钼（钒）金属—氧簇的合成、结构与性能
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摘要
本论文是在水热合成条件下,使用成簇元素(Mo,W,V,等)的酸(盐)或是氧化物,引入适当的还原剂、选择合适的有机配体及第二种过渡金属,控制温度与pH等条件,合成了一系列具有新颖结构、优异性能的新型氧簇。所有合成的化合物都进行了元素分析,红外光谱及单晶衍射研究,同时对部分化合物的UV-Vis, XPS, TG, XRD, EPR及磁性进行了研究。
本论文合成了共十七个金属氧簇化合物,而且都为首次合成。
一.合成四个钒(钼)-氧簇合物[Fe(2,2`-bipy)_3]_2[HV_6~VV_(10)~(IV)O_(38)(Cl)]·4.67H_2O 1; [Ni(enMe)_3]_2[H_4V_5~VV_(10)~(IV)O_(36)(Cl)]·2H_2O 2 ; [HN(C_2H_5)_3]_3[PMo_(12)O_(40)]_3 ;[NH_2(C_2H_4NH_2)_2][Mo_5P_2O_(23)] 4。1是由簇[HV_6~VV_(10)~(IV)O_(38)(Cl)]6-与过渡金属配离子[Fe(2,2′-bipy)_3]~(3+)形成的二维超分子化合物; 2是由簇核[H_4V_5~VV_(10)~(IV)O_(36)(Cl)]~(4-)与平衡阳离子[Ni(enMe)_3]_2+结合形成新颖的二维超分子化合物。3是pseudo-Keggin结构阴离子[PMo_(12)O_(40)]~(3-)和质子化的阳离子TEA通过多点氢键形成三维超分子网络结构。4是[Mo_5P_2O_(23)]~(6-)阴离子和一个质子化的DETA阳离子通过多点氢键形成有趣的三维超分子网络结构。
二.合成了两个As-V-O簇合物[HAs_6V_(15)O_(42)(H_2O)][Cu(enMe)_2]_(2.5)·2H_2O 5;[H_2enMe]_2 [As_8V_(14)O_(42) (H_2O)]·3H_2O 6。5独特之处在于簇阴离子和两个不同构型双桥阳离子按照A-B-C-B-A-B-C-连接方式形成新颖一维链,链与链之间靠砖墙式的堆积方式形成二维空间结构。6含有特殊堆积方式的簇阴离子,三个相邻的簇阴离子聚合在一起形成一个等边三角形结构,这个聚合单元沿着c轴形成-A-B-A-B-堆积模式。
三.合成了七个具有Keggin结构的Mo-V-O簇合物[PMo_8V_6O_(42)][Co(Phen)_2(H_2O)]_2[TEA]_2·H_3O·3H_2O 7; [PMo_8V_6O_(42)][Ni(Phen)_2 (H_2O)]_2[TEA]_2·H_3O·3H_2O 8; [PMo_8V_6O_(42)][Zn(Phen)_2]_2[4,4′-bpy]·H_3O·3H_2O 9; [PMo_8V_6O_(42)][Co(Phen)_2][py]·4H_2O 10 ; [PMo_8V_6O_(42)][Co(Phen)_2] [Him]_2·2H_3O·3H_2O 11; {[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2(H_2O)]_2}{[PMo~(VI)_(10)V~(IV)_4O_(42)] [Co(Phen)_2]_2}·2OH-·4,4′-bpy 12; [H_2NC_4H_8NH_2]6 [Mo~(VI)_(16)V~V_(12)P_2O_(84)]·4H_2O 13。7-11的共同点是簇合物中有簇阴离子[PMo_8V_6O_(42)]6-,过渡金属阳离子,不同的有机胺以及水分子。化合物7,8和9都是簇阴离子支撑着过渡金属阳离子,形core {PMo12O40} with two antimony atoms capping two opposite pits. The most remarkable feature of compound 14-16 are that the novel anion [PMo_(12)O_(40)Sb_2]~(2-) is utilized as a multidentate chelating ligand, coordinating to the transition metal complex via the terminal oxygen atoms to yield an unprecedented 1-D chain. The linking mode of the chain is -A-A-A among compounds 14-16. For compound 17, it contains the first two types of Sb capped Keggin anions. The Si1, Si2 and Si3 POMs are connected together into a 2-D supramolecular layer (layer A) structure through the O···O interactions of the terminal oxygen atoms of the adjacent Si1, Si2 and Si2 POMs. The linking mode of the layer based on Si1 and Si2 POMs is -A-B-A-, while the linking mode of the layer based on Si3 is -A-A-A-. The most interesting feature is that the two different type layers are stacked together alternately. There still exit very complex hydrogen bonding interactions between the oxygen atoms of the anions and the water molecules into a novel supramolecular structure.
In this paper, by the applications of hydrothermal technique, through the use of a metal element (Mo, W, V etc.) acid (salt) or oxides, selecting the appropriate organic ligands as well as the second transition metal salts, controlling the temperature and pH of reaction system, we synthesized a series of polyoxometalates with novel structures and interesting properties. The structures of all the compounds have been characterized by elemental analyses, IR spectra and X-ray diffraction analyses, some compounds have been characterized by UV-Vis, XPS spectra, TG, XRD, EPR
analyses and magnetic property studies.
In this paper, 17 new metal oxygen clusters were synthesized.
I. Vanadium oxygen clusters and molybdenum- oxygen clusters By the applycation of hydrothermal synthesis technology, we synthesized two vanadium oxygen clusters and two molybdenum oxygen clusters. [Fe(2,2`-bipy)_3]_2[HV_6~VV_(10)~(IV)O_(38)(Cl)]·4.67H_2O 1; [Ni(enMe)_3]_2[H_4V_5~VV_(10)~(IV)O_(36) (Cl)]·2H_2O 2; [HN(C_2H_5)_3]_3[PMo_(12)O_(40)] 3; [NH_2(C_2H_4NH_2)_2][Mo_5P_2O_(23)]_4. Compound 1 is composed of the [HV_6~VV_(10)~(IV)O_(38)(Cl)]6- and transition metal complex [Fe(2,2`-bipy)_3]~(3+), Compound 2 is composed of an [H_4V_5~VV_(10)~(IV)O_(36)(Cl)]4- cluster and [Ni(enMe)_3]_2+. Both compounds are further linked into a novel two dimensional structure through hydrogen bonds. Compound 3 is composed of a pseudo-Keggin [PMo_(12)O_(40_]~(3-) anions and the protonated TEA cations. Compound 4 is composed of the [Mo_5P_2O~(23)]~(6-) anions and the protonated DETA moieties. Compound 3 and Compound 4 all exhibit an unusual 3-D supramolecular network structure through N-H···O hydrogen bonding interactions.
II. AsIII-VIV Polyoxometalates oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized two AsIII-VIV polyoxometalates. [HAs_6V_(15)O_(42)(H_2O)][Cu(enMe)_2]_2.5·2H_2O 5;[H_2enMe]_2 [As_8V_(14)O_(42) (H_2O)]·3H_2O 6. The two compounds have been firstly hydrothermally synthesized. X-ray crystallographic studies reveal that compound 5 represents the first example of 2-D structure constructed from [HAs_6V_(15)O_(42)(H_2O)]5- anions and TMCs. The anions [HAs_6V_(15)O_(42)(H_2O)]5- are connected by two different types of double-bridges into a novel chain structure. Moreover, there exits the“orientation”of the anions in chains, it exhibits an unprecedented -A-B↑-C-B↓-A-B↑-C-B↓- linking mode. And the chains are further connected into a brick-wall-like two-dimensional layer structure constructed from POMs and TMCs. Compound 6 exhibits very interesting stacking mode. The trimers are stacked along the c axis into a novel -A-B-A-B- stacking mode.
III. Keggin-structure molybdenum-vanadium oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized seven Keggin-structure tungsten oxygen clusters. [PMo_8V_6O_(42)][Co(Phen)_2(H_2O)]_2 [TEA]_2A·H_3O·3H_2O 7; [PMo_8V_6O_(42)][Ni(Phen)_2(H_2O)]_2[TEA]_2·H_3O·3H_2O 8; [PMo_8V_6O_(42)][Zn(Phen)_2]_2[4,4′-bpy]·H_3O·3H_2O9; [PMo_8V_6O_(42)][Co(Phen)_2][py]·4H_2O 10; [PMo_8V_6O_(42)][Co(Phen)_2][Him]_2·2H_3O·3H_2O 11; {[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2 (H_2O)]_2}{[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2]_2}·2OH-·4,4′-bpy 12; [H_2NC_4H_8NH_2]_6 [ Mo~(VI)_(16)V~V_(12) P_2O_(84)]·4H_2O 13
The seven compounds all were first synthesized. Compounds 7-11 all contain [PMo_8V_6O_(42)]5- anion, transition metal complex, organic amine, protonated water molecule, and water molecules. Compound 7, 8 and 9 are POM supported coordination complexes, while the compound 10 and compound 11 exhibit 1-D extended structures. In addition, the POMs, TMCs and the organic amines construct a supramolecular structure through hydrogen bonds between the oxygen atoms of the water molecules and the oxygen atoms of the anions and the weak van der Waals interactions. Among compounds 10, 11 and 12, there exit a mass of phenol rings between organic amine and transition metal complex, however, there did not exist strongπ···πinteractions between the rings for the steric hindrance.
Compound 12 contains two half of crystallographically different anions [PMo~(VI)_(10)V~(IV)_4O_(42)]~(3-), named as POM 1 and POM 2, respectively. The POM 1 supports two [Co(Phen)_2(H_2O)]~(2+) TMCs with the Co-O bond forming a novel bi-supported coordination complex. POM 2 interconnect [Co(Phen)_2]~(2+) via the Co-O bonds to yield an unusual infinite 2-D {[PMo_(10)V_4O_(42)][Co(Phen)_2]~(2+)} positive layer. Moreover, the discrete POM is sandwiched by two adjacent layers into a novel–ABAB- stacking fashion. According to the synthesis of Compound 7-12, we can get an interesting conclusion: different building blocks will build different structures. This approach using different building blocks to build different structures is quite attractive and appears to hold the key to the development of rational approaches for tailor-making materials based on polyoxometalates with desirable features. Compound 13 is composed of [Mo~(VI)_(16)V~V_(12)P_2O_(84)]~(14-) by polymerization of two basic unit { Mo8V6P O42}, containing six piperazines and five water molecules around. The every four dimers and the seven piperazines along a certain direction are formed wind model like units through the hydrogen bonds, and the sub-unit repeats expansion to form a beautiful two-dimensional polymer layer, and then stacks into a three-dimensional network structure.
V. Keggin-structure molybdenum- antimony oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized four Keggin-structure molybdenum- antimony oxygen clusters. [PMo_(12)Sb_2O_(40)][Cu (enMe)_2]·4H_2O14;[PMo_(12)Sb_2O_(40)][Ni(enMe)_2]·4H_2O15;[PMo_(12)Sb_2O_(40)][Cu(en)_2]·H_3O·H_2O 16; [SiMo~(VI)_9MoV_3O_(40)Sb_2][SiMo~(VI)_7MoV_5O_(40)Sb_2](H_2en)_2 (en)0.5·(H_2O)8 17.
Since our group prepared the first Sb capped Pseudo-Keggin POM {PMo_(12)O_(40)Sb_2} in 2006, Compounds 14-17 were prepared first time for extended structures containing antimony. Compounds 14-16 all exhibit the well-known Pseudo-Keggin core {PMo12O40} with two antimony atoms capping two opposite pits. The most remarkable feature of compound 14-16 are that the novel anion [PMo12O40Sb2]_2- is utilized as a multidentate chelating ligand, coordinating to the transition metal complex via the terminal oxygen atoms to yield an unprecedented 1-D chain. The linking mode of the chain is -A-A-A among compounds 14-16. For compound 17, it contains the first two types of Sb capped Keggin anions. The Si1, Si2 and Si3 POMs are connected together into a 2-D supramolecular layer (layer A) structure through the O···O interactions of the terminal oxygen atoms of the adjacent Si1, Si2 and Si2 POMs. The linking mode of the layer based on Si1 and Si2 POMs is -A-B-A-, while the linking mode of the layer based on Si3 is -A-A-A-. The most interesting feature is that the two different type layers are stacked together alternately. There still exit very complex hydrogen bonding interactions between the oxygen atoms of the anions and the water molecules into a novel supramolecular structure.
本论文合成了共十七个金属氧簇化合物,而且都为首次合成。
一.合成四个钒(钼)-氧簇合物[Fe(2,2`-bipy)_3]_2[HV_6~VV_(10)~(IV)O_(38)(Cl)]·4.67H_2O 1; [Ni(enMe)_3]_2[H_4V_5~VV_(10)~(IV)O_(36)(Cl)]·2H_2O 2 ; [HN(C_2H_5)_3]_3[PMo_(12)O_(40)]_3 ;[NH_2(C_2H_4NH_2)_2][Mo_5P_2O_(23)] 4。1是由簇[HV_6~VV_(10)~(IV)O_(38)(Cl)]6-与过渡金属配离子[Fe(2,2′-bipy)_3]~(3+)形成的二维超分子化合物; 2是由簇核[H_4V_5~VV_(10)~(IV)O_(36)(Cl)]~(4-)与平衡阳离子[Ni(enMe)_3]_2+结合形成新颖的二维超分子化合物。3是pseudo-Keggin结构阴离子[PMo_(12)O_(40)]~(3-)和质子化的阳离子TEA通过多点氢键形成三维超分子网络结构。4是[Mo_5P_2O_(23)]~(6-)阴离子和一个质子化的DETA阳离子通过多点氢键形成有趣的三维超分子网络结构。
二.合成了两个As-V-O簇合物[HAs_6V_(15)O_(42)(H_2O)][Cu(enMe)_2]_(2.5)·2H_2O 5;[H_2enMe]_2 [As_8V_(14)O_(42) (H_2O)]·3H_2O 6。5独特之处在于簇阴离子和两个不同构型双桥阳离子按照A-B-C-B-A-B-C-连接方式形成新颖一维链,链与链之间靠砖墙式的堆积方式形成二维空间结构。6含有特殊堆积方式的簇阴离子,三个相邻的簇阴离子聚合在一起形成一个等边三角形结构,这个聚合单元沿着c轴形成-A-B-A-B-堆积模式。
三.合成了七个具有Keggin结构的Mo-V-O簇合物[PMo_8V_6O_(42)][Co(Phen)_2(H_2O)]_2[TEA]_2·H_3O·3H_2O 7; [PMo_8V_6O_(42)][Ni(Phen)_2 (H_2O)]_2[TEA]_2·H_3O·3H_2O 8; [PMo_8V_6O_(42)][Zn(Phen)_2]_2[4,4′-bpy]·H_3O·3H_2O 9; [PMo_8V_6O_(42)][Co(Phen)_2][py]·4H_2O 10 ; [PMo_8V_6O_(42)][Co(Phen)_2] [Him]_2·2H_3O·3H_2O 11; {[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2(H_2O)]_2}{[PMo~(VI)_(10)V~(IV)_4O_(42)] [Co(Phen)_2]_2}·2OH-·4,4′-bpy 12; [H_2NC_4H_8NH_2]6 [Mo~(VI)_(16)V~V_(12)P_2O_(84)]·4H_2O 13。7-11的共同点是簇合物中有簇阴离子[PMo_8V_6O_(42)]6-,过渡金属阳离子,不同的有机胺以及水分子。化合物7,8和9都是簇阴离子支撑着过渡金属阳离子,形core {PMo12O40} with two antimony atoms capping two opposite pits. The most remarkable feature of compound 14-16 are that the novel anion [PMo_(12)O_(40)Sb_2]~(2-) is utilized as a multidentate chelating ligand, coordinating to the transition metal complex via the terminal oxygen atoms to yield an unprecedented 1-D chain. The linking mode of the chain is -A-A-A among compounds 14-16. For compound 17, it contains the first two types of Sb capped Keggin anions. The Si1, Si2 and Si3 POMs are connected together into a 2-D supramolecular layer (layer A) structure through the O···O interactions of the terminal oxygen atoms of the adjacent Si1, Si2 and Si2 POMs. The linking mode of the layer based on Si1 and Si2 POMs is -A-B-A-, while the linking mode of the layer based on Si3 is -A-A-A-. The most interesting feature is that the two different type layers are stacked together alternately. There still exit very complex hydrogen bonding interactions between the oxygen atoms of the anions and the water molecules into a novel supramolecular structure.
