配合物阴离子柱撑水滑石的制备及其催化性能研究
|
摘要
在本论文研究中,通过Ni~(2+)、Cu~(2+)、Co~(2+)、Mn~(2+)、Cr~(3+)及Fe~(3+)等过渡金属离子与EDTA、草酸、丙二酸及CN~-等多齿或单齿配体配位,合成了相应的过渡金属配合物阴离子,利用共沉淀及离子交换插层组装方法,制备了过渡金属配合物阴离子柱撑水滑石Mg_3Al-LDHs/[MY](M为Ni~(2+)、CU~(2+)、Co~(2+)、Mn~(2+)、Cr~(3+),Y为EDTA)、Ni_3Fe-LDH/[CoY]、Ni_3Al-LDH/[CoY]及Ni_2Al-LDH/[Cr(C_2O_4)_3]、Ni_2Al-LDH/[Cr(C_3H_2O_4)_3]、Ni_2Al-LDH/[Fe(C_2O_4)_3]、Ni_2Al-LDH/[Fe(CN)_6]。通过XRD、FT-IR、ICP、TG-DTA等对它们的组成和结构进行了分析表征,研究了反应条件对插层组装的影响。以肉桂醛的过氧化氢氧化反应为探针反应,考察了过渡金属配合物阴离子柱撑水滑石插层化合物的氧化催化性能。
研究结果表明,利用共沉淀插层组装方法制备Mg_3Al-LDHs/[MY]的适宜条件为:Mg/Al配比为3.00、共沉淀酸度pH=9.0、晶化温度为90℃,晶化时间为24 h。利用离子交换法制备过渡金属配合物阴离子-Ni_2Al-LDHs的适宜插层组装条件为:以Ni_2Al-LDH/NO_3为前躯体,控制体系酸度pH=6.5、85-90℃下交换48h。粉末X-射线衍射及元素分析表明,在上述插层组装条件下,得到的过渡金属配合物阴离子柱撑水滑石层状结构规则有序,具有典型的水滑石结构特征,且组成符合类水滑石组成通式。FT-IR分析表明,LDHs层间过渡金属配合物阴离子保持其原有结构不变。TG热分析表明,所制备的层柱复合体具有较高的热稳定性,层柱结构完全破坏的温度一般在400℃以上。
通过考察过渡金属配合物阴离子尺寸和LDHs层间孔道高度,结合主客体间的相互作用,推断了LDHs层间配合物阴离子的排布方式。在Mg_3Al-LDHs/[MY]层间,过渡金属-EDTA配合物阴离子采取以其最小维度垂直于层板、双分子层叠加的方式在层间排布;在Ni_2Al-LDH/[Cr(C_2O_4)_3]、Ni_2Al-LDH/[Cr(C_3H_2O_4)_3]、Ni_2Al-LDH/[Fe(C_2O_4)_3]及Ni_2Al-LDH/[Fe(CN)_6]层间,客体阴离子均采取以其C3轴垂直于层板的、单层形式在层间排布。这样的排布方式使主客体间的静电作用及氢键作用最大,插层化合物结构最为稳定。在体积匹配、电性匹配和空间构型匹配的前提下,主客体间的相互作用是影响层间配阴离子排布形式的关键因素。
柱撑水滑石化合物对过氧化氢氧化肉桂醛反应具有明显的催化作用,其催化效果来源于层板和层间阴离子的双重作用,层板的组成及层间阴离子的种类对催化性能有很大影响,当层板元素为过渡金属Ni和Fe、层间阴离子为[CoY]~(2-)时,催化活性最好。
In this thesis anionic EDTA,oxalate,malonate,cyanide coordination compound of transition metal ions Ni~(2+),Cu~(2+),Co~(2+),Mn~(2+),Cr~(3+),are bridged through electrostatic and H-bonding interactions into Mg_3Al-LDHs and Ni_2Al-LDHs on the basis of the their anion exchange property.Mg_3Al-LDHs/[MY](M=Ni~(2+),Cu~(2+),Co~(2+),Mn~(2+),Cr~(3+), Y=EDTA),Ni_3Fe-LDH/[CoY]and Ni_3Al-LDH/[CoY]were synthsized by co-precipitation method.Intercalation compounds of Ni_2Al-LDHs,with[Cr(C_2O_4)_3]~(3-), [Cr(C_3H_2O_4)_3]~(3-),[Fe(C_2O_4)_3]~(3-) and[Fe(CN)_6]~(3-) complexes were obtained via intercalation and assembly processes.The composition,structure and property of the products thereby obtained have been studied by using XRD,FT-IR,ICP and TG-DTA. Catalytic activity for the H_2O_2 oxidation of cinnamaldehyde of the composite materials was also investigated.
The results indicated that,all the obtained composites had better organized stacking arrangement by controlling experimental conditions:when the Mg/Al ratio was 3.00,co-precipitation was under pH=9.0,aging at 90℃24 h;when the Ni/Al ratio was 2.00,ion-exchange processes was under pH=6.5 and 85-90℃or ambient temperature for 48 h.XRD and vibrational spectroscopy studies confirmed that the integrity of the transition metal complexes was preserved upon incorporation into LDHs.TG analysis showed that all the composite materials obtained had well thermal stability,the layer structure was completely destoried above 400℃.
The orientation and arrangement of the transition metal complexes within the interlayer had also been investigated.In the case of Mg_3Al- LDHs/[MY]the interlayer separation indicated that the guest species were arranged in a bilayer with the minimal dimension perpendicular to the host layers;In Ni_2Al-LDH/[Cr(C_2O_4)_3]、Ni_2Al-LDH /[Cr(C_3H_2O_4)_3]、Ni_2Al-LDH/[Fe(C_2O_4)_3]、Ni_2Al-LDH/[Fe(CN)_6]the guest species were all arranged in a monolayer with their C3 axises perpendicular to the host layers.These orientations can maximize the electrostatic force and hydrogen bonds between the host and guest species.The host materials can meet the matching of volume,electricity and construction of the guest species,which were main factors in affecting the orientation and arrangement of the guest species.
The catalytic activities of the composite materials were extensively studied.It was observed that the catalytic activities of the composite materials LDHs mainly attributed to the synergetic effect between transition metal complexes and LDHs.The most optimal catalytic performance came from the LDHs which the[CoY]~(2-) anion was intercalated into the interlayer space of Ni_3Fe-LDHs.
