二取代基二硫代磷酸金属配合物及其混配物的合成、表征、晶体结构和杀菌活性研究
|
摘要
论文以五硫化二磷和醇或酚类化合物为主要原料，通过固—液和固—固反应合成了一系列新的含有P、S、O和N的过渡金属配合物，即O，O’—二烷基二硫代磷酸和O，O’—二芳基二硫代磷酸金属配合物，及其与中性配体的混配物。取代基涉及了乙基、异丙基、环己基、氯乙基、烯丙基、苄基、苯基、对甲苯基、对氯苯基、α—萘基、2，4—二硝基苯基十一种；用到的含氮或其它配位原子的中性配体有：咪唑(Im)、吡啶(Py)、α—氨基吡啶(Apy)、2，2’—联吡啶(2BiPy)、4，4’—联吡啶(4BiPy)、乙二胺(En)、1，10—菲咯啉(Phen)和三苯基膦(PPh_3)七类。采用元素分析、红外光谱、UV—vis电子光谱、核磁共振技术和热分析的分析手段对合成的产物进行了表征。
借助单晶X射线衍射技术，解析合成的配合物的单晶结构，并首次报道了其中的九种配合物的晶体结构。
配合物[Ni(p-tolyl_2-DTP)_2Phen]的晶系是三斜，空间群是P(-)1，晶胞参数α=1.11819(2)nm，b=1.20934(2)nm，c=1.72860(2)nm，α=107.693(1)°，β=96.349(1)°，γ=109.896(1)°，d_(calcd)=1.401Mg／m~3，Z=2。Ni是六配位的，六个配位原子分别来自两个DTP二齿配体的四个S原子和邻菲咯啉配体中的两个N原子。整个配合物的分子呈现出围绕在中心Ni原子周围的扭曲的八面体几何构型。
{[Cu(Ⅱ)(En)_2](Et_2-DTP)_2}的晶系是单斜，空间群为P21／c，晶胞参数α=1.46683(3)nm，b=0.69409(1)nm，c=1.35889(1)nm，α=90°，β=111.157(1)°，γ=90°，d_(calcd)=1.426Mg／m~3，Z=2。铜(Ⅱ)分别和来自两个乙二胺的四个氮原子构成相同的Cu-N键，形成了两个以Cu(Ⅱ)为中心呈四边形构型的CuN4。分子中的dtp作为阴离子中和分子中配位中心的二价铜。分子内存在着N-H…S型分子氢键。
{[Ni(Im)_6](iPr_2-DTP)_2}分子处于单斜晶系，空间群为C 2／c，α=2.47585(4)nm，b=1.14460(2)nm，c=1.65815(1)nm，α=90°，β=112.689(1)°，γ=90°。Z=4，d_(calcd)=1.369 Mg／m~3。Ni(Ⅱ)位于对称的八面体的六咪唑合镍中心，外围分布着两个一价的O，O’—二异丙基二硫代磷酸根离子。晶胞堆积中存在着N-H…S型分子内氢键、分子间氢键和S2…S2型分子间作用力。
双核配合物[Ag_2(allyl_2-DTP)_2(Phen)_2]的晶系是单斜，空间群为P1，晶胞参数α=0.9828(2)nm，b=1.0950(2)nm，c=1.1187(2)nm，α=68.31(3)°，β=74.95(3)°，γ=65.05(3)°，Z=2。二聚物的晶体结构中，每个银原子分别与来自Phen的两个N原子和来自两个O，O’—二(烯丙基)二硫代磷酸配体的两个S原子配位，形成
中文摘要
博士论文
了四面体构型;同时两个银原子相互作用形成Ag一Ag弱的作用力一‘(键)，从而整
个分子呈现双四面体几何构型SZNZAg--A叨252。
[Ni(iPrZ一DTP)2(APy)21晶系单斜，空间群为p 21/n，晶胞参数a=0.66296(1)nm，
b=1 .63605(2)nm，c=1.46386(2)nm，a=900，刀=99.938(l)o，尹=900，Z=20
Ni(n)离子位于配位中心NINZS4的对称中心，生色团NINZS4的晶体构型是八
面体几何构型。
[Zn(功(iPrZ一DTP)ZPhen]单斜晶系，CZ/c空间群。晶胞参数a=1 .93 15(4)nm，b
== 1 .0438(2)nm，c=1.6567(3)nm，a=900，刀=102.89(3)“，夕=900，Z=4。Zll(11)
原子周围有两个来自邻菲咯琳(P hen)的N原子和分别来自两个口，a一二异丙
基二硫代磷酸根(D仰)的S原子与其配位成键，四配位的Zn的配位环境呈现的
是扭曲的四面体几何构型。
配合物[M(功(iPr-D开)ZPhen](M=Ni、Cd、FC)均结晶在正交晶系，空间群为
Pbcn，Z二4。M(n)是六配位的，分别与来自两个DTP配体的四个S原子和来
自Phen的两个N原子配位成键形成MNZS4的生色团，配合物是扭曲的八面体几
何构型。
最后，借助金黄色葡萄球菌、大肠杆菌和枯草杆菌，测定了.口，口’一二取代
基二硫代磷酸金属配合物及其与中性配体的混配物的杀菌活性。
关键词:二取代基二硫代磷酸金属配合物，合成，晶体结构，表征，杀菌活性
Novel coordination compounds containing P, S, O, N atoms, named transition metal 0,0'- di-substituent dithiophosphates and their mixed complexes with neutral ligands, have been synthesized by the main reactants of P2S5 and alcohol or phenols through solid-liquid phase and solid-solid phase reactions. The used substituents cover iso-propyl (iPr), ethyl (Et), cyclohexyl, allyl, p-tolyl, benzyl (Ph); p-chlorophenyl, 2,4-di-nitrophenyl, a-naphthyl; the neutral ligands containing nitron or other coordination atoms consist of imidazole (Im), pyridine (Py), a-aminopyridine (Apy), 2, 2'-bipyridine (2BiPy), 4, 4'-bipyridine (4BiPy), 1, 10-phenanthroline (Phen), ethylenediamine (En), and triphenylphosphine (PPh3). Metal O, O' -di-substituent dithiophosphates and their mixed complexes were characterized by Infrared spectra (IR), elemental analysis (EA), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and ultraviolet-visible (UV-vis) spectrophotometry analysis. Single crystals have been determinated by means of X-ray single crystal diffraction, among twenty two sorts of single crystals, nine structures of new complexes with mixed ligands were first reported. The main results were studied as follows:[Ni(p-tolyl2-DTP)2Phen] cystallizes as green prisms in the triclinic crystal system, space group P(-)l, with unit cell parameters a = 1.11819(2) nm, b = 1.20934(2) nm, c = 1.72860(2) nm, α = 107.693(1)°, β= 96.349(1)°, γ= 109.896(1)°. The calculated density is 1.401 Mg/m3 for Z = 2 molecules/unit cell. Nickel atom is coordinated through four S atoms from DTP groups and two N atoms from Phen, forming a distorted octahedron.Blue prisms of {[Cu(n)(En)2](Et2-DTP)2} were crystallized in the monoclinic crystal system, space group of P21/c, with unit cell parameters a = 1.46683(3) nm, b = 0.69409(1) nm, c = 1.35889(1) nm, α= 90°, β= 111.157(1)°, γ=90°. The calculated density is 1.426 Mg/m3 for Z = 2 molecules per unit. Chelated to the copper atom through four N atom are two ethylenediamine groups, forming a square geometry of CuN4. The DTP groups of molecule around the coordination center neutralize the charge of Cu (E) as anions. A network structure of {[Cu(II)(En)2](Et-DTP)2} is formed through the intermolecular hydrogen bonds of N-H ...S.The compound of {[Ni(Im)6](iPr2-DTP)2} crystallizes in the monoclinic space
group C 2/c, with a = 2.47585(4) nm, b = 1.14460(2) nm,c = 1.65815(1) nm, α= 90°, β= 112.689(1)°, γ= 90°, Z=4, and calculated density 1.369 Mg/m3 at 293 (2) K. The coordination around the Ni atom, located in an inversion center, is octhaheral with all positions being occupied by tertiary N atoms of the imidazole moieties. Two O, O '-diisopropyl dithiophosphorous anions lie around the NiN6 center.The dimeric compound of [Ag2(allyl2-DTP)2(Phen)2] forms colorless multihydrogen in the monoclinic space group P1, with unit cell parameters a = 0.9828(2) nm,. b = 1.0950(2) nm, c = 1.1187(2) nm, a= 68.31(3)°, β= 74.95(3)°, γ= 65.05(3)°, Z = 2. The crystal structure is comprised of one independent dimer containing two coordination centers. Each Ag atom is coordinated through one of two S atoms from one DTP groups, respectively, and two N atoms from Phen. A double tetrahedral geometry of S2N2Ag-AgN2S2 is bridged through the weak silver-silver interaction.The crystalline compound [Ni(/Pr2-DTP)2(Apy)2] is formed in the monoclinic space group P21/n, with unit cell parameters a = 0.66296(1) nm, b = 1.63605(2) nm, c = 1.46386(2) nm, α= 90°, β = 99.938(1)°, γ = 90°, Z = 2. The Ni atom is located in the coordination center of the chromophore, NiN2S4, forming an octahedral geometry.The complex [Zn(n)(/Pr2-DTP)2Phen] is crystallized in the monoclinic space group C2/c. The unit cell parameters are a = 1.9315(4) nm, b = 1.0438(2) nm, c = 1.6567(3) nm, α= 90°, β= 102.89(3)°, γ= 90°, and the calculated density 1.371 Mg/m3 (for Z = 4). The four-coordinated Zn atom is bonded to two N atoms from the Phen ligand and two S atoms from two DTP groups, leading to the disto
借助单晶X射线衍射技术，解析合成的配合物的单晶结构，并首次报道了其中的九种配合物的晶体结构。
配合物[Ni(p-tolyl_2-DTP)_2Phen]的晶系是三斜，空间群是P(-)1，晶胞参数α=1.11819(2)nm，b=1.20934(2)nm，c=1.72860(2)nm，α=107.693(1)°，β=96.349(1)°，γ=109.896(1)°，d_(calcd)=1.401Mg／m~3，Z=2。Ni是六配位的，六个配位原子分别来自两个DTP二齿配体的四个S原子和邻菲咯啉配体中的两个N原子。整个配合物的分子呈现出围绕在中心Ni原子周围的扭曲的八面体几何构型。
{[Cu(Ⅱ)(En)_2](Et_2-DTP)_2}的晶系是单斜，空间群为P21／c，晶胞参数α=1.46683(3)nm，b=0.69409(1)nm，c=1.35889(1)nm，α=90°，β=111.157(1)°，γ=90°，d_(calcd)=1.426Mg／m~3，Z=2。铜(Ⅱ)分别和来自两个乙二胺的四个氮原子构成相同的Cu-N键，形成了两个以Cu(Ⅱ)为中心呈四边形构型的CuN4。分子中的dtp作为阴离子中和分子中配位中心的二价铜。分子内存在着N-H…S型分子氢键。
{[Ni(Im)_6](iPr_2-DTP)_2}分子处于单斜晶系，空间群为C 2／c，α=2.47585(4)nm，b=1.14460(2)nm，c=1.65815(1)nm，α=90°，β=112.689(1)°，γ=90°。Z=4，d_(calcd)=1.369 Mg／m~3。Ni(Ⅱ)位于对称的八面体的六咪唑合镍中心，外围分布着两个一价的O，O’—二异丙基二硫代磷酸根离子。晶胞堆积中存在着N-H…S型分子内氢键、分子间氢键和S2…S2型分子间作用力。
双核配合物[Ag_2(allyl_2-DTP)_2(Phen)_2]的晶系是单斜，空间群为P1，晶胞参数α=0.9828(2)nm，b=1.0950(2)nm，c=1.1187(2)nm，α=68.31(3)°，β=74.95(3)°，γ=65.05(3)°，Z=2。二聚物的晶体结构中，每个银原子分别与来自Phen的两个N原子和来自两个O，O’—二(烯丙基)二硫代磷酸配体的两个S原子配位，形成
中文摘要
博士论文
了四面体构型;同时两个银原子相互作用形成Ag一Ag弱的作用力一‘(键)，从而整
个分子呈现双四面体几何构型SZNZAg--A叨252。
[Ni(iPrZ一DTP)2(APy)21晶系单斜，空间群为p 21/n，晶胞参数a=0.66296(1)nm，
b=1 .63605(2)nm，c=1.46386(2)nm，a=900，刀=99.938(l)o，尹=900，Z=20
Ni(n)离子位于配位中心NINZS4的对称中心，生色团NINZS4的晶体构型是八
面体几何构型。
[Zn(功(iPrZ一DTP)ZPhen]单斜晶系，CZ/c空间群。晶胞参数a=1 .93 15(4)nm，b
