琼东南盆地天然气运聚成藏规律研究
|
摘要
琼东南盆典型特点是高温高压,天然气成藏复杂。长期以来对油气运聚成藏规律认识深度不够,对开拓新的勘探领域缺少科学依据。本研究开展琼东南盆天然气运聚成藏规律研究,取得了如下主要成果与认识:
(1) 崖13-4与崖13-6构造天然气与崖13-1构造天然气属同期形成,均来自崖南凹陷斜坡带崖城组含煤岩系;天然气主成藏期在2Ma以后;天然气经历了从崖13-1/崖13-6向崖13-4构造的区域性运移规律。
(2) 宝岛构造有两次天然气充注:早期为低成熟度烃类气,充注时间在10—8Ma以前;晚期为CO_2气,充注时间为10—8Ma;由于CO_2气突发性大量注入而充满了储层空间,阻止烃类气体进一步注入,因而形成CO2气藏。
(3) 崖21-1构造储层超压形成时间于晚中新世,明显早于崖南凹陷烃源岩大量生排气阶段;超压的形成妨碍了天然气的区域性运移,是导致了崖21-1构造未形成商业性气田的主要原因。
(4) 崖城凸起天然气勘探应将重点放在崖南凹陷的西北部;宝岛地区烃类气体勘探应避开断层,寻找较晚的圈闭构造;在超压区的天然气勘探,应寻找早期形成的圈闭体系。
本研究成果不仅对于琼东南盆地油气评价与勘探具有指导作用,而且对于我国其它类似油气盆地成藏规律的研究具有借鉴与参考价值。
The Qiongdong Basin is characterized by high temperatures and strong pressures, and complicated types of natural gas pools. For these reasons, there has been no deep understanding on the migration and accumulation patterns of gases for a long period, and lack of scientific ideas for further exploration in this basin. In this study, a combination method of fluid inclusion technique with hydrocarbon generation kinetics modeling has been applied to investigate the migration and accumulation pattern of gases in the basin. The following main results have been obtained:(1). The Ya13-4 and Ya13-6 gas pools formed with the same period of the Ya 13-1 gas pool. They were originated from a set of coal measure source rock in the Yacheng Formation from the slope area of the Yanan Depression. The gas pools were mainly filled after 2 Ma. The gas migrated from the Ya13-1/Ya13-6 structure to the Ya13-4 structure.(2). The Baodao gas pools experienced two phases of gas charging. The first phase occurred before 10-8 Ma with a lower mature hydrocarbon gas, and the second after 10-8 Ma with a large amount of CO_2 gas. The reservoirs were fully filled by the CO_2 gas during a short period, which prevented the hydrocarbon gas from further migration into the reservoirs to form the CO2 gas pools.(3) . The super-pressure system of The Ya21-1 structure was formed during late Miocene, obviously earlier than the main stage of gas generation and expulsion of the source rock. The super-pressure obstructed natural gases from a regional migration into the reservoir, which became the main reason for the Ya21-1 trap without a commercial gas.(4). The perspective area for natural gas in the Yacheng Uplift is believed in the north- west region of the Yanan Depression. The exploration for hydrocarbon gases should look for the later-formed trap , or be away from the faults in the Baodao area. The gas exploration in the super-pressure area should address the earlier-formed traps.These results not only give a guide to the gas evaluation and exploration in the Qiongddongnan Basin, but also provide a case study of gas migration and accumulation for the petroleum-bearing basins with a similar geological background.
