针阵列电晕放电降低室内苯实验研究
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摘要
苯污染是室内空气污染物中一个重要部分,具有微量、易挥发、高毒性等特点。现有的降低苯污染技术包括吸附净化法、吸收法、燃烧法、生物净化法、光催化氧化法等,这些方法仅对工业废气或高浓度苯废气具有明显效果。室内空气苯具有浓度低、处理空间大等特点。因此,一种处理低浓度、大空间污染气体方法成为目前研究重点。本论文在结合实验室前期非热放电净化室内空气研究的基础上,采用多种针阵列电晕放电方式,建立高效的净化室内空气中苯污染的实验装置。
     本文首先采用针阵列对板正电晕放电进行降低苯污染的实验研究。分别研究了三种初始浓度下的空白实验,通过改变初始浓度、风速、放电功率和相对湿度,探讨各参数对苯去除率的影响。
     随后,改变高压电源极性,研究针阵列对板负电晕放电中,初始浓度、放电功率、和相对湿度对苯去除率的影响。
     最后,采用针阵列双极电晕放电技术,研究正、负高压供电时针阵列双极电晕放电对苯的去除效果,并与针阵列对板电晕放电对苯的去除效果作出比较,从而筛选出降低苯的最佳放电方式和放电参数。
     通过比较实验结果并结合理论分析,筛选出去除室内空气中苯的最优放电方式是针阵列对板正电晕放电方式,具体运行参数为风速采用2.4m/s,放电功率为9W,室内空气湿度为40%。
Benzene pollutant is an important part of the indoor air pollutants. It is characterized by micro-scale, highly toxic, and volatility. Current technologies consist of adsorption purification method, absorption method, combustion method, biological purification method, photo catalytic oxidation method and etc. These methods only apply to control industrial emissions or high concentrations of benzene. However, indoor air benzene pollutant is low concentrations in large spaces. So how to treat benzene pollutant with low concentration in a large space becomes an important research. In this thesis, based on the early research in indoor air cleaning using non-thermal discharge, the needle-matrix corona discharges are used to reduce indoor benzene pollutant. An experimental device for efficient purification of benzene in indoor air is established.
     Firstly, the needle-matrix to plate positive corona discharge is used to remove benzene pollutant. The blank experiment of three kinds of initial concentrations is studied. By changing initial concentration of benzene, wind velocity, discharge power and relative humidity, the effects of each parameter on benzene removal rate is studied.
     Then, using the needle-matrix plate negative corona discharge, the effect of various parameters including initial concentration of benzene, discharge power and relative humidity on benzene removal rate is studied.
     At last, using the needle-matrix bipolar corona discharge, the effect of discharge power on benzene removal rate is studied. By comparing all these methods for benzene removal, the best kind of discharges and the optimal discharge parameters are obtained.
     By comparing the experimental results and combining with theoretical analysis, it is including that the best discharge is the needle-matrix to plate positive corona discharge. And the optimal discharge parameters are as follows:the wind velocity is 2.4m/s, the discharge power is 9W, and the relative humidity is 40%.
引文
[1]Ramanathan K, Debler V L. Kosusko M et al. Environmental Progress,1988,7(4): 230-235.
    [2]Namiesnik J, Gorecki T, Bozena K. et al. Building and Enviroment.1992,27(3): 339-356.
    [3]2002年世界卫生报告.世界卫生组织,2003.
    [4]戴天有,刘德全,曾燕君等.装修房屋室内空气的污染.环境科学研究,2002,15(4)27-30.
    [5]徐钢.浅论室内空气污染对人体健康的影响.China’s Foreign Trade,2011,6:350.
    [6]白月华.室内空气中挥发性有机污染物治理对策.环境科学与技术,2011,34(6G):334-339.
    [7]Roman M, Tunga S, Helmut K. Interaction of volatile organic compounds with indoor materials a small scale screening method. Atmospheric Evironnment,1999,33: 395-2401.
    [8]Jones A P, indoor air quality and health. Atmospheric Environment,1999,33: 4534-4564.
    [9]Huali Y, Songting G, Jianfang F, et al. Trace analysis of nicotine in indoor air by a SPME method. Bulletin of Environment Contamination and Toxicology,2002, 68:485-489.
    [10]谢海英,陈康民.室外空气污染对室内空气质量的影响研究.环境科学研究,2008,21(2):73-78.
    [11]高书霞.物理性污染的危害及防治方法.物理通报,2004,3:6-48.
    [12]叶玮玮.隐形杀手—电磁污染技术.物理教学,2006,14(3):47.
    [13]刘洪涛,晁福寰.室内空气物理性因素污染研究.中国预防医学杂志,2002,3(3):170-173.
    [14]郭金妹,韩惠敏.室内噪声污染及其控制.技术创新导报,2011,10(20):238.
    [15]赵彤,孙江,刘继凤.室内空气污染现状及处理方法的探讨.环境科学与管理,2011,36(6):48-49.
    [16]鲍肖波.浅析室内空气污染的危害与治理.能源环境保护,2011,26(3):55-56.