== 1 .0438(2)nm，c=1.6567(3)nm，a=900，刀=102.89(3)“，夕=900，Z=4。Zll(11)
原子周围有两个来自邻菲咯琳(P hen)的N原子和分别来自两个口，a一二异丙
基二硫代磷酸根(D仰)的S原子与其配位成键，四配位的Zn的配位环境呈现的
是扭曲的四面体几何构型。
配合物[M(功(iPr-D开)ZPhen](M=Ni、Cd、FC)均结晶在正交晶系，空间群为
Pbcn，Z二4。M(n)是六配位的，分别与来自两个DTP配体的四个S原子和来
自Phen的两个N原子配位成键形成MNZS4的生色团，配合物是扭曲的八面体几
何构型。
最后，借助金黄色葡萄球菌、大肠杆菌和枯草杆菌，测定了.口，口’一二取代
基二硫代磷酸金属配合物及其与中性配体的混配物的杀菌活性。
关键词:二取代基二硫代磷酸金属配合物，合成，晶体结构，表征，杀菌活性
Novel coordination compounds containing P, S, O, N atoms, named transition metal 0,0'- di-substituent dithiophosphates and their mixed complexes with neutral ligands, have been synthesized by the main reactants of P2S5 and alcohol or phenols through solid-liquid phase and solid-solid phase reactions. The used substituents cover iso-propyl (iPr), ethyl (Et), cyclohexyl, allyl, p-tolyl, benzyl (Ph); p-chlorophenyl, 2,4-di-nitrophenyl, a-naphthyl; the neutral ligands containing nitron or other coordination atoms consist of imidazole (Im), pyridine (Py), a-aminopyridine (Apy), 2, 2'-bipyridine (2BiPy), 4, 4'-bipyridine (4BiPy), 1, 10-phenanthroline (Phen), ethylenediamine (En), and triphenylphosphine (PPh3). Metal O, O' -di-substituent dithiophosphates and their mixed complexes were characterized by Infrared spectra (IR), elemental analysis (EA), nuclear magnetic resonance (NMR), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and ultraviolet-visible (UV-vis) spectrophotometry analysis. Single crystals have been determinated by means of X-ray single crystal diffraction, among twenty two sorts of single crystals, nine structures of new complexes with mixed ligands were first reported. The main results were studied as follows:[Ni(p-tolyl2-DTP)2Phen] cystallizes as green prisms in the triclinic crystal system, space group P(-)l, with unit cell parameters a = 1.11819(2) nm, b = 1.20934(2) nm, c = 1.72860(2) nm, α = 107.693(1)°, β= 96.349(1)°, γ= 109.896(1)°. The calculated density is 1.401 Mg/m3 for Z = 2 molecules/unit cell. Nickel atom is coordinated through four S atoms from DTP groups and two N atoms from Phen, forming a distorted octahedron.Blue prisms of {[Cu(n)(En)2](Et2-DTP)2} were crystallized in the monoclinic crystal system, space group of P21/c, with unit cell parameters a = 1.46683(3) nm, b = 0.69409(1) nm, c = 1.35889(1) nm, α= 90°, β= 111.157(1)°, γ=90°. The calculated density is 1.426 Mg/m3 for Z = 2 molecules per unit. Chelated to the copper atom through four N atom are two ethylenediamine groups, forming a square geometry of CuN4. The DTP groups of molecule around the coordination center neutralize the charge of Cu (E) as anions. A network structure of {[Cu(II)(En)2](Et-DTP)2} is formed through the intermolecular hydrogen bonds of N-H ...S.The compound of {[Ni(Im)6](iPr2-DTP)2} crystallizes in the monoclinic space
group C 2/c, with a = 2.47585(4) nm, b = 1.14460(2) nm,c = 1.65815(1) nm, α= 90°, β= 112.689(1)°, γ= 90°, Z=4, and calculated density 1.369 Mg/m3 at 293 (2) K. The coordination around the Ni atom, located in an inversion center, is octhaheral with all positions being occupied by tertiary N atoms of the imidazole moieties. Two O, O '-diisopropyl dithiophosphorous anions lie around the NiN6 center.The dimeric compound of [Ag2(allyl2-DTP)2(Phen)2] forms colorless multihydrogen in the monoclinic space group P1, with unit cell parameters a = 0.9828(2) nm,. b = 1.0950(2) nm, c = 1.1187(2) nm, a= 68.31(3)°, β= 74.95(3)°, γ= 65.05(3)°, Z = 2. The crystal structure is comprised of one independent dimer containing two coordination centers. Each Ag atom is coordinated through one of two S atoms from one DTP groups, respectively, and two N atoms from Phen. A double tetrahedral geometry of S2N2Ag-AgN2S2 is bridged through the weak silver-silver interaction.The crystalline compound [Ni(/Pr2-DTP)2(Apy)2] is formed in the monoclinic space group P21/n, with unit cell parameters a = 0.66296(1) nm, b = 1.63605(2) nm, c = 1.46386(2) nm, α= 90°, β = 99.938(1)°, γ = 90°, Z = 2. The Ni atom is located in the coordination center of the chromophore, NiN2S4, forming an octahedral geometry.The complex [Zn(n)(/Pr2-DTP)2Phen] is crystallized in the monoclinic space group C2/c. The unit cell parameters are a = 1.9315(4) nm, b = 1.0438(2) nm, c = 1.6567(3) nm, α= 90°, β= 102.89(3)°, γ= 90°, and the calculated density 1.371 Mg/m3 (for Z = 4). The four-coordinated Zn atom is bonded to two N atoms from the Phen ligand and two S atoms from two DTP groups, leading to the disto
引文
1．游效曾，孟庆金，韩万书编。配位化学进展。第一版。北京：高等教育出版社，2000。
2．徐光宪，21世纪的配位化学是处于现代化学中心地位的二级学科。北京大学学报(自然科学版)，2002，38(2)：149-151。
3．孟庆金，戴安邦编，配位化学的创始与现代化。第一版。北京：高等教育出版社，1998。
4．Basolo Fred,Johnson Ronald C．著．宋银柱，王耕霖等译．配位化学．第一版．北京：北京大学出版社，1982．
5. Swiegers F, Malefetse T.J., Classification of coordination polygons and polyhedra according to their mode of self-assembly. 2. Review of the literature. Coord. Chem. Rev. 2002, 225: 91-121.
6. Alvarez S., Palacios A.A., Aullon G., Ligand orientation effects on metal-metal, ligand-ligand and metal-ligand interactions. Coord. Chem. Rev. 1999, 185-186.
7. Ouahab L., Coordination complexes in conducting and magnetic molecular materials. Coord. Chem. Rev. 1997, 165: 475-567.
8. Ward M.D., The coordination chemistry of macrocyclic ligands. Annu. Rep. Prog. Chem., Sec. A: Inorg. Chem. 1990, 87: 303-309.
9. Barigelletti E, Flamigni L., Photoactive molecular wires based on metal complexes. Chem. Soc. Rev., 2000, 29(1): 1-12.
10. Raper E.S. Complexes of heterocyclic thionates. Part 1: Complexes of monodentate and chelating ligands. Coord. Chem. Rev., 1996, 153: 199-255.
11. Costamagna J., Ferraudi G., Matsuhiro B., Campos-Vallette M, Canales J., Villagran M., Vargas J., Aguirre M. J., Complexes of macrocycles with pendant arms as models for biological molecules. Coord. Chem. Rev. 2000, 196: 125-164.
12. Jeffrey George A., Huang Dc-bin. Hydrogen bonding in the crystal structure of the tetrasaccharide stachyose hydrate: 1:1 complex of the conformers. Carbohydrate Research., 1990, 210: 89-104.
13
13．王夔主编，生命科学中的微量元素．第一版．北京：中国计量出版社，(上卷)：1991；(下卷)：1992
14．Ochiai E-I著．罗锦新，张乃正，陈汉文译．生物无机化学导论．第一版．北京：化学工业出版社，1987
15．龚钰秋．混合配体络合物化学．第一版．北京：高等教育出版社，1991
16. Laidler K.J., Physical chemistry with biological applications, Frntiers of Chemistry. Pergamon Press, 1981.
17．任杰，陈志达，分子磁性的量子化学研究进展，无机化学学报．2002，18(8)．-753-760
18．邝代治，冯泳兰茂金属配合物[Mo(eta~5—C_5H_4Si_2Me_5)(CO)_3Cl]的晶体结构和量子化学研究，无机化学学报．2002，18(4)．-394-398
19．李林涛，麻生明，以N—杂环卡为配体的金属络合物催化有合成的反应，有机化学．2001，21(1)．75-81
20．翁文，曾庆乐，手性高分子金属络合物在不对称催化中的应用，高分子通报：2000，(3)50-55，68
21．张玉玲，阮文娟，金属络合物催化剂在不对称氮杂环丙烷反应中的研究进展，应用化学．2002，19(3)．-205-211
22．张玉良，钱明星等，过渡金属络合物催化乙烯齐聚，应用化学．2001，18(5)．360-364
23．唐黎明，吴丹，高分子金属络合物催化剂的合成及其催化氢化的应用，高分子材料．1996，3(3)．-34-37，45
24．燕远勇，金子林，水溶性过渡金属络合物催化两相氢甲酰化反应新进展，煤炭转化．1994，17(1)．-58-63
25．王荣民，王云普，高分子类卟啉金属配合物催化活化分子氧研究，西北师范大学学报：自然科学版．2000，36(1)．-100-103
26．王荣民，索继栓，分子筛基类卟啉金属络合物模拟生物氧化催化作用，精细石油化工．2000，(2)．-48-51
27．俞晓东，苯酚双氧水羟基化反应催化剂研究进展，化工生产与技 术．2000，7(5)．-23-25
28
28．王素青，过渡金属络合物催化的不对称氢硅烷化反应，昌潍师专学报．1997，16(5)．-6-9
29．张振学，杨松松，黄酮金属络合物作为潜在药物的研制与开发，中草药．1996，27(3)．-179-181
30．刘晶莹，王国清，王鸿刚，金属配台物抗癌活性的研究进展，化学试剂，2003，25(5)，274-276；295
31．李勤喜，王流芳，刘映琦，王印月，维甲酸镍配合物(Ni(RA)2·3H2O)抗白血病HL-60细胞的研究，厦门大学学报：自然科学版．2003，42(6)．-795-799
32. Hodnett E.M., Dunn W.J., Cobalt derivatives of Schiff bases of aliphatic amines as antitumor agents. J Med Chem, 1972,15(3):339.
