别为20000和22370 cm-1,与Eu3+离子的共振发射能级(5D0,17200 cm-1)具有良好匹配,其中,配体Aphen的匹配程度优于Hamq。
2)研究了系列配合物Eu(β-diketone)3(Aphen)、Eu(TTA)2(amq)、Eu(TTA)3(H2O)2、Eu(TTA)2(AA)的光物理性能(光色纯度、荧光强度、荧光寿命、量子效率等),发现在Eu(β-diketone)3 (Aphen)系列配合物中,Eu(TTA)3(Aphen)的荧光性能最强(荧光寿命、量子产率分别为590μs、40.1%),其5D0→7F2跃迁的荧光发射强度分别为配合物Eu(TTA)3(H2O)2、Eu(TTA)2(AA)和Eu(TTA)2(amq)的4.5、11.3和3.9倍。指出丙烯酸配体AA对Eu3+离子的发光基本不起作用,而配位水分子则对Eu3+离子的发光起到荧光猝灭作用,揭示了配体Aphen、Hamq敏化Eu3+离子发光的Antenna效应、协同效应。
3)通过强荧光稀土配合物单体Eu(TTA)3(Aphen)、Eu(TTA)2(amq)分别与MMA的共聚合反应成功地合成了基于邻菲罗啉和8-羟基喹啉衍生物的键合型强荧光稀土聚合物复合发光材料。实验考察了稀土聚合物的红外光谱、紫外光谱、核磁共振氢谱、分子量及其分布、热稳定性、荧光寿命、荧光激发及发射光谱,发现：①稀土配合物单体具有良好的共聚合性能,其结构单元在聚合及提纯过程中不容易解离；②稀土配合物结构单元的引入有助于提高共聚物的热稳定性及玻璃化转变温度；③共聚物中甲基丙烯酸甲酯单元虽参与配位,但是起能量传递作用的主要物质依然是TTA；④共聚物的荧光同样表现为稀土离子的特征发射,均观测到5D0→7FJ(J=0-4)的跃迁,其中5D0→7F2跃迁的强度最大,在所研究的Eu含量范围内,共聚物荧光强度随Eu含量增加而增大,没有出现明显的荧光猝灭现象。指出共聚物荧光性能的提高与配合物结构单元在聚合物基质中所处的微环境有关：一方面由于甲基丙烯酸甲酯单元参与配位,使得稀土配位趋于饱和,从而荧光性能大为增强；另一方面由于配合物单体与MMA共聚后,每一个配合物单元都被PMMA柔韧链围绕,而且还可能被高分子链扭曲,稀土离子就象被圈在聚合物的笼子中一样,产生所谓的“笼蔽效应”,在这种特殊的构象下,稀土小分子配合物单元之间的相互作用变得非常微弱,稀土离子的聚集体不容易生成,同时由于高分子链的介入,更进一步降低了Eu3+的对称性,增加了5D0→7F2跃迁的可能性。
4)在Eu(TTA)2(amq)/PMMA的共混体系中,当Eu的含量较低时,共混物的荧光强度随Eu含量的增加而增强,基本呈现了良好的线性关系,当Eu%=3.30wt%时,荧光强度值达到最大,在此以后,随Eu%的增加荧光强度逐渐降低,出现荧光猝灭现象。
The rare earth polymer materials have attracted considerable interests for their good luminescent characteristics, high color purity of rare earths and the excellent processability of polymers. The bonding-type rare earth polymers in which the lanthanide complexes are covalently bound in the main chain would cause the lanthanide complexes to distribute evenly in the polymer marixes, and could still maintain the luminescence intensity when the rare earth metal content is high. Furthermore, the luminescence intensities of the polymers increase linearly with an increase in the rare earth content. Up to now most of the approaches to bind a lanthanide complex to a polymer backbone take advantage of a polymerizable ligand such as acrylic acid. But it should be noted that the acrylic acid ligand makes little contribution to the luminescence of the complexes, and occupies the coordination number of rare earth ions, which would significantly affect the luminescence properties of the polymers. This thesis aims to synthesize highly luminescent rare earth polymers through the design of multifunctional ligands, and to develop the synthesis and preparation methods for the rare earth polymer luminescent materials with high performance. The following results have been achieved:
1) Two multi-functional ligands,5-acrylamido-1,10-phenanthroline (Aphen) and 5-acryloxyethoxymethyl-8-hydroxyquinoline (Hamq), were designed and synthesized, and their synthesis processes were optimized. Our design is based upon the fact that the ligands phenanthroline and 8-hydroxyquinoline have characteristics of big rigid planar, large absorption coefficient, and strong coordination. The luminescence emission spectra and the low temperature phosphorescence spectra of the two ligands were studied, and the experimental results showed that they have a strong tendency of energy transfer to the rare earth ion, and that the triplet state energies of Aphen and Hamq were 20000 and 22370 cm-1, respectively, which are much higher in energy than the resonance levels of Eu3+(5D0, 17200 cm-1), indicating that the triplet state energies of the two ligand are suitable for the sensitization of the luminescence of Eu3+, especially Aphen.
2) The photophysical properties (color purity, luminescence intensity, lifetime, and quantum yield) of a series Eu(β-diketone)3(Aphen) complexes, complex Eu(TTA)2(amq), Eu(TTA)3(H2O)2 and Eu(TTA)2(AA) were investigated. The results showed that the complex Eu(TTA)3(Aphen) has the strongest luminescence emission among the series Eu(β-diketone)3(Aphen) complexes, and its luminescence intensity of 5D0→7F2 transition is 4.5, 11.3, and 3.9 times as high as that of Eu(TTA)3(H2O)2、Eu(TTA)2(AA) and Eu(TTA)2(amq), respectively, indicating that the acrylic acid ligand plays little or no role in the luminescence of Eu(TTA)2(AA) and the coordinated water molecules can effectively quench the luminescence intensity of Eu(TTA)3(H2O)2, and that the ligands Aphen and Hamq can sensitize the luminescence of Eu(Ⅲ) ion efficiently.
3) Highly luminescent bonding-type Eu-containing copolymers were synthesized through the copolymerization of Eu(TTA)3(Aphen) or Eu(TTA)2(amq) with MMA, and characterized by FT-IR, UV-Vis,1H NMR, GPC, TGA, DSC, lifetime, and luminescence excitation and emission spectra. The results indicated that the Eu-complex moieties are directly bonded to the polymer backbone as an integrated unit, and the dissociation of the complex unit is negligible during the copolymerization and purification processes, that the thermal stabilities and the glass transition temperatures of the copolymers are enhanced upon the introduction of the Eu-complex moiety into the polymer chain, that the energy transfer is still mainly from the coordinated TTA although the MMA unit has taken part in the coordination, and that the copolymers all display the characteristic emissions of Eu(III) ions and five narrow emission peaks centered at 579,591, 612,651 and 698 nm, assigned to the 5D0→7F0,5D0→7F1,5D0→7F2,5D0→7F3,5D0→7F4 transitions, respectively, are well resolved, and the hypersensitive 5Do→7F2 transition is very intense. The luminescence intensities of the copolymers increased with an increase in the Eu content, and no significant concentration quenching phenomenon was observed at the Eu content within the studied range. The improvement of the luminescence properties for the copolymers may be attributed to the special microenvironment. On the one hand, the coordination stability of the Eu-complex unit in the copolymer is improved because the coordination degree of the unsaturated Eu-complex unit is satisfied through the intra- and intermolecular coordination, which results in the decrease of nonradiative decay rate of the excited levels of Eu(III) ion and the increase of the luminescence lifetime. On the other hand, the Eu-complex units can be twisted or distorted by the surrounding polymer chain, as the rare earth ions are kept in cages in the same polymer, resulting in so-called "cage effect". This may further lower the symmetry of the Eu(III) ion and consequently enhance the 5D0→7F2 transition of Eu-copolymers.
4) In the Eu(TTA)2(amq)/PMMA blend system, the luminescence intensity increases with the increase in the Eu content and reaches a maximum at 3.30 wt% and then exhibits typical emission concentration quenching on further increase in the Eu content.
1)针对邻菲罗啉和8-羟基喹啉配体具有刚性大、吸光系数大、配位能力强等特点,设计合成了基于这两种物质的多功能配体——5-丙烯酰胺基-1,10-邻菲罗啉(Aphen)和5-丙烯酰氧乙氧基甲基-8-羟基喹啉(Hamq),并对合成工艺进行了优化。分别实验考察了两种配体的荧光发射光谱及低温磷光光谱,发现两者都具有具有较强的向稀土离子能量转移的趋势,它们的最低三重态能级分别为20000和22370 cm-1,与Eu3+离子的共振发射能级(5D0,17200 cm-1)具有良好匹配,其中,配体Aphen的匹配程度优于Hamq。
2)研究了系列配合物Eu(β-diketone)3(Aphen)、Eu(TTA)2(amq)、Eu(TTA)3(H2O)2、Eu(TTA)2(AA)的光物理性能(光色纯度、荧光强度、荧光寿命、量子效率等),发现在Eu(β-diketone)3 (Aphen)系列配合物中,Eu(TTA)3(Aphen)的荧光性能最强(荧光寿命、量子产率分别为590μs、40.1%),其5D0→7F2跃迁的荧光发射强度分别为配合物Eu(TTA)3(H2O)2、Eu(TTA)2(AA)和Eu(TTA)2(amq)的4.5、11.3和3.9倍。指出丙烯酸配体AA对Eu3+离子的发光基本不起作用,而配位水分子则对Eu3+离子的发光起到荧光猝灭作用,揭示了配体Aphen、Hamq敏化Eu3+离子发光的Antenna效应、协同效应。
3)通过强荧光稀土配合物单体Eu(TTA)3(Aphen)、Eu(TTA)2(amq)分别与MMA的共聚合反应成功地合成了基于邻菲罗啉和8-羟基喹啉衍生物的键合型强荧光稀土聚合物复合发光材料。实验考察了稀土聚合物的红外光谱、紫外光谱、核磁共振氢谱、分子量及其分布、热稳定性、荧光寿命、荧光激发及发射光谱,发现：①稀土配合物单体具有良好的共聚合性能,其结构单元在聚合及提纯过程中不容易解离；②稀土配合物结构单元的引入有助于提高共聚物的热稳定性及玻璃化转变温度；③共聚物中甲基丙烯酸甲酯单元虽参与配位,但是起能量传递作用的主要物质依然是TTA；④共聚物的荧光同样表现为稀土离子的特征发射,均观测到5D0→7FJ(J=0-4)的跃迁,其中5D0→7F2跃迁的强度最大,在所研究的Eu含量范围内,共聚物荧光强度随Eu含量增加而增大,没有出现明显的荧光猝灭现象。指出共聚物荧光性能的提高与配合物结构单元在聚合物基质中所处的微环境有关：一方面由于甲基丙烯酸甲酯单元参与配位,使得稀土配位趋于饱和,从而荧光性能大为增强；另一方面由于配合物单体与MMA共聚后,每一个配合物单元都被PMMA柔韧链围绕,而且还可能被高分子链扭曲,稀土离子就象被圈在聚合物的笼子中一样,产生所谓的“笼蔽效应”,在这种特殊的构象下,稀土小分子配合物单元之间的相互作用变得非常微弱,稀土离子的聚集体不容易生成,同时由于高分子链的介入,更进一步降低了Eu3+的对称性,增加了5D0→7F2跃迁的可能性。
4)在Eu(TTA)2(amq)/PMMA的共混体系中,当Eu的含量较低时,共混物的荧光强度随Eu含量的增加而增强,基本呈现了良好的线性关系,当Eu%=3.30wt%时,荧光强度值达到最大,在此以后,随Eu%的增加荧光强度逐渐降低,出现荧光猝灭现象。
The rare earth polymer materials have attracted considerable interests for their good luminescent characteristics, high color purity of rare earths and the excellent processability of polymers. The bonding-type rare earth polymers in which the lanthanide complexes are covalently bound in the main chain would cause the lanthanide complexes to distribute evenly in the polymer marixes, and could still maintain the luminescence intensity when the rare earth metal content is high. Furthermore, the luminescence intensities of the polymers increase linearly with an increase in the rare earth content. Up to now most of the approaches to bind a lanthanide complex to a polymer backbone take advantage of a polymerizable ligand such as acrylic acid. But it should be noted that the acrylic acid ligand makes little contribution to the luminescence of the complexes, and occupies the coordination number of rare earth ions, which would significantly affect the luminescence properties of the polymers. This thesis aims to synthesize highly luminescent rare earth polymers through the design of multifunctional ligands, and to develop the synthesis and preparation methods for the rare earth polymer luminescent materials with high performance. The following results have been achieved:
1) Two multi-functional ligands,5-acrylamido-1,10-phenanthroline (Aphen) and 5-acryloxyethoxymethyl-8-hydroxyquinoline (Hamq), were designed and synthesized, and their synthesis processes were optimized. Our design is based upon the fact that the ligands phenanthroline and 8-hydroxyquinoline have characteristics of big rigid planar, large absorption coefficient, and strong coordination. The luminescence emission spectra and the low temperature phosphorescence spectra of the two ligands were studied, and the experimental results showed that they have a strong tendency of energy transfer to the rare earth ion, and that the triplet state energies of Aphen and Hamq were 20000 and 22370 cm-1, respectively, which are much higher in energy than the resonance levels of Eu3+(5D0, 17200 cm-1), indicating that the triplet state energies of the two ligand are suitable for the sensitization of the luminescence of Eu3+, especially Aphen.
