煤对CH_4、CO_2、N_2及其二元混合气体吸附特性、预测和CO_2驱替CH_4的研究
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摘要
本文利用物理化学、界面化学、煤化学、煤质学、煤岩学等知识,在实验研究和文
献资料数据的基础上借助计算机作为辅助工具对煤吸附CH_4、N_2、CO_2及CH_4/CO_2二元
混合气体吸附特性、吸附量预测进行了系统研究,最后对CO_2驱替煤吸附CH_4特性及中
国煤采用cO_2-ECBM技术可增收的煤层气采收率和CO_2的埋藏量进行了初步研究。
本文在对晋城和潞安煤对纯CH_4、N_2、CO_2及CH_4/CO_2二元混合气体吸附/解吸特性
研究的基础上,对二煤和所收集到的煤对纯气体吸附数据采用SPSS、线性回归法和迭代
法对Langmuir、BET、DA、DR、Toth、Frendulich、扩展Langmuir、Langmuir-Freundlicht
8种吸附模型和二次方程、三次方程和对数方程进行拟合;在平衡气游离相组分浓度已
知和未知条件下采用扩展Langmuir、理想吸附溶液理论和实际吸附溶液理论对煤吸附
CH_4/CO_2二元混合气体吸附量进行预测,采用的吸附等温方程有Langmuir、BET、DA、
DR:通过材料收集、审查和整理,利用SPSS软件对煤吸附CH_4的Langmuir吸附常量
与煤质指标、CO_2/CH_4和CH_4/N_2吸附比与煤质指标间的线性回归关系进行了研究;在
CO_2-ECBM实验模拟装置建立的基础上,对注CO_2提高煤层气采收率进行了初步的实验
室研究,并初步研究了注CO_2对煤中矿物质的影响。
通过CH_4、N_2、CO_2及混合气体的吸附等温线和预测结果可大体上了解煤的微孔结
构和煤的吸附特性。通过本文的研究,进一步丰富了煤吸附气体理论,为CO_2-ECBM技
术预测提供了理论基础、预测方法,为注CO_2提高煤层气采收率和CO_2埋藏提供了资源
评价技术和方法。
Adsorption characteristics and adsorbed amount prediction of CH_4,C0_2, N_2 single and binary gas on coals have been studied comprehensively on the basis of experiments and literature data with computer program from the point of view of Physical Chemistry, Interface Chemistry, Coal Chemistry, Coal Quality, Coal Petrology and so on in the paper. Finally, the properties of adsorbed methane displacement with carbon dioxide and enhanced coalbed methane recovery and C0_2 sequestration in China' s coal have been investigated primarily in the paper.First of all, adsorption/desorption characteristics of CH_4, C0_2, N_2 pure and binary gas adsorption on Jincheng coal and Luan coal has been studied, and then, the eight different models viz. Langmuir, BET, DA, DR, Toth, Freundlich, Expended-Langmuir, Langmuir-Freundlich and three curvilinear equations viz. quadratic equation, cubic equation and logarithmic equation were used to fit the experimental and literature data of CH_4, C0_2, N_2 adsorption on coals by SPSS software, linear regression and iterative method. Expended Langmuir, Ideal adsorption Solution Theory and Real adsorption Solution Theory combined with pure gas absorption isotherms equation viz. Langmuir, DA, DR, BET were employed to predict the adsorbed amount of C0_2/CH_4 adsorption on coals on the conditions of known and unknown compositions concentration in the free phase. The linear regression relation between the Langmuir adsorption constants and adsorption ratio of CO_2/CH_4 or CH4/N2 and coal quality indexes were studied with SPSS software. The primary experimental study about enhanced coalbed methane recovery with C0_2 injection with the founded experimental equipment simulating C0_2-ECBM technology, and the interaction between C0_2 injected into coal and mineral matter in coal was studied primarily in the paper.In the light of the adsorption isotherms and predicted results of CH_4, C0_2, N_2 and their mixtures, the coal micropore structure and gases adsorption characteristics on coal can be known on the whole. The studied results in the paper improve gases adsorption theory on coal, and provide the theoretical basis and prediction method for CO_2-ECBM, and supply the technique or method for ECBM and C0_2 sequestration with C0_2-ECBM.
献资料数据的基础上借助计算机作为辅助工具对煤吸附CH_4、N_2、CO_2及CH_4/CO_2二元
混合气体吸附特性、吸附量预测进行了系统研究,最后对CO_2驱替煤吸附CH_4特性及中
国煤采用cO_2-ECBM技术可增收的煤层气采收率和CO_2的埋藏量进行了初步研究。
本文在对晋城和潞安煤对纯CH_4、N_2、CO_2及CH_4/CO_2二元混合气体吸附/解吸特性
研究的基础上,对二煤和所收集到的煤对纯气体吸附数据采用SPSS、线性回归法和迭代
法对Langmuir、BET、DA、DR、Toth、Frendulich、扩展Langmuir、Langmuir-Freundlicht
8种吸附模型和二次方程、三次方程和对数方程进行拟合;在平衡气游离相组分浓度已
知和未知条件下采用扩展Langmuir、理想吸附溶液理论和实际吸附溶液理论对煤吸附
CH_4/CO_2二元混合气体吸附量进行预测,采用的吸附等温方程有Langmuir、BET、DA、
DR:通过材料收集、审查和整理,利用SPSS软件对煤吸附CH_4的Langmuir吸附常量
与煤质指标、CO_2/CH_4和CH_4/N_2吸附比与煤质指标间的线性回归关系进行了研究;在
CO_2-ECBM实验模拟装置建立的基础上,对注CO_2提高煤层气采收率进行了初步的实验
室研究,并初步研究了注CO_2对煤中矿物质的影响。
通过CH_4、N_2、CO_2及混合气体的吸附等温线和预测结果可大体上了解煤的微孔结
构和煤的吸附特性。通过本文的研究,进一步丰富了煤吸附气体理论,为CO_2-ECBM技
术预测提供了理论基础、预测方法,为注CO_2提高煤层气采收率和CO_2埋藏提供了资源
评价技术和方法。
Adsorption characteristics and adsorbed amount prediction of CH_4,C0_2, N_2 single and binary gas on coals have been studied comprehensively on the basis of experiments and literature data with computer program from the point of view of Physical Chemistry, Interface Chemistry, Coal Chemistry, Coal Quality, Coal Petrology and so on in the paper. Finally, the properties of adsorbed methane displacement with carbon dioxide and enhanced coalbed methane recovery and C0_2 sequestration in China' s coal have been investigated primarily in the paper.First of all, adsorption/desorption characteristics of CH_4, C0_2, N_2 pure and binary gas adsorption on Jincheng coal and Luan coal has been studied, and then, the eight different models viz. Langmuir, BET, DA, DR, Toth, Freundlich, Expended-Langmuir, Langmuir-Freundlich and three curvilinear equations viz. quadratic equation, cubic equation and logarithmic equation were used to fit the experimental and literature data of CH_4, C0_2, N_2 adsorption on coals by SPSS software, linear regression and iterative method. Expended Langmuir, Ideal adsorption Solution Theory and Real adsorption Solution Theory combined with pure gas absorption isotherms equation viz. Langmuir, DA, DR, BET were employed to predict the adsorbed amount of C0_2/CH_4 adsorption on coals on the conditions of known and unknown compositions concentration in the free phase. The linear regression relation between the Langmuir adsorption constants and adsorption ratio of CO_2/CH_4 or CH4/N2 and coal quality indexes were studied with SPSS software. The primary experimental study about enhanced coalbed methane recovery with C0_2 injection with the founded experimental equipment simulating C0_2-ECBM technology, and the interaction between C0_2 injected into coal and mineral matter in coal was studied primarily in the paper.In the light of the adsorption isotherms and predicted results of CH_4, C0_2, N_2 and their mixtures, the coal micropore structure and gases adsorption characteristics on coal can be known on the whole. The studied results in the paper improve gases adsorption theory on coal, and provide the theoretical basis and prediction method for CO_2-ECBM, and supply the technique or method for ECBM and C0_2 sequestration with C0_2-ECBM.
