右江盆地地质热事件及其在卡林型金矿成矿中的意义
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摘要
本文运用区域成矿学、矿床有机地球化学、盆地沉积-构造演化与成矿、矿床地质地球化学和大地构造与边缘成矿等理论,对右江盆地沉积-构造演化历史以及与之伴生的地质热事件进行系统研究,探讨地质热事件的类型、特点、成生机制,分析矿床中的有机质、有机质对于地质热事件的示踪意义及其在金成矿中的作用,讨论桂西北卡林型金矿成矿与有机质、与地质热事件的关系以及金的成矿机理,总结桂西北成矿区卡林型金矿的时空分布特点及成矿规律,并在综合研究的基础上进行找矿前景评价。主要取得了以下主要认识和研究成果:
     1、以“热源”为主线,以地质热事件为关键因素,系统研究右江盆地沉积-构造演化过程中与之伴生的地质热事件及其成矿、控矿意义。
     在右江盆地沉积-构造演化过程中,与卡林型金矿成矿作用有关的地质热事件主要是沉积地层的深埋地热增温、大地构造位置及构造运动、岩浆-火山活动以及热液活动。其中,最重要、最直接的热事件是沉积地层的深埋地热增温。对于成矿物质的初步富集、再次分配、活化转移、重新改造都发挥过不同意义的直接与间接作用,为“成矿地质热事件”。
     2、综合评价了右江盆地沉积地层深埋增温作用及其地质热事件。
     右江盆地演化相应经历了泥盆纪-早二叠世被动大陆边缘裂谷盆地阶段、晚二叠世-早三叠世弧后盆地阶段和中三叠世-晚三叠世早期挤压拗陷盆地阶段,晚三叠世后陆内挤压褶皱隆升成陆。右江盆地在海西期和印支期沉积最大厚度可近万米(或中、下三叠统地层的最大厚就可达万米)。按照地热增温率为3~5℃/100m来计算,右江盆地底部的温度可高达300~500℃(或三叠系地层底部的地温就可达到300~500℃)。因此,在桂西北地区卡林型金矿成矿的地质时期,右江盆地地层深埋地热温度完全可以满足卡林型金矿床成矿作用的需要。
     3、探讨了桂西北右江盆地沉积-构造演化过程中岩浆-火山活动的性质以及地质热事件的成矿控矿意义。
     桂西北地区卡林型金的成矿作用主要发生于印支晚期-燕山早期,由岩浆-火山活动所产生的地质热事件,其成矿意义主要表现在两个方面:(1)形成矿源层。(2)提供热能和热液。
     4、综合分析了右江盆地热液活动的特点及地质热事件意义。
     根据桂西北地区卡林型金矿床的地质、地球化学综合研究结果可知,在桂西北卡林型金矿床形成过程中,成矿流体主要是盆地热卤水。矿物流体包裹体以及煤层最大镜质组反射率研究结果标明,桂西北卡林型金矿的成矿温度范围主要分布于100~350℃区段,显示了地质热事件的存在。
     5、采用矿床学及矿床地球化学的最新理论,在前人研究的基础上,进行综合归纳,将桂西北金矿床的成因归类为与盆地热卤水成矿有关的“卡林型金矿”。
     6、探讨了右江盆地卡林型金矿床中的有机质及其地质热事件的示踪意义和成矿意义。右江盆地金矿床中的有机质有原生型干酪根和迁移型有机流体,有机碳含量为0.18%~2.95%,平均为0.97%。原生有机质为Ⅱ型干酪根,有少量Ⅰ型干酪根。导致右江盆地有机质发生成熟异常的地质热事主要是沉积地层的深埋导致地热增温,而与岩浆侵入、火山喷发、构造挤压、变质破坏和放射性元素蜕变等地质热事件的影响效果明显不同。
     7、研究了有机质及其热成熟产物的成矿意义。生物标志化合物研究结果表明,在成矿过程中有下渗大气降水以及细菌类微生物的参与,也有从他地迁移来的有机流体的掺和。这表明金的成矿机理包含了不同物化性质流体的混合作用,成矿反应时的温度不高,一般不应高于100℃;成矿时深度不大,不应超过2000m深。
     8、根据氢-氧同位素地球化学研究,确定了右江盆地演化以及以大气降水为主要水源的特点。桂西北卡林型金矿床标本氢-氧同位素地球化学研究表明桂西北卡林型金矿床成矿过程中的水溶液主要是盆地热卤水,表明成矿过程以大气降水为主,有少量岩浆水和变质溶液或地层水的掺和。
     9、通过对桂西北主要矿床的硫-铅-碳稳定同位素以及围岩蚀变、矿石特征、流体包裹体、浆活动和古地热场研究,确定了桂西北卡林型金矿床金等成矿物质主要来源于盆内地层中的矿质,盆地内存在一套成矿物质相对富集的矿源层。矿石中的硫主要来自围岩地层,部分来自地层有机质,部分是深部来源。这些特征表明高龙矿区的铅主要来自上部地壳,即来源于沉积岩地层,小部分来源于造山带,在以地层来源为主的基础上,混入了少量的深源造山带铅。
     10、系统研究了桂西北卡林型金矿床中的输矿通道和赋矿空间。桂西北卡林型金矿床的成矿作用和矿床的时空分布,均受到该地区多级、各种类型构造的控制。
     在区域性范围内,桂西北地区位于扬子准地台与华南褶皱系西南缘的结合部位,其大地构造位置处于板块构造的边缘;桂西北深大断裂构造发育,有右江断裂、南丹-昆仑关断裂、田林-巴马断裂和巴马-乐业隐伏断裂等大型构造,它们控制了右江盆地和金矿带的形成。古陆边缘是地壳的构造薄弱地带,是壳幔沟通的窗口和通道,其壳幔边界处于开放状态。在古陆边缘,壳幔之间双向物质交换与混合作用活跃、能量交换与转换作用强烈,构造运动频繁,成岩成矿作用显著,往往能形成多种多样的成矿系统。
     11、探讨了桂西北地区各个地层不整合面的特点及其控矿意义。在矿区范围,在桂西北D-∈、C1-D3、P2-P1、T1-T2和T2-T1等之间5个地层不整合面及其复合断层、切层断层、层间破碎带,控制了桂西北卡林型金矿床的分布规律和矿体的产出部位。矿体主要产于沉积间断面上,呈似层状、透镜状,有的呈藤瓜组合形式。部份产于间断面上盘的断层或层间破碎带中,呈脉状、似层状等。
     12、以成矿地质热事件为主导因素,确定成矿模式。桂西北卡林型金矿床的形成过程和成矿模式,可以分为初始聚集期、盆地流体期、成矿作用期、和表生风化期。
     13、系统总结了桂西北地区卡林型金矿控矿地质因素,提出了5个成矿预测区,总结了预测区成矿模式和找矿标志,提出了预测区圈定方法及原则,并划定了预测靶区。
This article applies the theory of regional metallogeny,deposit organic geochemistry,basin sediment-tectonic evolution and mineralization,deposit geology geochemistry and geotectonic marginal mineralization etc to the systematic study of Youjiang basin sediment-tectonic evolution history and its associated geological thermal events,then investgating the geological thermal events type,characteristics and the formation mechanism, analyzing the organics in deposits which have the tracer significance in the geological thermal events and play an important role in gold mineralization,discussing the relationship between Carlin-type gold deposits in northwestern Guangxi mineralization and the organics and the geological thermal events as well as the minerogenetic mechanism of gold, summarizing the time-space distribution feature and the metallogenic regularity of Carlin-type gold deposits in northwestern Guangxi metallogenic province,Finally evaluating the ore-finding prospects based on the comprehensive research.The main cognitive and research results are as follows:
