海南儋州南江铅锌矿地质地球化学特征及成因探讨
|
摘要
南江铅锌矿处于华南褶皱系南部的五指山褶皱带内,归属于广东-海南成矿带的海南成矿区,位于王五-文教深大断裂以南的儋县-白沙断裂带上。
本文通过系统收集研究区的研究资料和有关文献、专著和研究报告,在充分熟悉和全面把握矿区地质特征的基础上,通过野外地质调研,运用矿床学、矿物岩石学、成矿构造学、地球化学(常量元素、微量元素、稀土元素)等理论知识,论述了矿区的地质地球化学特征,并探讨了矿床的成因。
研究发现南江村铅锌矿脉呈近东西向走向,呈“透镜状”、“脉状”分布于志留系下统空列村组中的结晶灰岩中。矿石金属矿物主要为闪锌矿和方铅矿,矿石结构以粒状镶嵌结构、浸染状结构、交代残余结构为主,矿石构造为块状或条带状构造。
通过室内硅酸盐分析、微量元素测试、稀土元素测试等,研究了矿区花岗岩、围岩、矿石的地球化学特征。认为矿体附近的粗粒黑云母花岗岩与成矿关系密切。花岗岩为壳源钙碱性强过铝质花岗岩系列,为铅锌矿提供了主要的物质来源。花岗岩为形成于后碰撞期的张性造山岩类。
在上述工作基础上对矿床成因进行了探讨,认为本区矿床的形成经历了早期沉积富集作用和晚期岩浆热液叠加改造成矿作用两个阶段,矿床成因属产于碳酸盐岩地层中的以岩浆热液成矿作用为主形成的多因复成铅锌矿床。本区灰岩在沉积、变质的过程中形成“矿胚”,为铅锌矿富集提供了有利的赋矿岩性,随后岩浆活动使成矿流体增温、流动与反复环流,使得灰岩的成矿元素被溶解出来,促使第一成矿阶段形成的“胚胎矿”溶解、活化、搬运,由于灰岩的裂隙中压力低,铅锌矿在灰岩的裂隙中沉淀富集。随着构造运动的多次复活,热液作用的不断加强,外来的成矿物质叠加在先成矿体之上,并使之进一步富化,最终形成本区铅锌矿体。
The Nanjiang lead-zinc deposit is located in WuZhishan fold belt of Southern China foldzone, belong to Hainan mining area of Guangdong-Hainan metallogenic belt and lies in Danzhou-Baisha fault zone which is in south of Wangwu-Wenjiao deep fault.
According to collecting systematically research datas and relevant literatures, monographs and research reports of study area, based on knowing well and grasping the basis of mining geological features, using the latest research results of metallogeny and through of comprehensive research of field geological investigation, mineral deposit geology and mineral petrology, ore-forming tectonics and geochemical (major elements, trace elements and rare earth elements), discusses the geochemical characteristics of mining area and probes into the causes of the ore deposit.
The Nanjiang lead-zinc veins distributed in crystallization limestone of the Kongliecun group of lower silurian system with "lens shape"and "pulse shape". Sphalerite and Galena are the main metal mineral of ore. The prior structures of mineral are granular mosaic and dyeing shape structure. The main ore tectonics are massive and strap.
By silicate analysis, trace elements and rare earth elements test etc, the paper studys the granites, surrounding rocks and ore geochemical characteristics in the mining area, thinks Coarse-grained biotite granites near the ore bodies are closely related to mineralization. The granites belong to strongly peraluminous granitoid series. Granites are formed in the post-collisional stage of the tensile built rock type.
The writer considers that the Nanjiang lead-zinc deposit formed through the early depositional enrichment and late stage superimposed magmatic hydrothermal mineralization in two phases, is produced in the genesis of the carbonate rocks and magmatic hydrothermal mineralization formed mainly due to complex into a multi-lead-zinc deposits. The limestone of the ore area formed ore embryo through the time the deposition and metamorphism which provides a good metallogenic setting for enrichment of lead-zinc deposit. Frequent activities of the magma forming fluid temperature, flow and repeated circulation, making the metallogenic elements to be dissolved out of limestone, prompting "embryo mine" dissolved, activation and transported of the first mineralization stage. Due to the low pressure of a crack in the limestone, lead and zinc precipita and enrich in the crack of the limestone. With the many resurrection of tectonic, hydrothermal role has been strengthened, outside metallogenic material superimposed on top of earlier one and make the ore further enriched, ultimately form lead-zinc body.
