可交联LDPE高压电力电缆绝缘料的研制
摘要
为了改变国内高压电力电缆绝缘料尚需大量进口和国内研制的高压电力电缆绝缘料存在加工设备繁杂、能耗大和工艺流程长等不足的现状，本论文采用国产通用树脂，加入交联剂、抗氧剂、加工助剂等，通过物理预混和熔融共混的方法，用国产设备特定的组合和特定的生产工艺，成功开发了可交联LDPE高压电力电缆绝缘料。试制的这种绝缘料具有市场上绝缘料要求的质量指标和加工性能，可以替代同等级的进口产品，为国家节省外汇，为电缆厂降低生产成本，提高我国高压电力电缆的生产水平。
There are some disadvantages in the processing of the materials for the insulation of high voltage power cable in China such as the process equipments are complicate, which need more energy and the process flow is long and so on, we need to intake that vast scale from foreign enterprises yet. In order to change the present status, this paper has successfully developed the materials with new process equipments and new process flow, which are made with compounds containing universal resins of china and assistants such as peroxide, antioxidant and so on. The compounds are extruded through special equipments and process How at a temperature below the decomposition temperature of the peroxide after mixed in special equipments. The studied insulation materials have satisfied the national standards and have good process properties, which can replace the same level products of foreign and which can spare national foreign exchange and reduce cost for cable works.
There are some disadvantages in the processing of the materials for the insulation of high voltage power cable in China such as the process equipments are complicate, which need more energy and the process flow is long and so on, we need to intake that vast scale from foreign enterprises yet. In order to change the present status, this paper has successfully developed the materials with new process equipments and new process flow, which are made with compounds containing universal resins of china and assistants such as peroxide, antioxidant and so on. The compounds are extruded through special equipments and process How at a temperature below the decomposition temperature of the peroxide after mixed in special equipments. The studied insulation materials have satisfied the national standards and have good process properties, which can replace the same level products of foreign and which can spare national foreign exchange and reduce cost for cable works.
引文
1．日洪编，交联聚乙烯电力电缆线路，中国电力出版社，1997年
2．董翠霞等，浅论交联电力电缆，本钢技术，1998，(8)
3．超高压干式电缆的发展和应用，国际电力，1999，(2)
4．郭述禹等，LDPE电力电缆料的发展趋势，合成树脂及塑料，2001，18(4)：60
5．陈中强，国外电缆材料的研究及发展的趋势，电线电缆，2001(3)
6．朱宝宗，高压交联聚乙烯电力电缆及生产，电线电缆，1998，(3)
7．张丽等，XLPE和OF电缆国内外发展近况及选型之我见，华东电力，2001，(3)
8．应启良等，我国高压及超高压交联聚乙烯绝缘电力电缆的应用与发展，电线电缆，2001，6(3)
9. Ying, Qiliang;Wei, Dong;Gao, Xiaoqing etc, Proceedings of the IEEE International Conference on Properties and Applications of Dielectric Materials 1 Jun 21-Jun 26 2000, 2000
10．陈光高等，220KV交联聚乙烯绝缘电力电缆的研制，电线电缆，1997，(6)：13～16
11．刘书全，220KV XLPE绝缘电力电缆的设计及研制，电线电缆，2000，(5)
12．王文英，聚乙烯树脂专用料的需求量和构成及新产品开发，现代化工，2000，20(1)：43～46
13．辅才，我国电缆料行业的现状及发展，电工技术杂志，2001，(5)：57～59
14．赵芳灿，超高压交联聚乙烯绝缘电力电缆的技术进步，电线电缆译丛，1998(1)
15. Yutao Zhu, Ho Gyu Yoon and Kwang S. Suh, Electrical Properties of Silane Crosslinked Polyethylene in Comparison with DCP Crosslinked Polyethylene, IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 6 No. 2, April1999
