片状铝粉复合粒子的制备及性能研究
|
摘要
为了使片状铝粉颜料满足水性及粉末涂料的环保要求并增加其颜色多样性,以普通片状铝粉颜料为研究对象,采用液相法研制了铝/二氧化硅(Al/SiO2)、铝/二氧化硅/氧化铁(Al/SiO2/Fe2O3)、铝/二氧化硅/普鲁士蓝(Al/SiO2/PB)三种复合粒子。为了获得包覆物在片状铝粉表面优良的包覆效果,考察了包覆物与底材表面电荷的匹配及表面活性剂的作用,优化了制备过程各主要影响因素,对所制备的复合粒子的分散性、耐腐蚀性及颜色特征等性能进行了表征,最后考察了三种复合粒子在水性及粉末涂料中的应用。
1、溶胶凝胶法制备Al/SiO2复合粒子及其表征。以正硅酸乙酯(TEOS)水解缩合及A1与Si02间静电吸附理论为依据,实验考察了水(nw)、乙二胺(nE)、正硅酸乙酯(nTEOS)及铝(nAl)之间摩尔比的影响,结果表明：nW:nTEOS、nE:nTEOS和nTEOS:nAl的增大有利于提高包覆效率(CE)和包覆率(PC),可增强Al/SiO2复合粒子的耐腐蚀性能,但摩尔比太高会导致片状铝粉间的团聚,影响复合粒子的分散性能；最佳条件为：nw:nTEOS=11.6,nE:nTEOS=5.54×10-2,nTEOS:nAl=6.06×10-2,此时CE值可达到99.6%。包覆前后粒子的中位径分别为16.05和16.20μm,表明复合粒子之间基本无团聚现象；SEM、EDS及FTIR分析表明Al/SiO2复合粒子表面存在一层二氧化硅包覆膜；AFM分析表明二氧化硅包覆层表面均匀平整,平均粗糙度(Ra)仅为3.9nm；BET结果表明表面包覆层结构比较致密,其平均孔径为19.4nm,孔隙率仅为7.52%。
2、表面活性剂在Al/SiO2复合粒子表面的吸附。依据静电引力及疏水力作用原理,考察了三种表面活性剂在Al/SiO2表面的吸附特性,发现十六烷基三甲基溴化铵(CTAB)在Al/SiO2粒子表面的吸附可能是双层吸附,第一层通过静电引力产生吸附,第二层的吸附作用力则是长碳链间的疏水力。Al/SiO2表面对十二烷基硫酸钠(SDS)吸附量很少。壬基酚聚氧乙烯醚磷酸酯(PPOP)在不同pH条件下表现出非离子或阴离子表面活性剂的特性,在Al/SiO2粒子表面可能产生多层吸附。通过表面活性剂的吸附可在一定范围内调控Al/SiO2复合粒子表面电性等性能。
3、液相沉淀法制备Al/SiO2/Fe2O3复合粒子及其表征。在Al/SiO2表面进行Fe2O3的包覆过程中,考察了表面活性剂、pH等参数的影响。结果表明：SDS和CTAB对CE有抑制作用,而PPOP能显著提高CE值,并有利于氧化铁在Al/SiO2表面形成均匀的纳米颗粒膜,最佳浓度条件下样品的CE值可达到95.5%。随着反应过程pH值的增大,形成包覆层的氧化铁颗粒粒径呈增大的趋势,会降低金属鳞片动态式指数(FI)。XRD结果表明Al/SiO2/Fe(OH)3表面的颗粒膜是无定型的,450℃锻烧后可转变为α-Fe2O3。锻烧后制得的Al/SiO2/Fe2O3复合粒子,由Al/SiO2的银灰色转变为金黄色,且具有明显的“随角异色”效应。
4、液相沉淀法制备Al/SiO2/PB复合粒子及其表征。实验考察了PB包覆过程的影响因素,发现采用阳离子表面活性剂CTAB对PC及CE具有明显的提升作用,其中CE可达到99.5%,pH值及温度对CE的影响很小。SEM和XRD结果表明包覆层为PB纳米粒子组成的颗粒膜,排列均匀致密,为立方相普鲁士蓝。经PB包覆后,复合粒子表面的平均粗糙度为16.9nm。制备得到的Al/SiO2/PB复合粒子呈蓝色并具有极强的金属光泽,色差仪分析结果表明复合粒子至少在三个角度具有不同的颜色。
5、片状铝粉复合粒子在涂料中的应用。选取某国外产品为参比对象,对制得的三种复合粒子在普通商用水性涂料和粉末涂料中的应用性能进行了系统地对比分析,结果表明：四种复合粒子的储存稳定性均优良,附着力等级达到国家标准1级以上,含Al/SiO2和Al/SiO2/Fe2O3的色板的耐酸碱性能明显好于国外样品。对复合粒子耐腐蚀性能的研究表明,采用pH10的氢氧化钠溶液为腐蚀液可对片状铝粉颜料在水性涂料中的稳定性进行快速定量检测,40℃10天的析氢量小于1ml/g可满足实际水性涂料90天的储存要求,大大缩短了含铝粉颜料的水性涂料稳定性的检测时间。
Silica coated flaky aluminium powders (Al/SiO2), ferric oxide and silica coated flaky aluminium powders (Al/SiO2/Fe2O3) and Prussian blue and silica coated flaky aluminium powders (Al/SiO2/PB) were developed using common flaky aluminium pigments as subject by liquid method to meet the needs of waterborne coatings and powder coatings and to improve the color diversity. For good coating layer on alminium powder, the charge proportion between coating material and base, role of surfactants and main influencing factors of preparation process were investigated. Dispersibility, corrosive resistance and color feature of composite particles were characterized, and also, the application of three composite particles in waterborne coatings and powder coatings were studied.