研究结果表明,利用共沉淀插层组装方法制备Mg_3Al-LDHs/[MY]的适宜条件为:Mg/Al配比为3.00、共沉淀酸度pH=9.0、晶化温度为90℃,晶化时间为24 h。利用离子交换法制备过渡金属配合物阴离子-Ni_2Al-LDHs的适宜插层组装条件为:以Ni_2Al-LDH/NO_3为前躯体,控制体系酸度pH=6.5、85-90℃下交换48h。粉末X-射线衍射及元素分析表明,在上述插层组装条件下,得到的过渡金属配合物阴离子柱撑水滑石层状结构规则有序,具有典型的水滑石结构特征,且组成符合类水滑石组成通式。FT-IR分析表明,LDHs层间过渡金属配合物阴离子保持其原有结构不变。TG热分析表明,所制备的层柱复合体具有较高的热稳定性,层柱结构完全破坏的温度一般在400℃以上。
通过考察过渡金属配合物阴离子尺寸和LDHs层间孔道高度,结合主客体间的相互作用,推断了LDHs层间配合物阴离子的排布方式。在Mg_3Al-LDHs/[MY]层间,过渡金属-EDTA配合物阴离子采取以其最小维度垂直于层板、双分子层叠加的方式在层间排布;在Ni_2Al-LDH/[Cr(C_2O_4)_3]、Ni_2Al-LDH/[Cr(C_3H_2O_4)_3]、Ni_2Al-LDH/[Fe(C_2O_4)_3]及Ni_2Al-LDH/[Fe(CN)_6]层间,客体阴离子均采取以其C3轴垂直于层板的、单层形式在层间排布。这样的排布方式使主客体间的静电作用及氢键作用最大,插层化合物结构最为稳定。在体积匹配、电性匹配和空间构型匹配的前提下,主客体间的相互作用是影响层间配阴离子排布形式的关键因素。
柱撑水滑石化合物对过氧化氢氧化肉桂醛反应具有明显的催化作用,其催化效果来源于层板和层间阴离子的双重作用,层板的组成及层间阴离子的种类对催化性能有很大影响,当层板元素为过渡金属Ni和Fe、层间阴离子为[CoY]~(2-)时,催化活性最好。
In this thesis anionic EDTA,oxalate,malonate,cyanide coordination compound of transition metal ions Ni~(2+),Cu~(2+),Co~(2+),Mn~(2+),Cr~(3+),are bridged through electrostatic and H-bonding interactions into Mg_3Al-LDHs and Ni_2Al-LDHs on the basis of the their anion exchange property.Mg_3Al-LDHs/[MY](M=Ni~(2+),Cu~(2+),Co~(2+),Mn~(2+),Cr~(3+), Y=EDTA),Ni_3Fe-LDH/[CoY]and Ni_3Al-LDH/[CoY]were synthsized by co-precipitation method.Intercalation compounds of Ni_2Al-LDHs,with[Cr(C_2O_4)_3]~(3-), [Cr(C_3H_2O_4)_3]~(3-),[Fe(C_2O_4)_3]~(3-) and[Fe(CN)_6]~(3-) complexes were obtained via intercalation and assembly processes.The composition,structure and property of the products thereby obtained have been studied by using XRD,FT-IR,ICP and TG-DTA. Catalytic activity for the H_2O_2 oxidation of cinnamaldehyde of the composite materials was also investigated.
The results indicated that,all the obtained composites had better organized stacking arrangement by controlling experimental conditions:when the Mg/Al ratio was 3.00,co-precipitation was under pH=9.0,aging at 90℃24 h;when the Ni/Al ratio was 2.00,ion-exchange processes was under pH=6.5 and 85-90℃or ambient temperature for 48 h.XRD and vibrational spectroscopy studies confirmed that the integrity of the transition metal complexes was preserved upon incorporation into LDHs.TG analysis showed that all the composite materials obtained had well thermal stability,the layer structure was completely destoried above 400℃.
The orientation and arrangement of the transition metal complexes within the interlayer had also been investigated.In the case of Mg_3Al- LDHs/[MY]the interlayer separation indicated that the guest species were arranged in a bilayer with the minimal dimension perpendicular to the host layers;In Ni_2Al-LDH/[Cr(C_2O_4)_3]、Ni_2Al-LDH /[Cr(C_3H_2O_4)_3]、Ni_2Al-LDH/[Fe(C_2O_4)_3]、Ni_2Al-LDH/[Fe(CN)_6]the guest species were all arranged in a monolayer with their C3 axises perpendicular to the host layers.These orientations can maximize the electrostatic force and hydrogen bonds between the host and guest species.The host materials can meet the matching of volume,electricity and construction of the guest species,which were main factors in affecting the orientation and arrangement of the guest species.
The catalytic activities of the composite materials were extensively studied.It was observed that the catalytic activities of the composite materials LDHs mainly attributed to the synergetic effect between transition metal complexes and LDHs.The most optimal catalytic performance came from the LDHs which the[CoY]~(2-) anion was intercalated into the interlayer space of Ni_3Fe-LDHs.
引文
[1]Vaccari A.Preparation and catalytic properties of cationic and anionic clays[J].Catal Today,1998,41:53-71.
[2]Cavani F,Trifiro F,Vaccari A.Hydrotalcite-Type anionic clays:preparation,properties and applications[J].Catal Today,1991,11:173-301.
[3]雷立旭,张卫锋,胡锰,等.层状复合金属氢氧化物:结构、性质及其应用[J].无机化学学报,2005,21(4):451-463.
[4]Newman S P,Jones W.Supramolecular Organization and Material Design[M].UK:Cam bridge University Press,2002.295-331.
[5]Trifiro F,Vaccari A.Comprehensive Supramolecular Chemistry[M].New York:Pergamon Press,1996.251-291.
[6]Vaccari A.Clays and catalysis:a promising future[J].Appl Clay Sci,1999,14:161-198.
[7]Makoto Ogawa,Kazuyuki Kuroda.Photofunctions of intercalation compounds[J].Chem.Rev,1995,95:399-438.
[8]徐征,叶兴凯,吴越.前景广阔的催化材料-水滑石类阴离子粘土[J].石油化工.1995,24:63-71.
[9]Roy D A,Forano C,El Malki K,et al.Synthesis of Microporous Materials[M].New York:Van Nostrand Reinhold Press,1992.108-169.
[10]Foshag W F.The chemical composition of hydrotalcite and the hydrotalcite group of minerals[J].Proc US Nat Museum,1920,58:147-153.
[11]Treadewell W D,Bernasconi E.Versuche zur elektrometrischen Titration von Aluminiumund Magnesiumion nebeneinander[J].Helv Chim Acta,1930,13:500-509.
[12]Feitknecht W.(U|¨)ber die α-Form der Hydroxyde zweiwertiger Metalle[J].Helv Chim Acta,1938,21:766-784.
[13]Feitknecht W,Gerber M.Zur Kenntnis der Doppelhydroxyde und basischen Doppelsalze Ⅲ.(U|¨)ber Magnesium-Aluminium doppelhydroxyde[J].Helv Chim Acta,1942,25:131-137.
[14]Feitknecht W.(U|¨)ber die Bildung von Doppelhydroxyden zwischen zwei-und dreiwertigen Metallen[J].Helv Chim Acta,1942,25:555-569.
[15]Allmann R.The crystal structure of pyroaurite[J].Acta Cryst,1968,B24:972-977.
[16]Taylor H F W.Segregation and cation-ordering of sjdgrenite and pyroaurite[J].Miner Mag,1969,37:338-342.
[17]Miyata S,Kumura T.Synthesis of new hydrotalcite-like compounds and their physico -chemical properties[J].Chem Lett,1973,8:843-848.
[18]Miyata S.The syntheses of hydrotalcite-like compoundsand their structure and physico -chemical properties-The systems Mg~(2+)-Al~(3+)-NO_3~-,Mg~(2+)-Al~(3+)-Cl~-,Mg~(2+)-Al~(3+)-ClO_4~-,Ni~(2+)-Al~(3+)-Cl~-and Zn~(2+)-Al~(3+)-Cl~-[J].Clay Miner,1975,23:369-375.