本文通过系统收集研究区的研究资料和有关文献、专著和研究报告,在充分熟悉和全面把握矿区地质特征的基础上,通过野外地质调研,运用矿床学、矿物岩石学、成矿构造学、地球化学(常量元素、微量元素、稀土元素)等理论知识,论述了矿区的地质地球化学特征,并探讨了矿床的成因。
研究发现南江村铅锌矿脉呈近东西向走向,呈“透镜状”、“脉状”分布于志留系下统空列村组中的结晶灰岩中。矿石金属矿物主要为闪锌矿和方铅矿,矿石结构以粒状镶嵌结构、浸染状结构、交代残余结构为主,矿石构造为块状或条带状构造。
通过室内硅酸盐分析、微量元素测试、稀土元素测试等,研究了矿区花岗岩、围岩、矿石的地球化学特征。认为矿体附近的粗粒黑云母花岗岩与成矿关系密切。花岗岩为壳源钙碱性强过铝质花岗岩系列,为铅锌矿提供了主要的物质来源。花岗岩为形成于后碰撞期的张性造山岩类。
在上述工作基础上对矿床成因进行了探讨,认为本区矿床的形成经历了早期沉积富集作用和晚期岩浆热液叠加改造成矿作用两个阶段,矿床成因属产于碳酸盐岩地层中的以岩浆热液成矿作用为主形成的多因复成铅锌矿床。本区灰岩在沉积、变质的过程中形成“矿胚”,为铅锌矿富集提供了有利的赋矿岩性,随后岩浆活动使成矿流体增温、流动与反复环流,使得灰岩的成矿元素被溶解出来,促使第一成矿阶段形成的“胚胎矿”溶解、活化、搬运,由于灰岩的裂隙中压力低,铅锌矿在灰岩的裂隙中沉淀富集。随着构造运动的多次复活,热液作用的不断加强,外来的成矿物质叠加在先成矿体之上,并使之进一步富化,最终形成本区铅锌矿体。
The Nanjiang lead-zinc deposit is located in WuZhishan fold belt of Southern China foldzone, belong to Hainan mining area of Guangdong-Hainan metallogenic belt and lies in Danzhou-Baisha fault zone which is in south of Wangwu-Wenjiao deep fault.
According to collecting systematically research datas and relevant literatures, monographs and research reports of study area, based on knowing well and grasping the basis of mining geological features, using the latest research results of metallogeny and through of comprehensive research of field geological investigation, mineral deposit geology and mineral petrology, ore-forming tectonics and geochemical (major elements, trace elements and rare earth elements), discusses the geochemical characteristics of mining area and probes into the causes of the ore deposit.
The Nanjiang lead-zinc veins distributed in crystallization limestone of the Kongliecun group of lower silurian system with "lens shape"and "pulse shape". Sphalerite and Galena are the main metal mineral of ore. The prior structures of mineral are granular mosaic and dyeing shape structure. The main ore tectonics are massive and strap.
By silicate analysis, trace elements and rare earth elements test etc, the paper studys the granites, surrounding rocks and ore geochemical characteristics in the mining area, thinks Coarse-grained biotite granites near the ore bodies are closely related to mineralization. The granites belong to strongly peraluminous granitoid series. Granites are formed in the post-collisional stage of the tensile built rock type.
The writer considers that the Nanjiang lead-zinc deposit formed through the early depositional enrichment and late stage superimposed magmatic hydrothermal mineralization in two phases, is produced in the genesis of the carbonate rocks and magmatic hydrothermal mineralization formed mainly due to complex into a multi-lead-zinc deposits. The limestone of the ore area formed ore embryo through the time the deposition and metamorphism which provides a good metallogenic setting for enrichment of lead-zinc deposit. Frequent activities of the magma forming fluid temperature, flow and repeated circulation, making the metallogenic elements to be dissolved out of limestone, prompting "embryo mine" dissolved, activation and transported of the first mineralization stage. Due to the low pressure of a crack in the limestone, lead and zinc precipita and enrich in the crack of the limestone. With the many resurrection of tectonic, hydrothermal role has been strengthened, outside metallogenic material superimposed on top of earlier one and make the ore further enriched, ultimately form lead-zinc body.