引文
1.张新民,张遂安等.中国的煤层甲烷[M],西安:陕西科学技术出版社,1991,102-103.
2. U. S. Environmental Protection Agency. Coalbed Methane Notes: U. S. Coalbed Methane Production Increases 3%[OL], http://www.epa.gov/coalbed/resources/notes/2004/1-29.html.
3.钱凯,赵庆波等.煤层甲烷气勘探开发理论与测试技术[M],北京:石油工业出版社,1996,1-14.
4.傅雪海,秦勇等.中国部分煤储层解吸特性及甲烷采收率[J],煤田地质与勘探,2000,28(2):19-22.
5. Scott H. Stevens, Lanny Schoeling et al. CO_2 Injection for Enhanced Coalbed Methane Recovery: Project Screening and Design[C], 1999 Internatinal Coalbed Methane Symposium Proceedings, USA, Alabama, May 3-7, 1999, 309-317.
6. Byrer Charles W., Guthrie H. D.. Appalachian Coals: Potential Reservoirs for Sequestration Carbon Dioxide Emissions from Power Plants While Enhancing CBM Production[C], 1999 Internatinal Coalbed Methane Symposium Proceedings, USA, Alabama, May 3-7, 1999, 319-327.
7. Stanton, R., Flores, R., et al. Coal Bed Sequestration of Carbon Dioxide[C], DOE's First National Conference on Carbon Sequestration, USA, Washington, May 14-17, 2001, 1-8.
8. Krooss B. M., Bergen F. Van. High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals[J], International Journal of Coal Geology, 2002, 51: 69-91.
9.蔺金太,郭勇义等.煤层气注气开采中煤对不同气体的吸附作用[J],太原理工大学学报,2001,32(1):18-20.
10. Clarkson C. R., Bustin B. M.. Binaly gas adsorption/desorption isotherms: effect of moisture and coal composition upon carbon dioxide and selectivity over methane[J], International Journal of Coal Geology, 2000, 42: 241-271.
11.张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J],煤炭学报,1999,24(6):566-570.
12.周胜国,郭淑敏.煤储层吸附,解吸等温曲线测试技术[J],石油实验地质,1999,2l(1):76-80.
13.吴俊.煤表面能的吸附法计算用研究意义[J],煤田地质与勘探,1994,22(2):18-23.
14. Dreisbach F., Staudt R.. High Pressure Adsorption Data of Methane, Nitrogen, Carbon Dioxide and their Binary and Ternary Mixtures on Activated Carbon[J], Adsorption, 1999, 5: 215-227.
15.杨福荣,杨思敬等.高压重量法测定煤对甲烷吸附的实验研究[J],煤矿安全,1995,4:7-8.
16.张庆玲,曹利戈.煤的等温吸附测试中数据处理问题研究[J],煤炭学报,2003,28(2):131-135.
17.崔永君.煤等温吸附特性参数测试中的体积校正方法探讨[J],煤田地质与勘探,1999,27(5):27-32.
18. Stevenson M. D., Pinczewski W. V., et al. Adsorption/Desorption of Multieomponent Gas Mixtures at In-Seam Conditions[J], paper SPE 23026, Presented at the SPE Asia-Pacific Conference, Perth, Western Australia, 1991, 741-755.
19. Greaves K. H., Owen L. B., McLennan J. D.. Multi-component Gas Adsorption-Desorption Behavior of Coal[C], Proceedings of the 1993 International Coalbed Methane Symposium, Tuscaloosa, Alabama, 1993, 197-205.
20. Arri L. E., Yee D., Morgan W. D., et al. Modeling Coal Methane Production with Binary Gas sorption[C], paper SPE 24363, presented at the SPE Rocky Mountain Regional Meeting and Exhibition, Casper, Wyomin, May 18-21, 1991, 459-472.
21. Harpalani S. and Pariti U. M.. Study of Coal Sorption Isotherms Using a Multicomponent Gas Mixture[C], Proceedings of the 1993 International Coalbed Methane Symposium. Tuscaloosa, Alabama, 1993, 151-160.
22. Busch A., Krooss B. M., et al. High-pressure adsorption of methane, carbon dioxide and their mixtures on coals with a special focus on the preferential sorption behaviour[J], Journal of Geochemical Exploration, 2003, 78-79: 671-674.
23.周胜国,侯瑞云,郭淑敏.煤对双组分气体的等温吸附实验方法[J],焦作工学院学报,1996,15(6):84-87.
24.唐书恒.晋城地区煤储层特征及多元气体的吸附-解吸特性[D],北京:中国矿业大学(北京校区),2001.
25.唐书恒,韩德馨.煤对多元气体的吸附与解吸[J].煤炭科学技术,2002,30(1):58-60.
26.唐书恒,韩德馨.用多元气体等温吸附成果评价煤层气开发潜力[J],中国矿业大学学报,2002,31(6):630-633.
27.唐书恒,杨起等.注气提高煤层甲烷采收率机理及实验研究[J],石油实验地质,2002,24(6):545-549.
28.辜敏,陈昌国,鲜学福.混合气体的吸附特征[J],天然气工业,2001,21(4):91-94.
29.崔永君.煤对CH_4、N_2、CO_2及多组分气体吸附的研究[D],陕西西安:煤炭科学研究总院西安分院,2003.
30.崔永君,杨锡禄.多组分等温吸附测试中的体积校正方法探讨[J],煤田地质勘探,2001,29(5):25-27.
31. Rupple T. C., Grein C. T.. Adsorption of methane on dry coal at elevated pressure[J], Fuel, 1974, 53: 152-162.
32.艾鲁尼 AT(唐修义,宋德淑,王荣龙译).煤矿瓦斯动力学现象的预测和预防[M].北京:煤炭工业出版社,1992.
33. Clarkson C. R.. Adsorption potential theories to coal methane adsorption isotherms at elevated temperature and pressure[J]. Carbon, 1997, 35: 1689-1705.
34. Laxminarayana Ch., Crosdalc P. J.. Modeling methane adsorption isotherms using pore filling models: a case study on India coals[C], 1999 International coalbcd methane symposium Proceedings, USA, Alabama, May 3-7,1999, 117-128.
35. Weishauptova Z., Medck J.. Bound forms of methane in the porous system of coal[J]. Fuel, 1998, 77: 71-76.
36. Collins R. E.. New theory for gas adsorption and transport in coal[C], Proceedings of the 1991 Coalbed Methane Symposium, Tuscaloosa, Alabama, 1991: 525-531.