[19]Miyata S,Okada A.Synthesis of hydrotalcite-like compounds and their physico-chemical properties-The systems Mg~(2+)-Al~(3+)-SO_4~(2-) and Mg~(2+)-Al~(3+)-CrO_4~(2-)[J].Clay Miner,1977,25:14-18.
[20]Rives V,Ulibarri M A.Layered double hydroxides(LDHs) intercalated with metal coordinati- on compounds and oxometalates[J].Coordin Chem Rev,1999,181:61-120.
[21]Velu S,Ramaswamy V,Sivasanker S.New hydrotalcite-like anionic clays containing Zr~(4+) in the layers[J].Chem Commun,1997,62:2107-2108.
[22]Velu S,Suzuki K,Osaki T,et al.Synthesis of new Sn incorporated layered double hydroxides and their evolution to mixed oxides[J].Mater Res Bull,1999,34:1707-1717.
[23]Das N,Samal A.Synthesis,characterisation and rehydration behaviour of titanium(Ⅳ)containing hydrotalcite like compounds[J].Micro Meso Mater,2004,72:219-225.
[24]Roy D A,Forano C,Besse J P,et al.Expanded Clays and Other Microporous Solids[M].New York:Van Nostrand Reinhold Press,1992.108-169.
[25]Alejandre A,Medina F,Rodriguez X,.Cu/Ni/Al layered double hydroxides as precursors of catalysts for the wet air oxidation of phenol aqueous solutions[J].Appl Catal B Environmental,2001,30:195-207.
[26]Coq B,Tichit B,Ribet S.Co/Ni/Mg/Al Layered Double Hydroxides as Precursors of Catalysts for the Hydrogenation of Nitriles:Hydrogenation of Acetonitrile[J].Journal of Catalysis,2000,189:117-128.
[27]Porta P,Morpurgo S.Cu/Zn/Co/Al/Cr-containing hydrotalcite-type anionic clays[J].Appl ClaySci,1995,10:31-44.
[28]Newman P S,Jones W.Synthesis,characterization and applications of layered double hydroxides containing organic guests[J].New J Chem,1998,22:105-115.
[29]Meyn M,Beneke K,Lagaly G.Anion-exchange reactions of layered double hydroxides[J].Inorg Chem,1990,29:5201-5207.
[30]Park I Y,Kuroda K,Kato C.Direct synthesis of intercalation compounds between a layered double hydroxide and an anionic dye[J].J Chem Soc,Dalton Trans,1990,11:3071-3074.
[31]Oriakhi C O,Farr I V,Lemer M M.Incorporation ofpoly(acrylic acid),poly(vinylsulfonate)and poly(styrenesulfonate) within layered double hydroxides[J].J Mater Chem,1996,6:103-107.
[32]]Challier T,Slade C T.Nanocomposite materials:polyaniline-intercalated layered double hydroxides[J].J Mater Chem,1994,4:367-371.
[33]Messersmith P B,Stupp S I.High-Temperature Chemical and Microstructural Transformation of a Nanocomposite Organoceramic[J].Chem Mater,1995,7:454-460.
[34]Roto R,Villemure G.Mass transport in thin films of[Fe(CN)_6]~(4-) exchanged Ni-Allayered double hydroxide monitored with an electrochemical quartz crystal microbalance[J].J Electroanal Chem 2006,588:140-146.
[35]Malherbe F,Besse J P.Investigating the effects of guest-host intercalations on the properties of anion-exchanged Mg-Al hydrotalcites[J].J Solid State Chem,2000,15:332-341.
[36]Prevot V,Forano C,Besse J P.Intercalation of Anionic Oxalato Complexes into Layered Double Hydroxides[J].J Solid State Chem,2000,153:301-309.
[37]Bonnet S,Forano C,Besse J P.Synthesis of Hybrid Organo-Mineral Materials:Anionic Tetraphenylporphyrins in Layered Double Hydroxides[J].Chem Mater,1996,8:1962-1968.
[38]Park I Y,Kuroda K,Kato C.Preparation of a Layered Double Hydroxide-Porphyrin Intercalation Compound[J].Chem Lett,1989,18:2057-2058.
[39]Perezbernal M E,Ruanocasero R,Pinnavaia T J.Catalytic autoxidation of 1-decanethiol by cobalt(Ⅱ) phthalocyaninetetrasulfonate intercalated in a layered double hydroxide[J].Catal Lett,1991,11:55-62.
[40]Robins D S,Dutta P K.Examination of Fatty Acid Exchanged Layered Double Hydroxides as Supports for Photochemical Assemblies[J].Langmuir,1996,12:402-408.
[41]Hu C,He Q,Zhang Y,.Synthesis,stability and oxidative activity of polyoxometalates pillared anionic clays ZnAl-SiW_(11) and ZnAl-SiW_(11)Z[J].Catal Today,1996,30:41-146.
[42]Mark R,Weir,Ronald A,.Synthesis of heteropolyoxometalate-pillared Mg/Al,Mg/Ga and Zn/Al Layered Double Hydroxides via LDH-Hydroides Precursors[J].Inorg Chem,1998,37:619-5624.
[43]Ikeda T,Amoh H,Yasunaga T.Stereoselective exchange kinetics of L-and D-histidines for chloride ion in the interlayer of a hydrotalcite-like compound by the chemical relaxation method[J].J Am Chem Soc,1984,106:5772-5775.
[44]Aisawa S,Kudo H,Hoshi T.Intercalation behavior of amino acids into Zn-Al-layered doublehydroxide by calcinations-rehydration reaction[J].J Solid State Chem,2004,177:3987-3994.
[45]Choy J H,Kwak S Y,Park J S,et al.Intercalative Nanohybrids of Nucleoside Monophos -phates and DNA in Layered Metal Hydroxide[J].J Am Chem Soc,1999,121:1399-1400.
[46]Choy J H,Kwak S Y,Park J S,et al.Cellular uptake behavior of[γ~-~(32)P]labeled ATP-LDH nanohybrids[J].J Mater Chem,2001,11:1671-1674.
[47]Oh J M,Hwang S H,Choy J H.The effect of synthetic conditions on tailoring the size of hydrotacite particles[J].Solid State Ionics,2002,151:285-291.
[48]冯桃,李殿卿,D G Evans,等.层状双金属氢氧化物晶粒尺寸的控制[J].应用化学,2003, 21(2):117-120.
[49]Eduardo L,Crepaldi,Paulo C,.Comparative Study of the Coprecipitation Methods for the Preparation of Layered Double Hydroxides[J].J Brazil Chem Soc,2000,11:64-70.
[50]Courthy P,Marcilly C.Preparation of Catalysts Ⅲ[M].Amsterdam:Elsevier Press,1983.485-517.
[51]Yamaoka T,Abe M,Tsuji M.Synthesis of Cu-Al hydrotalcite like compound and its ion exchange property[J].Mater Res Bull,1989,24:1183-1199.
[52]Miyata S.Anion-Exchange Properties of Hydrotalcite-Like Compounds[J].Clays Clay Miner,1983,31:305-311.
[53]Chibwe K,Jones W.Intercalation of organic and inorganic anions into layered double hydroxides[J].J Chem Soc Chem Commun,1989,14:926-927.