引文
[1]邓昕.全球铅锌资源概况[J].中国铅锌锡锑,2008,11：41～46；
[2]许德如、马驰等.海南岛北西部邦溪地区奥陶纪火山-碎屑沉积岩岩石学、矿物学和地球化学源区及构造环境暗示[J].地球化学,2007,36(1)11～26；
[3]涂绍雄、邓孺孺、战明国等.海南岛断裂构造的遥感解译及构造对金矿的控制作用[J].广东地质,1992,7(3)83～95；
[4]涂绍雄.海南岛金矿分布规律及成矿地质条件的初步研究[J].地质找矿论丛,1992,7(3)71～82：
[5]龙文国.海南岛中生代地洼期构造与金银多金属成矿特征[J].大地构造与成矿学,1999,23(4)308～314；
[6]陈沐龙、李孙雄、曾雁玲等.海南岛白垩纪千家岩体岩石地球化学特征及其成矿作用分析[J].矿产与地质,2008,22(1)36～42；
[7]新发现.海南新增铅锌资源量10万吨[J].中国矿山工程,2008年,37(2)：56～57：
[8]陈志国.面向21世纪的中国铅锌材料[J].材料导报,1999,13(1)：8～9；
[9]曹异生.当前铅锌矿业进展及前景展望.中国铅锌锡锑,2005,9：7～12；
[10]吴荣庆、张燕如、张安宁.铅锌资源供需形势分析及市场前景预测.江苏地质,2007,31(1)：59～63：
[11]张燕如、吴荣庆、张安玲.铅锌资源供需形势及政府宏观调控的政策取向.中国国土资源经济,2006,6：13～15；
[12]戴自希.世界铅锌资源和开发利用现状.世界有色金属,2004,3：22～29；
[13]宋新宇、郎一环、张启芳.我国铅锌矿产资源及其生产和消费.资源开发和市场,1998,14(3)：108～111；
[14]冯君从、张放、黄国平.世界铅锌市场动向和中国铅锌工业的未来.世界有色金属,1996,12：41～45；
[15]张乾.中国铅锌矿床的元素组合及时空[J].河北地质学院学报,1993,16(3)215～221；
[16]朱上庆.中国层控铜铅锌矿矿床的时间和分布特征[J].地球科学-中国地质大学学报,1984,4：1～10；
[17]朱笑青、张乾、何玉良等.地史早期岩石中的铅锌演化-狼山渣尔泰山中元古带铅锌矿成矿的物质基础.矿物学报,2005,25(4)：325～333；
[18]Unsworth、M J Siripunvaraporn、W Craven、J A. Exploration for unconformity-type uranium deposits with audiomagnetotelluric data:a case study from the McArthur river mine, Saskatchewan, Canada[J]. Geophysics, 2006,71:201～9;
[19]Conor、C H HStevens、B P J Gibsom、G MPreiss、W VSouthgate、P N. Correlation of Olary and Broken Hill domains, Curnamona Province: Possible relationship to Mount Isa and other north Australian Pb-Zn-Ag-bearing successions[J]. Economic Geology,2005,100:663～676;
[20]Stevens、B P J Gibson、G M. Geochronology of the sequence hosting the Broken Hill Pb-Zn-Ag orebody, Australia[J]. Economic Geology,2005,100:633～ 661;
[21]Gregory,Melissa J Wilde、Andy R Jones、Peter A. Uranium deposits of the Mount Isa Region and their relationship to deformation, metamorphism, and copper deposition[J]. Economic Geology,2005,100:537～546;
[22]Bierlein、F P Betts PC., The Proterozoic Mount Isa Fault Zone, northeastern Australia:is it really a ca.1.9 Ga terrane-bounding suture[J]. Earth and Planetary Science Letters,2004,225:279～94;
[23]Large、Ross R Mc Goldrick、Peter J. Lithogeochemical halos and geochemical vectors to stratiform sediment hosted Zn-Pb-Ag deposits,1. Lady Loretta deposit, Queensland[J]. Journal of Geochemical Exploration,1998,63:37～ 56:
[24]Valenta.R.K. Syntectohic discordant copper mineralization in the Hilton mine, Mount Isa[J]. Econ Geol,1994,89:1031～1052;