2) The photophysical properties (color purity, luminescence intensity, lifetime, and quantum yield) of a series Eu(β-diketone)3(Aphen) complexes, complex Eu(TTA)2(amq), Eu(TTA)3(H2O)2 and Eu(TTA)2(AA) were investigated. The results showed that the complex Eu(TTA)3(Aphen) has the strongest luminescence emission among the series Eu(β-diketone)3(Aphen) complexes, and its luminescence intensity of 5D0→7F2 transition is 4.5, 11.3, and 3.9 times as high as that of Eu(TTA)3(H2O)2、Eu(TTA)2(AA) and Eu(TTA)2(amq), respectively, indicating that the acrylic acid ligand plays little or no role in the luminescence of Eu(TTA)2(AA) and the coordinated water molecules can effectively quench the luminescence intensity of Eu(TTA)3(H2O)2, and that the ligands Aphen and Hamq can sensitize the luminescence of Eu(Ⅲ) ion efficiently.
3) Highly luminescent bonding-type Eu-containing copolymers were synthesized through the copolymerization of Eu(TTA)3(Aphen) or Eu(TTA)2(amq) with MMA, and characterized by FT-IR, UV-Vis,1H NMR, GPC, TGA, DSC, lifetime, and luminescence excitation and emission spectra. The results indicated that the Eu-complex moieties are directly bonded to the polymer backbone as an integrated unit, and the dissociation of the complex unit is negligible during the copolymerization and purification processes, that the thermal stabilities and the glass transition temperatures of the copolymers are enhanced upon the introduction of the Eu-complex moiety into the polymer chain, that the energy transfer is still mainly from the coordinated TTA although the MMA unit has taken part in the coordination, and that the copolymers all display the characteristic emissions of Eu(III) ions and five narrow emission peaks centered at 579,591, 612,651 and 698 nm, assigned to the 5D0→7F0,5D0→7F1,5D0→7F2,5D0→7F3,5D0→7F4 transitions, respectively, are well resolved, and the hypersensitive 5Do→7F2 transition is very intense. The luminescence intensities of the copolymers increased with an increase in the Eu content, and no significant concentration quenching phenomenon was observed at the Eu content within the studied range. The improvement of the luminescence properties for the copolymers may be attributed to the special microenvironment. On the one hand, the coordination stability of the Eu-complex unit in the copolymer is improved because the coordination degree of the unsaturated Eu-complex unit is satisfied through the intra- and intermolecular coordination, which results in the decrease of nonradiative decay rate of the excited levels of Eu(III) ion and the increase of the luminescence lifetime. On the other hand, the Eu-complex units can be twisted or distorted by the surrounding polymer chain, as the rare earth ions are kept in cages in the same polymer, resulting in so-called "cage effect". This may further lower the symmetry of the Eu(III) ion and consequently enhance the 5D0→7F2 transition of Eu-copolymers.
4) In the Eu(TTA)2(amq)/PMMA blend system, the luminescence intensity increases with the increase in the Eu content and reaches a maximum at 3.30 wt% and then exhibits typical emission concentration quenching on further increase in the Eu content.
引文
[1]Weissman S. I. Intramolecular energy transfer:The fluorescence of complexes of europium [J]. Journal of Chemical Physics,1942,10(4):214-217.
[2]Schimitschek E. J., Schwarz E. G. K. Organometallic compounds as possible laser materials [J]. Nature,1962,196(4857):832-833.
[3]Sato S., Wada M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates [J]. Bulletin of the Chemical Society of Japan, 1970,43(7):1995-1962.
[4]Lempicki A., Samelson H. Optical maser action in europium benzoylacetonate [J]. Physics Letters,1963,4(2):133-135.
[5]Bhaumik M. L., Telk C. L. Fluorescence quantum efficiency of rare-earth chelates [J]. Journal of the Optical Society of America,1964,54(10):1211-1214.
[6]Bhaumik M. L., Fletcher P. C., Nugent L. J., Lee S. M., Higa S., Telk C. L., Weinberg M. Laser emission from a europium benzoylacetonate alcohol solution [J]. Journal of Physical Chemistry,1964,68(6):1490-1493.
[7]Bhaumik M. L., El-Sayed M. A. Studies on the triplet-triplet energy transfer to rare earth chelates [J]. Journal of Physical Chemistry,1965,69(1):275-280.
[8]Hinckley C. C. Paramagnetic shifts in solutions of cholesterol and the dipyridine adduct of trisdipivalomethanatoeuropium(III). A shift reagent [J]. Journal of the American Chemical Society,1969,91(18):5160-5162.
[9]王冬梅.含稀土配合物聚合物透明材料的设计合成与发光性质研究[D].吉林大学.2004.
[10]Lamola A. A., Hammond G. S. Mechanisms of photochemical reactions in solution: Intersystem crossing efficiencies [J]. Journal of Chemical Physics,1965,43(6):2129-2135.
[11]Matsuda Y., Makishima S., Shionoya S. Intramolecular energy transfer in europium chelates due to excitation of the triplet state [J]. Bulletin of the Chemical Society of Japan, 1968,41(7):1513-1518.
[12]Mikula J. J., Salomon R. E. Deuterium isotope effects on the luminescence of terbium and europium chelates [J]. Journal of Chemical Physics,1968,48(3):1077-1085.
[13]Gallagher P. K., Heller A., Wasserman E. Two-step energy transfer in solution [J]. Journal of Chemical Physics,1964,41(12):3921-3924.
[14]Meares C. F., Wensel T. G. Metal chelates as probes of biological systems [J]. Accounts of Chemical Research,1984,17(6):202-209.
[15]Kolodner P., Tyson J. A. Remote thermal imaging with 0.7-μm spatial resolution using temperature-dependent fluorescent thin flims [J]. Applied Physics Letters,1983,42(1): 117-119.
[16]Kolodner P., Tyson J. A. Microscopic fluorescent imaging of surface temperature profiles with 0.01℃ resolution [J]. Applied Physics Letters,1982,40(9):782-784.
[17]Matthews L. R., Knobbe E. T. Luminescence behavior of europium complexes in sol-gel derived host materials [J]. Chemistry of Materials,1993,5(12):1697-1700.
[18]Jin T., Tsutsumi S., Deguchi Y., Machida K., Adachi G. Luminescence property of the terbium bipyridyl complex incorporated in silica matrix by a sol-gel method [J]. Journal of the Electrochemical Society,1995,142(10):L195-L197.
[19]Wang K. Z., huang C. H., Xu G. X., Zhao X. S., Xia X. H., Wu N. Z., Xu L. G., Li T. K. Optical properties of Langmuir-Blodgett film of hemicyanine containing the rare earth complex anion Dy(BPMPHD)2-[J]. Thin Solid Films,1994,252(2):139-144.
[20]Zhou D. J., Huang C. H., Wang K. Z., Xu G. X., Zhao X. S., Xie X. M., Xu L. G., Li T. K. Langmuir-Blodgett film and second harmonic generation of a europium hemicyanine complex, Me2NC6H4CH=CHC5H4NC16H33+Eu(NTA)4-[J]. Langmuir,1994,10(6): 1910-1912.
[21]Kido J., Nagai K., Okamoto Y., Skotheim T. Electroluminescence from polysilane film doped with europium complex [J]. Chemistry Letters,1991,20(7):1267-1270.
[22]Kido J., Hayase H., Hongawa K., Nagai K., Okuyama K. Bright red light-emitting organic electroluminescent devices having a europium complex as an emitter [J]. Applied Physics Letters,1994,65(17):2124-2126.
[23]Sawada T., Ando S. Synthesis, characterization, and optical properties of metal-containing fluorinated polyimide films [J]. Chemistry of Materials,1998,10(11):3368-3378.
[24]Wang L. H., Wang W., Zhang W. G., Kang E. T., Huang W. Synthesis and luminescence properties of novel Eu-containing copolymers consisting of Eu(Ⅲ)-acrylate-β-diketonate complex monomers and methyl methacrylate [J]. Chemistry of Materials,2000,12(8): 2212-2218.
[25]Yang C. Y., Srdanov V., Robinson M. R., Bazan G. C., Heeger A. J. Orienting Eu(dnm)3phen by tensile drawing in polyetnylene:Eu3+ emission [J]. Advanced Materials, 2002,14(13-14):980-983.
[26]Cong Y., Fu J., Cheng Z., Li J., Han Y., Lin J. Self-organization and luminescent properties of nanostructured europium (Ⅲ)-block copolymer complex thin films [J]. Journal of Polymer Science Part B:Polymer Physics,2005,43:2181-5189.
[27]de Bettencourt-Dias A., Viswanathan S., Rollett A. Thiophene-derivatized pybox and its highly luminescent lanthanide ion complexes [J]. Journal of the American Chemical Society, 2007,129:15436-15437.
[28]Chen X.-Y., Yang X., Holliday B. J. Photoluminescent europium-containing inner sphere conducting metallopolymer [J]. Journal of the American Chemical Society,2008,130: 1546-1547.
[29]苏锵.稀土有机化合物的发光与能量传递[J].发光学报,1986,7(1)：1-5.
[30]李文连.稀土有机配合物发光研究的新进展[J].化学通报,1991,8：1-9.
[31]李文连.稀土有机电致发光研究进展[J].中国稀土学报,1999,17(3)：267-270.
[32]杨迟,杨燕生.发光镧系超分子的设计及应用[J].大学化学,1995,10(1)：6-10.
[33]苏庆德,孙燕.稀土有机配合物发光及光声光谱研究方[J].稀土,1997,18(6)：56-60.
[34]Weibel N., Charbonniere L. J., Guardigli M., Roda A., Ziessel R. Engineering of highly luminescent lanthanide tags suitable for protein labeling and time-resolved luminescence imaging [J]. Journal of the American Chemical Society,2004,126(15):4888-4896.
[35]Woods M., Sherry A. D. Synthesis and luminescence studies of aryl substituted tetraamide complexes of europium (Ⅲ):A new approach to pH responsive luminescent europium probes [J]. Inorganic Chemistry,2003,42(14):4401-4408.
[36]Hanaoka K., Kikuchi K., Kobayashi S., Nagano T. Time-resolved long-lived luminescence imaging method employing luminescent lanthanide probes with a new microscopy system [J]. Journal of the American Chemical Society,2007,129(44):13502-13509.
[37]Yamada T., Shinoda S., Sugimoto H., Uenishi J., Tsukube H. Luminescent lanthanide complexes with stereocontrolled tris(2-pyridylmethyl)amine ligands:Chirality effects on lanthanide Complexation and luminescence properties [J]. Inorganic Chemistry,2003. 42(24):7932-7937.
[38]Sabbatini N., Guardigli M., Lehn J. M. Luminescent lanthanide complexes as photochemical supramolecular devices [J]. Coordination Chemistry Reviews,1993.123: 201-228.
[39]Dexter D. L. A theory of sensitized luminescence in solids [J]. Journal of Chemical Physics, 1953,21(5):836-850.
[40]Crosby G. A., Whan R. E., Alire R. M. Intramolecular energy transfer in rare earth chelates. Role of the triplet state [J]. Journal of Chemical Physics,1961,34(3):743-748.
[41]Bhaumik M. L., Nugent L. J. Time-resolved spectroscopy of europium chelates [J]. Journal of Chemical Physics,1965,43:1680-1687.
[42]M. Kleinerman, Energy migration in lanthanide chelates[J]. Journal of Chemical Physics, 1969,51:2370-2381.
[43]Buono-core G. E., Li H., Marciniak B. Quenching of excited states by lanthanide ions and chelates in solution [J]. Coordination Chemistry Reviews,1990,99:55-87.
[44]李建宇.稀土发光材料及其应用[M].北京：化学工业出版社,2003.
[45]Tobita S., Arakawa M., Tanaka I. Electronic relaxation processes of rare earth chelates of benzoyltrifluoroacetone [J]. Journal of Physical Chemistry,1984,88(13):2697-2702.