[54]Morioka H,Tagaya H,Karasu M,et al.Preparation of New Useful Materials by Surface Modification of Inorganic Layered Compound[J].J Solid State Chem,1995,117:337-342.
[55]Grey I E,Ragozzini R.Formation and characterization of new magnesium aluminum hydroxycarbonates[J].J Solid State Chem,1991,94:244-253.
[56]Mariko A P,Forano C,Besse J P.Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction-control of size and morphology[J].J Mater Chem,2003,13:1988-1993.
[57]Zhao Y,Li F,Zhang R,et al.Preparation of Layered Double-Hydroxide Nanomaterials with a Uniform Crystallite Size Using a New Method Involving Separate Nucleation and Aging Steps[J].Chem Mater,2002,14:4286-4291.
[58]Prinetto F,Ghiotti G,Graffin P.Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples[J].Micropor Mesopor Mater,2000,39:229-247.
[59]Hickey L,Kloprogge J T,Frost R L.The effects of various hydrothermal treatments on magnesium-aluminium hydrotalcites[J].J Mater Sci,2000,35:4347-4355.
[60]Kannan S,Jasra R V.Microwave assisted rapid crystallization of Mg-M(Ⅲ) hydrotalcite where M(Ⅲ)=Al,Fe or Cr[J].J Mater Chem,2000,10:2311-2314.
[61]Gastuche M C,Brown G,Mortland M M.Mixed mangnesium-aluminium hydroxides[J].Clay Clay Miner,1967,17:177-192.
[62]矫庆泽,赵芸,谢晖,等.水滑石的插层及其选择性红外吸收性能[J].应用化学,2002,19:1011-1013.
[63]Sun W L,He Q L,Luo Y.Synthesis and properties of cinnamic acid series organic UV ray absorbents-interleaved layered double hydroxides[J].Mater Lett,2007,61:1881-1884.
[64]He Q,Yin S,Sato T.Synthesis and photochemical properties of zinc-aluminum layered double hydroxides/organic UV ray absorbing molecule/silica nanocomposites[J].J Phys Chem Solid,2004,65:395-402.
[65]Sun W,He Q,Lu L,et al.Synthesis and properties of layered double hydroxides intercalated with cinnamic acid series organic UV ray absorbents[J].Mater Chem Phys,2008,107:261-265.
[66]任庆利,罗强,吴洪才.镁铝摩尔比对水滑石电缆阻燃剂热性能的影响[J].绝缘材料,2001,6:22-25.
[67]赵芸,梁吉,李峰,等.纳米LDH作为热稳定剂在PMMA中的应用[J].应用化学,2003,20:382-386.
[68]Costantino U,Coletti N,Nocchetti M.Surface uptake and intercalation of fluorescein anions into Zn-Al-hydrotalcite,Photophysical characterization of material obtained[J].Langmuir,2000,16:10351-10358.
[69]Guo S C,Evans D G,Li D Q.Preparation of C.I.Pigrnent 52:1 anion-pillared layered double hydroxide and the thermo- and photostability of the resulting intercalated material[J].J Phys ChemSolid,2006,67:1002-1006.
[70]Auxilio A R,Andrews P C,Junk P C,et al.Adsorption and intercalation of Acid Blue 9 on Mg-Al layered double hydroxides of variable metal composition[J].Polyhedron,2007,26:3479-3490.
[71]唐明义,耿奎士.高分子药物缓释材料[J].化工新型材料,1998,26:26-28.
[72]Khan A I,Lei L,Norquist A J,et al.Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide[J].Chem Commun,2001,8:2342-2343.
[73]Ambrogi V,Fardella G,Grandolini G.Intercalation compounds of hydrotalcite-like anionic clays with anti-inflammatory agents I:intercalation and in vitro release of ibuprofen[J].Int J Pharm,2001,220:23-32.
[74]孟锦宏,张慧,Evans D G,等.新型层状农药缓/控释材料-草甘膦插层双金属氢氧化物的超分子结构与缓释性能[J].科学通报,2005,50:208-214.
[75]Huang L,Li D Q,Evans D G,et al.Preparation of highly dispersed MgO and its bactericidal properties[J].Eur Phys J D,2005,34:321-323.
[76]]Li C,Wang G,Evans D G,et al.Incorporration of rare-earth ions in Mg-Al layered double hydroxides:intercalation with an[Eu(EDTA)]~- chelate[J].J Solid State Chem,2004,177:4569-4575.
[77]周彤,李峰,战可涛,等.层状前体镍铁水滑石及磁性材料的制备及表征[J].化学学报,2002,60:1078-1083.
[78]周彤,战可涛,李峰,等.层状前体镁铁水滑石及磁性材料的制备及表征[J].无机化学学报,2002,18:777-781.
[79]陈忠明,陶克毅.固体碱催化剂的研究进展[J].化工进展,1994,3:18-25.
[80]Tichit D,Lutic D,Coq B,et al.The aldol condensation of acetaldehyde and heptanal on hydrotalcite-type catalysts[J].J Catal,2003,219:167-175.
[81]Unnihrishnan R,Narayanan S.Metal containing layered double hydroxides as efficient catalyst precursors for the selective conversion of acetone[J].J Mol Catal A,1999,144:173-179.
[82]Roelofs J C A A,Van Dillen A J,De Jong K P.Base-catalyzed condensation of citral and acetone at low temperature using modified hydrotalcite catalysts[J].Catal Today,2000,60:297-303.
[83]Chen Y Z,Hwang C M,Liaw C W.One-step synthesis of methyl isobutyl ketone from acetone with calcined Mg/Al hydrotalcite-supported palladium or nickel catalysts[J].Appl Catal A,1998,169:207-214.
[84]Tichit D,Bennani M N,Figueras F,et al.Aldol condensation of acetone over layered double hydroxides of the meixnerite type[J].Appl Clay Sci,1998,13:401-415.
[85]Reichle W T.Catalytic reactions by thermally activated,synthetic,anionic clay minerals[J].J Catal,1985,94:547-557.
[86]Palomares A E,Eder-Mirth G,Rep M,et al.Alkylation of Toluene over Basic Catalysts-Key Requirements for Side Chain Alkylation[J].J Catal,1998,180:56-65.
[87]Climent M J,Corma A,Iborra S,et al.Activated hydrotalcites as catalysts for the synthesis of chalcones of pharmaceutical interest[J].J Catal,2004,221:474-482.
[88]Suzuki E,Nomoto Y,Okamoto M,et al.Disproportionation of triethoxysilane over KF/A1203 and heat-treated hydrotalcite[J].Appl Catal A,1998,167:7-10.
[89]Fraile J M,Garcia J I,Mayotal J A.Basic solids in the oxidation of organic compounds[J].Catal Today,2003,57:3-16.
[90]Takehira K,Shishido T,Wang P,et al.Autothermal reforming of CH_4 over supported Ni catalysts prepared from Mg-Al hydrotalcite-like anionic clay[J].J Catal,2004,221:43-54.
[91]Tsyganok A I,Suzuki K,Hamakawa S,et al.Mg-Al Layered Double Hydroxide Intercalated with[Ni(edta)]~(2-) Chelate as a Precursor for an Efficient Catalyst of Methane Reforming with Carbon Dioxide[J].Catal Lett,2001,77:75-86.