[25]Xu G. Structural geology of the Dugald River Zn-Pb-Ag deposit, Mount Isa Inlier, Australia[J]. Ore Geology Reviews,1996,11:339～361;
[26]Chandler F W、Zieg G A. Was the depositional environment of the Sullivan Zn-Pb deposit in British Columbia marine or lacustrine and how saline was it?A summary of the data[J]. Current Research, Geol Survey Canada Paper,1994, 94(1 A):123～130;
[27]Cook F A、Vander Velden A J. Three-dimensional crustal structure of the Purcell anticlinorium in the Cordillera of southwestern[J]. Canada Geolsoc Am Bull, 1995,107:642～664;
[28]Perkins W G. Mount Isa lead-zinc orebodies:Replacement lodes in a zoned syndeformational copper-lead-zinc system?[J]. Ore Geology Reviews,1997,12: 61～110;
[[29]Large、Ross R. Bull、Stuart W Mc Goldrick、Peter J. Lithogeochemical halos and geochemical vectors to stratiform sediment hosted Zn-Pb-Ag deposits Part 2. HYC deposit, McArthur river, North Territory [J]. Journal of Geochemical Exploration,2000,68:105～126;
[30]Elliott、P Turner、P Jensen、P Kolitsch、U Pring A. Description and crystal structure of nyholmite, a new mineral related to hureaulite, from Broken Hill, New South Wales, Australia[J]. Mineralogical Magazine,2009,73:723-735;
[31]Heimann、Adriana.Spry、 Paul G Teale、Graham S Conor、Colin H H Leyh、 Wolfgang R. Geochemistry of garnet-rich rocks in the southern curnamona province, Australia, and their genetic relationship to Broken Hill-type Pb-Zn-Ag mineralization [J]. Economic Geology,2009,104:687～712;
[32]Hofmann A. The geochemistry of sedimentary rocks from the Fig Tree Group, Barberton greenstone belt:Implications for tectonic, hydrothermal and surface processes during mid-Archaean times [J]. Precambrian Research,2005,143: 23-49;
[33]郭文魁、张玉华.1：3000000中国铅锌矿成矿规律略图简要说明[J].地质评论,1959,20(1)：17～31；
[34]中国矿床编委会.中国矿床(上册)[M].北京：地质出版社,1989,114～119；
[35]涂光炽.中国层控矿床地球化学[M].北京：地质出版社,1984,16～20；
[36]朱上庆、黄华盛.层控矿床地质学[M].北京：冶金工业出版社,1988,18～21：
[37]王育民.试论中国铅锌矿床类型及基本特征[J].矿床地质,1983,2(1)：21～27；
[38]刘瑛、吕风翔.我国铅锌矿床成因类型及其时空分布[J].资源调查与环境,1983,1：73～83；
[39]郑知一、季绍新、傅德鑫.论中国铅锌矿床成因类型[J].资源调查与环境,1983,1：97～111：
[40]郭洪中.铅锌矿床的类型划分及特征[J].地质地球科学,1994,(6)：3～8；
[41]戴自希.世界铅锌资源的分布、类型和勘查准则[J].世界有色金属,2005,(3)：15～23；
[42]刘瑛、吕凤翔.我国铅锌矿床成因类型及其时、空分布[J].中国地质科学院南京地质矿产研究所所刊,1983,4(1)：73～84；
[43]陈喜峰、彭润民.铅锌矿床类型划分评析[J].化工矿产地质,2007,29(4)：209～214；
[44]中国科学院华南富铁科学研究队.海南岛地质与石碌铁矿地球化学[M].北京：科学出版社,1986；
[45]徐绍雄.海南岛金矿分布规律及成矿地质条件的初步研究[J].地质找矿论丛,1992,71～82；
[46]汪啸风、马大栓、蒋大海.海南岛地质(三)构造地质[M].地质出版社,1991,1～161；