16. K. R. Bambery and R.J. Fleming, Space Charge Accumulation in Two power Cable Grades of XLPE, IEEE Transactions on Dielectrics and Electrical Insulation, Vol.5 No. 1, February 1998
17．党智敏等，EAA改性XLPE中空间电荷和电树、水树的关系，中国电机工程学报，2001，21(7)。
18．刘平原，交联聚乙烯绝缘老化的试验与建模研究，绝缘材料，2002(1)
19．袁检、罗俊华等，XLPE电力电缆介质引发水树机理的研究，高电压技术．2002，28(2)．-8-9，12
20. Ranby B, Ranbek J F. ESR Spectroscopy in Polymer Research, Springer Verlag, Berlin, 1977
21. Suwanda D, Balke S T. Polymer Engineering and Science, 1993,33:1585
22．胡发亭等，聚乙烯交联改性研究进展，现代塑料加工应用，2002，14(2)
23. Smedberg, Annika; Gustafsson, Bill;Hj0ertberg, Thomas, New insights in the peroxide crosslinking mechanism of polyethylene, Proceedings of the IEEE International Conference on Properties and Applications of Dielectric Materials 1 Jun 21-Jun 26 2000
24. Anon, Invention of chemically crosslinked polyethylene, IEEE Electrical Insulation Magazine v 15 n 1 Jan-Feb 1999 IEEE 3p 0883-7554
25. Dole M. Chem.& Eng. News, 1948,26:2289
26. Becket R C. Electron Beam Processing of Rubber and Plastics. Dynamitron. 1980.
27．王硕等，交联聚乙烯的生产技术及应用，弹性体，1999，9(4)
28. Scott H G. Brit. Patent, 1 286 460(1968).
29．王正洲等，聚乙烯的交联技术研究进展，高分子材料科学与工程，2001，17(1)
30．黄棋尤，国内外聚乙烯电缆料的研究与开发，塑料世界，1996，16(3)
1．王文广编，塑料改性使用技术，中国轻工业出版社，2000．1
2. Annika Smedberg, Bill Gustafsson and Thomas Hjertberg, New Insights in the Peroxide Crosslinking Mechanism of Polyethylene, Proceedings of the 6th International Conference on Properties and Applications of Dielectric Materials, June21-26,2000, Xi' an JiaotongUniversity.
3. K.R. Bambery and R.J. Fleming, Space Charge Accumulation in Two Power Cable Grades of XLPE, IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 5 Nol, February 1998
4．陈铭，干式交联的工艺参数，电线电缆译丛，1996(4)。
5．刘春林等，过氧化物交联聚乙烯的研究，现代塑料加工应用，1998，10(2)；
6．郑吉平，35KV及以下交联聚乙烯电缆用绝缘料的研制，应用技术研究，2000(8)
7．龙永会等，交联结构对聚乙烯结晶形态及电性能的影响，电线电缆，1993，(5)
8．龙永会等，酚酞对交联聚乙烯的改性作用，绝缘材料通讯，1993，(6)
9．成都科技大学高分子物理编写组，高分子物理。
10. S.N. Kolosov, IEEE Trans. Electr. Insul.,1980, EI-15(5):382;S. Bamti et al, IEEE Trans. Electr. Insul.,1983, EI-18(1):32;R.M. Eichhoro. IEEE Trans. Electr. Insul.,1977, EI-12(1):2
11. H. Wagner. 1974 Annual Report Conference on Elecgr. Insul. And Dielec. Phenomena, 1975
1. D. Suwanda and S.T. Balke, Polym. Eng. Sci.,1993,33:1585
2. Bolland, J.L.;Gee, G.:Trans. Faraday Soc. 42(1946):236
3. Bolland, J.L.: Trans. Faraday Soc. 42(1948):669
4．周大纲，谢鸽成著，塑料老化和防老化技术，中国轻工业出版社，1998：15
5. Bremner, Rudin J.,Appli. Polym. Sci. 57(1995):271-286
6. Kamiya, Y.;Niki, E. in Aspects of Degradation and Stabilization of polymers, Jellinek, H.G.(Ed.).Eisevier, Smsterdam 1978:78
7. Stivala, S.;Kamiya, J., Degradation and Stabilization of
Polyolefins. Allen, N.S. (Ed.)Applied science Publishers, London 1983:63
8．方开泰著，均匀设计与均匀设计表，科学出版社，1994
1．金标义，电线电缆用塑料与橡胶加工的新进展，电线电缆，2002(3)
2．96232604. 6
3．98111989. 1
4．吴廷禄等，35KV含氟交流聚乙烯绝缘料，绝缘材料，2002(4)
5. Blong, T.T.,Klein, D.F.,Pocius, A.V.,Storbet M.A. The influence of polymer processing additives on the surface, mechanical and potical properties of LLDPE blown film. TAPPI Polymer Laminations and Coatiings Conference Proceedings, 1993.