33．李桂芝，2种水杨醛缩氨基酸及其10种金属配合物的杀菌活性研究，聊城大学学报：自然科学版．2003，16(1)．-57-59
34. Bonson, D., Mechanisms of Inorganic Reaction in Solution, McGraw-Hill. New York. 1968.
35. Just O., Gaul D.A., Rees Jr.W.S. Low-coordinate volatile group 12 amides: syntheses and crystal structure determinations of dimeric {M{N[Si(CH_3)_2CH_2CH_2Si(CH_3)_2]}_2}_2; M = Zn, Cd and monomeric Hg{N[Si(CH_3)_2CH_2CH_2Si(CH_3)_2]}_2. Polyhedron. 2001, 20:815-821.
36. Xiong R-G., Song B-L., You X-Z., Syntheses and properties of some transition metal complexes with methyl substituted 1-hydroxy-2(1H)-pyridinethione and crystal structure of bis(1-hydroxy-4-methyl-2(1H)-pyridinethionato-O,S') zinc (Ⅱ). Polyhedron. 1996, 15(5): 991-996.
37. Richburg L.M., Farouq J.A., Incarvito C.D., Arnold L., Rheingold, R.D., Zinc bis(pyrazoly) silane complexes. Polyhedron. 2000, 19:1815-1820.
38. Darensbourg D.J., Yarbrough J.C., Synthesis and crystal structure of [H_2B(3-Phpz)_2]_2Zn. J. Organometal Chem. 2000, 614-615: 305-308.
39. Sahin E., Ide S., Kurt M., Yurdakul S. Structural investigation of dibromobis (benzimidazole) Zn(Ⅱ) complex. J. Molecular Structure. 2002, 616: 259-264.
40. Mareque Rivas J.C., Martin de Rosales R.T., Parsons S., Internal hydrogen bonding and amide co-ordination in zinc (Ⅱ) complexes of a tripodal N4 ligand: structural, spectroscopic and reactivity studies. J. Chem. Soc. Dalton Trans. 2003:2156-2163.
41. Cheng B, Scheidt W.R., Stereochemistry of aquo (5,10,15,20-tetra phenylporphinato) zinc(Ⅱ) as its 18-crown-6, methylene chloride solvate. Inorg. Chim. Acta. 1995, 237: 5-11.
42. Dell'Amico D.B., Boschi D., Calderazzo F., Labella L., Marchetti F., Synthesis, and crystal and molecular structures of the triflato and trifluroacetato complexes of zinc, Zn(O_3SCF_3)_2(DME)_2 and [Zn(O_2CCF_3)_2(DME)]_n. Inorg. Chim. Acta. 2002, 330: 149-154.
43. Jian, F. F., Hao, Q. L., Yang, X., Lu, L., Wang, Xin., Structure of bis(O' O-diisopropyl dithiophosphato-s, s') (1,10-Phenanthroline-N1, N10) zinc(Ⅱ) complex, [Zn(phen)(S_2P(OiPr)_2)_2]. J. Chem. Crystallogra. 2000, 30(7): 469-472.
44. Lindoy, L.E, The chemistry of macrocyclic ligand complexes. Cambridge University Press, 1999.
45. Stiefel, E.I., The structures and spectra of molydoenxyme active sites and their models. Prog. Inorg. Chem. 1977, 1: 22-26.
46. Hagan, K.S., Watson, A.D., Holm, R.H., Systematic stereochemistry of metal (Ⅱ) thiolates: systematic structures of [M_2(SC_2H_5)_6]~(2-) (M = Mn, Ni, Zn, Cd). Inorg. Chem. 1984, 23: 2984-2988.
47. Holm, R.H., Synthetic analogs of the active sites of iron-sulfur proteins and enzymes and their relevance to dinitrogen fixation, Chem. Soc. Rev. 1981, 10: 455-459.
48．百熙编著．浮药选剂．第一版．北京：冶金工业出版社，1981，192．
49．邓玉珍，选矿药剂概括．北京：冶金工业出版社，1981．
50. Holm R.H., Kennepohl E, Solomon E.I., Structural and functional aspects metal sites in biology. Chem. Rev. 1996, 96: 2239-2314.
51. Mingionc Phillip A., Use of dialkyl and diaryl dithiophosphate promoters as mineral flotation agents. Reagents Miner. Ind. Pap. 1984:19-24
52. Soedinenii Khim i. Primenenie Fosfororg, Organophosphorus in secticides. Akad. Nauk S.S.S.R Trudy, 1-0I, Konferents. 1995: 148-63.
53. Mohan KR., Ramesh A., Seshaih K., Extractive fluorimetric determination of malathion residues in water samples. Analyst, 2000, 125 (2): 323-326
54. Chen W.B., Jin G.Y., Synthesis and biological activities of O, O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds. Phosphorus Sulfur and Silicon and the Related Elements, 2003, 178 (2): 311-317
55. Chen W.B., Jin G.Y., Syntheses and biological activities of S-1,2,4-triazolo[1,5-a]pyrimidinylalkyl dithiophosphates. Heteroatom Chem., 2003, 14 (7): 607-611
56. Haiduc, I.; Bryan-Sowerby, D.; Lu S. F., Stereochemical aspects of phosphor-l,l-dithioato metal complexes (dithiophos phates, dithiophosphinates): coordination patterns, molecular structures and supramolecular associations-I. Polyhedron, 1995, 14, 3389.
57. Jones, J.R.; Symes, T.J. Linear dimerization of 1-olefine catalyzed by complexes of nickel β-diketonates and aluminum alkyls. J. Chem. Soc., C, 1971, 1124-1130.
58. Howard J.A., Yamada T., Metal complexes as antioxidants. 9. Application of the spin scavenging technique to the reaction of transition metal dialkyldithiophosphates and dialkyldithiocarbamates with tertiary alkyl hydroperoxides, Can. J. Chem. 1982 (60): 224-228.
59. Kovtun G.A., Zhukovskaya G.B., Kratko G.A., Sukhoveev V.V., Antioxidative properties of metal bis(dialkyldithiophosphates) in lubricant oils: effect of metal\ nature and stoichiometry of alkyl substituents. Dokl. Akad. Nauk Ukr. SSR. 1991(4): 105-107.
60. Tarasova Z.N., Senatorskaya L.G., Fedorova T.V., Eitingon I.I., Kirpichnikov RA., Kavun S.E, Dogadkin B.A., Effect of the structure of a vulcanization network on aging and fatigue of rubbers. Kauchuk I Rezina, 1965, 24(7): 5-10.
61．李克华，周玉贺，吴振烈，二硫代磷酸硫化氧钼与硫、磷添加剂的复配特性研究．石油炼制与化工。1995，26(10)：43-48
62. So H., Lin Y.C., Huang GS, Chang S.T., Antiwear mechanism of zinc dialkyl dithiophosphates added to a paraffmicoil in the boundary lubrication condition, wear, 1993(166): 17-23
63. Lohr Delmar FJr., Kay Eward L., Berth Harry J., High-temperature stabilization of 1, 2-polybutadiene resins. J. Soc. Plast. Eng., Tech. Pap. 1974(20): 647-650.
64. Vinogradov GV., Soedinenii Khim. I Primenenie Fosfororgan., Application and mechanism of organophosphorus compounds as antiwear additives to oils. Akad. Nauk S.S.S.R., Trudy 1-01 Konferents. 1995: 124-147
65. Wakefield C.C., Cragg John C, Zinc dialkyl thiolthionophosphates for use as lubricant additives. Brit. 822655, Oct. 28, 1959.
66. Okamura Nobuyuki, Hojo Masahiro, Pnenumatic tires with styrene-butadinee rubber tread. Eur. Pat. Appl. Ep832920, (1998)
67. Evstaf ev V.P,, Kononova E.A., Levin A.Y., Trofimova G.L., Ivanova O.V., A new dithiophosphate additive for lubricating oils. Chem. Tech. Fuels Oils. 2001, 37 (6): 427-431
68. Rossi A., Eglin M., Piras F.M., Matsumoto K., Spencer N.D., Surface analytical studies of surface-additive interactions, by means of in situ and combinatorial approaches. WEAR, 2004, 256 (6): 578-584
69. Ye J.P., Kano M., Yasuda Y., Evaluation of nanoscale friction depth distribution in ZDDP and MoDTC tnbochemical reacted films using a nanoscratch method. Tribol. Lett., 2004, 16(1-2): 107-112
70. Muraki M., Wada H., Influence of the alkyl group of zinc dialkyldithiophosphate on the frictional characteristics of molybdenum dialkyldithiocarbamate under sliding conditions. Tribol. Intern. 2002, 35 (12): 857-863
71. Kovtun GA., Zhukovskaya GB., Kretko GA., Sukhoveev, V.V., Effect of structure of metal dialkyl dithiophosphate on their antioxidative properties in lubricating oils. Neftepererab. Neftekhim. 1992(42): 39-41
72. Hu X.G., Study of friction and wear performance of zinc dialkyldithiophosphate in the presence of trace ketone. Tribol. Lett., 2002,12 (1): 67-74
73. Wan Yong, Cao Lili, Xue Qunji, Friction and wear characteristics of ZDDP in the sliding of steel against aluminum alloy. Tribol. Inter. 1998, 30(10): 762-772
74. Breytenbach W., Vermaak M.K.G., Davidtz J.C., Synergistic effects among dithiocarbonates (DTC), dithiophosphate (DTP) and trithiocarbonates (TTC) in the flotation of Merensky ores. Journal Of The South African Institute Of Mining And Metallurgy. 2003, 103 (10): 667-670
75. Shlepnina T.G, Hygienic significance and standardization of hydrobyzed butyl flotation reagent in water reservoirs. Gig. Sanit. 1971, 36(7): 14-19.
76.邓玉珍，选矿药剂概括.北京:冶金工业出版社，1981.
