吡啶基类衍生配体及其过渡/稀土金属配合物的合成、晶体结构及性质研究
|
摘要
近年来,随着晶工程和超分子化学的迅速发展,设计合成具有新颖结构和优良性能的配位聚合物已成为现代配位化学的研究热点之一。本文以设计合成具有优良光学性能、磁学性能以及具有较高热稳定性的过渡/稀土金属配合物为目标,选用合成的四种不同的含吡啶基配体,与过渡金属(ZnⅡ、MnⅡ、CoⅡ、NiⅡ)和稀土金属离子(EuⅢ、TbⅢ、DyⅢ、 NdⅢ、YbⅢ、LaⅢ、GdⅢ、PrⅢ)反应,成功合成了四个系列28个不同维度的配合物,用X-射线单晶衍射分析了其单晶结构,通过元素分析、红外光谱等技术对配合物进行了表征,研究了所得配合物的光学性质、磁学性质,并进一步研究了其热稳定性。全文分为五章,主要内容简介如下：
第一章：简要介绍超分子化学、晶体工程、配位聚合物的定义发展,阐述了配位聚合物的合成、影响配位聚合物合成的因素、配位聚合物的结构及配位聚合物的实际应用。
第二章：设计合成配体2,6-双(2-吡嗪基)吡啶-4-甲酸(HL1),用此配体和过渡金属ZnⅡ在芳香族羧酸和脂肪族羧酸作为辅助配体的条件下,得到了9个配位聚合物(1-9),与稀土离子EuⅢ、TbⅢ、DyⅢ等反应得到了7个稀土配位聚合物(10-16),探讨了辅助配体和反应条件对配位聚合物结构的影响,对配位聚合物的光学性能和热稳定性进行了研究。
第三章：改进参考文献的方法合成了配体2,6-双(2-吡嗪基)吡啶-4-对苯甲酸(HL2),用此配体和过渡金属离子ZnⅡ、MnⅡ在水热条件下合成了五个结构不同的配位聚合物(17-21),探讨了不同的反应条件对配合物结构的影响,结果表明,辅助配体、pH值、金属盐阴离子、反应物配比等因素对配合物的结构可以起到一定的调控作用。对配合物的光学性能和热稳定性也进行了初步的研究。
第四章：设计合成了一个新颖的有机配体2,6-双(2-吡嗪基)-4,4'-联吡啶(L3),并用此配体在多羧酸为辅助配体的条件下,运用水热法得到了四个过渡金属ZnⅡ/MnII的配位聚合物(22-25),讨论了氢键相互作用及π-π相互作用在超分子结构自组装过程中的作用。
第五章：改进参考文献的合成方法,运用克莱森缩合反应制得了一个双p-二酮配体2,6-双(3-噻吩基-1,3-丙二酮基)吡啶(H2L4),运用扩散法用此配体和过渡金属离子以及稀土金属离子反应,得到了三个3d-4f混配三螺旋金属配合物(26-28)。通过对配合物26和27的磁学性质研究发现,配合物中的过渡金属和稀土金属之间有反铁磁作用存在,此外对配合物的紫外可见以及PXRD和热稳定性进行了研究,研究表明配合物26-28是具有较高热稳定性的均相纯净配合物。
With the rapid development of crystal engineering discipline and supramolecular chemistry, the design and synthesis of novel functional coordination polymers which have interesting and useful structure have been one of the most interesting research topics in coordination chemistry. The dissertation is aimed to synthesize transition and/or lanthanide coordination complexes with excellent photophysical or magnetic properties and good thermal stabilities. Four series,28transition and/or lanthanide coordination complexes are successfully designed by the reactions of transition metals (ZnⅡ、MnⅡ、CoⅡ、NiⅡ) and/or lanthanide ions (EuⅢ、TbⅢ、DyⅢ、NdⅢ、YbⅢ、LaⅢ、GdⅢ、PrⅢ) with four different kinds of derivatives of pyridyl derivative ligands. The coordination complexes are characterized by X-ray single crystal diffraction, elemental analyses, IR spectral analyses. Their luminescence properties and magnetism have been investigated, their thermal stabilities have also been studied. The dissertation includes the following five parts:
Chapter1:The basic theory and concept of supramolecular chemistry, crystal engineering and coordination polymer are simply introduced. The synthesis of coordination polymer, the factors which affect the synthesis of coordination polymer, the structures of coordination polymers and the practical application of coordination polymers have also been briefly introduced.
Chapter2:The2,6-bis(pyrazin-2-yl)pyridine-4-carboxylate (HL1) has been synthesized. Nine novel ZnⅡ coordination complexes (1-9) based on the HL1and aliphatic/aromatic carboxylic acid as auxiliary ligands have been synthesized successfully, and seven lanthanide coordination polymers (10-16) were also based on the HL1and lanthanide ions EuⅢ、TbⅢ、 DyⅢ etc. The influence factors of auxiliary ligands and reaction conditions have been discussed. The luminescence properties and the thermal stability of the coordination polymers have been also investigated.
Chapter3:The ligand4-(2,6-di(pyrazin-2-yl)pyridine-4-yl)-benzoic acid (H2L) was synthesized according to a modified literature procedure. Five novel ZnⅡ/MnⅡ coordination polymers (17-21) with different structure have been hydrothermally synthesized. The influence factors of different reaction conditions have been discussed. The results is during the construction of the coordination polymers, the auxiliary ligands, pH values, the anions of the metal salts, molar ratio of the reagent, reaction temperature, et, have important influences on the final structures to some extent. The luminescence properties and the thermal stability of the coordination polymers have been also investigated.
Chapter4:The ligand2,6-di(pyrazin-2-yl)-4,4'-bipyridine (L3) which has never been reported has been synthesized. Four novel transition metal (ZnⅡ, MnⅡ) coordination polymers (22-25) based on HL3and carboxylic acid as auxiliary ligands have been hydrothermally synthesized successfully. The hydrogen interactions and π-π stacking interactions play an important role on the constructing of supramolecular network.
Chapter5:The ligand2,6-bis(3-thienyl-3-henylpropionyl)-pyridine (H2L4) was synthesized according to a modified literature procedure using the Claisen condensation reaction. Three novel3d-4f heterotrinuclear complexes with triple-helical architectures (26-28) have been synthesized successfully by the reactions of transition meta and lanthanide ions with H2L4. The research results of the magnetic properties of26and27support the existence of a ferromagnetic exchange interaction between the transition meta and lanthanide ions. In addition, the UV-visible spectra, the PXRD and the thermal stability of the coordination polymers have been also investigated and the results indicate the coordination polymers are pure and possess good thermal stability.
第一章：简要介绍超分子化学、晶体工程、配位聚合物的定义发展,阐述了配位聚合物的合成、影响配位聚合物合成的因素、配位聚合物的结构及配位聚合物的实际应用。
第二章：设计合成配体2,6-双(2-吡嗪基)吡啶-4-甲酸(HL1),用此配体和过渡金属ZnⅡ在芳香族羧酸和脂肪族羧酸作为辅助配体的条件下,得到了9个配位聚合物(1-9),与稀土离子EuⅢ、TbⅢ、DyⅢ等反应得到了7个稀土配位聚合物(10-16),探讨了辅助配体和反应条件对配位聚合物结构的影响,对配位聚合物的光学性能和热稳定性进行了研究。
第三章：改进参考文献的方法合成了配体2,6-双(2-吡嗪基)吡啶-4-对苯甲酸(HL2),用此配体和过渡金属离子ZnⅡ、MnⅡ在水热条件下合成了五个结构不同的配位聚合物(17-21),探讨了不同的反应条件对配合物结构的影响,结果表明,辅助配体、pH值、金属盐阴离子、反应物配比等因素对配合物的结构可以起到一定的调控作用。对配合物的光学性能和热稳定性也进行了初步的研究。
第四章：设计合成了一个新颖的有机配体2,6-双(2-吡嗪基)-4,4'-联吡啶(L3),并用此配体在多羧酸为辅助配体的条件下,运用水热法得到了四个过渡金属ZnⅡ/MnII的配位聚合物(22-25),讨论了氢键相互作用及π-π相互作用在超分子结构自组装过程中的作用。
第五章：改进参考文献的合成方法,运用克莱森缩合反应制得了一个双p-二酮配体2,6-双(3-噻吩基-1,3-丙二酮基)吡啶(H2L4),运用扩散法用此配体和过渡金属离子以及稀土金属离子反应,得到了三个3d-4f混配三螺旋金属配合物(26-28)。通过对配合物26和27的磁学性质研究发现,配合物中的过渡金属和稀土金属之间有反铁磁作用存在,此外对配合物的紫外可见以及PXRD和热稳定性进行了研究,研究表明配合物26-28是具有较高热稳定性的均相纯净配合物。
With the rapid development of crystal engineering discipline and supramolecular chemistry, the design and synthesis of novel functional coordination polymers which have interesting and useful structure have been one of the most interesting research topics in coordination chemistry. The dissertation is aimed to synthesize transition and/or lanthanide coordination complexes with excellent photophysical or magnetic properties and good thermal stabilities. Four series,28transition and/or lanthanide coordination complexes are successfully designed by the reactions of transition metals (ZnⅡ、MnⅡ、CoⅡ、NiⅡ) and/or lanthanide ions (EuⅢ、TbⅢ、DyⅢ、NdⅢ、YbⅢ、LaⅢ、GdⅢ、PrⅢ) with four different kinds of derivatives of pyridyl derivative ligands. The coordination complexes are characterized by X-ray single crystal diffraction, elemental analyses, IR spectral analyses. Their luminescence properties and magnetism have been investigated, their thermal stabilities have also been studied. The dissertation includes the following five parts:
Chapter1:The basic theory and concept of supramolecular chemistry, crystal engineering and coordination polymer are simply introduced. The synthesis of coordination polymer, the factors which affect the synthesis of coordination polymer, the structures of coordination polymers and the practical application of coordination polymers have also been briefly introduced.
Chapter2:The2,6-bis(pyrazin-2-yl)pyridine-4-carboxylate (HL1) has been synthesized. Nine novel ZnⅡ coordination complexes (1-9) based on the HL1and aliphatic/aromatic carboxylic acid as auxiliary ligands have been synthesized successfully, and seven lanthanide coordination polymers (10-16) were also based on the HL1and lanthanide ions EuⅢ、TbⅢ、 DyⅢ etc. The influence factors of auxiliary ligands and reaction conditions have been discussed. The luminescence properties and the thermal stability of the coordination polymers have been also investigated.
Chapter3:The ligand4-(2,6-di(pyrazin-2-yl)pyridine-4-yl)-benzoic acid (H2L) was synthesized according to a modified literature procedure. Five novel ZnⅡ/MnⅡ coordination polymers (17-21) with different structure have been hydrothermally synthesized. The influence factors of different reaction conditions have been discussed. The results is during the construction of the coordination polymers, the auxiliary ligands, pH values, the anions of the metal salts, molar ratio of the reagent, reaction temperature, et, have important influences on the final structures to some extent. The luminescence properties and the thermal stability of the coordination polymers have been also investigated.