In this paper, by the applications of hydrothermal technique, through the use of a metal element (Mo, W, V etc.) acid (salt) or oxides, selecting the appropriate organic ligands as well as the second transition metal salts, controlling the temperature and pH of reaction system, we synthesized a series of polyoxometalates with novel structures and interesting properties. The structures of all the compounds have been characterized by elemental analyses, IR spectra and X-ray diffraction analyses, some compounds have been characterized by UV-Vis, XPS spectra, TG, XRD, EPR
analyses and magnetic property studies.
In this paper, 17 new metal oxygen clusters were synthesized.
I. Vanadium oxygen clusters and molybdenum- oxygen clusters By the applycation of hydrothermal synthesis technology, we synthesized two vanadium oxygen clusters and two molybdenum oxygen clusters. [Fe(2,2`-bipy)_3]_2[HV_6~VV_(10)~(IV)O_(38)(Cl)]·4.67H_2O 1; [Ni(enMe)_3]_2[H_4V_5~VV_(10)~(IV)O_(36) (Cl)]·2H_2O 2; [HN(C_2H_5)_3]_3[PMo_(12)O_(40)] 3; [NH_2(C_2H_4NH_2)_2][Mo_5P_2O_(23)]_4. Compound 1 is composed of the [HV_6~VV_(10)~(IV)O_(38)(Cl)]6- and transition metal complex [Fe(2,2`-bipy)_3]~(3+), Compound 2 is composed of an [H_4V_5~VV_(10)~(IV)O_(36)(Cl)]4- cluster and [Ni(enMe)_3]_2+. Both compounds are further linked into a novel two dimensional structure through hydrogen bonds. Compound 3 is composed of a pseudo-Keggin [PMo_(12)O_(40_]~(3-) anions and the protonated TEA cations. Compound 4 is composed of the [Mo_5P_2O~(23)]~(6-) anions and the protonated DETA moieties. Compound 3 and Compound 4 all exhibit an unusual 3-D supramolecular network structure through N-H···O hydrogen bonding interactions.
II. AsIII-VIV Polyoxometalates oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized two AsIII-VIV polyoxometalates. [HAs_6V_(15)O_(42)(H_2O)][Cu(enMe)_2]_2.5·2H_2O 5;[H_2enMe]_2 [As_8V_(14)O_(42) (H_2O)]·3H_2O 6. The two compounds have been firstly hydrothermally synthesized. X-ray crystallographic studies reveal that compound 5 represents the first example of 2-D structure constructed from [HAs_6V_(15)O_(42)(H_2O)]5- anions and TMCs. The anions [HAs_6V_(15)O_(42)(H_2O)]5- are connected by two different types of double-bridges into a novel chain structure. Moreover, there exits the“orientation”of the anions in chains, it exhibits an unprecedented -A-B↑-C-B↓-A-B↑-C-B↓- linking mode. And the chains are further connected into a brick-wall-like two-dimensional layer structure constructed from POMs and TMCs. Compound 6 exhibits very interesting stacking mode. The trimers are stacked along the c axis into a novel -A-B-A-B- stacking mode.
III. Keggin-structure molybdenum-vanadium oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized seven Keggin-structure tungsten oxygen clusters. [PMo_8V_6O_(42)][Co(Phen)_2(H_2O)]_2 [TEA]_2A·H_3O·3H_2O 7; [PMo_8V_6O_(42)][Ni(Phen)_2(H_2O)]_2[TEA]_2·H_3O·3H_2O 8; [PMo_8V_6O_(42)][Zn(Phen)_2]_2[4,4′-bpy]·H_3O·3H_2O9; [PMo_8V_6O_(42)][Co(Phen)_2][py]·4H_2O 10; [PMo_8V_6O_(42)][Co(Phen)_2][Him]_2·2H_3O·3H_2O 11; {[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2 (H_2O)]_2}{[PMo~(VI)_(10)V~(IV)_4O_(42)][Co(Phen)_2]_2}·2OH-·4,4′-bpy 12; [H_2NC_4H_8NH_2]_6 [ Mo~(VI)_(16)V~V_(12) P_2O_(84)]·4H_2O 13
The seven compounds all were first synthesized. Compounds 7-11 all contain [PMo_8V_6O_(42)]5- anion, transition metal complex, organic amine, protonated water molecule, and water molecules. Compound 7, 8 and 9 are POM supported coordination complexes, while the compound 10 and compound 11 exhibit 1-D extended structures. In addition, the POMs, TMCs and the organic amines construct a supramolecular structure through hydrogen bonds between the oxygen atoms of the water molecules and the oxygen atoms of the anions and the weak van der Waals interactions. Among compounds 10, 11 and 12, there exit a mass of phenol rings between organic amine and transition metal complex, however, there did not exist strongπ···πinteractions between the rings for the steric hindrance.
Compound 12 contains two half of crystallographically different anions [PMo~(VI)_(10)V~(IV)_4O_(42)]~(3-), named as POM 1 and POM 2, respectively. The POM 1 supports two [Co(Phen)_2(H_2O)]~(2+) TMCs with the Co-O bond forming a novel bi-supported coordination complex. POM 2 interconnect [Co(Phen)_2]~(2+) via the Co-O bonds to yield an unusual infinite 2-D {[PMo_(10)V_4O_(42)][Co(Phen)_2]~(2+)} positive layer. Moreover, the discrete POM is sandwiched by two adjacent layers into a novel–ABAB- stacking fashion. According to the synthesis of Compound 7-12, we can get an interesting conclusion: different building blocks will build different structures. This approach using different building blocks to build different structures is quite attractive and appears to hold the key to the development of rational approaches for tailor-making materials based on polyoxometalates with desirable features. Compound 13 is composed of [Mo~(VI)_(16)V~V_(12)P_2O_(84)]~(14-) by polymerization of two basic unit { Mo8V6P O42}, containing six piperazines and five water molecules around. The every four dimers and the seven piperazines along a certain direction are formed wind model like units through the hydrogen bonds, and the sub-unit repeats expansion to form a beautiful two-dimensional polymer layer, and then stacks into a three-dimensional network structure.
V. Keggin-structure molybdenum- antimony oxygen clusters
By the applycation of hydrothermal synthesis technology, we synthesized four Keggin-structure molybdenum- antimony oxygen clusters. [PMo_(12)Sb_2O_(40)][Cu (enMe)_2]·4H_2O14;[PMo_(12)Sb_2O_(40)][Ni(enMe)_2]·4H_2O15;[PMo_(12)Sb_2O_(40)][Cu(en)_2]·H_3O·H_2O 16; [SiMo~(VI)_9MoV_3O_(40)Sb_2][SiMo~(VI)_7MoV_5O_(40)Sb_2](H_2en)_2 (en)0.5·(H_2O)8 17.
Since our group prepared the first Sb capped Pseudo-Keggin POM {PMo_(12)O_(40)Sb_2} in 2006, Compounds 14-17 were prepared first time for extended structures containing antimony. Compounds 14-16 all exhibit the well-known Pseudo-Keggin core {PMo12O40} with two antimony atoms capping two opposite pits. The most remarkable feature of compound 14-16 are that the novel anion [PMo12O40Sb2]_2- is utilized as a multidentate chelating ligand, coordinating to the transition metal complex via the terminal oxygen atoms to yield an unprecedented 1-D chain. The linking mode of the chain is -A-A-A among compounds 14-16. For compound 17, it contains the first two types of Sb capped Keggin anions. The Si1, Si2 and Si3 POMs are connected together into a 2-D supramolecular layer (layer A) structure through the O···O interactions of the terminal oxygen atoms of the adjacent Si1, Si2 and Si2 POMs. The linking mode of the layer based on Si1 and Si2 POMs is -A-B-A-, while the linking mode of the layer based on Si3 is -A-A-A-. The most interesting feature is that the two different type layers are stacked together alternately. There still exit very complex hydrogen bonding interactions between the oxygen atoms of the anions and the water molecules into a novel supramolecular structure.
引文
[1] POPE M T, MüLLER A . Polyoxometalate Chemistry. Kluwer, Dor drecht. 2001, 1-10.
[2]王恩波,胡长文,许林著.多酸化学导论[M].北京:化学工业出版社. 1998. 1.
[3] POPE M T著,王恩波等译.杂多和同多金属氧酸盐[M].长春:吉林大学出版社. 1991.
[4] KATSOULIS D E. A Survey of Applications of Polyoxometalates [J]. Chem. Rev.1998, 98, 359-387.
[5] KUNTSEVICH T S, TARKHOVA T N, RAKOVA E E. Plenum Publishing Corporation [J].1984, 133, 508-509.
[6] HAGRMAM P J, FINN R C, ZUBIETA J. Molecular manipulation of solid state structure: influences of organic components of vanadium oxide architectures [J]. Solid State Sci. 2001, 3, 745-774.
[7] FUCHS J, MAHJOUR S, PICKARDT J. Structure of the True Metavanadate Ion [J]. Angew. Chem. Int. Ed. Engl. 1976, 15, 374-375.
[8] HEINRICH D D. et al., Synthesis of tetranuclear and pentanuclear vanadium- oxide-carboxylate aggregates [J]. Chem. Soc. Chem. Commun.1989, 1411.
[9] WAY V W, KLEMPERER W G, YAGHI O M. A New Structure Type in Polyoxoanion Chemistry: Synthesis and Structure of the [V5O14]3- Anion [J]. Am. Chem. Soc. 1989, 111, 4518-4519.
[10] CHAE H K, KLEMPERER W G, DAY V W, An Organometal Hydroxide Route to [ (C5Me5)Rh]4(V6O19) [J]. Inorg.Chem. 1989, 28, 1423-1424.
[11] CHEN Q, LIU S, ZUBIETA J. A Cyclic Octa nuclear Polyoxoalkoxyvanadate (IV) with an Oxalate-Binding Cavity, [(n-C4H9)4N]2[V8O8(OCH3)16(C2O4)]. StructureComparison with the Analogous Polymolybdate (V) Complex [(n-C4H9)4 N2Mo8 (OC2H5)8 (C2O4)] [J]. 1989, 28, 4433-4434.
[12] DAY V W, KLEMPERER W G, MALTBIE D J. Where Are the Protons in H3V 10O283- ? '[J]. Am. Chem. Soc. 1987, 109, 2991-2992.
[13] DURAISAMY T, OJHA N, RAMANAN A, VITTAL J J. New Inorganic-Organic Hybrid Materials Based on Polyoxovanadates: [Morp]6 [VO4V14O32(OH)6]·2H2O, [Morp]VO3[HMTA-CH3]4[H2V10O28]·5H2O, and [HMTA-H] [HMTA-CH2OH]2[H5V10O28]·6H2O”[J]. Chem. Mater. 1999, 11, 2339-2349.
[14] DAY V W, KLEMPERER W G, YAGHI O M. Synthesis and characterization of a soluble oxide inclusion complex, [CH3CN.cntnd. (V12O32)4-] [J]. Am. Chem. Soc. 1989, 111, 5959-5960.
[15] HOU D, HAGEN K S, HILL C L. Tridecavanadate, [V13O34]3-, a new high-potential isopolyvanadate [J]. Am. Chem. Soc. 1992,114, 5864-5865.
[16] MüLLER A, KRICHEMEYER E, PENK M, WALBERG H J, B?GGE H. Spherical Mixed-Valence [V15O36]5 , an Example from an Unusual Cluster Family [J]. Angew. Chem, Int. Ed. Engl. 1987, 26, 1045-1046.
[17] HOU D, HAGEN K S, HILL C L. Pentadecavanadate, V15O429–, a new highly condensed fully oxidized isopolyvanadate with kinetic stability in water [J]. Chem. Soc. Chem. Commun.1993, 426-427.
[18] LIU C M, ZHANG D Q, XIONG M, ZHU D B. A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt (II) complex fragments as bridges [J]. Chem. Commun. 2002, 1416–1417.
[19] HAYASHI Y, FUKUYAMA K, TAKATERA T, UEHARA A. Synthesis and Structure of a New Reduced Isopolyvandate [V17O42]4-[J]. Chem. Lett. 2000, 770-771
[20] JOHNSON G K, SCHLEMPER E O. Existence and Structure of the Molecular Ion 18-Vanadate (IV) [J]. Am. Chem. Soc. 1978, 3645-3646.
[21] MüLLER A, PENK M, KRICKEMEYER E, B?GGE H, WALLBERG H J. [V19O41(OH)9]8 , An Ellipsoid-Shaped Cluster Anion Belonging to the Unusual Family of VIV/VV Oxygen Clusters [J]. Angew.Chem. Int. Ed. Engl. 1988, 27, 1719-1721.
[22] MüLLER A, Erich Krickemeyer, Michael Penk, Ralf Rohlfing, Anja Armatage, Hartmut B?gge.Template-Controlled Formation of Cluster Shellsor a Type of Molecular Recognition: Synthesis of [HV22O54(ClO4)]6- and [H2V18O44(N3)]5- [J]. Angew. Chem. Int. Ed. Engl.1991, 30, 1674-1677.
[23] MüLLER A, ROHLFING R, D?RING J, PENK M. Bildung einer Clusterhülle um einen zentralen Cluster durch einen: Selbstorganisationsproze: das gemischtvalente Polyoxovanadat [V34O82]10 [J]. Angew. Chem., 1991, 103, 575-577.
[24] MüLLER A, ROHLFING R, D?RING J, PENK M. Formation of a Cluster Sheath around a Central Cluster by a Self-Organization Process : the Mixed Valence Polyoxovanadate [V34O82]10- [J]. Angew. Chem. Int. Ed. Engl.1991, 30, 588-590.
[25] KHAN M I, YOHANNES E, POWELL D. Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4) (H2O)12]·24H2O [J]. Chem. Commun. 1999, 23-24.
[26] KHAN M I, YOHANNES E, DOEDENS R J. [M3V18O42(H2O)12(XO4)]·24 H2O (M = Fe, Co; X = V, S): Metal Oxide Based Framework Materials Composed of Polyoxovanadate Clusters [J]. Angew. Chem. Int. Ed. 1999, 38, 1292-1294.