1. The preparation of Al/SiO2composite particles by sol-gel method and their characterization. Based on the theory of hydrolytic condensation of tetraethyl orthosilicate (TEOS) and electrostatic adsorption between Al particle and silica, the concentrations of water (nw:nTEOs), ethylenediamine (nE:nTEOs) and TEOS (nTEOs:nAl) were investigated deeply. Results of the tests indicated that the improvement of nw:nTEOS, nE:nTEOS and nTEOS:nAl help the coating efficiency (CE) and percentage of coating (PC) values and improve the corrosive resistance, however, exceptionally high concentration will lead to aggregation and therefore reduce the dispersibility. The optimum conditions are nw:nTEOS=11.6, nE:nTEOS=5.54×10-2, nTEOS:nAl=6.06×10-2and CE value is99.6%. Grain size of Al and Al/SiO2indicated that the composite particle have excellent dispersibility. Results of SEM、EDS and FTIR analyses proved that there is a layer of silica coating on the surface of flaky aluminium particle. The average roughness (Ra) is only3.9nm through AFM analysis. Average pore size and porosity are19.4nm and7.52%, indicating that the coating layer is dense.
2. Adsorption of surfactants on Al/SiO2surface. According to the theory of electric attraction and hydrophobic force, the adsorbing of three surfactants on Al/SiO2surface was investigated. The results showed that the adsorption of cetyltri methyl ammonium bromide (CTAB) on Al/SiO2surface may be two layers, which one is obtained by electric attraction and the other is by hydrophobic force among the long-chain carbon. Quantity of adsorbing for sodium dodecyl sulfate (SDS) on Al/SiO2surface is poor. The structure of phosphate polyoxyethylene octyl phenol (PPOP) is affected by pH, therefore, it exhibits the characteristic of non-ionic surfactant or anionic surfactant. Adsorption of PPOP on Al/SiO2surface may be multilayer structure. The surface charge of Al/SiO2could be easily changed through the adsorption of surfactants.
3. The preparation of Al/SiO2/Fe2O3composite particles by liquid precipitation and their characterization. The influence of parameters like surfactants, pH and so on were investigated during the coating of Fe2O3. The results showed that SDS and CTAB are harmful to CE, however, PPOP is very beneficial to the CE value which is95.5%under the best PPOP concentration. The particle size of Fe2O3increases with the increase of pH leading to the decrease of flop index (FI). Results of XRD indicated that the nano particle structure is amorphous and it will be transformed into α-Fe2O3through calcination at450℃. The gained Al/SiO2/Fe2O3is golden color and has excellent sparkle effect.
4. The preparation of Al/SiO2/PB composite particles by liquid precipitation and their characterization. It can be seen that CTAB benefits PC and CE, however, pH and temperature influence the CE value little. The highest CE value is99.5%. SEM and XRD results showed that the layer is composed of nano cubic phase PB particles. Ra is16.9nm. Al/SiO2/PB composite particles are metallic blue and at least have three colors under different angles.
5. Application of flaky aluminium composite particles in coatings. Compared with the product abroad, the performance of the three composite particles in waterborne coatings and powder coatings were tested systematically. The results showed that storage stability of the four is good, adhesion rate is above1according to national standard and anticorrosive of paint film with Al/SiO2or Al/SiO2/Fe2O3is better than product abroad. The anticorrosive of composite particles indicated that the stability of aluminium pigments in waterborne coating could be tested rapidly and quantitatively through sodium hydroxide of pH10. The gas volume less than1ml/g in10days at40℃could meet the stability about90days for the actual waterborne coatings, reducing the stability testing time for waterborne coating which contains aluminium pigments.