Chapter4:The ligand2,6-di(pyrazin-2-yl)-4,4'-bipyridine (L3) which has never been reported has been synthesized. Four novel transition metal (ZnⅡ, MnⅡ) coordination polymers (22-25) based on HL3and carboxylic acid as auxiliary ligands have been hydrothermally synthesized successfully. The hydrogen interactions and π-π stacking interactions play an important role on the constructing of supramolecular network.
Chapter5:The ligand2,6-bis(3-thienyl-3-henylpropionyl)-pyridine (H2L4) was synthesized according to a modified literature procedure using the Claisen condensation reaction. Three novel3d-4f heterotrinuclear complexes with triple-helical architectures (26-28) have been synthesized successfully by the reactions of transition meta and lanthanide ions with H2L4. The research results of the magnetic properties of26and27support the existence of a ferromagnetic exchange interaction between the transition meta and lanthanide ions. In addition, the UV-visible spectra, the PXRD and the thermal stability of the coordination polymers have been also investigated and the results indicate the coordination polymers are pure and possess good thermal stability.
引文
[1]Lehn J M. Superamolecular chemistry-scope and perspectives molecules, supermolecules, and molecular devices [J]. Angew. Chem. Int. Ed.,1988,27:89
[2]Braga D., Brammer L., Champness N. R.. New trends in crystal engineering CrystEngComm, 2005,7:1-19.
[3]Chen B. L., Wang L. B., Xia, Y. Q., et al. A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions[J], Angewandte Chemie International Edition, 2009,48:500-503
[4]周秋香,王延吉,赵新强等.多纳米孔道配位聚合物的研究进展[J].化学通报,2003,66：1-7
[5]陈小明,蔡继文.单晶结构分析原理与实践(第二版)[M].北京：科学出版社,2007
[6]陈荣,高松.无机化学学科前沿与展望[M].北京：科学出版社,2012
[7]Zou L. F., Zhao L., Guo Y.N.,et al. A dodecanuclear heterometallic dysprosium-cobalt wheel exhibiting single-molecule magnet behaviour [J]. Chem. Commun, 2011, 47:8659-8661
[8]Sanz S., Ferreira K., Ruaraidh D.et al. Calix[4]arene-supported FeⅢ2LnⅢ2 clusters [J]. Chem. Commun, 2011,47:9042-9044
[9]Mereacre V. M., Ako A. M., Cle'rac R., et al. A Bell-Shaped Mn11Gd2 Single-Molecule Magnet [J]. J. AM. CHEM. SOC. 2007,129:9248-9249
[10]Jami A. K., Kishore P.V.N., Baskar V. Functionalised β-diketone assisted self-assembly of a hexanuclear yttriumoxo-hydroxo cluster [J]. Polyhedron, 2009,28:2284-2286
[11]Chen X.Y., Yang X.P., Holliday B. J. Metal-Controlled Assembly of Near Infrared Em-itting Pentanuclear Lanthanide β-Diketone Clusters[J]. Inorganic Chemistry, 2010, 49(6):2583-2585
[12]Tian A. X., Ying J., Peng J., et al. Using Flexible and Rigid Organic Ligands to Tune Topology Structures Based on Keggin Polyoxometalates[J]. Crystal Growth & Design, 2010,10(3):1104-1110
[13]Sen R., Mal D., Brandao P.,et al. Cadmium-Furandicarboxylate Coordination Polymers Prepared with Different Types of Pyridyl Linkers:Synthesis, Divergent Dimensionalities, and Luminescence Study [J]. Crystal Growth & Design, 2013,13:5271-5281
[14]Dai F.N., He H.Y., Zhao X.L.,et al. 1D zigzag chain vs. 1D helical chain: the role of the supramolecular interactions on the formation of chiral architecture [J]. CrystEngComm, 2010,12:337-340
[15]Hu H., Zhang R.H., Yang F.,et al. Synthesis, structure and magnetic properties of hete-rometallic coordination polymers constructed from Cu (Ⅱ)/Mn (Ⅱ), H2bdc and Hjbtec [J]. Inorganic Chemistry Communications, 2014,40:87-91
[16]Meng X.R., Wu X.J., Li D. W.,et al. Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(Ⅱ) complexes: From discrete molecule to one-and two-dimensional structures [J]. Polyhedron,2010,29:2619-262
[17]Ma L.F., Wang L.Y., Hu J.L.,et al. Syntheses, Structures, and Photoluminescence of a Se-ries of d10 Coordination Polymers with R-Isophthalate (R=-OH,-CH3, and-C(CH3)3) [J]. Crystal Growth & Design, 2009,9(12):5334-5342
[18]Wang X.L., Luan J., Sui F.F.,et al. Structural Diversities and Fluorescent and Photo cata-lytic Properties of a Series of CuⅡ Coordination Polymers Constructed from Flexible Bis-py ridyl-bis-amide Ligands with Different Spacer Lengths and Different Aromatic Carbo-xylates [J]. Crystal Growth & Design, 2013,13:3561-3576
[19]Sun Y.Q., Xu Y.Y., Gao D.Z.,et al. 2D Coordination polymers of macrocyclic oxamide with polycarboxylates:syntheses, crystal structures and magnetic properties [J]. Dalton Trans.,2012,41:5704-5714
[20]Jin X.H., Sun J.K., Cai L. X.,et al.2D flexible metal-organic frameworks with [Cd2. (μ2-X)2](X=Cl or Br) units exhibiting selective fluorescence sensing for small molecules[J]. Chem. Commun.,2011,47:2667-2669
[21]Zhang K.L., Zhang J.B., Jing C.Y.,et al. Synthesis, structures and properties of a family of four two-dimensional coordination polymers constructed from 5-hydroxyisophthalate [J]. Journal of Solid State Chemistry 2014,211:8-20
[22]Dai M., Su X.R., Wang X.,et al. Three Zinc(Ⅱ) Coordination Polymers Based on Tetrakis (4-pyridyl)cyclobutane and Naphthalenedicarboxylate Linkers: Solvothermal Syntheses, Structures, and Photocatalytic Properties [J]. Crystal Growth & Design, 2014,14:240-248
[23]Xiong W.W., Athresh E. U., Ng Y.T.,et al. Growing Crystalline Chalcogenidoarsenates in Surfactants: FromZero-Dimensional Cluster to Three-Dimensional Framework [J]. J. Am. Chem. Soc.,2013,135:1256-1259
[24]Qin L., Hu J.S., Li Y.Z.,et al. Effect of Carboxylate Coligands with Different Rigidity on upramolecular Architectures Based on One Rigid Didentate Linear igand [J]. Crystal Gro-wth & Design, 2012,12:403-413
[25]Li Y.W., Ma H., Chen Y.Q.,et al. Structure Modulation in Zn(Ⅱ)-1,4-Bis(imidazol-l-yl) benzene Frameworks by Varying Dicarboxylate Anions [J]. Cryst. Growth Des.,2012, 12:189-196
[26]Lee H. Y., Park J., Lah M. S., et al. One-Dimensional Double Helical Structure and 4-Fold Type [2+2] Interpenetration of Diamondoid Networks with Helical Fashion [J]. Crystal Growth & Design, 2008,2, (8):587-591
[27]Maji T. K., Ohba M., Kitagawa S.. Transformation from a 2D Stacked Layer to 3D Int-erpenetrated Framework by Changing the Spacer Functionality: Synthesis, Structure, Ad-sorption, and Magnetic Properties [J]. Inorganic Chemistry,44:9225-9231
[28]Wang H.Y., Gao S., Huo L.H., et al. Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal. [J]. Cryst. Growth Des., 2008,2, (8):665-670
[29]Christiane O., Buchecker D., Sauvage J.P.. Templated Synthesis of Interlocked Mac rocyclicLigands: The Catenands [J]. J. Am. Chem. Soc. 1984,106:3045-3046
[30]J. P. Collman, P. J. Brothers, L. McElwee-White, E. Rose [J]. J. Am. Chem. Soc. 1985, 107:6110-6111
[31]Armaroli N., Balzani V., Barigelletti J.,et al. Supramolecular Photochemistry and Phot ophysics. A [3]-Catenand and Its Mononuclear and Homo-and Heterodinuclear [3]-Catenates [J]. J. Am. Chem. Soc.1994,116:5211-5217
[32]Whang D., Kim K.. Polycatenated Two-Dimensional Polyrotaxane Net [J]. J. Am. Chem. Soc.1997,119:451-452
[33]Tong M.L., Chen X.M., Ye B.H.. Helical Silver(Ⅰ)-2,4'-Bipyridine Chains Organized into 2-D Networks by Metal-Counterion or Metal-Metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X-) NO3-or ClO4-) [J]. Inorg. Chem.,1998, 37:5278-5281
[34]Carlucci L., Ciani G., Gudenberg D. W., et al. Self-Assembly of Infinite Double Helical and Tubular Coordination Polymers from Ag(CF3SO3) and 1,3-Bis(4-pyridyl)propane [J]. Inorg. Chem.,1997,36:3812-3813.