     1.With heat source as the main line and geological thermal events as the key factors, we research the Youjiang basin's sedimentary-tectonic evolution process and the associated geological thermal event, mineralization, ore-controlling significance systematically.
     In the process of Youjiang basin's sedimental-tectonic evolution,the main geological thermal events related with the mineralization of Carlin-type gold deposits are deep buried sedimentary stratas'geothermal gradient,geotectonic position and tectonic movement,magma-volcanic activity as well as hydrothermal activity.Among them, the deep buried sedimentary stratas'geothermal gradient is the most important and direct thermal event, for the metallogenic materials preliminary enrichment,second distribution,remobilization,reconstruction,It play a different meaning of direct and indirect effect, as "the geological thermal events of mineralization".
     2.This paper comprehensive evaluated the deep buried constructive role and geological thermal events of sedimentary statum in the Youjiang basin.
     The evolution of Youjiang basin had experienced Passive continental margin rift basin stage of Devonian-Early Permian, back-arc basin stage of Late Permian-early Triassic, extrusion and downwarping basin stage of In Triassic-late Triassic, after the late Triassic intracontinental extrusion fold uplift into land. The maximum thickness of sedimentation belonging to Youjiang basin can be nearly meters (or The lower and middle Triassic formation of maximum thickness can be CTKM meters). According to the geothermal gradient for3~5°C/100m to calculate, the Youjiang basin bottom temperature can be up to300~500°C (or Trias formation at the bottom of the ground temperature can reach300~500°C). Therefore, the Metallogenic geologic time belonging to Carlin-type gold deposits in the region of the northwest of Guangxi, the Youjiang basin formation deep buried geothermal temperature can completely satisfy the Carlin-type gold deposits mineralization needs.
     3.This paper discusses the Youjiang basin in northwest of Guangxi sedimentation-structure in the evolution process of the nature of the magma-volcanic activity and the geological thermal event metallogenic ore-controlling significance.
     The mineralization of this Carlin-type gold deposits mainly occurs in the late indosinian period and early yanshanian, the magma-volcanic activity produced by the geological thermal events, its metallogenic meaning mainly manifested in two aspects:(1)the formation of source bed.(2) providing heat and thermal fluid.
     4.Have been Comprehensive analysised the characteristic of the hydrothermal activity in Youjiang basin and the geological hot events significance.
