锰矿石氧化—磷酸铵镁沉淀处理焦化废水
|
摘要
针对焦化废水含有高浓度挥发酚和氨氮,难以生化处理的特性,本文提出以锰矿石氧化、磷酸铵镁(鸟粪石)沉淀两步处理焦化废水的方法。以磷酸、硫酸调节焦化废水pH-至酸性,利用锰矿石在酸性条件下的氧化性,氧化去除废水中的挥发酚及其他还原性污染物,降低废水的COD_(cr)浓度。再向锰矿石氧化后的焦化废水投加菱苦土粉,搅拌反应进行磷酸铵镁沉淀实验,去除和回收废水中的氨氮及所加的磷酸。
调节10L焦化废水pH至1.2,酸化后废水经锰矿石氧化,挥发酚浓度去除率达99%,COD_(cr)去除率达70%;向处理后废水投加菱苦土使固液比为18g/L,搅拌反应24h,氨氮以磷酸铵镁沉淀的形式得到去除和回收,去除率达90.1%,pH升高至9.4。X射线衍射(XRD)和透射电镜(TEM)对沉淀产物表征分析表明,磷酸钱镁沉淀是在菱苦土颗粒表面形成并生长的。
通过锰矿石对几种取代酚氧化的静态实验,发现锰矿石对几种对位取代酚氧化效果的顺序为:4-氯酚>4-甲酚>4-硝基酚。当苯环对位取代基为供电基时,取代酚不稳定性增大,更易被锰矿石氧化;当苯环对位取代基为吸电基时,取代酚稳定性增大,难以被锰矿石氧化。
To treat the coking wastewater which contains high concentrations of volatile phenols, ammonia-nitrogen, a two step method of manganese ore oxidation and magnesium ammonium phosphate (struvite) precipitation was proposed in this study. Firstly, the pH value was adjusted to acidity using phosphoric acid and sulphuric acid, volatile phenols and other reducing contaminations in the coking wastewater were removed by manganese oxides accoding to its strong oxidation in acidic condition. And the concentration of COD_(Cr) was decreased. Secondly, the magnesia was added to the above coking wastewater treated by manganese ore to perform the precipitation experiment, then ammonia-nitrogen and phosphate will be removed and recovered.
Adjusted pH value of 10L coking wastewater to 1.2, then acidic wastewater was oxidized by manganese ore. The removal efficiencies of volatile phenols and COD_(Cr) were 99% and 70%; then magnesia was added to the above coking wastewater treated by manganese ore, ammonia-nitrogen was removed and recovered in the form of magnesium ammonium phosphate at a solid-liquid ratio of 18 g/L after 24 hours stirring. The removal efficiency of ammonia-nitrogen was 90.1% and pH value of wastewater increased to 9.4. The characterization of the crystallized product by X-ray diffraction (XRD) and transmission electron microscope (TEM) indicated that the struvite formed and grew on the surface of the magnesia particles.
Through the static experiment on oxidation of 3 substituted phenols by manganese ore, substituted phenols reduced in the following order: 4-chlorophenol > 4-methylphenol > 4-nitrophenol. When para substituents on the benzene ring is electron-donating groups, substituted phenols are oxidized by manganese ore more easily according to the instability of substituted phenols increased. When para substituents is electron withdrawing group, substituted phenols are difficult to oxidize by manganese ore according to the stability of substituted phenols increased.
调节10L焦化废水pH至1.2,酸化后废水经锰矿石氧化,挥发酚浓度去除率达99%,COD_(cr)去除率达70%;向处理后废水投加菱苦土使固液比为18g/L,搅拌反应24h,氨氮以磷酸铵镁沉淀的形式得到去除和回收,去除率达90.1%,pH升高至9.4。X射线衍射(XRD)和透射电镜(TEM)对沉淀产物表征分析表明,磷酸钱镁沉淀是在菱苦土颗粒表面形成并生长的。
通过锰矿石对几种取代酚氧化的静态实验,发现锰矿石对几种对位取代酚氧化效果的顺序为:4-氯酚>4-甲酚>4-硝基酚。当苯环对位取代基为供电基时,取代酚不稳定性增大,更易被锰矿石氧化;当苯环对位取代基为吸电基时,取代酚稳定性增大,难以被锰矿石氧化。
To treat the coking wastewater which contains high concentrations of volatile phenols, ammonia-nitrogen, a two step method of manganese ore oxidation and magnesium ammonium phosphate (struvite) precipitation was proposed in this study. Firstly, the pH value was adjusted to acidity using phosphoric acid and sulphuric acid, volatile phenols and other reducing contaminations in the coking wastewater were removed by manganese oxides accoding to its strong oxidation in acidic condition. And the concentration of COD_(Cr) was decreased. Secondly, the magnesia was added to the above coking wastewater treated by manganese ore to perform the precipitation experiment, then ammonia-nitrogen and phosphate will be removed and recovered.
Adjusted pH value of 10L coking wastewater to 1.2, then acidic wastewater was oxidized by manganese ore. The removal efficiencies of volatile phenols and COD_(Cr) were 99% and 70%; then magnesia was added to the above coking wastewater treated by manganese ore, ammonia-nitrogen was removed and recovered in the form of magnesium ammonium phosphate at a solid-liquid ratio of 18 g/L after 24 hours stirring. The removal efficiency of ammonia-nitrogen was 90.1% and pH value of wastewater increased to 9.4. The characterization of the crystallized product by X-ray diffraction (XRD) and transmission electron microscope (TEM) indicated that the struvite formed and grew on the surface of the magnesia particles.
Through the static experiment on oxidation of 3 substituted phenols by manganese ore, substituted phenols reduced in the following order: 4-chlorophenol > 4-methylphenol > 4-nitrophenol. When para substituents on the benzene ring is electron-donating groups, substituted phenols are oxidized by manganese ore more easily according to the instability of substituted phenols increased. When para substituents is electron withdrawing group, substituted phenols are difficult to oxidize by manganese ore according to the stability of substituted phenols increased.
引文
[1]Zhang M,Tay J H,Qian Y,et al.Coke plant wastewater treatment by fixed biofilm system for COD and NH_3-N removal[J].Water Research,1998,32(2):519-527.
[2]Chao Y M,Tseng I C,Chang J S.Mechanism for sludge acidification in aerobic treatment of coking wastewater[J].Journal of Hazardous Materials,2006,137(3):1781-1787.
[3]Maran(?)n E,V(?)zquezI,Rodr(?)guez J,et al.Treatment of coke wastewater in a sequential batch reactor(SBR) at pilot plant scale[J].Bioresource Technology,2008,99(10):4192-4198.