37. Stevenson M. D., Pinczewski W. V.. Adsorption/Desorption of multicomponent gas mixture at in-seam conditions[J], SPE 23026, SPE Asia-Pacific Conference, Perth. Australia, 4-7 November, 1991, 741-756.
38. Nodzenski A.. Sorption and desorption of gases (CH_4, CO_2) on hard coal and activated carbon at elevated pressures[J], Fuel, 1998, 78: 1243-1246.
39. Vishnyakov A., Piotrovskaya E. M.. Capillary condensation and melting/freezing transitions for methane in slit coal pores[J], Adsorption, 1998, 4: 207-224.
40. Karacan C. O., Okandan E.. Assessment of energetic heterogeneity of coals for gas adsorption and its effect on mixture predictions for coalbed methane studies. Fuel, 2000, 79: 1963-1974.
41.陈昌国,鲜晓红.微孔填充理论研究无烟煤煤炭对甲烷的吸附特性[J],重庆大学学报,1998,21(2):75-79.
42.唐修义.有关煤煤层气几个基本问题的认识[J].煤田地质与勘探,1996,24(3):20-26.
43.越志根,唐修义.对吸附甲烷的Langmuir方程的讨论[J],焦作工学院学报,2002,21(1):1-4.
44. Yang R. T., Saunders J. T.. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64: 616-620.
45. Laxminarayana Ch., Chikatamarla. Heat of methae adsorption of coal: implications for pore structure development[C], 2001 International coalbed methane Symposium, Tuscaloosa, Alabama, May 14-18, 2001, 151-162.
46.聂百胜,何学秋等.煤表面自由能及应用探讨[J],太原理工大学学报,2000,31(4):346-348.
47. Arri, L. E., Yee, D., Morgan, W. D., Jeansonne, M. W.. Modeling coalbed methane production with binary gas sorption[J], SPE Paper 24363, Presented at the SPE Rocky Mountain Regional Meeting, Casper, WY, 1992, 459-472.
48. Fitzgerald J. E., Sudibandriyo M., et al. Modeling the adsorption of pure gases on coals with the SLD model[J], Carbon, 2003, 41: 2203-2216.
49. Harpalani S., Pariti U. M.. Study of Coal Sorption Isotherms Using a Multicomponent Gas Mixture[C], Proceedings of the 1993 International Coalbed Methane Symposium. Tuscaloosa, Alabama, 1993, 151-160.
50. Hall F. E., Zhou C., Gasem K. A. M., Robinson, et al. Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Binary Mixtures on Wet Fruitland Coal[J], paper SPE 29194, presented at the 1994 Eastern Regional Conference and Exhibition, Charleston, South Carolina, Nov. 8-10, 1994, 329-344.
51. Goodman, A. L., Busch A., et al. An Inter-laboratory Comparison of CO_2 Isotherms Measured on Argonne Premium Coal Samples[J], Energy & Fuels, 2004, 18: 1175-1182.
52. C. R. Clarkson, R. M. Bustin. Binary gas adsorptionrdesorption isotherms: effect of moisture and coal composition upon carbon dioxide selectivity over methane[J], International Journal of Coal Geology, 2000, 42: 241-271.
53.唐书恒,杨起,汤达祯.二元混合气体等温吸附实验结果与扩展Langmuir方程预测值的比较[J],地质科技情报,2003,22(2):68-70.
54. Levy J. H., Day S. J., et al.. Methane capacities of Bowen Basin coals related to coal properties[J], Fuel, 1997, 74: 1-7.
55. Bustin R. M., Clarkson C. R.. Geological controls on coalbed methane reservoir capacity and gas content[J], International Journal of Coal Geology, 1998, 38: 3-36.
56. Lamberson M. N., Bustin R. M.. Coalbed methane characteristics of Gates formations coals, Northeastern British Columbia: Effect of maceral composition[J], AAPG, 1993, 77: 2062-2076.
57.刘志钧.关于煤吸附甲烷容量的研究[J],煤矿安全,1988,10:7-14.
58.钟玲文,张新民.煤的吸附能力及其煤化程度和煤岩组成间的关系[J],煤田地质与勘探,1990,18(4):29-35.
59.张庆玲,崔永君,曹利戈.压力对不同变质程度煤的吸附性能影响分析[J],天然气工业,2004,24(1):98-100.
60.张力,何学秋,王恩元等.煤吸附特性的研究[J],太原理工大学学报,2001,32(4):449-451.
61.张新民,庄军,张遂安.中国煤层气地质与资源评价[M],北京:科学出版社,2002.
62.傅雪海,秦勇,李贵中.特高煤级煤平衡水条件下的吸附试验[J],石油试验地质,2002,24(2):177-180.
63. Laxminarayana Ch., Crosdale P. J. Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia, coals[J], International Journal of Coal Geology, 1999, 40: 309-325.
64. Yee D., Seidle J. R., Hanson W. B.. Gas sorption on coal and measurement of gas content[J], Hydrocarbon from coal: AAPG studies in Geology, 1993, 38: 203-218.
65. Joubert J. R.,, Grein C. R.. Sorption of methane in moist coal[J], Fuel, 1973, 52: 181-185.
66. Levine J. R., Johnson P.. High microbalance sorption studies[C], 1993 International coalbed methane symposium, Tuscaloosa, Alabama, 1993, 187-195.
67. Bustin, M. Research Activities on CO_2, H_2S and SO_2 Sequestration at UBC[R], Coal-Seq I Forum, Houston, March 14-15, 2002.
68. Gluskoter, H. J., Mastalerz, M., et al. The potential for carbon dioxide sequestration in coal beds: new evidence from methane and carbon dioxide adsorption analyses of coals from lignite to anthracite [abs], Geological Society of America, Abstracts with Programs, 2002, 34(2).
69. Gasem, K. A. M., Robinson R. L., Reeves, S. R.. Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on San Juan Basin Coal[R], DOE Topical Report, contract no. DE-FC26-00NT40924, May, 2002.
70. Pashin, J. C., Carroll, R. E.. Geologic Screening Criteria for Sequestration of CO2 in Coal: Quantifying Potential of the Black Warrior Coalbed Methane Fairway, Alabama[R], Annual Technical Progress Report, U. S. Department of Energy, National Technology Laboratory, contract DE-FC-00NT40927, 2003.
71. Nelson, C. R., Hill, D. G.. Properties of Paleocene Fort Union Formation Canyon Seam Coal at the Triton Federal Coalbed Methane Well, Campbell County, Wyoming [J], paper SPE 59786 presented at the 2000 CERI/SPE Gas Technology Symposium, Calgary, Alberta, Canada, April 3-5, 2002.
72. Robert C. Burruss. CO_2 adsorption in coals as a function of rank and composition: A task in USGS research on geologic sequestration of CO_2[R], Intemational ECBM/Sequestration Consortium (Coal-Seq Ⅱ), Baltimore MD, March 25-26, 2004.
73. Maria Mastalcrz, Hal Gluskoterb, John Rupp. Carbon dioxide and methane sorption in high volatile bituminous coals from Indiana, USA[J], International Journal of Coal Geology, 2004, 60: 43-55.
74.吴世跃,郭勇义.关于注气开发煤层气机理的探讨[J],太原理工大学学报,2000,31(4):361-363.
