松辽盆地北部中浅层水化学场特征及共与成岩作用关系研究
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摘要
本文在全面搜集和整理松辽盆地北部中浅层的分析实验数据的基础上,总结归纳了松辽盆地北部中浅层地下水在垂向和平面上的分布规律以及主要的砂岩成岩特征。
通过对松辽盆地北部中浅层地层水化学垂向分布规律的研究,认识到可以将松辽盆地地层水划分为自由交替带(0～800m),交替阻滞带(800～1350m),交替停止带(>1350m),以及成岩水淡化带(主要分布在1350～1650m,个别层段淡化强烈时,淡化带范围有所扩大)。各带因自由水交替、成岩水淡化、水岩反应等因素的影响,水化学特征表现出有规律地变化。通过对平面上分布规律的研究看出,地质条件与水化学性质之间有着密切的关系,地质条件相似,水化学特征也相近。同时发现,在成岩过程中由于水岩作用的不断进行,砂岩颗粒、杂基、胶结物、孔隙空间的变化与成岩特征中的碳酸盐胶结、硅质胶结、钠长石化、粘土胶结以及砂岩溶蚀密切相关。
针对现今地层水中的pH值失真的问题,本文建立了醋酸溶解平衡模型,应用有机酸恢复法对地层水的原位pH值进行了恢复,此方法在使用上有一定的局限性,只适用于以有机酸分解为主要缓冲体系的地层。通过对恢复和实测pH值的比较发现,恢复的pH值比实测的pH值小,其分布范围较窄。同时,利用恢复后的pH值所得的氢离子浓度求得了长石溶解的反应商,将其与长石的溶解平衡常数比较,对地下的长石溶解状态进行了判断,结果发现,在以有机酸分解为主要缓冲体系的地层中,长石溶解处于平衡(或近似平衡)的状态。
通过对水化学特征及成岩作用特征的研究,在蒙皂石和高岭石向伊利石转变的过程中消耗钾离子,在松辽盆地北部中浅层中这一过程主要是由于钾离子浓度的过高促使了蒙皂石和高岭石向伊利石转化。地层水中钙、镁离子浓度的变化特征与碳酸盐胶结作用的形成过程相对应,主要发生在早成岩的B期和中成岩的A期,这与松辽盆地北部中浅层方解石的成岩演化特征是一致的。地层水中钠离子的矿化机制与氯离子相似,都是以蒸发浓缩作用为主,它为钾长石和钙长石的钠长石化提供了丰富的来源。
Based on comprehensive collecting and sorting the analysis data in the middle-shallow strata of northern songliao basin, summarized the characteristics of formation water in vertical peace and surface distribution regularity and the main diagenetic characteristics of the sandstone.
Through the research, we found that formation water can be vertically divided into three zones: free exchanging zone (0~800m), exchanging-retarded zone (800~1350m), a exchanging-stagnant zone (>1350m) and diagenetic water desalting zone (1350~1650m). The result of free water changing, diagenetic water desalting, water-rock reacting and other factors, chemistry characteristics of formation water changed regularly. Researching the distribution laws of plane, recognized that there is a close relationship between geological conditions and water chemistry, geological conditions similar, hydrochemistry characteristic also similar. Also found that during diagenesis sandstone particle, miscellaneous base, cementation, content and pore space changes closely related with diagenetic features of carbonate cementation, siliceous cementation, albitization, clay cementation and sandstone dissolution.
For now the pH value of the formation water distortion, this paper established the acetic acid dissolution balance model, the application of organic acid recovery act of formation water in situ pH value, this method have certain limitation, it only applies to with organic acid decomposition for main buffer system formation. Through the recovery and measured the pH value of the comparison, its distribution area of the recovery pH value than the measured pH value is small to narrow. At the same time, use after restoring pH value income obtained the hydrogen ions concentration of dissolved feldspar with the contractor, reaction equilibrium constant comparison dissolution of feldspar, the dissolved state judge found in with organic acid decomposition for the main buffer system stratum, feldspar dissolved in balance.
Through reseach the hydrochemistry characteristic and diagenesis characteristics, this process was mainly because potassium ion concentration of exorbitant prompting smectite and kaolinite to illite transformation in the middle-shallow strata of northern songliao basin. Formation water calcium and magnesium ions concentration change characteristics and carbonate cementation, the formation process of the corresponding with northern songliao basin in the diagenetic evolution characteristics of shallow calcite is consistent.