(1) 崖13-4与崖13-6构造天然气与崖13-1构造天然气属同期形成,均来自崖南凹陷斜坡带崖城组含煤岩系;天然气主成藏期在2Ma以后;天然气经历了从崖13-1/崖13-6向崖13-4构造的区域性运移规律。
(2) 宝岛构造有两次天然气充注:早期为低成熟度烃类气,充注时间在10—8Ma以前;晚期为CO_2气,充注时间为10—8Ma;由于CO_2气突发性大量注入而充满了储层空间,阻止烃类气体进一步注入,因而形成CO2气藏。
(3) 崖21-1构造储层超压形成时间于晚中新世,明显早于崖南凹陷烃源岩大量生排气阶段;超压的形成妨碍了天然气的区域性运移,是导致了崖21-1构造未形成商业性气田的主要原因。
(4) 崖城凸起天然气勘探应将重点放在崖南凹陷的西北部;宝岛地区烃类气体勘探应避开断层,寻找较晚的圈闭构造;在超压区的天然气勘探,应寻找早期形成的圈闭体系。
本研究成果不仅对于琼东南盆地油气评价与勘探具有指导作用,而且对于我国其它类似油气盆地成藏规律的研究具有借鉴与参考价值。
The Qiongdong Basin is characterized by high temperatures and strong pressures, and complicated types of natural gas pools. For these reasons, there has been no deep understanding on the migration and accumulation patterns of gases for a long period, and lack of scientific ideas for further exploration in this basin. In this study, a combination method of fluid inclusion technique with hydrocarbon generation kinetics modeling has been applied to investigate the migration and accumulation pattern of gases in the basin. The following main results have been obtained:(1). The Ya13-4 and Ya13-6 gas pools formed with the same period of the Ya 13-1 gas pool. They were originated from a set of coal measure source rock in the Yacheng Formation from the slope area of the Yanan Depression. The gas pools were mainly filled after 2 Ma. The gas migrated from the Ya13-1/Ya13-6 structure to the Ya13-4 structure.(2). The Baodao gas pools experienced two phases of gas charging. The first phase occurred before 10-8 Ma with a lower mature hydrocarbon gas, and the second after 10-8 Ma with a large amount of CO_2 gas. The reservoirs were fully filled by the CO_2 gas during a short period, which prevented the hydrocarbon gas from further migration into the reservoirs to form the CO2 gas pools.(3) . The super-pressure system of The Ya21-1 structure was formed during late Miocene, obviously earlier than the main stage of gas generation and expulsion of the source rock. The super-pressure obstructed natural gases from a regional migration into the reservoir, which became the main reason for the Ya21-1 trap without a commercial gas.(4). The perspective area for natural gas in the Yacheng Uplift is believed in the north- west region of the Yanan Depression. The exploration for hydrocarbon gases should look for the later-formed trap , or be away from the faults in the Baodao area. The gas exploration in the super-pressure area should address the earlier-formed traps.These results not only give a guide to the gas evaluation and exploration in the Qiongddongnan Basin, but also provide a case study of gas migration and accumulation for the petroleum-bearing basins with a similar geological background.
引文
1 胡忠良,等,1995.莺-琼盆地天然气富集条件及寻找大中型气田勘探目标选择.南海西部石油公司内部报告.
2.龚再升、李思田,等,1997.南海北部大陆边缘盆地分析与油气聚集.北京:科学出版社
3.董伟良,黄保家,1999.莺歌海东方1-1气田天然气组成的非均质性和幕式充注研究。石油勘探与开发,26(2).
4.黄保家,1999.琼东南盆地天然气潜力及有利勘探方向.天然气工业.19(1):24-28.
5.张敏强、黄保家、吕明,2000.琼东南盆地生烃凹陷的比较性评价.“9.5”国家天然气攻关成果
6.董伟良,黄保家,2000.莺歌海盆地流体压裂与热流体活动及天然气的幕式运移.石油勘探与开发,27(4):36-40
7.中国石油地质志(卷16下),1990,石油工业出版社,北京,1—508。
8.林壬子,将基平,梅博文,1985.琼东南盆地油气来源的初步研究.南海西部石油公司内部报告
9.汪集呖,罗晓容,等,1996.莺歌海盆地地温场特征与天然气成藏关系研究.“9.5”国家天然气攻关成果.
10.杨计海,陈红汉1998.莺-琼盆地的压力系统及油气运移.“9.5”国家天然气攻关成果.
11.张国华、黄保家、潘贤庄,1998.莺歌海-琼东南盆地天然气的成因联系及海相烃源岩研究.“9.5”国家天然气攻关成果.
12.傅家谟,陈军红,盛国英,耿安松,刘德汉等,1995.莺歌海.琼东南盆地第三系烃源岩研究.南海西部石油公司内部报告.
13.陈红汉等,1997.琼东南盆地含烃流体活动得流体包裹体证据.中国科学,27(4):343～348。
14.张国华、黄保家、潘贤庄,1998.莺歌海-琼东南盆地天然气的成因联系及海相烃源岩研究.“9.5”国家天然气攻关成果,1-11.
15.马启富、陈斯忠、张启明、郭水生、王善书,2000.超压盆地与油气分布.北京:地质出版社.
16.董伟良,黄保家,2001.莺-琼盆地煤型气的鉴别标志和气源判识.天然气工业.20(1):23-27
17.肖贤明,李绪深,黄保家,等,2002,莺琼盆地第三系烃源岩生烃动力学研究,中海油“十五”攻关中期研究成果.
18.施继锡,等,1993.琼东南盆崖13-1气田天然气来源和运移的有机包裹体地球化学研究.内部报告.
19. Huang, B, J. and Xiao, X. M., 2002, Multiphase natural gas migration and accumulation and ist relation to diapir structure in the DF1-1 gas field, South China Sea. Marine and Petroleum Geology. 19(7): 861-872.