75.吴世跃,郭勇义.注气开采煤层气增产机制的研究[J],煤炭学报,2001,26(2):199-203.
76.马志宏,郭勇义,吴世跃.注入二氧化碳及氮气驱替煤层气机理的实验研究[J],太原理工大学学报,2001,32(4):335-338.
77.吴建光,叶建平,唐书恒.注入CO2提高煤层气产能的可行性研究[J],高校地质学报,2004,10(3):463-467.
78. Gary D. Stricker, Romeo M. Flores. Potential Carbon Dioxide Sequestration and Enhanced coalbed methane Productionin the Power River and Williston Basins[C], Proceedings of the 28th International Technical Conference on Coal Utilization & Fuel Systems (Volume Ⅰ), Clearwater, Florida, USA, March 9-13, 2003, 387-401.
79. Scott R. Reeves. Assessment of CO_2 Sequestration and ECBM Potential of U. S. Coalbeds[R], U. S. Department of Energy, DE-FC26-00NT40924, February, 2003.
80. Reeves S. R. Geologie Sequestration of CO_2 in Deep, Unmineable Coalbeds: An Integrated Research and Commercial-Scale Field Demonstration Project[C], SPE 71749, presented at the SPE Annual Technical Conference and Exhibition, New Orleans, September 30-October 3, 2001.
81. Harry C. E. Schreurs. Potential for CO_2 sequestration in the Netherlands[C], 27th International Technical Conference on Coal Utilization & Fuel Systems, Clearwater, Florida, USA, March 4-7, 2002, 731-742.
82. Harry C. E. Schreurs. Potential for CO_2 sequestration .and enhanced coalbed methane Production in the Netherlands[C], Proceedings of the 26th International Technical Conference on Coal Utilization & Fuel Systems, Florida, USA, March 5-8, 2001, 967-978.
83. Wong S., MacLeod K., Wold M., et al. CO_2 enhanced coalbed methane Recovery Demonstration Pilot-A Case for Australia[C], 2001 International coalbed methane Symposium, Tuscaloosa, Alabama, May 14-18, 2001, 75-86.
84. Nishino J.. Adsorption of water vapor and carbon dioxide at carboxylic functional groups on the surface of coal[J], Fuel, 2001, 80: 757-764.
85.胡涛,马正飞等.甲烷超临界高压吸附等温线研究[J],天然气化工,2002,27(2):36-40.
86. C. Ozgen Karacan. Heterogeneous Sorption and Swelling in a Confined and Stressed Coal during CO_2 Injection[J], Energy & Fuels, 2003, 17(6): 1595-1608.
87. Harpalani S., Schraufnagel R. A.. Influence of Matrix Shrinkage and Compressibility on Gas Production from Coalbed Methane Reservoirs[C], SPE 20729, SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, 23-26 September, 1990.
88. Seidle, J. P. and Huitt, L. G.. Experimental Measurement of Coal Matrix Shrinkage Due to Gas Desorption and Implications for Cleat Permeability Increases, SPE 30010, International Meeting on Petroleum Engineering, Beijing, China, 14-17 November, 1995.
89. St. George J. D., Barakat, M. A.. The Change in Effective Stress with Shrinkage from Gas Desorption in Coal[J], International Journal of Coal Geology, 2001, 45: 105-113.
90.李明,顾安忠.气体临界温度以上吸附平衡的预测研究[J],物理化学学报,2004,17(5):602-606.
91.胡英.物理化学(上册)[M],第4版,北京:高等教育出版社,1999,1-30.
92.朱自强,徐汛.化工热力学[M],第2版,北京:化工工业出版社,1991,6-30.
93.胡英.物理化学(下册)[M],第4版,北京:高等教育出版社,1999.
94.郗怡佳.单孔、多孔材料的分子吸附模型[J],青海大学学报(自然科学版),2001,19(6):30-34.
95.顾惕人,朱步瑶等.表面化学[M],北京:科学出版社,1994,268-274.
96.周理,周亚平.关于氢在活性炭上高压吸附特性的实验研究[J],中国科学(B辑),1996,26(5):473-480.
97. Ozawa S., Kusumi S., Ogino Y.. Physical adsorption of gases at high pressure Ⅳ: An improvement of the Dubinin-Asakhov adsorption[J], Journal Colloid Interface Science, 1976: 83-89.
98. Li Zhou, Yaping Zhou. Linearization of adsorption isotherms for high-pressure applications[J], Chemical Engineering Science, 1998, 53(14): 2531-2536.
99. Amankwah K. A. G., Schwarz J. A.. A modified approach for estimating pseudovapor pressures in the application of the Dubinin-Astakhov equatinn[J], Carbon, 1995, 33(9): 1313-1319.
100.梁燕波,童景山.简便通用型蒸汽压方程及汽化热的新算法.工程热物理学报[J],1998,19(6):673-676.
101.周亚平,周理.超临界氢在活性炭上的吸附等温线研究[J],物理化学学报,1997,13(2):119-127.
102. J. D. St. George, M. A. Barakat. The change in effective stress associated with shrinkage from gas desorption in coal[J], International Journal of Coal Geology, 2001, 45: 105-113.
103. Harpalani, S.,Schraufnagel, R.. Shrinkage of coal matrix with release of gas and its impact on permeability of coal[J], Fuel, 1990, 69: 551-556.
104.盛骤,谢式千等.概率论与数理统计[M],第三版,北京:高等教育出版社,2001,270-318.
105.史济民,汤观全.Visual Foxpro及其应用系统开发[M],北京:清华大学出版社,2000.
106. Myers A. L., Prausnitz, J. M.. Thermodynamics of mixed-gas adsorption [J], AIChE Journal., 1965, 11, 121-127.
107. Mahle J. J.. A Henry's law limits for DR and DA equations[J], Carbon, 1997, 35(3): 432-435.
108. Talu O., Zwiebel I. Multieomponent adsorption equilibria of nonideal mexture[J], AIChE Joural, 1986, 32, 1263.
109.郑丹星.化工热力学教程[M],北京:中国石化出版社,2000,81-193.
110.叶道敏,肖文钊等.等变质煤镜质体的差异与煤层甲烷的关系[J],煤田地质与勘探,1997,25(3):27-30.
111. Ettinger I. L., Eremin I., Zimakov B., et al. Natural factors influencing coal sorption Properties. I. Petrography and the sorption properties of coals[J]. Fuel, 1966, 45: 267-276.
112. Zou Shengguo, Hou Ruiyun. Application Study of Coal Content and Adsorption/Desorption Isotherm Test Technique[C], International Conference on Coalbed Methane Development and Utilization Proceedings, Beijing, 1995: 237-242.
113.钟玲文,郑玉柱,员争荣.煤在温度和压力综合影响下的吸附性能及气含量预测[J],煤炭学报,2002,27(6):581-585.
114.傅雪海.多相介质煤岩体物性的物理模拟与数值模拟[D],江苏徐州:中国矿业大学,2001.
115.GB 483—87,煤质分析试验方法一般规定[S].
116.GB5751—86,中国煤炭分类[S].
117.白浚仁,刘凤歧等.煤质分析[M],北京:煤炭工业出版社,1990,676-691.