[46]Chen C. H., Shi J. M. Metal chelates as emitting materials for organic electroluminescence, [J]. Coordination Chemistry Reviews,1998,171:161-174.
[47]黄春辉,李富友,黄维.有机电致发光材料与器件导论[M].上海：复旦大学出版社,2005.
[48]Whan R. E., Crosby G. A. Luminescence studies of rare earth complexes: Benzoylacetonate and dibenzoylmethide chelates [J]. Journal of Molecular Spectroscopy, 1962,8(1-6):315-327.
[49]黄春辉.稀土配位化学[M].北京：科学技术出版社,1997.
[50]Carnall W. T. Handbook of the Physics and Chemistry of Rare Earths [M]. Vol.3, Northholland, Amsterdam,1979.
[51]Brennetot R., Georges J. Investigation of chelate formation, intramolecular energy transfer and luminescence efficiency and lifetimes in the Eu-thenoyltrifluoroacetone-trioctylphosphine oxide-Triton X-100 system using absorbance, fluorescence and photothermal measurements [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2000,56(4):703-715.
[52]Yan B., Zhang H., Wang S., Ni J. Intramolecular energy transfer mechanism between ligands in ternary rare earth complexes with aromatic carboxylic acids and 1,10-phenanthroline [J]. Journal of Photochemistry and Photobiology A:Chemistry,1998, 116(3):209-214.
[53]Renaud F., Piguet C., Bernardinelli G, Bunzli J.-C. G., Hopfgartner G. Nine-coordinate lanthanide podates with predetermined structural and electronic properties:Facial organization of unsymmetrical tridentate binding units by a protonated covalent tripod [J]. Journal of the American Chemical Society,1999,121(40):9326-9342.
[54]Sato S., Wada M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates [J]. Bulletin of the Chemical Society of Japan, 1970,43(7):1955-1962.
[55]王薇.多酰胺型配体及其稀土配合物的合成、表征及荧光性能研究[D].兰州大学.2007.
[56]Crosby G A., Whan R. E., Freeman J. J. Spectroscopic studies of rare earth chelates [J]. Journal of Physical Chemistry,1962,66(12):2493-2499.
[57]Khreis O. M., Curry R. J., Somerton M., Gillin W. P. Infrared organic light emitting diodes using neodymium tris-(8-hydroxyquinoline) [J]. Journal of Applied Physics,2000,88: 777-780.
[58]苏锵.稀土化学[M].郑州：河南科技出版社,1993：269-284.
[59]Yang Y. S., Gong M. L., Li Y. Y. Effects of the structure of ligands and their Ln3+ complexes on the luminescence of the central Ln3+ ions [J]. Journal of Alloys and Compounds,1994,207-208:112-114.
[60]Brito H. F., Malta O. L., Felinto M. C. F. C., Teotonio E. E. S., Menezes J. F. S., Silva C. F. B., Tomiyama C. S., Carvalho C. A. A. Luminescence investigation of the Sm(III)-β-diketonates with sulfoxides, phosphine oxides and amides ligands [J]. Journal of Alloys and Compounds,2002,344(1-2):293-297.
[61]Tang B., Jin L. P., Zheng X. J., Zhu L. Y. Photoluminescence enhancement of Eu3+ in the Ei3+-dibenzoylmethide-oligomer (styrene-co-acrylic acid) ternary composite [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,1999,55(9): 1731-1736.
[62]Xu C. J., Yang H., Xie F., Guo X. Z. Photoluminescence enhancement of Sm3+ in the Sm3+-salicylic acid-o-phenanthroline ternary composite [J]. Journal of Alloys and Compounds, 2005,392(1-2):96-99.
[63]汪祖成,蔡汝秀,张华山.稀土元素分析化学[M].北京：科学出版社,2000：222-253.
[64]Yan B., Zhang H. J., Wang S. B., Ni J. Z. Photophysical properties of rare earth complexes with 3,4-furandicarboxylic acid and 1,10-phenanthroline [J]. Journal of Rare Earths,1999, 17(1):16-19.
[65]林惠文,朱文祥.铕(Ⅲ)-β-二酮-4,4'-联吡啶-N,N'-二氧化物三元配合物的合成与表征[J].高等学校化学学报,1996,17(10)：1516-1518.
[66]Zhao Y. L., Zhao F. Y. Synthesis and luminescence of complexes EuxY1-x(Phen)L3 [J]. Journal of Rare Earths,2002,20(5):427-429.
[67]Panigrahi B. S., Peter S., Viswanathan K. S. Cofluorescence of Eu3+ in complexes of aromatic carboxylic acids [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,1997,53:2579-2585.
[68]Xu C. J., Xie F., Guo X. Z., Yang H. Synthesis and cofluorescence of Eu(Y) complexes with salicylic acid and o-phenanthroline, Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2005,61:2005-2008.
[69]刘铭钊,杨展澜,张莉,翁诗甫,吴瑾光.配合物Eu XM(1-X)(TTA)3(H2O)2 (M=La, Gd)光致发光特性[J].物理化学学报,2001,17(9)：797-801.
[70]徐存进.铕(钆)-水杨酸-邻菲罗啉配合物的合成及光致发光性能[J].中国稀土学报.2006,24(3)：361-365.
[71]周忠诚.光致发光稀土(铕、铽)配合物的合成、荧光性能及理论研究[D].中南大学.2002.
[72]Murray G. M., Pesterfield L. L., Stump N. A., Schweitzer G. K. Effects of inorganic countercations on the fluorescence spectra of the tetrakis(1-phenyl-1,3-butanedionato)europium(Ⅲ) anion [J]. Inorganic Chemistry,1989, 28(10):1994-1998.
[73]Fu Y. J., Wong T. K. S., Yan Y. K., Hu X. Syntheses, structures and luminescent properties of Sm (Ⅲ) and Eu (Ⅲ) chelates for organic electroluminescent device applications [J]. Journal of Alloys and Compounds,2003,358:235-244.
[74]de Sa G. F., Malta O. L., Donega C. M., Simas A. M., Longo R. L., Santa-Cruz P. A., da Silva E. F., Jr. Spectroscopic properties and design of highly luminescent lanthanide coordination complexes [J]. Coordination Chemistry Reviews,2000,196(1):165-195.
[75]Malta O. L., Brito H. F., Menezes J. F. S., Silva F. R. G., Donega C. M., Alves S., Jr. Experimental and theoretical emission quantum yield in the compound Eu(thenoyltrifluoroacetonate)3·2(dibenzyl sulfoxide) [J]. Chemical Physics Letters.1998, 282:233-238.
[76]Brito H. F., Malta O. L., Felinto M. C. F. C., Teotonio E. E. S., Menezes J. F. S., Silva C. F. B., Tomiyama C. S., Carvalho C. A. A. Luminescence investigation of the Sm(III)-β-diketonates with sulfoxides, phosphine oxides and amides ligands [J]. Journal of Alloys and Compounds,2002,344:293-297.
[77]安保礼,罗一帆,叶剑清,麦堪成,石建新,龚孟濂.稀土配合物Na3Eu(DPA)3掺杂的PMMA树脂的制备及其发光性能[J].中国稀土学报,2001,19(3)：268-271.
[78]李勇,高新,邓振波,徐怡庄,高宏成,吴瑾光,徐叙瑢.苯甲酰水杨酸的制备及其与稀土络合物光致发光现象研究[J].中国稀土学报,2001,19(6)：548-551.
[79]Erostya k J., Buzady A., Hornyak I., Kozma L. Sensitized luminescence of the Eu3+/La3+/cinnamic acid mixed complex:comparison to the Eu3+/Gd3+/cinnamic acid mixed complex [J]. Journal of Photochemistry and Photobiology A:Chemistry,1999,121:43-48.
[80]Yu X., Su Q. Photoacoustic and luminescence properties study on energy transfer and relaxation processes of Tb(III) complexes with benzoic acid [J]. Journal of Photochemistry and Photobiology A:Chemistry,2003,155:73-78.
[81]Yan B., Zhou B. Photophysical properties of dysprosium complexes with aromatic carboxylic acids by molecular spectroscopy [J]. Journal of Photochemistry and Photobiology A:Chemistry,2005,171:181-186.
[82]Sabbatini N., Dellonte S., Blasse G. The luminescence of the rare earth cryptates [Tb-2.2.1]3+ and [Sm-2.2.1]3+ [J]. Chemical Physics Letters,1986,129(6):541-545.
[83]Bunzli J. C. G., Froidevaux P., Harrowfield J. M. Complexes of lanthanoid salts with macrocyclic ligands.41. Photophysical properties of lanthanide dinuclear complexes with p-tert-butylcalix[8]arene [J]. Inorganic Chemistry,1993.32(15):3306-3311.
[84]Piguet C., Buenzli J. C. G., Bernardinelli G., Hopfgartner G., Williams A. F. Self-assembly and photophysical properties of lanthanide dinuclear triple-helical complexes [J]. Journal of the American Chemical Society,1993,115(18):8197-8206.
[85]Mukkala V. M., Helenius M., Hemmila I., Kankare J., Takalo H. Development of luminescent europium(Ⅲ) and terbium(Ⅲ) chelates of 2, 2':6',2"-terpyridine derivatives for protein labeling [J]. Helvetica Chimica Acta,1993,76(3):1361-1378.
[86]Mukkala V. M., Sund C., Kwiatkowski M., Pasanen P., Hogberg M., Kankare J., Takalo H. New heteroaromatic complexing agents and luminescence of their europium(Ⅲ) and terbium(Ⅲ) chelates [J]. Helvetica Chimica Acta,1992,75(5):1621-1632.
[87]Lehn J. M., Roth C. O. Synthesis and properties of sodium and europium(Ⅲ) cryptates incorporating the 2,2'-bipyridine 1,1'-dioxide and 3,3'-biisoquinoline 2,2'-dioxide units [J]. Helvetica Chimica Acta,1991,74(3):572-578.
[88]Lehn J. M., Pietraszkiewicz M., Karpiuk J. Synthesis and properties of acyclic and cryptate europium(Ⅲ) complexes incorporating the 3,3'-biisoquinoline 2,2'-dioxide unit [J]. Helvetica Chimica Acta,1990,73(1):106-111.
[89]Aime S., Fasano M., Terreno E. Lanthanide (Ⅲ) chelates for NMR biomedical applications [J]. Chemical Society Reviews,1998,27(1):19-29.
[90]Romanelli M., Kumar G. A., Emge T. J., Riman R. E., Brennan J. G. Intense near-IR emission from nanoscale lanthanoid fluoride clusters [J]. Angewandte Chemie International Edition,2008,47(32):6049-6051.
[91]Sun W. X., Xu Y. Z., Liu X. X., Guo F. X., Wu J. G., Xu D. F. Uncommon fluorescent properties of nano-structured terbium(Ⅲ)-phthalic acid complex in polyvinylpyrrolidone [J]. Spectroscopy and Spectral Analysis,2001,21(2):204-207.
[92]Bhargava R. N., Gallagher D., Welker T. Doped nanocrystals of semiconductors-a new class of luminescent materials[J]. Journal of Luminescence,1994,60-61:275-280.
[93]Bhargava R. N., Gallagher D., Hong X., Nurmikko A. Optical properties of manganese-doped nanocrystals of ZnS [J]. Physical Review Letters,1994,72:416-419.
[94]Wang Y., Herron N. Photoluminescence and relaxation dynamics of cadmium sulfide superclusters in zeolites [J]. Journal of Physical Chemistry,1988,92(17):4988-4994.
[95]Likawa F., Bernussi A. A., Soares A. G., Plentz F. O., Motisuke P., Sacilotti M. A. Luminescence and photomodulated transmission measurements in InGaAs/GaAs modulation doped single quantum wells [J]. Journal of Applied Physics,1994,75(6):3071-3074.
[96]Mo C. M., Zhang L. D., Xie C. Y., Wang T. Luminescence of nanometer-sized amorphous silicon nitride solids [J]. Journal of Applied Physics,1993,73(10):5185-5188.
[97]Shea L. E., McKittrick J., Lopez O. A., Sluzky E. Synthesis of red-emitting, small particle size luminescent oxides using an optimized combustion process [J]. Journal of the American Ceramic Society,1996,79(12):3257-3265.
[98]Hong K. S., Meltzer R. S., Bihari B., Williams D. K., Tissue B. M. Spectral hole burning in crystalline Eu2O3 and Y2O3:Eu3+ nanoparticles [J]. Journal of Luminescence,1998,76-77: 234-237.
[99]Sharma P. K., Jilavi M. H., Nass R., Schmidt H. Tailoring the particle size from μm→ nm scale by using a surface modifier and their size effect on the fluorescence properties of europium doped yttria [J]. Journal of Luminescence,1999,82:187-193.