77. Piantadosi C, Jasieniak M., Skinner W.M., Smart R.S.C., Statistical comparison of surface species in flotation concentrates and tails from TOF-SIMS evidence. Miner. Engineering 2000, 13 (13): 1377-1394
78. Tian G.X., Zhu Y.J., Xu J.M., Zhang P., Hu T.D., Xie Y.N., Zhang J., Investigation of the extraction complexes of light lanthanides(III) with bis(2,4,4-trimethylpentyl)dithiophosphinic acid by EXAFS, IR, and MS in comparison with the americium(HI) complex. Inorg. Chem., 2003, 42 (3): 735-741
79. Ertelt Henry R., Wythe Stephen L., Furey Michael J., Appeldoorn John K., Metal chelates of dialkyl dithiophosphoric acids for recovery and determination of heavy metals. U.S. 2976122. March. 21, 1961
80. Rickelton W.A., Novel uses for thiophosphinic acids in solvent-extraction. Jom-J Min.Met. Mat. Soc. 1992, 44(5): 52-54
81. Rickelton W.A., Boyle R.J., The selective recovery of zinc with new thiophosphinic acids. Solvent Extr. Ion Exc. 1990, 8(6): 783-797
82. Rickelton W.A., The removal of cadmium impurities from cobalt-nickel solutions by precipitation with sodium diisobutyldithiophosphinate. Hydrometallurgy 1998, 50 (3): 339-344
83. Aliev V.S., Aliev S.M., Azizov A.G., Mamedaliev G.A., Nasirov F.A., Ismailov T.A., Kruchinina V.M., Dzhanibekov N.F., Gol'berg I.P., Organoaluminum compounds and transition metal dithiophophates as catalysts for polymerization of dienes. PCT Int. Appl. WO 91 02,587. Mar. 07 1991.
84
84. Porta P., Sgamellotti A., Vinciguerra N., The crystal and molecular structure of bis(diphenyl dithiophosphato) nickel (Ⅱ). Inorg. Chem. 1968, 7(12): 2625-2629
85. Lawton Stephen L., Kokotailo George T., The crystal and molecular structure of polymeric lead (Ⅱ) O,O'—diisopropylphosphorodithioate, Pb[(I-C_3H_7O)_2PS_2]_2. Deformation of a hexathiocoordinate lead group by a stereochemically active lone pair of electrons, Inorg. Chem., 1972. 11(2): 363-368
86. Drew Michael G.B., Hopkins W.A., Mitchell P.C.H., Colclough T., Preparation, properties, and X-ray crystal structure of tris (O,O'-diisopropyl phosphorodithioato) iron (Ⅲ), [Fe{S_2P(OPr~i)_2}_3]. Comparison of structure and bonding in phosphorodithioato- and dithiocarbamato- complexes. J. Chem. Soc. Dalton Trans. 1986 (2): 351-354
87. You X., Xu Z., Yu Y., Liu S., Lin C., Crystal structure of adduct of bis (O,O'-dibutyldithiophosphato) nickel (Ⅱ) with bipyridyl. J. Struct. Chem. 1986. 5(3): 154-158.
88．刘世雄，林墀昌，徐正，林建华，俞运鹏，游效曾，Ni[(C_6H_(11)O)_2PS_2]_2与吡啶加和反应平衡常数的测定及加合物的晶体结构．高等学校化学学报．1989．10(12)：1225-1228
89. Liu C., Liu S., Xu Z., Lin J., You X., Crystal and molecular structure of bis (O,O'-dicyclohexyl dithiophosphato) nickel (Ⅱ). J. Struc. Chem. 1987. 6(3): 186-188
90．徐正，俞运鹏，林建华，于秀华，游效曾，Ni[(C_6H_(11)O)_2PS_2]_2与氮碱加合反应的研究．无机化学学报．1990．6(1)：25-30
91. Shapiro P.J., Henling L.M., March R.E., Bercaw J.E., Hydrazido and 2,2'-dimethylhydrazido derivatives of permethylscandocene., Inorg. Chem. 1990 (29): 4560-4568
92. Nicholson T., Lombandi P., Zubieta J., Monomeric five-coordinate rhenium diazenide and hydrazido complexes with aromatic thiolate ligands, Polyhedron. 1987(7): 1577-1581
93. Latham J.A., Leigh G.J., The chemistry of dinitrogen redidues: the decomposition of hydrazide (1-) and hydrazide (2-) bond to titanium (Ⅳ). J. Chem. Soc. Dalton Trans., 1986:399-403
94. Sammes P.G., Yahioglu G., 1, 10-phenanthroline: a Versatile ligand. J. Chem. Soc. Rev., 1994, 23(5): 327-331
95．敬炳文，吴韬，张曼华，沈涛，功能性多吡啶配体的合成．高等学校化学学报．2000(3)：395-398
96．钱士雄，王恭明编著．非线性学-原理与进展．第一版．上海：复旦大学出版社，2001
97．张克从，王希敏．非线性光学晶体材料科学．第一版．北京：科学出版社，1996
98. Kanis D.R., Ratner M.A., Marks T.J., Design and construction of molecular assemblies with large second-order optical nonlinearitiee. Quantum Chemical Aspects. Chem. Rev. 1994, 94:195-242
99. Ramasesha S., Das P.K., Second harmonic generation coefficients in push-pull polyenes: a model exact study. Chem. Physics. 1990, 145:343-353
100. Henderson R.A., Leigh G.J., Pickett C.J., The chemistry of nitrogen-fixation and models for the reactions of nitrogenase. Adv. Inorg. Chem. Rad. 1983, 27:197-292
101. Thorneley R.N.F., Lowe D.J., The mechanism of nitrogen fixation and models for the reactions of nitrogenese. Molybdenum Enzymes. New York. 1985, 5:221-227
102. Pickett C.J., Ryder K.S., Tolarmin J.J., Electrochemical carbon-carbon coupling of cliazomethane ligands. J. Chem. Soc. Dalton Trans., 1986, 1453-1458
103. Henriksson H.A., The crystal structure of bis(imidazole) copper (Ⅱ) diacetate. Acta Crystallorg., B, 1977, B33(6): 1947-1950
104. Abuhijleh A.L., Woods C., Synthesis, crystal structure and superoxide dismutase mimetic activity of hexakis (N-methylimidazole) copper(Ⅱ) salicylate. Inorg Chem Commun. 2002, 5 (4): 269-273
105. Abuhijleh A.L., Woods C., Mononuclear copper (Ⅱ) salicylate imidazole complexes derived from copper (Ⅱ) aspirinate. Crystallographic determination of three copper geometries in a unit cell. Inorg Chem Commun, 2001, 4 (3): 119-123
106.AbdulGhani A.S., AbuHijleh A.L., Nahas N., et al. Hypoglycemic effect of copper(II) acetate imidazole complexes. Biol Trace Elem Res, 1996, 54 (2): 143-151
107.Abuhijleh A.L., Catalytic activities of the antitumour complex bis(acetato) bis(imidazole) copper(II) and bis(valproato) bis(imidazole) copper(II) for the oxidation of organic substrates. Polyhedron, 1996, 15 (2): 285-293
108.Abuhijleh A.L., Synthesis And Characterization Of Mononuclear Copper (II) Aspirinate Adducts With Imidazole And Its Methyl-Derivatives. Polyhedron, 1989,8 (23): 2777-2783
109.Abuijeh A.L., Woods C, Synthesis, spectroscopic and structural characterization of bis(acetato) tetrabis(imidazole) copper (II): a model complex for DNA binding. Inorg. Acta., 1992, 194(1): 9-14
110.Drew Micheal G.B., Hobson Richard J., Mumba Peter P.E.M., Rice David A., Crystal and molecular structure of [{Ag[S2P(OEt)2].PPh3}2]. J. Chem. Soc. Dalton Trans. 1987, 6: 1569-1571
111 .Drew Michael G.B., Forsyth George A., Hassan M., Hobson Richard J., Rice David A., Reactions of copper (II) with [S2P(OP)2]- (R = Et or Pri) and single-crystal X-ray studies of Cu[S2P(OEt)2].bipy and Cu[S2P(OEt)2].2PPh3. J. Chem. Soc. Dalton Trans. 1987 (5): 1027-1033
112.Hao Q.L., Yang X.J., Jian F.F., Lu L.D., Wang X., Razak LA., Chantrapromma S., Fun H.K., Bis(O,O'-diisopropyl dithiophosphato-S,S ') (l,10-phenanthroline-N,N ') metal(II) complexes with cadmium(II) and iron(II). Acta Crystallographica Section C-Crystal Structure Communications 2001, 57: 42-44
113.Jian F.F., Liu G.Y., Hao Q.L., Wang X., Synthesis and crystal structure of Cu(phen) (H2O)(2) center dot C104(phen = phenanthroline). Chinese Journal Of Inorganic Chemistry, 2003, 19 (4): 419-422
114.Hao Q.L., Jian F.F., Wang X., Razak LA., Shanmuga S., Raj S., Fun H.K., trans-Bis(2-aminopyridine-N)bis(O,O '-diisopropyl dithiophosphato-S,S ') nickel(II). Acta Crystallographica Section C-Crystal Structure Communications, 2001, 57: 160-161
115.Hao Q.L., Fun H.K., Chantrapromma S., Razak LA., Jian F.F., Yang X.J., Lu L.d., Wang X., Bis(O,O '-di-p-tolyldithiophosphato-S,S ') (l,10-phenanthroline-N,N ') nickel(II). Acta Crystallographica Section C-Crystal Structure Communications, 2001,57:717-718
116.Hao Q.L., Jian F.F., Yang X.J., Wang X., Razak LA., Raj S.S.S., Fun H.K., Hexakis(lH-imidazole-kappa N-3) nickel(II) bis[O,O '-diisopropyl dithiophosphate(l-)]. Acta Crystallographica Section C-Crystal Structure Communications, 2000, 56: 1431-1432
117.Fun H.K., Hao Q.L., Wu J., Yang X.J., Lu L.D., Wang X., Chantrapromma S., Razak LA., Usman A., Bis(ethylenediamine) copper (II) bis(O,O '-diethyl dithiophosphate), Acta Crystallographica Section C-Crystal Structure Communications, 2002, 58: m87-m88
118.Jian F.F., Hao Q.L., Yang X.J., Lu L., Wang X., Structure of bis(O,O '-diisopropyldithiophosphato-S,S') (1,10-phenanthroline-N-1 ,N-10) zinc(II) complex, [Zn(phen)(S2P(OiPr)2)2]. J. Chem. Crystallogra., 2000, 30 (7): 469-472
119.Gianini M., Caseri Walter R., Gramlich V., Suter Ulrich W., Synthesis and characterization of liquid platinum compounds. Inorg. Chim. Acta. 2000, 299: 199-208
120.Wystrach V.P., Hook E.O., Christopher G.L.M., Basic Zinc double salts of O,O'-dialkyl phosphorodithioic acids, J. Org. Chem. 1956, 21: 705-707
121.Zemlyanskii N.I., Drach B.S., Synthesis of salts of some O,O'-diaryl phosphorodithioates. Zh. Obshch. Khim. 1962, 32: 1962-1966
122.Kudrev A.G., Complexation in the copper(II)-ethylenediamine-heterocyclic diimine system. Zh. Neorg. Khim. 1994, 39(12): 2041-2046
123.Zimina K.I., Kotova G.G., Sanin P.I., Sher V.V., Kuz'mina G.N., The infrared absorption spectra of metal dialkyldithiophosphates. Neftekhimiya 1965, 5(4): 629-635
124.Shishkov A.N., Nikolov N.K., Infrared spectra of some bis(dialkoxy- and diaryloxyphosphinothioyl) disulfides. Nauch. Tr., Plovdivski Univ. Mat., Fiz., Khim., Biol. 1972, 10(3): 87-95
12
125．陈国珍，黄贤智等编著．紫外可见分光光度法(上册)．原子能出版社出版．北京：1987，p7～34
126. Ionel Haiduc, Rodica Micu-Semeniuc, Luminita Silaghi-Dumitrescu, Transition metal complexes of organothiophosphorus ligands. Ⅸ. Addaucts .of nickel alkoxyand phenoxyethyl phosphorodithioates with primary and tertiary mono- and diamines. Synth. React. Inorg. Met. Org. Chem., 1993, 23(10): 1629-1643
127．蔡正千编，热分析．高等教育出版社．北京：1990，102
128. Livingstone Stanley E. and Mihkelson Anu E., Metal chelates of biologically important compounds. Ⅱ. Nickel complexes of dialkyldithiophosphates and their adducts with nitrogen heterocycles. Inorg. Chem. 1970, 9(11), 2550.