1、溶胶凝胶法制备Al/SiO2复合粒子及其表征。以正硅酸乙酯(TEOS)水解缩合及A1与Si02间静电吸附理论为依据,实验考察了水(nw)、乙二胺(nE)、正硅酸乙酯(nTEOS)及铝(nAl)之间摩尔比的影响,结果表明：nW:nTEOS、nE:nTEOS和nTEOS:nAl的增大有利于提高包覆效率(CE)和包覆率(PC),可增强Al/SiO2复合粒子的耐腐蚀性能,但摩尔比太高会导致片状铝粉间的团聚,影响复合粒子的分散性能；最佳条件为：nw:nTEOS=11.6,nE:nTEOS=5.54×10-2,nTEOS:nAl=6.06×10-2,此时CE值可达到99.6%。包覆前后粒子的中位径分别为16.05和16.20μm,表明复合粒子之间基本无团聚现象；SEM、EDS及FTIR分析表明Al/SiO2复合粒子表面存在一层二氧化硅包覆膜；AFM分析表明二氧化硅包覆层表面均匀平整,平均粗糙度(Ra)仅为3.9nm；BET结果表明表面包覆层结构比较致密,其平均孔径为19.4nm,孔隙率仅为7.52%。
2、表面活性剂在Al/SiO2复合粒子表面的吸附。依据静电引力及疏水力作用原理,考察了三种表面活性剂在Al/SiO2表面的吸附特性,发现十六烷基三甲基溴化铵(CTAB)在Al/SiO2粒子表面的吸附可能是双层吸附,第一层通过静电引力产生吸附,第二层的吸附作用力则是长碳链间的疏水力。Al/SiO2表面对十二烷基硫酸钠(SDS)吸附量很少。壬基酚聚氧乙烯醚磷酸酯(PPOP)在不同pH条件下表现出非离子或阴离子表面活性剂的特性,在Al/SiO2粒子表面可能产生多层吸附。通过表面活性剂的吸附可在一定范围内调控Al/SiO2复合粒子表面电性等性能。
3、液相沉淀法制备Al/SiO2/Fe2O3复合粒子及其表征。在Al/SiO2表面进行Fe2O3的包覆过程中,考察了表面活性剂、pH等参数的影响。结果表明：SDS和CTAB对CE有抑制作用,而PPOP能显著提高CE值,并有利于氧化铁在Al/SiO2表面形成均匀的纳米颗粒膜,最佳浓度条件下样品的CE值可达到95.5%。随着反应过程pH值的增大,形成包覆层的氧化铁颗粒粒径呈增大的趋势,会降低金属鳞片动态式指数(FI)。XRD结果表明Al/SiO2/Fe(OH)3表面的颗粒膜是无定型的,450℃锻烧后可转变为α-Fe2O3。锻烧后制得的Al/SiO2/Fe2O3复合粒子,由Al/SiO2的银灰色转变为金黄色,且具有明显的“随角异色”效应。
4、液相沉淀法制备Al/SiO2/PB复合粒子及其表征。实验考察了PB包覆过程的影响因素,发现采用阳离子表面活性剂CTAB对PC及CE具有明显的提升作用,其中CE可达到99.5%,pH值及温度对CE的影响很小。SEM和XRD结果表明包覆层为PB纳米粒子组成的颗粒膜,排列均匀致密,为立方相普鲁士蓝。经PB包覆后,复合粒子表面的平均粗糙度为16.9nm。制备得到的Al/SiO2/PB复合粒子呈蓝色并具有极强的金属光泽,色差仪分析结果表明复合粒子至少在三个角度具有不同的颜色。
5、片状铝粉复合粒子在涂料中的应用。选取某国外产品为参比对象,对制得的三种复合粒子在普通商用水性涂料和粉末涂料中的应用性能进行了系统地对比分析,结果表明：四种复合粒子的储存稳定性均优良,附着力等级达到国家标准1级以上,含Al/SiO2和Al/SiO2/Fe2O3的色板的耐酸碱性能明显好于国外样品。对复合粒子耐腐蚀性能的研究表明,采用pH10的氢氧化钠溶液为腐蚀液可对片状铝粉颜料在水性涂料中的稳定性进行快速定量检测,40℃10天的析氢量小于1ml/g可满足实际水性涂料90天的储存要求,大大缩短了含铝粉颜料的水性涂料稳定性的检测时间。
Silica coated flaky aluminium powders (Al/SiO2), ferric oxide and silica coated flaky aluminium powders (Al/SiO2/Fe2O3) and Prussian blue and silica coated flaky aluminium powders (Al/SiO2/PB) were developed using common flaky aluminium pigments as subject by liquid method to meet the needs of waterborne coatings and powder coatings and to improve the color diversity. For good coating layer on alminium powder, the charge proportion between coating material and base, role of surfactants and main influencing factors of preparation process were investigated. Dispersibility, corrosive resistance and color feature of composite particles were characterized, and also, the application of three composite particles in waterborne coatings and powder coatings were studied.
1. The preparation of Al/SiO2composite particles by sol-gel method and their characterization. Based on the theory of hydrolytic condensation of tetraethyl orthosilicate (TEOS) and electrostatic adsorption between Al particle and silica, the concentrations of water (nw:nTEOs), ethylenediamine (nE:nTEOs) and TEOS (nTEOs:nAl) were investigated deeply. Results of the tests indicated that the improvement of nw:nTEOS, nE:nTEOS and nTEOS:nAl help the coating efficiency (CE) and percentage of coating (PC) values and improve the corrosive resistance, however, exceptionally high concentration will lead to aggregation and therefore reduce the dispersibility. The optimum conditions are nw:nTEOS=11.6, nE:nTEOS=5.54×10-2, nTEOS:nAl=6.06×10-2and CE value is99.6%. Grain size of Al and Al/SiO2indicated that the composite particle have excellent dispersibility. Results of SEM、EDS and FTIR analyses proved that there is a layer of silica coating on the surface of flaky aluminium particle. The average roughness (Ra) is only3.9nm through AFM analysis. Average pore size and porosity are19.4nm and7.52%, indicating that the coating layer is dense.