[100]Williams D. K., Bihari B., Tissue B. M., McHale J. M. Preparation and fluorescence spectroscopy of bulk monoclinic Eu3+:Y2O3 and comparison to Eu3+:Y2O3 Nanocrystals [J]. Journal of Physical Chemistry B,1998,102(6):916-920.
[101]Mufit Akinc, Ahmet Celikkaya. Advance in ceramics [M]. Vol,21:Ceramic Powder Science, The American Ceramic Society, Inc.1987.
[102]Gary L Messing, Edwin R Fuller Jr. Hans. Hausner, Ceramic Tramsactions [M]. Vol 17: Ceramic Powder Science Ⅳ, The American Ceramic Society, Inc.1988.
[103]胡林学,王宝兰,李建平,李小琴,李洪彬Eu(DBM)3超微粒子的光谱特性[J].物理化学学报,1997,13(1)：56-59.
[104]Qian D. J., Liu H. G., Huang H. X., Fu Q., Feng X. S. Europium complex nanoparticles: preparation, characterization and optical properties [J]. Materials Letters,2001,51(6): 525-528.
[105]Bihari B., Eilers H., Tissue B. M. Spectra and dynamics of monoclinic Eu2O3 and Eu3+ Y2O3 nanocrystals [J]. Journal of Luminescence,1997,75:1-10.
[106]Zhou D. J., Wang K. Z., Huang C. H., Xu G. X., Xu L. G., Li T. K. Langmuir-Blodgett film study on N-hexadecyl pyridinium tetrakis (2-naphthyltrifluoroacetone) europium, HDP·Eu(NTA)4 [J]. Solid State Communications.,1995,93(2):167-169.
[107]Qian D. J., Nakahara H., Fukuda K., Yang K. Z. Monolayer assemblies of long-chain complex containing rare-earth metal:N, N-distearyl-dimethylammonium tetra (4,4,4-trifluoro-l-(2-thienyl)-1,3-butanediono) europate(III) [J]. Chemistry Letters,1995, 24(3):175-176.
[108]Pogreb R., Popov O., Lirtsman V., Pyshkin O., Kazachkov A., Musin A., Whyman G., Finkelshtein B., Shmukler Y., Davidov D., Gladkikh A., Bormashenko E. Luminescent properties of PP and LDPE films and rods doped with the Eu(III)-La(III) complex [J]. Polymers for Advanced Technologies,2006,17(1):20-25.
[109]Liu L., Lu Y. L., He L., Zhang W., Yang C., Liu Y. D., Zhang L. Q. Novel europium-complex/nitrile-butadiene rubber composites [J]. Advanced Functional Materials, 2005,15(2):309-314.
[110]Pogreb R., Finkelshtein B., Shmukler Y., Musina A., Popov O., Stanevsky O., Yitzchaik S., Gladkikh A., Shulzinger A., Streltsov V., Davidov D., Bormashenko E. Low-density polyethylene films doped with europium(Ⅲ) complex:their properties and applications [J]. Polymers for Advanced Technologies,2004,15:414-418.
[111]Hasegawa Y., Yamamuro M., Wada Y., Kanehisa N., Kai Y., Yanagida S. Luminescent polymer containing the Eu(Ⅲ) complex having fast radiation rate and high emission quantum efficiency [J]. Journal of Physical Chemistry A,2003,107 (11):1697-1702.
[112]Liu H. G., Lee Y. I., Feng X. S., Xiao F., Zhang L., Chen X., Jang K., Seo H. J. Studies on photoluminescent properties of Eu(Ⅲ) ions in composite europium complex/polymer systems [J]. Colloids and Surfaces A,2005,257/258:301-305.
[113]Liang H., Chen B., Xu J., Su W., Guo F., Guo B., Zhang Q., Zheng Z., Ming H. Properties of Eu chelate doped polymer thin film [J]. Materials Letters,2005,59:4030-4033.
[114]Liu H.G., Xiao F., Zhang W. S., Chung Y., Seo H. J., Jang K., Lee Y. I. Influences of matrices and concentrations on luminescent characteristics of Eu(TTA)3(H2O)2/polymer composites [J]. Journal of Luminescence,2005,114 (3):187-196.
[115]Manseki K., Hasegawa Y., Wada Y., Yanagida S. Photophysical properties of tetranuclear Eu(Ⅲ) complexes in polyphenylsilsesqioxane (PPSQ) [J]. Journal of Alloys and Compounds,2006,408-412:805-808.
[116]de Bettencourt-Dias A. Lanthanide-based emitting materials in light-emitting diodes [J]. Dalton Transactions,2007,2229-2241.
[117]Zhang T., Xu Z., Qian L., Tao D. L., Teng F., Gao X., Xu X. R. The condition for electroplex emission from an europium complex doped poly(N-vinylcarbazole) [J]. Chemical Physics Letters,2005,415:30-33.
[118]Kang T. S., Harrison B. S., Foley T. J., Knefely A. S., Boncella J. M., Reynolds J. R., Schanze K. S. Near-Infrared electroluminescence from lanthanide tetraphenylporphyrin: polystyrene blends [J]. Advanced Materials,2003,15(13):1093-1097.
[119]McGehee M. D., Bergstedt T., Zhang C., Saab A. P., Regan M. B. O., Bazan G. C., Srdanov V. I., Heeger A. J. Narrow bandwidth luminescence from blends with energy transfer from semiconducting conjugated polymers to europium complexes [J]. Advanced Materials,1999,11(16):1349-1354.
[120]Kang T. S., Harrison B. S., Bouguettaya M., Foley T. J., Boncella J. M., Schanze K. S., Reynolds J. R. Near-Infrared light-emitting diodes (LEDs) based on poly(phenylene)/Yb-tris(β-diketonate) complexes [J]. Advanced Functional Materials,2003, 13(3):205-210.
[121]廉世勋,李承志,张华京,毛向辉.单基双能转光剂光谱性质的调控[J].湖南师范大学自然科学学报,2001,24(4)：66-70.
[122]王则民.我国稀土转光农膜的研究进展[J].稀土,2000,21(5)：55-59.
[123]王则民,傅楚瑾,曹锦荣,陈志荣.稀土转光农膜的光色效应研究[J].中国塑料,1999,13(12)：21-23.
[124]李文连,王庆荣,卫革东,关继舜,于贵.含稀土有机配合物的光能转换蔬菜大棚薄膜的研究[J].稀土,1993,14(1)：25-28.
[125]Saissy A., Ostrowsky D. B., Maze G. Fluorescence in rare earth-doped fluorozirconate fibers [J]. Applied Optics,1991,30(15):1933-1938.
[126]Okamoto Y., Ueba Y., Dzhanibekov N. F., Banks E. Rare earth metal containing polymers. 3. Characterization of ion-containing polymer structures using rare earth metal fluorescence probes [J]. Macromolecules,1981,14:17-22.
[127]赵莹,杨丽敏,张莉,周维金,吴瑾光,鲍春丽,王笃金,徐端夫.含三价铕荧光络合物与聚甲基丙烯酸甲酯的发光材料[J].高分子学报,2000,(4)：393-396.
[128]汪联辉,章文贡,王文.稀土高分子聚合物及其应用[J].稀土,1999,20(3)：58-62.
[129]Banks E., Okamoto Y., Ueba Y. Synthesis and characterization of rare earth metal-containing polymers. Ⅰ. Fluorescent properties of ionomers containing Dy3+, Er3+, Eu3+, and Sm3+[J]. Journal of Applied Polymer Science,1980,25:359-368.
[130]Ueba Y., Banks E., Okamoto Y. Investigation on the synthesis and characterization of rare earth metal-containing polymers. Ⅱ. Fluorescence properties of Eu3+-polymer complexes containing β-diketone ligand [J]. Journal of Applied Polymer Science,1980,25:2007-2017.
[131]Ueba Y., Zhu K. J., Banks E. Synthesis, characterization and fluorescence properties of Eu3+-polymer complexes containing carboxylbenzoyl and carboxylnaphthoyl ligands [J]. Journal of Polymer Science-Polymer Chemistry Edition,1982,20:1271-1278.
[132]Wang Y. P., Lei Z. Q., Feng H. Y., Bao J. T., Wang Y. B. Synthesis and fluorescence properties of rare earth metal ion-polymer ligand-low molecular weight ligand ternary complexes [J]. Journal of Applied Polymer Science,1992,45(9):1641-1648.
[133]Feng H. Y., Jian S. H., Wang Y. P., Lei Z. Q., Wang R. M. Fluorescence properties of ternary complexes of polymer-bond triphenylphosphine, triphenylarsine, triphenylstibine, and triphenylbismuthine, rare earth metal ions, and thenoyltrifluoroacetone [J]. Journal of Applied Polymer Science,1998,68(10):1605-1611.
[134]汪联辉,凌启淡,章文贡,王文,杨慕杰,沈之荃.甲基丙烯酸甲酯与稀土配合物单体的共聚合研究[J].高分子学报,2000,(1)：19-26.
[135]史素姣,王国光,刘明大.聚合物二极管结构激光器[J].激光杂志,1997,18(3)：5-8.
[136]王林同.高(大)分子——稀土配合物的发光应用研究进展[J].昌潍师专学报,2001,20(2)：1-4.
[137]王惠琴,黄京根,胡建国,余兴海,徐燕,孙维根.稀土植物生长光源[J].复旦学报：自然科学版,1991,30(3)：287-292.
[138]杨武,高锦章,康敬万,李存雄.镧系(Eu3+, Tb3+)-β-二酮—醋酸纤维素荧光膜的制备与性质[J].稀土,1998,19(1)：10-14.
[139]Wolff N. E., Pressley R. J. Optical maser action in an Eu3+-containing organic matrix [J]. Applied Physics Letters,1963,2(8):152-154.
[140]Okamoto Y. Synthesis, characterization, and applications of polymers containing lanthanide metals [J]. Journal of Macromolecular Science Pure and Applied Chemistry,1987, 24(3):455-477.
[141]Ida K. Synthetic resin composition and process for producing the same:EP,0108622 [P]. 1984-05-16.
[142]井田浩三.日本专利,公开特许公报,昭60-161458.1985.
[143]Shimizu T., Uehara H. Neodymium-containing transparent resin and method for manufacture thereof:EP 0100519 [P].1984-02-15.
[144]井田浩三.日本专利,公开特许公报，昭 60～110756.1985.
[145]汪联辉,章文贡.含烷氧基钕共聚物的合成及其光学性质[J].高等学校化学学报,1996,17(5)：808-811.
[146]张继松.粘结稀土永磁体的概况[J].磁性材料及器件,1991,22(1)：41-44.
[147]王冬梅.含稀土功能性光学树脂的设计合成与性能研究[D].吉林：吉林大学化学学院,2001.
[148]Yoshioka N., Nishide H., Tsuchida E. Complexation of gadolinium ion with poly(methacrylic acid)s and magnetic properties of the complexes [J]. Inorganica Chimica Acta,1987,128(1):135-138.
[149]田君,尹敬群.稀土紫外荧光防伪油墨的制备[J].精细化工,1999,16(2)：31-32.
[150]周谨.稀土发光纤维发展现状及趋势[J].四川丝绸,2003,(2)：12-13.
[151]Bergbreiter D. E., Chen L. B., Chandran R. Recyclable polymer-bound lanthanide diene polymerization catalysts [J]. Macromolecules,1985,18(6):1055-1057.
[152]于广谦,李玉良.聚合物载体-稀土金属络合物的研究Ⅴ.聚(乙烯-丙烯酸)钕的合成及其对丁二烯聚合的催化活性[J].催化学报,1988,9(2)：190-196.
[153]刘光冬,李玉良.聚合物载体-稀土金属络合物的研究Ⅵ.聚合物载体-钕络合物对丁二烯聚合的催化活性[J].高分子学报,1990,2：136-140.
[154]Richardson F. S. Terbium(III) and europium(Ⅲ) ions as luminescent probes and stains for biomolecular systems [J]. Chemical Reviews,1982,82(5):541-552.
[155]Chen J., Selvin P. R. Lifetime- and color-tailored fluorophores in the micro- to millisecond time regime [J]. Journal of the American Chemical Society,2000,122(4):657-660.
[156]宋苑苑,李晓峰,王立波,徐怡庄,吴瑾光.希土离子Eu3+、Tb3+对钙调素二级结构 的影响[J].无机化学学报,1999.15(4)：509-512.
[157]Du N. Y., Tian R. Y., Peng J. B., Mei Q. B., Lu M. G. Cross-linked Alq3-containing polymers with improved electroluminescence efficiency used for OLEDs [J]. Macromolecular Rapid Communications,2006,27:412-417.