[35]Zang S.Q., Su Y., Li Y.Z.,et al. Interweaving of Triple-Helical and Extended Metal-O-Metal Single-Helical Chains with the Same Helix Axis in a 3D Metal-Organic Frame work [J]. Inorg. Chem.,45:3855-3857
[36]Wu H., Liu H.Y., Yang J.,et al. Series of Coordination Polymers Based on Different Carboxylates and a Tri(4-imidazolylphenyl)amine Ligand:Entangled Structures and Photoluminescence [J]. Cryst. Growth Des.,2011,11:2317-2324
[37]Xu C.Y., Li T., Wang Y.,et al. Three-Dimensional Cd(II) Coordination Polymers Based on Semirigid Bis(Methylbenzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties [J]. Cryst. Growth Des.,2011, 11:4667-4675
[38]Park J. H., Lee W. R., Ryu D.W.,et al. Sulfate-Incorporated Co(Ⅱ) Coordination Frame-works with Bis-imidazole Bridging Ligands Constructed by Covalent and Noncovalent Interactions [J]. Cryst. Growth Des.,2012,12:2691-2698
[39]Wang X.S., Zhao H., Qu Z.R.,et al. An Unprecedented 8-Fold Interpenetrating Diamon doid-like CoordinationPolymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node [J]. Inorganic Chemistry,2003,42:5786-5788
[40]Wang H.Y., Gao S., Huo L.H.,et al. Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal [J]. Cryst. Growth Des., 2008,8: 665-670
[41]Pasatoiu T. D., Tiseanu C., Madalan A. M.,et al. Study of the Luminescent and Magnetic Properties of a Series of Heterodinuclear [ZnⅡLnⅢ] Complexes [J]. Inorganic Chemistry, 2011,50(13):5879-5889
[42]Li D.M., Zhou W., Xu G.Y.,et al. Dinuclear (bis-β-diketonato)Ni(Ⅱ) and Cu(Ⅱ) coordin-ation complexes with different 3D supramolecular structures incorporating 1D columns [J]. Journal of Molecular Structure 2009,929:120-124
[43]Lu W.G., Jiang L., Lu T.B.. Lanthanide Contraction and Temperature-Dependent Struct-ures of Lanthanide Coordination Polymers with Imidazole-4,5-Dicarboxylate and Oxalate[J]. [J]. Crystal Growth & Design, 2010,10:4310-4318
[44]Hammarstrom L., Johansson O.. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuⅡ polypyridine complexes[J], Coordination Chemistry Reviews, 2010,254:2546-2559
[45]Leth J. M. Cardiac Changes in Muscular Dystrophy [J]. Nordisk medicin, 1971,86(50): 1544-1546
[46]Mantel C., Baffert C., Romero I., et al. Structural Characterization and Electronic Properties Determination by High-Field and High-Frequency EPR of a Series of Five-Coordinated Mn(Ⅱ) Complexes[J]. Inorganic Chemistry, 2004, V43(20):6455-6463
[47]Di Bella. S., Dragonetti C., Pizzotti M.. Coordination and Organometallic Complexes as Second-Order Nonlinear Optical Molecular Materials, Topics in Organometallic Chemistry[J],2010,28:1-55
[48]Werner A. On the Constitution of Inorganic Compounds, [J]. Zeitschrift flier Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre, 1893,12:35
[49]Long E. C., Barton J. K. On demonstrating DNA intercalation[J]. Accounts of Chemical Research. 1990, V23(9):271-273
[50]Beer R. H., Jimenez J., Drago R. S. Syntheses of 2,9-bis(halomethyl-1,10- phenanthrolines:potential robust ligands for metal oxidation catalysts[J]. Journal of Organic Chemistry.1993, V58(7):1746-174
[51]Terada K., Kobayashi K., Haga M. aki.. Synthesis, electrochemical, and molecular inclusion properties of 'canopied' trinuclear ruthenium complexes with six anchoring groups on an ITO electrode[J], Dalton Transactions, 2008,4846-4854
[52]Wang W. S., Ma Y., Song H.B., et alTwo- and Three-Dimensional Lanthanide Complexes:Synthesis, Crystal Structures, and Properties[J], Inorganic Chemistry, 2007, 46:3450-3458
[53]Zhu W.H., Wang Z.M., Gao S.. Two 3D Porous Lanthanide-Fumarate-Oxalate Frameworks Exhibiting Framework Dynamics and Luminescent Change upon Reversible De- and Rehydration[J], Inorganic Chemistry, 2007,46:1337-1342
[54]Jia W.W., Luo J.H., Zhu M.L.. A Molecular Basketwork: Self-Assembly of Coordination Polymers from Zn(Ⅱ) and Biphenyl-3,40-dicarboxylate Regulated by Different Flexible Bridging and Chelating N-Donor Ancillary Ligands [J]. Cryst. Growth Des., 2011,11:2386-2397
[55]Sun X.L., Wang Z.J., Zang S.Q.,et al. A Series of Cd(Ⅱ) and Zn(Ⅱ) Coordination Polymers with Helical Subunits Assembled from a Versatile 3-(4-hydroxypyridinium-l-y1) Phthalic Acid and N-Donor Ancillary Coligands [J]. Cryst. Growth Des., 2012,12:4431-4440
[56]Ramya A. R., Sharma D., Natarajan S., et al.Highly Luminescent and Thermally Stable Lanthanide Coordination Polymers Designed from 4-(Dipyridin-2-y1)aminobenzoate: Efficient Energy Transfer from Tb3+ to Eu3+ in a Mixed Lanthanide Coordination Compound[J]. Inorg. Chem. 2012,51:8818-8826
[57]Ma X., Li X., Cha Y. E.,et al. Highly Thermostable One-Dimensional Lanthanide(Ⅲ) Coordination Polymers Constructed from Benzimidazole-5,6-dicarboxylic Acid and 1,10-Phenanthroline: Synthesis, Structure, and Tunable White-Light Emission[J]. Cryst. Growth Des. 2012,12:5227-5232
[58]Guag Y.N.,Chen X.H.,Xiang S.F.,et al. Modulating Magnetic Dynamics of Three Dy2 Complexes through Keto-Enol Tautomerism of the o-Vanillin Picolinoylhydrazone Ligand [J].Inorg.Chem.,2011,50:9705-9713
[59]Yang F.P., Fatemah P.H.H.. Planar Tetranuclear Dy(Ⅲ) Single-Molecule Magnet and Its Sm(),Gd(),and Tb() Analogues Encapsulated by Salen-Type and β-Diketonate Ligands [J].Inorg.Chem.2011,50:7059-7065
[60]Yang P.P., Gao X.F., Sun H.B., et al. Slow Magnetic Relaxation in Novel Dy4 and Dy8 Compounds[J].Inorg.Chem.2011,50:720-722
[61]Gamer M.T., Lan Y.H., Roesky P.W.,et al. Pentanuclear Dysprosium Hydroxy Cluster Showing Single-Molecule-Magnet Behavior [J].Inorg. Chem.2008,47:6581-6583
[62]Zeng Y.F., Xu G.C., Hu X.,et a.l Single-Molecule-Magnet Behavior in a Fe12Sm4 Cluster[J]. Inorg. Chem., 2010,49:9734-9736
[63]Xu G.H., He X.Y., Lv J.Y., et al. Solvent-Dependent Assemblies of Trinuclear Copper Cluster into Variable Frameworks Based on Mixed Ligands of Polyalcohol Amines Organic Carboxylates[J]. Cryst. Growth Des. 2012,12:3619-3630
[64]Huang K., Song Y.L., Pan Z.R.,et al. Porous Nonlinear-Optical Material Based on a Twin-Nest-Shaped Heterothiometallic Cluster:{[NH4][W2O2S6Cu6I3(4,4'-bipy) 4]·5H2_O}n [J].Inorg. Chemistry.,2007,46:6233-6235
[65]Xue D.X., Cairns A. J., Belmabkhout Y., et al. Tunable Rare-Earth Fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake [J]. J. Am. Chem. Soc. 2013,135:7660-7667
[66]Uchida S., Kawamoto R., Tagami H., et al. Highly Selective Sorption of Small Unsaturated Hydrocarbons by Nonporous Flexible Framework with Silver Ion[J]. J. Am. Chem. Soc.2008,130,12370-12376
[67]Mohapatra S., Rajeswaran B., Chakraborty A., et al.Bimodal Magneto-Luminescent Dysprosium (DyⅢ)-Potassium (KⅠ)-Oxalate Framework: Magnetic Switchability with High Anisotropic Barrier and Solvent Sensing[J]. Chem. Mater. 2013,25:1673-1679
[68]He H.Y., Ma H.Q., Sun D., et al.Porous Lanthanide-Organic Frameworks:Control over Interpenetration, Gas Adsorption, and Catalyst Properties [J]. Cryst. Growth Des. 2013, 13,3154-3161
[1]Gerhard F. Swiegers, Tshepo J. Malefetse, New Self-Assembled Structural Motifs in Coordination Chemistry[J], Chem. Rev. 2000,100:3483-3537
[2]Brian Moulton, Michael J. Zaworotko, From Molecules to Crystal Engineering: Supram-olecular Isomerism and Polymorphism in Network Solids[J], Chem. Rev.2001,101, 1629-1658
[3]Leininger M., Olenyuk B., Stang P. J., Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals [J], Chem. Rev.2000,100,853-908
[4]Cui G.H., Li J.R., Tian J.L.,et al. Multidimensional Metal-Organic Frameworks Construct-ed from Flexible Bis(imidazole) Ligands[J], Crystal Growth & Design,2005,5:1775-1780
[5]Zhu H.F., Fan J., Okamura T., Sun W. Y., et al. Syntheses and Structures of Zinc(Ⅱ), Silver(Ⅰ), Copper(Ⅱ), and Cobalt(Ⅱ) Complexes with Imidazole-Containing Ligand: 1-(1-Imidazolyl)-4-(imidazol-1-ylmethyl)benzene[J],CrystalGrowth& Design, 2005,5:289-294
[6]Chen B.G., Fronczek F. R. Maverick A. W. Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2 (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(Ⅱ)) [J],Chem.Commun.,2003,2166-2167
[7]Yoshizawa M., Nagao M., Umemoto K., et al. chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone[J],Chem.Commun.,2003,1808-1809
[8]Cummings S. D., Platinum complexes of terpyridine: Synthesis, structure and reactivity [J], Coordination Chemistry Reviews, 2009,253:449-478
[9]Cummings S. D., Platinum complexes of terpyridine: Interaction and reactivity with biomolecules[J], Coordination Chemistry Reviews 2009, 253:1495-1516
[10]Figgemeier E., Aranyos V., Constable E. C., et al. Modification of electron transfer properties in photoelectrochemical solar cells by substituting {Ru(terpy)2}2+ dyes with thiophene[J], Inorganic Chemical Communications, 2004,7:117-121
[11]Galoppini E., Linkers for anchoring sensitizers to semiconductor nanoparticles[J], Coordination Chemistry Reviews, 2004,248:1283-1297
[12]Gratzel M., Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells[J], Inorganic Chemistry, 2005,44:6841-6851
[13]Cooke M. W., Hanan G. S., Luminescent polynuclear assemblies [J], Chemical Society Reviews,2007,36,1466-1476
[14]Altobello S., Argazzi R., Caramori S., et al. Sensitization of Nanocrystalline TiO2 with Black Absorbers Based on Os and Ru Polypyridine Complexes[J], Journal of American Chemical Society, 2005,127,15342-15343
[15]Puntoriero F., Campagna S., Stadler A. M., et al. Luminescence properties and redox behavior of Ru(Ⅱ) molecular racks[J], Coordination Chemistry Reviews 2008, 252: 2480-2492
[16]Andres P. R., Schubert U. S.. New functional polymers and materials based on 2,2':6',2"-Terpyridines Metal Complexes[J], Advanced Materials, 2004,16:1043-1068
[17]Hammarstrom L., Johansson O.. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuⅡ polypyridine complexes[J], Coordination Chemistry Reviews, 2010,254:2546-2559
[18]Hua Feng, Xiao-Ping Zhou, Tao Wu, Dan Li, Ye-Gao Yin, Seik Weng Ng, Hydrothermal synthesis of copper complexes of 4'-pyridyl terpyridine:From discrete monomer to zigzag chain polymer[J], Inorganica Chimica Acta, 2006,359:4027-4035
[19]Paul J., Spey S., Adams H., et al. Synthesis and structure of rhodium complexes containing extended terpyridyl ligands[J], Inorganica Chimica Acta,2004,357:2827-2832
[20]Nader Noshiranzadeh, Ali Ramazani, Ali Morsali,Allen D. Hunter, Matthias Zeller,4'-(4-Pyridyl)-2,2':6',2 "-terpyridine as ligand in the lead(Ⅱ) complexes, [Pb(pyterpy)(MeOH)I2] MeOH and[Pb(pyterpy) (μ-Ac0)]2(C104)2[J], Inorganica Chimica Acta,2007,360:3603-3609
[21]Shi W. J., Hou L., Li D., et al. Supramolecular assembly driven by hydrogen-bonding and π-π stacking interactions based on copper(Ⅱ)-terpyridyl complexes[J], Inorganica Chimica Acta, 2007,360:588-598
[22]Granifo J., Garland M., Baggio R., Hydrogen bonding and p-stacking interactions in the zipper-like supramolecular structure of the monomeric cadmium(Ⅱ) complex [Cd(pyterpy)(H2O)(NO3)2] (pyterpy 4'-(4-pyridyl)-2,2':6'2"-terpyridine) [J], Inorganic Chemistry Communications 2004,7:77-81
[23]Lopez J. P., Kraus W., Reck G.,et al. Alternating perpendicular 1-D channels in the supramolecular structure of the copper(Ⅱ) complex [Cu(pyterpy)2](PF6)2 CH3OH 0.5 CH2C12 (pyterpy=4'-(4'"-pyridyl)-2,2':6',2"-terpyridine) [J], Inorganic Chemistry Communications,2005,8:281-284
[24]Luo F., Hu D.X., Xue L., et al. Pillared 3d-4f Frameworks with Rare 3D Architecture Showing the Coexistence of Ferromagnetic and Antiferromagnetic Interactions between Gadolinium Ions[J], Crystal Growth & Design,2007,7:851-853
[25]张波.三联吡啶、联吡啶和吡啶羧酸衍生物配体及其配合物的合成、结构和性质研究[D],西北大学硕士学位论文,2009
[26]Sheldrick GM.. SHELXS-97, Program for Crystal Structure Solution, University of Gottingen, Germany, 1997
[27]Sheldrick GM. SHELXL-97, Program for Crystal Structure Refinement, University of Gottingen, Germany, 1997.