[92]Dubey A,Kannan S,Velu S,et al.Catalytic hydroxylation of phenol over CuM(Ⅱ)M(Ⅲ) ternary hydrotalcites,where M(Ⅱ) = Ni or Co and M(Ⅲ) = Al,Cr or Fe[J].Appl Catal A,2003,238:319-326.
[93]Dubey A,Rives V,Kannan S.Catalytic hydroxylation of phenol over ternary hydrotalcites containing Cu,Ni andAl[J].J Mol Catal A,2002,181:151-160.
[94]Narayanan S,Krishna K.Structure activity relationship in Pd/hydrotalcite:effect of calcination of hydrotalcite on palladium dispersion and phenol hydrogenation[J].Catal Today,1999,49:57-63.
[95]Gines M J L,Amadeo N,Laborde M,et al.Activity and structure-sensitivity of the water-gas shift reaction over Cu-Zn-Al mixed oxide catalysts[J].Appl Catal A,1995,131:283-296.
[96]Carpentier J,Lamonier J F.Siffert S,et al.Characterisation of Mg/Al hydrotalcite with interlayer palladium complex for catalytic oxidation of toluene[J].Appl Catal A,2002,234:91-101.
[97]Chatti I,Ghorbel A,Grange P,et al.Oxidation of mercaptans in light oil sweetening by cobalt(Ⅱ) phthalocyanine-hydrotalcite catalysts[J].Catal Today,2002,75:113-117.
[98]Amin S,Jayson G G.Humic substance uptake by hydrotalcites and PILCs[J].Water Res,1996,30 (2):299-306.
[99]Ulibarri M A,Pavovic I,Hermosin M C,et al.Hydrotalcite-like compounds as potential sorbents of phenols from water[J].Apply Clay Sci,1995,10:131-145.
[100]Bailar J C,Jones E M.Inorganic Synthesis Vol.1[M].New York:Mcgraw-Hill Book Company Press,1939.35-39.
[101]Britton H T S,Jarrett M E D.Physicochemical studies of complex formation involving weak acids.Part XIV.Complex formation between malonates of the heavy metals and of sodium[J].J Chem Soc,1935,10:1728-1735.
[102]Weakliem H A,Hoard J L.The Structures of Ammonium and Rubidium Ethylenediaminetetra-acetatocobaltate(Ⅲ)[J].J Am Chem Soc,1959,81:549-555.
[103]Smith G S,Hoard J H.The Structure of Dihydrogen Ethylenediaminetetraacetatoaquo nickel (Ⅱ)[J].J Am ChemSoc,1959,81:556-561.
[104]Kirschner S.Six-coordinate Copper(Ⅱ)[J].J Am Chem Soc,1956,78:2372-2375.
[105]Brintzinger H,Hesse G.Kupfer-,Nickel-und Uranylverbindungen der Athylendiam-intetraessigsaure[J].Z Anorg Allgem Chem,1942,249:113-118.
[106]Wyckoff R W G.Crystal Structures,2nd ed[M].New York:Interscience Publishers,1996.418-419.
[107]Gutmann N H,Spiccia L,Turney T W.Complexation of Cu(Ⅱ) and Ni(Ⅱ) by nitrilotriacetate intercalated in Zn-Cr layered double hydroxides[J].J Mater Chem,2000,10:1219-1224.
[108]Tsyganok A,Sayari A.Incorporation of transition metals into Mg-Al layered double hydroxides:Coprecipitation of cations vs.their pre-complexation with an anonic chelator[J].J Solid State Chem,2006,179:1830-1841.
[109]Tarasov K A,O'Hare D.Solid-State chelation of metal ions by ethylenediaminetetraacetate intercalated in a layered double hydroxides[J].Inorg Chem,2003,42:1919-1927.
[110]You Y W,Zhao H T,Vance G F.Hybrid organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate:Preparation and adsorption characteristics[J].J Mater Chem,2002,12:907-912.
[111]Kloprogge J T,Frost R L.Infrared and Raman Spectroscopic Studies of Layered Double Hydroxides(LDHs) in Layered Double Hydroxides:Present and Future[M].New York:Nova Press,2001.139-192.
[112]Nakamoto K.Infrared and Raman Spectra of Inorganic and Coordination Compounds[M].New York:Wiley-Interscience Press,1997.88-95,180-184.
[113]Sumio Aisawa,Yuuki Ohnuma,Kimihiro Hirose,et al.Intercalation of nucleotides into layered double hydroxides by ion-exchange reaction[J].Appl Clay Sci,2005,28:137-145.
[114]Holgado M J,Rives V,Sanroman M S,et al.Hexacyanoferrate-interlayered hydrotalcite[J].Solid State Ionics,1996,92:273-283.
[115]Nijs H,Bock M D,Vansant E F.Evaluation of the microporosity of pillared[Fe(CN)_6]-MgAl -LDHs[J].Micro Meso Mater,1999,30:243-253.
[116]Idemura S,Suzuki E,Ono Y.Electronic state of iron complexes in the interlayer of hydrotalcite-like materials[J].Clay Clay Miner,1989,37:553-557.
[117]Kikkawa S,Koizumi M.Ferrocyanide anion bearing Mg,Al hydroxide[J].Mater Res Bull,1982,17:191-198.
[118]Grant N W,Dodgen H W,Hunt J P.Oxygen-17 nuclear magnetic resonance study of nickel (Ⅱ)-ethylenediaminetetraacetate complexes in aqueous solution[J].J Am Chem Soc,1971,93:6828-6831.
[119]徐克勤.精细有机化工原料及中间体手册[M].北京:化学化工出版社,1986.3-151.
[120]王直刚.肉桂酸的制备[J].广西化工,1996,25:28-31.
[2]Cavani F,Trifiro F,Vaccari A.Hydrotalcite-Type anionic clays:preparation,properties and applications[J].Catal Today,1991,11:173-301.
[3]雷立旭,张卫锋,胡锰,等.层状复合金属氢氧化物:结构、性质及其应用[J].无机化学学报,2005,21(4):451-463.
[4]Newman S P,Jones W.Supramolecular Organization and Material Design[M].UK:Cam bridge University Press,2002.295-331.
[5]Trifiro F,Vaccari A.Comprehensive Supramolecular Chemistry[M].New York:Pergamon Press,1996.251-291.
[6]Vaccari A.Clays and catalysis:a promising future[J].Appl Clay Sci,1999,14:161-198.
[7]Makoto Ogawa,Kazuyuki Kuroda.Photofunctions of intercalation compounds[J].Chem.Rev,1995,95:399-438.
[8]徐征,叶兴凯,吴越.前景广阔的催化材料-水滑石类阴离子粘土[J].石油化工.1995,24:63-71.
[9]Roy D A,Forano C,El Malki K,et al.Synthesis of Microporous Materials[M].New York:Van Nostrand Reinhold Press,1992.108-169.
[10]Foshag W F.The chemical composition of hydrotalcite and the hydrotalcite group of minerals[J].Proc US Nat Museum,1920,58:147-153.
[11]Treadewell W D,Bernasconi E.Versuche zur elektrometrischen Titration von Aluminiumund Magnesiumion nebeneinander[J].Helv Chim Acta,1930,13:500-509.