     According to the northwest Guangxi Carlin-type gold deposit geological、geochemical comprehensive researched result, and we know that the formation process of the northwest Guangxi Carlin-type gold deposit, ore-forming fluid is mainly basin thermal brine. Mineral fluid inclusions and the largest coal vitrinite reflectance results indicate that the northwest Guangxi Carlin-type gold deposit's metallogenic temperature range mainly distributed in100~350°C,which shows the existence of geological thermal events.
     5.Using of the latest theory that mineral deposits and geochemistry of mineral deposits,
     on the basis of previous studies, conducting comprehensive conclude, and considering the gold deposits of Northwest Guangxi is a kind of Carlin-type gold deposit that relates to mineralize of basin thermal brine.
     6.Having been explored the organic matter of the Youjiang Basin Carlin-type gold deposits and its geological thermal events tracer and metallogenic significance. The organic matter of the Youjiang Basin Carlin-type gold deposits contain native-kerogen and migrating organic fluid, and organic carbon content is0.18%-2.95%,an average of0.97%.Primary organic matter include II-kerogen and little I-kerogen. Causing the organic matter of Youjiang-basin occur mature anomaly geological thermal events was mainly the deep burial diagenesis of sedimentary formation that caused geothermal heating, but with the effect of the geological thermal events which include magmatic intrusion,volcanic eruption,tectonic compression,metamorphic damage,radioactive disintegration and so on was obviously different.
     7.Have been studied the metallogenic significance of organic matter and its thermal mature product. The biomarker research results show that it has infiltration of precipitation and Bacterial microorganisms participated in the process of mineralization, and it has organic fluid from migration participated. This indicates that the mineralization mechanism of gold contained the mixing effect of different physical and chemical properties of the fluid. The mineralization reaction when the temperature was not high that it generally no higher than100℃; Metallogenic depth was not deep, and its depth was not more than2000m.
     8. The hydrogen-oxygen isotope geochemistry study has confirmed that the evolution of Youjiang basin and atmospheric precipitation as its main characteristics of the water. Hydrogen-oxygen isotope geochemical analysis of the samples of Calin-type of gold deposits,northwest of Guangxi, show that the aqoeous solution of this type deposits in the process of ore-forming is mainly basin thermal brine, and metallogenic process has given priority to atmospheric precipitation, with a small amount of magmatic water and metamorphic solution or stratum water admixed.
     9. The research of S-Pb-C stable isotope and wallrock alteration, ore characteristics, fluid inclusions, magmatic activities and ancient geothermal field of the main deposits in northwest guangxi, determine that the metallogenic material such as gold of Calin-type of gold deposits in this area mainly come from the mineral of mainland basin layer, where exist a set of source bed with relatively abundant metallogenic material.The sulfur of ore mainly comes from wallrock formation,while partly from organic matter of stratum and resourse of deep. All these features show that the lead of GaoLong mining area mainly comes from the upper crust, namely sedimentary rock formation,and partly from the orogenic belt, in conclusion that the lead is predominate stratum resoures,while mixed with a bit of leac of orogenic belt in deep.
     lO.This system study the guide ore structure and ore space of the Carlin-type gold deposits which is located in the northwest of Guangxi. The mineralization and space-time distribution of Carlin-type gold deposits are controlled by the region multistage and various types of structure.
     In the regional range, the region is located in the combining site of Yangtze paraplatform and the south rim of the south china fold system,its tectonic structure position is in the edge of the plate tectonic; the deep and large scale fault structure of the northwest of Guangxi is very developing, such as Youjiang fault, Nandan-KunLunguan fault, Tianlin-Bama fault and Bama-Leye concealed fault, etc, which control the formation of Youjiang basin and gold ore belt. The edge of ancient land is tectonic weak zone in the crust and the window and channel of crust-mantle whose boundary is in open state. Two way exchange of material between the crust and the mantle,the active of mixing action and the strong of energy exchange and switching action,the frequent of tectonic movement and the significant of diagenesis and mineralization often can form various metallogenic system in the edge of ancient land.
     11.This paper will discuss every stratum unconformity surface and the significance of ore-controlling in the region of the northwest of Guangxi. In the mining area within the range, there are more than5stratum such as D-∈、C1-D3、P2-Pi、T1-T2and T2-T2whose unconformity surface as well as its composite fault, insequent fault, interformational broken belt, which control this Carlin-type gold deposits regularities of distribution and the output location of ore body. Ore body whose shape is stratoid, leticular and the combination of Rattan melon is chiefly located in the sedimentation surface of discontinuity, A little of ore body whose shape is veined and stratoid is located in the hanging wall of the surface of discontinuity or interformational broken belt.
     12.It is the leading factor that the ore-forming geological ensure the metallogenic model. This Carlin-type gold deposits based on the forming process and metallogenic model can be divided into initial gathered period, basin fluid phase, mineralization period and supergene weathering period.
     13.This system had summaried the geological factors of ore-controlling which belongs to the region of the northwest of Guangxi, putted forward five metallogenic forecasting areas, summaried the metallogenic model of forecasting area and prospecting marks, putted forward delineation of method and principle of forecasting area and defined the forecasting target area.
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