[28]Sun,Y.Q.,Zhang,J.,Ju,Z.F.,etal.Two-Dimensional Noninterpenetrating Transition Metal Coordination Polymers with Large Honeycomb-like Hexagonal Cavities Constructed from a Carboxybenzyl Viologen Ligand[J],Turkey journal of Chemistry,2009,33:677-684
[29]中本一雄著,黄德如,汪仁庆译,廖代伟校.无机和配位化合物的红外和拉曼光谱[M].化学工业出版社,北京,1986
[30]Li, W., Jia, H. P., Ju, Z. F., etal.A novel Chiral CⅡ Coordination Polymer Based on Achiral Unsymmetrical 3-Amino-1,2,4-triazole with an Unprecedented μ4-Bridging Mode[J], Crystal Growth & Design,2006,6:2136-2340
[31]Schmittel M., Lin H. W., Luminescent Iridium Phenanthroline Crown Eeher Complex for the Detection of SilverⅠIions in Aqueous Media[J], Inorganic Chemistry, 2007,46: 9139-9145
[32]Kirby A. F., Foster D., Richardson F. S.. Comparison of 7FJ←5D0 Emission Spectra for Eu (Ⅲ) in Crystalline Environments of Octahedral, Near-Octahedral, and Trigonal Symmetry[J], Chemical Physics Letters, 1983,95:507-512
[1]洪茂椿,陈荣,梁文平.21世纪的无机化学[M].北京：科学出版社,2005：5-8.
[2]Das, Bharadwaj P. K. Water clusters gather luminescent zinc (Ⅱ) complexes around hydrogen-bonded framework strueture and associated fluorescence modulation[J]. Crystal Growth & Design, 2006,6:187-192
[3]Huang Y.Q., Ding B., Song H. B.,et al. Anovel 3D porous metal-organic framework Based on trinuclear cadmium clusters as a promising luminescent material exhibiting tunable emissions between UV and visible wavelengths[J].Chemical Communications, 2006, (47):4906-4908
[4]Liu X., Guo G.C., Wu A.Q., et al. Two halogeno(cyano)cuprates with long-lived and strong luminescence [J]. Inorganic Chemistry, 2005,44:4282-4286
[5]Wang Y.T., Fan H.H., Wang H.Z., et al. A solvothermally in situ generated mixed-ligand approach for NLO-active metal-organic framework materials[J]. Inorganic Chemistry, 2005,44:4148-4150
[6]Serre C., Pelle F., Gardant N., et al. Synthesis and characterization of MIL-79 and MIL-80: two new open-framework rare-earth dicarboxylates with unusual 1D inorganic subnetworks[J]. Chemistry of Materials, 2004,16:1177-1182
[7]Ko H.H., Lim J. H., Kim H. C., et al. Coexistence of spin canting and metamagnetism in a one-dimensional Mn(Ⅲ) complex bridged by a single end-to-end azide[J]. Inorganic Chemistry, 2006,45:8847-8849
[8]Liu F.C., Zeng Y.F., Li J. R., et al. Novel 3D framework nickel(Ⅱ) complex with azide, nicotinic acid, and nicotinate(1-) as coligands: hydrothermal synthesis, structure, and magnetic properties [J]. Inorganic Chemistry, 2005,44:7298-7300
[9]Murugesu M., Wernsdorfer W., Abboud K.A., et al. New struetural motifs in Manganese single-molecule magnetism from the use of triethanolamine ligands[J]. Angewandte Chemie, International Edition, 2005,44:892-896
[10]Foguet-Albiol D., O'Brien T.A., Wemsdorfer W., et al. DFT computational rationalization of an unusual spin ground state in a Mn12 single-molecule magnet with a low-symmetry loop structure[J]. Angewandte Chemie, International Edition, 2005, 44(6):897-901
[11]Monfort M., Resino I., Fallah M.S.E., et al. Synthesis, structure, and magnetic properties of three new one-dimensional nickel(Ⅱ) complexes: new magnetic model for the first one-dimensional S=1 complex with alternating
ferro-ferromagnetic coupling[J]. chemistry-A European Journal, 2001,7(1):280-287
[12]王宝成.4-吡啶基取代三联吡啶配位聚合物的合成、结构与性质研究[D].西北大学硕士学位论文,2010
[13]上官亦卿.4'-吡啶取代-三联吡啶配体配位聚合物的合成、结构与性质研究[D].西北大学硕士学位论文,2010
[14]中本一雄著,黄德如,汪仁庆译,廖代伟校.无机和配位化合物的红外和拉曼光谱[M].北京：化学工业出版社,1991,第四版
[15]Zhang J., Li Z.J., KangY., Hydrothermal Synthese, Crystal Structures, and Properties of a Novel Class of 3,3,4,4-benzophen-tetracarboxylate (BPTC) Polymers[J]. Inorganic Chemistry, 2004,43:8085-8091
[1]Zhang, J. P., Lin, Y. Y., Weng, Y. Q., et al. Copper-mediated dihydroxylation of 2,2'-bipyridine-like ligands under solvothermal conditions[J]. Inorganica Chimica Acta, 2006, 359:3666-3670
[2]Constable, E. C., Housecroft, C. E., Neuburger, M., et al. Functionalised 2,2'-bipyridine ligands for the preparation of metallostars; X-ray structures of free ligands and preparation of copper(Ⅰ) and silver(Ⅰ) complexes[J]. Polyhedron, 2003,22:93-108
[3]Liang, Y., Wang, Z. Jin, L. P., et al. Supramolecular formation by aromatic ring stacking and hydrogen bonding in lanthanide(Ⅲ) complexes with amino acids and 1,10-phenanthrolineHH[J]. Journal of Molecular Structure, 2002,616:231-239
[4]Shuku, Y., Suizu, R., Awaga, K., et al. Fe(Ⅱ) spincrossover complex of [1,2,5] thiadiazolo [3,4-f][1,10] phenanthroline[J]. CrystEngComm, 2009,11:2065-2068
[5]Constable, E. C., Zhang, G. Q., Housecroft, C. E., et al. Phase-separated hydrogen-bonded chloride ion-water-oxonium ion sheets and protonated 4'-(4-bromophenyl)-2,2':6',2"-terpyridine stacks, and condensation products of 2-acetyl pyridine and benzaldehydes revisited[J]. CrystEngComm, 2009,11:1014-1021
[6]Constable, E. C., Housecroft, C. E., Medlycott, E., et al. The first complex of 4'-(4-methylthiophenyl)-2,2':6',2"-terpyridine-A model for terpylated self-assembled monolayers[J]. Inorganic Chemistry Communications, 2008,11:518-520
[7]Orain, P. Y., Capon, J. F., Kervarec, N., et al. HUse of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active siteH[J]. Dalton Transactions,2007,3754-3756
[8]Berthet, J. C., Nierlich, M., Miquel, Y, et al. Selective complexation of uranium(Ⅲ) over lanthanide(Ⅲ) triflates by 2,2':6',2"-terpyridine. X-Ray crystal structures of [M(OTf)3(terpy)2] and [M(OTf)2(terpy)2(py)][OTf] (M=Nd, Ce, U) and of polynuclear μ-oxo uranium(Ⅳ) complexes resulting from hydrolysis [J]. Dalton Transactions, 2005,369-379
[9]Margan, T. G., Burstall, F. H., Heterocyclic Systems Containing Selenium. PartⅣ. Cyclo Selenohexane[J]. J. Chem. Soc.,1931:173-180
[10]Winter, A., Friebe, C., Chiper, M., et al. Synthesis, Characterization, and Electro-Optical Properties of ZnⅡ Complexes with π-Conjugated Terpyridine Ligands[J]. ChemPhysChem, 2009,10:787-798
[11]Hong. Y., Chen. S. J., Tung L. C. W., et al. Fluorogenic Zn(Ⅱ) and Chromogenic Fe(Ⅱ) Sensors Based on Terpyridine-Substituted Tetraphenylethenes with Aggregation-Induced Emission Characteristics[J]. Materials Interfaces. 2011,3:3411-3418
[12]Maier. A., Tieke. B. Coordinative Layer-by-Layer Assembly of Electrochromic Thin Films based on Metal Ion Complexes of Terpyridine-Substituted Polyaniline Derivatives[J], Journal of Physical Chemistry B. 2012,116:925-934
[13]Heine. J., Gunne. J. S., Dehnen. S., Formation of a Strandlike Polycatenane of Icosahedral Cages for Reversible One-Dimensional Encapsulation of Guests[J]. Journal of the American Chemical Society. 2011,133:10018-10021
[14]张林,王国松,刘伟民等,2,2'：6',2"-三联吡啶衍生物配体的合成及研究[J].山西大学学报(自然科学版),2007,30：68-70
[15]蔡小华,张国林,无溶剂一锅法合成1,4-二氢吡啶[J].有机化学,2005,25：930-933
[16]敬炳文,吴韬,张曼华等,功能性多吡啶配体的合成[J].高等学校化学学报,2000,21：395-400
[17]中本一雄著,黄德如,汪仁庆译,无机和配位化合物的红外和拉曼光谱[M].北京,化学工业出版社,1991,第四版
[18]W. Goodall, J.Williams, A new highly fluorescent terpyridine which responds to zinc ions with a large red-shift in emission [J].Chemical Communications,2001,2514-2515.