[4]Ghose M K.Complete physico-chemical treatment for coke plant effluents[J].Water Research,2002,36(5):1127-1134.
[5]Azhar N G,Stuckey D C.The influence of chemical structure on the anaerobic catabolism of refractory compounds:a case study of instant coffee waste[J].Water Science and Technology,1994,30(1):223-232.
[6]Li Y M,Gu G W,Zhao J F,et al.Anoxic degradation of nitrogenous heterocyclic compounds by acclimated activated sludge[J].Process Biochemistry,2001,37(1):81-86.
[7]张能一,唐秀华,邹平,等.我国焦化废水的水质特点及其处理方法[J].净水技术,2005,24(2):42-47.
[8]D.Rajkumar,K.Palanivelu.Electrochemical treatment of industrial wastewater[J].Journal of Hazardous Materials,2004,113:123-129.
[9]李咏梅,彭永臻,顾国维,等.焦化废水中有机物在A_1-A_2-O生物膜系统中的降解机理研究[J].环境科学学报,2004,24(2):242-248.
[10]任源,韦朝海,吴超飞,等.生物流化床A/O~2工艺处理焦化废水过程中有机组分的GC/MS分析[J].环境科学学报,2006,26(11):1785-1791.
[11]赖鹏,赵华章,叶正芳,等.生物滤池A/O工艺处理焦化废水研究[J].环境科学,2007,28(12):2727-2733.
[12]李捍东,王强,田禹,等.投菌法处理高浓度焦化废水的研究[J].哈尔滨工业大学学报,2006,38(10):1801-1805.
[13]蔡军,安立超,黄荣富,等.曝气生物滤池处理焦化废水脱氮的研究[J].环境污染治理技术与设备,2006,7(11):138-141.
[14]徐金球,贾金平,徐晓军,等.超声空化效应降解焦化废水中有机物的研究[J].高校化学工程学报,2004,18(3):344-350.
[15]Ning P,Bart H J,Jiang Y J,et al.Treatment of organic pollutants in coke plant wastewater by the method of ultrasonic irradiation catalytic oxidation and activated sludge[J].Separation and Purification Technology,2005,41(2):133-139.
[16]彭荣华,李晓湘.用催化氧化法处理焦化高浓度含酚废水[J].煤炭学报,2007,32(1):90-93.
[17]赖鹏,赵华章,王超,等.铁炭微电解深度处理焦化废水的研究[J].环境工程学报,2007,1(3):15-20.
[18]谢成,晏波,韦朝海,等.焦化废水Fenton氧化预处理过程中主要有机污染物的去除[J].环境科学学报,2007,27(7):1101-1106.
[19]陈新宇,董秀芹,张敏华.焦化废水在超临界水中的催化氧化研究[J].高校化学工程学报,2007,21(6):1065-1071.
[20]贺启坏,方华,高蓉菁,等.二氧化氯催化氧化处理难降解废水技术的研究[J].环境污染治理技术与设备,2003,4(11):39-43.
[21]春媚,陈双全,杨曦,等.几种难降解有机废水的光化学处理研究[J].环境科学,1997,18(6):27-30,92-93
[22]王广建,曹长青.用Fe~0-H_2O_2氧化法处理高浓度有机废液研究[J].工业水处理,2001,21(9):21-23.
[23]陈拥军,窦和瑞,杨民,等.催化湿式氧化法在苯酚废水预处理中的应用研究[J].工业水处理,2002,22(6):19-22.
[24]方振炜,李光明,赵建夫.催化湿式氧化法处理焦化废水的分析[J].工业水处理,2003,23(1):12-15.
[25]王红梅,郑振晖.焦化废水物化方法综述.大众科技[J].2005,82(8):162-163.
[26]张小璇,任源,韦朝海,等.焦化废水生物处理尾水中残余有机污染物的活性炭吸附及其机理[J].环境科学学报,2007,27(7):1113-1120.
[27]卢建杭,王红斌,刘维屏,等.焦化废水专用混凝剂对污染物的去除效果与规律[J].环境科学,2000,21:65-68.
[28]左晨燕,何苗,张彭义,等.Fenton氧化/混凝协同处理焦化废水生物出水的研究[J].环境科学,2006,27(11):2201-2205.
[29]宁平,徐金球,黄东宾,等.超声辐照2活性污泥联合处理焦化废水[J].环境科学,2003,24(3):65-69.
[30]刘红,张林霞,吴克明.吸附-氧化法处理焦化废水的研究[J].工业水处理,2003,23(5):35-37.
[31]许海燕,刘亚菲,唐文伟,等.超声、电解与Fenton试剂处理焦化废水的试验研究[J].工业水处理,2004,24(2):43-45.
[32]王业耀,袁彦肖,田仁生.焦化废水处理技术研究进展[J].工业水处理,2002,22(7):1-5.
[33]高翔,鲁安怀,郑辙,等.锰的氧化物和氢氧化物在污染水体净化中的应用研究 现状[J].矿物岩石,2002,22(1):77-82.
[34]高翔,鲁安怀,秦善,等.天然锰钾矿晶体化学特征及其环境属性[J].岩石矿物学杂志,2001,20(4):477-484.
[35]鲁安怀.无机界矿物天然自净化功能之矿物超微孔道效应[J].岩石矿物学杂志,2005,24(6):503-510.
[36]鲁安怀.环境矿物材料基本性能—无机界矿物天然自净化功能[J].岩石矿物学杂志,2001,20(4):371-381.
[37]刘迎新,秦善,刘瑞,等.孔道结构矿物及其晶体结构特征[J].北京大学学报(自然科学版),2004,40(6):993-1000.
[38]Julien C M,Massot M,Poinsignon C.Lattice vibrations of manganese oxides:Part Ⅰ.Periodic structures[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2004,60(3):689-700.
[39]Post Jeffrey E.Manganese oxide minerals:Crystal structures and economic and environmental significance[J].Process National Academic Society,1999,96:3447-3454.
[40]Hill J R,Freeman C M,Rossouw M H.Understanding γ-MnO2 by molecular modeling[J].Journal of Solid State Chemistry,2004,177(1):165-175.
[41]郑德圣,鲁安怀,秦善,等.天然锰钾矿吸附水溶液中Hg~(2+)的实验研究[J].岩石矿物学杂志,2001,20(4):559-567.
[42]郑德圣,鲁安怀,高翔,等.天然锰钾矿处理含Cd~(2+)废水实验研究[J].岩石矿物学杂志,2003,22(4):360-364.