118.俞启香.矿井瓦斯防治[M].徐州:中国矿业大学出版社,1992,12-13.
119.胡宝林等:新疆地区侏罗系中低变质煤储层吸附特征及煤层气资源前景[J],现代地质,2002,16(1):77-82.
120.李建武等.陕西省煤层气资源与勘探开发前景分析,煤田地质与勘探[J],2001,29(5):30-32.
121.刘新荣等.矿井煤层瓦斯涌出量及其与煤质关系[J],煤炭科学技术,2000,28(10):27-29.
122.罗新荣等.矿井瓦斯预测与评价[J],中国安全科学学报,1994,4(3):45-52.
123.GB/T 212—2001,煤的工业分析方法[S].
124. Jack C. Pashinl, Richard E. Carroll, Richard H. Groshong, Jr., et al. Geologic screening criteria for equestration of CO_2 in coal: quantifying potential of the black warrior coalbed methane fairway, Alabama[R], U. S. Department of Energy, National Energy Technology Laboratory, 2004.
125.蔺金太.注气提高煤层气采收率的机理研究[D],太原:太原理工大学,2000.
126. Busch, Andreas, et al. Methane and CO_2 sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures[J], International Journal of Coal Geology, 55: 205-224.
127.唐书恒,汤达帧,杨起.二元气体等温吸附-解吸中气分的变化规律[J],中国矿业大学学报,2004,33(4):448-452.
128.GB 474—1996,煤样的制各方法[S].
129.GB 476—91,煤的元素分析方法[S].
130.白浚仁.煤质学[M],北京:地质出版社,1989.
131. Kojima T., Nagamine A., et al. Absorption and Fixation of Carbon Dioxide by Rock Weathering[C], Proceedings of the Third International Conference on Carbon Dioxide Removal, Cambridge Massachusetts, September 9-11, 1996, Energy and Conservation Management, 1997, 38 Suppl: S461-S466.
131.孙茂远,黄盛初.煤层气开发利用手册[M],北京:煤炭工业出版社,1998,12-17.
132.中国煤田地质总局.中国煤层气资源[M],江苏徐州:中国矿业大学出版社,1998,1-229.
133. Ivory J., Gunter W. D., Law D., et al. Recovery of CO_2 from flue gas, CO_2 sequestration, and methane production from coalbed methane reservoirs[C], 39th Annual Conference of Metallurgists of CIM, Ottawa, Ontario, Canada, August 20-23, 2000, 487-501.
134.宋武成.天然气与中国能源[J],石油化工技术经济,2002,1:7-13.
135.周总瑛,唐跃刚.中国天然气资源特点及其在能源结构中的地位分析[J],中国矿业,2004,13(6):17-20.
136.中华人民共和国国家统计局.中国统计年鉴-2003[R],北京:中国统计出版社,2003,265.
137.胡见义.中国天然气开发利用的资源保证[A],21世纪中国石油发展战略(第一辑)[M].北京:石油工业出版社,2000,115-117.
138.张伟.关注气候变化 实现可持续发展—“减缓气候变化:发展的机遇与挑战”国际研讨会综述[R],中国社会科学院可持续发展研究中心研究快讯,2002,22:1-5.
139.黄盛初.中国煤炭开发与利用的环境影响研究[R],煤炭信息研究院洁净能源与环境中心,2003,27-100.
140.郎一环,王礼茂,顾鹏.全面建设小康社会的能源合理利用与CO_2减排[J],资源科学,2004,26(6):119-124.
141.范维唐.中国煤炭工业面临的挑战与战略对策[J],煤炭企业管理,2005,1:5-8.
142.GB/T 3715—1996,煤质及煤分析有关术语[S].
143.何宏舟.改善一次能源消费结构减少温室气体排放[J],节能与环保,2002,10:9-12.
144.俞建洪,郭祥冰.气体燃料对减缓CO_2排放的贡献[J],江西能源,2002,3:9-13.
145.张群,冯三利,杨锡禄.试论我国煤层气的基本储层特点及开发策略[J],煤炭学报,2001,26(3):230-235.
2. U. S. Environmental Protection Agency. Coalbed Methane Notes: U. S. Coalbed Methane Production Increases 3%[OL], http://www.epa.gov/coalbed/resources/notes/2004/1-29.html.
3.钱凯,赵庆波等.煤层甲烷气勘探开发理论与测试技术[M],北京:石油工业出版社,1996,1-14.
4.傅雪海,秦勇等.中国部分煤储层解吸特性及甲烷采收率[J],煤田地质与勘探,2000,28(2):19-22.
5. Scott H. Stevens, Lanny Schoeling et al. CO_2 Injection for Enhanced Coalbed Methane Recovery: Project Screening and Design[C], 1999 Internatinal Coalbed Methane Symposium Proceedings, USA, Alabama, May 3-7, 1999, 309-317.
6. Byrer Charles W., Guthrie H. D.. Appalachian Coals: Potential Reservoirs for Sequestration Carbon Dioxide Emissions from Power Plants While Enhancing CBM Production[C], 1999 Internatinal Coalbed Methane Symposium Proceedings, USA, Alabama, May 3-7, 1999, 319-327.
7. Stanton, R., Flores, R., et al. Coal Bed Sequestration of Carbon Dioxide[C], DOE's First National Conference on Carbon Sequestration, USA, Washington, May 14-17, 2001, 1-8.
8. Krooss B. M., Bergen F. Van. High-pressure methane and carbon dioxide adsorption on dry and moisture-equilibrated Pennsylvanian coals[J], International Journal of Coal Geology, 2002, 51: 69-91.
9.蔺金太,郭勇义等.煤层气注气开采中煤对不同气体的吸附作用[J],太原理工大学学报,2001,32(1):18-20.
10. Clarkson C. R., Bustin B. M.. Binaly gas adsorption/desorption isotherms: effect of moisture and coal composition upon carbon dioxide and selectivity over methane[J], International Journal of Coal Geology, 2000, 42: 241-271.
11.张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J],煤炭学报,1999,24(6):566-570.
12.周胜国,郭淑敏.煤储层吸附,解吸等温曲线测试技术[J],石油实验地质,1999,2l(1):76-80.
13.吴俊.煤表面能的吸附法计算用研究意义[J],煤田地质与勘探,1994,22(2):18-23.
14. Dreisbach F., Staudt R.. High Pressure Adsorption Data of Methane, Nitrogen, Carbon Dioxide and their Binary and Ternary Mixtures on Activated Carbon[J], Adsorption, 1999, 5: 215-227.
15.杨福荣,杨思敬等.高压重量法测定煤对甲烷吸附的实验研究[J],煤矿安全,1995,4:7-8.
16.张庆玲,曹利戈.煤的等温吸附测试中数据处理问题研究[J],煤炭学报,2003,28(2):131-135.
17.崔永君.煤等温吸附特性参数测试中的体积校正方法探讨[J],煤田地质与勘探,1999,27(5):27-32.
18. Stevenson M. D., Pinczewski W. V., et al. Adsorption/Desorption of Multieomponent Gas Mixtures at In-Seam Conditions[J], paper SPE 23026, Presented at the SPE Asia-Pacific Conference, Perth, Western Australia, 1991, 741-755.