[27] HAN M I, YOHANNES E, DOEDENS R J. A Novel Series of Materials Composed of Arrays of Vanadium Oxide Container Molecules, {V18O42(X)} (X = H2O, Cl-, Br-): Synthesis and Characterization of [M2(H2N(CH2)2NH2)5] [{M(H2N(CH2)2NH2)2}2V18O42(X)]·9H2O (M = Zn, Cd) [J]. Inorg. Chem. 2003, 42, 3125-3129.
[28] KHAN M I, YOHANNES E, POWELL D. Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-ray Crystal Structure of [H6Mn3VIV15VV4O46 (H2O)12]·30H2O [J]. Inorg. Chem.1999, 38, 212-213.
[29] KHAN M I, YOHANNES E, POWELL D. Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4)(H2O)12]·24H2O [J].Chem. Commun. 1999, 23-24.
[30] KHAN M I, AYESH S, DOEDENS R J, YUC M H, O’CONNORC C J. Synthesis and characterization of a polyoxovanadate cluster representing a new topology [J]. Chem. Commun.2005, 4658-4660.
[31] CHEN L, JIANG F L, LIN Z Z, ZHOU Y F, YUE C Y, HONG M C. A basket tetradecavandate cluster with blue luminescence [J]. Am. Chem. Soc. 2005, 127, 8588–8589.
[32] TRIPATHI A, HUGHBANKS T, CLEAR F A. The First Frame work Solid Composed of Vanado silica Clusters [J]. Am. Chem. Soc. 2003, 125, 10528- 10529.
[33] LIU S X, XIE L H , GAO B. An organic–inorganic hybrid material con structed from a three dimensional coordination complexcat ionic frame work an dentrapped hexadecavanadate clusters [J]. Chem. Commun. 2005, 5023-5025.
[34] PAN C L, XU J Q, LI G H, CUI X B, YE L, YANG G D. A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{VIV12VV6O42Cl [Ni(en)2]3}·8H2O [J]. Chem. Soc. Dalton Trans. 2003, 517-518.
[35] PAN C L, XU J Q, LI G H, CHU D Q, WANG T G. A three-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: Ni(en)3{VIV11VV5O38Cl{Ni(en)2}3}·4H2O [J]. Eur. J. Inorg. Chem. 2003, 1514-1517.
[36] KATO R, KOBAYASHI A, SASAKI Y. 1:14 Heteropolyvanadate of Phosphorus: Preparation and Structure [J]. Am.Chem.Soc.1980, 102, 6571-6572.
[37] HUANG G Q, ZHANG S W, WEI Y G, SHAO M C. Synthesis and crystal structure of the heteropolyvanadate anion [AsV12P40(VO)2]9?[J]. Polyhedron. 993, 12, (12) 1483-1485.
[38] DURAISAMY T, OJHA N, RAMANAN A, VITTAL J. J. New Inorganic-Organic Hybrid Materials Based on Polyoxovanadates:[Morp]6[VO4V14O32 (OH)6]·2H2O, [Morp]VO3[HMTA-CH3]4[H2V10O28] 5H2O, and [HMTA-H] [HMTA-CH2OH]2 [H5V10O28]·6H2O [J]. Chem. Mater. 1999, 11, 2339-2349.
[39] HAO N, QIN C, XU Y, WANG E B, LI Y G, SHEN E H, XU L. A new pseudo Keggin-type polyvanadate (NH4)4[H12VV12O36(VIVO4)]·11H2O: hydrothermal synthesis and crystal structure”[J]. Inorg Chem Comm. 2005, 8, 592-595.
[40]崔小兵.砷(钼)-钒-氧簇合物的合成、结构及性质研究[D].中国科学院研究生院[D], 2004.
[41]齐燕飞.功能化多金属钒酸盐的控制合成、结构和性质研究[D].东北师范大学研究生院.
[42] MüLLER A, D?RING J. A novel heterocluster with 3D-summetry containing twenty-one core atoms [As6V15O42(H2O)]6- [J]. Angew. Chem. Int. Ed.1988, 27, 1271-1271.
[43] HUAN G H, GREANEY M A, JACOBSON A J. The synthesis and crystal structure of a new polyoxovanadium cluster anion: [As8V14O42(0.5H2O)]4- [J]. Chem. Soc., Chem.Commun.1991, 160-261.
[44] CUI X B, XU J Q, DING L, DING H, YE L, YANG G Y. Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V15O42(H2O)]·2H2O [J]. Mol. Struct. 2003, 660, 131–137.
[45] CUI X B, XU J Q, LI Y, SUN Y H, YE L, YANG G Y. Hydrothermal synthesis and characterization of (enH2)3.5[As8V14O42(PO4)]·2H2O [J]. Mol. Struct. 2003, 655, 207–213.
[46] ZHENG S T, XU J Q, YANG G Y. Hydrothermal Syntheses and Structural Characterization of Two Novel Arsenic–Vanadium Clusters: [Co(2,2`-bpy)3]2 [As8V14O42(H2O)]·3H2O and [2,2`-bpy][Ni(2,2`-bpy)3]2[As8V14O42 (H2O)]·3H2O [J]. J. Cluster Sci. 2005, 1.
[47] ZHENG S T, CHEN Y M, ZHANG J, YANG G.Y. Two New Polyoxovanadate-supported Transition Metal Complexes: [Zn(en)2] [Zn(en)2 (H2O)2][{Zn(en)(enMe)}As6V15O42(H2O)]·4H2O and [Zn2(enMe)2(en)3] [{Zn(enMe)2} As6V15O42(H2O)]·4H2O [J]. Z. Anorg. Allg. Chem. 2006, 632, 155-159
[48] ZHENG S T, ZHANG J, YANG G Y. [{{Zn(en)2}2As6V15O42(H2O)}2 {Zn(en)2}]·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge [J].Chem. Lett. 2003, 32, 810.
[49] QI Y F, LI Y G, WANG E B , JIN H, ZHANG Z M, WANG X L, CHANG S. Syntheses and structures of four organic–inorganic hybrids based on the surface restricted [As8V14O42] building unit and various zinc coordination groups. Inorg anica Chimica Acta. 2007, 360, 1841-1853.
[50] ZHENG S T, ZHANG J,YANG G Y. [{Zn(enMe)2}2 (enMe)2 {Zn2 As8V12O40 (H2O)}·4H2O]: A Hybrid Molecular Material Based on Covalently Linked Inorganic Zn-As-V Clusters and Transition Metal Complexes via enMe Ligands Eur [J]. Inorg Chem. 2004, 2004-2007.
[51] ZHENG S T, M H WANG, YANG G Y. In Situ Ligand Reactions under Hydrothermal Conditions Afford a Novel Zinc-Substituted Polyoxovanadate Dimer [J]. Inorg Chem. 2007, 22, 9503.
[52] CUI X B, XU J Q, MENG H, ZHENG S T , YANG G Y. A Novel Chainlike As-V-O Polymer Based on a Transition Metal Complex and a Dimeric Polyoxoanion [J]. Inorg. Chem. 2004, 43, 8005-8009.
[53] ZHENG S T, CHEN Y M, ZHANG J, XU J Q, YANG G Y. Hybrid Inorganic–Organic 1D and 2D Frameworks with [As6V15O42]6– Polyoxoanions as Building Blocks [J]. Eur. Inorg. Chem. 2006, 397-406.
[54] CUI X B, XU J Q, SUN Y H, LI Y, YE L, YANG G Y. Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments[J]. Inorg Chem Comm. 2004, 7, 58-61.
[55] BU W M, YANG G Y, YE L, XU J Q, FAN Y G. One-Dimensional Arsenic-Vanadium Cluster Chain Bridged by Two Co(en)2 Groups [J]. Chem. Lett. 2000, 29, 462.
[56] CUI X B, XU J Q, LI Y, SUN Y H, YANG G Y. Hydrothermal Synthesis andCharacterization of a Novel Sinusoidal Layer Structure Constructed From Polyoxometalates and Coordination Complex Fragments. Eur [J]. Inorg. Chem. 2004, 1051-1055.
[57] QI Y F, LI Y G, WANG E B, JIN H, ZHANG Z M, WANG X L, CHANG S. Two unprecedented inorganic–organic boxlike and chainlike hybrids based on arsenic–vanadium clusters linked by nickel complexes [J]. Solid State Chem. 2007, 180, 382–389.
[58] QI Y F, LI Y G, WANG E B, JIN H, ZHANG Z M, WANG X L, Chang S. Synthesis and structure of four organic-inorganic hygbids bsased on the surface restricted [As8IIIV14IVO42] building unit and various zinc coordination groups [J]. Inorganica Chimica Acta. 2007, 360, 1841-1853.
[59] ZHANG L J, ZHAO X L, XU J Q, WANG T G, A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters: [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O [J]. Chem. Soc, Dalton Trans. 2002, 3275-3276.
[60] HU X X, XU J Q, CUI X B, SONG J F, WANG T G. A novel one-dimensional framework material constructed from antimony-substituted polyoxovanadium clusters: [(C2N2H10)2β-{SbIII8VIV14O42(H2O)}] (C2N2H8)·4H2O [J]. Inorg Chem Comm. 2004, 7, 264-267.
[61] IEBACH R, N?THER C, K?GERLER P, BENSCH W. [VIV15SbIII6O42]6?: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6? [J]. Dalton Trans. 2007, 3221-3223.
[62] TKOWSKI A, N?THER C, K?GERLER P, BENSCH W. [V16Sb4O42 (H2O)VO(C6H14N2)2}4]: A Terminal Expansion to a Polyoxovanadate Archetype [J]. Inorg Chem. 2008, 47, 1916-1918.
[63]迈克尔·波普著,王恩波等译,“杂多和同多金属氧酸盐”[M],吉林大学出版社1991, 24.
[64]杨国昱.长春:吉林大学博士学位论文, 1998.
[65]施展.无机-有机杂化晶体材料的合成与结构表征[D].长春:吉林大学化学学院,2002.
[66] ZAPF P J, WARREN C J, HAUSHALTER R C, ZUBIETA J. One-and two dimensional organic-inorganic composite solids constructed from molybdenum oxide and chain linked through{M(2,2`-bipy)}2+ fragments (M=Co,Ni,Cu) [J].Chem.Commun.1997,1543-1544.
[67] BURKHOLDER E, WRIGHT S, GOLUB V, O’CONNOR C J, ZUBIETA J. Solid state coordination chemistry of oxomolybdenum organoarsonate materials [J]. Inorg Chem. 2003, 42, 7460-7471.
[68] XU J Q, WANG R Z, YANG G Y, XING Y H, LI D M, BU W M, YE L, FAN Y G, YANG G D, XING Y, LIN Y H, JIA H Q. Metal–oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M (phen)2}2(Mo8O26)] (M = Ni or Co) [J]. Chem. Commun .1999, 983-984.
[69] LAN Y Q, LI S L, WANG X L, SHAO K Z, DU D Y, ZANG H Y, SU Z M. Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine [J]. Inorg. Chem. 2008, 47 (18), 8179-8187.
[70] HAN Z G, GAO Y Z, HU C W. Noncovalently Connected Framework Assembled from UnusualOctamolybdate-Based Inorganic Chain and Organic Cation. Cryst. Grow. Des. 2008, 8, 1261-1264.
[71] HAGRMAN D, ZAPF P J, ZUBIETA J. A two-dimensional network constructed from hexamolybdate, octamolybdate and Cu3(4,7-phen)3]3+ clusters: [{Cu3 (4,7-phen)3}2{Mo14O45}] [J]. Chem. Commun.1998, 1283-1284.
[72] LAN Y Q, LI S L, WANG X L, SHAO K Z, SU Z M, WANG E B. Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers [J]. Inorg. Chem. 2008, 47 (2), 529-534.
[73] HAGRAMAN D, ZAPF P J, ZUBIEAT J. A two dimentional network constructed from hexamolybdate octamolybdate and Cu3(47-phen)3]3+ clusters: [{Cu3(4,7-phen)3}2{Mo14O45}] [J]. Chem.Commun.1998, 1283-1284.
[74] SHA J Q, PENG J, ZHANG Y, PANG H J, TIAN A X, ZHANG P P, LIUH. Assembly of Multiply Chain-Modified Polyoxometalates: From One to Three-Dimensional and from Finite to Infinite Track[J]. Cryst. Grow. Des. 2009, 9, 1709.
[75] KHAN M I, CHEN Q, SALTA J, O’CONNOR C J, ZUBIETA J. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14 Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X=Na(H2O)3+: n=13, m=9; n=15, m=7. X= Mo: n=14, m=9; n=13, m=10) [J]. Inorg. Chem.1996, 35 (7), 1880-1901.
[76] MüLLER A, MEYER J, KRICKEMEYER E, BEUGHOLT C, B?GGE H, PETERS F, SCHMIDTMANN M, K?GERLER P, KOOP M J. Unusual Stepwise Assembly and Molecular Growth: [H14Mo37O112]14? and [H3Mo57V6 (NO)6O189(H2O)12(MoO)6]21? [J]. Eur.Chem. 1998, 4, 1000-1006.
[77] KHAN M I, CHEN Q, SALTA J, O’CONNOR C J, ZUBIETA J. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14 Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X=Na(H2O)3+: n=13, m=9; n=15, m=7. X= Mo: n=14, m=9; n=13, m=10) [J]. Inorg. Chem.1996, 35 (7), 1880-1901.
[78] KREBS B, PAULAT-BOSCHEN I. The structure of the potassium isopolymoly date K8[Mo36O12(H2O)16·nH2O (n = 36.40) [J]. Acta Crystallogr. B. 1982, 38, 1710.
[79] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, DEUGHOLT C, K?GRLER P, LU C Z. Formation of a Ring-Shaped Reduced“Metal Oxide”with the Simple Composition [(MoO3)176(H2O)80H32] [J]. Angew. Chem. Int. Ed. 1998, 37, 1220-1223.
[80] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, P K?GERLER, ROSU C, BECKMANN E.‘Nanoobjects’by Self-Assembly Concomitant with Modifications under Alterable Boundary Conditions: Incorpo ration of Paramagnetic Metal Centers (Cu2+) in Ring-ShapedMolybdenum- Oxide Based Clusters [J]. Angew. Chem. Int. Ed. 2001, 40, 4034-4037.
[81] MüLLER A, SHAH S Q N, B?GGE H., SCHMIDTMANN M. Molecular Growth from a Mo176 to a Mo248 Cluster [J]. Nature.1999, 397, 48-50.
[82] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, PETERS F. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed.1998, 40, 3360-3363.
[83] MüLLER A, ROY S, SCHMIDTMANN M, B?GGE H. Urea as‘deus ex machina’in giant molybdenum blue type cluster synthesis: an unusual hybrid compound with perspectives for related nano, supramolecular and extended structures [J]. Chem. Commun. 2002, 2000-2002.
[84] MüLLER A, K?GRLER P, KUHLMANN C. A variety of combinatorially linkable units as disposition: from a giant icosahedral Keplerate to multi-functional metal-oxide based network structures [J]. Chem. Commun, 1999, 1347-1358.
[85] CRONIN L, BEUGHOLT C, KRICKEMEYER E, SCHMIDTMANN M, B?GGE H, K?GERLER P, LUONG T K K, MüLLER A.“Molecular symmetry breakers’generating metal-oxide-based nanoobject fragments as synthons for complex structures: [{Mo128Eu4O388H10(H2O)81}2]20-, a giant-cluster dimmer [J]. Angew. Chem. Int. Ed. 2002, 41, 2805-2808.