[43]朱孟强,潘纲,李贤良,等.EXAFS研究不同酸度下Zn~(2+)在水锰矿表面的吸附和沉淀[J].物理化学学报,2005,21(10):1169-1173.
[44]陈红,叶兆杰,方士,等.不同状态MnO_2对废水中As(Ⅲ)的吸附研究[J].中国环境科学,1998,18(2):126-130.
[45]Ouvrard S,Donato P H,Simonnot M O,et al.Natural manganese oxide:Combined analytical approach for solid characterization and arsenic retention[J].Geochimicaet Cosmochimica Acta,2005,69(11):2715-2724.
[46]Wolfgang D,Reiner S,Martin J.Oxidation of arsenate(Ⅲ) with manganese oxides in water treatment[J].Water research,1995,29(1):297-305.
[47]Debasish M,Debaraj M,Roy C G,et al.Effect of dissolved organic matter on the adsorption and stability of As(Ⅴ) on manganese wad[J].Separation and Purification Technology,2006,49:223-229.
[48]Randall S R,Sherman D M,Ragnarsdottir K V.An extended X-ray absorption fine structure spectroscopy investigation of cadmium sorption on cryptomelane(KMn_8O_16)[J].Chemical Geology,1998,(151):95-106.
[49]Loganathan P,Burau R G.Sorption of heavy metal lons by a hydrous manganese oxide[J].Geochimicaet Cosmochimica Acta,1973,37:1277-1293.
[50]陈天虎,汪家权.天然锰矿物催化氧化法处理含硫废水研究[J].环境科学,1993,14(4):58-61.
[51]刘瑞霞,汤鸿霄.不同染料化合物在天然锰矿界面的脱色特性[J].环境化学,2000,19(4):341-347.
[52]Liu R X,Tang H X.Oxidative decolorization of direct light red F3B dye at natural manganese mineral surface[J].Water research,2000,34(16):4029-4035.
[53]杨欣,鲁安怀,李改云,等.天然锰钾矿处理印染废水实验研[J].岩石矿物学杂志,2003,22(4):369-373.
[54]Chen G,Qing C S,Chen T H,et al.Study on decoloration of acidic scarlet GR by pyrolusite oxidation under acid condition[J].Acta of Geologica Sinica,2006,80(2):257-261.
[55]马子川,蒋兰宏,董丽丽,等.新生MnO_2对水中酸性媒介深黄GG的吸附脱色作用[J].环境污染与防治,2002,24(3):157-158,179.
[56]马子川,董丽丽,康跃惠,等.新生态MnO_2吸附剂对酸性媒介染料废水脱色特性研究[J].环境污染治理技术与设备,2002,3(1):19-22.
[57]董丽丽,马子川,王洪义.新生态MnO_2吸附法处理水溶性阴离子染料废水的研究[J].环境污染与防治,2004,16(2):98-100.
[58]郑红,汤鸿霄.天然矿物锰矿砂对苯酚的界面吸附与降解研究[J].环境科学学报,1999,19(6):619-624.
[59]郑红,汤鸿霄.锰矿砂对取代酚的光氧化作用研究[J].环境科学学报,1999,19(5):550-555.
[60]李改云,鲁安怀,高翔,等.天然锰钾矿氧化降解水体中苯酚实验研究[J].岩石矿物学杂志,2003,22(2):162-166.
[61]李改云,鲁安怀,饶竹,等.天然锰钾矿氧化降解水体中的苯胺研究[J].矿物岩石地球化学通报,2004,23(4):314-317.
[62]李改云,鲁安怀,饶竹.天然锰钾矿氧化降解水体中苯酚机理研究[J].岩石矿物学杂志,2003,22(4):365-368.
[63]Ioffe L M,Bosch P,Viveros T,et al.Natural manganese oxides as catalysts for oxidative coupling of methane:a structural and degradation study[J].Materials chemistry and physics,1997,51:269-275.
[64]Ioffe L M,Lopez T,Borodko Y G,et al.Oxidative coupling of methane over natural manganese oxide[J].Journal of molecular catalysis,1995,98:25-34.
[65]Vione D,Maurino V,Minero C,et al.Phenol nitration upon oxidation of nitrite by Mn(Ⅲ,Ⅳ)(hydr)oxides[J].Chemosphere,2004,55:941-949.
[66]Bernard S,Chazal P H,Mazet M.Removal of organic compounds by adsorption on pyrolusite(β-MnO_2)[J].Water Research,1997,31(5):1216-1222.
[67]王建森,宋永会,袁鹏,等.基于PHREEQC程序的磷酸铵镁结晶法污水处理工艺模型化研究[J].环境科学学报,2006,26(2):208-213.
[68]Rawn A M,Banta A P,Pomeroy R.Multiple-stage sewage sludge digestion[J].Transactions of ASCE,1993,10(1):93-132.
[69]Ohlinger K N,Young T M,Schroeder E D.Kinetics effects on preferential struvite accumulation in wastewater[J].Journal of Environmental Engineering,1999,125(5):730-737.
[70]Doyle J D,Parsons S A.Struvite formation,control and recovery[J].Water Research,2002,36:3925-3940.
[71]Nelson N O,Mikkelsen R L,Hesterberg D L.Struvite precipitation in anaerobic swine lagoon liquid:effect of pH and Mg:P ratio and determination of rate constant[J].Bioresource Technology,2003,89(3):229-236.
[72]Burns R T,Moody L B,Walker F R,et al.Laboratory and in situ reductions of soluble phosphorus in swine waste slurries[J].Environmental Technology,2001,22(11):1273-1278.
[73]Li X Z,Zhao Q L,Hao X D.Ammonium removal from landfill leachate by chemical precipitation[J].Waste Management,1999,19:409-415.
[74]Zdybiewska M W,Kula B.Removal of ammonia nitrogen by the precipitation method,on the example of some selected waste waters[J].Water Science and Technology,1991,24(7):229-234.
[75]T(?)nay O,Kabdasli I,Orhon D,et al.Ammonia removal by magnesium ammonium phosphate precipitation in industrial wastewaters[J].Water Science and Technology,1997,36(2):225-228.
[76]Battistoni P,Fava G,Pavan P,et al.Phosphate removal in anaerobic liquors by struvite crystallization without addition of chemicals:preliminary results[J].Water Research,1997,31(11):2925-2929.
[77]M(?)nch E V,Barr K.Controlled struvite crystallization for removing phosphorus from anaerobic digester sidestreams[J].Water Research,2001,35(1):151-159.
[78]Kvarnstr(?)m E,Sch(?)nning C,Carlsson-Reich M,et al.Recycling of wastewater-derived phosphorus in Swedish agriculture-a proposal[J].Water Science and Technology,2003,48(1):19-25.