129. Sheldrick, G.M. SHELXTL V5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA 1997
130. Siemens. SMART and SAINT. Area Detector Control and Integration Software. Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA. 1996
131. Sheldrick, G. M. (1996). SADABS. Program for Empirical Absorption Correction of Area Detector Data, University of Gttingen, Germany.
132. Sheldrick, G. M. SHELXTL-97. Program for crystal structure determination. University of Gttingen, Germany, 1997
133. Sheldrick, G. M. SHELXTL-97. Program for the refinement of crystal structures. University of Gttingen, Germany, 1997
134. Sheldrick, G. M. SHELXTL-97. Acta Crystallogr., Sect. A, 1990, 46:467
135. Siemens. XSCANA User's Manual, Version 2.1, Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1994
136. Wilson A.J., International Table for X-ray Crystallography, Vol. C. Kluwer Academic Publishers, Dordrecht: 1992, Table 6.1.1.4 (P500-502) and Table 4.2.6.8 (P219-222)
137. Chen H.W., Fackler Jr.J.P., Sulfur chelates. 30. Crystal and molecular structure of aryl xanthates. Bis(O-4-tert-butylphenyl dithiocarbonato) nickel (Ⅱ), Ni(S_2COC_6H_4-4-t-Bu)_2, tris(O-2,4,6-trimethylphenyl dithiocarbonato) Cobalt (Ⅲ), Co(S_2COC_6H_4-2,4,6-Me_3)_3, and Bis(O-2,4,6-trimethyl-phenyl dithiocarbonato) palladium (Ⅱ), Pd(S_2COC_6H_2-2,4,6-Me_3)_2. Inorg. Chem., 1978, 17(1): 22-26
13
138. Hoskins B.F., Tiekink E.R.T., Structure of bis(O,O'-diisopropyl phosphoro dithioato) nickel (Ⅱ), Ni[S_2P(O~iC_3H_7)_2]_2. Acta Cryst., 1985, C41:322-324
139. Arca M., Cornia A., Devillanova EA., Fabretti A.C., Isaia E, Lippolis V., Verani G., New perspectives in phosphonodithioate coordination chemistry. Synthesis and X-ray crystal structure of trans-bis-[O-ethyl (4-methoxyphenyl) phosphono dithioato] nickel(Ⅱ). Inorg. Chim. Acta, 1997, 262(1): 81-84
140. Xiong R.G, Liu C.M., Zuo J.L., Li H.Z., You X.Z., Fun H.K., Sivakumar K., A novel molecular channel: Thermal analyses and X-ray structure of [Ni(Et-XA)(2)center dot phen]center dot 3H(2)O (Et-XA equals ethylcarbonodithiolato-S,S', phen equals phenanthroline). Polyhedron, 1997, 16(13): 2315-2319
141. Huang X.Y., Xiong R.G., You X.Z., The adduct of bis(o,o'-diethyl dithiophosphato)nickel(Ⅱ) with 3-aminopyridine. Acta Cryst., 1995, C51: 2261-2263
142．刘世雄，林犀昌，徐正，余运鹏，游效曾，双-(O，O’-二正丁基二硫代磷酸酯)合镍-二吡啶加合物的晶体结构和分子结构．1987，5：369-373
143. Byrom C., Malik M.A., O'Brien P., White A.J.P., Williams D.J., Synthesis and X-ray single crystal structures of bis(diisobutyldithiophosphinato)cadmium(Ⅱ) or zinc(Ⅱ): Potential single-source precursors for Ⅱ/Ⅳ materials. Polyhedron, 2000, 19(2): 211-215.
144. Palopoli S.F., Geib S.J., Rheingold A.L., Brill T.B., Synthesis and modes of coordination of energetic nitramine ligands in copper(ⅱ), nickel(ⅱ), and palladium(ⅱ) complexes. Inorg. Chem. 1988, 27:2963-2971.
145. Vrabel V., Kell E., Garaj J., tris[Bis(ethylenediamine)copper(ⅱ)] poly [hexakis (mu-cyano) hexakis (mu-seleno-cyanato) hexacopper(ⅰ)], [Cu(Ⅱ)en_2]_3 [Cu6(I)(cn)6(secn)6]. Acta Cryst. 1995, C51: 1286-1288
146.Drew M.GB., Forsyth GA., Hasan M., Hobson R.J., Rice D.A., Reactions of copper(ii) with [S2P(oEt)2] or [S2P(oPr-i)2) and single-crystal x-ray studies of Cu[S2P(oEt)2].bipy and Cu[S2P(oEt)2].2PPh3. J. Chem. Soc. Dalton Trans. 1987, 5: 1027-1033
147Jeffrey GA., Maluszynska H., Mitra J., H-Bond classification. Int. J. Biol. Macromol. 1985, 7: 336-348
148.Jian RE, Wang Z.X., Bai Z.P., You X.Z., Fun H.K., Chinnakali K., Structure of hexakis(imidazole)nickel(II) disalicylate, [Ni(Im)(6)](Sal)2. J. Chem. Crystallogr., 1999, 29(3): 359-363
149.Wang Z., Zhang Y., Razak LA., Shanmuga Sundara Raj.S., Fun H.-K., Li E, Song H., Hexakis(imidazole-N-3)nickel(II) bis(4-methoxybenzoate). Acta Crystallogr. 2000, C56: 161-162
150.Ooi S., Fernando Q., The crystal and molecular structure of the adduct of bis (O, O'-diethyldithiophosphato) nickel (II) with Pyridine. Inorg.. Chem.1967, 6(8): 1558-1562
151.Harrison P.G, Begley M.J., Kikabhai T, Killer E, J. Chem. Soc. Dalton. Trans., 1986, 929-938
152.Steiner Th., C-H...Acceptor Interactions. Cryst. Rev, 1996, 6: 1-57
153.Drew Michael GB., Hobson Richard J., Mumba Peter P.E.M., Rice David A., Reactions of metal diakyl dithiophosphates Part IV. The crystal structure of [Ag{S2P(OEt)2}2]22- a silver anion containing monodentate and tridentate dialkyl dithiophosphate groups. Inorg. Chim. Acta 1988, 142: 301-303
154.Drew Michael G., Hasan Masihul, Hobson Richard J., Rice David, Reactions of [Zn{S2P(OR)2}] with nitrogen bases and the single-crystal X-ray structures of [Zn{S2P(OPri)2}2] H2NCH2CH2NH2 and [Zn{S2P(OPri)2}2]NC5H5, J. Chem. Soc. Dalton Trans. 1986,1:1161-1166
155.Parvez M., Rusiewicz M., Bis(antazoline)dichlorozinc(II). Acta Crystallogr. 1995, C51: 2277-2279
156. Ng C.H., Fun H.K., Teo S.B., Teoh S.G., Chinnakali K., Bis(1-prolinato-n,o) zinc(Ⅱ). Acta Crystallogr. 1995, C51:244-245
157. Glinskaya L.A., Klevtsova R.E, Zemskova S.M., Crystal and molecular structures of volatile complexes of bis(diethyl dithio carbamato) cadmium with 1, 10-phenanthroline and 2,2'-bipyridine. Zh. Strukt. Khim., 1992, 33 (1): 106-114
158. Annan T.A., Peppe C., Tuck, D.G., The direct electrochemical synthesis of d10 metal-ion derivatives of some anionic bidentate oxygen donors. Can. J. Chem., 1990, 68:423-430
159. Lawton S.L., Kokotailo G.T., The crystal and molecular structures of Zinc and Cadmium O, O'-diisopropylphosphorodithioates. Inorg. Chem. 1969, 8(11): 2410-2421
160．张建民，李瑞芳，刘树祥，过渡金属席夫碱配合物的稳定性及其杀菌活性．无机化学学报，1999，15(4)：493-496
2．徐光宪，21世纪的配位化学是处于现代化学中心地位的二级学科。北京大学学报(自然科学版)，2002，38(2)：149-151。
3．孟庆金，戴安邦编，配位化学的创始与现代化。第一版。北京：高等教育出版社，1998。
4．Basolo Fred,Johnson Ronald C．著．宋银柱，王耕霖等译．配位化学．第一版．北京：北京大学出版社，1982．
5. Swiegers F, Malefetse T.J., Classification of coordination polygons and polyhedra according to their mode of self-assembly. 2. Review of the literature. Coord. Chem. Rev. 2002, 225: 91-121.
6. Alvarez S., Palacios A.A., Aullon G., Ligand orientation effects on metal-metal, ligand-ligand and metal-ligand interactions. Coord. Chem. Rev. 1999, 185-186.
7. Ouahab L., Coordination complexes in conducting and magnetic molecular materials. Coord. Chem. Rev. 1997, 165: 475-567.
8. Ward M.D., The coordination chemistry of macrocyclic ligands. Annu. Rep. Prog. Chem., Sec. A: Inorg. Chem. 1990, 87: 303-309.
9. Barigelletti E, Flamigni L., Photoactive molecular wires based on metal complexes. Chem. Soc. Rev., 2000, 29(1): 1-12.
10. Raper E.S. Complexes of heterocyclic thionates. Part 1: Complexes of monodentate and chelating ligands. Coord. Chem. Rev., 1996, 153: 199-255.
11. Costamagna J., Ferraudi G., Matsuhiro B., Campos-Vallette M, Canales J., Villagran M., Vargas J., Aguirre M. J., Complexes of macrocycles with pendant arms as models for biological molecules. Coord. Chem. Rev. 2000, 196: 125-164.
12. Jeffrey George A., Huang Dc-bin. Hydrogen bonding in the crystal structure of the tetrasaccharide stachyose hydrate: 1:1 complex of the conformers. Carbohydrate Research., 1990, 210: 89-104.