[86] MüLLER A, ROY S. En route from the mystery of molybdenum blue via related manipulatable building blocks to aspects of materials science [J]. Coordin. Chem. Rev. 2003, 245, 153-166.
[87] LIU T B, DIEMANN E, LI H L, DRESS A W M, MüLLE A. R, Self-assembly in aqueous solution of wheel-shaped Mo-154 oxide clusters into vesicles [J]. Nature. 2003, 426, 59-62.
[88] MüLLER A, KOGERLER P, DRESS A W M. Giant metal-oxide-based spheres and their topology: from pentagonal building blocks to keplerates and unusual spin systems [J]. Coordin. Chem. Rev. 2001, 222, 193-218.
[89] BOTAR B, K?GERLER P, HILL C L. A Nanoring-Nanosphere Molecule, {Mo214-V30}: Pushing the Boundaries of Controllable Inorganic Structural Organization at the Molecular Level [J]. Am. Chem. Soc. 2006, 128, 5336-5337.
[90] JIANG C C, WEI Y G, LIU Q, ZHANG S W, SHAO M C, TANG Y Q. Self- assembly of a novel nanoscale giant cluster: [Mo176O496(OH)32(H2O)80] [J]. Chem. Commun.1998, 1937-1938.
[91] YANG W B, LU C Z, LIN X, ZHUANG H H. Novel Acetate Polyoxomolybdate“Host”Accommodating a Zigzag-Chainlike“Guest”of Five Edge-Shared Sodium Cations: Na21{[Na5(H2O)14][Mo46O134(OH)10 (μ-CH3COO)4]}·CH3COO Na·≈95H2O [J]. Inorg. Chem.2002, 41 (3), 452-454.
[92] MüLLER A, ZHOU Y S, B?GGE H.“Gating”the Pores of a Metal Oxide Based Capsule:After Initial Cation Uptake Susequent Cations AreFound Hydrated and Supramolecularly Fixed above the Pores [J ]. Angew. Chem: Int. Ed. 2006, 45, 460-465.
[93] MüLLER A, BECHKMANN E, B?GGE H, SCHMIDTMANN M, DREDD A. Inorganic Chemistry Goes Protein Size: A Mo368 Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int, Ed. Engl. 2002, 41, 1162 -1167
[94] TIAN A X, YING J, PENG J, SHA J Q, PANG H J, ZHANG P P, CHEN Y, ZHU M, SU Z M. Tuning the Dimensionality of the Coordination Polymer Based on Polyoxometalate by Changing the Spacer Length of Ligands [J]. Cryst. Grow. Des. 2008, 10, 3717-3724.
[95] DONG B X, XU Q. Structural Investigation of Flexible 1,4-Bis (1,2,4-triazol- 1-ylmethyl)benzene Ligand in Keggin-Based Polyoxometalate Frameworks [J]. Cryst. Grow. Des. 2009, 6, 2781.
[96] BJORNBERG A, B. HEDMAN. Multicomponent polyanions: Crystal structure and electron spin resonance spectrum of K6[V2Mo10VO40]?13H2O, a new one-electron heteropoly blue [J]. Acta Cryst.1980, B36, 1018.
[97] CHEN Q, HILL C. L. A Bivanadyl Capped, Highly Reduced Keggin Polyanion, [PMoV6MoVI6O40(VIVO)2]5-[J]. Inorg. Chem. 1996, 35, 2403-2405.
[98] SHI Z.Y, GU X J, PENG J, CHEN Y H. Controlled assembly of two new bicapped bisupporting Keggin-polyoxometalate derivatives: [M(2,2’-bipy)2 (H2O)]2[SiMoVI8MoV4VIV2O42](M = Co, Zn) [J]. Solid State Chem. 2005, 178, 1988-1995.
[99] SHI Z Y , GU X J, PENG J, WANG E B. Target synthesis of a new bicapped keggin polyoxometalate derivative: [Co(phen)3]2[SiMoVI8MoV4VIV2 O42]·H2O [J]. Mol. Struct. 2005, 737, 147-151.
[100] GU X J, PENG J, SHI Z Y, CHEN Y H, HAN Z H, WANG E B, MA J F, HU N H. Target syntheses of saturated Keggin polyoxometalate-based extended solids [J]. Inorg. Chim. Acta. 2005, 385, 3701-3710.
[101] SHI Z Y , GU X J, PENG J. Hydrothermal assembly of a new hydrogen-bonded network featuring bicapped dimerized [Si2Mo24O80 (VO)4]8- polyanion[J]. Inorg. Chem. Commun. 2005, 8, 886-889.
[102] GU X Y, PENG J, SHI Z Y, CHEN Y H., HAN Z G, WANG E B, MA J F, Hu N H. Target syntheses of saturated Keggin polyoxometalate-based extended solids [J]. Inorg. Chim. Acta. 2005, 358, 3701-3710.
[103] SHI Z Y, PENG J, C. J. GóMEZ-GARC?, BENMANSOUR S, GU X J. Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties [J]. Solid State Chem. [J] .2006, 179, 253-265.
[104] SHI Z Y , GU X J, PENG J, YU X, WANG E B. From molecular double-ladders to an unprecedented polycatenation: a parallel catenated 3D network containing bicapped Keggin polyoxometalate clusters [J]. Eur. Inorg. Chem. 2006, 385-388.
[105] SHA J Q, PENG J, LIU H S, CHEN J, TIAN A X, ZHANG P P. Asymmetrical Polar Modification of a Bivanadium-Capped Keggin POM by Multiple Cu-N Coordination Polymeric Chains [J]. Inorg. Chem. 2007, 46, 11183-11189.
[106] LUAN G Y, LI Y G., WANG E B, HAN Z B, HU C W, Hu N H, JIA H Q. hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)3]2[SiMo10VIV2O40(VIVO)2]·5H2O [J]. Inorg. Chem. Commun. 2002, 5, 509-511.
[107] LI F Y, XU L, WEI Y G, WANG E B. A new polyoxometalate-based complex with alternate ionic layer structures: hydrothermal synthesis, crystal structure and magnetic property [J]. Inorg. Chem. Commun.2005, 8, 263-266.
[108] ZHANG Y P, HAUSHALTER R C, CLEARAFIELD A. A heteropolyanion containing two linked mixed Mo/V pentadecaoxometalate clusters: structure of [Mo16V14O84]14-[J]. Chem. Commun. 1995, 1149-1150.
[109] MüLLER A, KOOP M, SCHIFFELS P, B?GGE H. [MoVI8VIV4O36(VVO4) (VIVO)2]7n-: capped Keggin fragments linked to a chain [J]. Chem. Commun. 1997, 1715-1716.
[110] LUAN G Y, WANG E B, HAN Z B, LI YG. Hydrothermal synthesis and structure of a bicapped 1D chain (H2en)3H3O[Mo8V4O36(VO4)(VO)2]·4H2O [J].Inorg. Chem. Commun. 2001, 4, 541-543.
[111] LIU C M, ZHANG D Q, ZHU D B. One- and two-dimensional coordination polymers constructed from bicapped Keggin mixed molybdenum-vanadium heteropolyoxoanions and polynuclear copper (I) clusters bridg by asymmetrical bipyridine (2,4’-bipy and 2,3’-bipy) ligands [J]. Cryst. Grow. Des. 2006, 6, 524-529.
[112] XU Y, XU J Q, YANG G Y, WANG T G., XING Y, LING YH, JIA H Q. Synthesis and structure of [NH4]4H[PMo8VIV4VV2O42]·24H2O [J]. Polyhedron. 1998, 17, 2441-2445.
[113] PAN C L, XU J Q, CHU D Q, LüZ L, DUAN L M , WANG T G. Reduced polyoxoanion with the bicapped quasi-Keggin structure [Ni(1,10’-phen)3] [Ni(en)3][Ni(en)2(H2O)2]{Ni(en)2}0.5}[PMoVI6MoV2VV2VIV4O42]·6H2O[J].Meedeleev Commun. 2002, 12, 233-234.
[114] ZENG Q X, XU J Q, SONG Y J, CUI X B, SHI Z. A bicappedα-Keggin unit-supported transition metal complex: Hydrothermal synthesis andcharacterization of [Cu(en)2(H2O)]2[Cu(en)2]0.5[Mo8V7O42{Cu(en)2}][J]. Z. Anorg. Allg. Chem. 2005, 631, 1528-1531.
[115] PAN C L, XU J Q, SUN Y, CHU D Q, YE L, LüZ L. WANG T G. First transition metal coordination compound supported on metal-oxygen cluster with bicapped quasi-Keggin structure: [Cu(en)2(H2O)]4[Cu(en)2]3.5[PMoVI8 VIV6O42Cu(en)(1,10’-phen)]3·14H2O [J]. Inorg. Chem. Commun. 2003, 6, 233-237.
[116] PAN C L, XU J Q, CHU D Q, LI G. H, LüZ L, YANG G D. First two- dimensional framework material constructed from bicapped Keggin structure clusters: {[PMoVI8VIV6O42Cu(en)2][Cu0.5(en)]}·5.5H2O [J]. Inorg. Chem. Commun. 2003, 6, 939-941.
[117] DUAN L M, PAN C L, XU J Q, CUI X B, XIE F T, WANG T G. Two- and Three-Dimensional Frameworks Constructed From Bicapped Keggin Clusters [J]. Eur. Inorg. Chem. 2003, 2578-2581.
[118] LUAN G Y, LI Y G, WANG E B, HAN Z B, HU C W, HU N H, JIA H Q. Hydrothermal synthesis and srystal structure of a bicapped Keggin polyoxoanions: [As2AsMo8V4O40]5-[J]. Inorg. Chem. Commun. 2001, 4, 632-634.
[119] XU Y, ZHU H G, CAI H, YOU X Z. [MoV2MoVI6VIV8O40(PO4)]5-: the first polyanion with a tetra-capped Keggin structure [J]. Chem. Commun.1999, 787-788.
[120] XU Y, ZHU D R, GUO Z J, SHI Y J, ZHANG K L, YOU X Z. Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions [J]. Dalton Trans. 2001, 772-773.
[121] XU Y, ZHU D R, SONG Y, ZHENG X F, YOU X Z. Hydrothermal synthesis and crystal structure of the novel mixed Mo/V metal–oxygen cluster compound [Co(C2N2H8)3]4[MoV2MoVI14VIV16O80(PO4)2]5-·10H2O containing the two types of typical heteropoly anions [J]. Mol. Struct. 2006, 782, 165-170.
[122] YUAN M, LI G Y, WANG E B, TIAN CG, WANG L, HU C W, HU N H,JIA HQ. Modified polyoxometalates: hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metalcomplexes [J]. Inorg. Chem. 2003, 42, 3670-3676.
[123] LI F Y, XU L, WEI Y G, WANG X L, WANG X L, WANG W J, WANG E B. Arsenicum-centered Molybdenum–Vanadium polyoxometalates bearing transition metal complexes: Hydrothermal syntheses, crystal structures and magnetic properties [J]. Mol. Struct. 2005, 753, 61-67.
[124] SUN Y H, XU J Q, YE L, CUI X B, LI Y, YU H H, LI G H, YANG G D, CHEN Y. Hydrothermal synthesis and crystal structural characterization of two new modified polyoxometalates constructed of positive and negative metal-oxo cluster ions”[ J]. Mol. Struct. 2005, 740, 193-201.
[125] SUN Y H, DING H, XU J Q, LI Y, LI G H. Hydrothermal synthesis and crystal structure of a highly reduced mixed molybdenum-vanadium polyoxometalate with phosphorus-centered [Ni(phen)3]2H2[PMoV4MoVI4VIV6M2O44]·4H2O (M = 0.78MoV + 0.22VIV) [J]. Chem. Res, Chinese U. 2005, 21, 368-371.
[126] SUN Y H, CUI XI B, LI G H, XU J Q, WANG T G , XU W, PAN L L, YANG Q X. A new mixed molybdenum-vanadium polyoxometalate double- supporting transition metal complex: {[Co(phen)2]2-C2O4}{H2PMoVI3 MoV5VIV8O44Co(phen)2(H2O)]2}·7H2O”[J]. J. Coord. Chem. 2005, 1561-1571.
[127] CUI X B, YANG G D. [{(H2O)Ni(enMe)2MoV4MoVI4VIV8(VVO4)O40}2 {Ni(enMe)2}][Ni(enMe)2]4·8H2O: The First Dimer of Polyoxometalates Linked through Coordination Fragment [J] .Chem. Letters.2002, 31,1238- 1239.
[128] DUAN L M, XU J Q, XIE F T, CUI X B, DING H, SONG J F. Synthesis and characterization of a new compound based on mixed Mo/V polyoxometalates connected and modified by [Ni(en)2]2+ groups [J]. Mendeleev commun. 2005, 9, 79-80.
[129]段莉梅,“金属簇聚物与配位聚合物的水热合成与表征”,吉林大学博士学位论文,2004.
[130] LIU Y B, CUI X B, XU J Q, LU Y K, LIU J, ZHANG Q B, YANG G D. Hydrothermal synthesis and characterization of three one-dimensional chain materials fromed by reduced tetra-capped Keggin polyoxoanions and [M(en)2]2+ (M = Cu, Co and Ni) cations[J]. Mol. Struct. 2006, 825, 45-52.
[131]崔小兵,郑寿添,杨国昱,“1-D链状簇合物[Ni(enMe)2]2[Ni(enMe)2- {HMoVI4MoV4VIV8O40(VVO4)}]·4H2O的水热合成和晶体结构”,结构化学(Chinese J. Struct. Chem). 2004. 3, 300-305.
[132] ZENG Q X, XU J Q, YANG G D, CUI X B, SONG J F, ZHENG Z D. Synthesis and structure of [Ni(en)2]2H{[Ni(en)2][MoVI4MoV4VIV8O40 (VVO4)]}·3H2O with 1-D extended heteronuclear chains [J]. Polish. J. Chem. 2001, 1791-1796.
[133] BU W M, YE L, YANG G D, GAO J S, FAN YG, SHAO Y G, XU J Q. One- and two-dimensional framework materials constructed from the mixed Mo/V tetra-capped Keggin structure clusters and M(en)2 (M = Ni, Cu) complexes groups [J]. Inorg. Chem. Commun. 2001, 4, 1-4.
[134] LIU C M, ZHANG D Q, XIONG M, ZHU D B. A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt (II) complex fragments as bridges”[J]. Chem. Commun. 2002, 1416-1417.
[135] LIU C M, ZHANG D Q, ZHU D B D. Mixed Molybdenum-Vanadium Polyoxoanion-Bridged Trimetallic Nanocluster Complexes: Hydrothermal Syntheses and Crystal Structures of {MoVI6MoV2VIV8O40(PO4)[Co(phen)2 (H2O)]2}[Co2(phen)2(OH)2(H2O)4]1/2 and {MoVI5MoV5VIV8O40(PO4)[Co(phen) (en) (H2O)]2}[Co2(phen)3]·1.5H2O [J]. Cryst. Grow. Des. 2003, 3, 363-368.
[136] LIU C M, LUO J L, ZHANG D Q, WANG N L, CHEN Z J,ZHU D B. Spin Glass Behaviour in a 1D Mixed Molybdenum-Vanadium Heteropolyoxo metalate-Bridged Coordination Polymer [J]. Eur. Inorg. Chem. 2004, 4774-4779.