Formation water sodium ions mineralization mechanism and chloride ions similar are mainly evaporation and concentration effect, it provides a rich source for potash feldspar and calcium feldspar albitization.
通过对松辽盆地北部中浅层地层水化学垂向分布规律的研究,认识到可以将松辽盆地地层水划分为自由交替带(0～800m),交替阻滞带(800～1350m),交替停止带(>1350m),以及成岩水淡化带(主要分布在1350～1650m,个别层段淡化强烈时,淡化带范围有所扩大)。各带因自由水交替、成岩水淡化、水岩反应等因素的影响,水化学特征表现出有规律地变化。通过对平面上分布规律的研究看出,地质条件与水化学性质之间有着密切的关系,地质条件相似,水化学特征也相近。同时发现,在成岩过程中由于水岩作用的不断进行,砂岩颗粒、杂基、胶结物、孔隙空间的变化与成岩特征中的碳酸盐胶结、硅质胶结、钠长石化、粘土胶结以及砂岩溶蚀密切相关。
针对现今地层水中的pH值失真的问题,本文建立了醋酸溶解平衡模型,应用有机酸恢复法对地层水的原位pH值进行了恢复,此方法在使用上有一定的局限性,只适用于以有机酸分解为主要缓冲体系的地层。通过对恢复和实测pH值的比较发现,恢复的pH值比实测的pH值小,其分布范围较窄。同时,利用恢复后的pH值所得的氢离子浓度求得了长石溶解的反应商,将其与长石的溶解平衡常数比较,对地下的长石溶解状态进行了判断,结果发现,在以有机酸分解为主要缓冲体系的地层中,长石溶解处于平衡(或近似平衡)的状态。
通过对水化学特征及成岩作用特征的研究,在蒙皂石和高岭石向伊利石转变的过程中消耗钾离子,在松辽盆地北部中浅层中这一过程主要是由于钾离子浓度的过高促使了蒙皂石和高岭石向伊利石转化。地层水中钙、镁离子浓度的变化特征与碳酸盐胶结作用的形成过程相对应,主要发生在早成岩的B期和中成岩的A期,这与松辽盆地北部中浅层方解石的成岩演化特征是一致的。地层水中钠离子的矿化机制与氯离子相似,都是以蒸发浓缩作用为主,它为钾长石和钙长石的钠长石化提供了丰富的来源。
Based on comprehensive collecting and sorting the analysis data in the middle-shallow strata of northern songliao basin, summarized the characteristics of formation water in vertical peace and surface distribution regularity and the main diagenetic characteristics of the sandstone.
Through the research, we found that formation water can be vertically divided into three zones: free exchanging zone (0~800m), exchanging-retarded zone (800~1350m), a exchanging-stagnant zone (>1350m) and diagenetic water desalting zone (1350~1650m). The result of free water changing, diagenetic water desalting, water-rock reacting and other factors, chemistry characteristics of formation water changed regularly. Researching the distribution laws of plane, recognized that there is a close relationship between geological conditions and water chemistry, geological conditions similar, hydrochemistry characteristic also similar. Also found that during diagenesis sandstone particle, miscellaneous base, cementation, content and pore space changes closely related with diagenetic features of carbonate cementation, siliceous cementation, albitization, clay cementation and sandstone dissolution.
For now the pH value of the formation water distortion, this paper established the acetic acid dissolution balance model, the application of organic acid recovery act of formation water in situ pH value, this method have certain limitation, it only applies to with organic acid decomposition for main buffer system formation. Through the recovery and measured the pH value of the comparison, its distribution area of the recovery pH value than the measured pH value is small to narrow. At the same time, use after restoring pH value income obtained the hydrogen ions concentration of dissolved feldspar with the contractor, reaction equilibrium constant comparison dissolution of feldspar, the dissolved state judge found in with organic acid decomposition for the main buffer system stratum, feldspar dissolved in balance.
Through reseach the hydrochemistry characteristic and diagenesis characteristics, this process was mainly because potassium ion concentration of exorbitant prompting smectite and kaolinite to illite transformation in the middle-shallow strata of northern songliao basin. Formation water calcium and magnesium ions concentration change characteristics and carbonate cementation, the formation process of the corresponding with northern songliao basin in the diagenetic evolution characteristics of shallow calcite is consistent.
Formation water sodium ions mineralization mechanism and chloride ions similar are mainly evaporation and concentration effect, it provides a rich source for potash feldspar and calcium feldspar albitization.
引文
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