20. Baojia Huang, Xiaoming Xiao, Xuxuan Li, 2003, Geochemistry and origins of natural gases in the Yinggehai and Qiongdongnan basins, offshore South China Sea. Organic Geochemistry, 34: 1009-1025.
21. Baojia Huang, Xiaoming Xiao, Mingqiang Zhang, 2003, Geoch emistry, grouping and origins of crude oils in the Western Pearl River Mouth Basin, offshore South China Sea. Organic Geochemistry, 34: 993-1008.
22. Huang, B. J., Xiao, X. M., Hu, Z. L., and Yi, P., 2005, Geochemistry and episodic accumulation of natural gases from the Ledong gas field in the Yinggehain Basin, Organic Geochemistry, 36: 1689-1702.
23. Huang, B. J., Xiao, X. M., Zhu, W. L., 2004, Geochemistry, origin, and accumulation of CO2 in natural gases of thr Yinggehai basin, offshore South China Sea. AAPG 88(9), 1277-1293.
24. Hermanrud, C. 1993. Basin modelling techniques--an overview. In A. G. Dore" (Ed.), Basin modelling: Advances and applications (pp. 1-34).Stavanger: Norwegian Petroleum Society.
25. Skjeveruy, A., & Sylta, e. 1993. Modelling of expulsion and secondary migration along the south-west margin of the Horda Platform. In A. G. DoreA et al., Basin modelling: Advances and applications (pp. 499-537). In NPF Special Publication, Vol. 3. Elsevier.
26. Pepper, A. S., & Corvi, P. J. 1995. Simple kinetic models of petroleum formation. Part Ⅰ: Oil and gas generation from kerogen. Marine and Pet. Geol., 12, 291-319.
27. Pepper, A. S., & Corvi, P. J. 1995. Simple kinetic models of petroleurn formation. Part Ⅲ: modelling an open system. Marine and Pet. Geol., 12, 417-452.
28. Ungger, P. And Pelet, R., 1987, Exptrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins, Nature, 327: 52-54.
29. Ungerer, P., 1990, State of the art of research in kinetics modeling of oil formation and expulsion, Org. Geochem., 16(1-3): 1-25.
30. Braum, R., 1992, Oil and gas evolution kinetics for oil shale and petroleum source rock determined from pyrolysis-TQMS data at two heating rates, Energy and Fuel, (6): 468-474.
31. Tang, Y., Stauffer, M, 1993, Multiple cold trap pyrolysis gas chrmatography: a new technique for modeling hydrocarbon generation, Org. Geochem., 22(3-5): 863-972.
32. Schenk, H. J., and Horsfield, B., 1993, Kinetics of petroleum generation by programmed-temperature closed-verus open system pyrolysis: Geochimica et Cosmochimica Acta, 57: 623-630.
33. Reynolds, J. C., Burnham, A. K. 1995, Comparison of kinetic analysis of source rocks and kerogen concentrates, Org. Geochem., 23(1): 11-19.
34. Tang, Y., Perry, J., Jenden, P. D., et al., 2000, Mathematical modeling of stable carbon isotope ratios in natural gases, Geochimica et Cosmochimica Acta, 64 (15): 2673-2687.
35.王建宝,肖贤明,郭汝泰,鹿洪友,高喜龙,2003,渤海湾盆地东营凹陷烃源岩生烃动力学研究,石油实验地质,25:4):403-409。
36.高喜龙,肖贤明,刘中云,王建宝,等,2003,用开放体系的热解方法对烃源岩生烃动力学的研究:以东营凹陷某生油岩为例,地球化学,32(5):484-490
37.陈永红,鹿洪友,曾庆辉,肖贤明,2004,应用生烃动力学方法研究渤海湾盆地埕岛油田成藏地质时期石油实验地质,26(6):580—585
38.胡忠良,肖贤明,黄保家,Tang Yongchun,2005,琼东南盆地崖13-1气田气源区圈定与成藏运聚模式,地球化学,34:1,66-67.