[137] LIU C M, ZHANG D Q, ZHU D B. 3D Supramolecular Array Assembled byPolyoxometalate Bridged Coordination Polymer Chains: Hydrothermal Synthesis and Crystal Structure of {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]} [Ni(en)2]2·4H2O [J]. Cryst. Grow. Des. 2005, 5, 1639-1642.
[138] GONG Y, LI Y G, LI H, WANG Y H, HU C W. Synthesis, Characterization and Properties of Two Novel Complexes Based on 2-Aminopyridine and Polyoxometalates[J]. Chinese Journal of Chemistry. 2006, 24, 1148-1153.
[139] YANG W B, LU C Z, ZHAN X P , ZHUANG H H .Hydrothermal Synthesis of the first Vanadomolybdenum polyoxocation with a‘metal-bonded’spherical framework [J]. Inorg. Chem. 2002, 41, 4621-4623.
[140]卢玉坤,“非经典金属-氧簇合物的合成、结构与性能”,吉林大学博士学位论文, 2009.
[141] KHAN M I, CHEN Q, ZUBIETA J. Hydrothermal Synthesis and Structure of [H4AsIII2AsVMoV8MoVI4O40]?, A Bicapped, Reduced Keggin Species [J]. Inorg. Chem. 1993, 32 (13), 2924-2928.
[142] LUAN G Y, LI Y G , E.B. WANG E B, HAN Z B, HU C W, HU N H,JIA H Q. Hydrothermal synthesis and srystal structure of a bicapped Keggin polyoxoanions: [As2AsMo8V4O40]5- [J]. Inorg. Chem. Commun. 2001, 4, 632-634.
[143] ZHANG Q B, LU Y K, LIU Y B, LU J, BI M H, YU J H, WANG T G, XU J Q, LIU J. Synthesis and characterization of the first polyoxometalate possessing bicapped by antimonyα-Keggin structure (C2N2H9)2 [PMoV5MoVI7SbIII2O40] 4H2O [J]. Inorg Chem Commun. 2006, 9, 544-547.
[144] MIALANE P, DOLBECQ A, LISNARD L, MALLARD A, MARROT J, SéCHERESSE F. [ε-PMo12O36(OH)4{La(H2O)4}4]5?: The Firstε-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reducedε-PMo12O40 Isomer [J]. Angew. Chem. Int. Ed. 2002, 41 (13), 2398?2401.
[145] DOLBECQ A, MIALANE P, LISNARD L, MARROT J, SéCHERESSE F. Hybrid Organic-Inorganic 1D and 2D Frameworks withε-Keggin Polyoxo- molybdates as Building Blocks [J]. Chem. Eur. J. 2003, 9, 2914-2920.
[146] KHAN M I, MüLLER A, DILLINGER S, B?GGE H, CHEN Q, ZUBIETA J.Cation inclusion within the Mixed-Valence Polyanion cluster [J]. Angew. Chem. Int. Ed. 1993, 32, 1780-1782.
[147] OLBECQ A, CADOT E, EISNER D, SéCHERESSE F. Hydrothermal Syntheses: A Route to the Stepwise Condensation of Reduced Keggin Polyanions. From Reducedβ-[HmSiMo12O40]n? Monomers to Bicapped Dimerized [Si2Mo28O84(H2O)2]6? Anions [J]. Inorg. Chem. 1999, 38 (19), 4217-4223.
[148] MüLLER A, BEUGHOLT C, K?GERLER P, B?GGE H, BUD’KO S, LUBAN M. [MoV12O30(μ2-OH)10H2{NiII(H2O)3}4], a Highly Symmetricalε-Keggin Unit Capped with Four Ni Centers: Synthesis and Magnetism [J]. Inorg. Chem. 2000, 39, 5176-5177.
[149] EI C, MAO J G, SUN Y Q, SONG J L. A Novel Organic Inorganic Hybrid Based on an 8-Electron-Reduced Keggin Polymolybdate Capped by Tetrahedral, Trigonal Bipyramidal, and Octahedral Zinc: Synthesis and Crystal Structure of (CH3NH3)(H2bipy)[Zn4(bipy)3(H2O)2MoV8MoVI4O36 (PO4)]·4H2O [J]. Inorg. Chem. 2004, 43, 1964-1968.
[150] UI X B, ZHENG S T, YANG G Y. First nickel (II) cation inclusion within the mixed-valence polyoxomolybdate capped with four NiII(en)(H2O) Groups: hydrothermal synthesis and structure of [MoV8MoVI4O30(μ2-OH)6(NiIIO4){NiII (en)(H2O)}4] [J]. Z. Anorg. Allg. Chem. 2005, 631, 642-644.
[151] BAI Y P, LI Y G, WANG E B, WANG X L, LU Y, XU L. A novel reduced a- Keggin type polyoxometalate coordinated to two and a half copper complex moieties:[Cu(2,2`-bipy)2][PMoVI8MoV4O40{Cu(2,2`-bipy)}2.5]·H2O [J]. Mol. Struc. 2005, 752, 54–59.
[152] GAUNT J, MAY I, SARSFIELD M J, COLLISON D, HEDELEINE M, DENNISS I S. A rare structural characterisation of the phosphomolybdate lacunary anion, [PMo11O39]7–. Crystal structures of the Ln (III) complexes, (NH4)11 [Ln(PMo11O39)2]·16H2O (Ln = CeIII, SmIII, DyIII or LuIII) [J]. Dalton Trans. 2003, 2767-2771.
[153] WANG J P, DUAN X Y, DU X D, NIU J Y, Novel Rare EarthGermanotungstates and Organic Hybrid Derivatives: Synthesis and Structures of M/[-GeW11O39](M Nd, Sm, Y, Yb) and Sm/[-GeW11O39](DMSO) [J]. Cryst. Grow. Des, 2006, 10, 2266-2270.
[154] LU Y, XU Y, WANG E B, LüJ, HU C W, XU L. Novel two-dimensional Network constructed from polyoxomolybdate chains linked through copper- organonitrogen coordination polymer chains: hydrothermal synthesis and structure of [H2bipy][Cu(4,4’-bipy)]2[HPCuMo11O39] [J]. Cryst. Grow. Des. 2005, 1, 257-260.
[155] DAI L M, YOU W S, WANG E B, WU S X, SU Z M, DU Q H, ZHAO Y, FANG Y. Two Novel One-Dimensional-Keggin-Based Coordination Polymers with Argentophilic{Ag3}3/{Ag4}4 Clusters [J]. Cryst. Grow. Des. 2009, 5, 2111.
[156] LU J J, XU Y, GOH N G, CHIA L S. Hydrothermal assembly and structral characterisation of one- and two-dimensional organic/inorganic hybrid materials constructed from diphosphopentamolybdate clusters and {Cu(en)}2+ comlpex groups [J]. Chem. Commun. 1998, 2733-2734.
[157] CHEN J, LU S F, YU R M, CHEN Z N, HUANG Z X, LU C Z. A novel compound with an interpenetrating 2D nerwork structure constructed by [P2Mo5O23] and Ni-4,4`-bipyridine components: its synthesis charaterization and magnetic behavior [J]. Chem, Commun. 2002, 2640-2641.
[158] RUIGE C, LIU S X, CAO J F, WANG L, TANG Q, LIU Y, REN Y H. An organi-inorganic hybrid compound constructed by Strandberg-type polyoxoanions and transition metal coordination complexes [J]. Mol. Struct. 2008, 888, 307-312.
[159] QIN C, WANG X L, YUAN L, WANG E B. Chiral Self-Threading Frameworks Based on Polyoxometalate Building Blocks Comprising Unprecedented Tri-Flexure Helix [J]. Cryst. Grow. Des. 2008, 7, 2093-2095.
[160] MUHDI L A, HAUSHALTER R C. Hydrothermal Synthesis of a Layered Zinc Molybdenum Phosphate with Octahedral and Tetrahedral Zinc: Structure of (TMA)2(H3O)2[Zn3Mo12O30(HPO4)2(H2PO4)6]·11.5H2O [J]. Inorg. Chem.1992, 31, 3050-3053.
[161] CHEN Y H, PENG J, YU H Q, HAN Z G, GU X J, SHI Z Y, WANG E B, HU N H. A supramolecular assembly of chiral L/D-[Cd(Cl)(H2O)(phen)2]+ and L, L/D, D-dinuclear Cd complex coordinated by phen and {V16O38(Cl)} cluster [J]. Inorg. Chim. Acta. 2005, 358, 403-408.
[162] CHEN Y H, GU X U, PENG J, SHI Z U, YU H Q, WANG E B HU N H. The synthesis, structure and characterization of [V16O38(Cl)]8-[J]. Inorg. Chem. Commun. 2004, 7, 705-708.
[163] LONG D L, ORR D, G. SEEBER G, P. K?ERLER P, FARRUGIA L J, CRONIN L. The Missing Link in Low Nuclearity Pure Polyoxovanadate Clusters: Preliminary Synthesis and Structural Analysis of a New {V16} Cluster and Related ProductsJ [J]. Cluster Science. 2003, 14, 13-324.
[164] LIN S, YEA Y Z, ZHANG X F, LIU C L. Synthesis, crystal structure and properties of a charge-transfer compound [(CH3)3CNH3]3[PMo12O40]·2H2O [J]. Transition. Met. Chem. 2006, 31, 760-764.
[165] CARO B, MATRIO B, VINCEZO F. BEDT-TTF Salts with. Alpha -Keggin Poly (oxometallates): Electrical, Magnetic, and Optical Properties of (BEDT-TTF)8[PMo12O40] and (BEDT-TTF)8[SiW12O40] and X-ray Crystal Structure of (BEDT-TTF)8[PMo12O40].cntdot.{(CH3CN.cntdot.H2O)2}[J]. Chem. Mater. 1995, 8, 1475-1484.
[166] BI L H, WANG E B, XU L, HUANG R D. Synthesis, properties and crystal structure of some polyoxometallates containing the tris (hydroxymethyl) -aminomethane cation [J]. Inorg. Chim. Acta. 2000, 305,163-171.
[167] BROWN I D, ?KEEFE M, NAVROTSKY A. (Eds.), Structure and Bonding in Crystals [J]. Academic Press, New York. 1981, 2, 1.
[168] GHARAH N, CHOWDHURY K, MUKHERJEE M, BHATTACHARYYA R. Synthesis and crystal structure of a mixed valence heteropoly green compound, (PPh4)4[PMo12O40], and its use as a catalyst in olefin epoxidation.Transition [J]. Met. Chem. 2008, 33, 635-642.
[169] CAVANI F, KOUTYREV M, TRIFIRO F. The role of promoters in theoxidehydrogenation of ethane over structurally stable Keggin-type heteropolyoxomolybdates. Catal. Today, 1996, 28, 319-333.
[170] CAVANI F, KOUTYREV M, TRIFIRO F. Oxidative dehydrogenation of ethane to ethylene over antimony-containing Keggin-type heteropolyoxomolybdates [J]. Catal. Today, 1995, 24, 365.
[171] ALBONETTI S, CAVANI F, TRIFIRO F, KOUTYREV M, On the antimony-stabilized cubic structure of potassium/ammonium salts of 12-molybdophosphoric acid and its catalytic performance in the oxidehydroge nation of ethane [J]. Catal. Lett. 1994, 30, 253-262.
[172] CHEN X M, TONG M L. Solvothermal in Situ Metal/ Ligand Reactions: A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry Acc [J]. Chem. Res. 2007, 40, 162-170.
[2]王恩波,胡长文,许林著.多酸化学导论[M].北京:化学工业出版社. 1998. 1.
[3] POPE M T著,王恩波等译.杂多和同多金属氧酸盐[M].长春:吉林大学出版社. 1991.
[4] KATSOULIS D E. A Survey of Applications of Polyoxometalates [J]. Chem. Rev.1998, 98, 359-387.
[5] KUNTSEVICH T S, TARKHOVA T N, RAKOVA E E. Plenum Publishing Corporation [J].1984, 133, 508-509.
[6] HAGRMAM P J, FINN R C, ZUBIETA J. Molecular manipulation of solid state structure: influences of organic components of vanadium oxide architectures [J]. Solid State Sci. 2001, 3, 745-774.
[7] FUCHS J, MAHJOUR S, PICKARDT J. Structure of the True Metavanadate Ion [J]. Angew. Chem. Int. Ed. Engl. 1976, 15, 374-375.
[8] HEINRICH D D. et al., Synthesis of tetranuclear and pentanuclear vanadium- oxide-carboxylate aggregates [J]. Chem. Soc. Chem. Commun.1989, 1411.
[9] WAY V W, KLEMPERER W G, YAGHI O M. A New Structure Type in Polyoxoanion Chemistry: Synthesis and Structure of the [V5O14]3- Anion [J]. Am. Chem. Soc. 1989, 111, 4518-4519.
[10] CHAE H K, KLEMPERER W G, DAY V W, An Organometal Hydroxide Route to [ (C5Me5)Rh]4(V6O19) [J]. Inorg.Chem. 1989, 28, 1423-1424.
[11] CHEN Q, LIU S, ZUBIETA J. A Cyclic Octa nuclear Polyoxoalkoxyvanadate (IV) with an Oxalate-Binding Cavity, [(n-C4H9)4N]2[V8O8(OCH3)16(C2O4)]. StructureComparison with the Analogous Polymolybdate (V) Complex [(n-C4H9)4 N2Mo8 (OC2H5)8 (C2O4)] [J]. 1989, 28, 4433-4434.
[12] DAY V W, KLEMPERER W G, MALTBIE D J. Where Are the Protons in H3V 10O283- ? '[J]. Am. Chem. Soc. 1987, 109, 2991-2992.
[13] DURAISAMY T, OJHA N, RAMANAN A, VITTAL J J. New Inorganic-Organic Hybrid Materials Based on Polyoxovanadates: [Morp]6 [VO4V14O32(OH)6]·2H2O, [Morp]VO3[HMTA-CH3]4[H2V10O28]·5H2O, and [HMTA-H] [HMTA-CH2OH]2[H5V10O28]·6H2O”[J]. Chem. Mater. 1999, 11, 2339-2349.
[14] DAY V W, KLEMPERER W G, YAGHI O M. Synthesis and characterization of a soluble oxide inclusion complex, [CH3CN.cntnd. (V12O32)4-] [J]. Am. Chem. Soc. 1989, 111, 5959-5960.
[15] HOU D, HAGEN K S, HILL C L. Tridecavanadate, [V13O34]3-, a new high-potential isopolyvanadate [J]. Am. Chem. Soc. 1992,114, 5864-5865.
[16] MüLLER A, KRICHEMEYER E, PENK M, WALBERG H J, B?GGE H. Spherical Mixed-Valence [V15O36]5 , an Example from an Unusual Cluster Family [J]. Angew. Chem, Int. Ed. Engl. 1987, 26, 1045-1046.
[17] HOU D, HAGEN K S, HILL C L. Pentadecavanadate, V15O429–, a new highly condensed fully oxidized isopolyvanadate with kinetic stability in water [J]. Chem. Soc. Chem. Commun.1993, 426-427.
[18] LIU C M, ZHANG D Q, XIONG M, ZHU D B. A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt (II) complex fragments as bridges [J]. Chem. Commun. 2002, 1416–1417.