[19]Zhang J., Li Z.J., KangY., Hydrothermal Synthese, Crystal Structures, and Properties of a Novel Class of 3,3,4,4-benzophen-tetracarboxylate (BPTC) Polymers [J]. Inorganic Chemistry, 2004,43:8085-8091
[1]Zhao B., Cheng P., Chen X. Y., et al. Design and Synthesis of 3d-4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated "Water" Pipe [J]. Journal of the American Chemical Society, 2004,10:3012-3013
[2]Koner R., Lee G. H., Wang Y., et al. Two New Diphenoxo-Bridged Discrete Dinuclear CuⅡGdⅢ Compounds with Cyclic Diimino Moieties: Syntheses, Structures, and Magnetic Properties [J]. European Journal of Inorganic Chemistry, 2005,8:1500-1505
[3]Song Y. S., Yan B., Weng L. H. Synthesis and crystal structure of a novel two-dimensional 3d-4f heterometallic coordination polymer constructed from three-ply-like layers [J]. Inorganic Chemistry Communications, 2006,6:567-570
[4]Liang Y. C., Cao R., Su W. P., et al. Syntheses, Structures, and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(Ⅱ) Coordination Polymers by a Hydrothermal Reaction [J]. Angewandte Chemie, International Edition, 2000,18:3304-3307
[5]Caravan P., Ellison J. J., McMurry T. J., et al. Gadolinium(Ⅲ) Chelates as MRI Contrast Agents Structure, Dynamics, and Applications [J]. Chemical Reviews, 1999,99: 2293-2352
[6]Costes J. P., DupuisA., Laurent J. P. A Very-High-Spin Molecule: Preparation, Characterization and Magnetic Properties of an FeⅢ-GdⅢ Complex with an S=12/2 Ground State [J]. European Journal of Inorganic Chemistry, 1998,10:1543-1546
[7]潘勤鹤,李激扬,于吉红等.具有氢键假想孔道结构的[M(en)3][GeF6](M=Ni,Co)的合成与表征[J].高等学校化学学报,2005,12：2199-2202
[8]Zaleski C. M., Depperman E. C., Kampf J. W., et al. Synthesis, Structure, and Magnetic Properties of a Large Lanthanide-Transition-Metal Single-Molecule Magnet [J]. Angewandte Chemie, International Edition,2004,30:3912-3914
[9]Mori F., Nyui T., Ishida T., et al. Oximate-Bridged Trinuclear Dy-Cu-Dy Complex Behaving as a Single-Molecule Magnet and Its Mechanistic Investigation [J]. Journal of the American Chemical Society, 2006,5:1440-1441
[10]Costes J. P., Dahan F., Wernsdorfer W. Heterodinuclear Cu-Tb Single-Molecule Magnet [J]. Inorganic Chemistry, 2006,1:5-7
[11]Mishra A., Wernsdorfer W., Parsons S., et al. The search for 3d-4f single-molecule magnets:synthesis, structure and magnetic properties of a [MnⅢ2DyⅢ2] cluster [J]. Chemical Communications,2005:2086-2088
[12]Aronica C., Pilet G., Chastanet G., et al. A Nonanuclear Dysprosium(Ⅲ)-Copper(Ⅱ) Complex Exhibiting Single-Molecule Magnet Behavior with Very Slow Zero-Field Relaxation [J]. Angewandte Chemie, International Edition, 2006,28:4659-4662
[13]Takashi K., Motohiro N., Shinya T., et al. Coordination-Tuned Single-Molecule-Magnet Behavior of TbⅢ-CuⅡ Dinuclear Systems[J]. Inorg. Chem.2008,47:8604-8606
[14]Vadapalli C., Balasubramanian M. P., Ramamoorthy B., et al. Trinuclear Hetero bimet-allic Ni2Ln complexes [L2Ni2Ln][C104] (Ln) La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3) (S)P[N(Me)NdCH-C6H3-2-OH-3-OMe]3):From Simple Paramagnetic Co-mplexes to Single-Molecule Magnet Behavior[J]. Inorg. Chem.2008,47:4918-4929
[15]Tomoka Y.,Yukinari S., Hiroyuki I., et al. Synthesis, Structures, and Magnetic Properties of Face-SharingHeterodinuclear Ni(Ⅱ)-Ln(Ⅲ) (Ln) Eu, Gd, Tb, Dy) Complexes[J]. Ino-rg. Chem.2008,47:5736-5745
[16]Tomoka Y.,Jean-Pierre C., Yukana K., et al. Face-Sharing Heterotrinuclear MⅡ-LnⅢ-MⅡ(M=Mn, Fe, Co, Zn; Ln=La, Gd, Tb, Dy) Complexes: Synthesis, Structures, and Magnetic Properties[J]. Inorg. Chem.2010,49:9125-9135
[17]David E. F., John R. T., Casellato U. Metal Complexes of Tetrakonates and their Schiff Bases [J]. Inorganica Chimica Acta, 1984,83:23-31
[18]Yamazaki S., Hanada M., Yanase Y., et al. A Simple Synthesis of Novel Extraction Reagents.4-Acyl-5-Pyrazolone-Substituted Crown Ethers [J]. Journal of the Chemical Society, Perkin Transactions 1:Organic and Bio-Organic Chemistry, 1999,6:693-696
[19]Fenton, D. E., Casellato U., Vigato P., et al. The Evolution of Binucleating Ligands [J]. Inorganica Chimica Acta, 1982,1:57-66
[20]Aromi G., Gamez P., Roubeau O., et al. Ligand-templated four-metal chains dimerize into a unique [CuⅡ8] cluster [J]. Angewandte Chemie, International Edition, 2002,41: 1168-1170
[21]Fenton D. E., Regan C. M. Umberto Casellato and. Binuclear Complexes of Tetrakonates [J]. Inorganica Chimica Acta, 1982,58,:83-88.
[22]Aromi G., Gamez P., Krzystek J., et al. Novel Linear Transition Metal Clusters of a Heptadentate Bis-β-diketone Ligand [J]. Inorganic Chemistry, 2007,46:2519-2529
[23]Dams H., Clunas S., Fenton D. E., et al. A Tetranuclear Nickel(Ⅱ) Complex Sembled from an Asymmetric Compartmental Ligand and Bearing an Intramolecular [H3O2]-Bridge [J]. Chemical communications (Cambridge, England), 2002,5:418-419
[2]Braga D., Brammer L., Champness N. R.. New trends in crystal engineering CrystEngComm, 2005,7:1-19.
[3]Chen B. L., Wang L. B., Xia, Y. Q., et al. A Luminescent Metal-Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions[J], Angewandte Chemie International Edition, 2009,48:500-503
[4]周秋香,王延吉,赵新强等.多纳米孔道配位聚合物的研究进展[J].化学通报,2003,66：1-7
[5]陈小明,蔡继文.单晶结构分析原理与实践(第二版)[M].北京：科学出版社,2007
[6]陈荣,高松.无机化学学科前沿与展望[M].北京：科学出版社,2012
[7]Zou L. F., Zhao L., Guo Y.N.,et al. A dodecanuclear heterometallic dysprosium-cobalt wheel exhibiting single-molecule magnet behaviour [J]. Chem. Commun, 2011, 47:8659-8661
[8]Sanz S., Ferreira K., Ruaraidh D.et al. Calix[4]arene-supported FeⅢ2LnⅢ2 clusters [J]. Chem. Commun, 2011,47:9042-9044
[9]Mereacre V. M., Ako A. M., Cle'rac R., et al. A Bell-Shaped Mn11Gd2 Single-Molecule Magnet [J]. J. AM. CHEM. SOC. 2007,129:9248-9249
[10]Jami A. K., Kishore P.V.N., Baskar V. Functionalised β-diketone assisted self-assembly of a hexanuclear yttriumoxo-hydroxo cluster [J]. Polyhedron, 2009,28:2284-2286
[11]Chen X.Y., Yang X.P., Holliday B. J. Metal-Controlled Assembly of Near Infrared Em-itting Pentanuclear Lanthanide β-Diketone Clusters[J]. Inorganic Chemistry, 2010, 49(6):2583-2585
[12]Tian A. X., Ying J., Peng J., et al. Using Flexible and Rigid Organic Ligands to Tune Topology Structures Based on Keggin Polyoxometalates[J]. Crystal Growth & Design, 2010,10(3):1104-1110
[13]Sen R., Mal D., Brandao P.,et al. Cadmium-Furandicarboxylate Coordination Polymers Prepared with Different Types of Pyridyl Linkers:Synthesis, Divergent Dimensionalities, and Luminescence Study [J]. Crystal Growth & Design, 2013,13:5271-5281
[14]Dai F.N., He H.Y., Zhao X.L.,et al. 1D zigzag chain vs. 1D helical chain: the role of the supramolecular interactions on the formation of chiral architecture [J]. CrystEngComm, 2010,12:337-340
[15]Hu H., Zhang R.H., Yang F.,et al. Synthesis, structure and magnetic properties of hete-rometallic coordination polymers constructed from Cu (Ⅱ)/Mn (Ⅱ), H2bdc and Hjbtec [J]. Inorganic Chemistry Communications, 2014,40:87-91
[16]Meng X.R., Wu X.J., Li D. W.,et al. Influence of the anion on the coordination mode of an unsymmetrical N-heterocyclic ligand in Cd(Ⅱ) complexes: From discrete molecule to one-and two-dimensional structures [J]. Polyhedron,2010,29:2619-262
[17]Ma L.F., Wang L.Y., Hu J.L.,et al. Syntheses, Structures, and Photoluminescence of a Se-ries of d10 Coordination Polymers with R-Isophthalate (R=-OH,-CH3, and-C(CH3)3) [J]. Crystal Growth & Design, 2009,9(12):5334-5342
[18]Wang X.L., Luan J., Sui F.F.,et al. Structural Diversities and Fluorescent and Photo cata-lytic Properties of a Series of CuⅡ Coordination Polymers Constructed from Flexible Bis-py ridyl-bis-amide Ligands with Different Spacer Lengths and Different Aromatic Carbo-xylates [J]. Crystal Growth & Design, 2013,13:3561-3576
[19]Sun Y.Q., Xu Y.Y., Gao D.Z.,et al. 2D Coordination polymers of macrocyclic oxamide with polycarboxylates:syntheses, crystal structures and magnetic properties [J]. Dalton Trans.,2012,41:5704-5714
[20]Jin X.H., Sun J.K., Cai L. X.,et al.2D flexible metal-organic frameworks with [Cd2. (μ2-X)2](X=Cl or Br) units exhibiting selective fluorescence sensing for small molecules[J]. Chem. Commun.,2011,47:2667-2669
[21]Zhang K.L., Zhang J.B., Jing C.Y.,et al. Synthesis, structures and properties of a family of four two-dimensional coordination polymers constructed from 5-hydroxyisophthalate [J]. Journal of Solid State Chemistry 2014,211:8-20
[22]Dai M., Su X.R., Wang X.,et al. Three Zinc(Ⅱ) Coordination Polymers Based on Tetrakis (4-pyridyl)cyclobutane and Naphthalenedicarboxylate Linkers: Solvothermal Syntheses, Structures, and Photocatalytic Properties [J]. Crystal Growth & Design, 2014,14:240-248
[23]Xiong W.W., Athresh E. U., Ng Y.T.,et al. Growing Crystalline Chalcogenidoarsenates in Surfactants: FromZero-Dimensional Cluster to Three-Dimensional Framework [J]. J. Am. Chem. Soc.,2013,135:1256-1259
[24]Qin L., Hu J.S., Li Y.Z.,et al. Effect of Carboxylate Coligands with Different Rigidity on upramolecular Architectures Based on One Rigid Didentate Linear igand [J]. Crystal Gro-wth & Design, 2012,12:403-413
[25]Li Y.W., Ma H., Chen Y.Q.,et al. Structure Modulation in Zn(Ⅱ)-1,4-Bis(imidazol-l-yl) benzene Frameworks by Varying Dicarboxylate Anions [J]. Cryst. Growth Des.,2012, 12:189-196
[26]Lee H. Y., Park J., Lah M. S., et al. One-Dimensional Double Helical Structure and 4-Fold Type [2+2] Interpenetration of Diamondoid Networks with Helical Fashion [J]. Crystal Growth & Design, 2008,2, (8):587-591
[27]Maji T. K., Ohba M., Kitagawa S.. Transformation from a 2D Stacked Layer to 3D Int-erpenetrated Framework by Changing the Spacer Functionality: Synthesis, Structure, Ad-sorption, and Magnetic Properties [J]. Inorganic Chemistry,44:9225-9231
[28]Wang H.Y., Gao S., Huo L.H., et al. Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal. [J]. Cryst. Growth Des., 2008,2, (8):665-670
[29]Christiane O., Buchecker D., Sauvage J.P.. Templated Synthesis of Interlocked Mac rocyclicLigands: The Catenands [J]. J. Am. Chem. Soc. 1984,106:3045-3046
[30]J. P. Collman, P. J. Brothers, L. McElwee-White, E. Rose [J]. J. Am. Chem. Soc. 1985, 107:6110-6111
[31]Armaroli N., Balzani V., Barigelletti J.,et al. Supramolecular Photochemistry and Phot ophysics. A [3]-Catenand and Its Mononuclear and Homo-and Heterodinuclear [3]-Catenates [J]. J. Am. Chem. Soc.1994,116:5211-5217
[32]Whang D., Kim K.. Polycatenated Two-Dimensional Polyrotaxane Net [J]. J. Am. Chem. Soc.1997,119:451-452
[33]Tong M.L., Chen X.M., Ye B.H.. Helical Silver(Ⅰ)-2,4'-Bipyridine Chains Organized into 2-D Networks by Metal-Counterion or Metal-Metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X-) NO3-or ClO4-) [J]. Inorg. Chem.,1998, 37:5278-5281
[34]Carlucci L., Ciani G., Gudenberg D. W., et al. Self-Assembly of Infinite Double Helical and Tubular Coordination Polymers from Ag(CF3SO3) and 1,3-Bis(4-pyridyl)propane [J]. Inorg. Chem.,1997,36:3812-3813.