[12]Feitknecht W.(U|¨)ber die α-Form der Hydroxyde zweiwertiger Metalle[J].Helv Chim Acta,1938,21:766-784.
[13]Feitknecht W,Gerber M.Zur Kenntnis der Doppelhydroxyde und basischen Doppelsalze Ⅲ.(U|¨)ber Magnesium-Aluminium doppelhydroxyde[J].Helv Chim Acta,1942,25:131-137.
[14]Feitknecht W.(U|¨)ber die Bildung von Doppelhydroxyden zwischen zwei-und dreiwertigen Metallen[J].Helv Chim Acta,1942,25:555-569.
[15]Allmann R.The crystal structure of pyroaurite[J].Acta Cryst,1968,B24:972-977.
[16]Taylor H F W.Segregation and cation-ordering of sjdgrenite and pyroaurite[J].Miner Mag,1969,37:338-342.
[17]Miyata S,Kumura T.Synthesis of new hydrotalcite-like compounds and their physico -chemical properties[J].Chem Lett,1973,8:843-848.
[18]Miyata S.The syntheses of hydrotalcite-like compoundsand their structure and physico -chemical properties-The systems Mg~(2+)-Al~(3+)-NO_3~-,Mg~(2+)-Al~(3+)-Cl~-,Mg~(2+)-Al~(3+)-ClO_4~-,Ni~(2+)-Al~(3+)-Cl~-and Zn~(2+)-Al~(3+)-Cl~-[J].Clay Miner,1975,23:369-375.
[19]Miyata S,Okada A.Synthesis of hydrotalcite-like compounds and their physico-chemical properties-The systems Mg~(2+)-Al~(3+)-SO_4~(2-) and Mg~(2+)-Al~(3+)-CrO_4~(2-)[J].Clay Miner,1977,25:14-18.
[20]Rives V,Ulibarri M A.Layered double hydroxides(LDHs) intercalated with metal coordinati- on compounds and oxometalates[J].Coordin Chem Rev,1999,181:61-120.
[21]Velu S,Ramaswamy V,Sivasanker S.New hydrotalcite-like anionic clays containing Zr~(4+) in the layers[J].Chem Commun,1997,62:2107-2108.
[22]Velu S,Suzuki K,Osaki T,et al.Synthesis of new Sn incorporated layered double hydroxides and their evolution to mixed oxides[J].Mater Res Bull,1999,34:1707-1717.
[23]Das N,Samal A.Synthesis,characterisation and rehydration behaviour of titanium(Ⅳ)containing hydrotalcite like compounds[J].Micro Meso Mater,2004,72:219-225.
[24]Roy D A,Forano C,Besse J P,et al.Expanded Clays and Other Microporous Solids[M].New York:Van Nostrand Reinhold Press,1992.108-169.
[25]Alejandre A,Medina F,Rodriguez X,.Cu/Ni/Al layered double hydroxides as precursors of catalysts for the wet air oxidation of phenol aqueous solutions[J].Appl Catal B Environmental,2001,30:195-207.
[26]Coq B,Tichit B,Ribet S.Co/Ni/Mg/Al Layered Double Hydroxides as Precursors of Catalysts for the Hydrogenation of Nitriles:Hydrogenation of Acetonitrile[J].Journal of Catalysis,2000,189:117-128.
[27]Porta P,Morpurgo S.Cu/Zn/Co/Al/Cr-containing hydrotalcite-type anionic clays[J].Appl ClaySci,1995,10:31-44.
[28]Newman P S,Jones W.Synthesis,characterization and applications of layered double hydroxides containing organic guests[J].New J Chem,1998,22:105-115.
[29]Meyn M,Beneke K,Lagaly G.Anion-exchange reactions of layered double hydroxides[J].Inorg Chem,1990,29:5201-5207.
[30]Park I Y,Kuroda K,Kato C.Direct synthesis of intercalation compounds between a layered double hydroxide and an anionic dye[J].J Chem Soc,Dalton Trans,1990,11:3071-3074.
[31]Oriakhi C O,Farr I V,Lemer M M.Incorporation ofpoly(acrylic acid),poly(vinylsulfonate)and poly(styrenesulfonate) within layered double hydroxides[J].J Mater Chem,1996,6:103-107.
[32]]Challier T,Slade C T.Nanocomposite materials:polyaniline-intercalated layered double hydroxides[J].J Mater Chem,1994,4:367-371.
[33]Messersmith P B,Stupp S I.High-Temperature Chemical and Microstructural Transformation of a Nanocomposite Organoceramic[J].Chem Mater,1995,7:454-460.
[34]Roto R,Villemure G.Mass transport in thin films of[Fe(CN)_6]~(4-) exchanged Ni-Allayered double hydroxide monitored with an electrochemical quartz crystal microbalance[J].J Electroanal Chem 2006,588:140-146.
[35]Malherbe F,Besse J P.Investigating the effects of guest-host intercalations on the properties of anion-exchanged Mg-Al hydrotalcites[J].J Solid State Chem,2000,15:332-341.
[36]Prevot V,Forano C,Besse J P.Intercalation of Anionic Oxalato Complexes into Layered Double Hydroxides[J].J Solid State Chem,2000,153:301-309.
[37]Bonnet S,Forano C,Besse J P.Synthesis of Hybrid Organo-Mineral Materials:Anionic Tetraphenylporphyrins in Layered Double Hydroxides[J].Chem Mater,1996,8:1962-1968.
[38]Park I Y,Kuroda K,Kato C.Preparation of a Layered Double Hydroxide-Porphyrin Intercalation Compound[J].Chem Lett,1989,18:2057-2058.
[39]Perezbernal M E,Ruanocasero R,Pinnavaia T J.Catalytic autoxidation of 1-decanethiol by cobalt(Ⅱ) phthalocyaninetetrasulfonate intercalated in a layered double hydroxide[J].Catal Lett,1991,11:55-62.
[40]Robins D S,Dutta P K.Examination of Fatty Acid Exchanged Layered Double Hydroxides as Supports for Photochemical Assemblies[J].Langmuir,1996,12:402-408.
[41]Hu C,He Q,Zhang Y,.Synthesis,stability and oxidative activity of polyoxometalates pillared anionic clays ZnAl-SiW_(11) and ZnAl-SiW_(11)Z[J].Catal Today,1996,30:41-146.
[42]Mark R,Weir,Ronald A,.Synthesis of heteropolyoxometalate-pillared Mg/Al,Mg/Ga and Zn/Al Layered Double Hydroxides via LDH-Hydroides Precursors[J].Inorg Chem,1998,37:619-5624.
[43]Ikeda T,Amoh H,Yasunaga T.Stereoselective exchange kinetics of L-and D-histidines for chloride ion in the interlayer of a hydrotalcite-like compound by the chemical relaxation method[J].J Am Chem Soc,1984,106:5772-5775.
[44]Aisawa S,Kudo H,Hoshi T.Intercalation behavior of amino acids into Zn-Al-layered doublehydroxide by calcinations-rehydration reaction[J].J Solid State Chem,2004,177:3987-3994.
[45]Choy J H,Kwak S Y,Park J S,et al.Intercalative Nanohybrids of Nucleoside Monophos -phates and DNA in Layered Metal Hydroxide[J].J Am Chem Soc,1999,121:1399-1400.