    [17]ACGIH. Guidelines for the assessment of hioaerosols in the indoor environm-ent. American Conference of Governmental Industrial Hygienists,1989.
    [18]Burge HA. Bioaerosol prevalence and health effects in indoor environment. J A Hergy Clin Immun,1990,86(5):687-701.
    [19]2007年世界无烟日宣传资料.世界卫生组织,2007.
    [20]朱迪迪,戴海夏,钱华.我国室内空气污染现状调查与分析.上海环境科学,2010,29(4):174-180.
    [21]邱建华,吴彩斌.挥发性有机物(VOCs)对室内环境的影响研究.闽西职业技术学院学报,2009,11(1):124-127.
    [22]Violante F S, Sanguinetti G, Barbieri A, et al. Lack of correlation between environmental or biological indicators of benzene exposure at parts per-billion levels and micronucle induction. Environmental Research,2003,91(3):135-142.
    [23]沈志野.新装修室内空气污染物-苯的污染调查分析及防治对策:(硕士学位论文).西安:西安建筑科技大学,2010.
    [24]杨卫芳,邢冰梅,杨玉军等.室内空气中苯的污染.职业与健康,2006,22(8):569-570.
    [25]张义,陈彪,杨宇锋等.室内空气中苯系物污染及防治.四川建设,2009,35(4):91-92.
    [26]Guo H, Lee S C, LI, W M, et al. Source characterization of BTEX in indoor microenvironments in Hong Kong. Atmospheric Environment,2003,37 (1):73-82.
    [27]史德,苏广和.室内空气质量对人体健康的影响[M].北京:中国环境科学出版社,2005.
    [28]刘向新译.室内空气质量-有机污染物.北京:人民卫生出版社,1991,8.
    [29]万俊香,夏昭林,金锡鹏.与苯血液毒性易感性相关的儿种毒物代谢酶多态性研究进展.中华劳动卫生职业病杂志,2001,19(1):76-78.
    [30]www.zgsnhj.com.cn
    [31]余淑苑.新型装修材料所致室内空气污染对人体免疫系统的影响.山西预防医学,2001,10(2):134-134.
    [32]张明先,于明月,解名环.新型装修居室中苯及甲醛污染对人体健康的影响.中国卫生工程学,2007,4(6).
    [33]旷亦乐.装修居室甲醛、苯系物等对女性生殖危害的研究:(硕士学位论文).衡阳:南华大学,2011.
    [34]史德,苏广和.室内空气质量对人体健康的影响.北京:中国环境科学出版社,2005.
    [35]成东艳.室内空气中苯系物污染的危害及防治.环境保护与循环经济,2008,28(1):40-41.
    [36]朱联锡,蒋文举等.空气污染控制原理.成都:成都科技大学出版社,1990.
    [37]蒋绿林,施明恒,高玉明.活性炭对苯蒸汽吸附分离过程的实验研究.工程物理学报,2003,24(2):274-276.
    [38]张丽丹,赵晓鹏,马群等.改性活性炭对苯废气吸附性能的研究.新型炭材料,2002,17,(2):41-44.
    [39]颜幼平,陈凡植,邵英贤.吸附净化低浓度废气实验研究.环境污染治理技术与设备,2000,1(4):76-80.
    [40]M.A.Lillo-Rodenas, D. Cazoria-Amoros, A. Linares-Solano. Behaviour of acti-vated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentration. Carbon,2005,43:1758-1767.
    [41]刘英.苯系物新型吸收剂制备与性能研究:(硕士学位论文).济南:山东科技大学,2010.
    [42]许锦翔.BDO吸收剂治理含苯废气的实验研究.化学工程与装备,2006,5:64-67,52.
    [43]张丽珍.膜基-溶剂吸收含苯废气吸收剂的选择研究:(硕士学位论文).南京:南京理工大学,2008.
    [44]罗教生.用水-洗油吸收剂处理含苯废气的研究.环境与开发,1999,14(3):19-21.
    [45]程从兰,黄小林,朗爽.苯系物新型吸收剂的研究.北京工业大学学报,2000,26(1)107-111.
    [46]Ozturk, B, Yilmaz, D. Absorptive removal of volatile organic compounds from flue gas streams[J]. Process Safety and Environmental Protection,2006,84(5):391-398.
    [47]Ferrai C. P., Kaluzny P.Roche A., etal. Aromatic Hydrocarbons and Aldehydes in the Atomsphere of Grenoble, France Chemosphere,1978,37(8):1587-1601.
    [48]余凤江,张丽丹.苯催化燃烧反应Cu-Mn-Ce-Zr-O催化剂催化活性的研究.北京化工大学学报,2001,28(4):67-68+72.
    [49]王筱喃,赵磊,郝晓霞等.Pt/Pd催化燃烧催化剂处理含苯系物废气技术研究.当代化工,2011,40,(11):1101-1103.
    [50]张志强,贺站锋,王娟芸等.ZrO2对CuMn2/Al-Ti整体式催化剂催化苯燃烧反应性能的影响.催化学报,2010,31(7):793-796.