[35]Zang S.Q., Su Y., Li Y.Z.,et al. Interweaving of Triple-Helical and Extended Metal-O-Metal Single-Helical Chains with the Same Helix Axis in a 3D Metal-Organic Frame work [J]. Inorg. Chem.,45:3855-3857
[36]Wu H., Liu H.Y., Yang J.,et al. Series of Coordination Polymers Based on Different Carboxylates and a Tri(4-imidazolylphenyl)amine Ligand:Entangled Structures and Photoluminescence [J]. Cryst. Growth Des.,2011,11:2317-2324
[37]Xu C.Y., Li T., Wang Y.,et al. Three-Dimensional Cd(II) Coordination Polymers Based on Semirigid Bis(Methylbenzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties [J]. Cryst. Growth Des.,2011, 11:4667-4675
[38]Park J. H., Lee W. R., Ryu D.W.,et al. Sulfate-Incorporated Co(Ⅱ) Coordination Frame-works with Bis-imidazole Bridging Ligands Constructed by Covalent and Noncovalent Interactions [J]. Cryst. Growth Des.,2012,12:2691-2698
[39]Wang X.S., Zhao H., Qu Z.R.,et al. An Unprecedented 8-Fold Interpenetrating Diamon doid-like CoordinationPolymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node [J]. Inorganic Chemistry,2003,42:5786-5788
[40]Wang H.Y., Gao S., Huo L.H.,et al. Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal [J]. Cryst. Growth Des., 2008,8: 665-670
[41]Pasatoiu T. D., Tiseanu C., Madalan A. M.,et al. Study of the Luminescent and Magnetic Properties of a Series of Heterodinuclear [ZnⅡLnⅢ] Complexes [J]. Inorganic Chemistry, 2011,50(13):5879-5889
[42]Li D.M., Zhou W., Xu G.Y.,et al. Dinuclear (bis-β-diketonato)Ni(Ⅱ) and Cu(Ⅱ) coordin-ation complexes with different 3D supramolecular structures incorporating 1D columns [J]. Journal of Molecular Structure 2009,929:120-124
[43]Lu W.G., Jiang L., Lu T.B.. Lanthanide Contraction and Temperature-Dependent Struct-ures of Lanthanide Coordination Polymers with Imidazole-4,5-Dicarboxylate and Oxalate[J]. [J]. Crystal Growth & Design, 2010,10:4310-4318
[44]Hammarstrom L., Johansson O.. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuⅡ polypyridine complexes[J], Coordination Chemistry Reviews, 2010,254:2546-2559
[45]Leth J. M. Cardiac Changes in Muscular Dystrophy [J]. Nordisk medicin, 1971,86(50): 1544-1546
[46]Mantel C., Baffert C., Romero I., et al. Structural Characterization and Electronic Properties Determination by High-Field and High-Frequency EPR of a Series of Five-Coordinated Mn(Ⅱ) Complexes[J]. Inorganic Chemistry, 2004, V43(20):6455-6463
[47]Di Bella. S., Dragonetti C., Pizzotti M.. Coordination and Organometallic Complexes as Second-Order Nonlinear Optical Molecular Materials, Topics in Organometallic Chemistry[J],2010,28:1-55
[48]Werner A. On the Constitution of Inorganic Compounds, [J]. Zeitschrift flier Physikalische Chemie, Stoechiometrie und Verwandtschaftslehre, 1893,12:35
[49]Long E. C., Barton J. K. On demonstrating DNA intercalation[J]. Accounts of Chemical Research. 1990, V23(9):271-273
[50]Beer R. H., Jimenez J., Drago R. S. Syntheses of 2,9-bis(halomethyl-1,10- phenanthrolines:potential robust ligands for metal oxidation catalysts[J]. Journal of Organic Chemistry.1993, V58(7):1746-174
[51]Terada K., Kobayashi K., Haga M. aki.. Synthesis, electrochemical, and molecular inclusion properties of 'canopied' trinuclear ruthenium complexes with six anchoring groups on an ITO electrode[J], Dalton Transactions, 2008,4846-4854
[52]Wang W. S., Ma Y., Song H.B., et alTwo- and Three-Dimensional Lanthanide Complexes:Synthesis, Crystal Structures, and Properties[J], Inorganic Chemistry, 2007, 46:3450-3458
[53]Zhu W.H., Wang Z.M., Gao S.. Two 3D Porous Lanthanide-Fumarate-Oxalate Frameworks Exhibiting Framework Dynamics and Luminescent Change upon Reversible De- and Rehydration[J], Inorganic Chemistry, 2007,46:1337-1342
[54]Jia W.W., Luo J.H., Zhu M.L.. A Molecular Basketwork: Self-Assembly of Coordination Polymers from Zn(Ⅱ) and Biphenyl-3,40-dicarboxylate Regulated by Different Flexible Bridging and Chelating N-Donor Ancillary Ligands [J]. Cryst. Growth Des., 2011,11:2386-2397
[55]Sun X.L., Wang Z.J., Zang S.Q.,et al. A Series of Cd(Ⅱ) and Zn(Ⅱ) Coordination Polymers with Helical Subunits Assembled from a Versatile 3-(4-hydroxypyridinium-l-y1) Phthalic Acid and N-Donor Ancillary Coligands [J]. Cryst. Growth Des., 2012,12:4431-4440
[56]Ramya A. R., Sharma D., Natarajan S., et al.Highly Luminescent and Thermally Stable Lanthanide Coordination Polymers Designed from 4-(Dipyridin-2-y1)aminobenzoate: Efficient Energy Transfer from Tb3+ to Eu3+ in a Mixed Lanthanide Coordination Compound[J]. Inorg. Chem. 2012,51:8818-8826
[57]Ma X., Li X., Cha Y. E.,et al. Highly Thermostable One-Dimensional Lanthanide(Ⅲ) Coordination Polymers Constructed from Benzimidazole-5,6-dicarboxylic Acid and 1,10-Phenanthroline: Synthesis, Structure, and Tunable White-Light Emission[J]. Cryst. Growth Des. 2012,12:5227-5232
[58]Guag Y.N.,Chen X.H.,Xiang S.F.,et al. Modulating Magnetic Dynamics of Three Dy2 Complexes through Keto-Enol Tautomerism of the o-Vanillin Picolinoylhydrazone Ligand [J].Inorg.Chem.,2011,50:9705-9713
[59]Yang F.P., Fatemah P.H.H.. Planar Tetranuclear Dy(Ⅲ) Single-Molecule Magnet and Its Sm(),Gd(),and Tb() Analogues Encapsulated by Salen-Type and β-Diketonate Ligands [J].Inorg.Chem.2011,50:7059-7065
[60]Yang P.P., Gao X.F., Sun H.B., et al. Slow Magnetic Relaxation in Novel Dy4 and Dy8 Compounds[J].Inorg.Chem.2011,50:720-722
[61]Gamer M.T., Lan Y.H., Roesky P.W.,et al. Pentanuclear Dysprosium Hydroxy Cluster Showing Single-Molecule-Magnet Behavior [J].Inorg. Chem.2008,47:6581-6583
[62]Zeng Y.F., Xu G.C., Hu X.,et a.l Single-Molecule-Magnet Behavior in a Fe12Sm4 Cluster[J]. Inorg. Chem., 2010,49:9734-9736
[63]Xu G.H., He X.Y., Lv J.Y., et al. Solvent-Dependent Assemblies of Trinuclear Copper Cluster into Variable Frameworks Based on Mixed Ligands of Polyalcohol Amines Organic Carboxylates[J]. Cryst. Growth Des. 2012,12:3619-3630
[64]Huang K., Song Y.L., Pan Z.R.,et al. Porous Nonlinear-Optical Material Based on a Twin-Nest-Shaped Heterothiometallic Cluster:{[NH4][W2O2S6Cu6I3(4,4'-bipy) 4]·5H2_O}n [J].Inorg. Chemistry.,2007,46:6233-6235
[65]Xue D.X., Cairns A. J., Belmabkhout Y., et al. Tunable Rare-Earth Fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake [J]. J. Am. Chem. Soc. 2013,135:7660-7667
[66]Uchida S., Kawamoto R., Tagami H., et al. Highly Selective Sorption of Small Unsaturated Hydrocarbons by Nonporous Flexible Framework with Silver Ion[J]. J. Am. Chem. Soc.2008,130,12370-12376
