内蒙古四子王旗卫境苏木电气石矿床研究
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摘要
本文通过综合利用野外调查取证和室内分析相结合的方法,对内蒙古四子王旗卫境苏木电气石矿床的地质特征及其产出的电气石矿物学特征进行了研究,探讨了矿床的成因,并进行了资源评价,为该电气石矿床的进一步工业开发利用奠定基础。
野外调查表明,该电气石矿床按照电气石含量≥15%标准可圈定矿体38条,其中大多数矿体赋存于下二叠统江岸群新乌苏组中的变凝灰岩―白云质灰岩过渡岩段,平行于地层走向展布,集中产于西里庙向斜北西翼次一级褶皱查干哈达背斜的核部,艾力登查干德断层的上盘。
成分分析统计表明,B2O3与MgO、Al2O3呈正相关,与SiO2和CaO负相关,成矿物质相对富Al、Mg,而贫Si、Ca。微量元素分析显示,电气石大离子亲石元素和深源元素亏损。稀土元素(La/Yb)N值介于0.41-8.74,呈高度分异型;δEu介于0.48-0.93之间,显示小负异常;标准化配分模式曲线为一右倾曲线,显示为轻稀土富集型。共生石英包裹体氢、氧同位素分析表明,δD值介于-82.65- -97.88,接近岩浆水的δD值(-80%～-40%)。薄片镜下特点显示,各类矿石均具有交代凝灰岩层的残余结构。总体反映该电气石矿床属火山沉积期后热液交代复合改造成因。
电气石单矿物全岩化学分析和物相分析显示, MgO/(MgO+FeO)介于0.47~0.75之间,晶胞参数a=15.973 ?、c=7.221 ?、V=1595.4417?3,属黑电气石―镁电气石系列,偏于镁电气石。矿物特征表明,105μm粒级电气石样品的负离子释放量为42个/cm3,喷铝后的包覆粉体样品体积电阻率为1.55×108Ω.cm,具有较好的释放负离子性能和电磁屏蔽性能。
根据经验法、经济分析法、统计分析法计算结果,确定本区电气石矿床的边界品位为电气石矿物含量15%;根据方案对比法,选择电气石矿物含量20%为电气石矿的最低工业品位。共求得<334>预测经济资源量为矿石量309.29万吨,电气石矿物量为133.06万吨。同时在工作区提出深部寻找硼矿床的可能性,发现沉积锰矿床找矿线索。
A systematical study has been carried out on the Weijingsumu tourmaline deposit in Inner Mongolia, with a focus on its mineralization, geological conditions, tourmaline mineralogical characteristics, genesis and resource evaluation.
38 orebodies can be defined in the deposit according to the content of tourmaline≥15%. The majority of them exist in the transition part of metamorphosed tuff to dolomitic limestone in the Xinwusu formation of the Jiangan group of Lower Permian. The orebodies concentrate in core of the Xili Temple syncline fold, north-west wing Chaganhada anticline, top of Elidengchagan and the direction of them parallel to the stratigraphic distribution.
Component analysis shows that B2O3 is positively correlated to MgO, Al2O3, but negatively correlated to SiO2 and CaO. Al, Mg are relatively rich, while Si ,Ca are poor in mineralization substance. Trace element analysis displays that the large-ion tourmaline stone elements and the elements of deep is depleted. The ratio of (La/Yb)N, which ranges from 0.41 to 8.74, is high-shaped;δEu, from 0.48 to 0.93, is slightly negative anomaly; normalized distribution patterns curve, with light REE enrichment, is right inclined. Symbiotic quartz inclusions in hydrogen and oxygen isotope analysis exhibitδD, between -82.65 and -97.88, is close to the magma waterδD (from -80% to -40%). Various types of ore appear tuff layer of the residual structure through slice observation. Generally, it reflects that the tourmaline deposits result from the hydrothermal transformation after volcanic sedimentary.
Chemical analysis of tourmaline single mineral shows that the ratio of MgO/(MgO+FeO) rangs from 0.47 to 0.75. The parameters of tourmaline unit cell are a=15.973 ?, c=7.221 ? and V=1595.4417?3 through phase analysis. Both of analysis indicate that tourmaline in the deposit indulge in dravite, which belongs to schorl-dravite series. Tourmaline samples of 105μm particle release 42/cm3 anion and the sample coated by aluminum powder retain volume resistivity of 1.55×108?.cm. The experiment’s result shows that the tourmaline plays excellent performance on anion release and electromagnetic shielding.
Based on experience, economic analysis and statistical analysis, the thesis determine this work area's boundaries grade of tourmaline deposit for tourmaline mineral content is beyond 15%; By the contrast of project, 20% tourmaline mineral content is the minimum of Electric Industrial grade quarry. The reserves of ore resources, with <334> economic forecast, are 3.09 million tons and tourmaline mineral amount to 1.33 million tons. Moreover, the possibility of deep seabed boron prospecting in work area is put forward and prospecting clues of sedimentary manganese ore bed are discovered.