2. Adsorption of surfactants on Al/SiO2surface. According to the theory of electric attraction and hydrophobic force, the adsorbing of three surfactants on Al/SiO2surface was investigated. The results showed that the adsorption of cetyltri methyl ammonium bromide (CTAB) on Al/SiO2surface may be two layers, which one is obtained by electric attraction and the other is by hydrophobic force among the long-chain carbon. Quantity of adsorbing for sodium dodecyl sulfate (SDS) on Al/SiO2surface is poor. The structure of phosphate polyoxyethylene octyl phenol (PPOP) is affected by pH, therefore, it exhibits the characteristic of non-ionic surfactant or anionic surfactant. Adsorption of PPOP on Al/SiO2surface may be multilayer structure. The surface charge of Al/SiO2could be easily changed through the adsorption of surfactants.
3. The preparation of Al/SiO2/Fe2O3composite particles by liquid precipitation and their characterization. The influence of parameters like surfactants, pH and so on were investigated during the coating of Fe2O3. The results showed that SDS and CTAB are harmful to CE, however, PPOP is very beneficial to the CE value which is95.5%under the best PPOP concentration. The particle size of Fe2O3increases with the increase of pH leading to the decrease of flop index (FI). Results of XRD indicated that the nano particle structure is amorphous and it will be transformed into α-Fe2O3through calcination at450℃. The gained Al/SiO2/Fe2O3is golden color and has excellent sparkle effect.
4. The preparation of Al/SiO2/PB composite particles by liquid precipitation and their characterization. It can be seen that CTAB benefits PC and CE, however, pH and temperature influence the CE value little. The highest CE value is99.5%. SEM and XRD results showed that the layer is composed of nano cubic phase PB particles. Ra is16.9nm. Al/SiO2/PB composite particles are metallic blue and at least have three colors under different angles.
5. Application of flaky aluminium composite particles in coatings. Compared with the product abroad, the performance of the three composite particles in waterborne coatings and powder coatings were tested systematically. The results showed that storage stability of the four is good, adhesion rate is above1according to national standard and anticorrosive of paint film with Al/SiO2or Al/SiO2/Fe2O3is better than product abroad. The anticorrosive of composite particles indicated that the stability of aluminium pigments in waterborne coating could be tested rapidly and quantitatively through sodium hydroxide of pH10. The gas volume less than1ml/g in10days at40℃could meet the stability about90days for the actual waterborne coatings, reducing the stability testing time for waterborne coating which contains aluminium pigments.
引文
[1]Gunter K, Werner O, Gunter S. Corrosion-stable aluminum pigments and process for the production thereoftP]. United States, US6287695,2001-09-11.
[2]Sabine S, Christoph S. Colored pigments[P]. United States, US6884289, 2005-04-26.
[3]Matthias K, Reiner D, Rodney R. Optically variable marking[P]. United States, US20030012935,2003-01-16.
[4]Carsten H, Thomas R, Herwig B. Particles comprising an anion-binding layer containing anion-forming organic active compounds, and method of making and using thereof[P]. United States, US7914893,2011-03-29.
[5]Yukitaka W. Cosmetic body pigment and process for preparing the same[P]. United States, US20030147819,2003-08-07.
[6]Hans-jurgen B, Manfred K, Emil A. Plastic part comprising lustrous pigments and filler particles[P]. United States, US20020120051,2002-08-29.
[7]Gerhard E. Laser-markable plastics and their preparation and use[P]. United States, US20020107305,2002-08-08.
[8]Ulrich K, Peter S, Thomas L. Metallic ink, and use thereof for improving prints[P]. United States, US20070022901,2007-02-01.
[9]Sabine S, Reiner V, Norbert S. Pigment preparation and its use especially in printing inks[P]. United States, US20020056399,2002-05-16.
[10]Ralf A, Klaus A, Marcus M. Effect pigments based on coated glass flakes[P]. United States, US7226503,2007-06-05.
[11]Veronika H, Sabine S. Pigment mixture, and the use thereof in cosmetics and in the foods and pharmaceuticals sector[P]. United States, US7485183,2009-02-03.
[12]Silvia R, Guido O, Dieter H. Infrared-reflective material [P]. United States, US20030215627,2003-10-20.
[13]Glausch R. Pigment preparation for anticorrosion paints[P]. United States, US20020148390,2002-10-17.
[14]Glausch R. Process for preparing electrically conductive pigments[P]. United States, US20020053661,2002-05-09.