[67]Mohapatra S., Rajeswaran B., Chakraborty A., et al.Bimodal Magneto-Luminescent Dysprosium (DyⅢ)-Potassium (KⅠ)-Oxalate Framework: Magnetic Switchability with High Anisotropic Barrier and Solvent Sensing[J]. Chem. Mater. 2013,25:1673-1679
[68]He H.Y., Ma H.Q., Sun D., et al.Porous Lanthanide-Organic Frameworks:Control over Interpenetration, Gas Adsorption, and Catalyst Properties [J]. Cryst. Growth Des. 2013, 13,3154-3161
[1]Gerhard F. Swiegers, Tshepo J. Malefetse, New Self-Assembled Structural Motifs in Coordination Chemistry[J], Chem. Rev. 2000,100:3483-3537
[2]Brian Moulton, Michael J. Zaworotko, From Molecules to Crystal Engineering: Supram-olecular Isomerism and Polymorphism in Network Solids[J], Chem. Rev.2001,101, 1629-1658
[3]Leininger M., Olenyuk B., Stang P. J., Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals [J], Chem. Rev.2000,100,853-908
[4]Cui G.H., Li J.R., Tian J.L.,et al. Multidimensional Metal-Organic Frameworks Construct-ed from Flexible Bis(imidazole) Ligands[J], Crystal Growth & Design,2005,5:1775-1780
[5]Zhu H.F., Fan J., Okamura T., Sun W. Y., et al. Syntheses and Structures of Zinc(Ⅱ), Silver(Ⅰ), Copper(Ⅱ), and Cobalt(Ⅱ) Complexes with Imidazole-Containing Ligand: 1-(1-Imidazolyl)-4-(imidazol-1-ylmethyl)benzene[J],CrystalGrowth& Design, 2005,5:289-294
[6]Chen B.G., Fronczek F. R. Maverick A. W. Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2 (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(Ⅱ)) [J],Chem.Commun.,2003,2166-2167
[7]Yoshizawa M., Nagao M., Umemoto K., et al. chain-directed assembly of triangular molecular panels into a tetrahedron vs. open cone[J],Chem.Commun.,2003,1808-1809
[8]Cummings S. D., Platinum complexes of terpyridine: Synthesis, structure and reactivity [J], Coordination Chemistry Reviews, 2009,253:449-478
[9]Cummings S. D., Platinum complexes of terpyridine: Interaction and reactivity with biomolecules[J], Coordination Chemistry Reviews 2009, 253:1495-1516
[10]Figgemeier E., Aranyos V., Constable E. C., et al. Modification of electron transfer properties in photoelectrochemical solar cells by substituting {Ru(terpy)2}2+ dyes with thiophene[J], Inorganic Chemical Communications, 2004,7:117-121
[11]Galoppini E., Linkers for anchoring sensitizers to semiconductor nanoparticles[J], Coordination Chemistry Reviews, 2004,248:1283-1297
[12]Gratzel M., Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells[J], Inorganic Chemistry, 2005,44:6841-6851
[13]Cooke M. W., Hanan G. S., Luminescent polynuclear assemblies [J], Chemical Society Reviews,2007,36,1466-1476
[14]Altobello S., Argazzi R., Caramori S., et al. Sensitization of Nanocrystalline TiO2 with Black Absorbers Based on Os and Ru Polypyridine Complexes[J], Journal of American Chemical Society, 2005,127,15342-15343
[15]Puntoriero F., Campagna S., Stadler A. M., et al. Luminescence properties and redox behavior of Ru(Ⅱ) molecular racks[J], Coordination Chemistry Reviews 2008, 252: 2480-2492
[16]Andres P. R., Schubert U. S.. New functional polymers and materials based on 2,2':6',2"-Terpyridines Metal Complexes[J], Advanced Materials, 2004,16:1043-1068
[17]Hammarstrom L., Johansson O.. Expanded bite angles in tridentate ligands. Improving the photophysical properties in bistridentate RuⅡ polypyridine complexes[J], Coordination Chemistry Reviews, 2010,254:2546-2559
[18]Hua Feng, Xiao-Ping Zhou, Tao Wu, Dan Li, Ye-Gao Yin, Seik Weng Ng, Hydrothermal synthesis of copper complexes of 4'-pyridyl terpyridine:From discrete monomer to zigzag chain polymer[J], Inorganica Chimica Acta, 2006,359:4027-4035
[19]Paul J., Spey S., Adams H., et al. Synthesis and structure of rhodium complexes containing extended terpyridyl ligands[J], Inorganica Chimica Acta,2004,357:2827-2832
[20]Nader Noshiranzadeh, Ali Ramazani, Ali Morsali,Allen D. Hunter, Matthias Zeller,4'-(4-Pyridyl)-2,2':6',2 "-terpyridine as ligand in the lead(Ⅱ) complexes, [Pb(pyterpy)(MeOH)I2] MeOH and[Pb(pyterpy) (μ-Ac0)]2(C104)2[J], Inorganica Chimica Acta,2007,360:3603-3609
[21]Shi W. J., Hou L., Li D., et al. Supramolecular assembly driven by hydrogen-bonding and π-π stacking interactions based on copper(Ⅱ)-terpyridyl complexes[J], Inorganica Chimica Acta, 2007,360:588-598
[22]Granifo J., Garland M., Baggio R., Hydrogen bonding and p-stacking interactions in the zipper-like supramolecular structure of the monomeric cadmium(Ⅱ) complex [Cd(pyterpy)(H2O)(NO3)2] (pyterpy 4'-(4-pyridyl)-2,2':6'2"-terpyridine) [J], Inorganic Chemistry Communications 2004,7:77-81
[23]Lopez J. P., Kraus W., Reck G.,et al. Alternating perpendicular 1-D channels in the supramolecular structure of the copper(Ⅱ) complex [Cu(pyterpy)2](PF6)2 CH3OH 0.5 CH2C12 (pyterpy=4'-(4'"-pyridyl)-2,2':6',2"-terpyridine) [J], Inorganic Chemistry Communications,2005,8:281-284
[24]Luo F., Hu D.X., Xue L., et al. Pillared 3d-4f Frameworks with Rare 3D Architecture Showing the Coexistence of Ferromagnetic and Antiferromagnetic Interactions between Gadolinium Ions[J], Crystal Growth & Design,2007,7:851-853
[25]张波.三联吡啶、联吡啶和吡啶羧酸衍生物配体及其配合物的合成、结构和性质研究[D],西北大学硕士学位论文,2009
[26]Sheldrick GM.. SHELXS-97, Program for Crystal Structure Solution, University of Gottingen, Germany, 1997
[27]Sheldrick GM. SHELXL-97, Program for Crystal Structure Refinement, University of Gottingen, Germany, 1997.
[28]Sun,Y.Q.,Zhang,J.,Ju,Z.F.,etal.Two-Dimensional Noninterpenetrating Transition Metal Coordination Polymers with Large Honeycomb-like Hexagonal Cavities Constructed from a Carboxybenzyl Viologen Ligand[J],Turkey journal of Chemistry,2009,33:677-684
[29]中本一雄著,黄德如,汪仁庆译,廖代伟校.无机和配位化合物的红外和拉曼光谱[M].化学工业出版社,北京,1986
[30]Li, W., Jia, H. P., Ju, Z. F., etal.A novel Chiral CⅡ Coordination Polymer Based on Achiral Unsymmetrical 3-Amino-1,2,4-triazole with an Unprecedented μ4-Bridging Mode[J], Crystal Growth & Design,2006,6:2136-2340
[31]Schmittel M., Lin H. W., Luminescent Iridium Phenanthroline Crown Eeher Complex for the Detection of SilverⅠIions in Aqueous Media[J], Inorganic Chemistry, 2007,46: 9139-9145
[32]Kirby A. F., Foster D., Richardson F. S.. Comparison of 7FJ←5D0 Emission Spectra for Eu (Ⅲ) in Crystalline Environments of Octahedral, Near-Octahedral, and Trigonal Symmetry[J], Chemical Physics Letters, 1983,95:507-512
[1]洪茂椿,陈荣,梁文平.21世纪的无机化学[M].北京：科学出版社,2005：5-8.