39.李贤庆,肖贤明,唐永春,米敬奎,申家贵,肖中尧,包建平,熊波,
2005,库车坳陷煤成甲烷碳同位素动力学研究,石油与天然气地质,25(1):21-25。
40.李贤庆,肖贤明,田辉,唐永春,方家虎,周强,2005,碳同位素动力学模拟及其在天然气评价中的应用,地学前缘,12(4):543-550。
41.李贤庆,肖贤明,米敬奎,唐永春,肖中尧,刘德汉,申家贵,刘金钟,2005,塔里木盆地库车坳陷烃源岩生成甲烷的动力学参数及其应用,地质学报,79(1):133-142。
42.覃建雄,1992.矿物包裹体在沉积学中的应用.矿物岩石,12(2):132-142
43.张新安,1990.包裹体研究的新进展.国外地质科技,1990,(2):132～135
44.卢焕章、李秉伦,等,1990.包裹体地球化学.北京:地质出版社,p6～16
45.刘斌、沈昆,1999.流体包裹体热力学.北京:地质出版社,1999.p25～42
46.刘德汉、肖贤明,1995.包裹体研究——盆地流体追踪的有利工具地学前缘,2(4):149～154
47.肖贤明著,1992,有机岩石学及其在油气评价中的应用,广东省科技出版社,广州,P12-64
48. Roeder, E., Bodnar, R. J, 1980. Geologic pressure determinations from fluid inclusion studies. Ann. Rev. Earth. Planet. Sci. 8: 263-301.
49. Burruss, R. C.. 1981, Hydrocarbon fluid inclusions in studies of sedimentary diagenesis, Applications to petrology. Min. Ass. Canada Short Course Handbook, 6: 138-156
50. Crawford M. L., 1981. Phase equilibria in aqueous flusion inclusions. In Short Course in Fluid inclusion: Applications to petrology (ed. L. S. Hollister and M. L. Crawford). Min. Ass. Canada Short Course Handbook, 6: 75-100
51. Mclimans. R. K., 1981, Application of fluid inclusions studies to reservoir diagenesis and petroleum migration: Smackover Formation, U. S. Gulf Coast, and Fatch field, Dubai.. AAPG, 65: 957
52. Kadke B. M and Mathis R. L. 1981, Origin of fluid inclusions and changes that occurs after trapping. Applications to Petrology: Short Course in Fluid Inclusions, Min. Ass Canada, 101-137.
53.Visser. 1982, Maximum diagentic temperature in a petroleum source-rock from Venezuela by fluid inclusion geothermometry. Chemical Geology, 37:95-101
54.Burruss R.C. et al., 1983, Fluid inclusion petrology and tectonicburial history of the Al Ali No. 2 well: evidence for the timing of diagenesis and oil migration. Northern Oman fore-deep. Geology, 11:567-570
55.Haszeldine, R.S., Samson, I.M. and Cornflord, C. 1984, Dating of diagenesis in a petroleum basin, a new fluid inclusion method. Nature, 307:354-359
56.Burruss R.C. and Harris P. M. 1985, Timing of hydrocarbon migration: evidence from fluid inclusions in calcite cements, tectonics, and bural history. SEPM Special Pub., 26:227-289
57.Tsui, T.F. and Jordan, C.F.. 1985, Fluid inclusions and porosity development in Arun Gas Field, Indonesia. AAPG, 69:312-313
58. Parnell, J., P.F.Carey, B.Monson. 1996, Fluid inclusion constraints on temperatures of petroleum migration from authigenic quartz in bitumen vein, Chemical Geology, 129:217-226.
59.Roger K. Mclimans. 1987, The application of fluid inclusions to migration of oil and diagenesis in petroleum reservoirs. Applied Geochemistry, 2:585-603
60.Aplin, A.C., GNacleod, S.R.Larter, et al. 1999, Combined use of Confocal Laser Microscopy and PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions. Marine and petroleum geology, 16:98-101
61 Aplin, A.C., S.R.Larter, M.A.Bigge, et al. 2000, PVTX history of the North sea's Judy oilfield[J]. Journal of Geochemical Exploration, 60-70:641-644.
62.Middleton, D., J.Parnell, P.Carey, G.Xu.. 2000, Reconstruction of fluid migration history in Northwest Ireland using fluid inclusion studies, Journal of Geochemical Exploration, 69-70:673-677.
63.施继锡,等,1987.有机包裹体在碳酸盐岩区油气评价中的意义.沉积学报,5(1):86～92
64.施继锡,等,1987.有机包裹体及其与油气的关系.中国科学B辑,17(3):318-325
65.施继锡,等,1993.琼东南盆崖13-1气田天然气来源和运移的有机包裹体地球化学研究.内部报告.
66.谢奕汉,等,1998.流体包裹体与盆地油气的生成和演化.地质科技隋报,17(增刊);100～104。
67.陈红汉,等,1997.琼东南盆地含烃流体活动得流体包裹体证据.中国科学,27(4):343～348.
68.米敬奎、肖贤明、刘德汉、申家贵,2002.利用PVTsim模拟计算油气藏形成古压力.地球化学,第3期,33-39.
69.王建宝、郭汝泰、肖贤明、刘祖发、申家贵,2002.塔里木轮南低隆起早古生代油气藏形成的期次与时间研究.沉积学报,20(2):320-325.