[158]Du N. Y., Tian R. Y., Peng J. B., Mei Q. B., Lu M. G. Enhanced performance in organic light-emitting diodes with copolymers containing both tris(8-hydroxyquinoline) aluminum and 8-hydroxyquinoline lithium groups [J]. Journal of Applied Polymer Science,2006,102: 4404-4410.
[159]Mei Q. B., Du N. Y, Lu M. G. Synthesis and characterization of high molecular weight metaloquinolate-containing polymers [J]. Journal of Applied Polymer Science,2006,99: 1945-1952.
[160]Du N. Y, Tian R. Y., Peng J. B., Lu M. G. Synthesis and photophysical characterization of the free-radical copolymerization of metaloquinolate-pendant monomers with methyl methacrylate [J]. Journal of Polymer Science Part A:Polymer Chemistry,2005,43:397-406.
[161]Du N. Y, Mei Q. B., Lu M. G. Quinolinate aluminum and zinc complexes with multi-methyl methacrylate end groups:synthesis, photoluminescence, and electroluminescence characterization [J]. Synthetic Metals,2005,149:193-197.
[162]Slim M., Sleiman H. F. Ruthenium(Ⅱ)-phenanthroline-biotin complexes:synthesis and luminescence enhancement upon binding to avidin [J]. Bioconjugate Chemistry,2004,15(5): 949-953.
[163]Quici S., Marzanni G., Cavazzini M., Anelli P. L., Botta M., Gianolio E., Accorsi G., Armaroli N., Barigelletti F. Highly luminescent Eu3+ and Tb3+ macrocyclic complexes bearing an appended phenanthroline chromophore [J]. Inorganic Chemistry,2002,41: 2777-2784.
[164]Beeston R. F., Aldridge W. S., Treadway J. A., Fitzgerald M. C., DeGraff B. A., Stitzel S. E. Synthesis, characterization, and photochemical/photophysical properties of ruthenium(II) complexes with hexadentate bipyridine and phenanthroline ligands [J]. Inorganic Chemistry, 1998,37:4368-4379.
[165]Lenaerts P., Driesen K., Deun R. V., Binnemans K. Covalent coupling of luminescent tris(2-thenoyltrifluoroacetonato)lanthanide(III) complexes on a merrifield resin [J]. Chemistry of Materials,2005,17:2148-2154.
[166]Zhong G. L., Yang K. Z. Luminescence enhancement effect of Y(TTA)3Phen on europium(III) and intermolecular energy transfer in Langmuir-Blodgett films [J]. Langmuir, 1998,14:5502-5506.
[167]Al Lawati H. A. J., Suliman F. E. O., Al Kindy S. M. Z., Al-Lawati A. M., Varma G. B., Nour I. E. M. Enhancement of on chip chemiluminescence signal intensity of tris(1, 10-phenanthroline)-ruthenium(Ⅱ) peroxydisulphate system for analysis of chlorpheniramine maleate in pharmaceutical formulations [J]. Talanta,2010,82(5):1999-2002.
[168]Yan Q., Wu Y, Han K., Luo Y, Zhang Q. Luminescence of Eu(DBM)3Phen-doped in azobenzene-containing copolymers—Effects of absorption overlapping of two components [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2010,75(3): 992-996.
[169]Melhuish W. H. Quantum efficiencies of fluorescence of organic substances:effect of solvent and concentration of the fluorescent solute [J]. Journal of Physical Chemistry,1961, 65(2):229-235.
[170]Mozingo R. Organic Syntheses [M]. Wiley:New York,1955, Coll. Vol.3685.
[171]Hammett L. P., Walden G. H., Jr., Edmonds S. M. New indicators for oxidimetry:some phenanthroline and diphenylamine derivatives [J]. Journal of the American Chemical Society,1934,56:1092-1094
[172]凌启淡,章文贡.稀土高分子荧光材料研究综述[J].高分子通报,1998,(1)：48-58.
[173]胡宏纹.有机化学[M].北京：高等教育出版社,1990.
[174]Koft E., Case F. H. Substituted 1,10-phenanthrolines, Ⅻ. Beno and pyride derivatives [J]. Journal of Organic Chemistry,1962,27(3):865-868.
[175]韦长梅.Pd/C催化水合肼还原法制备4-氨基苄醇[J].精细化工,2007,24(1)：94-96.
[176]Taylor M. D., Carter C. P. Preparation of anhydrous lanthanide halides, especially iodides [J]. Journal of Inorganic and Nuclear Chemistry,1962,24(4):387-391.
[177]Sinha R. N. P. Studies on the chemistry of lanthanum alkoxides [J]. Science and Culture, 1960,25(10):594-595.
[178]Melby L. R., Rose N. J., Abramson E., Caris J. C. Synthesis and fluorescence of some trivalent lanthanide complexes [J]. Journal of the American Chemical Society,1964,86: 5117-5125.
[179]Jablonski Z., Rychlowska-Himmel I., Dyrek M. Indium chelates with 1,3-diketones and their monothioderivatives.Ⅰ. Preparation, analysis and IR spectra [J]. Spectrochimica Acta, 1979,35A(12):1297-1301.
[180]洪山海.光谱解析法在有机化学中的应用[M].科学出版社,1981.
[181]Hu X., Cui S., Yan L., Yang R. Synthesis, characterization and fluorescence of rare earth nitrate complexes with triaza-crown ether derivative [J]. Journal of Rare Earths,2003,21(3): 395-397.
[182]Salama S., Richardson F. S. Influence of ligand nitrogen-hydrogen oscillators vs. water oxygen-hydrogen oscillators on the luminescence decay constants of terbium(III) complexes in aqueous solution [J]. Journal of Physical Chemistry,1980,84(5):512-517.
[183]Biinzli J. C. G., Choppin G. R. Lathanide Probes in Life [M]. Chemical and Earth Science, Elsevier, Amsterdam,1989.
[184]Dean C. R. S., Shepherd T. M. Evaluation of the intramolecular energy transfer rate constants in crystalline Eu(hfaa)4ButNH3 [J]. Journal of the Chemical Society, Faraday Transactions, Ⅱ,1975,71:146-155.
[185]Bassett A. P., Magennis S. W., Glover P. B., Lewis D. J., Spencer N., Parsons S., Williams R. M., De Cola L., Pikramenou Z. Highly luminescent, triple- and quadruple-stranded, dinuclear Eu, Nd, and Sm(III) lanthanide complexes based on bis-diketonate ligands [J]. Journal of the American Chemical Society,2004,126(30): 9413-9424.
[186]Sager W. F., Filipescu N., Serafin F. A. Substituent effects on intramolecular energy transfer. I. Absorption and phosphorescence spectra of rare earth β-diketone chelates [J]. Journal of Physical Chemistry,1965,69(4):1092-1100.
[187]Burckhalter J. H., Leib R. I. Amino- and chloromethylation of 8-quinolinol. Mechanism of preponderant ortho substitution in phenols under mannich conditions [J]. Journal of Organic Chemistry,1961,26:4078-4083.
[188]Altomare A., Burla M. C., Camalli M., Cascarano G. L., Giacovazzo C., Guagliardi A., Moliterni A. G. G., Polidori G., Spagna R. SIR97:a new tool for crystal structure determination and refinement [J]. Journal of Applied Crystallography,1999,32(1):115-119.
[189]Betteridge P. W., Carruthers J. R., Cooper R. I., Prout K., Watkin D. J. CRYSTALS version 12:software for guided crystal structure analysis [J]. Journal of Applied Crystallography,2003,36(6):1487-1487.
[190]Kolobielski M. The synthesis of substituted 8-quinolinols [J]. Journal of Heterocyclic Chemistry,1966,3:275-277.
[191]王文,汪联辉,章文贡,潘贤明,李娜Sm (III), Eu (Ⅲ)-丙烯酸-8-羟基喹啉三元配合物的合成及荧光性质研究[J].稀土,1999,20：50-52.
[192]付献彩.物理化学[M].高等教育出版社,2001.
[193]Matthews K. D., Bailey-Folkes S. A., Kahwa I. A., McPherson G. L., O'Mahoney C. A., Ley S. V., Williams D. J., Groombridge C. J., O'Connor C. A. Luminescence dynamics and carbon-13 NMR characteristics of dinuclear complexes exhibiting coupled lanthanide(III) cation pairs [J]. Journal of Physical Chemistry,1992,96(17):7021-7027.
[2]Schimitschek E. J., Schwarz E. G. K. Organometallic compounds as possible laser materials [J]. Nature,1962,196(4857):832-833.
[3]Sato S., Wada M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates [J]. Bulletin of the Chemical Society of Japan, 1970,43(7):1995-1962.
[4]Lempicki A., Samelson H. Optical maser action in europium benzoylacetonate [J]. Physics Letters,1963,4(2):133-135.
[5]Bhaumik M. L., Telk C. L. Fluorescence quantum efficiency of rare-earth chelates [J]. Journal of the Optical Society of America,1964,54(10):1211-1214.
[6]Bhaumik M. L., Fletcher P. C., Nugent L. J., Lee S. M., Higa S., Telk C. L., Weinberg M. Laser emission from a europium benzoylacetonate alcohol solution [J]. Journal of Physical Chemistry,1964,68(6):1490-1493.
[7]Bhaumik M. L., El-Sayed M. A. Studies on the triplet-triplet energy transfer to rare earth chelates [J]. Journal of Physical Chemistry,1965,69(1):275-280.
[8]Hinckley C. C. Paramagnetic shifts in solutions of cholesterol and the dipyridine adduct of trisdipivalomethanatoeuropium(III). A shift reagent [J]. Journal of the American Chemical Society,1969,91(18):5160-5162.
[9]王冬梅.含稀土配合物聚合物透明材料的设计合成与发光性质研究[D].吉林大学.2004.
[10]Lamola A. A., Hammond G. S. Mechanisms of photochemical reactions in solution: Intersystem crossing efficiencies [J]. Journal of Chemical Physics,1965,43(6):2129-2135.
[11]Matsuda Y., Makishima S., Shionoya S. Intramolecular energy transfer in europium chelates due to excitation of the triplet state [J]. Bulletin of the Chemical Society of Japan, 1968,41(7):1513-1518.
[12]Mikula J. J., Salomon R. E. Deuterium isotope effects on the luminescence of terbium and europium chelates [J]. Journal of Chemical Physics,1968,48(3):1077-1085.
[13]Gallagher P. K., Heller A., Wasserman E. Two-step energy transfer in solution [J]. Journal of Chemical Physics,1964,41(12):3921-3924.
[14]Meares C. F., Wensel T. G. Metal chelates as probes of biological systems [J]. Accounts of Chemical Research,1984,17(6):202-209.
[15]Kolodner P., Tyson J. A. Remote thermal imaging with 0.7-μm spatial resolution using temperature-dependent fluorescent thin flims [J]. Applied Physics Letters,1983,42(1): 117-119.
[16]Kolodner P., Tyson J. A. Microscopic fluorescent imaging of surface temperature profiles with 0.01℃ resolution [J]. Applied Physics Letters,1982,40(9):782-784.
[17]Matthews L. R., Knobbe E. T. Luminescence behavior of europium complexes in sol-gel derived host materials [J]. Chemistry of Materials,1993,5(12):1697-1700.
[18]Jin T., Tsutsumi S., Deguchi Y., Machida K., Adachi G. Luminescence property of the terbium bipyridyl complex incorporated in silica matrix by a sol-gel method [J]. Journal of the Electrochemical Society,1995,142(10):L195-L197.
[19]Wang K. Z., huang C. H., Xu G. X., Zhao X. S., Xia X. H., Wu N. Z., Xu L. G., Li T. K. Optical properties of Langmuir-Blodgett film of hemicyanine containing the rare earth complex anion Dy(BPMPHD)2-[J]. Thin Solid Films,1994,252(2):139-144.
[20]Zhou D. J., Huang C. H., Wang K. Z., Xu G. X., Zhao X. S., Xie X. M., Xu L. G., Li T. K. Langmuir-Blodgett film and second harmonic generation of a europium hemicyanine complex, Me2NC6H4CH=CHC5H4NC16H33+Eu(NTA)4-[J]. Langmuir,1994,10(6): 1910-1912.
[21]Kido J., Nagai K., Okamoto Y., Skotheim T. Electroluminescence from polysilane film doped with europium complex [J]. Chemistry Letters,1991,20(7):1267-1270.
[22]Kido J., Hayase H., Hongawa K., Nagai K., Okuyama K. Bright red light-emitting organic electroluminescent devices having a europium complex as an emitter [J]. Applied Physics Letters,1994,65(17):2124-2126.
[23]Sawada T., Ando S. Synthesis, characterization, and optical properties of metal-containing fluorinated polyimide films [J]. Chemistry of Materials,1998,10(11):3368-3378.