[79]Stratful I,Scrimshaw M D,Lester J N.Conditions influencing the precipitation of magnesium ammonium phosphate[J].Water Research,2001,35(17):4191-4199.
[80]Booker N A,Priestley A J,Fraser I H.Struvite formation in wastewater treatment plants:opportunities for nutrient recovery[J].Environmental Technology,1999,20(7):777-782.
[81]刘小澜,王继徽,黄稳水,等.磷酸铵镁法处理焦化厂高浓度氨氮废水[J].环境污染治理技术与设备,2005,6(3):65-68.
[82]赵庆良,李湘中.化学沉淀法去除垃圾渗滤液中的氨氮[J].环境科学,1999,20(5):90-92.
[83]Lee S I,Weon S Y,Lee C W,et al.Removal of nitrogen and phosphate from wastewater by addition of bittern[J].Chemosphere,2003,51:265-271.
[84]Jaffer Y,Clark T A,Pearce P,et al.Potential phosphorus recovery by struvite formation[J].Water Research,2002,36:1834-1842.
[85]Suzuki K,Tanaka Y,Osada T,et al.Removal of phosphate,magnesium and calcium from swine wastewater through crystallization enhanced by aeration[J].Water Research,2002,36(12):2991-2998.
[86]Battistoni P,Angelis A D,Pavan P,et al.Phosphorus removal from a real anaerobic supernatant by struvite crystallization[J].Water Research,2001,35(9):2167-2178.
[87]Yoshino M,Yao M,Tsuno H,et al.Removal and recovery of phosphate and ammonium as struvite from supernatant in anaerobic digestion[J].Water Science and Technology,2003,48:171-178.
[88]Song Y H,Yuan P,Zheng B H,et al.Nutrients removal and recovery by crystallization of magnesium ammonium phosphate from synthetic swine wastewater[J].Chemosphere,2007,69(2):319-324.
[89]Chimenos J M,Fern(?)ndez A I,Villalba G,et al.Removal of ammonium and phosphates from wastewater resulting from the process of cochineal extraction using MgO-containing by-product[J].Water Research,2003,37:1601-1607.
[90]Quintana M,S(?)nchez E,Colmenarejo M F,et al.Kinetics of phosphorus removal and struvite formation by the utilization of by-product of magnesium oxide production[J].Chemical Engineering Journal,2005,111(1):45-52.
[91]钱易,文一波.焦化废水中难降解有机物去除的研究[J].环境科学研究,1992,5(5):1-8.
[92]赵建夫,钱易.用厌氧酸化预处理焦化废水的研究[J].环境科学,1990,11(3):30-33.
[93]矿产地质研究院.锰矿石分析[M].北京:地质出版社,1991.
[94]周方钦,彭美春,黄刚,等.软锰矿中二氧化锰含量的快速滴定[J].冶金分析,2004,24(3):46-47.
[95]Kijima N,Yasuda H,Sato T,et al.Preparation and characterization of open tunnel oxide α-MnO_2 precipitated by ozone oxidation[J].Journal of Solid State Chemistry, 2001.159:94-102.
[96]大连理工大学无机化学教研室.无机化学(第四版)[M].北京:高等教育出版社,2001.
[97]张芳西,金承基,周淑芬,等.含酚废水的处理与利用[M].北京:化学工业出版社.1983.
[98]王红娟,奚红霞,夏启斌,等.含酚废水处理技术的现状与丌发前景[J].工业水处理,2002,22(6):6-9.
[99]包军杰,余贵芬,蒋新,等.改性凹凸棒石对模拟含酚废水处理机制的研究[J].环境化学,2006,25(1):37-40.
[100]王文军,王文华,张学林,等.生物膜及其各种组分对4-氯酚化合物的吸附特征[J].环境科学,2001,22(2):19-24.
[101]辛梅华,李明春,谢英.新型改性壳聚糖微球的制备及其对氯酚的吸附研究[J].环境科学学报,2007,27(8):1275-1280.
[102]叶李艺,钟辉,张会平.对氯苯酚在活性炭上的吸附与脱附工艺[J].厦门大学学报(自然科学版),1998,37(4):542-546.
[103]许金全,段五华,周秀珠,等.用HL离心萃取器处理含对硝基酚废水的研究[J].环境污染治理技术与设备,2006,7(10):124-127.
[104]王琳玲,杨海,张磊,等.活性碳纤维对硝基酚的吸附行为和应用研究[J].工业水处理,2003,23(2):23-25.
[105]唐树民,唐树和,费正皓.对硝基酚在几种树脂上的吸附性能研究[J].应用化工,2006,35(7):507-509.
[106]陈一良,潘丙才,孟凡伟,等.苯酚及对硝基酚在大孔树脂上吸附等温线的研究[J].离子交换与吸附,2004,20(3):205-213.
[107]郜瑞莹,王建龙.pH对厌氧颗粒污泥吸附4-氯酚的影响[J].环境科学,2007,28(4):791-794.
[108]付川,祁俊生,蔡杭锋.Fe~(3+)掺杂对纳米TiO2薄膜光催化降解苯酚活性的影响[J].重庆大学学报(自然科学版),2004,27(11):74-76.
[109]王丽娟,廖立兵,韩琳.TiO_2-蒙脱石光催化降解苯酚的实验研究[J].矿物岩石地球化学通报,2004,23(4):310-313.
[110]胡春,王怡中,汤鸿霄.TiO_2光催化氧化苯酚动力学研究[J].环境科学,1997,18(4):1-5.
[111]李海燕,施银桃,曾庆福.紫外光锰矿协同催化臭氧化水中4-氯苯酚[J].安全与环境学报,2004,4(2):31-33.
[112]王怡中,胡春,汤鸿霄.在TiO_2催化剂上苯酚光催化氧化反应研究:1.降解产物分布及反应途径[J].环境科学学报,1995,15(4):472-479.
[113]姜洪泉,于秀娟,王鹏,等.高铁酸钾预氧化去除水中苯酚及其机理[J].中国给 水排水,2003,19(13):47-48.
[114]王怡中,胡春,汤鸿霄.在TiO_2催化剂上苯酚光催化氧化反应研究:2.多相光催化氧化与直接光解反应的比较[J].环境科学学报,1998,18(3):260-264.
[115]席红安,方能虎,李中凯,等.SBA215的二氧化钛改性及其光催化降解对氯苯酚[J].化学学报,2002,60(12):2124-2128.