[19] HAYASHI Y, FUKUYAMA K, TAKATERA T, UEHARA A. Synthesis and Structure of a New Reduced Isopolyvandate [V17O42]4-[J]. Chem. Lett. 2000, 770-771
[20] JOHNSON G K, SCHLEMPER E O. Existence and Structure of the Molecular Ion 18-Vanadate (IV) [J]. Am. Chem. Soc. 1978, 3645-3646.
[21] MüLLER A, PENK M, KRICKEMEYER E, B?GGE H, WALLBERG H J. [V19O41(OH)9]8 , An Ellipsoid-Shaped Cluster Anion Belonging to the Unusual Family of VIV/VV Oxygen Clusters [J]. Angew.Chem. Int. Ed. Engl. 1988, 27, 1719-1721.
[22] MüLLER A, Erich Krickemeyer, Michael Penk, Ralf Rohlfing, Anja Armatage, Hartmut B?gge.Template-Controlled Formation of Cluster Shellsor a Type of Molecular Recognition: Synthesis of [HV22O54(ClO4)]6- and [H2V18O44(N3)]5- [J]. Angew. Chem. Int. Ed. Engl.1991, 30, 1674-1677.
[23] MüLLER A, ROHLFING R, D?RING J, PENK M. Bildung einer Clusterhülle um einen zentralen Cluster durch einen: Selbstorganisationsproze: das gemischtvalente Polyoxovanadat [V34O82]10 [J]. Angew. Chem., 1991, 103, 575-577.
[24] MüLLER A, ROHLFING R, D?RING J, PENK M. Formation of a Cluster Sheath around a Central Cluster by a Self-Organization Process : the Mixed Valence Polyoxovanadate [V34O82]10- [J]. Angew. Chem. Int. Ed. Engl.1991, 30, 588-590.
[25] KHAN M I, YOHANNES E, POWELL D. Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4) (H2O)12]·24H2O [J]. Chem. Commun. 1999, 23-24.
[26] KHAN M I, YOHANNES E, DOEDENS R J. [M3V18O42(H2O)12(XO4)]·24 H2O (M = Fe, Co; X = V, S): Metal Oxide Based Framework Materials Composed of Polyoxovanadate Clusters [J]. Angew. Chem. Int. Ed. 1999, 38, 1292-1294.
[27] HAN M I, YOHANNES E, DOEDENS R J. A Novel Series of Materials Composed of Arrays of Vanadium Oxide Container Molecules, {V18O42(X)} (X = H2O, Cl-, Br-): Synthesis and Characterization of [M2(H2N(CH2)2NH2)5] [{M(H2N(CH2)2NH2)2}2V18O42(X)]·9H2O (M = Zn, Cd) [J]. Inorg. Chem. 2003, 42, 3125-3129.
[28] KHAN M I, YOHANNES E, POWELL D. Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-ray Crystal Structure of [H6Mn3VIV15VV4O46 (H2O)12]·30H2O [J]. Inorg. Chem.1999, 38, 212-213.
[29] KHAN M I, YOHANNES E, POWELL D. Synthesis and characterization of a new mixed-metal oxide framework material composed of vanadium oxide clusters: X-ray crystal structure of (N2H5)2[Zn3VIV12VV6O42(SO4)(H2O)12]·24H2O [J].Chem. Commun. 1999, 23-24.
[30] KHAN M I, AYESH S, DOEDENS R J, YUC M H, O’CONNORC C J. Synthesis and characterization of a polyoxovanadate cluster representing a new topology [J]. Chem. Commun.2005, 4658-4660.
[31] CHEN L, JIANG F L, LIN Z Z, ZHOU Y F, YUE C Y, HONG M C. A basket tetradecavandate cluster with blue luminescence [J]. Am. Chem. Soc. 2005, 127, 8588–8589.
[32] TRIPATHI A, HUGHBANKS T, CLEAR F A. The First Frame work Solid Composed of Vanado silica Clusters [J]. Am. Chem. Soc. 2003, 125, 10528- 10529.
[33] LIU S X, XIE L H , GAO B. An organic–inorganic hybrid material con structed from a three dimensional coordination complexcat ionic frame work an dentrapped hexadecavanadate clusters [J]. Chem. Commun. 2005, 5023-5025.
[34] PAN C L, XU J Q, LI G H, CUI X B, YE L, YANG G D. A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: K{VIV12VV6O42Cl [Ni(en)2]3}·8H2O [J]. Chem. Soc. Dalton Trans. 2003, 517-518.
[35] PAN C L, XU J Q, LI G H, CHU D Q, WANG T G. A three-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+: Ni(en)3{VIV11VV5O38Cl{Ni(en)2}3}·4H2O [J]. Eur. J. Inorg. Chem. 2003, 1514-1517.
[36] KATO R, KOBAYASHI A, SASAKI Y. 1:14 Heteropolyvanadate of Phosphorus: Preparation and Structure [J]. Am.Chem.Soc.1980, 102, 6571-6572.
[37] HUANG G Q, ZHANG S W, WEI Y G, SHAO M C. Synthesis and crystal structure of the heteropolyvanadate anion [AsV12P40(VO)2]9?[J]. Polyhedron. 993, 12, (12) 1483-1485.
[38] DURAISAMY T, OJHA N, RAMANAN A, VITTAL J. J. New Inorganic-Organic Hybrid Materials Based on Polyoxovanadates:[Morp]6[VO4V14O32 (OH)6]·2H2O, [Morp]VO3[HMTA-CH3]4[H2V10O28] 5H2O, and [HMTA-H] [HMTA-CH2OH]2 [H5V10O28]·6H2O [J]. Chem. Mater. 1999, 11, 2339-2349.
[39] HAO N, QIN C, XU Y, WANG E B, LI Y G, SHEN E H, XU L. A new pseudo Keggin-type polyvanadate (NH4)4[H12VV12O36(VIVO4)]·11H2O: hydrothermal synthesis and crystal structure”[J]. Inorg Chem Comm. 2005, 8, 592-595.
[40]崔小兵.砷(钼)-钒-氧簇合物的合成、结构及性质研究[D].中国科学院研究生院[D], 2004.
[41]齐燕飞.功能化多金属钒酸盐的控制合成、结构和性质研究[D].东北师范大学研究生院.
[42] MüLLER A, D?RING J. A novel heterocluster with 3D-summetry containing twenty-one core atoms [As6V15O42(H2O)]6- [J]. Angew. Chem. Int. Ed.1988, 27, 1271-1271.
[43] HUAN G H, GREANEY M A, JACOBSON A J. The synthesis and crystal structure of a new polyoxovanadium cluster anion: [As8V14O42(0.5H2O)]4- [J]. Chem. Soc., Chem.Commun.1991, 160-261.
[44] CUI X B, XU J Q, DING L, DING H, YE L, YANG G Y. Hydrothermal synthesis, crystal structure and characterization of [Zn(H2O)4]2 [H2As6V15O42(H2O)]·2H2O [J]. Mol. Struct. 2003, 660, 131–137.
[45] CUI X B, XU J Q, LI Y, SUN Y H, YE L, YANG G Y. Hydrothermal synthesis and characterization of (enH2)3.5[As8V14O42(PO4)]·2H2O [J]. Mol. Struct. 2003, 655, 207–213.
[46] ZHENG S T, XU J Q, YANG G Y. Hydrothermal Syntheses and Structural Characterization of Two Novel Arsenic–Vanadium Clusters: [Co(2,2`-bpy)3]2 [As8V14O42(H2O)]·3H2O and [2,2`-bpy][Ni(2,2`-bpy)3]2[As8V14O42 (H2O)]·3H2O [J]. J. Cluster Sci. 2005, 1.
[47] ZHENG S T, CHEN Y M, ZHANG J, YANG G.Y. Two New Polyoxovanadate-supported Transition Metal Complexes: [Zn(en)2] [Zn(en)2 (H2O)2][{Zn(en)(enMe)}As6V15O42(H2O)]·4H2O and [Zn2(enMe)2(en)3] [{Zn(enMe)2} As6V15O42(H2O)]·4H2O [J]. Z. Anorg. Allg. Chem. 2006, 632, 155-159
[48] ZHENG S T, ZHANG J, YANG G Y. [{{Zn(en)2}2As6V15O42(H2O)}2 {Zn(en)2}]·2Hen·3H2O. The First Dimeric Arsenic-Vanadium Cluster Linked by Zn(en)2 Complex Bridge [J].Chem. Lett. 2003, 32, 810.
[49] QI Y F, LI Y G, WANG E B , JIN H, ZHANG Z M, WANG X L, CHANG S. Syntheses and structures of four organic–inorganic hybrids based on the surface restricted [As8V14O42] building unit and various zinc coordination groups. Inorg anica Chimica Acta. 2007, 360, 1841-1853.
[50] ZHENG S T, ZHANG J,YANG G Y. [{Zn(enMe)2}2 (enMe)2 {Zn2 As8V12O40 (H2O)}·4H2O]: A Hybrid Molecular Material Based on Covalently Linked Inorganic Zn-As-V Clusters and Transition Metal Complexes via enMe Ligands Eur [J]. Inorg Chem. 2004, 2004-2007.
[51] ZHENG S T, M H WANG, YANG G Y. In Situ Ligand Reactions under Hydrothermal Conditions Afford a Novel Zinc-Substituted Polyoxovanadate Dimer [J]. Inorg Chem. 2007, 22, 9503.
[52] CUI X B, XU J Q, MENG H, ZHENG S T , YANG G Y. A Novel Chainlike As-V-O Polymer Based on a Transition Metal Complex and a Dimeric Polyoxoanion [J]. Inorg. Chem. 2004, 43, 8005-8009.
[53] ZHENG S T, CHEN Y M, ZHANG J, XU J Q, YANG G Y. Hybrid Inorganic–Organic 1D and 2D Frameworks with [As6V15O42]6– Polyoxoanions as Building Blocks [J]. Eur. Inorg. Chem. 2006, 397-406.
[54] CUI X B, XU J Q, SUN Y H, LI Y, YE L, YANG G Y. Hydrothermal synthesis and crystal structure of a novel 1-D chain structure constructed from polyoxometalates and coordination complex fragments[J]. Inorg Chem Comm. 2004, 7, 58-61.
[55] BU W M, YANG G Y, YE L, XU J Q, FAN Y G. One-Dimensional Arsenic-Vanadium Cluster Chain Bridged by Two Co(en)2 Groups [J]. Chem. Lett. 2000, 29, 462.
[56] CUI X B, XU J Q, LI Y, SUN Y H, YANG G Y. Hydrothermal Synthesis andCharacterization of a Novel Sinusoidal Layer Structure Constructed From Polyoxometalates and Coordination Complex Fragments. Eur [J]. Inorg. Chem. 2004, 1051-1055.
[57] QI Y F, LI Y G, WANG E B, JIN H, ZHANG Z M, WANG X L, CHANG S. Two unprecedented inorganic–organic boxlike and chainlike hybrids based on arsenic–vanadium clusters linked by nickel complexes [J]. Solid State Chem. 2007, 180, 382–389.
[58] QI Y F, LI Y G, WANG E B, JIN H, ZHANG Z M, WANG X L, Chang S. Synthesis and structure of four organic-inorganic hygbids bsased on the surface restricted [As8IIIV14IVO42] building unit and various zinc coordination groups [J]. Inorganica Chimica Acta. 2007, 360, 1841-1853.
[59] ZHANG L J, ZHAO X L, XU J Q, WANG T G, A novel two-dimensional structure containing the first antimony-substituted polyoxovandium clusters: [{Co(en)2}2SbIII8VIV14O42(H2O)]·6H2O [J]. Chem. Soc, Dalton Trans. 2002, 3275-3276.
[60] HU X X, XU J Q, CUI X B, SONG J F, WANG T G. A novel one-dimensional framework material constructed from antimony-substituted polyoxovanadium clusters: [(C2N2H10)2β-{SbIII8VIV14O42(H2O)}] (C2N2H8)·4H2O [J]. Inorg Chem Comm. 2004, 7, 264-267.
[61] IEBACH R, N?THER C, K?GERLER P, BENSCH W. [VIV15SbIII6O42]6?: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6? [J]. Dalton Trans. 2007, 3221-3223.
[62] TKOWSKI A, N?THER C, K?GERLER P, BENSCH W. [V16Sb4O42 (H2O)VO(C6H14N2)2}4]: A Terminal Expansion to a Polyoxovanadate Archetype [J]. Inorg Chem. 2008, 47, 1916-1918.
[63]迈克尔·波普著,王恩波等译,“杂多和同多金属氧酸盐”[M],吉林大学出版社1991, 24.
[64]杨国昱.长春:吉林大学博士学位论文, 1998.
[65]施展.无机-有机杂化晶体材料的合成与结构表征[D].长春:吉林大学化学学院,2002.
[66] ZAPF P J, WARREN C J, HAUSHALTER R C, ZUBIETA J. One-and two dimensional organic-inorganic composite solids constructed from molybdenum oxide and chain linked through{M(2,2`-bipy)}2+ fragments (M=Co,Ni,Cu) [J].Chem.Commun.1997,1543-1544.
[67] BURKHOLDER E, WRIGHT S, GOLUB V, O’CONNOR C J, ZUBIETA J. Solid state coordination chemistry of oxomolybdenum organoarsonate materials [J]. Inorg Chem. 2003, 42, 7460-7471.
[68] XU J Q, WANG R Z, YANG G Y, XING Y H, LI D M, BU W M, YE L, FAN Y G, YANG G D, XING Y, LIN Y H, JIA H Q. Metal–oxo cluster-supported transition metal complexes: hydrothermal synthesis and characterization of [{M (phen)2}2(Mo8O26)] (M = Ni or Co) [J]. Chem. Commun .1999, 983-984.
[69] LAN Y Q, LI S L, WANG X L, SHAO K Z, DU D Y, ZANG H Y, SU Z M. Self-Assembly of Polyoxometalate-Based Metal Organic Frameworks Based on Octamolybdates and Copper-Organic Units: from CuII, CuI,II to CuI via Changing Organic Amine [J]. Inorg. Chem. 2008, 47 (18), 8179-8187.
[70] HAN Z G, GAO Y Z, HU C W. Noncovalently Connected Framework Assembled from UnusualOctamolybdate-Based Inorganic Chain and Organic Cation. Cryst. Grow. Des. 2008, 8, 1261-1264.
[71] HAGRMAN D, ZAPF P J, ZUBIETA J. A two-dimensional network constructed from hexamolybdate, octamolybdate and Cu3(4,7-phen)3]3+ clusters: [{Cu3 (4,7-phen)3}2{Mo14O45}] [J]. Chem. Commun.1998, 1283-1284.
[72] LAN Y Q, LI S L, WANG X L, SHAO K Z, SU Z M, WANG E B. Supramolecular Isomerism with Polythreaded Topology Based on [Mo8O26]4- Isomers [J]. Inorg. Chem. 2008, 47 (2), 529-534.
[73] HAGRAMAN D, ZAPF P J, ZUBIEAT J. A two dimentional network constructed from hexamolybdate octamolybdate and Cu3(47-phen)3]3+ clusters: [{Cu3(4,7-phen)3}2{Mo14O45}] [J]. Chem.Commun.1998, 1283-1284.
[74] SHA J Q, PENG J, ZHANG Y, PANG H J, TIAN A X, ZHANG P P, LIUH. Assembly of Multiply Chain-Modified Polyoxometalates: From One to Three-Dimensional and from Finite to Infinite Track[J]. Cryst. Grow. Des. 2009, 9, 1709.