19. Greaves K. H., Owen L. B., McLennan J. D.. Multi-component Gas Adsorption-Desorption Behavior of Coal[C], Proceedings of the 1993 International Coalbed Methane Symposium, Tuscaloosa, Alabama, 1993, 197-205.
20. Arri L. E., Yee D., Morgan W. D., et al. Modeling Coal Methane Production with Binary Gas sorption[C], paper SPE 24363, presented at the SPE Rocky Mountain Regional Meeting and Exhibition, Casper, Wyomin, May 18-21, 1991, 459-472.
21. Harpalani S. and Pariti U. M.. Study of Coal Sorption Isotherms Using a Multicomponent Gas Mixture[C], Proceedings of the 1993 International Coalbed Methane Symposium. Tuscaloosa, Alabama, 1993, 151-160.
22. Busch A., Krooss B. M., et al. High-pressure adsorption of methane, carbon dioxide and their mixtures on coals with a special focus on the preferential sorption behaviour[J], Journal of Geochemical Exploration, 2003, 78-79: 671-674.
23.周胜国,侯瑞云,郭淑敏.煤对双组分气体的等温吸附实验方法[J],焦作工学院学报,1996,15(6):84-87.
24.唐书恒.晋城地区煤储层特征及多元气体的吸附-解吸特性[D],北京:中国矿业大学(北京校区),2001.
25.唐书恒,韩德馨.煤对多元气体的吸附与解吸[J].煤炭科学技术,2002,30(1):58-60.
26.唐书恒,韩德馨.用多元气体等温吸附成果评价煤层气开发潜力[J],中国矿业大学学报,2002,31(6):630-633.
27.唐书恒,杨起等.注气提高煤层甲烷采收率机理及实验研究[J],石油实验地质,2002,24(6):545-549.
28.辜敏,陈昌国,鲜学福.混合气体的吸附特征[J],天然气工业,2001,21(4):91-94.
29.崔永君.煤对CH_4、N_2、CO_2及多组分气体吸附的研究[D],陕西西安:煤炭科学研究总院西安分院,2003.
30.崔永君,杨锡禄.多组分等温吸附测试中的体积校正方法探讨[J],煤田地质勘探,2001,29(5):25-27.
31. Rupple T. C., Grein C. T.. Adsorption of methane on dry coal at elevated pressure[J], Fuel, 1974, 53: 152-162.
32.艾鲁尼 AT(唐修义,宋德淑,王荣龙译).煤矿瓦斯动力学现象的预测和预防[M].北京:煤炭工业出版社,1992.
33. Clarkson C. R.. Adsorption potential theories to coal methane adsorption isotherms at elevated temperature and pressure[J]. Carbon, 1997, 35: 1689-1705.
34. Laxminarayana Ch., Crosdalc P. J.. Modeling methane adsorption isotherms using pore filling models: a case study on India coals[C], 1999 International coalbcd methane symposium Proceedings, USA, Alabama, May 3-7,1999, 117-128.
35. Weishauptova Z., Medck J.. Bound forms of methane in the porous system of coal[J]. Fuel, 1998, 77: 71-76.
36. Collins R. E.. New theory for gas adsorption and transport in coal[C], Proceedings of the 1991 Coalbed Methane Symposium, Tuscaloosa, Alabama, 1991: 525-531.
37. Stevenson M. D., Pinczewski W. V.. Adsorption/Desorption of multicomponent gas mixture at in-seam conditions[J], SPE 23026, SPE Asia-Pacific Conference, Perth. Australia, 4-7 November, 1991, 741-756.
38. Nodzenski A.. Sorption and desorption of gases (CH_4, CO_2) on hard coal and activated carbon at elevated pressures[J], Fuel, 1998, 78: 1243-1246.
39. Vishnyakov A., Piotrovskaya E. M.. Capillary condensation and melting/freezing transitions for methane in slit coal pores[J], Adsorption, 1998, 4: 207-224.
40. Karacan C. O., Okandan E.. Assessment of energetic heterogeneity of coals for gas adsorption and its effect on mixture predictions for coalbed methane studies. Fuel, 2000, 79: 1963-1974.
41.陈昌国,鲜晓红.微孔填充理论研究无烟煤煤炭对甲烷的吸附特性[J],重庆大学学报,1998,21(2):75-79.
42.唐修义.有关煤煤层气几个基本问题的认识[J].煤田地质与勘探,1996,24(3):20-26.
43.越志根,唐修义.对吸附甲烷的Langmuir方程的讨论[J],焦作工学院学报,2002,21(1):1-4.
44. Yang R. T., Saunders J. T.. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64: 616-620.
45. Laxminarayana Ch., Chikatamarla. Heat of methae adsorption of coal: implications for pore structure development[C], 2001 International coalbed methane Symposium, Tuscaloosa, Alabama, May 14-18, 2001, 151-162.
46.聂百胜,何学秋等.煤表面自由能及应用探讨[J],太原理工大学学报,2000,31(4):346-348.
47. Arri, L. E., Yee, D., Morgan, W. D., Jeansonne, M. W.. Modeling coalbed methane production with binary gas sorption[J], SPE Paper 24363, Presented at the SPE Rocky Mountain Regional Meeting, Casper, WY, 1992, 459-472.
48. Fitzgerald J. E., Sudibandriyo M., et al. Modeling the adsorption of pure gases on coals with the SLD model[J], Carbon, 2003, 41: 2203-2216.
49. Harpalani S., Pariti U. M.. Study of Coal Sorption Isotherms Using a Multicomponent Gas Mixture[C], Proceedings of the 1993 International Coalbed Methane Symposium. Tuscaloosa, Alabama, 1993, 151-160.
50. Hall F. E., Zhou C., Gasem K. A. M., Robinson, et al. Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Binary Mixtures on Wet Fruitland Coal[J], paper SPE 29194, presented at the 1994 Eastern Regional Conference and Exhibition, Charleston, South Carolina, Nov. 8-10, 1994, 329-344.
51. Goodman, A. L., Busch A., et al. An Inter-laboratory Comparison of CO_2 Isotherms Measured on Argonne Premium Coal Samples[J], Energy & Fuels, 2004, 18: 1175-1182.
52. C. R. Clarkson, R. M. Bustin. Binary gas adsorptionrdesorption isotherms: effect of moisture and coal composition upon carbon dioxide selectivity over methane[J], International Journal of Coal Geology, 2000, 42: 241-271.
53.唐书恒,杨起,汤达祯.二元混合气体等温吸附实验结果与扩展Langmuir方程预测值的比较[J],地质科技情报,2003,22(2):68-70.
54. Levy J. H., Day S. J., et al.. Methane capacities of Bowen Basin coals related to coal properties[J], Fuel, 1997, 74: 1-7.
55. Bustin R. M., Clarkson C. R.. Geological controls on coalbed methane reservoir capacity and gas content[J], International Journal of Coal Geology, 1998, 38: 3-36.
56. Lamberson M. N., Bustin R. M.. Coalbed methane characteristics of Gates formations coals, Northeastern British Columbia: Effect of maceral composition[J], AAPG, 1993, 77: 2062-2076.
57.刘志钧.关于煤吸附甲烷容量的研究[J],煤矿安全,1988,10:7-14.
58.钟玲文,张新民.煤的吸附能力及其煤化程度和煤岩组成间的关系[J],煤田地质与勘探,1990,18(4):29-35.