13
13．王夔主编，生命科学中的微量元素．第一版．北京：中国计量出版社，(上卷)：1991；(下卷)：1992
14．Ochiai E-I著．罗锦新，张乃正，陈汉文译．生物无机化学导论．第一版．北京：化学工业出版社，1987
15．龚钰秋．混合配体络合物化学．第一版．北京：高等教育出版社，1991
16. Laidler K.J., Physical chemistry with biological applications, Frntiers of Chemistry. Pergamon Press, 1981.
17．任杰，陈志达，分子磁性的量子化学研究进展，无机化学学报．2002，18(8)．-753-760
18．邝代治，冯泳兰茂金属配合物[Mo(eta~5—C_5H_4Si_2Me_5)(CO)_3Cl]的晶体结构和量子化学研究，无机化学学报．2002，18(4)．-394-398
19．李林涛，麻生明，以N—杂环卡为配体的金属络合物催化有合成的反应，有机化学．2001，21(1)．75-81
20．翁文，曾庆乐，手性高分子金属络合物在不对称催化中的应用，高分子通报：2000，(3)50-55，68
21．张玉玲，阮文娟，金属络合物催化剂在不对称氮杂环丙烷反应中的研究进展，应用化学．2002，19(3)．-205-211
22．张玉良，钱明星等，过渡金属络合物催化乙烯齐聚，应用化学．2001，18(5)．360-364
23．唐黎明，吴丹，高分子金属络合物催化剂的合成及其催化氢化的应用，高分子材料．1996，3(3)．-34-37，45
24．燕远勇，金子林，水溶性过渡金属络合物催化两相氢甲酰化反应新进展，煤炭转化．1994，17(1)．-58-63
25．王荣民，王云普，高分子类卟啉金属配合物催化活化分子氧研究，西北师范大学学报：自然科学版．2000，36(1)．-100-103
26．王荣民，索继栓，分子筛基类卟啉金属络合物模拟生物氧化催化作用，精细石油化工．2000，(2)．-48-51
27．俞晓东，苯酚双氧水羟基化反应催化剂研究进展，化工生产与技 术．2000，7(5)．-23-25
28
28．王素青，过渡金属络合物催化的不对称氢硅烷化反应，昌潍师专学报．1997，16(5)．-6-9
29．张振学，杨松松，黄酮金属络合物作为潜在药物的研制与开发，中草药．1996，27(3)．-179-181
30．刘晶莹，王国清，王鸿刚，金属配台物抗癌活性的研究进展，化学试剂，2003，25(5)，274-276；295
31．李勤喜，王流芳，刘映琦，王印月，维甲酸镍配合物(Ni(RA)2·3H2O)抗白血病HL-60细胞的研究，厦门大学学报：自然科学版．2003，42(6)．-795-799
32. Hodnett E.M., Dunn W.J., Cobalt derivatives of Schiff bases of aliphatic amines as antitumor agents. J Med Chem, 1972,15(3):339.
33．李桂芝，2种水杨醛缩氨基酸及其10种金属配合物的杀菌活性研究，聊城大学学报：自然科学版．2003，16(1)．-57-59
34. Bonson, D., Mechanisms of Inorganic Reaction in Solution, McGraw-Hill. New York. 1968.
35. Just O., Gaul D.A., Rees Jr.W.S. Low-coordinate volatile group 12 amides: syntheses and crystal structure determinations of dimeric {M{N[Si(CH_3)_2CH_2CH_2Si(CH_3)_2]}_2}_2; M = Zn, Cd and monomeric Hg{N[Si(CH_3)_2CH_2CH_2Si(CH_3)_2]}_2. Polyhedron. 2001, 20:815-821.
36. Xiong R-G., Song B-L., You X-Z., Syntheses and properties of some transition metal complexes with methyl substituted 1-hydroxy-2(1H)-pyridinethione and crystal structure of bis(1-hydroxy-4-methyl-2(1H)-pyridinethionato-O,S') zinc (Ⅱ). Polyhedron. 1996, 15(5): 991-996.
37. Richburg L.M., Farouq J.A., Incarvito C.D., Arnold L., Rheingold, R.D., Zinc bis(pyrazoly) silane complexes. Polyhedron. 2000, 19:1815-1820.
38. Darensbourg D.J., Yarbrough J.C., Synthesis and crystal structure of [H_2B(3-Phpz)_2]_2Zn. J. Organometal Chem. 2000, 614-615: 305-308.
39. Sahin E., Ide S., Kurt M., Yurdakul S. Structural investigation of dibromobis (benzimidazole) Zn(Ⅱ) complex. J. Molecular Structure. 2002, 616: 259-264.
40. Mareque Rivas J.C., Martin de Rosales R.T., Parsons S., Internal hydrogen bonding and amide co-ordination in zinc (Ⅱ) complexes of a tripodal N4 ligand: structural, spectroscopic and reactivity studies. J. Chem. Soc. Dalton Trans. 2003:2156-2163.
41. Cheng B, Scheidt W.R., Stereochemistry of aquo (5,10,15,20-tetra phenylporphinato) zinc(Ⅱ) as its 18-crown-6, methylene chloride solvate. Inorg. Chim. Acta. 1995, 237: 5-11.
42. Dell'Amico D.B., Boschi D., Calderazzo F., Labella L., Marchetti F., Synthesis, and crystal and molecular structures of the triflato and trifluroacetato complexes of zinc, Zn(O_3SCF_3)_2(DME)_2 and [Zn(O_2CCF_3)_2(DME)]_n. Inorg. Chim. Acta. 2002, 330: 149-154.
43. Jian, F. F., Hao, Q. L., Yang, X., Lu, L., Wang, Xin., Structure of bis(O' O-diisopropyl dithiophosphato-s, s') (1,10-Phenanthroline-N1, N10) zinc(Ⅱ) complex, [Zn(phen)(S_2P(OiPr)_2)_2]. J. Chem. Crystallogra. 2000, 30(7): 469-472.
44. Lindoy, L.E, The chemistry of macrocyclic ligand complexes. Cambridge University Press, 1999.
45. Stiefel, E.I., The structures and spectra of molydoenxyme active sites and their models. Prog. Inorg. Chem. 1977, 1: 22-26.
46. Hagan, K.S., Watson, A.D., Holm, R.H., Systematic stereochemistry of metal (Ⅱ) thiolates: systematic structures of [M_2(SC_2H_5)_6]~(2-) (M = Mn, Ni, Zn, Cd). Inorg. Chem. 1984, 23: 2984-2988.
47. Holm, R.H., Synthetic analogs of the active sites of iron-sulfur proteins and enzymes and their relevance to dinitrogen fixation, Chem. Soc. Rev. 1981, 10: 455-459.
48．百熙编著．浮药选剂．第一版．北京：冶金工业出版社，1981，192．
49．邓玉珍，选矿药剂概括．北京：冶金工业出版社，1981．
50. Holm R.H., Kennepohl E, Solomon E.I., Structural and functional aspects metal sites in biology. Chem. Rev. 1996, 96: 2239-2314.
51. Mingionc Phillip A., Use of dialkyl and diaryl dithiophosphate promoters as mineral flotation agents. Reagents Miner. Ind. Pap. 1984:19-24
52. Soedinenii Khim i. Primenenie Fosfororg, Organophosphorus in secticides. Akad. Nauk S.S.S.R Trudy, 1-0I, Konferents. 1995: 148-63.
53. Mohan KR., Ramesh A., Seshaih K., Extractive fluorimetric determination of malathion residues in water samples. Analyst, 2000, 125 (2): 323-326
54. Chen W.B., Jin G.Y., Synthesis and biological activities of O, O-dialkyl-dithiophosphoryl-S-acetoxy triazolo compounds. Phosphorus Sulfur and Silicon and the Related Elements, 2003, 178 (2): 311-317
55. Chen W.B., Jin G.Y., Syntheses and biological activities of S-1,2,4-triazolo[1,5-a]pyrimidinylalkyl dithiophosphates. Heteroatom Chem., 2003, 14 (7): 607-611
56. Haiduc, I.; Bryan-Sowerby, D.; Lu S. F., Stereochemical aspects of phosphor-l,l-dithioato metal complexes (dithiophos phates, dithiophosphinates): coordination patterns, molecular structures and supramolecular associations-I. Polyhedron, 1995, 14, 3389.
57. Jones, J.R.; Symes, T.J. Linear dimerization of 1-olefine catalyzed by complexes of nickel β-diketonates and aluminum alkyls. J. Chem. Soc., C, 1971, 1124-1130.
58. Howard J.A., Yamada T., Metal complexes as antioxidants. 9. Application of the spin scavenging technique to the reaction of transition metal dialkyldithiophosphates and dialkyldithiocarbamates with tertiary alkyl hydroperoxides, Can. J. Chem. 1982 (60): 224-228.
59. Kovtun G.A., Zhukovskaya G.B., Kratko G.A., Sukhoveev V.V., Antioxidative properties of metal bis(dialkyldithiophosphates) in lubricant oils: effect of metal\ nature and stoichiometry of alkyl substituents. Dokl. Akad. Nauk Ukr. SSR. 1991(4): 105-107.
60. Tarasova Z.N., Senatorskaya L.G., Fedorova T.V., Eitingon I.I., Kirpichnikov RA., Kavun S.E, Dogadkin B.A., Effect of the structure of a vulcanization network on aging and fatigue of rubbers. Kauchuk I Rezina, 1965, 24(7): 5-10.
61．李克华，周玉贺，吴振烈，二硫代磷酸硫化氧钼与硫、磷添加剂的复配特性研究．石油炼制与化工。1995，26(10)：43-48
62. So H., Lin Y.C., Huang GS, Chang S.T., Antiwear mechanism of zinc dialkyl dithiophosphates added to a paraffmicoil in the boundary lubrication condition, wear, 1993(166): 17-23
63. Lohr Delmar FJr., Kay Eward L., Berth Harry J., High-temperature stabilization of 1, 2-polybutadiene resins. J. Soc. Plast. Eng., Tech. Pap. 1974(20): 647-650.
64. Vinogradov GV., Soedinenii Khim. I Primenenie Fosfororgan., Application and mechanism of organophosphorus compounds as antiwear additives to oils. Akad. Nauk S.S.S.R., Trudy 1-01 Konferents. 1995: 124-147
65. Wakefield C.C., Cragg John C, Zinc dialkyl thiolthionophosphates for use as lubricant additives. Brit. 822655, Oct. 28, 1959.