[75] KHAN M I, CHEN Q, SALTA J, O’CONNOR C J, ZUBIETA J. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14 Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X=Na(H2O)3+: n=13, m=9; n=15, m=7. X= Mo: n=14, m=9; n=13, m=10) [J]. Inorg. Chem.1996, 35 (7), 1880-1901.
[76] MüLLER A, MEYER J, KRICKEMEYER E, BEUGHOLT C, B?GGE H, PETERS F, SCHMIDTMANN M, K?GERLER P, KOOP M J. Unusual Stepwise Assembly and Molecular Growth: [H14Mo37O112]14? and [H3Mo57V6 (NO)6O189(H2O)12(MoO)6]21? [J]. Eur.Chem. 1998, 4, 1000-1006.
[77] KHAN M I, CHEN Q, SALTA J, O’CONNOR C J, ZUBIETA J. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14 Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X=Na(H2O)3+: n=13, m=9; n=15, m=7. X= Mo: n=14, m=9; n=13, m=10) [J]. Inorg. Chem.1996, 35 (7), 1880-1901.
[78] KREBS B, PAULAT-BOSCHEN I. The structure of the potassium isopolymoly date K8[Mo36O12(H2O)16·nH2O (n = 36.40) [J]. Acta Crystallogr. B. 1982, 38, 1710.
[79] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, DEUGHOLT C, K?GRLER P, LU C Z. Formation of a Ring-Shaped Reduced“Metal Oxide”with the Simple Composition [(MoO3)176(H2O)80H32] [J]. Angew. Chem. Int. Ed. 1998, 37, 1220-1223.
[80] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, P K?GERLER, ROSU C, BECKMANN E.‘Nanoobjects’by Self-Assembly Concomitant with Modifications under Alterable Boundary Conditions: Incorpo ration of Paramagnetic Metal Centers (Cu2+) in Ring-ShapedMolybdenum- Oxide Based Clusters [J]. Angew. Chem. Int. Ed. 2001, 40, 4034-4037.
[81] MüLLER A, SHAH S Q N, B?GGE H., SCHMIDTMANN M. Molecular Growth from a Mo176 to a Mo248 Cluster [J]. Nature.1999, 397, 48-50.
[82] MüLLER A, KRICKEMEYER E, B?GGE H, SCHMIDTMANN M, PETERS F. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed.1998, 40, 3360-3363.
[83] MüLLER A, ROY S, SCHMIDTMANN M, B?GGE H. Urea as‘deus ex machina’in giant molybdenum blue type cluster synthesis: an unusual hybrid compound with perspectives for related nano, supramolecular and extended structures [J]. Chem. Commun. 2002, 2000-2002.
[84] MüLLER A, K?GRLER P, KUHLMANN C. A variety of combinatorially linkable units as disposition: from a giant icosahedral Keplerate to multi-functional metal-oxide based network structures [J]. Chem. Commun, 1999, 1347-1358.
[85] CRONIN L, BEUGHOLT C, KRICKEMEYER E, SCHMIDTMANN M, B?GGE H, K?GERLER P, LUONG T K K, MüLLER A.“Molecular symmetry breakers’generating metal-oxide-based nanoobject fragments as synthons for complex structures: [{Mo128Eu4O388H10(H2O)81}2]20-, a giant-cluster dimmer [J]. Angew. Chem. Int. Ed. 2002, 41, 2805-2808.
[86] MüLLER A, ROY S. En route from the mystery of molybdenum blue via related manipulatable building blocks to aspects of materials science [J]. Coordin. Chem. Rev. 2003, 245, 153-166.
[87] LIU T B, DIEMANN E, LI H L, DRESS A W M, MüLLE A. R, Self-assembly in aqueous solution of wheel-shaped Mo-154 oxide clusters into vesicles [J]. Nature. 2003, 426, 59-62.
[88] MüLLER A, KOGERLER P, DRESS A W M. Giant metal-oxide-based spheres and their topology: from pentagonal building blocks to keplerates and unusual spin systems [J]. Coordin. Chem. Rev. 2001, 222, 193-218.
[89] BOTAR B, K?GERLER P, HILL C L. A Nanoring-Nanosphere Molecule, {Mo214-V30}: Pushing the Boundaries of Controllable Inorganic Structural Organization at the Molecular Level [J]. Am. Chem. Soc. 2006, 128, 5336-5337.
[90] JIANG C C, WEI Y G, LIU Q, ZHANG S W, SHAO M C, TANG Y Q. Self- assembly of a novel nanoscale giant cluster: [Mo176O496(OH)32(H2O)80] [J]. Chem. Commun.1998, 1937-1938.
[91] YANG W B, LU C Z, LIN X, ZHUANG H H. Novel Acetate Polyoxomolybdate“Host”Accommodating a Zigzag-Chainlike“Guest”of Five Edge-Shared Sodium Cations: Na21{[Na5(H2O)14][Mo46O134(OH)10 (μ-CH3COO)4]}·CH3COO Na·≈95H2O [J]. Inorg. Chem.2002, 41 (3), 452-454.
[92] MüLLER A, ZHOU Y S, B?GGE H.“Gating”the Pores of a Metal Oxide Based Capsule:After Initial Cation Uptake Susequent Cations AreFound Hydrated and Supramolecularly Fixed above the Pores [J ]. Angew. Chem: Int. Ed. 2006, 45, 460-465.
[93] MüLLER A, BECHKMANN E, B?GGE H, SCHMIDTMANN M, DREDD A. Inorganic Chemistry Goes Protein Size: A Mo368 Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int, Ed. Engl. 2002, 41, 1162 -1167
[94] TIAN A X, YING J, PENG J, SHA J Q, PANG H J, ZHANG P P, CHEN Y, ZHU M, SU Z M. Tuning the Dimensionality of the Coordination Polymer Based on Polyoxometalate by Changing the Spacer Length of Ligands [J]. Cryst. Grow. Des. 2008, 10, 3717-3724.
[95] DONG B X, XU Q. Structural Investigation of Flexible 1,4-Bis (1,2,4-triazol- 1-ylmethyl)benzene Ligand in Keggin-Based Polyoxometalate Frameworks [J]. Cryst. Grow. Des. 2009, 6, 2781.
[96] BJORNBERG A, B. HEDMAN. Multicomponent polyanions: Crystal structure and electron spin resonance spectrum of K6[V2Mo10VO40]?13H2O, a new one-electron heteropoly blue [J]. Acta Cryst.1980, B36, 1018.
[97] CHEN Q, HILL C. L. A Bivanadyl Capped, Highly Reduced Keggin Polyanion, [PMoV6MoVI6O40(VIVO)2]5-[J]. Inorg. Chem. 1996, 35, 2403-2405.
[98] SHI Z.Y, GU X J, PENG J, CHEN Y H. Controlled assembly of two new bicapped bisupporting Keggin-polyoxometalate derivatives: [M(2,2’-bipy)2 (H2O)]2[SiMoVI8MoV4VIV2O42](M = Co, Zn) [J]. Solid State Chem. 2005, 178, 1988-1995.
[99] SHI Z Y , GU X J, PENG J, WANG E B. Target synthesis of a new bicapped keggin polyoxometalate derivative: [Co(phen)3]2[SiMoVI8MoV4VIV2 O42]·H2O [J]. Mol. Struct. 2005, 737, 147-151.
[100] GU X J, PENG J, SHI Z Y, CHEN Y H, HAN Z H, WANG E B, MA J F, HU N H. Target syntheses of saturated Keggin polyoxometalate-based extended solids [J]. Inorg. Chim. Acta. 2005, 385, 3701-3710.
[101] SHI Z Y , GU X J, PENG J. Hydrothermal assembly of a new hydrogen-bonded network featuring bicapped dimerized [Si2Mo24O80 (VO)4]8- polyanion[J]. Inorg. Chem. Commun. 2005, 8, 886-889.
[102] GU X Y, PENG J, SHI Z Y, CHEN Y H., HAN Z G, WANG E B, MA J F, Hu N H. Target syntheses of saturated Keggin polyoxometalate-based extended solids [J]. Inorg. Chim. Acta. 2005, 358, 3701-3710.
[103] SHI Z Y, PENG J, C. J. GóMEZ-GARC?, BENMANSOUR S, GU X J. Influence of metal ions on the structures of Keggin polyoxometalate-based solids: Hydrothermal syntheses, crystal structures and magnetic properties [J]. Solid State Chem. [J] .2006, 179, 253-265.
[104] SHI Z Y , GU X J, PENG J, YU X, WANG E B. From molecular double-ladders to an unprecedented polycatenation: a parallel catenated 3D network containing bicapped Keggin polyoxometalate clusters [J]. Eur. Inorg. Chem. 2006, 385-388.
[105] SHA J Q, PENG J, LIU H S, CHEN J, TIAN A X, ZHANG P P. Asymmetrical Polar Modification of a Bivanadium-Capped Keggin POM by Multiple Cu-N Coordination Polymeric Chains [J]. Inorg. Chem. 2007, 46, 11183-11189.
[106] LUAN G Y, LI Y G., WANG E B, HAN Z B, HU C W, Hu N H, JIA H Q. hydrothermal synthesis and crystal structure of a novel compound: [Ni(phen)3]2[SiMo10VIV2O40(VIVO)2]·5H2O [J]. Inorg. Chem. Commun. 2002, 5, 509-511.
[107] LI F Y, XU L, WEI Y G, WANG E B. A new polyoxometalate-based complex with alternate ionic layer structures: hydrothermal synthesis, crystal structure and magnetic property [J]. Inorg. Chem. Commun.2005, 8, 263-266.
[108] ZHANG Y P, HAUSHALTER R C, CLEARAFIELD A. A heteropolyanion containing two linked mixed Mo/V pentadecaoxometalate clusters: structure of [Mo16V14O84]14-[J]. Chem. Commun. 1995, 1149-1150.
[109] MüLLER A, KOOP M, SCHIFFELS P, B?GGE H. [MoVI8VIV4O36(VVO4) (VIVO)2]7n-: capped Keggin fragments linked to a chain [J]. Chem. Commun. 1997, 1715-1716.
[110] LUAN G Y, WANG E B, HAN Z B, LI YG. Hydrothermal synthesis and structure of a bicapped 1D chain (H2en)3H3O[Mo8V4O36(VO4)(VO)2]·4H2O [J].Inorg. Chem. Commun. 2001, 4, 541-543.
[111] LIU C M, ZHANG D Q, ZHU D B. One- and two-dimensional coordination polymers constructed from bicapped Keggin mixed molybdenum-vanadium heteropolyoxoanions and polynuclear copper (I) clusters bridg by asymmetrical bipyridine (2,4’-bipy and 2,3’-bipy) ligands [J]. Cryst. Grow. Des. 2006, 6, 524-529.
[112] XU Y, XU J Q, YANG G Y, WANG T G., XING Y, LING YH, JIA H Q. Synthesis and structure of [NH4]4H[PMo8VIV4VV2O42]·24H2O [J]. Polyhedron. 1998, 17, 2441-2445.
[113] PAN C L, XU J Q, CHU D Q, LüZ L, DUAN L M , WANG T G. Reduced polyoxoanion with the bicapped quasi-Keggin structure [Ni(1,10’-phen)3] [Ni(en)3][Ni(en)2(H2O)2]{Ni(en)2}0.5}[PMoVI6MoV2VV2VIV4O42]·6H2O[J].Meedeleev Commun. 2002, 12, 233-234.
[114] ZENG Q X, XU J Q, SONG Y J, CUI X B, SHI Z. A bicappedα-Keggin unit-supported transition metal complex: Hydrothermal synthesis andcharacterization of [Cu(en)2(H2O)]2[Cu(en)2]0.5[Mo8V7O42{Cu(en)2}][J]. Z. Anorg. Allg. Chem. 2005, 631, 1528-1531.
[115] PAN C L, XU J Q, SUN Y, CHU D Q, YE L, LüZ L. WANG T G. First transition metal coordination compound supported on metal-oxygen cluster with bicapped quasi-Keggin structure: [Cu(en)2(H2O)]4[Cu(en)2]3.5[PMoVI8 VIV6O42Cu(en)(1,10’-phen)]3·14H2O [J]. Inorg. Chem. Commun. 2003, 6, 233-237.
[116] PAN C L, XU J Q, CHU D Q, LI G. H, LüZ L, YANG G D. First two- dimensional framework material constructed from bicapped Keggin structure clusters: {[PMoVI8VIV6O42Cu(en)2][Cu0.5(en)]}·5.5H2O [J]. Inorg. Chem. Commun. 2003, 6, 939-941.
[117] DUAN L M, PAN C L, XU J Q, CUI X B, XIE F T, WANG T G. Two- and Three-Dimensional Frameworks Constructed From Bicapped Keggin Clusters [J]. Eur. Inorg. Chem. 2003, 2578-2581.
[118] LUAN G Y, LI Y G, WANG E B, HAN Z B, HU C W, HU N H, JIA H Q. Hydrothermal synthesis and srystal structure of a bicapped Keggin polyoxoanions: [As2AsMo8V4O40]5-[J]. Inorg. Chem. Commun. 2001, 4, 632-634.
[119] XU Y, ZHU H G, CAI H, YOU X Z. [MoV2MoVI6VIV8O40(PO4)]5-: the first polyanion with a tetra-capped Keggin structure [J]. Chem. Commun.1999, 787-788.
[120] XU Y, ZHU D R, GUO Z J, SHI Y J, ZHANG K L, YOU X Z. Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions [J]. Dalton Trans. 2001, 772-773.
[121] XU Y, ZHU D R, SONG Y, ZHENG X F, YOU X Z. Hydrothermal synthesis and crystal structure of the novel mixed Mo/V metal–oxygen cluster compound [Co(C2N2H8)3]4[MoV2MoVI14VIV16O80(PO4)2]5-·10H2O containing the two types of typical heteropoly anions [J]. Mol. Struct. 2006, 782, 165-170.
[122] YUAN M, LI G Y, WANG E B, TIAN CG, WANG L, HU C W, HU N H,JIA HQ. Modified polyoxometalates: hydrothermal syntheses and crystal structures of three novel reduced and capped Keggin derivatives decorated by transition metalcomplexes [J]. Inorg. Chem. 2003, 42, 3670-3676.
[123] LI F Y, XU L, WEI Y G, WANG X L, WANG X L, WANG W J, WANG E B. Arsenicum-centered Molybdenum–Vanadium polyoxometalates bearing transition metal complexes: Hydrothermal syntheses, crystal structures and magnetic properties [J]. Mol. Struct. 2005, 753, 61-67.
[124] SUN Y H, XU J Q, YE L, CUI X B, LI Y, YU H H, LI G H, YANG G D, CHEN Y. Hydrothermal synthesis and crystal structural characterization of two new modified polyoxometalates constructed of positive and negative metal-oxo cluster ions”[ J]. Mol. Struct. 2005, 740, 193-201.
[125] SUN Y H, DING H, XU J Q, LI Y, LI G H. Hydrothermal synthesis and crystal structure of a highly reduced mixed molybdenum-vanadium polyoxometalate with phosphorus-centered [Ni(phen)3]2H2[PMoV4MoVI4VIV6M2O44]·4H2O (M = 0.78MoV + 0.22VIV) [J]. Chem. Res, Chinese U. 2005, 21, 368-371.