野外调查表明,该电气石矿床按照电气石含量≥15%标准可圈定矿体38条,其中大多数矿体赋存于下二叠统江岸群新乌苏组中的变凝灰岩―白云质灰岩过渡岩段,平行于地层走向展布,集中产于西里庙向斜北西翼次一级褶皱查干哈达背斜的核部,艾力登查干德断层的上盘。
成分分析统计表明,B2O3与MgO、Al2O3呈正相关,与SiO2和CaO负相关,成矿物质相对富Al、Mg,而贫Si、Ca。微量元素分析显示,电气石大离子亲石元素和深源元素亏损。稀土元素(La/Yb)N值介于0.41-8.74,呈高度分异型;δEu介于0.48-0.93之间,显示小负异常;标准化配分模式曲线为一右倾曲线,显示为轻稀土富集型。共生石英包裹体氢、氧同位素分析表明,δD值介于-82.65- -97.88,接近岩浆水的δD值(-80%～-40%)。薄片镜下特点显示,各类矿石均具有交代凝灰岩层的残余结构。总体反映该电气石矿床属火山沉积期后热液交代复合改造成因。
电气石单矿物全岩化学分析和物相分析显示, MgO/(MgO+FeO)介于0.47~0.75之间,晶胞参数a=15.973 ?、c=7.221 ?、V=1595.4417?3,属黑电气石―镁电气石系列,偏于镁电气石。矿物特征表明,105μm粒级电气石样品的负离子释放量为42个/cm3,喷铝后的包覆粉体样品体积电阻率为1.55×108Ω.cm,具有较好的释放负离子性能和电磁屏蔽性能。
根据经验法、经济分析法、统计分析法计算结果,确定本区电气石矿床的边界品位为电气石矿物含量15%;根据方案对比法,选择电气石矿物含量20%为电气石矿的最低工业品位。共求得<334>预测经济资源量为矿石量309.29万吨,电气石矿物量为133.06万吨。同时在工作区提出深部寻找硼矿床的可能性,发现沉积锰矿床找矿线索。
A systematical study has been carried out on the Weijingsumu tourmaline deposit in Inner Mongolia, with a focus on its mineralization, geological conditions, tourmaline mineralogical characteristics, genesis and resource evaluation.
38 orebodies can be defined in the deposit according to the content of tourmaline≥15%. The majority of them exist in the transition part of metamorphosed tuff to dolomitic limestone in the Xinwusu formation of the Jiangan group of Lower Permian. The orebodies concentrate in core of the Xili Temple syncline fold, north-west wing Chaganhada anticline, top of Elidengchagan and the direction of them parallel to the stratigraphic distribution.
Component analysis shows that B2O3 is positively correlated to MgO, Al2O3, but negatively correlated to SiO2 and CaO. Al, Mg are relatively rich, while Si ,Ca are poor in mineralization substance. Trace element analysis displays that the large-ion tourmaline stone elements and the elements of deep is depleted. The ratio of (La/Yb)N, which ranges from 0.41 to 8.74, is high-shaped;δEu, from 0.48 to 0.93, is slightly negative anomaly; normalized distribution patterns curve, with light REE enrichment, is right inclined. Symbiotic quartz inclusions in hydrogen and oxygen isotope analysis exhibitδD, between -82.65 and -97.88, is close to the magma waterδD (from -80% to -40%). Various types of ore appear tuff layer of the residual structure through slice observation. Generally, it reflects that the tourmaline deposits result from the hydrothermal transformation after volcanic sedimentary.
Chemical analysis of tourmaline single mineral shows that the ratio of MgO/(MgO+FeO) rangs from 0.47 to 0.75. The parameters of tourmaline unit cell are a=15.973 ?, c=7.221 ? and V=1595.4417?3 through phase analysis. Both of analysis indicate that tourmaline in the deposit indulge in dravite, which belongs to schorl-dravite series. Tourmaline samples of 105μm particle release 42/cm3 anion and the sample coated by aluminum powder retain volume resistivity of 1.55×108?.cm. The experiment’s result shows that the tourmaline plays excellent performance on anion release and electromagnetic shielding.
Based on experience, economic analysis and statistical analysis, the thesis determine this work area's boundaries grade of tourmaline deposit for tourmaline mineral content is beyond 15%; By the contrast of project, 20% tourmaline mineral content is the minimum of Electric Industrial grade quarry. The reserves of ore resources, with <334> economic forecast, are 3.09 million tons and tourmaline mineral amount to 1.33 million tons. Moreover, the possibility of deep seabed boron prospecting in work area is put forward and prospecting clues of sedimentary manganese ore bed are discovered.
引文
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