[15]Griessmann C, Rathschlag T. Stabilized BiOCl pigments[P]. United States, US7318862,2008-02-15.
[16]Stephanie A, Gerald F, Martin F. Multilayered luster pigments[P]. United States, US7060126,2006-06-13.
[17]Elke S, Hans-Dieter B, Gerhard P. Transparent medium having angle-selective transmission or reflection properties and/or absorption properties[P]. United States, US6767633,2004-07-27.
[18]Gerhard P, Cornelia F, Doreen W. Effect pigments having a strong color flop[P]. United States, US7169223,2007-01-30.
[19]Gerhard P, Cornelia F, Doreen W. Intensely colored red effect pigments[P]. United States, US7156913,2007-02-02.
[20]Stephanie A, Sabine G, Margarete H. Multilayer pigments based on coated metal platelets[P]. United States, US6776835,2004-08-17.
[21]Clarke T, Francis A. Mica containing pigment and method of making the same[P]. United States,1942-4-7.
[22]Katuhisa N, Ming ST, Jun S. Flaky aluminum oxide and pearlescent pigment, and production thereof[P]. European Patent, EP0763573,2001-07-04.
[23]Gerhard P, Sabine S, Nishimagi A. Pigment mixture[P]. United States, US6267810,2001-07-31.
[24]Teaney S, Pfaff G, Nitta K. New effect pigments using innovative substrates silica and alumina platelets extend the product variety and performance range of pearlescent pigments[J]. Eur Coat J 1999,51(4):90-96.
[25]Bauer G, Karl O, Christoph S. Colored and coated plateletlike pigments[P]. United States, US6630018,2003-10-07.
[26]Pfaff G, Reynders P. Angle-dependent optical effects deriving from submicron structures of films and pigments[J]. Chem Rev 1999,39(99):1963-1981.
[27]Burkhard K, Matthias K, Rein R. Optically variable pigments of high electrical conductivity[P]. United States, US20100258769,2010-10-14.
[28]Sabine S, Reiner V, Norbert S. Pigment mixture[P]. United States, US20030177950,2003-09-25.
[29]Gerhard P, Helge K, Peter R. Multilayered interference pigments[P]. United States, US20030039836,2003-02-27.
[30]Gerhard P, Doreen W, Johann D. Effect pigments based on thin SiO2 flakes[P]. United States, US7255736,2007-08-14.
[31]Stephanie A, Gerd B, Gunt B. Multilayer interference pigments[P]. United States, US20010001174,2001-05-17.
[32]Stephanie A, Gerd B, Gunter B. Metal oxide coated titanium dioxide lamellas[P]. United States, US6238472,2001-05-29.
[33]Linton HR. Nacreous pigment compositions[P]. United States, US3087828, 1963-04-30.
[34]王世荣.云母钛珠光颜料及其有机着色[D].天津：天津大学,1994.
[35]Horst B, Kurt M. Dyed lustrous pigments[P]. United States, US4084983, 1978-04-18.
[36]Stephanie A, Gerald F, Martin F. Multilayered luster pigments[P]. United States, US20030005859,2003-01-09.
[37]Lilia H, Manuela L, Nicole S. Coloured interference pigments[P]. United States, US20030097965,2003-05-29.
[38]Carsten H, Marcus M, Nicole S. Pearlescent Pigments[P]. United States, US20100021565,2010-01-28.
[39]Christoph S, Andrea H, Claudia F. Silver-colored luster pigment[P]. United States, US20030205170,2003-10-06.
[40]Sabine S, Klaus B, Christoph S. Intensely colored interference pigments[P]. United States, US6692561,2004-02-17.
[41]Christoph S, Andrea H, Sabine S. Five-layered pigments[P]. United States, US20040052743,2004-03-18.
[42]Glausch R. After coating of pearl luster pigments with hydrophobic coupling reagents[P]. United States, US6488757,2002-12-03.
[43]Reiner V, Hans-dieter B. Interference pigments having a blue mass tone[P]. United States, US6238471,2001-05-29.
[44]Gerhard P, Matthias K, Reiner V. Sulfide and oxysulphide pigments[P]. United States, US6419736,2002-07-16.
[45]钟盛文,匡敬忠,叶雪均.珠光颜料的研究方法与新进展[J].中国矿业,2001,16(4)：33-36.
[46]彭同江,宋功保,刘福生.国内外云母珠光颜料的生产研究进展[J].中国非金属矿业导刊,2000,(5)：25-29.
[47]王显祥,章娴君.国内外云母珠光颜料研究进展[J].西南师范大学学报自然科学版,2002,(3).
[48]韩云芳,谭俊茹,侯文祥.着色型云母系珠光颜料的制备工艺进展[J].化学工业与工程,2001,18(3)：167-172.
[49]张德文,韩明友.金色云母钛珠光颜料的制备[J].1998,(8)：402-405.
[50]张德文,孙淑清.蓝色云母钛珠光颜料的制备[J].辽宁化工,1996,(3)：35-36.
[51]Raimund S, Norbert M. Luster pigments with a metal sulfide coating[P]. United States, US5401306,1995-03-28.