[2]Das, Bharadwaj P. K. Water clusters gather luminescent zinc (Ⅱ) complexes around hydrogen-bonded framework strueture and associated fluorescence modulation[J]. Crystal Growth & Design, 2006,6:187-192
[3]Huang Y.Q., Ding B., Song H. B.,et al. Anovel 3D porous metal-organic framework Based on trinuclear cadmium clusters as a promising luminescent material exhibiting tunable emissions between UV and visible wavelengths[J].Chemical Communications, 2006, (47):4906-4908
[4]Liu X., Guo G.C., Wu A.Q., et al. Two halogeno(cyano)cuprates with long-lived and strong luminescence [J]. Inorganic Chemistry, 2005,44:4282-4286
[5]Wang Y.T., Fan H.H., Wang H.Z., et al. A solvothermally in situ generated mixed-ligand approach for NLO-active metal-organic framework materials[J]. Inorganic Chemistry, 2005,44:4148-4150
[6]Serre C., Pelle F., Gardant N., et al. Synthesis and characterization of MIL-79 and MIL-80: two new open-framework rare-earth dicarboxylates with unusual 1D inorganic subnetworks[J]. Chemistry of Materials, 2004,16:1177-1182
[7]Ko H.H., Lim J. H., Kim H. C., et al. Coexistence of spin canting and metamagnetism in a one-dimensional Mn(Ⅲ) complex bridged by a single end-to-end azide[J]. Inorganic Chemistry, 2006,45:8847-8849
[8]Liu F.C., Zeng Y.F., Li J. R., et al. Novel 3D framework nickel(Ⅱ) complex with azide, nicotinic acid, and nicotinate(1-) as coligands: hydrothermal synthesis, structure, and magnetic properties [J]. Inorganic Chemistry, 2005,44:7298-7300
[9]Murugesu M., Wernsdorfer W., Abboud K.A., et al. New struetural motifs in Manganese single-molecule magnetism from the use of triethanolamine ligands[J]. Angewandte Chemie, International Edition, 2005,44:892-896
[10]Foguet-Albiol D., O'Brien T.A., Wemsdorfer W., et al. DFT computational rationalization of an unusual spin ground state in a Mn12 single-molecule magnet with a low-symmetry loop structure[J]. Angewandte Chemie, International Edition, 2005, 44(6):897-901
[11]Monfort M., Resino I., Fallah M.S.E., et al. Synthesis, structure, and magnetic properties of three new one-dimensional nickel(Ⅱ) complexes: new magnetic model for the first one-dimensional S=1 complex with alternating
ferro-ferromagnetic coupling[J]. chemistry-A European Journal, 2001,7(1):280-287
[12]王宝成.4-吡啶基取代三联吡啶配位聚合物的合成、结构与性质研究[D].西北大学硕士学位论文,2010
[13]上官亦卿.4'-吡啶取代-三联吡啶配体配位聚合物的合成、结构与性质研究[D].西北大学硕士学位论文,2010
[14]中本一雄著,黄德如,汪仁庆译,廖代伟校.无机和配位化合物的红外和拉曼光谱[M].北京：化学工业出版社,1991,第四版
[15]Zhang J., Li Z.J., KangY., Hydrothermal Synthese, Crystal Structures, and Properties of a Novel Class of 3,3,4,4-benzophen-tetracarboxylate (BPTC) Polymers[J]. Inorganic Chemistry, 2004,43:8085-8091
[1]Zhang, J. P., Lin, Y. Y., Weng, Y. Q., et al. Copper-mediated dihydroxylation of 2,2'-bipyridine-like ligands under solvothermal conditions[J]. Inorganica Chimica Acta, 2006, 359:3666-3670
[2]Constable, E. C., Housecroft, C. E., Neuburger, M., et al. Functionalised 2,2'-bipyridine ligands for the preparation of metallostars; X-ray structures of free ligands and preparation of copper(Ⅰ) and silver(Ⅰ) complexes[J]. Polyhedron, 2003,22:93-108
[3]Liang, Y., Wang, Z. Jin, L. P., et al. Supramolecular formation by aromatic ring stacking and hydrogen bonding in lanthanide(Ⅲ) complexes with amino acids and 1,10-phenanthrolineHH[J]. Journal of Molecular Structure, 2002,616:231-239
[4]Shuku, Y., Suizu, R., Awaga, K., et al. Fe(Ⅱ) spincrossover complex of [1,2,5] thiadiazolo [3,4-f][1,10] phenanthroline[J]. CrystEngComm, 2009,11:2065-2068
[5]Constable, E. C., Zhang, G. Q., Housecroft, C. E., et al. Phase-separated hydrogen-bonded chloride ion-water-oxonium ion sheets and protonated 4'-(4-bromophenyl)-2,2':6',2"-terpyridine stacks, and condensation products of 2-acetyl pyridine and benzaldehydes revisited[J]. CrystEngComm, 2009,11:1014-1021
[6]Constable, E. C., Housecroft, C. E., Medlycott, E., et al. The first complex of 4'-(4-methylthiophenyl)-2,2':6',2"-terpyridine-A model for terpylated self-assembled monolayers[J]. Inorganic Chemistry Communications, 2008,11:518-520
[7]Orain, P. Y., Capon, J. F., Kervarec, N., et al. HUse of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active siteH[J]. Dalton Transactions,2007,3754-3756
[8]Berthet, J. C., Nierlich, M., Miquel, Y, et al. Selective complexation of uranium(Ⅲ) over lanthanide(Ⅲ) triflates by 2,2':6',2"-terpyridine. X-Ray crystal structures of [M(OTf)3(terpy)2] and [M(OTf)2(terpy)2(py)][OTf] (M=Nd, Ce, U) and of polynuclear μ-oxo uranium(Ⅳ) complexes resulting from hydrolysis [J]. Dalton Transactions, 2005,369-379
[9]Margan, T. G., Burstall, F. H., Heterocyclic Systems Containing Selenium. PartⅣ. Cyclo Selenohexane[J]. J. Chem. Soc.,1931:173-180
[10]Winter, A., Friebe, C., Chiper, M., et al. Synthesis, Characterization, and Electro-Optical Properties of ZnⅡ Complexes with π-Conjugated Terpyridine Ligands[J]. ChemPhysChem, 2009,10:787-798
[11]Hong. Y., Chen. S. J., Tung L. C. W., et al. Fluorogenic Zn(Ⅱ) and Chromogenic Fe(Ⅱ) Sensors Based on Terpyridine-Substituted Tetraphenylethenes with Aggregation-Induced Emission Characteristics[J]. Materials Interfaces. 2011,3:3411-3418
[12]Maier. A., Tieke. B. Coordinative Layer-by-Layer Assembly of Electrochromic Thin Films based on Metal Ion Complexes of Terpyridine-Substituted Polyaniline Derivatives[J], Journal of Physical Chemistry B. 2012,116:925-934
[13]Heine. J., Gunne. J. S., Dehnen. S., Formation of a Strandlike Polycatenane of Icosahedral Cages for Reversible One-Dimensional Encapsulation of Guests[J]. Journal of the American Chemical Society. 2011,133:10018-10021
[14]张林,王国松,刘伟民等,2,2'：6',2"-三联吡啶衍生物配体的合成及研究[J].山西大学学报(自然科学版),2007,30：68-70
[15]蔡小华,张国林,无溶剂一锅法合成1,4-二氢吡啶[J].有机化学,2005,25：930-933
[16]敬炳文,吴韬,张曼华等,功能性多吡啶配体的合成[J].高等学校化学学报,2000,21：395-400
[17]中本一雄著,黄德如,汪仁庆译,无机和配位化合物的红外和拉曼光谱[M].北京,化学工业出版社,1991,第四版
[18]W. Goodall, J.Williams, A new highly fluorescent terpyridine which responds to zinc ions with a large red-shift in emission [J].Chemical Communications,2001,2514-2515.
[19]Zhang J., Li Z.J., KangY., Hydrothermal Synthese, Crystal Structures, and Properties of a Novel Class of 3,3,4,4-benzophen-tetracarboxylate (BPTC) Polymers [J]. Inorganic Chemistry, 2004,43:8085-8091
[1]Zhao B., Cheng P., Chen X. Y., et al. Design and Synthesis of 3d-4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated "Water" Pipe [J]. Journal of the American Chemical Society, 2004,10:3012-3013
[2]Koner R., Lee G. H., Wang Y., et al. Two New Diphenoxo-Bridged Discrete Dinuclear CuⅡGdⅢ Compounds with Cyclic Diimino Moieties: Syntheses, Structures, and Magnetic Properties [J]. European Journal of Inorganic Chemistry, 2005,8:1500-1505
[3]Song Y. S., Yan B., Weng L. H. Synthesis and crystal structure of a novel two-dimensional 3d-4f heterometallic coordination polymer constructed from three-ply-like layers [J]. Inorganic Chemistry Communications, 2006,6:567-570
[4]Liang Y. C., Cao R., Su W. P., et al. Syntheses, Structures, and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(Ⅱ) Coordination Polymers by a Hydrothermal Reaction [J]. Angewandte Chemie, International Edition, 2000,18:3304-3307
[5]Caravan P., Ellison J. J., McMurry T. J., et al. Gadolinium(Ⅲ) Chelates as MRI Contrast Agents Structure, Dynamics, and Applications [J]. Chemical Reviews, 1999,99: 2293-2352
[6]Costes J. P., DupuisA., Laurent J. P. A Very-High-Spin Molecule: Preparation, Characterization and Magnetic Properties of an FeⅢ-GdⅢ Complex with an S=12/2 Ground State [J]. European Journal of Inorganic Chemistry, 1998,10:1543-1546
[7]潘勤鹤,李激扬,于吉红等.具有氢键假想孔道结构的[M(en)3][GeF6](M=Ni,Co)的合成与表征[J].高等学校化学学报,2005,12：2199-2202
[8]Zaleski C. M., Depperman E. C., Kampf J. W., et al. Synthesis, Structure, and Magnetic Properties of a Large Lanthanide-Transition-Metal Single-Molecule Magnet [J]. Angewandte Chemie, International Edition,2004,30:3912-3914
[9]Mori F., Nyui T., Ishida T., et al. Oximate-Bridged Trinuclear Dy-Cu-Dy Complex Behaving as a Single-Molecule Magnet and Its Mechanistic Investigation [J]. Journal of the American Chemical Society, 2006,5:1440-1441
[10]Costes J. P., Dahan F., Wernsdorfer W. Heterodinuclear Cu-Tb Single-Molecule Magnet [J]. Inorganic Chemistry, 2006,1:5-7
[11]Mishra A., Wernsdorfer W., Parsons S., et al. The search for 3d-4f single-molecule magnets:synthesis, structure and magnetic properties of a [MnⅢ2DyⅢ2] cluster [J]. Chemical Communications,2005:2086-2088
[12]Aronica C., Pilet G., Chastanet G., et al. A Nonanuclear Dysprosium(Ⅲ)-Copper(Ⅱ) Complex Exhibiting Single-Molecule Magnet Behavior with Very Slow Zero-Field Relaxation [J]. Angewandte Chemie, International Edition, 2006,28:4659-4662
[13]Takashi K., Motohiro N., Shinya T., et al. Coordination-Tuned Single-Molecule-Magnet Behavior of TbⅢ-CuⅡ Dinuclear Systems[J]. Inorg. Chem.2008,47:8604-8606
[14]Vadapalli C., Balasubramanian M. P., Ramamoorthy B., et al. Trinuclear Hetero bimet-allic Ni2Ln complexes [L2Ni2Ln][C104] (Ln) La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3) (S)P[N(Me)NdCH-C6H3-2-OH-3-OMe]3):From Simple Paramagnetic Co-mplexes to Single-Molecule Magnet Behavior[J]. Inorg. Chem.2008,47:4918-4929
[15]Tomoka Y.,Yukinari S., Hiroyuki I., et al. Synthesis, Structures, and Magnetic Properties of Face-SharingHeterodinuclear Ni(Ⅱ)-Ln(Ⅲ) (Ln) Eu, Gd, Tb, Dy) Complexes[J]. Ino-rg. Chem.2008,47:5736-5745
[16]Tomoka Y.,Jean-Pierre C., Yukana K., et al. Face-Sharing Heterotrinuclear MⅡ-LnⅢ-MⅡ(M=Mn, Fe, Co, Zn; Ln=La, Gd, Tb, Dy) Complexes: Synthesis, Structures, and Magnetic Properties[J]. Inorg. Chem.2010,49:9125-9135
[17]David E. F., John R. T., Casellato U. Metal Complexes of Tetrakonates and their Schiff Bases [J]. Inorganica Chimica Acta, 1984,83:23-31
[18]Yamazaki S., Hanada M., Yanase Y., et al. A Simple Synthesis of Novel Extraction Reagents.4-Acyl-5-Pyrazolone-Substituted Crown Ethers [J]. Journal of the Chemical Society, Perkin Transactions 1:Organic and Bio-Organic Chemistry, 1999,6:693-696
[19]Fenton, D. E., Casellato U., Vigato P., et al. The Evolution of Binucleating Ligands [J]. Inorganica Chimica Acta, 1982,1:57-66
[20]Aromi G., Gamez P., Roubeau O., et al. Ligand-templated four-metal chains dimerize into a unique [CuⅡ8] cluster [J]. Angewandte Chemie, International Edition, 2002,41: 1168-1170
[21]Fenton D. E., Regan C. M. Umberto Casellato and. Binuclear Complexes of Tetrakonates [J]. Inorganica Chimica Acta, 1982,58,:83-88.
[22]Aromi G., Gamez P., Krzystek J., et al. Novel Linear Transition Metal Clusters of a Heptadentate Bis-β-diketone Ligand [J]. Inorganic Chemistry, 2007,46:2519-2529
[23]Dams H., Clunas S., Fenton D. E., et al. A Tetranuclear Nickel(Ⅱ) Complex Sembled from an Asymmetric Compartmental Ligand and Bearing an Intramolecular [H3O2]-Bridge [J]. Chemical communications (Cambridge, England), 2002,5:418-419