70.肖贤明,刘祖发,刘德汉等,应用储层流体包裹体住处研究天然气气藏的成藏时间,2002,科学通报,47(12):957-960.
71. D. H. Liu, X. M. Xiao, J. K. Mi, X. Q. Li, J. K. Shen, Z. G. Song, P. A. Peng, 2003, Determination of trapping pressure and temperature of petroleum inclusions using PVT simulation software—a case study of Lower Ordovician carbonates from the Lunnan Low Uplift, Tarim Basin, Marine and Petroleum Geology, 20: 29-43.
72.肖贤明,刘祖发,刘德汉,等,2002,应用储层流体包裹体住处研究天然气气藏的成藏时间,科学通报,47(12):957-960。
73.米敬奎,肖贤明,刘德汉,李贤庆,申家贵,2003,利用包裹体信息研究鄂尔多斯盆地上古生界深分气的运移规律,石油学报,24(5):46-49。
74.米敬奎,肖贤明,刘德汉,申家贵,2003,利用储层流体包裹体的PVT特征模拟计算天然气藏形成古压力,中国科学(D辑),33(7):679-685。
75.刘中云,曾庆辉,肖贤明,2004,应用流体包裹体研究埕岛油田东斜坡带油气藏成藏期次与时间,中国海上油气,16(4):238-241.
76.刘中云,王东风,肖贤明,2004,库车依南2井包裹体形成的古温度与古压力,新疆石油地质,25(4):369-377.
77. Xiao Xianming, Liu Dehan, Fu Jiamo,et al., 2001, Dating hydrocarbon generation and migration baed on bitumen reflectance, Chinese Science Bulletin, 46(7):611-616.
78.刘德汉,宫色,刘东鹰,曾庆辉,肖贤明,田辉,申家贵,2005,江苏句容—黄桥地区有机包裹体形成期次和捕获温度、压力的PVTsim模拟计算,岩石学报2(5):1435—1448.
79. GeolsoChem Corporation, 2003. GOR-Isotope. Version 1.48.
80. Xiao, X M., Q. H. Zeng, H. Tian, R. W. T. Wilkins, Y. C. Tang, 2005, Origin and accumulation model of the AK1 natural gas pool from the Tarim Basin, China, Organic Geochemistry, 36: 1285-1298.
81.黄保家,1999.琼东南盆地天然气潜力及有利勘探方向.天然气工业.19(1)
82.黄保家、肖贤明,等,2002,莺歌海盆地烃源岩特征及成烃演化模式.天然气工业.22:26-32.
83.赵必强,肖贤明,胡忠良,等2005,莺歌海盆地东方1-1气田天然气来源与运聚模式,沉积学报,23(1):156—162
84. Mi, J. Q., Xiao, X. M., Liu, D. H., Determination of paleo-pressure for a natural gas pool formation based on PVT characteristics of fluid inclusions in reservoir rocks, Science in China(ser. D), 2004, 47(6): 507-513.
85.胡忠良,黄保家,肖贤明,2005.崖21-1构造储层包裹体古压力的求取及其与成藏关系研究.天然气工业.25(6):20—27.
86. Zhang Q. M.. 2002. Deep Overpressure gas accumulation. Chinese Science Bulletin, ,47 Supp.: 78-84.
87.张启明、董伟良,2000.中国含油气盆地中的超压体系.石油学报,21(6):1-11.
2.龚再升、李思田,等,1997.南海北部大陆边缘盆地分析与油气聚集.北京:科学出版社
3.董伟良,黄保家,1999.莺歌海东方1-1气田天然气组成的非均质性和幕式充注研究。石油勘探与开发,26(2).
4.黄保家,1999.琼东南盆地天然气潜力及有利勘探方向.天然气工业.19(1):24-28.
5.张敏强、黄保家、吕明,2000.琼东南盆地生烃凹陷的比较性评价.“9.5”国家天然气攻关成果
6.董伟良,黄保家,2000.莺歌海盆地流体压裂与热流体活动及天然气的幕式运移.石油勘探与开发,27(4):36-40
7.中国石油地质志(卷16下),1990,石油工业出版社,北京,1—508。
8.林壬子,将基平,梅博文,1985.琼东南盆地油气来源的初步研究.南海西部石油公司内部报告
9.汪集呖,罗晓容,等,1996.莺歌海盆地地温场特征与天然气成藏关系研究.“9.5”国家天然气攻关成果.
10.杨计海,陈红汉1998.莺-琼盆地的压力系统及油气运移.“9.5”国家天然气攻关成果.
11.张国华、黄保家、潘贤庄,1998.莺歌海-琼东南盆地天然气的成因联系及海相烃源岩研究.“9.5”国家天然气攻关成果.