6. K. Fromek, B. Johnson, T. Blong, J. Kunde, D. Duchesne. Tailoring processing additives for high density polyethylene applieation. SPE ANTEC 1990 Conference Proceedings, 1990:1172.
2．董翠霞等，浅论交联电力电缆，本钢技术，1998，(8)
3．超高压干式电缆的发展和应用，国际电力，1999，(2)
4．郭述禹等，LDPE电力电缆料的发展趋势，合成树脂及塑料，2001，18(4)：60
5．陈中强，国外电缆材料的研究及发展的趋势，电线电缆，2001(3)
6．朱宝宗，高压交联聚乙烯电力电缆及生产，电线电缆，1998，(3)
7．张丽等，XLPE和OF电缆国内外发展近况及选型之我见，华东电力，2001，(3)
8．应启良等，我国高压及超高压交联聚乙烯绝缘电力电缆的应用与发展，电线电缆，2001，6(3)
9. Ying, Qiliang;Wei, Dong;Gao, Xiaoqing etc, Proceedings of the IEEE International Conference on Properties and Applications of Dielectric Materials 1 Jun 21-Jun 26 2000, 2000
10．陈光高等，220KV交联聚乙烯绝缘电力电缆的研制，电线电缆，1997，(6)：13～16
11．刘书全，220KV XLPE绝缘电力电缆的设计及研制，电线电缆，2000，(5)
12．王文英，聚乙烯树脂专用料的需求量和构成及新产品开发，现代化工，2000，20(1)：43～46
13．辅才，我国电缆料行业的现状及发展，电工技术杂志，2001，(5)：57～59
14．赵芳灿，超高压交联聚乙烯绝缘电力电缆的技术进步，电线电缆译丛，1998(1)
15. Yutao Zhu, Ho Gyu Yoon and Kwang S. Suh, Electrical Properties of Silane Crosslinked Polyethylene in Comparison with DCP Crosslinked Polyethylene, IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 6 No. 2, April1999
16. K. R. Bambery and R.J. Fleming, Space Charge Accumulation in Two power Cable Grades of XLPE, IEEE Transactions on Dielectrics and Electrical Insulation, Vol.5 No. 1, February 1998
17．党智敏等，EAA改性XLPE中空间电荷和电树、水树的关系，中国电机工程学报，2001，21(7)。
18．刘平原，交联聚乙烯绝缘老化的试验与建模研究，绝缘材料，2002(1)
19．袁检、罗俊华等，XLPE电力电缆介质引发水树机理的研究，高电压技术．2002，28(2)．-8-9，12
20. Ranby B, Ranbek J F. ESR Spectroscopy in Polymer Research, Springer Verlag, Berlin, 1977
21. Suwanda D, Balke S T. Polymer Engineering and Science, 1993,33:1585
22．胡发亭等，聚乙烯交联改性研究进展，现代塑料加工应用，2002，14(2)
23. Smedberg, Annika; Gustafsson, Bill;Hj0ertberg, Thomas, New insights in the peroxide crosslinking mechanism of polyethylene, Proceedings of the IEEE International Conference on Properties and Applications of Dielectric Materials 1 Jun 21-Jun 26 2000
24. Anon, Invention of chemically crosslinked polyethylene, IEEE Electrical Insulation Magazine v 15 n 1 Jan-Feb 1999 IEEE 3p 0883-7554
