功能化电极界面的构筑及在分析化学中的应用
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摘要
本论文共分五部分，包括绪论、层-柱结构金属有机骨架材料(MOF)修饰碳糊电极的制作及其在多巴胺测量中的应用、含二茂铁的rho-ZMOF修饰电极的制作及其在对乙酰氨基酚测量中的应用、分子印迹聚合物膜修饰电极的制作及其在香草醛测量中的应用、分子印迹聚合物凝胶修饰电极的制作及其在牛血清白蛋白测量中的应用。
第一章为绪论部分。对化学修饰电极的基本原理、发展历史、现状；MOF的特点、制作、应用；分子印迹技术的原理、制作、应用进行了评述，对本文的选题思路、研究内容和创新点作了总结。
第二章是层-柱结构MOF修饰碳糊电极的制作及其在多巴胺测量中的应用。我们首次制成了MOF修饰碳糊电极，并研究了这种电极对多巴胺的吸附性质。我们使用这种电极对多巴胺的浓度进行了测定，发现使用这种电极可通过MOF的吸附作用对溶液中的多巴胺进行富集，从而提高检测的灵敏度。
第三章是含二茂铁的rho-ZMOF修饰电极的制作及其在对乙酰氨基酚测量中的应用。我们参考文献采用一步合成法在电极表面原位合成了含有催化剂二茂铁的rho-ZMOF，从而制成了MOF修饰电极并使用这种电极对对乙酰氨基酚的浓度进行了测定。发现使用这种电极可催化对乙酰氨基酚的电化学氧化从而提高测定的灵敏度。这种电极可排除常见的干扰物干扰，并可用于药片、血样等样品中的对乙酰氨基酚的检测。
第四章是分子印迹聚合物膜修饰电极的制作及其在香草醛测量中的应用。我们采用两种方法制作了香草醛的印迹聚合物膜修饰电极，并从印迹原理、合成、吸附性质等方面进行了对比。
第五章是分子印迹聚合物凝胶修饰电极的制作及其在牛血清白蛋白测量中的应用。我们使用化学法合成了牛血清白蛋白的分子印迹聚合物凝胶，并以此为活性物质制作了分子印迹聚合物膜修饰电极。这种电极可用于牛血清白蛋白浓度的测量，其测量响应时间短、操作简单。
This thesis consists of five chapters, including the introduction, the preparationof the pillared-layer metal-organic framework(MOF) modified electrode and itsapplication in the determination of dopamine, the preparation of ferroceneimmobilized rho-ZMOF modified electrode for the determination of acetaminophen,the preparation and application of electrodes modified with molecularly imprintedpolymer films, the preparation of potentiometric sensor for bovine serum albumin.
In chapter one, the basal knowledge, developing history and advance ofmodified electrodes; the properties, preparation and application of MOF; the principle,preparation and application of molecular imprinting technique are reviewed. Also, thecharacteristic, innovation and innovation point of this thesis are given.
In chapter two, a MOF modified carbon paste electrode was firstly prepared. Theadsorption properties for dopamine were studied. The amount of dopamine wasevaluated by linear sweep voltammetry. The sensitivity was enhanced by theabsorption of dopamine into MOF modified on the surface of the electrode.
In chapter three, a ferrocene immobilized rho-ZMOF modified electrode wasprepared by one-step method following the literature. The amount of acetaminophenwas evaluated by differential pulse voltammetry. The sensitivity was enhanced by thecatalysis of the oxidization.
In chapter four, two kind of molecularly imprinted polymer films weresynthesized in situ on the surface of the electrodes by chemical method andelectrochemical method. The principle, preparation and adsorption properties werecompared.
In chapter five, a potentiometric sensor based on molecularly imprinted polymergel for bovine serum albumin was developed. The amount of bovine serum albumincan be detected easily and fast.
第一章为绪论部分。对化学修饰电极的基本原理、发展历史、现状；MOF的特点、制作、应用；分子印迹技术的原理、制作、应用进行了评述，对本文的选题思路、研究内容和创新点作了总结。
第二章是层-柱结构MOF修饰碳糊电极的制作及其在多巴胺测量中的应用。我们首次制成了MOF修饰碳糊电极，并研究了这种电极对多巴胺的吸附性质。我们使用这种电极对多巴胺的浓度进行了测定，发现使用这种电极可通过MOF的吸附作用对溶液中的多巴胺进行富集，从而提高检测的灵敏度。
第三章是含二茂铁的rho-ZMOF修饰电极的制作及其在对乙酰氨基酚测量中的应用。我们参考文献采用一步合成法在电极表面原位合成了含有催化剂二茂铁的rho-ZMOF，从而制成了MOF修饰电极并使用这种电极对对乙酰氨基酚的浓度进行了测定。发现使用这种电极可催化对乙酰氨基酚的电化学氧化从而提高测定的灵敏度。这种电极可排除常见的干扰物干扰，并可用于药片、血样等样品中的对乙酰氨基酚的检测。
第四章是分子印迹聚合物膜修饰电极的制作及其在香草醛测量中的应用。我们采用两种方法制作了香草醛的印迹聚合物膜修饰电极，并从印迹原理、合成、吸附性质等方面进行了对比。
第五章是分子印迹聚合物凝胶修饰电极的制作及其在牛血清白蛋白测量中的应用。我们使用化学法合成了牛血清白蛋白的分子印迹聚合物凝胶，并以此为活性物质制作了分子印迹聚合物膜修饰电极。这种电极可用于牛血清白蛋白浓度的测量，其测量响应时间短、操作简单。
This thesis consists of five chapters, including the introduction, the preparationof the pillared-layer metal-organic framework(MOF) modified electrode and itsapplication in the determination of dopamine, the preparation of ferroceneimmobilized rho-ZMOF modified electrode for the determination of acetaminophen,the preparation and application of electrodes modified with molecularly imprintedpolymer films, the preparation of potentiometric sensor for bovine serum albumin.
In chapter one, the basal knowledge, developing history and advance ofmodified electrodes; the properties, preparation and application of MOF; the principle,preparation and application of molecular imprinting technique are reviewed. Also, thecharacteristic, innovation and innovation point of this thesis are given.
In chapter two, a MOF modified carbon paste electrode was firstly prepared. Theadsorption properties for dopamine were studied. The amount of dopamine wasevaluated by linear sweep voltammetry. The sensitivity was enhanced by theabsorption of dopamine into MOF modified on the surface of the electrode.
In chapter three, a ferrocene immobilized rho-ZMOF modified electrode wasprepared by one-step method following the literature. The amount of acetaminophenwas evaluated by differential pulse voltammetry. The sensitivity was enhanced by thecatalysis of the oxidization.
In chapter four, two kind of molecularly imprinted polymer films weresynthesized in situ on the surface of the electrodes by chemical method andelectrochemical method. The principle, preparation and adsorption properties werecompared.
In chapter five, a potentiometric sensor based on molecularly imprinted polymergel for bovine serum albumin was developed. The amount of bovine serum albumincan be detected easily and fast.
引文
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