[116]介雯,刘建荣,许慧平.水中酚的催化空气氧化研究[J].水处理技术,1991,17(3):179-186.
[117]魏凤玉,彭书传,崔鹏,等.非均相光催化氧化法处理含酚废水[J].合肥工业大学学报(自然科学版),2002,25(4):565-568.
[118]章少平,胡丽华,魏红,等.Ni/Fe二元金属脱氯降解对氯苯酚的研究[J].环境科学,2005,26(4):59-62.
[119]张文兵,肖贤明,傅家谟,等.溶液中阴离子对UV/H_2O_2降解4-硝基酚的影响[J].中国环境科学,2002,22(4):301-304.
[120]康春莉,高红杰,郭平,等.H2O_2存在下冰相中对氯苯酚的光转化[J].中国环境科学,2008,28(6):561-565.
[121]赵德明,史惠祥,雷乐成,等.US/UV协同催化氧化降解对氯苯酚的研究[J].环境科学学报,2003,23(5):588-592.
[122]陈琳,雷乐成,杜瑛珣.UV/Fenton光催化氧化降解对氯苯酚废水反应动力学[J].环境科学学报,2004,24(2):225-230.
[123]陈琳,杜瑛珣,雷乐成.UV/H_2O_2光化学氧化降解对氯苯酚废水的反应动力学[J].坏境科学,2003,24(5):106-109.
[124]赵德明,史惠祥,雷乐成,等.US/H_2O_2组合工艺催化降解苯酚水溶液的研究[J].浙江大学学报(工学版),2004,38(2):240-243.
[125]张锦,李圭白,陈忠林,等.氯与高锰酸钾复合药剂对水中苯酚及氯酚的去除效果[J].环境化学,2002,21(1):73-77
[126]刘征涛,李兆利,李政.氯酚类化合物对淡水发光菌Q67的联合毒性[J].环境科学研究,2008,21(2):115-119.
[127]张立珠,陈忠林,马军,等.水溶液中新生态MnO_2对苯酚的氧化作用及机理研究[J].环境科学,2006,27(5):941-944.
[128]宋垠先,谢巧勤,陈天虎,等.天然锰氧化物矿物氧化废水中苯酚的动力学研究[J].矿物岩石地球化学通报,2006,25(4):324-329.
[129]高鸿宾.有机化学(第三版)[M].北京,高等教育出版社,1999.
[130]朱荣.微电解-锰矿物氧化组合工艺处理硝基酚废水[D].合肥,合肥工业大学,2007.
[131]Stone A T.Reductive dissolution of manganese oxides by substituted phenols[J].Environmental Science & Technology,1987,21(10):979-988.
[132]鲁安怀.矿物学研究从资源属性到环境属性的发展[J].高校地质学报,2000,6(2):245-251.
[133]鲁安怀.环境矿物材料在土壤、水体、大气污染治理中的利用[J].岩石矿物学杂志,1999,18(4):292-300.
[134]鲁安怀.矿物法—环境污染治理的第四类方法[J].地学前缘,2005,12(1):196-205.
[135]宋垠先.氧化型锰矿石氧化焦化废水实验研究[D].合肥,合肥工业大学,2007.
[2]Chao Y M,Tseng I C,Chang J S.Mechanism for sludge acidification in aerobic treatment of coking wastewater[J].Journal of Hazardous Materials,2006,137(3):1781-1787.
[3]Maran(?)n E,V(?)zquezI,Rodr(?)guez J,et al.Treatment of coke wastewater in a sequential batch reactor(SBR) at pilot plant scale[J].Bioresource Technology,2008,99(10):4192-4198.
[4]Ghose M K.Complete physico-chemical treatment for coke plant effluents[J].Water Research,2002,36(5):1127-1134.
[5]Azhar N G,Stuckey D C.The influence of chemical structure on the anaerobic catabolism of refractory compounds:a case study of instant coffee waste[J].Water Science and Technology,1994,30(1):223-232.
[6]Li Y M,Gu G W,Zhao J F,et al.Anoxic degradation of nitrogenous heterocyclic compounds by acclimated activated sludge[J].Process Biochemistry,2001,37(1):81-86.
[7]张能一,唐秀华,邹平,等.我国焦化废水的水质特点及其处理方法[J].净水技术,2005,24(2):42-47.
[8]D.Rajkumar,K.Palanivelu.Electrochemical treatment of industrial wastewater[J].Journal of Hazardous Materials,2004,113:123-129.
[9]李咏梅,彭永臻,顾国维,等.焦化废水中有机物在A_1-A_2-O生物膜系统中的降解机理研究[J].环境科学学报,2004,24(2):242-248.
[10]任源,韦朝海,吴超飞,等.生物流化床A/O~2工艺处理焦化废水过程中有机组分的GC/MS分析[J].环境科学学报,2006,26(11):1785-1791.
[11]赖鹏,赵华章,叶正芳,等.生物滤池A/O工艺处理焦化废水研究[J].环境科学,2007,28(12):2727-2733.
[12]李捍东,王强,田禹,等.投菌法处理高浓度焦化废水的研究[J].哈尔滨工业大学学报,2006,38(10):1801-1805.
[13]蔡军,安立超,黄荣富,等.曝气生物滤池处理焦化废水脱氮的研究[J].环境污染治理技术与设备,2006,7(11):138-141.
[14]徐金球,贾金平,徐晓军,等.超声空化效应降解焦化废水中有机物的研究[J].高校化学工程学报,2004,18(3):344-350.
[15]Ning P,Bart H J,Jiang Y J,et al.Treatment of organic pollutants in coke plant wastewater by the method of ultrasonic irradiation catalytic oxidation and activated sludge[J].Separation and Purification Technology,2005,41(2):133-139.
[16]彭荣华,李晓湘.用催化氧化法处理焦化高浓度含酚废水[J].煤炭学报,2007,32(1):90-93.
[17]赖鹏,赵华章,王超,等.铁炭微电解深度处理焦化废水的研究[J].环境工程学报,2007,1(3):15-20.
[18]谢成,晏波,韦朝海,等.焦化废水Fenton氧化预处理过程中主要有机污染物的去除[J].环境科学学报,2007,27(7):1101-1106.
[19]陈新宇,董秀芹,张敏华.焦化废水在超临界水中的催化氧化研究[J].高校化学工程学报,2007,21(6):1065-1071.
[20]贺启坏,方华,高蓉菁,等.二氧化氯催化氧化处理难降解废水技术的研究[J].环境污染治理技术与设备,2003,4(11):39-43.