66. Okamura Nobuyuki, Hojo Masahiro, Pnenumatic tires with styrene-butadinee rubber tread. Eur. Pat. Appl. Ep832920, (1998)
67. Evstaf ev V.P,, Kononova E.A., Levin A.Y., Trofimova G.L., Ivanova O.V., A new dithiophosphate additive for lubricating oils. Chem. Tech. Fuels Oils. 2001, 37 (6): 427-431
68. Rossi A., Eglin M., Piras F.M., Matsumoto K., Spencer N.D., Surface analytical studies of surface-additive interactions, by means of in situ and combinatorial approaches. WEAR, 2004, 256 (6): 578-584
69. Ye J.P., Kano M., Yasuda Y., Evaluation of nanoscale friction depth distribution in ZDDP and MoDTC tnbochemical reacted films using a nanoscratch method. Tribol. Lett., 2004, 16(1-2): 107-112
70. Muraki M., Wada H., Influence of the alkyl group of zinc dialkyldithiophosphate on the frictional characteristics of molybdenum dialkyldithiocarbamate under sliding conditions. Tribol. Intern. 2002, 35 (12): 857-863
71. Kovtun GA., Zhukovskaya GB., Kretko GA., Sukhoveev, V.V., Effect of structure of metal dialkyl dithiophosphate on their antioxidative properties in lubricating oils. Neftepererab. Neftekhim. 1992(42): 39-41
72. Hu X.G., Study of friction and wear performance of zinc dialkyldithiophosphate in the presence of trace ketone. Tribol. Lett., 2002,12 (1): 67-74
73. Wan Yong, Cao Lili, Xue Qunji, Friction and wear characteristics of ZDDP in the sliding of steel against aluminum alloy. Tribol. Inter. 1998, 30(10): 762-772
74. Breytenbach W., Vermaak M.K.G., Davidtz J.C., Synergistic effects among dithiocarbonates (DTC), dithiophosphate (DTP) and trithiocarbonates (TTC) in the flotation of Merensky ores. Journal Of The South African Institute Of Mining And Metallurgy. 2003, 103 (10): 667-670
75. Shlepnina T.G, Hygienic significance and standardization of hydrobyzed butyl flotation reagent in water reservoirs. Gig. Sanit. 1971, 36(7): 14-19.
76.邓玉珍，选矿药剂概括.北京:冶金工业出版社，1981.
77. Piantadosi C, Jasieniak M., Skinner W.M., Smart R.S.C., Statistical comparison of surface species in flotation concentrates and tails from TOF-SIMS evidence. Miner. Engineering 2000, 13 (13): 1377-1394
78. Tian G.X., Zhu Y.J., Xu J.M., Zhang P., Hu T.D., Xie Y.N., Zhang J., Investigation of the extraction complexes of light lanthanides(III) with bis(2,4,4-trimethylpentyl)dithiophosphinic acid by EXAFS, IR, and MS in comparison with the americium(HI) complex. Inorg. Chem., 2003, 42 (3): 735-741
79. Ertelt Henry R., Wythe Stephen L., Furey Michael J., Appeldoorn John K., Metal chelates of dialkyl dithiophosphoric acids for recovery and determination of heavy metals. U.S. 2976122. March. 21, 1961
80. Rickelton W.A., Novel uses for thiophosphinic acids in solvent-extraction. Jom-J Min.Met. Mat. Soc. 1992, 44(5): 52-54
81. Rickelton W.A., Boyle R.J., The selective recovery of zinc with new thiophosphinic acids. Solvent Extr. Ion Exc. 1990, 8(6): 783-797
82. Rickelton W.A., The removal of cadmium impurities from cobalt-nickel solutions by precipitation with sodium diisobutyldithiophosphinate. Hydrometallurgy 1998, 50 (3): 339-344
83. Aliev V.S., Aliev S.M., Azizov A.G., Mamedaliev G.A., Nasirov F.A., Ismailov T.A., Kruchinina V.M., Dzhanibekov N.F., Gol'berg I.P., Organoaluminum compounds and transition metal dithiophophates as catalysts for polymerization of dienes. PCT Int. Appl. WO 91 02,587. Mar. 07 1991.
84
84. Porta P., Sgamellotti A., Vinciguerra N., The crystal and molecular structure of bis(diphenyl dithiophosphato) nickel (Ⅱ). Inorg. Chem. 1968, 7(12): 2625-2629
85. Lawton Stephen L., Kokotailo George T., The crystal and molecular structure of polymeric lead (Ⅱ) O,O'—diisopropylphosphorodithioate, Pb[(I-C_3H_7O)_2PS_2]_2. Deformation of a hexathiocoordinate lead group by a stereochemically active lone pair of electrons, Inorg. Chem., 1972. 11(2): 363-368
86. Drew Michael G.B., Hopkins W.A., Mitchell P.C.H., Colclough T., Preparation, properties, and X-ray crystal structure of tris (O,O'-diisopropyl phosphorodithioato) iron (Ⅲ), [Fe{S_2P(OPr~i)_2}_3]. Comparison of structure and bonding in phosphorodithioato- and dithiocarbamato- complexes. J. Chem. Soc. Dalton Trans. 1986 (2): 351-354
87. You X., Xu Z., Yu Y., Liu S., Lin C., Crystal structure of adduct of bis (O,O'-dibutyldithiophosphato) nickel (Ⅱ) with bipyridyl. J. Struct. Chem. 1986. 5(3): 154-158.
88．刘世雄，林墀昌，徐正，林建华，俞运鹏，游效曾，Ni[(C_6H_(11)O)_2PS_2]_2与吡啶加和反应平衡常数的测定及加合物的晶体结构．高等学校化学学报．1989．10(12)：1225-1228
89. Liu C., Liu S., Xu Z., Lin J., You X., Crystal and molecular structure of bis (O,O'-dicyclohexyl dithiophosphato) nickel (Ⅱ). J. Struc. Chem. 1987. 6(3): 186-188
90．徐正，俞运鹏，林建华，于秀华，游效曾，Ni[(C_6H_(11)O)_2PS_2]_2与氮碱加合反应的研究．无机化学学报．1990．6(1)：25-30
91. Shapiro P.J., Henling L.M., March R.E., Bercaw J.E., Hydrazido and 2,2'-dimethylhydrazido derivatives of permethylscandocene., Inorg. Chem. 1990 (29): 4560-4568
92. Nicholson T., Lombandi P., Zubieta J., Monomeric five-coordinate rhenium diazenide and hydrazido complexes with aromatic thiolate ligands, Polyhedron. 1987(7): 1577-1581
93. Latham J.A., Leigh G.J., The chemistry of dinitrogen redidues: the decomposition of hydrazide (1-) and hydrazide (2-) bond to titanium (Ⅳ). J. Chem. Soc. Dalton Trans., 1986:399-403
94. Sammes P.G., Yahioglu G., 1, 10-phenanthroline: a Versatile ligand. J. Chem. Soc. Rev., 1994, 23(5): 327-331
95．敬炳文，吴韬，张曼华，沈涛，功能性多吡啶配体的合成．高等学校化学学报．2000(3)：395-398
96．钱士雄，王恭明编著．非线性学-原理与进展．第一版．上海：复旦大学出版社，2001
97．张克从，王希敏．非线性光学晶体材料科学．第一版．北京：科学出版社，1996
98. Kanis D.R., Ratner M.A., Marks T.J., Design and construction of molecular assemblies with large second-order optical nonlinearitiee. Quantum Chemical Aspects. Chem. Rev. 1994, 94:195-242
99. Ramasesha S., Das P.K., Second harmonic generation coefficients in push-pull polyenes: a model exact study. Chem. Physics. 1990, 145:343-353
100. Henderson R.A., Leigh G.J., Pickett C.J., The chemistry of nitrogen-fixation and models for the reactions of nitrogenase. Adv. Inorg. Chem. Rad. 1983, 27:197-292
101. Thorneley R.N.F., Lowe D.J., The mechanism of nitrogen fixation and models for the reactions of nitrogenese. Molybdenum Enzymes. New York. 1985, 5:221-227
102. Pickett C.J., Ryder K.S., Tolarmin J.J., Electrochemical carbon-carbon coupling of cliazomethane ligands. J. Chem. Soc. Dalton Trans., 1986, 1453-1458
103. Henriksson H.A., The crystal structure of bis(imidazole) copper (Ⅱ) diacetate. Acta Crystallorg., B, 1977, B33(6): 1947-1950
104. Abuhijleh A.L., Woods C., Synthesis, crystal structure and superoxide dismutase mimetic activity of hexakis (N-methylimidazole) copper(Ⅱ) salicylate. Inorg Chem Commun. 2002, 5 (4): 269-273
105. Abuhijleh A.L., Woods C., Mononuclear copper (Ⅱ) salicylate imidazole complexes derived from copper (Ⅱ) aspirinate. Crystallographic determination of three copper geometries in a unit cell. Inorg Chem Commun, 2001, 4 (3): 119-123
106.AbdulGhani A.S., AbuHijleh A.L., Nahas N., et al. Hypoglycemic effect of copper(II) acetate imidazole complexes. Biol Trace Elem Res, 1996, 54 (2): 143-151
107.Abuhijleh A.L., Catalytic activities of the antitumour complex bis(acetato) bis(imidazole) copper(II) and bis(valproato) bis(imidazole) copper(II) for the oxidation of organic substrates. Polyhedron, 1996, 15 (2): 285-293
108.Abuhijleh A.L., Synthesis And Characterization Of Mononuclear Copper (II) Aspirinate Adducts With Imidazole And Its Methyl-Derivatives. Polyhedron, 1989,8 (23): 2777-2783
109.Abuijeh A.L., Woods C, Synthesis, spectroscopic and structural characterization of bis(acetato) tetrabis(imidazole) copper (II): a model complex for DNA binding. Inorg. Acta., 1992, 194(1): 9-14
110.Drew Micheal G.B., Hobson Richard J., Mumba Peter P.E.M., Rice David A., Crystal and molecular structure of [{Ag[S2P(OEt)2].PPh3}2]. J. Chem. Soc. Dalton Trans. 1987, 6: 1569-1571
111 .Drew Michael G.B., Forsyth George A., Hassan M., Hobson Richard J., Rice David A., Reactions of copper (II) with [S2P(OP)2]- (R = Et or Pri) and single-crystal X-ray studies of Cu[S2P(OEt)2].bipy and Cu[S2P(OEt)2].2PPh3. J. Chem. Soc. Dalton Trans. 1987 (5): 1027-1033
112.Hao Q.L., Yang X.J., Jian F.F., Lu L.D., Wang X., Razak LA., Chantrapromma S., Fun H.K., Bis(O,O'-diisopropyl dithiophosphato-S,S ') (l,10-phenanthroline-N,N ') metal(II) complexes with cadmium(II) and iron(II). Acta Crystallographica Section C-Crystal Structure Communications 2001, 57: 42-44