12.傅家谟,陈军红,盛国英,耿安松,刘德汉等,1995.莺歌海.琼东南盆地第三系烃源岩研究.南海西部石油公司内部报告.
13.陈红汉等,1997.琼东南盆地含烃流体活动得流体包裹体证据.中国科学,27(4):343～348。
14.张国华、黄保家、潘贤庄,1998.莺歌海-琼东南盆地天然气的成因联系及海相烃源岩研究.“9.5”国家天然气攻关成果,1-11.
15.马启富、陈斯忠、张启明、郭水生、王善书,2000.超压盆地与油气分布.北京:地质出版社.
16.董伟良,黄保家,2001.莺-琼盆地煤型气的鉴别标志和气源判识.天然气工业.20(1):23-27
17.肖贤明,李绪深,黄保家,等,2002,莺琼盆地第三系烃源岩生烃动力学研究,中海油“十五”攻关中期研究成果.
18.施继锡,等,1993.琼东南盆崖13-1气田天然气来源和运移的有机包裹体地球化学研究.内部报告.
19. Huang, B, J. and Xiao, X. M., 2002, Multiphase natural gas migration and accumulation and ist relation to diapir structure in the DF1-1 gas field, South China Sea. Marine and Petroleum Geology. 19(7): 861-872.
20. Baojia Huang, Xiaoming Xiao, Xuxuan Li, 2003, Geochemistry and origins of natural gases in the Yinggehai and Qiongdongnan basins, offshore South China Sea. Organic Geochemistry, 34: 1009-1025.
21. Baojia Huang, Xiaoming Xiao, Mingqiang Zhang, 2003, Geoch emistry, grouping and origins of crude oils in the Western Pearl River Mouth Basin, offshore South China Sea. Organic Geochemistry, 34: 993-1008.
22. Huang, B. J., Xiao, X. M., Hu, Z. L., and Yi, P., 2005, Geochemistry and episodic accumulation of natural gases from the Ledong gas field in the Yinggehain Basin, Organic Geochemistry, 36: 1689-1702.
23. Huang, B. J., Xiao, X. M., Zhu, W. L., 2004, Geochemistry, origin, and accumulation of CO2 in natural gases of thr Yinggehai basin, offshore South China Sea. AAPG 88(9), 1277-1293.
24. Hermanrud, C. 1993. Basin modelling techniques--an overview. In A. G. Dore" (Ed.), Basin modelling: Advances and applications (pp. 1-34).Stavanger: Norwegian Petroleum Society.
25. Skjeveruy, A., & Sylta, e. 1993. Modelling of expulsion and secondary migration along the south-west margin of the Horda Platform. In A. G. DoreA et al., Basin modelling: Advances and applications (pp. 499-537). In NPF Special Publication, Vol. 3. Elsevier.
26. Pepper, A. S., & Corvi, P. J. 1995. Simple kinetic models of petroleum formation. Part Ⅰ: Oil and gas generation from kerogen. Marine and Pet. Geol., 12, 291-319.
27. Pepper, A. S., & Corvi, P. J. 1995. Simple kinetic models of petroleurn formation. Part Ⅲ: modelling an open system. Marine and Pet. Geol., 12, 417-452.
28. Ungger, P. And Pelet, R., 1987, Exptrapolation of the kinetics of oil and gas formation from laboratory experiments to sedimentary basins, Nature, 327: 52-54.
29. Ungerer, P., 1990, State of the art of research in kinetics modeling of oil formation and expulsion, Org. Geochem., 16(1-3): 1-25.
30. Braum, R., 1992, Oil and gas evolution kinetics for oil shale and petroleum source rock determined from pyrolysis-TQMS data at two heating rates, Energy and Fuel, (6): 468-474.
31. Tang, Y., Stauffer, M, 1993, Multiple cold trap pyrolysis gas chrmatography: a new technique for modeling hydrocarbon generation, Org. Geochem., 22(3-5): 863-972.
32. Schenk, H. J., and Horsfield, B., 1993, Kinetics of petroleum generation by programmed-temperature closed-verus open system pyrolysis: Geochimica et Cosmochimica Acta, 57: 623-630.
33. Reynolds, J. C., Burnham, A. K. 1995, Comparison of kinetic analysis of source rocks and kerogen concentrates, Org. Geochem., 23(1): 11-19.
34. Tang, Y., Perry, J., Jenden, P. D., et al., 2000, Mathematical modeling of stable carbon isotope ratios in natural gases, Geochimica et Cosmochimica Acta, 64 (15): 2673-2687.