[47]覃慕陶、刘师先、朱淮江.广东-海南成矿带成矿系列地质特征及其演化规律[J].地球化学,1998,27(4)：391～399；
[48]廖香俊、王平安、丁式江等.海南岛主要成矿系列与矿床成矿规律研究[J].地质力学报,2005,11(2)：187～194；
[49]王春宏、聂凤莲、刘纲等.海南省金矿成矿规律及找矿方向[J].黄金地质,2002,8(1)：11～16；
[50]海南省地质调查院.海南省1：25万琼海县幅区域地质调查报告[R].中国地质调查局宜昌地质调查中心,2004；
[51]海南省地质矿产勘查开发局.海南省岩石地层[M].武汉：中国地质大学出版社,1997；
[52]彭格林.海南岛沉积建造特征及大地构造问题[J].大地构造成矿学,1990,14(4)：293～303；
[53]梁新权、侯威、陈惠芳.海南岛戈枕脆、韧性叠加剪切带基本特征及其成矿意义[J].大地构造与成科学,1990,44(14)：255-265；
[54]梁新权.海南省土外山金矿地质与成因[J].中国区域地质,1992,174～182；
[55]梁新权.海南省土外山金矿地质及其成矿时代[J].广东地质,1993,8(1)：65～74；
[56]陈志中、俞受望、陈炳辉.海南抱板金矿带地质特征及矿床成因[J].矿床地质,1993,12(4)：318～329；
[57]杨元根、吴学益.海南二甲金矿的地质地球化学研究[J].黄金科学技术,1995,3(3)：19～25；
[58]陈好寿.海南金矿成矿作用年代学[J].地质找矿论丛,1996,11(2)：59～75；
[59]汪啸风、马大栓、蒋大海.海南岛地质(二)岩浆岩[M].地质出版社,1991,1-161；
[60]袁见齐、朱上庆、瞿裕生.矿床学[M].地质出版社,1991；
[61]李佐臣、裴先治、丁仨平等.川西北平武地区南一里花岗岩体地球化学特征及其构造环境[J].地质学报,2009,83(2)：260～271；
[62]Sylvester P J. Post-collisional strongly peraluminous anites[J]. Lithos,1998, 45(1)：29～44；
[63]邱家骧.应用岩浆岩岩石学[M].武汉：中国地质大学出版社,1991；
[64]王淑芬.应用统计学[M].北京：中国林业出版社,北京大学出版社,2007：147～148；
[65]赵鹏大、胡旺亮、李紫金.矿床统计预测[M].北京：地质出版社,1994,161～178,260～276；
[66]何翔,李勇.评述统计学方法在环境地球化学研究中的应用[J].中山大学研究生学刊(自然科学、医学版),2009,30(2)：47～54；
[67]邱家骧、林景仟.岩石化学[M].北京：地质出版社,1991；
[68]王素娟、吴烈勤、张展适、谭正中.粤北下庄矿田帽峰岩体的岩石地球化学特征[J].华南理工学院学报：2005,28(2)：130～135；
[69]路远发.GeoKit:一个用VBA构建的地球化学工具软件包[J].地球化学,2004,33(5)：459-464；
[70]王中刚、于学元、赵振华等.稀土元素地球化学[M].北京：科学出版社,1989,1～495：
[71]陈德潜、陈刚.实用稀土元素地球化学[M].北京：冶金工业出版社,1990；
[72]Maniar P D]. Piccoli P M. Tectonic discrimination of granitoids[J]. Bull Geol Soc Am,1989,101:635～643;
[73]肖庆辉等.花岗岩研究思维与方法[M].北京：地质出版社,2002,21-32；
[74]Williamson B J、Shaw A、Downes H、Thirlwall M F. Geochemical constraints on the genesis of Hercynian teo-mica leucogranties from the Massive Central, France[J]. Chemical Geology,1996,127:25～42;
[75]Forster H J、Tischendorf G、Gottesmann B、Trumbull R B. Late-collisional granites in the Variscan Erzgebige, Germany [J]. Journal of Petrology.1999,40: 1613～1645;
[76]Zhao X X、Coe R S、 Gilder S A、Frost G M. Palaeomagnetic constraints on the palaeogeography of china:implications for Gondwanaland [J]. Australian Journal of Earth Sciences,1996,43(6):643～672;
[77]Liegeios J P、Naves J、Hertogen J、Black R. Contrasting origin of post-collisional high-K calc-alkaline and shoshonitic versus alkaline and per alkaline granitoids, the use of sliding normalization [J]. Lithos,1998,45(1):1～28;
[78]赵亮.甘肃金塔县玉山钨矿成矿规律及成矿预测研究[硕士学位论文].长沙：中南大学,2010；