[46]Choy J H,Kwak S Y,Park J S,et al.Cellular uptake behavior of[γ~-~(32)P]labeled ATP-LDH nanohybrids[J].J Mater Chem,2001,11:1671-1674.
[47]Oh J M,Hwang S H,Choy J H.The effect of synthetic conditions on tailoring the size of hydrotacite particles[J].Solid State Ionics,2002,151:285-291.
[48]冯桃,李殿卿,D G Evans,等.层状双金属氢氧化物晶粒尺寸的控制[J].应用化学,2003, 21(2):117-120.
[49]Eduardo L,Crepaldi,Paulo C,.Comparative Study of the Coprecipitation Methods for the Preparation of Layered Double Hydroxides[J].J Brazil Chem Soc,2000,11:64-70.
[50]Courthy P,Marcilly C.Preparation of Catalysts Ⅲ[M].Amsterdam:Elsevier Press,1983.485-517.
[51]Yamaoka T,Abe M,Tsuji M.Synthesis of Cu-Al hydrotalcite like compound and its ion exchange property[J].Mater Res Bull,1989,24:1183-1199.
[52]Miyata S.Anion-Exchange Properties of Hydrotalcite-Like Compounds[J].Clays Clay Miner,1983,31:305-311.
[53]Chibwe K,Jones W.Intercalation of organic and inorganic anions into layered double hydroxides[J].J Chem Soc Chem Commun,1989,14:926-927.
[54]Morioka H,Tagaya H,Karasu M,et al.Preparation of New Useful Materials by Surface Modification of Inorganic Layered Compound[J].J Solid State Chem,1995,117:337-342.
[55]Grey I E,Ragozzini R.Formation and characterization of new magnesium aluminum hydroxycarbonates[J].J Solid State Chem,1991,94:244-253.
[56]Mariko A P,Forano C,Besse J P.Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction-control of size and morphology[J].J Mater Chem,2003,13:1988-1993.
[57]Zhao Y,Li F,Zhang R,et al.Preparation of Layered Double-Hydroxide Nanomaterials with a Uniform Crystallite Size Using a New Method Involving Separate Nucleation and Aging Steps[J].Chem Mater,2002,14:4286-4291.
[58]Prinetto F,Ghiotti G,Graffin P.Synthesis and characterization of sol-gel Mg/Al and Ni/Al layered double hydroxides and comparison with co-precipitated samples[J].Micropor Mesopor Mater,2000,39:229-247.
[59]Hickey L,Kloprogge J T,Frost R L.The effects of various hydrothermal treatments on magnesium-aluminium hydrotalcites[J].J Mater Sci,2000,35:4347-4355.
[60]Kannan S,Jasra R V.Microwave assisted rapid crystallization of Mg-M(Ⅲ) hydrotalcite where M(Ⅲ)=Al,Fe or Cr[J].J Mater Chem,2000,10:2311-2314.
[61]Gastuche M C,Brown G,Mortland M M.Mixed mangnesium-aluminium hydroxides[J].Clay Clay Miner,1967,17:177-192.
[62]矫庆泽,赵芸,谢晖,等.水滑石的插层及其选择性红外吸收性能[J].应用化学,2002,19:1011-1013.
[63]Sun W L,He Q L,Luo Y.Synthesis and properties of cinnamic acid series organic UV ray absorbents-interleaved layered double hydroxides[J].Mater Lett,2007,61:1881-1884.
[64]He Q,Yin S,Sato T.Synthesis and photochemical properties of zinc-aluminum layered double hydroxides/organic UV ray absorbing molecule/silica nanocomposites[J].J Phys Chem Solid,2004,65:395-402.
[65]Sun W,He Q,Lu L,et al.Synthesis and properties of layered double hydroxides intercalated with cinnamic acid series organic UV ray absorbents[J].Mater Chem Phys,2008,107:261-265.
[66]任庆利,罗强,吴洪才.镁铝摩尔比对水滑石电缆阻燃剂热性能的影响[J].绝缘材料,2001,6:22-25.
[67]赵芸,梁吉,李峰,等.纳米LDH作为热稳定剂在PMMA中的应用[J].应用化学,2003,20:382-386.
[68]Costantino U,Coletti N,Nocchetti M.Surface uptake and intercalation of fluorescein anions into Zn-Al-hydrotalcite,Photophysical characterization of material obtained[J].Langmuir,2000,16:10351-10358.
[69]Guo S C,Evans D G,Li D Q.Preparation of C.I.Pigrnent 52:1 anion-pillared layered double hydroxide and the thermo- and photostability of the resulting intercalated material[J].J Phys ChemSolid,2006,67:1002-1006.
[70]Auxilio A R,Andrews P C,Junk P C,et al.Adsorption and intercalation of Acid Blue 9 on Mg-Al layered double hydroxides of variable metal composition[J].Polyhedron,2007,26:3479-3490.
[71]唐明义,耿奎士.高分子药物缓释材料[J].化工新型材料,1998,26:26-28.
[72]Khan A I,Lei L,Norquist A J,et al.Intercalation and controlled release of pharmaceutically active compounds from a layered double hydroxide[J].Chem Commun,2001,8:2342-2343.
[73]Ambrogi V,Fardella G,Grandolini G.Intercalation compounds of hydrotalcite-like anionic clays with anti-inflammatory agents I:intercalation and in vitro release of ibuprofen[J].Int J Pharm,2001,220:23-32.
[74]孟锦宏,张慧,Evans D G,等.新型层状农药缓/控释材料-草甘膦插层双金属氢氧化物的超分子结构与缓释性能[J].科学通报,2005,50:208-214.
[75]Huang L,Li D Q,Evans D G,et al.Preparation of highly dispersed MgO and its bactericidal properties[J].Eur Phys J D,2005,34:321-323.
[76]]Li C,Wang G,Evans D G,et al.Incorporration of rare-earth ions in Mg-Al layered double hydroxides:intercalation with an[Eu(EDTA)]~- chelate[J].J Solid State Chem,2004,177:4569-4575.
[77]周彤,李峰,战可涛,等.层状前体镍铁水滑石及磁性材料的制备及表征[J].化学学报,2002,60:1078-1083.
[78]周彤,战可涛,李峰,等.层状前体镁铁水滑石及磁性材料的制备及表征[J].无机化学学报,2002,18:777-781.
[79]陈忠明,陶克毅.固体碱催化剂的研究进展[J].化工进展,1994,3:18-25.
[80]Tichit D,Lutic D,Coq B,et al.The aldol condensation of acetaldehyde and heptanal on hydrotalcite-type catalysts[J].J Catal,2003,219:167-175.
[81]Unnihrishnan R,Narayanan S.Metal containing layered double hydroxides as efficient catalyst precursors for the selective conversion of acetone[J].J Mol Catal A,1999,144:173-179.
[82]Roelofs J C A A,Van Dillen A J,De Jong K P.Base-catalyzed condensation of citral and acetone at low temperature using modified hydrotalcite catalysts[J].Catal Today,2000,60:297-303.
[83]Chen Y Z,Hwang C M,Liaw C W.One-step synthesis of methyl isobutyl ketone from acetone with calcined Mg/Al hydrotalcite-supported palladium or nickel catalysts[J].Appl Catal A,1998,169:207-214.