35.王建宝,肖贤明,郭汝泰,鹿洪友,高喜龙,2003,渤海湾盆地东营凹陷烃源岩生烃动力学研究,石油实验地质,25:4):403-409。
36.高喜龙,肖贤明,刘中云,王建宝,等,2003,用开放体系的热解方法对烃源岩生烃动力学的研究:以东营凹陷某生油岩为例,地球化学,32(5):484-490
37.陈永红,鹿洪友,曾庆辉,肖贤明,2004,应用生烃动力学方法研究渤海湾盆地埕岛油田成藏地质时期石油实验地质,26(6):580—585
38.胡忠良,肖贤明,黄保家,Tang Yongchun,2005,琼东南盆地崖13-1气田气源区圈定与成藏运聚模式,地球化学,34:1,66-67.
39.李贤庆,肖贤明,唐永春,米敬奎,申家贵,肖中尧,包建平,熊波,
2005,库车坳陷煤成甲烷碳同位素动力学研究,石油与天然气地质,25(1):21-25。
40.李贤庆,肖贤明,田辉,唐永春,方家虎,周强,2005,碳同位素动力学模拟及其在天然气评价中的应用,地学前缘,12(4):543-550。
41.李贤庆,肖贤明,米敬奎,唐永春,肖中尧,刘德汉,申家贵,刘金钟,2005,塔里木盆地库车坳陷烃源岩生成甲烷的动力学参数及其应用,地质学报,79(1):133-142。
42.覃建雄,1992.矿物包裹体在沉积学中的应用.矿物岩石,12(2):132-142
43.张新安,1990.包裹体研究的新进展.国外地质科技,1990,(2):132～135
44.卢焕章、李秉伦,等,1990.包裹体地球化学.北京:地质出版社,p6～16
45.刘斌、沈昆,1999.流体包裹体热力学.北京:地质出版社,1999.p25～42
46.刘德汉、肖贤明,1995.包裹体研究——盆地流体追踪的有利工具地学前缘,2(4):149～154
47.肖贤明著,1992,有机岩石学及其在油气评价中的应用,广东省科技出版社,广州,P12-64
48. Roeder, E., Bodnar, R. J, 1980. Geologic pressure determinations from fluid inclusion studies. Ann. Rev. Earth. Planet. Sci. 8: 263-301.
49. Burruss, R. C.. 1981, Hydrocarbon fluid inclusions in studies of sedimentary diagenesis, Applications to petrology. Min. Ass. Canada Short Course Handbook, 6: 138-156
50. Crawford M. L., 1981. Phase equilibria in aqueous flusion inclusions. In Short Course in Fluid inclusion: Applications to petrology (ed. L. S. Hollister and M. L. Crawford). Min. Ass. Canada Short Course Handbook, 6: 75-100
51. Mclimans. R. K., 1981, Application of fluid inclusions studies to reservoir diagenesis and petroleum migration: Smackover Formation, U. S. Gulf Coast, and Fatch field, Dubai.. AAPG, 65: 957
52. Kadke B. M and Mathis R. L. 1981, Origin of fluid inclusions and changes that occurs after trapping. Applications to Petrology: Short Course in Fluid Inclusions, Min. Ass Canada, 101-137.
53.Visser. 1982, Maximum diagentic temperature in a petroleum source-rock from Venezuela by fluid inclusion geothermometry. Chemical Geology, 37:95-101
54.Burruss R.C. et al., 1983, Fluid inclusion petrology and tectonicburial history of the Al Ali No. 2 well: evidence for the timing of diagenesis and oil migration. Northern Oman fore-deep. Geology, 11:567-570
55.Haszeldine, R.S., Samson, I.M. and Cornflord, C. 1984, Dating of diagenesis in a petroleum basin, a new fluid inclusion method. Nature, 307:354-359
56.Burruss R.C. and Harris P. M. 1985, Timing of hydrocarbon migration: evidence from fluid inclusions in calcite cements, tectonics, and bural history. SEPM Special Pub., 26:227-289
57.Tsui, T.F. and Jordan, C.F.. 1985, Fluid inclusions and porosity development in Arun Gas Field, Indonesia. AAPG, 69:312-313
58. Parnell, J., P.F.Carey, B.Monson. 1996, Fluid inclusion constraints on temperatures of petroleum migration from authigenic quartz in bitumen vein, Chemical Geology, 129:217-226.
59.Roger K. Mclimans. 1987, The application of fluid inclusions to migration of oil and diagenesis in petroleum reservoirs. Applied Geochemistry, 2:585-603
60.Aplin, A.C., GNacleod, S.R.Larter, et al. 1999, Combined use of Confocal Laser Microscopy and PVT simulation for estimating the composition and physical properties of petroleum in fluid inclusions. Marine and petroleum geology, 16:98-101
61 Aplin, A.C., S.R.Larter, M.A.Bigge, et al. 2000, PVTX history of the North sea's Judy oilfield[J]. Journal of Geochemical Exploration, 60-70:641-644.