[2]许德如、马驰等.海南岛北西部邦溪地区奥陶纪火山-碎屑沉积岩岩石学、矿物学和地球化学源区及构造环境暗示[J].地球化学,2007,36(1)11～26；
[3]涂绍雄、邓孺孺、战明国等.海南岛断裂构造的遥感解译及构造对金矿的控制作用[J].广东地质,1992,7(3)83～95；
[4]涂绍雄.海南岛金矿分布规律及成矿地质条件的初步研究[J].地质找矿论丛,1992,7(3)71～82：
[5]龙文国.海南岛中生代地洼期构造与金银多金属成矿特征[J].大地构造与成矿学,1999,23(4)308～314；
[6]陈沐龙、李孙雄、曾雁玲等.海南岛白垩纪千家岩体岩石地球化学特征及其成矿作用分析[J].矿产与地质,2008,22(1)36～42；
[7]新发现.海南新增铅锌资源量10万吨[J].中国矿山工程,2008年,37(2)：56～57：
[8]陈志国.面向21世纪的中国铅锌材料[J].材料导报,1999,13(1)：8～9；
[9]曹异生.当前铅锌矿业进展及前景展望.中国铅锌锡锑,2005,9：7～12；
[10]吴荣庆、张燕如、张安宁.铅锌资源供需形势分析及市场前景预测.江苏地质,2007,31(1)：59～63：
[11]张燕如、吴荣庆、张安玲.铅锌资源供需形势及政府宏观调控的政策取向.中国国土资源经济,2006,6：13～15；
[12]戴自希.世界铅锌资源和开发利用现状.世界有色金属,2004,3：22～29；
[13]宋新宇、郎一环、张启芳.我国铅锌矿产资源及其生产和消费.资源开发和市场,1998,14(3)：108～111；
[14]冯君从、张放、黄国平.世界铅锌市场动向和中国铅锌工业的未来.世界有色金属,1996,12：41～45；
[15]张乾.中国铅锌矿床的元素组合及时空[J].河北地质学院学报,1993,16(3)215～221；
[16]朱上庆.中国层控铜铅锌矿矿床的时间和分布特征[J].地球科学-中国地质大学学报,1984,4：1～10；
[17]朱笑青、张乾、何玉良等.地史早期岩石中的铅锌演化-狼山渣尔泰山中元古带铅锌矿成矿的物质基础.矿物学报,2005,25(4)：325～333；
[18]Unsworth、M J Siripunvaraporn、W Craven、J A. Exploration for unconformity-type uranium deposits with audiomagnetotelluric data:a case study from the McArthur river mine, Saskatchewan, Canada[J]. Geophysics, 2006,71:201～9;
[19]Conor、C H HStevens、B P J Gibsom、G MPreiss、W VSouthgate、P N. Correlation of Olary and Broken Hill domains, Curnamona Province: Possible relationship to Mount Isa and other north Australian Pb-Zn-Ag-bearing successions[J]. Economic Geology,2005,100:663～676;
[20]Stevens、B P J Gibson、G M. Geochronology of the sequence hosting the Broken Hill Pb-Zn-Ag orebody, Australia[J]. Economic Geology,2005,100:633～ 661;
[21]Gregory,Melissa J Wilde、Andy R Jones、Peter A. Uranium deposits of the Mount Isa Region and their relationship to deformation, metamorphism, and copper deposition[J]. Economic Geology,2005,100:537～546;
[22]Bierlein、F P Betts PC., The Proterozoic Mount Isa Fault Zone, northeastern Australia:is it really a ca.1.9 Ga terrane-bounding suture[J]. Earth and Planetary Science Letters,2004,225:279～94;
[23]Large、Ross R Mc Goldrick、Peter J. Lithogeochemical halos and geochemical vectors to stratiform sediment hosted Zn-Pb-Ag deposits,1. Lady Loretta deposit, Queensland[J]. Journal of Geochemical Exploration,1998,63:37～ 56:
[24]Valenta.R.K. Syntectohic discordant copper mineralization in the Hilton mine, Mount Isa[J]. Econ Geol,1994,89:1031～1052;