[52]朱永成,刘文砥.一种光变油墨及其印刷方法[P].中国,201010183086.8,2010-05-26.
[53]Linton HR. Micaceous pigment composition[P]. United States, Patent US3087829,1963-04-30.
[54]章娴君,王显祥,郑慧雯.用MOCVD法制备TiO2/Fe2O3双包覆层珠光颜料[J].西南师范大学学报(自然科学版)2004,29(2)：245-248.
[55]伯恩斯.颜色技术原理[M].北京：化学工业出版社,2002.
[56]Li-Pin S, Mcknight ME. Optical reflectance of matallic coatings:effect of aluminum flake orientation[J]. Journal of Coatings Technology,2002, 932(74):55-63.
[57]付义平.铝粉颜料的制备及其改性研究[D].江苏南京：南京理工大学,2005.
[58]金晓鸿.防腐涂料和涂装技术(Ⅲ)[J].材料开发与应用,2001,16(3)：42-46.
[59]王锡春.高装饰性金属色汽车面漆涂装工艺[J].涂料工业,2004,34(8)：41-50.
[60]付义平,李凤生,付廷明.闪光铝粉颜料的制备研究[J].轻合金加工技术,2005,(33)：3.
[61]钱伯容.非浮型铝粉及珠光颜料在闪光漆中的应用[J].现代涂料与涂装,1998,(3)：30-35.
[62]郑水林.粉体表面改性[M].北京：中国建材工业出版社,1995.
[63]朱骥良,吴申年.颜料工艺学[M].北京：化学工业出版社,2002.
[64]吴和元.闪光铝颜料球磨工艺的研究[J].湖南冶金,1998,(1)：11-14.
[65]李会莉,陈岁元,刘常升.球磨法制备微细A1片的研究[J].有色矿冶,2001,17(6)：39-42.
[66]袁诚,何煜.振动磨法制备金属颜料[J].涂料工业,1999,(3)：18-20.
[67]陈振兴.特种粉体[M].北京：化学工业出版社,2004.
[68]Wheeler I. Metallic pigments in polymers[M]. London:Rapra Technology Limited,1999.
[69]Pertays KM, Thompson GE, Alexander MR. Self-assembly of stearic acid on aluminium:the importance of oxide surface chemistry [J]. Surf Interface Anal, 2004,41(36):1361-1366.
[70]Wolfgang G, Lothar B. Water-dispersible aluminium pastes[P]. United States, US3970577,1976-07-20.
[71]Gunter S, Colin A. Metal pigment dispersions, process for the production thereof and use thereof[P]. United States, US5849072,1998-12-15.
[72]Ferguson RL. Lamellar pigment particle dispersion[P]. United States, US6177486,2001-01-23.
[73]付义平,李凤生,付廷明.闪光铝粉颜料的制备研究[J].轻合金加工技术,2005,33(7)：33-36.
[74]周毅,贾延刚.铝粉化学着色初探[J].阴山学刊,1995,13(2)：30-33.
[75]Wolfgang R. Oxidized colored aluminium pigments, process for their production and their use[P]. United States, US5964936,1999-10-12.
[76]Frieser RG, Station N. Gold colored metallic pigments[P]. United States, US 3067052,1962-12-04.
[77]Keemer C, Jenkins WG, Lamborn TH. Water resistant metal pigment particles[P]. United States, US5215579,1991-08-21.
[78]Tetsufumi K, Toshiaki B, Takashi M. Aluminum pigment composition[P]. United States, US 4869754,1989-11-26.
[79]Tom K. Inhibitive treatment for aluminum pigments[P]. United States, US4808231,1989-02-28.
[80]Kondis T. Aluminum particles resistant to reaction with water[P]. United States, US 4693754,1987-11-15.
[81]Oppen D, Lampatzer K. Chromium-free surface treatment[P]. United States, US4264378,1981-04-28.
[82]Hashizume R, Yoshiki W. Colored aluminium pigments and the preparation process thereof[P]. United States, US5944886,1999-08-31.
[83]Yamamoto T, Uenishi M, Katoh H. Aluminum pigments[P]. United States, US5494512,1996-02-27.
[84]Jenkins WG, Lamborn KC, Taylor H. Aqueous resistant metal pigment-containing paste and method for making [P]. United States, US5356469, 1994-02-19.
[85]Keemer CB, Taylor H. Inhibited metal pigment pastes containing molybdate pigments and suitable for aqueous coating compositions [P]. United States, US5993523,1999-10-30.
[86]Cape R, Thomas W. Process and composition for sealing a conversion coated surface with a solution containing vanadium[P]. United States, US4828615, 1989-05-09.
[87]Souma T, Ishidoya M. Chromatic-color metal flake pigment and colored composition compounded therewith[P]. United States, US5091010,1992-02-25.
[88]Wolfgang R, Sommer G Synthetic resin-coated metal pigment, process for the production thereof and use thereof[P]. United States, US 5332767,1994-07-26.