62.Middleton, D., J.Parnell, P.Carey, G.Xu.. 2000, Reconstruction of fluid migration history in Northwest Ireland using fluid inclusion studies, Journal of Geochemical Exploration, 69-70:673-677.
63.施继锡,等,1987.有机包裹体在碳酸盐岩区油气评价中的意义.沉积学报,5(1):86～92
64.施继锡,等,1987.有机包裹体及其与油气的关系.中国科学B辑,17(3):318-325
65.施继锡,等,1993.琼东南盆崖13-1气田天然气来源和运移的有机包裹体地球化学研究.内部报告.
66.谢奕汉,等,1998.流体包裹体与盆地油气的生成和演化.地质科技隋报,17(增刊);100～104。
67.陈红汉,等,1997.琼东南盆地含烃流体活动得流体包裹体证据.中国科学,27(4):343～348.
68.米敬奎、肖贤明、刘德汉、申家贵,2002.利用PVTsim模拟计算油气藏形成古压力.地球化学,第3期,33-39.
69.王建宝、郭汝泰、肖贤明、刘祖发、申家贵,2002.塔里木轮南低隆起早古生代油气藏形成的期次与时间研究.沉积学报,20(2):320-325.
70.肖贤明,刘祖发,刘德汉等,应用储层流体包裹体住处研究天然气气藏的成藏时间,2002,科学通报,47(12):957-960.
71. D. H. Liu, X. M. Xiao, J. K. Mi, X. Q. Li, J. K. Shen, Z. G. Song, P. A. Peng, 2003, Determination of trapping pressure and temperature of petroleum inclusions using PVT simulation software—a case study of Lower Ordovician carbonates from the Lunnan Low Uplift, Tarim Basin, Marine and Petroleum Geology, 20: 29-43.
72.肖贤明,刘祖发,刘德汉,等,2002,应用储层流体包裹体住处研究天然气气藏的成藏时间,科学通报,47(12):957-960。
73.米敬奎,肖贤明,刘德汉,李贤庆,申家贵,2003,利用包裹体信息研究鄂尔多斯盆地上古生界深分气的运移规律,石油学报,24(5):46-49。
74.米敬奎,肖贤明,刘德汉,申家贵,2003,利用储层流体包裹体的PVT特征模拟计算天然气藏形成古压力,中国科学(D辑),33(7):679-685。
75.刘中云,曾庆辉,肖贤明,2004,应用流体包裹体研究埕岛油田东斜坡带油气藏成藏期次与时间,中国海上油气,16(4):238-241.
76.刘中云,王东风,肖贤明,2004,库车依南2井包裹体形成的古温度与古压力,新疆石油地质,25(4):369-377.
77. Xiao Xianming, Liu Dehan, Fu Jiamo,et al., 2001, Dating hydrocarbon generation and migration baed on bitumen reflectance, Chinese Science Bulletin, 46(7):611-616.
78.刘德汉,宫色,刘东鹰,曾庆辉,肖贤明,田辉,申家贵,2005,江苏句容—黄桥地区有机包裹体形成期次和捕获温度、压力的PVTsim模拟计算,岩石学报2(5):1435—1448.
79. GeolsoChem Corporation, 2003. GOR-Isotope. Version 1.48.
80. Xiao, X M., Q. H. Zeng, H. Tian, R. W. T. Wilkins, Y. C. Tang, 2005, Origin and accumulation model of the AK1 natural gas pool from the Tarim Basin, China, Organic Geochemistry, 36: 1285-1298.
81.黄保家,1999.琼东南盆地天然气潜力及有利勘探方向.天然气工业.19(1)
82.黄保家、肖贤明,等,2002,莺歌海盆地烃源岩特征及成烃演化模式.天然气工业.22:26-32.
83.赵必强,肖贤明,胡忠良,等2005,莺歌海盆地东方1-1气田天然气来源与运聚模式,沉积学报,23(1):156—162
84. Mi, J. Q., Xiao, X. M., Liu, D. H., Determination of paleo-pressure for a natural gas pool formation based on PVT characteristics of fluid inclusions in reservoir rocks, Science in China(ser. D), 2004, 47(6): 507-513.
85.胡忠良,黄保家,肖贤明,2005.崖21-1构造储层包裹体古压力的求取及其与成藏关系研究.天然气工业.25(6):20—27.
86. Zhang Q. M.. 2002. Deep Overpressure gas accumulation. Chinese Science Bulletin, ,47 Supp.: 78-84.
87.张启明、董伟良,2000.中国含油气盆地中的超压体系.石油学报,21(6):1-11.