[25]Xu G. Structural geology of the Dugald River Zn-Pb-Ag deposit, Mount Isa Inlier, Australia[J]. Ore Geology Reviews,1996,11:339～361;
[26]Chandler F W、Zieg G A. Was the depositional environment of the Sullivan Zn-Pb deposit in British Columbia marine or lacustrine and how saline was it?A summary of the data[J]. Current Research, Geol Survey Canada Paper,1994, 94(1 A):123～130;
[27]Cook F A、Vander Velden A J. Three-dimensional crustal structure of the Purcell anticlinorium in the Cordillera of southwestern[J]. Canada Geolsoc Am Bull, 1995,107:642～664;
[28]Perkins W G. Mount Isa lead-zinc orebodies:Replacement lodes in a zoned syndeformational copper-lead-zinc system?[J]. Ore Geology Reviews,1997,12: 61～110;
[[29]Large、Ross R. Bull、Stuart W Mc Goldrick、Peter J. Lithogeochemical halos and geochemical vectors to stratiform sediment hosted Zn-Pb-Ag deposits Part 2. HYC deposit, McArthur river, North Territory [J]. Journal of Geochemical Exploration,2000,68:105～126;
[30]Elliott、P Turner、P Jensen、P Kolitsch、U Pring A. Description and crystal structure of nyholmite, a new mineral related to hureaulite, from Broken Hill, New South Wales, Australia[J]. Mineralogical Magazine,2009,73:723-735;
[31]Heimann、Adriana.Spry、 Paul G Teale、Graham S Conor、Colin H H Leyh、 Wolfgang R. Geochemistry of garnet-rich rocks in the southern curnamona province, Australia, and their genetic relationship to Broken Hill-type Pb-Zn-Ag mineralization [J]. Economic Geology,2009,104:687～712;
[32]Hofmann A. The geochemistry of sedimentary rocks from the Fig Tree Group, Barberton greenstone belt:Implications for tectonic, hydrothermal and surface processes during mid-Archaean times [J]. Precambrian Research,2005,143: 23-49;
[33]郭文魁、张玉华.1：3000000中国铅锌矿成矿规律略图简要说明[J].地质评论,1959,20(1)：17～31；
[34]中国矿床编委会.中国矿床(上册)[M].北京：地质出版社,1989,114～119；
[35]涂光炽.中国层控矿床地球化学[M].北京：地质出版社,1984,16～20；
[36]朱上庆、黄华盛.层控矿床地质学[M].北京：冶金工业出版社,1988,18～21：
[37]王育民.试论中国铅锌矿床类型及基本特征[J].矿床地质,1983,2(1)：21～27；
[38]刘瑛、吕风翔.我国铅锌矿床成因类型及其时空分布[J].资源调查与环境,1983,1：73～83；
[39]郑知一、季绍新、傅德鑫.论中国铅锌矿床成因类型[J].资源调查与环境,1983,1：97～111：
[40]郭洪中.铅锌矿床的类型划分及特征[J].地质地球科学,1994,(6)：3～8；
[41]戴自希.世界铅锌资源的分布、类型和勘查准则[J].世界有色金属,2005,(3)：15～23；
[42]刘瑛、吕凤翔.我国铅锌矿床成因类型及其时、空分布[J].中国地质科学院南京地质矿产研究所所刊,1983,4(1)：73～84；
[43]陈喜峰、彭润民.铅锌矿床类型划分评析[J].化工矿产地质,2007,29(4)：209～214；
[44]中国科学院华南富铁科学研究队.海南岛地质与石碌铁矿地球化学[M].北京：科学出版社,1986；
[45]徐绍雄.海南岛金矿分布规律及成矿地质条件的初步研究[J].地质找矿论丛,1992,71～82；
[46]汪啸风、马大栓、蒋大海.海南岛地质(三)构造地质[M].地质出版社,1991,1～161；