25. Dole M. Chem.& Eng. News, 1948,26:2289
26. Becket R C. Electron Beam Processing of Rubber and Plastics. Dynamitron. 1980.
27．王硕等，交联聚乙烯的生产技术及应用，弹性体，1999，9(4)
28. Scott H G. Brit. Patent, 1 286 460(1968).
29．王正洲等，聚乙烯的交联技术研究进展，高分子材料科学与工程，2001，17(1)
30．黄棋尤，国内外聚乙烯电缆料的研究与开发，塑料世界，1996，16(3)
1．王文广编，塑料改性使用技术，中国轻工业出版社，2000．1
2. Annika Smedberg, Bill Gustafsson and Thomas Hjertberg, New Insights in the Peroxide Crosslinking Mechanism of Polyethylene, Proceedings of the 6th International Conference on Properties and Applications of Dielectric Materials, June21-26,2000, Xi' an JiaotongUniversity.
3. K.R. Bambery and R.J. Fleming, Space Charge Accumulation in Two Power Cable Grades of XLPE, IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 5 Nol, February 1998
4．陈铭，干式交联的工艺参数，电线电缆译丛，1996(4)。
5．刘春林等，过氧化物交联聚乙烯的研究，现代塑料加工应用，1998，10(2)；
6．郑吉平，35KV及以下交联聚乙烯电缆用绝缘料的研制，应用技术研究，2000(8)
7．龙永会等，交联结构对聚乙烯结晶形态及电性能的影响，电线电缆，1993，(5)
8．龙永会等，酚酞对交联聚乙烯的改性作用，绝缘材料通讯，1993，(6)
9．成都科技大学高分子物理编写组，高分子物理。
10. S.N. Kolosov, IEEE Trans. Electr. Insul.,1980, EI-15(5):382;S. Bamti et al, IEEE Trans. Electr. Insul.,1983, EI-18(1):32;R.M. Eichhoro. IEEE Trans. Electr. Insul.,1977, EI-12(1):2
11. H. Wagner. 1974 Annual Report Conference on Elecgr. Insul. And Dielec. Phenomena, 1975
1. D. Suwanda and S.T. Balke, Polym. Eng. Sci.,1993,33:1585
2. Bolland, J.L.;Gee, G.:Trans. Faraday Soc. 42(1946):236
3. Bolland, J.L.: Trans. Faraday Soc. 42(1948):669
4．周大纲，谢鸽成著，塑料老化和防老化技术，中国轻工业出版社，1998：15
5. Bremner, Rudin J.,Appli. Polym. Sci. 57(1995):271-286
6. Kamiya, Y.;Niki, E. in Aspects of Degradation and Stabilization of polymers, Jellinek, H.G.(Ed.).Eisevier, Smsterdam 1978:78
7. Stivala, S.;Kamiya, J., Degradation and Stabilization of
Polyolefins. Allen, N.S. (Ed.)Applied science Publishers, London 1983:63
8．方开泰著，均匀设计与均匀设计表，科学出版社，1994
1．金标义，电线电缆用塑料与橡胶加工的新进展，电线电缆，2002(3)
2．96232604. 6
3．98111989. 1
4．吴廷禄等，35KV含氟交流聚乙烯绝缘料，绝缘材料，2002(4)
5. Blong, T.T.,Klein, D.F.,Pocius, A.V.,Storbet M.A. The influence of polymer processing additives on the surface, mechanical and potical properties of LLDPE blown film. TAPPI Polymer Laminations and Coatiings Conference Proceedings, 1993.
6. K. Fromek, B. Johnson, T. Blong, J. Kunde, D. Duchesne. Tailoring processing additives for high density polyethylene applieation. SPE ANTEC 1990 Conference Proceedings, 1990:1172.