[21]春媚,陈双全,杨曦,等.几种难降解有机废水的光化学处理研究[J].环境科学,1997,18(6):27-30,92-93
[22]王广建,曹长青.用Fe~0-H_2O_2氧化法处理高浓度有机废液研究[J].工业水处理,2001,21(9):21-23.
[23]陈拥军,窦和瑞,杨民,等.催化湿式氧化法在苯酚废水预处理中的应用研究[J].工业水处理,2002,22(6):19-22.
[24]方振炜,李光明,赵建夫.催化湿式氧化法处理焦化废水的分析[J].工业水处理,2003,23(1):12-15.
[25]王红梅,郑振晖.焦化废水物化方法综述.大众科技[J].2005,82(8):162-163.
[26]张小璇,任源,韦朝海,等.焦化废水生物处理尾水中残余有机污染物的活性炭吸附及其机理[J].环境科学学报,2007,27(7):1113-1120.
[27]卢建杭,王红斌,刘维屏,等.焦化废水专用混凝剂对污染物的去除效果与规律[J].环境科学,2000,21:65-68.
[28]左晨燕,何苗,张彭义,等.Fenton氧化/混凝协同处理焦化废水生物出水的研究[J].环境科学,2006,27(11):2201-2205.
[29]宁平,徐金球,黄东宾,等.超声辐照2活性污泥联合处理焦化废水[J].环境科学,2003,24(3):65-69.
[30]刘红,张林霞,吴克明.吸附-氧化法处理焦化废水的研究[J].工业水处理,2003,23(5):35-37.
[31]许海燕,刘亚菲,唐文伟,等.超声、电解与Fenton试剂处理焦化废水的试验研究[J].工业水处理,2004,24(2):43-45.
[32]王业耀,袁彦肖,田仁生.焦化废水处理技术研究进展[J].工业水处理,2002,22(7):1-5.
[33]高翔,鲁安怀,郑辙,等.锰的氧化物和氢氧化物在污染水体净化中的应用研究 现状[J].矿物岩石,2002,22(1):77-82.
[34]高翔,鲁安怀,秦善,等.天然锰钾矿晶体化学特征及其环境属性[J].岩石矿物学杂志,2001,20(4):477-484.
[35]鲁安怀.无机界矿物天然自净化功能之矿物超微孔道效应[J].岩石矿物学杂志,2005,24(6):503-510.
[36]鲁安怀.环境矿物材料基本性能—无机界矿物天然自净化功能[J].岩石矿物学杂志,2001,20(4):371-381.
[37]刘迎新,秦善,刘瑞,等.孔道结构矿物及其晶体结构特征[J].北京大学学报(自然科学版),2004,40(6):993-1000.
[38]Julien C M,Massot M,Poinsignon C.Lattice vibrations of manganese oxides:Part Ⅰ.Periodic structures[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2004,60(3):689-700.
[39]Post Jeffrey E.Manganese oxide minerals:Crystal structures and economic and environmental significance[J].Process National Academic Society,1999,96:3447-3454.
[40]Hill J R,Freeman C M,Rossouw M H.Understanding γ-MnO2 by molecular modeling[J].Journal of Solid State Chemistry,2004,177(1):165-175.
[41]郑德圣,鲁安怀,秦善,等.天然锰钾矿吸附水溶液中Hg~(2+)的实验研究[J].岩石矿物学杂志,2001,20(4):559-567.
[42]郑德圣,鲁安怀,高翔,等.天然锰钾矿处理含Cd~(2+)废水实验研究[J].岩石矿物学杂志,2003,22(4):360-364.
[43]朱孟强,潘纲,李贤良,等.EXAFS研究不同酸度下Zn~(2+)在水锰矿表面的吸附和沉淀[J].物理化学学报,2005,21(10):1169-1173.
[44]陈红,叶兆杰,方士,等.不同状态MnO_2对废水中As(Ⅲ)的吸附研究[J].中国环境科学,1998,18(2):126-130.
[45]Ouvrard S,Donato P H,Simonnot M O,et al.Natural manganese oxide:Combined analytical approach for solid characterization and arsenic retention[J].Geochimicaet Cosmochimica Acta,2005,69(11):2715-2724.
[46]Wolfgang D,Reiner S,Martin J.Oxidation of arsenate(Ⅲ) with manganese oxides in water treatment[J].Water research,1995,29(1):297-305.
[47]Debasish M,Debaraj M,Roy C G,et al.Effect of dissolved organic matter on the adsorption and stability of As(Ⅴ) on manganese wad[J].Separation and Purification Technology,2006,49:223-229.
[48]Randall S R,Sherman D M,Ragnarsdottir K V.An extended X-ray absorption fine structure spectroscopy investigation of cadmium sorption on cryptomelane(KMn_8O_16)[J].Chemical Geology,1998,(151):95-106.
[49]Loganathan P,Burau R G.Sorption of heavy metal lons by a hydrous manganese oxide[J].Geochimicaet Cosmochimica Acta,1973,37:1277-1293.
[50]陈天虎,汪家权.天然锰矿物催化氧化法处理含硫废水研究[J].环境科学,1993,14(4):58-61.
[51]刘瑞霞,汤鸿霄.不同染料化合物在天然锰矿界面的脱色特性[J].环境化学,2000,19(4):341-347.
[52]Liu R X,Tang H X.Oxidative decolorization of direct light red F3B dye at natural manganese mineral surface[J].Water research,2000,34(16):4029-4035.
[53]杨欣,鲁安怀,李改云,等.天然锰钾矿处理印染废水实验研[J].岩石矿物学杂志,2003,22(4):369-373.
[54]Chen G,Qing C S,Chen T H,et al.Study on decoloration of acidic scarlet GR by pyrolusite oxidation under acid condition[J].Acta of Geologica Sinica,2006,80(2):257-261.
[55]马子川,蒋兰宏,董丽丽,等.新生MnO_2对水中酸性媒介深黄GG的吸附脱色作用[J].环境污染与防治,2002,24(3):157-158,179.
[56]马子川,董丽丽,康跃惠,等.新生态MnO_2吸附剂对酸性媒介染料废水脱色特性研究[J].环境污染治理技术与设备,2002,3(1):19-22.
[57]董丽丽,马子川,王洪义.新生态MnO_2吸附法处理水溶性阴离子染料废水的研究[J].环境污染与防治,2004,16(2):98-100.
[58]郑红,汤鸿霄.天然矿物锰矿砂对苯酚的界面吸附与降解研究[J].环境科学学报,1999,19(6):619-624.
[59]郑红,汤鸿霄.锰矿砂对取代酚的光氧化作用研究[J].环境科学学报,1999,19(5):550-555.