59.张庆玲,崔永君,曹利戈.压力对不同变质程度煤的吸附性能影响分析[J],天然气工业,2004,24(1):98-100.
60.张力,何学秋,王恩元等.煤吸附特性的研究[J],太原理工大学学报,2001,32(4):449-451.
61.张新民,庄军,张遂安.中国煤层气地质与资源评价[M],北京:科学出版社,2002.
62.傅雪海,秦勇,李贵中.特高煤级煤平衡水条件下的吸附试验[J],石油试验地质,2002,24(2):177-180.
63. Laxminarayana Ch., Crosdale P. J. Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia, coals[J], International Journal of Coal Geology, 1999, 40: 309-325.
64. Yee D., Seidle J. R., Hanson W. B.. Gas sorption on coal and measurement of gas content[J], Hydrocarbon from coal: AAPG studies in Geology, 1993, 38: 203-218.
65. Joubert J. R.,, Grein C. R.. Sorption of methane in moist coal[J], Fuel, 1973, 52: 181-185.
66. Levine J. R., Johnson P.. High microbalance sorption studies[C], 1993 International coalbed methane symposium, Tuscaloosa, Alabama, 1993, 187-195.
67. Bustin, M. Research Activities on CO_2, H_2S and SO_2 Sequestration at UBC[R], Coal-Seq I Forum, Houston, March 14-15, 2002.
68. Gluskoter, H. J., Mastalerz, M., et al. The potential for carbon dioxide sequestration in coal beds: new evidence from methane and carbon dioxide adsorption analyses of coals from lignite to anthracite [abs], Geological Society of America, Abstracts with Programs, 2002, 34(2).
69. Gasem, K. A. M., Robinson R. L., Reeves, S. R.. Adsorption of Pure Methane, Nitrogen, and Carbon Dioxide and Their Mixtures on San Juan Basin Coal[R], DOE Topical Report, contract no. DE-FC26-00NT40924, May, 2002.
70. Pashin, J. C., Carroll, R. E.. Geologic Screening Criteria for Sequestration of CO2 in Coal: Quantifying Potential of the Black Warrior Coalbed Methane Fairway, Alabama[R], Annual Technical Progress Report, U. S. Department of Energy, National Technology Laboratory, contract DE-FC-00NT40927, 2003.
71. Nelson, C. R., Hill, D. G.. Properties of Paleocene Fort Union Formation Canyon Seam Coal at the Triton Federal Coalbed Methane Well, Campbell County, Wyoming [J], paper SPE 59786 presented at the 2000 CERI/SPE Gas Technology Symposium, Calgary, Alberta, Canada, April 3-5, 2002.
72. Robert C. Burruss. CO_2 adsorption in coals as a function of rank and composition: A task in USGS research on geologic sequestration of CO_2[R], Intemational ECBM/Sequestration Consortium (Coal-Seq Ⅱ), Baltimore MD, March 25-26, 2004.
73. Maria Mastalcrz, Hal Gluskoterb, John Rupp. Carbon dioxide and methane sorption in high volatile bituminous coals from Indiana, USA[J], International Journal of Coal Geology, 2004, 60: 43-55.
74.吴世跃,郭勇义.关于注气开发煤层气机理的探讨[J],太原理工大学学报,2000,31(4):361-363.
75.吴世跃,郭勇义.注气开采煤层气增产机制的研究[J],煤炭学报,2001,26(2):199-203.
76.马志宏,郭勇义,吴世跃.注入二氧化碳及氮气驱替煤层气机理的实验研究[J],太原理工大学学报,2001,32(4):335-338.
77.吴建光,叶建平,唐书恒.注入CO2提高煤层气产能的可行性研究[J],高校地质学报,2004,10(3):463-467.
78. Gary D. Stricker, Romeo M. Flores. Potential Carbon Dioxide Sequestration and Enhanced coalbed methane Productionin the Power River and Williston Basins[C], Proceedings of the 28th International Technical Conference on Coal Utilization & Fuel Systems (Volume Ⅰ), Clearwater, Florida, USA, March 9-13, 2003, 387-401.
79. Scott R. Reeves. Assessment of CO_2 Sequestration and ECBM Potential of U. S. Coalbeds[R], U. S. Department of Energy, DE-FC26-00NT40924, February, 2003.
80. Reeves S. R. Geologie Sequestration of CO_2 in Deep, Unmineable Coalbeds: An Integrated Research and Commercial-Scale Field Demonstration Project[C], SPE 71749, presented at the SPE Annual Technical Conference and Exhibition, New Orleans, September 30-October 3, 2001.
81. Harry C. E. Schreurs. Potential for CO_2 sequestration in the Netherlands[C], 27th International Technical Conference on Coal Utilization & Fuel Systems, Clearwater, Florida, USA, March 4-7, 2002, 731-742.
82. Harry C. E. Schreurs. Potential for CO_2 sequestration .and enhanced coalbed methane Production in the Netherlands[C], Proceedings of the 26th International Technical Conference on Coal Utilization & Fuel Systems, Florida, USA, March 5-8, 2001, 967-978.
83. Wong S., MacLeod K., Wold M., et al. CO_2 enhanced coalbed methane Recovery Demonstration Pilot-A Case for Australia[C], 2001 International coalbed methane Symposium, Tuscaloosa, Alabama, May 14-18, 2001, 75-86.
84. Nishino J.. Adsorption of water vapor and carbon dioxide at carboxylic functional groups on the surface of coal[J], Fuel, 2001, 80: 757-764.
85.胡涛,马正飞等.甲烷超临界高压吸附等温线研究[J],天然气化工,2002,27(2):36-40.
86. C. Ozgen Karacan. Heterogeneous Sorption and Swelling in a Confined and Stressed Coal during CO_2 Injection[J], Energy & Fuels, 2003, 17(6): 1595-1608.
87. Harpalani S., Schraufnagel R. A.. Influence of Matrix Shrinkage and Compressibility on Gas Production from Coalbed Methane Reservoirs[C], SPE 20729, SPE Annual Technical Conference and Exhibition, New Orleans, Louisiana, 23-26 September, 1990.
88. Seidle, J. P. and Huitt, L. G.. Experimental Measurement of Coal Matrix Shrinkage Due to Gas Desorption and Implications for Cleat Permeability Increases, SPE 30010, International Meeting on Petroleum Engineering, Beijing, China, 14-17 November, 1995.
89. St. George J. D., Barakat, M. A.. The Change in Effective Stress with Shrinkage from Gas Desorption in Coal[J], International Journal of Coal Geology, 2001, 45: 105-113.
90.李明,顾安忠.气体临界温度以上吸附平衡的预测研究[J],物理化学学报,2004,17(5):602-606.
91.胡英.物理化学(上册)[M],第4版,北京:高等教育出版社,1999,1-30.
92.朱自强,徐汛.化工热力学[M],第2版,北京:化工工业出版社,1991,6-30.
93.胡英.物理化学(下册)[M],第4版,北京:高等教育出版社,1999.
94.郗怡佳.单孔、多孔材料的分子吸附模型[J],青海大学学报(自然科学版),2001,19(6):30-34.
95.顾惕人,朱步瑶等.表面化学[M],北京:科学出版社,1994,268-274.