[24]Wang L. H., Wang W., Zhang W. G., Kang E. T., Huang W. Synthesis and luminescence properties of novel Eu-containing copolymers consisting of Eu(Ⅲ)-acrylate-β-diketonate complex monomers and methyl methacrylate [J]. Chemistry of Materials,2000,12(8): 2212-2218.
[25]Yang C. Y., Srdanov V., Robinson M. R., Bazan G. C., Heeger A. J. Orienting Eu(dnm)3phen by tensile drawing in polyetnylene:Eu3+ emission [J]. Advanced Materials, 2002,14(13-14):980-983.
[26]Cong Y., Fu J., Cheng Z., Li J., Han Y., Lin J. Self-organization and luminescent properties of nanostructured europium (Ⅲ)-block copolymer complex thin films [J]. Journal of Polymer Science Part B:Polymer Physics,2005,43:2181-5189.
[27]de Bettencourt-Dias A., Viswanathan S., Rollett A. Thiophene-derivatized pybox and its highly luminescent lanthanide ion complexes [J]. Journal of the American Chemical Society, 2007,129:15436-15437.
[28]Chen X.-Y., Yang X., Holliday B. J. Photoluminescent europium-containing inner sphere conducting metallopolymer [J]. Journal of the American Chemical Society,2008,130: 1546-1547.
[29]苏锵.稀土有机化合物的发光与能量传递[J].发光学报,1986,7(1)：1-5.
[30]李文连.稀土有机配合物发光研究的新进展[J].化学通报,1991,8：1-9.
[31]李文连.稀土有机电致发光研究进展[J].中国稀土学报,1999,17(3)：267-270.
[32]杨迟,杨燕生.发光镧系超分子的设计及应用[J].大学化学,1995,10(1)：6-10.
[33]苏庆德,孙燕.稀土有机配合物发光及光声光谱研究方[J].稀土,1997,18(6)：56-60.
[34]Weibel N., Charbonniere L. J., Guardigli M., Roda A., Ziessel R. Engineering of highly luminescent lanthanide tags suitable for protein labeling and time-resolved luminescence imaging [J]. Journal of the American Chemical Society,2004,126(15):4888-4896.
[35]Woods M., Sherry A. D. Synthesis and luminescence studies of aryl substituted tetraamide complexes of europium (Ⅲ):A new approach to pH responsive luminescent europium probes [J]. Inorganic Chemistry,2003,42(14):4401-4408.
[36]Hanaoka K., Kikuchi K., Kobayashi S., Nagano T. Time-resolved long-lived luminescence imaging method employing luminescent lanthanide probes with a new microscopy system [J]. Journal of the American Chemical Society,2007,129(44):13502-13509.
[37]Yamada T., Shinoda S., Sugimoto H., Uenishi J., Tsukube H. Luminescent lanthanide complexes with stereocontrolled tris(2-pyridylmethyl)amine ligands:Chirality effects on lanthanide Complexation and luminescence properties [J]. Inorganic Chemistry,2003. 42(24):7932-7937.
[38]Sabbatini N., Guardigli M., Lehn J. M. Luminescent lanthanide complexes as photochemical supramolecular devices [J]. Coordination Chemistry Reviews,1993.123: 201-228.
[39]Dexter D. L. A theory of sensitized luminescence in solids [J]. Journal of Chemical Physics, 1953,21(5):836-850.
[40]Crosby G. A., Whan R. E., Alire R. M. Intramolecular energy transfer in rare earth chelates. Role of the triplet state [J]. Journal of Chemical Physics,1961,34(3):743-748.
[41]Bhaumik M. L., Nugent L. J. Time-resolved spectroscopy of europium chelates [J]. Journal of Chemical Physics,1965,43:1680-1687.
[42]M. Kleinerman, Energy migration in lanthanide chelates[J]. Journal of Chemical Physics, 1969,51:2370-2381.
[43]Buono-core G. E., Li H., Marciniak B. Quenching of excited states by lanthanide ions and chelates in solution [J]. Coordination Chemistry Reviews,1990,99:55-87.
[44]李建宇.稀土发光材料及其应用[M].北京：化学工业出版社,2003.
[45]Tobita S., Arakawa M., Tanaka I. Electronic relaxation processes of rare earth chelates of benzoyltrifluoroacetone [J]. Journal of Physical Chemistry,1984,88(13):2697-2702.
[46]Chen C. H., Shi J. M. Metal chelates as emitting materials for organic electroluminescence, [J]. Coordination Chemistry Reviews,1998,171:161-174.
[47]黄春辉,李富友,黄维.有机电致发光材料与器件导论[M].上海：复旦大学出版社,2005.
[48]Whan R. E., Crosby G. A. Luminescence studies of rare earth complexes: Benzoylacetonate and dibenzoylmethide chelates [J]. Journal of Molecular Spectroscopy, 1962,8(1-6):315-327.
[49]黄春辉.稀土配位化学[M].北京：科学技术出版社,1997.
[50]Carnall W. T. Handbook of the Physics and Chemistry of Rare Earths [M]. Vol.3, Northholland, Amsterdam,1979.
[51]Brennetot R., Georges J. Investigation of chelate formation, intramolecular energy transfer and luminescence efficiency and lifetimes in the Eu-thenoyltrifluoroacetone-trioctylphosphine oxide-Triton X-100 system using absorbance, fluorescence and photothermal measurements [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2000,56(4):703-715.
[52]Yan B., Zhang H., Wang S., Ni J. Intramolecular energy transfer mechanism between ligands in ternary rare earth complexes with aromatic carboxylic acids and 1,10-phenanthroline [J]. Journal of Photochemistry and Photobiology A:Chemistry,1998, 116(3):209-214.
[53]Renaud F., Piguet C., Bernardinelli G, Bunzli J.-C. G., Hopfgartner G. Nine-coordinate lanthanide podates with predetermined structural and electronic properties:Facial organization of unsymmetrical tridentate binding units by a protonated covalent tripod [J]. Journal of the American Chemical Society,1999,121(40):9326-9342.
[54]Sato S., Wada M. Relations between intramolecular energy transfer efficiencies and triplet state energies in rare earth β-diketone chelates [J]. Bulletin of the Chemical Society of Japan, 1970,43(7):1955-1962.
[55]王薇.多酰胺型配体及其稀土配合物的合成、表征及荧光性能研究[D].兰州大学.2007.
[56]Crosby G A., Whan R. E., Freeman J. J. Spectroscopic studies of rare earth chelates [J]. Journal of Physical Chemistry,1962,66(12):2493-2499.
[57]Khreis O. M., Curry R. J., Somerton M., Gillin W. P. Infrared organic light emitting diodes using neodymium tris-(8-hydroxyquinoline) [J]. Journal of Applied Physics,2000,88: 777-780.
[58]苏锵.稀土化学[M].郑州：河南科技出版社,1993：269-284.
[59]Yang Y. S., Gong M. L., Li Y. Y. Effects of the structure of ligands and their Ln3+ complexes on the luminescence of the central Ln3+ ions [J]. Journal of Alloys and Compounds,1994,207-208:112-114.
[60]Brito H. F., Malta O. L., Felinto M. C. F. C., Teotonio E. E. S., Menezes J. F. S., Silva C. F. B., Tomiyama C. S., Carvalho C. A. A. Luminescence investigation of the Sm(III)-β-diketonates with sulfoxides, phosphine oxides and amides ligands [J]. Journal of Alloys and Compounds,2002,344(1-2):293-297.
[61]Tang B., Jin L. P., Zheng X. J., Zhu L. Y. Photoluminescence enhancement of Eu3+ in the Ei3+-dibenzoylmethide-oligomer (styrene-co-acrylic acid) ternary composite [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,1999,55(9): 1731-1736.
[62]Xu C. J., Yang H., Xie F., Guo X. Z. Photoluminescence enhancement of Sm3+ in the Sm3+-salicylic acid-o-phenanthroline ternary composite [J]. Journal of Alloys and Compounds, 2005,392(1-2):96-99.
[63]汪祖成,蔡汝秀,张华山.稀土元素分析化学[M].北京：科学出版社,2000：222-253.
[64]Yan B., Zhang H. J., Wang S. B., Ni J. Z. Photophysical properties of rare earth complexes with 3,4-furandicarboxylic acid and 1,10-phenanthroline [J]. Journal of Rare Earths,1999, 17(1):16-19.
[65]林惠文,朱文祥.铕(Ⅲ)-β-二酮-4,4'-联吡啶-N,N'-二氧化物三元配合物的合成与表征[J].高等学校化学学报,1996,17(10)：1516-1518.
[66]Zhao Y. L., Zhao F. Y. Synthesis and luminescence of complexes EuxY1-x(Phen)L3 [J]. Journal of Rare Earths,2002,20(5):427-429.
[67]Panigrahi B. S., Peter S., Viswanathan K. S. Cofluorescence of Eu3+ in complexes of aromatic carboxylic acids [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,1997,53:2579-2585.
[68]Xu C. J., Xie F., Guo X. Z., Yang H. Synthesis and cofluorescence of Eu(Y) complexes with salicylic acid and o-phenanthroline, Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2005,61:2005-2008.
[69]刘铭钊,杨展澜,张莉,翁诗甫,吴瑾光.配合物Eu XM(1-X)(TTA)3(H2O)2 (M=La, Gd)光致发光特性[J].物理化学学报,2001,17(9)：797-801.
[70]徐存进.铕(钆)-水杨酸-邻菲罗啉配合物的合成及光致发光性能[J].中国稀土学报.2006,24(3)：361-365.
[71]周忠诚.光致发光稀土(铕、铽)配合物的合成、荧光性能及理论研究[D].中南大学.2002.
[72]Murray G. M., Pesterfield L. L., Stump N. A., Schweitzer G. K. Effects of inorganic countercations on the fluorescence spectra of the tetrakis(1-phenyl-1,3-butanedionato)europium(Ⅲ) anion [J]. Inorganic Chemistry,1989, 28(10):1994-1998.
[73]Fu Y. J., Wong T. K. S., Yan Y. K., Hu X. Syntheses, structures and luminescent properties of Sm (Ⅲ) and Eu (Ⅲ) chelates for organic electroluminescent device applications [J]. Journal of Alloys and Compounds,2003,358:235-244.
[74]de Sa G. F., Malta O. L., Donega C. M., Simas A. M., Longo R. L., Santa-Cruz P. A., da Silva E. F., Jr. Spectroscopic properties and design of highly luminescent lanthanide coordination complexes [J]. Coordination Chemistry Reviews,2000,196(1):165-195.
[75]Malta O. L., Brito H. F., Menezes J. F. S., Silva F. R. G., Donega C. M., Alves S., Jr. Experimental and theoretical emission quantum yield in the compound Eu(thenoyltrifluoroacetonate)3·2(dibenzyl sulfoxide) [J]. Chemical Physics Letters.1998, 282:233-238.
[76]Brito H. F., Malta O. L., Felinto M. C. F. C., Teotonio E. E. S., Menezes J. F. S., Silva C. F. B., Tomiyama C. S., Carvalho C. A. A. Luminescence investigation of the Sm(III)-β-diketonates with sulfoxides, phosphine oxides and amides ligands [J]. Journal of Alloys and Compounds,2002,344:293-297.
[77]安保礼,罗一帆,叶剑清,麦堪成,石建新,龚孟濂.稀土配合物Na3Eu(DPA)3掺杂的PMMA树脂的制备及其发光性能[J].中国稀土学报,2001,19(3)：268-271.
[78]李勇,高新,邓振波,徐怡庄,高宏成,吴瑾光,徐叙瑢.苯甲酰水杨酸的制备及其与稀土络合物光致发光现象研究[J].中国稀土学报,2001,19(6)：548-551.
[79]Erostya k J., Buzady A., Hornyak I., Kozma L. Sensitized luminescence of the Eu3+/La3+/cinnamic acid mixed complex:comparison to the Eu3+/Gd3+/cinnamic acid mixed complex [J]. Journal of Photochemistry and Photobiology A:Chemistry,1999,121:43-48.
[80]Yu X., Su Q. Photoacoustic and luminescence properties study on energy transfer and relaxation processes of Tb(III) complexes with benzoic acid [J]. Journal of Photochemistry and Photobiology A:Chemistry,2003,155:73-78.
[81]Yan B., Zhou B. Photophysical properties of dysprosium complexes with aromatic carboxylic acids by molecular spectroscopy [J]. Journal of Photochemistry and Photobiology A:Chemistry,2005,171:181-186.
[82]Sabbatini N., Dellonte S., Blasse G. The luminescence of the rare earth cryptates [Tb-2.2.1]3+ and [Sm-2.2.1]3+ [J]. Chemical Physics Letters,1986,129(6):541-545.