[60]李改云,鲁安怀,高翔,等.天然锰钾矿氧化降解水体中苯酚实验研究[J].岩石矿物学杂志,2003,22(2):162-166.
[61]李改云,鲁安怀,饶竹,等.天然锰钾矿氧化降解水体中的苯胺研究[J].矿物岩石地球化学通报,2004,23(4):314-317.
[62]李改云,鲁安怀,饶竹.天然锰钾矿氧化降解水体中苯酚机理研究[J].岩石矿物学杂志,2003,22(4):365-368.
[63]Ioffe L M,Bosch P,Viveros T,et al.Natural manganese oxides as catalysts for oxidative coupling of methane:a structural and degradation study[J].Materials chemistry and physics,1997,51:269-275.
[64]Ioffe L M,Lopez T,Borodko Y G,et al.Oxidative coupling of methane over natural manganese oxide[J].Journal of molecular catalysis,1995,98:25-34.
[65]Vione D,Maurino V,Minero C,et al.Phenol nitration upon oxidation of nitrite by Mn(Ⅲ,Ⅳ)(hydr)oxides[J].Chemosphere,2004,55:941-949.
[66]Bernard S,Chazal P H,Mazet M.Removal of organic compounds by adsorption on pyrolusite(β-MnO_2)[J].Water Research,1997,31(5):1216-1222.
[67]王建森,宋永会,袁鹏,等.基于PHREEQC程序的磷酸铵镁结晶法污水处理工艺模型化研究[J].环境科学学报,2006,26(2):208-213.
[68]Rawn A M,Banta A P,Pomeroy R.Multiple-stage sewage sludge digestion[J].Transactions of ASCE,1993,10(1):93-132.
[69]Ohlinger K N,Young T M,Schroeder E D.Kinetics effects on preferential struvite accumulation in wastewater[J].Journal of Environmental Engineering,1999,125(5):730-737.
[70]Doyle J D,Parsons S A.Struvite formation,control and recovery[J].Water Research,2002,36:3925-3940.
[71]Nelson N O,Mikkelsen R L,Hesterberg D L.Struvite precipitation in anaerobic swine lagoon liquid:effect of pH and Mg:P ratio and determination of rate constant[J].Bioresource Technology,2003,89(3):229-236.
[72]Burns R T,Moody L B,Walker F R,et al.Laboratory and in situ reductions of soluble phosphorus in swine waste slurries[J].Environmental Technology,2001,22(11):1273-1278.
[73]Li X Z,Zhao Q L,Hao X D.Ammonium removal from landfill leachate by chemical precipitation[J].Waste Management,1999,19:409-415.
[74]Zdybiewska M W,Kula B.Removal of ammonia nitrogen by the precipitation method,on the example of some selected waste waters[J].Water Science and Technology,1991,24(7):229-234.
[75]T(?)nay O,Kabdasli I,Orhon D,et al.Ammonia removal by magnesium ammonium phosphate precipitation in industrial wastewaters[J].Water Science and Technology,1997,36(2):225-228.
[76]Battistoni P,Fava G,Pavan P,et al.Phosphate removal in anaerobic liquors by struvite crystallization without addition of chemicals:preliminary results[J].Water Research,1997,31(11):2925-2929.
[77]M(?)nch E V,Barr K.Controlled struvite crystallization for removing phosphorus from anaerobic digester sidestreams[J].Water Research,2001,35(1):151-159.
[78]Kvarnstr(?)m E,Sch(?)nning C,Carlsson-Reich M,et al.Recycling of wastewater-derived phosphorus in Swedish agriculture-a proposal[J].Water Science and Technology,2003,48(1):19-25.
[79]Stratful I,Scrimshaw M D,Lester J N.Conditions influencing the precipitation of magnesium ammonium phosphate[J].Water Research,2001,35(17):4191-4199.
[80]Booker N A,Priestley A J,Fraser I H.Struvite formation in wastewater treatment plants:opportunities for nutrient recovery[J].Environmental Technology,1999,20(7):777-782.
[81]刘小澜,王继徽,黄稳水,等.磷酸铵镁法处理焦化厂高浓度氨氮废水[J].环境污染治理技术与设备,2005,6(3):65-68.
[82]赵庆良,李湘中.化学沉淀法去除垃圾渗滤液中的氨氮[J].环境科学,1999,20(5):90-92.
[83]Lee S I,Weon S Y,Lee C W,et al.Removal of nitrogen and phosphate from wastewater by addition of bittern[J].Chemosphere,2003,51:265-271.
[84]Jaffer Y,Clark T A,Pearce P,et al.Potential phosphorus recovery by struvite formation[J].Water Research,2002,36:1834-1842.
[85]Suzuki K,Tanaka Y,Osada T,et al.Removal of phosphate,magnesium and calcium from swine wastewater through crystallization enhanced by aeration[J].Water Research,2002,36(12):2991-2998.
[86]Battistoni P,Angelis A D,Pavan P,et al.Phosphorus removal from a real anaerobic supernatant by struvite crystallization[J].Water Research,2001,35(9):2167-2178.
[87]Yoshino M,Yao M,Tsuno H,et al.Removal and recovery of phosphate and ammonium as struvite from supernatant in anaerobic digestion[J].Water Science and Technology,2003,48:171-178.
[88]Song Y H,Yuan P,Zheng B H,et al.Nutrients removal and recovery by crystallization of magnesium ammonium phosphate from synthetic swine wastewater[J].Chemosphere,2007,69(2):319-324.
[89]Chimenos J M,Fern(?)ndez A I,Villalba G,et al.Removal of ammonium and phosphates from wastewater resulting from the process of cochineal extraction using MgO-containing by-product[J].Water Research,2003,37:1601-1607.
[90]Quintana M,S(?)nchez E,Colmenarejo M F,et al.Kinetics of phosphorus removal and struvite formation by the utilization of by-product of magnesium oxide production[J].Chemical Engineering Journal,2005,111(1):45-52.
[91]钱易,文一波.焦化废水中难降解有机物去除的研究[J].环境科学研究,1992,5(5):1-8.
[92]赵建夫,钱易.用厌氧酸化预处理焦化废水的研究[J].环境科学,1990,11(3):30-33.
[93]矿产地质研究院.锰矿石分析[M].北京:地质出版社,1991.
[94]周方钦,彭美春,黄刚,等.软锰矿中二氧化锰含量的快速滴定[J].冶金分析,2004,24(3):46-47.
[95]Kijima N,Yasuda H,Sato T,et al.Preparation and characterization of open tunnel oxide α-MnO_2 precipitated by ozone oxidation[J].Journal of Solid State Chemistry, 2001.159:94-102.