[47]覃慕陶、刘师先、朱淮江.广东-海南成矿带成矿系列地质特征及其演化规律[J].地球化学,1998,27(4)：391～399；
[48]廖香俊、王平安、丁式江等.海南岛主要成矿系列与矿床成矿规律研究[J].地质力学报,2005,11(2)：187～194；
[49]王春宏、聂凤莲、刘纲等.海南省金矿成矿规律及找矿方向[J].黄金地质,2002,8(1)：11～16；
[50]海南省地质调查院.海南省1：25万琼海县幅区域地质调查报告[R].中国地质调查局宜昌地质调查中心,2004；
[51]海南省地质矿产勘查开发局.海南省岩石地层[M].武汉：中国地质大学出版社,1997；
[52]彭格林.海南岛沉积建造特征及大地构造问题[J].大地构造成矿学,1990,14(4)：293～303；
[53]梁新权、侯威、陈惠芳.海南岛戈枕脆、韧性叠加剪切带基本特征及其成矿意义[J].大地构造与成科学,1990,44(14)：255-265；
[54]梁新权.海南省土外山金矿地质与成因[J].中国区域地质,1992,174～182；
[55]梁新权.海南省土外山金矿地质及其成矿时代[J].广东地质,1993,8(1)：65～74；
[56]陈志中、俞受望、陈炳辉.海南抱板金矿带地质特征及矿床成因[J].矿床地质,1993,12(4)：318～329；
[57]杨元根、吴学益.海南二甲金矿的地质地球化学研究[J].黄金科学技术,1995,3(3)：19～25；
[58]陈好寿.海南金矿成矿作用年代学[J].地质找矿论丛,1996,11(2)：59～75；
[59]汪啸风、马大栓、蒋大海.海南岛地质(二)岩浆岩[M].地质出版社,1991,1-161；
[60]袁见齐、朱上庆、瞿裕生.矿床学[M].地质出版社,1991；
[61]李佐臣、裴先治、丁仨平等.川西北平武地区南一里花岗岩体地球化学特征及其构造环境[J].地质学报,2009,83(2)：260～271；
[62]Sylvester P J. Post-collisional strongly peraluminous anites[J]. Lithos,1998, 45(1)：29～44；
[63]邱家骧.应用岩浆岩岩石学[M].武汉：中国地质大学出版社,1991；
[64]王淑芬.应用统计学[M].北京：中国林业出版社,北京大学出版社,2007：147～148；
[65]赵鹏大、胡旺亮、李紫金.矿床统计预测[M].北京：地质出版社,1994,161～178,260～276；
[66]何翔,李勇.评述统计学方法在环境地球化学研究中的应用[J].中山大学研究生学刊(自然科学、医学版),2009,30(2)：47～54；
[67]邱家骧、林景仟.岩石化学[M].北京：地质出版社,1991；
[68]王素娟、吴烈勤、张展适、谭正中.粤北下庄矿田帽峰岩体的岩石地球化学特征[J].华南理工学院学报：2005,28(2)：130～135；
[69]路远发.GeoKit:一个用VBA构建的地球化学工具软件包[J].地球化学,2004,33(5)：459-464；
[70]王中刚、于学元、赵振华等.稀土元素地球化学[M].北京：科学出版社,1989,1～495：
[71]陈德潜、陈刚.实用稀土元素地球化学[M].北京：冶金工业出版社,1990；
[72]Maniar P D]. Piccoli P M. Tectonic discrimination of granitoids[J]. Bull Geol Soc Am,1989,101:635～643;
[73]肖庆辉等.花岗岩研究思维与方法[M].北京：地质出版社,2002,21-32；
[74]Williamson B J、Shaw A、Downes H、Thirlwall M F. Geochemical constraints on the genesis of Hercynian teo-mica leucogranties from the Massive Central, France[J]. Chemical Geology,1996,127:25～42;
[75]Forster H J、Tischendorf G、Gottesmann B、Trumbull R B. Late-collisional granites in the Variscan Erzgebige, Germany [J]. Journal of Petrology.1999,40: 1613～1645;
[76]Zhao X X、Coe R S、 Gilder S A、Frost G M. Palaeomagnetic constraints on the palaeogeography of china:implications for Gondwanaland [J]. Australian Journal of Earth Sciences,1996,43(6):643～672;
[77]Liegeios J P、Naves J、Hertogen J、Black R. Contrasting origin of post-collisional high-K calc-alkaline and shoshonitic versus alkaline and per alkaline granitoids, the use of sliding normalization [J]. Lithos,1998,45(1):1～28;
[78]赵亮.甘肃金塔县玉山钨矿成矿规律及成矿预测研究[硕士学位论文].长沙：中南大学,2010；