[83]Bunzli J. C. G., Froidevaux P., Harrowfield J. M. Complexes of lanthanoid salts with macrocyclic ligands.41. Photophysical properties of lanthanide dinuclear complexes with p-tert-butylcalix[8]arene [J]. Inorganic Chemistry,1993.32(15):3306-3311.
[84]Piguet C., Buenzli J. C. G., Bernardinelli G., Hopfgartner G., Williams A. F. Self-assembly and photophysical properties of lanthanide dinuclear triple-helical complexes [J]. Journal of the American Chemical Society,1993,115(18):8197-8206.
[85]Mukkala V. M., Helenius M., Hemmila I., Kankare J., Takalo H. Development of luminescent europium(Ⅲ) and terbium(Ⅲ) chelates of 2, 2':6',2"-terpyridine derivatives for protein labeling [J]. Helvetica Chimica Acta,1993,76(3):1361-1378.
[86]Mukkala V. M., Sund C., Kwiatkowski M., Pasanen P., Hogberg M., Kankare J., Takalo H. New heteroaromatic complexing agents and luminescence of their europium(Ⅲ) and terbium(Ⅲ) chelates [J]. Helvetica Chimica Acta,1992,75(5):1621-1632.
[87]Lehn J. M., Roth C. O. Synthesis and properties of sodium and europium(Ⅲ) cryptates incorporating the 2,2'-bipyridine 1,1'-dioxide and 3,3'-biisoquinoline 2,2'-dioxide units [J]. Helvetica Chimica Acta,1991,74(3):572-578.
[88]Lehn J. M., Pietraszkiewicz M., Karpiuk J. Synthesis and properties of acyclic and cryptate europium(Ⅲ) complexes incorporating the 3,3'-biisoquinoline 2,2'-dioxide unit [J]. Helvetica Chimica Acta,1990,73(1):106-111.
[89]Aime S., Fasano M., Terreno E. Lanthanide (Ⅲ) chelates for NMR biomedical applications [J]. Chemical Society Reviews,1998,27(1):19-29.
[90]Romanelli M., Kumar G. A., Emge T. J., Riman R. E., Brennan J. G. Intense near-IR emission from nanoscale lanthanoid fluoride clusters [J]. Angewandte Chemie International Edition,2008,47(32):6049-6051.
[91]Sun W. X., Xu Y. Z., Liu X. X., Guo F. X., Wu J. G., Xu D. F. Uncommon fluorescent properties of nano-structured terbium(Ⅲ)-phthalic acid complex in polyvinylpyrrolidone [J]. Spectroscopy and Spectral Analysis,2001,21(2):204-207.
[92]Bhargava R. N., Gallagher D., Welker T. Doped nanocrystals of semiconductors-a new class of luminescent materials[J]. Journal of Luminescence,1994,60-61:275-280.
[93]Bhargava R. N., Gallagher D., Hong X., Nurmikko A. Optical properties of manganese-doped nanocrystals of ZnS [J]. Physical Review Letters,1994,72:416-419.
[94]Wang Y., Herron N. Photoluminescence and relaxation dynamics of cadmium sulfide superclusters in zeolites [J]. Journal of Physical Chemistry,1988,92(17):4988-4994.
[95]Likawa F., Bernussi A. A., Soares A. G., Plentz F. O., Motisuke P., Sacilotti M. A. Luminescence and photomodulated transmission measurements in InGaAs/GaAs modulation doped single quantum wells [J]. Journal of Applied Physics,1994,75(6):3071-3074.
[96]Mo C. M., Zhang L. D., Xie C. Y., Wang T. Luminescence of nanometer-sized amorphous silicon nitride solids [J]. Journal of Applied Physics,1993,73(10):5185-5188.
[97]Shea L. E., McKittrick J., Lopez O. A., Sluzky E. Synthesis of red-emitting, small particle size luminescent oxides using an optimized combustion process [J]. Journal of the American Ceramic Society,1996,79(12):3257-3265.
[98]Hong K. S., Meltzer R. S., Bihari B., Williams D. K., Tissue B. M. Spectral hole burning in crystalline Eu2O3 and Y2O3:Eu3+ nanoparticles [J]. Journal of Luminescence,1998,76-77: 234-237.
[99]Sharma P. K., Jilavi M. H., Nass R., Schmidt H. Tailoring the particle size from μm→ nm scale by using a surface modifier and their size effect on the fluorescence properties of europium doped yttria [J]. Journal of Luminescence,1999,82:187-193.
[100]Williams D. K., Bihari B., Tissue B. M., McHale J. M. Preparation and fluorescence spectroscopy of bulk monoclinic Eu3+:Y2O3 and comparison to Eu3+:Y2O3 Nanocrystals [J]. Journal of Physical Chemistry B,1998,102(6):916-920.
[101]Mufit Akinc, Ahmet Celikkaya. Advance in ceramics [M]. Vol,21:Ceramic Powder Science, The American Ceramic Society, Inc.1987.
[102]Gary L Messing, Edwin R Fuller Jr. Hans. Hausner, Ceramic Tramsactions [M]. Vol 17: Ceramic Powder Science Ⅳ, The American Ceramic Society, Inc.1988.
[103]胡林学,王宝兰,李建平,李小琴,李洪彬Eu(DBM)3超微粒子的光谱特性[J].物理化学学报,1997,13(1)：56-59.
[104]Qian D. J., Liu H. G., Huang H. X., Fu Q., Feng X. S. Europium complex nanoparticles: preparation, characterization and optical properties [J]. Materials Letters,2001,51(6): 525-528.
[105]Bihari B., Eilers H., Tissue B. M. Spectra and dynamics of monoclinic Eu2O3 and Eu3+ Y2O3 nanocrystals [J]. Journal of Luminescence,1997,75:1-10.
[106]Zhou D. J., Wang K. Z., Huang C. H., Xu G. X., Xu L. G., Li T. K. Langmuir-Blodgett film study on N-hexadecyl pyridinium tetrakis (2-naphthyltrifluoroacetone) europium, HDP·Eu(NTA)4 [J]. Solid State Communications.,1995,93(2):167-169.
[107]Qian D. J., Nakahara H., Fukuda K., Yang K. Z. Monolayer assemblies of long-chain complex containing rare-earth metal:N, N-distearyl-dimethylammonium tetra (4,4,4-trifluoro-l-(2-thienyl)-1,3-butanediono) europate(III) [J]. Chemistry Letters,1995, 24(3):175-176.
[108]Pogreb R., Popov O., Lirtsman V., Pyshkin O., Kazachkov A., Musin A., Whyman G., Finkelshtein B., Shmukler Y., Davidov D., Gladkikh A., Bormashenko E. Luminescent properties of PP and LDPE films and rods doped with the Eu(III)-La(III) complex [J]. Polymers for Advanced Technologies,2006,17(1):20-25.
[109]Liu L., Lu Y. L., He L., Zhang W., Yang C., Liu Y. D., Zhang L. Q. Novel europium-complex/nitrile-butadiene rubber composites [J]. Advanced Functional Materials, 2005,15(2):309-314.
[110]Pogreb R., Finkelshtein B., Shmukler Y., Musina A., Popov O., Stanevsky O., Yitzchaik S., Gladkikh A., Shulzinger A., Streltsov V., Davidov D., Bormashenko E. Low-density polyethylene films doped with europium(Ⅲ) complex:their properties and applications [J]. Polymers for Advanced Technologies,2004,15:414-418.
[111]Hasegawa Y., Yamamuro M., Wada Y., Kanehisa N., Kai Y., Yanagida S. Luminescent polymer containing the Eu(Ⅲ) complex having fast radiation rate and high emission quantum efficiency [J]. Journal of Physical Chemistry A,2003,107 (11):1697-1702.
[112]Liu H. G., Lee Y. I., Feng X. S., Xiao F., Zhang L., Chen X., Jang K., Seo H. J. Studies on photoluminescent properties of Eu(Ⅲ) ions in composite europium complex/polymer systems [J]. Colloids and Surfaces A,2005,257/258:301-305.
[113]Liang H., Chen B., Xu J., Su W., Guo F., Guo B., Zhang Q., Zheng Z., Ming H. Properties of Eu chelate doped polymer thin film [J]. Materials Letters,2005,59:4030-4033.
[114]Liu H.G., Xiao F., Zhang W. S., Chung Y., Seo H. J., Jang K., Lee Y. I. Influences of matrices and concentrations on luminescent characteristics of Eu(TTA)3(H2O)2/polymer composites [J]. Journal of Luminescence,2005,114 (3):187-196.
[115]Manseki K., Hasegawa Y., Wada Y., Yanagida S. Photophysical properties of tetranuclear Eu(Ⅲ) complexes in polyphenylsilsesqioxane (PPSQ) [J]. Journal of Alloys and Compounds,2006,408-412:805-808.
[116]de Bettencourt-Dias A. Lanthanide-based emitting materials in light-emitting diodes [J]. Dalton Transactions,2007,2229-2241.
[117]Zhang T., Xu Z., Qian L., Tao D. L., Teng F., Gao X., Xu X. R. The condition for electroplex emission from an europium complex doped poly(N-vinylcarbazole) [J]. Chemical Physics Letters,2005,415:30-33.
[118]Kang T. S., Harrison B. S., Foley T. J., Knefely A. S., Boncella J. M., Reynolds J. R., Schanze K. S. Near-Infrared electroluminescence from lanthanide tetraphenylporphyrin: polystyrene blends [J]. Advanced Materials,2003,15(13):1093-1097.
[119]McGehee M. D., Bergstedt T., Zhang C., Saab A. P., Regan M. B. O., Bazan G. C., Srdanov V. I., Heeger A. J. Narrow bandwidth luminescence from blends with energy transfer from semiconducting conjugated polymers to europium complexes [J]. Advanced Materials,1999,11(16):1349-1354.
[120]Kang T. S., Harrison B. S., Bouguettaya M., Foley T. J., Boncella J. M., Schanze K. S., Reynolds J. R. Near-Infrared light-emitting diodes (LEDs) based on poly(phenylene)/Yb-tris(β-diketonate) complexes [J]. Advanced Functional Materials,2003, 13(3):205-210.
[121]廉世勋,李承志,张华京,毛向辉.单基双能转光剂光谱性质的调控[J].湖南师范大学自然科学学报,2001,24(4)：66-70.
[122]王则民.我国稀土转光农膜的研究进展[J].稀土,2000,21(5)：55-59.
[123]王则民,傅楚瑾,曹锦荣,陈志荣.稀土转光农膜的光色效应研究[J].中国塑料,1999,13(12)：21-23.
[124]李文连,王庆荣,卫革东,关继舜,于贵.含稀土有机配合物的光能转换蔬菜大棚薄膜的研究[J].稀土,1993,14(1)：25-28.
[125]Saissy A., Ostrowsky D. B., Maze G. Fluorescence in rare earth-doped fluorozirconate fibers [J]. Applied Optics,1991,30(15):1933-1938.
[126]Okamoto Y., Ueba Y., Dzhanibekov N. F., Banks E. Rare earth metal containing polymers. 3. Characterization of ion-containing polymer structures using rare earth metal fluorescence probes [J]. Macromolecules,1981,14:17-22.
[127]赵莹,杨丽敏,张莉,周维金,吴瑾光,鲍春丽,王笃金,徐端夫.含三价铕荧光络合物与聚甲基丙烯酸甲酯的发光材料[J].高分子学报,2000,(4)：393-396.
[128]汪联辉,章文贡,王文.稀土高分子聚合物及其应用[J].稀土,1999,20(3)：58-62.
[129]Banks E., Okamoto Y., Ueba Y. Synthesis and characterization of rare earth metal-containing polymers. Ⅰ. Fluorescent properties of ionomers containing Dy3+, Er3+, Eu3+, and Sm3+[J]. Journal of Applied Polymer Science,1980,25:359-368.
[130]Ueba Y., Banks E., Okamoto Y. Investigation on the synthesis and characterization of rare earth metal-containing polymers. Ⅱ. Fluorescence properties of Eu3+-polymer complexes containing β-diketone ligand [J]. Journal of Applied Polymer Science,1980,25:2007-2017.
[131]Ueba Y., Zhu K. J., Banks E. Synthesis, characterization and fluorescence properties of Eu3+-polymer complexes containing carboxylbenzoyl and carboxylnaphthoyl ligands [J]. Journal of Polymer Science-Polymer Chemistry Edition,1982,20:1271-1278.
[132]Wang Y. P., Lei Z. Q., Feng H. Y., Bao J. T., Wang Y. B. Synthesis and fluorescence properties of rare earth metal ion-polymer ligand-low molecular weight ligand ternary complexes [J]. Journal of Applied Polymer Science,1992,45(9):1641-1648.