[89]Eiji U, Koushiro K. Flaky pigments coated with a coupling agent and a perfluoroalkyl phosphate[P]. United States, US7160374,2007-01-09.
[90]Uchiyama T, Hasegawa M. Process for preparing colored aluminum powder[P]. United States, US 4158074,1979-06-12.
[91]Garrigues PN, Dabosi F. An investigation of the corrosion inhibition of pure aluminum in neutral and acidic chloride solution[J]. Electrochimica Actra,1996, (41):1209.
[92]Szunerits S. Aluminum surface corrosion and the mechanism of inhibitors using pH and metal ion selective imaging fiber bundles[J]. Anal Chem,2002, (74):9.
[93]Huerta-Vilca D, Sandra R. Role of a chelating agent in the formation of polyaniline films on aluminum[J]. J Appl Polym Sci,2003,19(90):819-823.
[94]Das M, Mahiuddin S. Kinetics and adsorption behaviour of benzoate and phthalate at the a-alumina-water interface:Influence of functionality[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2005,27(264):90-100.
[95]Kummert R. The surface complexation of organic acids on hydrous-Al2O3[J]. J Colloid Interface Sci,1980, (75):13.
[96]Hidber PC, Gauckler LJ. Influence of the dispersant structure on properties of electrostatically stabilized aqueous alumina suspensions[J]. J Eur Ceram Soc, 1997,(17):11.
[97]Muller B. Corrosion inhibition of different metal pigments in aqueous alkaline media[J]. Corrosion Science,2001,43(6):1155-1164.
[98]Muller B, Kubitzki G, Kinet G Aromatic 2-Hydroxy-Oximes as corrosion inhibitors for aluminium and zinc pigments[J]. Corrosion Science,1998, 40(9):1469-1476.
[99]Muller B. Amino and polyamino acids as corrosion inhibitors for aluminum and zinc pigments[J]. Pigment & Resin Technology,2002, (31):4.
[100]Muller B. Corrosion inhibition of aluminium and zinc pigments by saccharides[J]. Corrosion Science,2002,44(7):1583-1591.
[101]Muller B, Kubitzki G, Kinet G. Citric acid as corrosion inhibitor for aluminium pigmen[J]. Corrosion Science,2004,46(1):159-167.
[102]Muller B, Shahid M, Kinet G Nitro-and aminophenols as corrosion inhibitors for aluminium and zinc pigments[J]. Corrosion Science,1999, 41(7):1323-1331.
[103]Wolfgang R, Guenter S. Synthetic resin-coated metal pigment, process for the production thereof and use thereof[P]. United States, US5332767,1994-07-24.
[104]Klaus G, Alfried K. Effect pigments coated with reactive orientation aids[P]. United States, US6761762,2004-07-13.
[105]Keemer CB, Jenkins WG Colored metallic pigments [P]. United States, US5558705 1996-12-24.
[106]潘卓,赵振声,何华辉.低红外发射率材料的研究[J].华中科技大学学报,2003,31(7)：28-30.
[107]Raimund S, Norbert M. Multiply coated metallic luster pigments[P]. United States, US5624486,1997-04-29.
[108]Bujard P, Rebbergweg O. Flake-form pigments based on aluminum coated with SiOz[P]. Canada, WO 2004/052999 A2,2004-06-24.
[109]Kaupp G, Neuhaus Q. Corrosion-stable aluminum pigments and process for the production thereof[P]. United States, US 6287695 B1,1997-07-08.
[110]Sato ST, Ryoji P. Fe2O3 particles coated with silica using TEOS[J]. Bulletin of the Chemical Society of Japan,2003, (1):7.
[111]Giinter S. Nacreous pigment and method for the manufacture thereof[P]. United States, US7217318,2007-05-15.
[112]Ostertag W, Gruenstadt F. Metal oxide coated aluminum pigments[P]. United States, US 4978394,1990-12-18.
[113]Werner O, Knut B, Gustav B. Preparation of metallic pigments having a metallic luster[P]. United States, US 4328042,1982-05-04.
[114]Armanini T, Louis W. Metal oxide platelets as nacreous pigments[P]. United States, US4192691,1980-03-11.
[115]Gale R, Jeannine M. Pearlescent pigments exhibiting color travel[P]. United States, US6165260,2000-12-20.
[116]Deluca JR. Interference pigments [P]. United States US6485556 2002-12-26.
[117]Rozumek ME. Pigments having a viewing angle dependent shift of color, method for producing said pigments, use of said pigments in security applications, coating composition comprising said pigments and a detecting device[P]. United States, US6695905,2004-02-24.
[118]Fu WY, Yang HB, Chang LX. Preparation and characteristics of core-shell structure nickel/silica nanoparticles[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2005,262:6.
[119]Mine E, Yamad A, Kobayashi Y. Direct coating of gold nanoparticles with silica by a seeded polymerization technique[J]. Journal of Colloid and Interface Science,2003,264(2):385-390.
[120]Li BY, Nobuaki N, Katsuhisa N. Highly anti-corrosive metal pigments[P]. United States, US7419538,2008-09-02.