96.周理,周亚平.关于氢在活性炭上高压吸附特性的实验研究[J],中国科学(B辑),1996,26(5):473-480.
97. Ozawa S., Kusumi S., Ogino Y.. Physical adsorption of gases at high pressure Ⅳ: An improvement of the Dubinin-Asakhov adsorption[J], Journal Colloid Interface Science, 1976: 83-89.
98. Li Zhou, Yaping Zhou. Linearization of adsorption isotherms for high-pressure applications[J], Chemical Engineering Science, 1998, 53(14): 2531-2536.
99. Amankwah K. A. G., Schwarz J. A.. A modified approach for estimating pseudovapor pressures in the application of the Dubinin-Astakhov equatinn[J], Carbon, 1995, 33(9): 1313-1319.
100.梁燕波,童景山.简便通用型蒸汽压方程及汽化热的新算法.工程热物理学报[J],1998,19(6):673-676.
101.周亚平,周理.超临界氢在活性炭上的吸附等温线研究[J],物理化学学报,1997,13(2):119-127.
102. J. D. St. George, M. A. Barakat. The change in effective stress associated with shrinkage from gas desorption in coal[J], International Journal of Coal Geology, 2001, 45: 105-113.
103. Harpalani, S.,Schraufnagel, R.. Shrinkage of coal matrix with release of gas and its impact on permeability of coal[J], Fuel, 1990, 69: 551-556.
104.盛骤,谢式千等.概率论与数理统计[M],第三版,北京:高等教育出版社,2001,270-318.
105.史济民,汤观全.Visual Foxpro及其应用系统开发[M],北京:清华大学出版社,2000.
106. Myers A. L., Prausnitz, J. M.. Thermodynamics of mixed-gas adsorption [J], AIChE Journal., 1965, 11, 121-127.
107. Mahle J. J.. A Henry's law limits for DR and DA equations[J], Carbon, 1997, 35(3): 432-435.
108. Talu O., Zwiebel I. Multieomponent adsorption equilibria of nonideal mexture[J], AIChE Joural, 1986, 32, 1263.
109.郑丹星.化工热力学教程[M],北京:中国石化出版社,2000,81-193.
110.叶道敏,肖文钊等.等变质煤镜质体的差异与煤层甲烷的关系[J],煤田地质与勘探,1997,25(3):27-30.
111. Ettinger I. L., Eremin I., Zimakov B., et al. Natural factors influencing coal sorption Properties. I. Petrography and the sorption properties of coals[J]. Fuel, 1966, 45: 267-276.
112. Zou Shengguo, Hou Ruiyun. Application Study of Coal Content and Adsorption/Desorption Isotherm Test Technique[C], International Conference on Coalbed Methane Development and Utilization Proceedings, Beijing, 1995: 237-242.
113.钟玲文,郑玉柱,员争荣.煤在温度和压力综合影响下的吸附性能及气含量预测[J],煤炭学报,2002,27(6):581-585.
114.傅雪海.多相介质煤岩体物性的物理模拟与数值模拟[D],江苏徐州:中国矿业大学,2001.
115.GB 483—87,煤质分析试验方法一般规定[S].
116.GB5751—86,中国煤炭分类[S].
117.白浚仁,刘凤歧等.煤质分析[M],北京:煤炭工业出版社,1990,676-691.
118.俞启香.矿井瓦斯防治[M].徐州:中国矿业大学出版社,1992,12-13.
119.胡宝林等:新疆地区侏罗系中低变质煤储层吸附特征及煤层气资源前景[J],现代地质,2002,16(1):77-82.
120.李建武等.陕西省煤层气资源与勘探开发前景分析,煤田地质与勘探[J],2001,29(5):30-32.
121.刘新荣等.矿井煤层瓦斯涌出量及其与煤质关系[J],煤炭科学技术,2000,28(10):27-29.
122.罗新荣等.矿井瓦斯预测与评价[J],中国安全科学学报,1994,4(3):45-52.
123.GB/T 212—2001,煤的工业分析方法[S].
124. Jack C. Pashinl, Richard E. Carroll, Richard H. Groshong, Jr., et al. Geologic screening criteria for equestration of CO_2 in coal: quantifying potential of the black warrior coalbed methane fairway, Alabama[R], U. S. Department of Energy, National Energy Technology Laboratory, 2004.
125.蔺金太.注气提高煤层气采收率的机理研究[D],太原:太原理工大学,2000.
126. Busch, Andreas, et al. Methane and CO_2 sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures[J], International Journal of Coal Geology, 55: 205-224.
127.唐书恒,汤达帧,杨起.二元气体等温吸附-解吸中气分的变化规律[J],中国矿业大学学报,2004,33(4):448-452.
128.GB 474—1996,煤样的制各方法[S].
129.GB 476—91,煤的元素分析方法[S].
130.白浚仁.煤质学[M],北京:地质出版社,1989.
131. Kojima T., Nagamine A., et al. Absorption and Fixation of Carbon Dioxide by Rock Weathering[C], Proceedings of the Third International Conference on Carbon Dioxide Removal, Cambridge Massachusetts, September 9-11, 1996, Energy and Conservation Management, 1997, 38 Suppl: S461-S466.
131.孙茂远,黄盛初.煤层气开发利用手册[M],北京:煤炭工业出版社,1998,12-17.
132.中国煤田地质总局.中国煤层气资源[M],江苏徐州:中国矿业大学出版社,1998,1-229.
133. Ivory J., Gunter W. D., Law D., et al. Recovery of CO_2 from flue gas, CO_2 sequestration, and methane production from coalbed methane reservoirs[C], 39th Annual Conference of Metallurgists of CIM, Ottawa, Ontario, Canada, August 20-23, 2000, 487-501.
134.宋武成.天然气与中国能源[J],石油化工技术经济,2002,1:7-13.
135.周总瑛,唐跃刚.中国天然气资源特点及其在能源结构中的地位分析[J],中国矿业,2004,13(6):17-20.
136.中华人民共和国国家统计局.中国统计年鉴-2003[R],北京:中国统计出版社,2003,265.
137.胡见义.中国天然气开发利用的资源保证[A],21世纪中国石油发展战略(第一辑)[M].北京:石油工业出版社,2000,115-117.
138.张伟.关注气候变化 实现可持续发展—“减缓气候变化:发展的机遇与挑战”国际研讨会综述[R],中国社会科学院可持续发展研究中心研究快讯,2002,22:1-5.
139.黄盛初.中国煤炭开发与利用的环境影响研究[R],煤炭信息研究院洁净能源与环境中心,2003,27-100.
140.郎一环,王礼茂,顾鹏.全面建设小康社会的能源合理利用与CO_2减排[J],资源科学,2004,26(6):119-124.
141.范维唐.中国煤炭工业面临的挑战与战略对策[J],煤炭企业管理,2005,1:5-8.
142.GB/T 3715—1996,煤质及煤分析有关术语[S].
143.何宏舟.改善一次能源消费结构减少温室气体排放[J],节能与环保,2002,10:9-12.
144.俞建洪,郭祥冰.气体燃料对减缓CO_2排放的贡献[J],江西能源,2002,3:9-13.
145.张群,冯三利,杨锡禄.试论我国煤层气的基本储层特点及开发策略[J],煤炭学报,2001,26(3):230-235.