[133]Feng H. Y., Jian S. H., Wang Y. P., Lei Z. Q., Wang R. M. Fluorescence properties of ternary complexes of polymer-bond triphenylphosphine, triphenylarsine, triphenylstibine, and triphenylbismuthine, rare earth metal ions, and thenoyltrifluoroacetone [J]. Journal of Applied Polymer Science,1998,68(10):1605-1611.
[134]汪联辉,凌启淡,章文贡,王文,杨慕杰,沈之荃.甲基丙烯酸甲酯与稀土配合物单体的共聚合研究[J].高分子学报,2000,(1)：19-26.
[135]史素姣,王国光,刘明大.聚合物二极管结构激光器[J].激光杂志,1997,18(3)：5-8.
[136]王林同.高(大)分子——稀土配合物的发光应用研究进展[J].昌潍师专学报,2001,20(2)：1-4.
[137]王惠琴,黄京根,胡建国,余兴海,徐燕,孙维根.稀土植物生长光源[J].复旦学报：自然科学版,1991,30(3)：287-292.
[138]杨武,高锦章,康敬万,李存雄.镧系(Eu3+, Tb3+)-β-二酮—醋酸纤维素荧光膜的制备与性质[J].稀土,1998,19(1)：10-14.
[139]Wolff N. E., Pressley R. J. Optical maser action in an Eu3+-containing organic matrix [J]. Applied Physics Letters,1963,2(8):152-154.
[140]Okamoto Y. Synthesis, characterization, and applications of polymers containing lanthanide metals [J]. Journal of Macromolecular Science Pure and Applied Chemistry,1987, 24(3):455-477.
[141]Ida K. Synthetic resin composition and process for producing the same:EP,0108622 [P]. 1984-05-16.
[142]井田浩三.日本专利,公开特许公报,昭60-161458.1985.
[143]Shimizu T., Uehara H. Neodymium-containing transparent resin and method for manufacture thereof:EP 0100519 [P].1984-02-15.
[144]井田浩三.日本专利,公开特许公报，昭 60～110756.1985.
[145]汪联辉,章文贡.含烷氧基钕共聚物的合成及其光学性质[J].高等学校化学学报,1996,17(5)：808-811.
[146]张继松.粘结稀土永磁体的概况[J].磁性材料及器件,1991,22(1)：41-44.
[147]王冬梅.含稀土功能性光学树脂的设计合成与性能研究[D].吉林：吉林大学化学学院,2001.
[148]Yoshioka N., Nishide H., Tsuchida E. Complexation of gadolinium ion with poly(methacrylic acid)s and magnetic properties of the complexes [J]. Inorganica Chimica Acta,1987,128(1):135-138.
[149]田君,尹敬群.稀土紫外荧光防伪油墨的制备[J].精细化工,1999,16(2)：31-32.
[150]周谨.稀土发光纤维发展现状及趋势[J].四川丝绸,2003,(2)：12-13.
[151]Bergbreiter D. E., Chen L. B., Chandran R. Recyclable polymer-bound lanthanide diene polymerization catalysts [J]. Macromolecules,1985,18(6):1055-1057.
[152]于广谦,李玉良.聚合物载体-稀土金属络合物的研究Ⅴ.聚(乙烯-丙烯酸)钕的合成及其对丁二烯聚合的催化活性[J].催化学报,1988,9(2)：190-196.
[153]刘光冬,李玉良.聚合物载体-稀土金属络合物的研究Ⅵ.聚合物载体-钕络合物对丁二烯聚合的催化活性[J].高分子学报,1990,2：136-140.
[154]Richardson F. S. Terbium(III) and europium(Ⅲ) ions as luminescent probes and stains for biomolecular systems [J]. Chemical Reviews,1982,82(5):541-552.
[155]Chen J., Selvin P. R. Lifetime- and color-tailored fluorophores in the micro- to millisecond time regime [J]. Journal of the American Chemical Society,2000,122(4):657-660.
[156]宋苑苑,李晓峰,王立波,徐怡庄,吴瑾光.希土离子Eu3+、Tb3+对钙调素二级结构 的影响[J].无机化学学报,1999.15(4)：509-512.
[157]Du N. Y., Tian R. Y., Peng J. B., Mei Q. B., Lu M. G. Cross-linked Alq3-containing polymers with improved electroluminescence efficiency used for OLEDs [J]. Macromolecular Rapid Communications,2006,27:412-417.
[158]Du N. Y., Tian R. Y., Peng J. B., Mei Q. B., Lu M. G. Enhanced performance in organic light-emitting diodes with copolymers containing both tris(8-hydroxyquinoline) aluminum and 8-hydroxyquinoline lithium groups [J]. Journal of Applied Polymer Science,2006,102: 4404-4410.
[159]Mei Q. B., Du N. Y, Lu M. G. Synthesis and characterization of high molecular weight metaloquinolate-containing polymers [J]. Journal of Applied Polymer Science,2006,99: 1945-1952.
[160]Du N. Y, Tian R. Y., Peng J. B., Lu M. G. Synthesis and photophysical characterization of the free-radical copolymerization of metaloquinolate-pendant monomers with methyl methacrylate [J]. Journal of Polymer Science Part A:Polymer Chemistry,2005,43:397-406.
[161]Du N. Y, Mei Q. B., Lu M. G. Quinolinate aluminum and zinc complexes with multi-methyl methacrylate end groups:synthesis, photoluminescence, and electroluminescence characterization [J]. Synthetic Metals,2005,149:193-197.
[162]Slim M., Sleiman H. F. Ruthenium(Ⅱ)-phenanthroline-biotin complexes:synthesis and luminescence enhancement upon binding to avidin [J]. Bioconjugate Chemistry,2004,15(5): 949-953.
[163]Quici S., Marzanni G., Cavazzini M., Anelli P. L., Botta M., Gianolio E., Accorsi G., Armaroli N., Barigelletti F. Highly luminescent Eu3+ and Tb3+ macrocyclic complexes bearing an appended phenanthroline chromophore [J]. Inorganic Chemistry,2002,41: 2777-2784.
[164]Beeston R. F., Aldridge W. S., Treadway J. A., Fitzgerald M. C., DeGraff B. A., Stitzel S. E. Synthesis, characterization, and photochemical/photophysical properties of ruthenium(II) complexes with hexadentate bipyridine and phenanthroline ligands [J]. Inorganic Chemistry, 1998,37:4368-4379.
[165]Lenaerts P., Driesen K., Deun R. V., Binnemans K. Covalent coupling of luminescent tris(2-thenoyltrifluoroacetonato)lanthanide(III) complexes on a merrifield resin [J]. Chemistry of Materials,2005,17:2148-2154.
[166]Zhong G. L., Yang K. Z. Luminescence enhancement effect of Y(TTA)3Phen on europium(III) and intermolecular energy transfer in Langmuir-Blodgett films [J]. Langmuir, 1998,14:5502-5506.
[167]Al Lawati H. A. J., Suliman F. E. O., Al Kindy S. M. Z., Al-Lawati A. M., Varma G. B., Nour I. E. M. Enhancement of on chip chemiluminescence signal intensity of tris(1, 10-phenanthroline)-ruthenium(Ⅱ) peroxydisulphate system for analysis of chlorpheniramine maleate in pharmaceutical formulations [J]. Talanta,2010,82(5):1999-2002.
[168]Yan Q., Wu Y, Han K., Luo Y, Zhang Q. Luminescence of Eu(DBM)3Phen-doped in azobenzene-containing copolymers—Effects of absorption overlapping of two components [J]. Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2010,75(3): 992-996.
[169]Melhuish W. H. Quantum efficiencies of fluorescence of organic substances:effect of solvent and concentration of the fluorescent solute [J]. Journal of Physical Chemistry,1961, 65(2):229-235.
[170]Mozingo R. Organic Syntheses [M]. Wiley:New York,1955, Coll. Vol.3685.
[171]Hammett L. P., Walden G. H., Jr., Edmonds S. M. New indicators for oxidimetry:some phenanthroline and diphenylamine derivatives [J]. Journal of the American Chemical Society,1934,56:1092-1094
[172]凌启淡,章文贡.稀土高分子荧光材料研究综述[J].高分子通报,1998,(1)：48-58.
[173]胡宏纹.有机化学[M].北京：高等教育出版社,1990.
[174]Koft E., Case F. H. Substituted 1,10-phenanthrolines, Ⅻ. Beno and pyride derivatives [J]. Journal of Organic Chemistry,1962,27(3):865-868.
[175]韦长梅.Pd/C催化水合肼还原法制备4-氨基苄醇[J].精细化工,2007,24(1)：94-96.
[176]Taylor M. D., Carter C. P. Preparation of anhydrous lanthanide halides, especially iodides [J]. Journal of Inorganic and Nuclear Chemistry,1962,24(4):387-391.
[177]Sinha R. N. P. Studies on the chemistry of lanthanum alkoxides [J]. Science and Culture, 1960,25(10):594-595.
[178]Melby L. R., Rose N. J., Abramson E., Caris J. C. Synthesis and fluorescence of some trivalent lanthanide complexes [J]. Journal of the American Chemical Society,1964,86: 5117-5125.
[179]Jablonski Z., Rychlowska-Himmel I., Dyrek M. Indium chelates with 1,3-diketones and their monothioderivatives.Ⅰ. Preparation, analysis and IR spectra [J]. Spectrochimica Acta, 1979,35A(12):1297-1301.
[180]洪山海.光谱解析法在有机化学中的应用[M].科学出版社,1981.
[181]Hu X., Cui S., Yan L., Yang R. Synthesis, characterization and fluorescence of rare earth nitrate complexes with triaza-crown ether derivative [J]. Journal of Rare Earths,2003,21(3): 395-397.
[182]Salama S., Richardson F. S. Influence of ligand nitrogen-hydrogen oscillators vs. water oxygen-hydrogen oscillators on the luminescence decay constants of terbium(III) complexes in aqueous solution [J]. Journal of Physical Chemistry,1980,84(5):512-517.
[183]Biinzli J. C. G., Choppin G. R. Lathanide Probes in Life [M]. Chemical and Earth Science, Elsevier, Amsterdam,1989.
[184]Dean C. R. S., Shepherd T. M. Evaluation of the intramolecular energy transfer rate constants in crystalline Eu(hfaa)4ButNH3 [J]. Journal of the Chemical Society, Faraday Transactions, Ⅱ,1975,71:146-155.
[185]Bassett A. P., Magennis S. W., Glover P. B., Lewis D. J., Spencer N., Parsons S., Williams R. M., De Cola L., Pikramenou Z. Highly luminescent, triple- and quadruple-stranded, dinuclear Eu, Nd, and Sm(III) lanthanide complexes based on bis-diketonate ligands [J]. Journal of the American Chemical Society,2004,126(30): 9413-9424.
[186]Sager W. F., Filipescu N., Serafin F. A. Substituent effects on intramolecular energy transfer. I. Absorption and phosphorescence spectra of rare earth β-diketone chelates [J]. Journal of Physical Chemistry,1965,69(4):1092-1100.
[187]Burckhalter J. H., Leib R. I. Amino- and chloromethylation of 8-quinolinol. Mechanism of preponderant ortho substitution in phenols under mannich conditions [J]. Journal of Organic Chemistry,1961,26:4078-4083.
[188]Altomare A., Burla M. C., Camalli M., Cascarano G. L., Giacovazzo C., Guagliardi A., Moliterni A. G. G., Polidori G., Spagna R. SIR97:a new tool for crystal structure determination and refinement [J]. Journal of Applied Crystallography,1999,32(1):115-119.
[189]Betteridge P. W., Carruthers J. R., Cooper R. I., Prout K., Watkin D. J. CRYSTALS version 12:software for guided crystal structure analysis [J]. Journal of Applied Crystallography,2003,36(6):1487-1487.
[190]Kolobielski M. The synthesis of substituted 8-quinolinols [J]. Journal of Heterocyclic Chemistry,1966,3:275-277.
[191]王文,汪联辉,章文贡,潘贤明,李娜Sm (III), Eu (Ⅲ)-丙烯酸-8-羟基喹啉三元配合物的合成及荧光性质研究[J].稀土,1999,20：50-52.
[192]付献彩.物理化学[M].高等教育出版社,2001.
[193]Matthews K. D., Bailey-Folkes S. A., Kahwa I. A., McPherson G. L., O'Mahoney C. A., Ley S. V., Williams D. J., Groombridge C. J., O'Connor C. A. Luminescence dynamics and carbon-13 NMR characteristics of dinuclear complexes exhibiting coupled lanthanide(III) cation pairs [J]. Journal of Physical Chemistry,1992,96(17):7021-7027.