[84]Tichit D,Bennani M N,Figueras F,et al.Aldol condensation of acetone over layered double hydroxides of the meixnerite type[J].Appl Clay Sci,1998,13:401-415.
[85]Reichle W T.Catalytic reactions by thermally activated,synthetic,anionic clay minerals[J].J Catal,1985,94:547-557.
[86]Palomares A E,Eder-Mirth G,Rep M,et al.Alkylation of Toluene over Basic Catalysts-Key Requirements for Side Chain Alkylation[J].J Catal,1998,180:56-65.
[87]Climent M J,Corma A,Iborra S,et al.Activated hydrotalcites as catalysts for the synthesis of chalcones of pharmaceutical interest[J].J Catal,2004,221:474-482.
[88]Suzuki E,Nomoto Y,Okamoto M,et al.Disproportionation of triethoxysilane over KF/A1203 and heat-treated hydrotalcite[J].Appl Catal A,1998,167:7-10.
[89]Fraile J M,Garcia J I,Mayotal J A.Basic solids in the oxidation of organic compounds[J].Catal Today,2003,57:3-16.
[90]Takehira K,Shishido T,Wang P,et al.Autothermal reforming of CH_4 over supported Ni catalysts prepared from Mg-Al hydrotalcite-like anionic clay[J].J Catal,2004,221:43-54.
[91]Tsyganok A I,Suzuki K,Hamakawa S,et al.Mg-Al Layered Double Hydroxide Intercalated with[Ni(edta)]~(2-) Chelate as a Precursor for an Efficient Catalyst of Methane Reforming with Carbon Dioxide[J].Catal Lett,2001,77:75-86.
[92]Dubey A,Kannan S,Velu S,et al.Catalytic hydroxylation of phenol over CuM(Ⅱ)M(Ⅲ) ternary hydrotalcites,where M(Ⅱ) = Ni or Co and M(Ⅲ) = Al,Cr or Fe[J].Appl Catal A,2003,238:319-326.
[93]Dubey A,Rives V,Kannan S.Catalytic hydroxylation of phenol over ternary hydrotalcites containing Cu,Ni andAl[J].J Mol Catal A,2002,181:151-160.
[94]Narayanan S,Krishna K.Structure activity relationship in Pd/hydrotalcite:effect of calcination of hydrotalcite on palladium dispersion and phenol hydrogenation[J].Catal Today,1999,49:57-63.
[95]Gines M J L,Amadeo N,Laborde M,et al.Activity and structure-sensitivity of the water-gas shift reaction over Cu-Zn-Al mixed oxide catalysts[J].Appl Catal A,1995,131:283-296.
[96]Carpentier J,Lamonier J F.Siffert S,et al.Characterisation of Mg/Al hydrotalcite with interlayer palladium complex for catalytic oxidation of toluene[J].Appl Catal A,2002,234:91-101.
[97]Chatti I,Ghorbel A,Grange P,et al.Oxidation of mercaptans in light oil sweetening by cobalt(Ⅱ) phthalocyanine-hydrotalcite catalysts[J].Catal Today,2002,75:113-117.
[98]Amin S,Jayson G G.Humic substance uptake by hydrotalcites and PILCs[J].Water Res,1996,30 (2):299-306.
[99]Ulibarri M A,Pavovic I,Hermosin M C,et al.Hydrotalcite-like compounds as potential sorbents of phenols from water[J].Apply Clay Sci,1995,10:131-145.
[100]Bailar J C,Jones E M.Inorganic Synthesis Vol.1[M].New York:Mcgraw-Hill Book Company Press,1939.35-39.
[101]Britton H T S,Jarrett M E D.Physicochemical studies of complex formation involving weak acids.Part XIV.Complex formation between malonates of the heavy metals and of sodium[J].J Chem Soc,1935,10:1728-1735.
[102]Weakliem H A,Hoard J L.The Structures of Ammonium and Rubidium Ethylenediaminetetra-acetatocobaltate(Ⅲ)[J].J Am Chem Soc,1959,81:549-555.
[103]Smith G S,Hoard J H.The Structure of Dihydrogen Ethylenediaminetetraacetatoaquo nickel (Ⅱ)[J].J Am ChemSoc,1959,81:556-561.
[104]Kirschner S.Six-coordinate Copper(Ⅱ)[J].J Am Chem Soc,1956,78:2372-2375.
[105]Brintzinger H,Hesse G.Kupfer-,Nickel-und Uranylverbindungen der Athylendiam-intetraessigsaure[J].Z Anorg Allgem Chem,1942,249:113-118.
[106]Wyckoff R W G.Crystal Structures,2nd ed[M].New York:Interscience Publishers,1996.418-419.
[107]Gutmann N H,Spiccia L,Turney T W.Complexation of Cu(Ⅱ) and Ni(Ⅱ) by nitrilotriacetate intercalated in Zn-Cr layered double hydroxides[J].J Mater Chem,2000,10:1219-1224.
[108]Tsyganok A,Sayari A.Incorporation of transition metals into Mg-Al layered double hydroxides:Coprecipitation of cations vs.their pre-complexation with an anonic chelator[J].J Solid State Chem,2006,179:1830-1841.
[109]Tarasov K A,O'Hare D.Solid-State chelation of metal ions by ethylenediaminetetraacetate intercalated in a layered double hydroxides[J].Inorg Chem,2003,42:1919-1927.
[110]You Y W,Zhao H T,Vance G F.Hybrid organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate:Preparation and adsorption characteristics[J].J Mater Chem,2002,12:907-912.
[111]Kloprogge J T,Frost R L.Infrared and Raman Spectroscopic Studies of Layered Double Hydroxides(LDHs) in Layered Double Hydroxides:Present and Future[M].New York:Nova Press,2001.139-192.
[112]Nakamoto K.Infrared and Raman Spectra of Inorganic and Coordination Compounds[M].New York:Wiley-Interscience Press,1997.88-95,180-184.
[113]Sumio Aisawa,Yuuki Ohnuma,Kimihiro Hirose,et al.Intercalation of nucleotides into layered double hydroxides by ion-exchange reaction[J].Appl Clay Sci,2005,28:137-145.
[114]Holgado M J,Rives V,Sanroman M S,et al.Hexacyanoferrate-interlayered hydrotalcite[J].Solid State Ionics,1996,92:273-283.
[115]Nijs H,Bock M D,Vansant E F.Evaluation of the microporosity of pillared[Fe(CN)_6]-MgAl -LDHs[J].Micro Meso Mater,1999,30:243-253.
[116]Idemura S,Suzuki E,Ono Y.Electronic state of iron complexes in the interlayer of hydrotalcite-like materials[J].Clay Clay Miner,1989,37:553-557.
[117]Kikkawa S,Koizumi M.Ferrocyanide anion bearing Mg,Al hydroxide[J].Mater Res Bull,1982,17:191-198.
[118]Grant N W,Dodgen H W,Hunt J P.Oxygen-17 nuclear magnetic resonance study of nickel (Ⅱ)-ethylenediaminetetraacetate complexes in aqueous solution[J].J Am Chem Soc,1971,93:6828-6831.
[119]徐克勤.精细有机化工原料及中间体手册[M].北京:化学化工出版社,1986.3-151.
[120]王直刚.肉桂酸的制备[J].广西化工,1996,25:28-31.