[126] SUN Y H, CUI XI B, LI G H, XU J Q, WANG T G , XU W, PAN L L, YANG Q X. A new mixed molybdenum-vanadium polyoxometalate double- supporting transition metal complex: {[Co(phen)2]2-C2O4}{H2PMoVI3 MoV5VIV8O44Co(phen)2(H2O)]2}·7H2O”[J]. J. Coord. Chem. 2005, 1561-1571.
[127] CUI X B, YANG G D. [{(H2O)Ni(enMe)2MoV4MoVI4VIV8(VVO4)O40}2 {Ni(enMe)2}][Ni(enMe)2]4·8H2O: The First Dimer of Polyoxometalates Linked through Coordination Fragment [J] .Chem. Letters.2002, 31,1238- 1239.
[128] DUAN L M, XU J Q, XIE F T, CUI X B, DING H, SONG J F. Synthesis and characterization of a new compound based on mixed Mo/V polyoxometalates connected and modified by [Ni(en)2]2+ groups [J]. Mendeleev commun. 2005, 9, 79-80.
[129]段莉梅,“金属簇聚物与配位聚合物的水热合成与表征”,吉林大学博士学位论文,2004.
[130] LIU Y B, CUI X B, XU J Q, LU Y K, LIU J, ZHANG Q B, YANG G D. Hydrothermal synthesis and characterization of three one-dimensional chain materials fromed by reduced tetra-capped Keggin polyoxoanions and [M(en)2]2+ (M = Cu, Co and Ni) cations[J]. Mol. Struct. 2006, 825, 45-52.
[131]崔小兵,郑寿添,杨国昱,“1-D链状簇合物[Ni(enMe)2]2[Ni(enMe)2- {HMoVI4MoV4VIV8O40(VVO4)}]·4H2O的水热合成和晶体结构”,结构化学(Chinese J. Struct. Chem). 2004. 3, 300-305.
[132] ZENG Q X, XU J Q, YANG G D, CUI X B, SONG J F, ZHENG Z D. Synthesis and structure of [Ni(en)2]2H{[Ni(en)2][MoVI4MoV4VIV8O40 (VVO4)]}·3H2O with 1-D extended heteronuclear chains [J]. Polish. J. Chem. 2001, 1791-1796.
[133] BU W M, YE L, YANG G D, GAO J S, FAN YG, SHAO Y G, XU J Q. One- and two-dimensional framework materials constructed from the mixed Mo/V tetra-capped Keggin structure clusters and M(en)2 (M = Ni, Cu) complexes groups [J]. Inorg. Chem. Commun. 2001, 4, 1-4.
[134] LIU C M, ZHANG D Q, XIONG M, ZHU D B. A novel two-dimensional mixed molybdenum–vanadium polyoxometalate with two types of cobalt (II) complex fragments as bridges”[J]. Chem. Commun. 2002, 1416-1417.
[135] LIU C M, ZHANG D Q, ZHU D B D. Mixed Molybdenum-Vanadium Polyoxoanion-Bridged Trimetallic Nanocluster Complexes: Hydrothermal Syntheses and Crystal Structures of {MoVI6MoV2VIV8O40(PO4)[Co(phen)2 (H2O)]2}[Co2(phen)2(OH)2(H2O)4]1/2 and {MoVI5MoV5VIV8O40(PO4)[Co(phen) (en) (H2O)]2}[Co2(phen)3]·1.5H2O [J]. Cryst. Grow. Des. 2003, 3, 363-368.
[136] LIU C M, LUO J L, ZHANG D Q, WANG N L, CHEN Z J,ZHU D B. Spin Glass Behaviour in a 1D Mixed Molybdenum-Vanadium Heteropolyoxo metalate-Bridged Coordination Polymer [J]. Eur. Inorg. Chem. 2004, 4774-4779.
[137] LIU C M, ZHANG D Q, ZHU D B. 3D Supramolecular Array Assembled byPolyoxometalate Bridged Coordination Polymer Chains: Hydrothermal Synthesis and Crystal Structure of {[MoVI5MoV3VIV8O40(PO4)][Ni(en)2]} [Ni(en)2]2·4H2O [J]. Cryst. Grow. Des. 2005, 5, 1639-1642.
[138] GONG Y, LI Y G, LI H, WANG Y H, HU C W. Synthesis, Characterization and Properties of Two Novel Complexes Based on 2-Aminopyridine and Polyoxometalates[J]. Chinese Journal of Chemistry. 2006, 24, 1148-1153.
[139] YANG W B, LU C Z, ZHAN X P , ZHUANG H H .Hydrothermal Synthesis of the first Vanadomolybdenum polyoxocation with a‘metal-bonded’spherical framework [J]. Inorg. Chem. 2002, 41, 4621-4623.
[140]卢玉坤,“非经典金属-氧簇合物的合成、结构与性能”,吉林大学博士学位论文, 2009.
[141] KHAN M I, CHEN Q, ZUBIETA J. Hydrothermal Synthesis and Structure of [H4AsIII2AsVMoV8MoVI4O40]?, A Bicapped, Reduced Keggin Species [J]. Inorg. Chem. 1993, 32 (13), 2924-2928.
[142] LUAN G Y, LI Y G , E.B. WANG E B, HAN Z B, HU C W, HU N H,JIA H Q. Hydrothermal synthesis and srystal structure of a bicapped Keggin polyoxoanions: [As2AsMo8V4O40]5- [J]. Inorg. Chem. Commun. 2001, 4, 632-634.
[143] ZHANG Q B, LU Y K, LIU Y B, LU J, BI M H, YU J H, WANG T G, XU J Q, LIU J. Synthesis and characterization of the first polyoxometalate possessing bicapped by antimonyα-Keggin structure (C2N2H9)2 [PMoV5MoVI7SbIII2O40] 4H2O [J]. Inorg Chem Commun. 2006, 9, 544-547.
[144] MIALANE P, DOLBECQ A, LISNARD L, MALLARD A, MARROT J, SéCHERESSE F. [ε-PMo12O36(OH)4{La(H2O)4}4]5?: The Firstε-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reducedε-PMo12O40 Isomer [J]. Angew. Chem. Int. Ed. 2002, 41 (13), 2398?2401.
[145] DOLBECQ A, MIALANE P, LISNARD L, MARROT J, SéCHERESSE F. Hybrid Organic-Inorganic 1D and 2D Frameworks withε-Keggin Polyoxo- molybdates as Building Blocks [J]. Chem. Eur. J. 2003, 9, 2914-2920.
[146] KHAN M I, MüLLER A, DILLINGER S, B?GGE H, CHEN Q, ZUBIETA J.Cation inclusion within the Mixed-Valence Polyanion cluster [J]. Angew. Chem. Int. Ed. 1993, 32, 1780-1782.
[147] OLBECQ A, CADOT E, EISNER D, SéCHERESSE F. Hydrothermal Syntheses: A Route to the Stepwise Condensation of Reduced Keggin Polyanions. From Reducedβ-[HmSiMo12O40]n? Monomers to Bicapped Dimerized [Si2Mo28O84(H2O)2]6? Anions [J]. Inorg. Chem. 1999, 38 (19), 4217-4223.
[148] MüLLER A, BEUGHOLT C, K?GERLER P, B?GGE H, BUD’KO S, LUBAN M. [MoV12O30(μ2-OH)10H2{NiII(H2O)3}4], a Highly Symmetricalε-Keggin Unit Capped with Four Ni Centers: Synthesis and Magnetism [J]. Inorg. Chem. 2000, 39, 5176-5177.
[149] EI C, MAO J G, SUN Y Q, SONG J L. A Novel Organic Inorganic Hybrid Based on an 8-Electron-Reduced Keggin Polymolybdate Capped by Tetrahedral, Trigonal Bipyramidal, and Octahedral Zinc: Synthesis and Crystal Structure of (CH3NH3)(H2bipy)[Zn4(bipy)3(H2O)2MoV8MoVI4O36 (PO4)]·4H2O [J]. Inorg. Chem. 2004, 43, 1964-1968.
[150] UI X B, ZHENG S T, YANG G Y. First nickel (II) cation inclusion within the mixed-valence polyoxomolybdate capped with four NiII(en)(H2O) Groups: hydrothermal synthesis and structure of [MoV8MoVI4O30(μ2-OH)6(NiIIO4){NiII (en)(H2O)}4] [J]. Z. Anorg. Allg. Chem. 2005, 631, 642-644.
[151] BAI Y P, LI Y G, WANG E B, WANG X L, LU Y, XU L. A novel reduced a- Keggin type polyoxometalate coordinated to two and a half copper complex moieties:[Cu(2,2`-bipy)2][PMoVI8MoV4O40{Cu(2,2`-bipy)}2.5]·H2O [J]. Mol. Struc. 2005, 752, 54–59.
[152] GAUNT J, MAY I, SARSFIELD M J, COLLISON D, HEDELEINE M, DENNISS I S. A rare structural characterisation of the phosphomolybdate lacunary anion, [PMo11O39]7–. Crystal structures of the Ln (III) complexes, (NH4)11 [Ln(PMo11O39)2]·16H2O (Ln = CeIII, SmIII, DyIII or LuIII) [J]. Dalton Trans. 2003, 2767-2771.
[153] WANG J P, DUAN X Y, DU X D, NIU J Y, Novel Rare EarthGermanotungstates and Organic Hybrid Derivatives: Synthesis and Structures of M/[-GeW11O39](M Nd, Sm, Y, Yb) and Sm/[-GeW11O39](DMSO) [J]. Cryst. Grow. Des, 2006, 10, 2266-2270.
[154] LU Y, XU Y, WANG E B, LüJ, HU C W, XU L. Novel two-dimensional Network constructed from polyoxomolybdate chains linked through copper- organonitrogen coordination polymer chains: hydrothermal synthesis and structure of [H2bipy][Cu(4,4’-bipy)]2[HPCuMo11O39] [J]. Cryst. Grow. Des. 2005, 1, 257-260.
[155] DAI L M, YOU W S, WANG E B, WU S X, SU Z M, DU Q H, ZHAO Y, FANG Y. Two Novel One-Dimensional-Keggin-Based Coordination Polymers with Argentophilic{Ag3}3/{Ag4}4 Clusters [J]. Cryst. Grow. Des. 2009, 5, 2111.
[156] LU J J, XU Y, GOH N G, CHIA L S. Hydrothermal assembly and structral characterisation of one- and two-dimensional organic/inorganic hybrid materials constructed from diphosphopentamolybdate clusters and {Cu(en)}2+ comlpex groups [J]. Chem. Commun. 1998, 2733-2734.
[157] CHEN J, LU S F, YU R M, CHEN Z N, HUANG Z X, LU C Z. A novel compound with an interpenetrating 2D nerwork structure constructed by [P2Mo5O23] and Ni-4,4`-bipyridine components: its synthesis charaterization and magnetic behavior [J]. Chem, Commun. 2002, 2640-2641.
[158] RUIGE C, LIU S X, CAO J F, WANG L, TANG Q, LIU Y, REN Y H. An organi-inorganic hybrid compound constructed by Strandberg-type polyoxoanions and transition metal coordination complexes [J]. Mol. Struct. 2008, 888, 307-312.
[159] QIN C, WANG X L, YUAN L, WANG E B. Chiral Self-Threading Frameworks Based on Polyoxometalate Building Blocks Comprising Unprecedented Tri-Flexure Helix [J]. Cryst. Grow. Des. 2008, 7, 2093-2095.
[160] MUHDI L A, HAUSHALTER R C. Hydrothermal Synthesis of a Layered Zinc Molybdenum Phosphate with Octahedral and Tetrahedral Zinc: Structure of (TMA)2(H3O)2[Zn3Mo12O30(HPO4)2(H2PO4)6]·11.5H2O [J]. Inorg. Chem.1992, 31, 3050-3053.
[161] CHEN Y H, PENG J, YU H Q, HAN Z G, GU X J, SHI Z Y, WANG E B, HU N H. A supramolecular assembly of chiral L/D-[Cd(Cl)(H2O)(phen)2]+ and L, L/D, D-dinuclear Cd complex coordinated by phen and {V16O38(Cl)} cluster [J]. Inorg. Chim. Acta. 2005, 358, 403-408.
[162] CHEN Y H, GU X U, PENG J, SHI Z U, YU H Q, WANG E B HU N H. The synthesis, structure and characterization of [V16O38(Cl)]8-[J]. Inorg. Chem. Commun. 2004, 7, 705-708.
[163] LONG D L, ORR D, G. SEEBER G, P. K?ERLER P, FARRUGIA L J, CRONIN L. The Missing Link in Low Nuclearity Pure Polyoxovanadate Clusters: Preliminary Synthesis and Structural Analysis of a New {V16} Cluster and Related ProductsJ [J]. Cluster Science. 2003, 14, 13-324.
[164] LIN S, YEA Y Z, ZHANG X F, LIU C L. Synthesis, crystal structure and properties of a charge-transfer compound [(CH3)3CNH3]3[PMo12O40]·2H2O [J]. Transition. Met. Chem. 2006, 31, 760-764.
[165] CARO B, MATRIO B, VINCEZO F. BEDT-TTF Salts with. Alpha -Keggin Poly (oxometallates): Electrical, Magnetic, and Optical Properties of (BEDT-TTF)8[PMo12O40] and (BEDT-TTF)8[SiW12O40] and X-ray Crystal Structure of (BEDT-TTF)8[PMo12O40].cntdot.{(CH3CN.cntdot.H2O)2}[J]. Chem. Mater. 1995, 8, 1475-1484.
[166] BI L H, WANG E B, XU L, HUANG R D. Synthesis, properties and crystal structure of some polyoxometallates containing the tris (hydroxymethyl) -aminomethane cation [J]. Inorg. Chim. Acta. 2000, 305,163-171.
[167] BROWN I D, ?KEEFE M, NAVROTSKY A. (Eds.), Structure and Bonding in Crystals [J]. Academic Press, New York. 1981, 2, 1.
[168] GHARAH N, CHOWDHURY K, MUKHERJEE M, BHATTACHARYYA R. Synthesis and crystal structure of a mixed valence heteropoly green compound, (PPh4)4[PMo12O40], and its use as a catalyst in olefin epoxidation.Transition [J]. Met. Chem. 2008, 33, 635-642.
[169] CAVANI F, KOUTYREV M, TRIFIRO F. The role of promoters in theoxidehydrogenation of ethane over structurally stable Keggin-type heteropolyoxomolybdates. Catal. Today, 1996, 28, 319-333.
[170] CAVANI F, KOUTYREV M, TRIFIRO F. Oxidative dehydrogenation of ethane to ethylene over antimony-containing Keggin-type heteropolyoxomolybdates [J]. Catal. Today, 1995, 24, 365.
[171] ALBONETTI S, CAVANI F, TRIFIRO F, KOUTYREV M, On the antimony-stabilized cubic structure of potassium/ammonium salts of 12-molybdophosphoric acid and its catalytic performance in the oxidehydroge nation of ethane [J]. Catal. Lett. 1994, 30, 253-262.
[172] CHEN X M, TONG M L. Solvothermal in Situ Metal/ Ligand Reactions: A New Bridge between Coordination Chemistry and Organic Synthetic Chemistry Acc [J]. Chem. Res. 2007, 40, 162-170.