113.Jian F.F., Liu G.Y., Hao Q.L., Wang X., Synthesis and crystal structure of Cu(phen) (H2O)(2) center dot C104(phen = phenanthroline). Chinese Journal Of Inorganic Chemistry, 2003, 19 (4): 419-422
114.Hao Q.L., Jian F.F., Wang X., Razak LA., Shanmuga S., Raj S., Fun H.K., trans-Bis(2-aminopyridine-N)bis(O,O '-diisopropyl dithiophosphato-S,S ') nickel(II). Acta Crystallographica Section C-Crystal Structure Communications, 2001, 57: 160-161
115.Hao Q.L., Fun H.K., Chantrapromma S., Razak LA., Jian F.F., Yang X.J., Lu L.d., Wang X., Bis(O,O '-di-p-tolyldithiophosphato-S,S ') (l,10-phenanthroline-N,N ') nickel(II). Acta Crystallographica Section C-Crystal Structure Communications, 2001,57:717-718
116.Hao Q.L., Jian F.F., Yang X.J., Wang X., Razak LA., Raj S.S.S., Fun H.K., Hexakis(lH-imidazole-kappa N-3) nickel(II) bis[O,O '-diisopropyl dithiophosphate(l-)]. Acta Crystallographica Section C-Crystal Structure Communications, 2000, 56: 1431-1432
117.Fun H.K., Hao Q.L., Wu J., Yang X.J., Lu L.D., Wang X., Chantrapromma S., Razak LA., Usman A., Bis(ethylenediamine) copper (II) bis(O,O '-diethyl dithiophosphate), Acta Crystallographica Section C-Crystal Structure Communications, 2002, 58: m87-m88
118.Jian F.F., Hao Q.L., Yang X.J., Lu L., Wang X., Structure of bis(O,O '-diisopropyldithiophosphato-S,S') (1,10-phenanthroline-N-1 ,N-10) zinc(II) complex, [Zn(phen)(S2P(OiPr)2)2]. J. Chem. Crystallogra., 2000, 30 (7): 469-472
119.Gianini M., Caseri Walter R., Gramlich V., Suter Ulrich W., Synthesis and characterization of liquid platinum compounds. Inorg. Chim. Acta. 2000, 299: 199-208
120.Wystrach V.P., Hook E.O., Christopher G.L.M., Basic Zinc double salts of O,O'-dialkyl phosphorodithioic acids, J. Org. Chem. 1956, 21: 705-707
121.Zemlyanskii N.I., Drach B.S., Synthesis of salts of some O,O'-diaryl phosphorodithioates. Zh. Obshch. Khim. 1962, 32: 1962-1966
122.Kudrev A.G., Complexation in the copper(II)-ethylenediamine-heterocyclic diimine system. Zh. Neorg. Khim. 1994, 39(12): 2041-2046
123.Zimina K.I., Kotova G.G., Sanin P.I., Sher V.V., Kuz'mina G.N., The infrared absorption spectra of metal dialkyldithiophosphates. Neftekhimiya 1965, 5(4): 629-635
124.Shishkov A.N., Nikolov N.K., Infrared spectra of some bis(dialkoxy- and diaryloxyphosphinothioyl) disulfides. Nauch. Tr., Plovdivski Univ. Mat., Fiz., Khim., Biol. 1972, 10(3): 87-95
12
125．陈国珍，黄贤智等编著．紫外可见分光光度法(上册)．原子能出版社出版．北京：1987，p7～34
126. Ionel Haiduc, Rodica Micu-Semeniuc, Luminita Silaghi-Dumitrescu, Transition metal complexes of organothiophosphorus ligands. Ⅸ. Addaucts .of nickel alkoxyand phenoxyethyl phosphorodithioates with primary and tertiary mono- and diamines. Synth. React. Inorg. Met. Org. Chem., 1993, 23(10): 1629-1643
127．蔡正千编，热分析．高等教育出版社．北京：1990，102
128. Livingstone Stanley E. and Mihkelson Anu E., Metal chelates of biologically important compounds. Ⅱ. Nickel complexes of dialkyldithiophosphates and their adducts with nitrogen heterocycles. Inorg. Chem. 1970, 9(11), 2550.
129. Sheldrick, G.M. SHELXTL V5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA 1997
130. Siemens. SMART and SAINT. Area Detector Control and Integration Software. Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA. 1996
131. Sheldrick, G. M. (1996). SADABS. Program for Empirical Absorption Correction of Area Detector Data, University of Gttingen, Germany.
132. Sheldrick, G. M. SHELXTL-97. Program for crystal structure determination. University of Gttingen, Germany, 1997
133. Sheldrick, G. M. SHELXTL-97. Program for the refinement of crystal structures. University of Gttingen, Germany, 1997
134. Sheldrick, G. M. SHELXTL-97. Acta Crystallogr., Sect. A, 1990, 46:467
135. Siemens. XSCANA User's Manual, Version 2.1, Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1994
136. Wilson A.J., International Table for X-ray Crystallography, Vol. C. Kluwer Academic Publishers, Dordrecht: 1992, Table 6.1.1.4 (P500-502) and Table 4.2.6.8 (P219-222)
137. Chen H.W., Fackler Jr.J.P., Sulfur chelates. 30. Crystal and molecular structure of aryl xanthates. Bis(O-4-tert-butylphenyl dithiocarbonato) nickel (Ⅱ), Ni(S_2COC_6H_4-4-t-Bu)_2, tris(O-2,4,6-trimethylphenyl dithiocarbonato) Cobalt (Ⅲ), Co(S_2COC_6H_4-2,4,6-Me_3)_3, and Bis(O-2,4,6-trimethyl-phenyl dithiocarbonato) palladium (Ⅱ), Pd(S_2COC_6H_2-2,4,6-Me_3)_2. Inorg. Chem., 1978, 17(1): 22-26
13
138. Hoskins B.F., Tiekink E.R.T., Structure of bis(O,O'-diisopropyl phosphoro dithioato) nickel (Ⅱ), Ni[S_2P(O~iC_3H_7)_2]_2. Acta Cryst., 1985, C41:322-324
139. Arca M., Cornia A., Devillanova EA., Fabretti A.C., Isaia E, Lippolis V., Verani G., New perspectives in phosphonodithioate coordination chemistry. Synthesis and X-ray crystal structure of trans-bis-[O-ethyl (4-methoxyphenyl) phosphono dithioato] nickel(Ⅱ). Inorg. Chim. Acta, 1997, 262(1): 81-84
140. Xiong R.G, Liu C.M., Zuo J.L., Li H.Z., You X.Z., Fun H.K., Sivakumar K., A novel molecular channel: Thermal analyses and X-ray structure of [Ni(Et-XA)(2)center dot phen]center dot 3H(2)O (Et-XA equals ethylcarbonodithiolato-S,S', phen equals phenanthroline). Polyhedron, 1997, 16(13): 2315-2319
141. Huang X.Y., Xiong R.G., You X.Z., The adduct of bis(o,o'-diethyl dithiophosphato)nickel(Ⅱ) with 3-aminopyridine. Acta Cryst., 1995, C51: 2261-2263
142．刘世雄，林犀昌，徐正，余运鹏，游效曾，双-(O，O’-二正丁基二硫代磷酸酯)合镍-二吡啶加合物的晶体结构和分子结构．1987，5：369-373
143. Byrom C., Malik M.A., O'Brien P., White A.J.P., Williams D.J., Synthesis and X-ray single crystal structures of bis(diisobutyldithiophosphinato)cadmium(Ⅱ) or zinc(Ⅱ): Potential single-source precursors for Ⅱ/Ⅳ materials. Polyhedron, 2000, 19(2): 211-215.
144. Palopoli S.F., Geib S.J., Rheingold A.L., Brill T.B., Synthesis and modes of coordination of energetic nitramine ligands in copper(ⅱ), nickel(ⅱ), and palladium(ⅱ) complexes. Inorg. Chem. 1988, 27:2963-2971.
145. Vrabel V., Kell E., Garaj J., tris[Bis(ethylenediamine)copper(ⅱ)] poly [hexakis (mu-cyano) hexakis (mu-seleno-cyanato) hexacopper(ⅰ)], [Cu(Ⅱ)en_2]_3 [Cu6(I)(cn)6(secn)6]. Acta Cryst. 1995, C51: 1286-1288
146.Drew M.GB., Forsyth GA., Hasan M., Hobson R.J., Rice D.A., Reactions of copper(ii) with [S2P(oEt)2] or [S2P(oPr-i)2) and single-crystal x-ray studies of Cu[S2P(oEt)2].bipy and Cu[S2P(oEt)2].2PPh3. J. Chem. Soc. Dalton Trans. 1987, 5: 1027-1033
147Jeffrey GA., Maluszynska H., Mitra J., H-Bond classification. Int. J. Biol. Macromol. 1985, 7: 336-348
148.Jian RE, Wang Z.X., Bai Z.P., You X.Z., Fun H.K., Chinnakali K., Structure of hexakis(imidazole)nickel(II) disalicylate, [Ni(Im)(6)](Sal)2. J. Chem. Crystallogr., 1999, 29(3): 359-363
149.Wang Z., Zhang Y., Razak LA., Shanmuga Sundara Raj.S., Fun H.-K., Li E, Song H., Hexakis(imidazole-N-3)nickel(II) bis(4-methoxybenzoate). Acta Crystallogr. 2000, C56: 161-162
150.Ooi S., Fernando Q., The crystal and molecular structure of the adduct of bis (O, O'-diethyldithiophosphato) nickel (II) with Pyridine. Inorg.. Chem.1967, 6(8): 1558-1562
151.Harrison P.G, Begley M.J., Kikabhai T, Killer E, J. Chem. Soc. Dalton. Trans., 1986, 929-938
152.Steiner Th., C-H...Acceptor Interactions. Cryst. Rev, 1996, 6: 1-57
153.Drew Michael GB., Hobson Richard J., Mumba Peter P.E.M., Rice David A., Reactions of metal diakyl dithiophosphates Part IV. The crystal structure of [Ag{S2P(OEt)2}2]22- a silver anion containing monodentate and tridentate dialkyl dithiophosphate groups. Inorg. Chim. Acta 1988, 142: 301-303
154.Drew Michael G., Hasan Masihul, Hobson Richard J., Rice David, Reactions of [Zn{S2P(OR)2}] with nitrogen bases and the single-crystal X-ray structures of [Zn{S2P(OPri)2}2] H2NCH2CH2NH2 and [Zn{S2P(OPri)2}2]NC5H5, J. Chem. Soc. Dalton Trans. 1986,1:1161-1166
155.Parvez M., Rusiewicz M., Bis(antazoline)dichlorozinc(II). Acta Crystallogr. 1995, C51: 2277-2279
156. Ng C.H., Fun H.K., Teo S.B., Teoh S.G., Chinnakali K., Bis(1-prolinato-n,o) zinc(Ⅱ). Acta Crystallogr. 1995, C51:244-245
157. Glinskaya L.A., Klevtsova R.E, Zemskova S.M., Crystal and molecular structures of volatile complexes of bis(diethyl dithio carbamato) cadmium with 1, 10-phenanthroline and 2,2'-bipyridine. Zh. Strukt. Khim., 1992, 33 (1): 106-114
158. Annan T.A., Peppe C., Tuck, D.G., The direct electrochemical synthesis of d10 metal-ion derivatives of some anionic bidentate oxygen donors. Can. J. Chem., 1990, 68:423-430
159. Lawton S.L., Kokotailo G.T., The crystal and molecular structures of Zinc and Cadmium O, O'-diisopropylphosphorodithioates. Inorg. Chem. 1969, 8(11): 2410-2421
160．张建民，李瑞芳，刘树祥，过渡金属席夫碱配合物的稳定性及其杀菌活性．无机化学学报，1999，15(4)：493-496