    [51]Centeno M A, Paulis M, Montes M, et al. Catalytic combustion of volatile or-ganic compounds on Au/CeOz/Al2O3 and Au/Al2O3, catalytic. Appl Catal A:General,2002, 234:65-78.
    [52]Salvador Ordonez, Lisardo Bello, Herminio Sastre, et al.Kinetics of the de-ep oxidation of benzene, toluene, n-hexane and their binary mixtures over a pla-tinum on γ-α-lumina catalyst. Appl Catal:Environmental,2002,38:139-149.
    [53]王建礼.催化燃烧去除挥发性有机气体的整体式催化剂:(博十学位论文).成都:四川大学,2007.
    [54]C. Lahousse, A. Bemier, P. Grange, etal. Evaluation of γ-MnO2 as a VOC removal catalyst:comparison with anobel metal catalyst. Journal of Catalysis,1998:178 (CA982148):214-225.
    [55]李国文.生物法净化挥发性有机废气(VOCs)的研究:(博十学位论文).西安:西安建筑科技大学,1999.
    [56]关晓辉,刘惠菊,张兰河等.生物滴滤法去除含苯挥发性有机废气试验研究.南京理工大学学报(自然科学版),2010,34,(2):279-282.
    [57]王晨吴,羌宁.生物滴滤器净化苯废气研究.四川环境,2006,25(5):1-4.
    [58]Fouhy K. Cleaning Waste Gas Naturally. Chem. Eng.,1992,41-46.
    [59]Sorial, G. A., Smith, F. L., Suidan, M.T. Evaluation of triekle bed air biofil-ter performance for BTEX removal. Environmental Engineering,1997,123(6):530-537.
    [60]C. Kennes, M. C. Veiga. Fungal biocatalysts in the biofiltration of VOC pol-luted air. Biotechnol,2004,113:305-319.
    [61]侯晨涛,马广大,曹晓强.净化三苯废气生物滤池中微生物的初步鉴定.环境科学与技术,2006,29(11):37-39.
    [62]钟俊波.Ti02基催化剂上气相色谱光催化降解苯的研究:(博士学位论文).四川:四川大学,2007.
    [63]刘洋,尚静,王忠.Ti02纳米粒子光催化降解室内挥发性有机污染物苯的研究.环境污染治理技术与设备,2006,7(10):43-46.
    [64]王金鹤,黄丽华,薛华欣等.Ti02薄膜光催化氧化降解苯的研究.复旦学报(自然科学版),2004,43(4):628-632.
    [65]Teruaki H, Keiichi T. Photocatalytic degradation of benzene on zeolite inco-rporated TiO2 film. J. Haz. Mats,2002, B93:331-337.
    [66]徐学基,诸定吕.气体放电物理.上海:复旦大学出版社,1996.
    [67]朱益民.正直流流光放电等离子体源装置,实用新型,00201301.0.2000.
    [68]朱益民.非热放电和光催化协同净化污染空气装置,实用新型,03104038.1.2003.
    [69]宿鹏浩,朱益民,陈海丰.发射光谱研究多针对板正电晕放电形貌.光谱学与光谱分析,2008,28(9):19982002.
    [70]宿鹏浩,朱益民,陈海丰.多针对板负电晕放电电离区形貌确定.光谱学与光谱分析,2007,27(11):2171-2174.
    [71]朱益民,杨树,黄丽萍等.电晕放电及催化法净化室内空气.环境科学与环境技术,2010,33,(6E):86-88.
    [72]陈海丰.针阵列双极电晕放电及其捕集颗粒物研究:(博十学位论文).大连:大连海事大学,2008.
    [73]冯春杨,赵君科.脉冲电晕技术在处理挥发性有机化合物中的应用研究.安全与环境学报,2004(1):59-61.
    [74]孟诺,鲁娜,李国锋等.填充床/沿面复合放电等离子体降解苯的研究.河北大学学报,2010,30(5):530-533.
    [75]李坚,马广大.电晕法处理易挥发性有机物(VOCs)的实验研究.环境工程,1999,17(3):30-32.
    [76]梁文俊,李坚,李依丽等.低温等离子体法去除苯和甲苯废气性能研究.环境污染治理技术与设备,2005,6(5):51-55.
    [77]余权.直流电晕自由基簇射中发射光谱检测与诊断:(硕士学位论文),杭州:浙江大学,2007.
    [78]杨树.多针对板电晕微观特性及降低其有害副产物:(博士学位论文).大连:大连海事大学,2011.
    [79]宿鹏浩.针阵列对板电晕放电及其与催化结合脱硝研究:(博士学位论文),大连:大连海事大学,2008.
    [80]张零零.发射光谱研究多针对板电晕放电微观电参数及激发态OH自由基特性:(硕十学位论文).大连:大连海事大学,2010.
    [81]孙明,吴彦,张家良等.空气电晕放电中的OH自由基发射光谱.光谱学与光谱分析,2005,25(1):108-112.
    [82]Hui Ge, Lingling Zhang, Ling Yan, et al. Parameter optimization of excited OH radical in multi-needle to plate negative DC corona discharge. Journal of El-ectrostatics,2011 (69):529-532.

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