[96]大连理工大学无机化学教研室.无机化学(第四版)[M].北京:高等教育出版社,2001.
[97]张芳西,金承基,周淑芬,等.含酚废水的处理与利用[M].北京:化学工业出版社.1983.
[98]王红娟,奚红霞,夏启斌,等.含酚废水处理技术的现状与丌发前景[J].工业水处理,2002,22(6):6-9.
[99]包军杰,余贵芬,蒋新,等.改性凹凸棒石对模拟含酚废水处理机制的研究[J].环境化学,2006,25(1):37-40.
[100]王文军,王文华,张学林,等.生物膜及其各种组分对4-氯酚化合物的吸附特征[J].环境科学,2001,22(2):19-24.
[101]辛梅华,李明春,谢英.新型改性壳聚糖微球的制备及其对氯酚的吸附研究[J].环境科学学报,2007,27(8):1275-1280.
[102]叶李艺,钟辉,张会平.对氯苯酚在活性炭上的吸附与脱附工艺[J].厦门大学学报(自然科学版),1998,37(4):542-546.
[103]许金全,段五华,周秀珠,等.用HL离心萃取器处理含对硝基酚废水的研究[J].环境污染治理技术与设备,2006,7(10):124-127.
[104]王琳玲,杨海,张磊,等.活性碳纤维对硝基酚的吸附行为和应用研究[J].工业水处理,2003,23(2):23-25.
[105]唐树民,唐树和,费正皓.对硝基酚在几种树脂上的吸附性能研究[J].应用化工,2006,35(7):507-509.
[106]陈一良,潘丙才,孟凡伟,等.苯酚及对硝基酚在大孔树脂上吸附等温线的研究[J].离子交换与吸附,2004,20(3):205-213.
[107]郜瑞莹,王建龙.pH对厌氧颗粒污泥吸附4-氯酚的影响[J].环境科学,2007,28(4):791-794.
[108]付川,祁俊生,蔡杭锋.Fe~(3+)掺杂对纳米TiO2薄膜光催化降解苯酚活性的影响[J].重庆大学学报(自然科学版),2004,27(11):74-76.
[109]王丽娟,廖立兵,韩琳.TiO_2-蒙脱石光催化降解苯酚的实验研究[J].矿物岩石地球化学通报,2004,23(4):310-313.
[110]胡春,王怡中,汤鸿霄.TiO_2光催化氧化苯酚动力学研究[J].环境科学,1997,18(4):1-5.
[111]李海燕,施银桃,曾庆福.紫外光锰矿协同催化臭氧化水中4-氯苯酚[J].安全与环境学报,2004,4(2):31-33.
[112]王怡中,胡春,汤鸿霄.在TiO_2催化剂上苯酚光催化氧化反应研究:1.降解产物分布及反应途径[J].环境科学学报,1995,15(4):472-479.
[113]姜洪泉,于秀娟,王鹏,等.高铁酸钾预氧化去除水中苯酚及其机理[J].中国给 水排水,2003,19(13):47-48.
[114]王怡中,胡春,汤鸿霄.在TiO_2催化剂上苯酚光催化氧化反应研究:2.多相光催化氧化与直接光解反应的比较[J].环境科学学报,1998,18(3):260-264.
[115]席红安,方能虎,李中凯,等.SBA215的二氧化钛改性及其光催化降解对氯苯酚[J].化学学报,2002,60(12):2124-2128.
[116]介雯,刘建荣,许慧平.水中酚的催化空气氧化研究[J].水处理技术,1991,17(3):179-186.
[117]魏凤玉,彭书传,崔鹏,等.非均相光催化氧化法处理含酚废水[J].合肥工业大学学报(自然科学版),2002,25(4):565-568.
[118]章少平,胡丽华,魏红,等.Ni/Fe二元金属脱氯降解对氯苯酚的研究[J].环境科学,2005,26(4):59-62.
[119]张文兵,肖贤明,傅家谟,等.溶液中阴离子对UV/H_2O_2降解4-硝基酚的影响[J].中国环境科学,2002,22(4):301-304.
[120]康春莉,高红杰,郭平,等.H2O_2存在下冰相中对氯苯酚的光转化[J].中国环境科学,2008,28(6):561-565.
[121]赵德明,史惠祥,雷乐成,等.US/UV协同催化氧化降解对氯苯酚的研究[J].环境科学学报,2003,23(5):588-592.
[122]陈琳,雷乐成,杜瑛珣.UV/Fenton光催化氧化降解对氯苯酚废水反应动力学[J].环境科学学报,2004,24(2):225-230.
[123]陈琳,杜瑛珣,雷乐成.UV/H_2O_2光化学氧化降解对氯苯酚废水的反应动力学[J].坏境科学,2003,24(5):106-109.
[124]赵德明,史惠祥,雷乐成,等.US/H_2O_2组合工艺催化降解苯酚水溶液的研究[J].浙江大学学报(工学版),2004,38(2):240-243.
[125]张锦,李圭白,陈忠林,等.氯与高锰酸钾复合药剂对水中苯酚及氯酚的去除效果[J].环境化学,2002,21(1):73-77
[126]刘征涛,李兆利,李政.氯酚类化合物对淡水发光菌Q67的联合毒性[J].环境科学研究,2008,21(2):115-119.
[127]张立珠,陈忠林,马军,等.水溶液中新生态MnO_2对苯酚的氧化作用及机理研究[J].环境科学,2006,27(5):941-944.
[128]宋垠先,谢巧勤,陈天虎,等.天然锰氧化物矿物氧化废水中苯酚的动力学研究[J].矿物岩石地球化学通报,2006,25(4):324-329.
[129]高鸿宾.有机化学(第三版)[M].北京,高等教育出版社,1999.
[130]朱荣.微电解-锰矿物氧化组合工艺处理硝基酚废水[D].合肥,合肥工业大学,2007.
[131]Stone A T.Reductive dissolution of manganese oxides by substituted phenols[J].Environmental Science & Technology,1987,21(10):979-988.
[132]鲁安怀.矿物学研究从资源属性到环境属性的发展[J].高校地质学报,2000,6(2):245-251.
[133]鲁安怀.环境矿物材料在土壤、水体、大气污染治理中的利用[J].岩石矿物学杂志,1999,18(4):292-300.
[134]鲁安怀.矿物法—环境污染治理的第四类方法[J].地学前缘,2005,12(1):196-205.
[135]宋垠先.氧化型锰矿石氧化焦化废水实验研究[D].合肥,合肥工业大学,2007.