[121]Kiehl A, Greiwe K. Encapsulated aluminium pigments[J]. Progress in Organic Coatings,1999,37:179-183.
[122]Supplit R, Schubert U. Corrosion protection of aluminum pigments by sol-gel coatings[J]. Corrosion Science,2007,49(8):3325-3332.
[123]Li LJ, Wen XF. Optimization of sol-gel coatings on the surface of aluminum pigments for corrosion protection[J]. Corrosion Science,2008,50:9.
[124]Batzar K, Piscataway R. Preparation of dense silica-encapsulated aluminum flake pigment treated with a carboxylic chromic chloride[P]. United States, US3954496,1976-05-04.
[125]Nadkarni SK, Mass L. Coloring aluminum flakes[P]. United States, US 5261955,1993-10-16.
[126]刘海峰,彭同江,孙红娟.α-Fe2O3-Mica纳米薄膜的制备[J].传感技术学报,2007,20(4)：755-759.
[127]侯文祥,付谭.古铜色珠光颜料的制备及动力学研究[J].硅酸盐学报,2003,(2)：81-85.
[128]侯文祥,谭俊茹,陈秀增.彩色云母系珠光颜料的制备机理研究及性能表征[J].现代涂料与涂装,2000,(2)：3-6.
[129]陈秀增,侯文祥,谭俊茹.虹彩型云母钛珠光颜料的制备与表征[J].化学工业与工程,1997,14(4)：1-5.
[130]谭俊茹,侯文祥,陈秀增.双包覆层Cr2O3/TiO2/MiCa彩色珠光颜料的制备机理及表征[J].现代涂料与涂装,1999,(1)：11-15.
[131]Rieger CJ. Exterior grade titanium dioxide coated mica [P]. United States US4134776,1979-01-16.
[132]Djur B, Mcgarry D, Pickering S. The preparation of ultra fine ceria-stabilized zircons particle coated with yttrium[J]. Ater Sci Lett,1993,23(12):1320-1323.
[133]孙家跃,郭萌萌,杜海燕.氧化钕改性云母钛光干涉颜料的制备及表征[J]. 硅酸盐学报,2006,25(6)：5-9.
[134]沈腊珍,谭俊茹,付贤松.纳米(1-x)SnO2.xSb2O3复合云母钛导电珠光颜料的制备[J].硅酸盐学报,2004,(4)：36-39.
[135]张德文,孙淑清.彩虹型云母钛珠光颜料的制备[J].石油化工高等学校学报,1999,(2)：42-44.
[136]刘永峙,韩爱军,叶明泉.均匀沉淀法制备Al/ZnS复合粒子[J].化工进展,2004,23(9)：990-992.
[137]李校远.片状铝粉和金属氧化物复合粒子的制备研究[D].南京：南京理工大学,2003.
[138]Glebov YL, Krishtopa LG, Usov OM. Coating of metal powders with polymers in supercritical carbon dioxide[J]. Ind Eng Chem Res,,2001,40:11.
[139]Miiller B. Polymeric corrosion inhibitors for aluminium pigment[J]. Reactive & Functional Polymers,1999,39(4):165-177.
[140]Liu H, Ye HQ, Zhang YC. Preparation and characterization of PMMA/flaky aluminum composite particle in the presence of MPS[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2008,315(1):1-6.
[141]Liu H, Ye HQ, Tang XD. Aluminum pigment encapsulated by in situ copolymerization[J]. Applied Surface Science,2007,2545.
[142]Liu H, Ye HQ, Zhang YC. Synthesis and property of poly(trimethylolpropane triacrylate)/Al nanocomposite particle by in situ solution polymerization[J]. Applied Surface Science,2008,254(15):4432-4438.
[143]Batzilla TH. Preparation of Encapsulated Aluminum Pigments by Emulsion Polymerization and their Characterization[J]. J Coat Technol,1998,70:7.
[144]Kimura TY, Yoshii H, Tanaka M. Encapsulation of aluminum flakes by dispersion polymerization of styrene in a nonaqueous system with reactive surfactants[J]. J Appl Polym Sci,2001,81(3):9.
[145]Kern GM. Resin compositions containing metals such as aluminum[P]. United States, US4544600,1985-10-01.
[146]何国兴.颜色科学[M].上海：东华大学出版社,2004.
[147]顺青.色度学[M].北京：北京理工大学出版社,1990.
[148]宋加金,刘长维,陈红军.耐腐蚀环氧粉末涂料的改性研究[J].热固性树脂,2007,(4).
[149]薛俊国.金、银与SiO2和α-Fe2O3复合纳米颗粒的制备[D].长春：东北师范大学,2007.
[150]Xu J, Carole C. A novel approach to Au@SiO2 core-shell spheres[J]. Journal of Non-Crystalline Solids,2007,353(5):1212-1215.
[151]袁俊杰.有机颜料的表面纳米包覆改性及其在涂料中的应用研究[D].上海：复旦大学,2006.
[152]Liu P, Su ZX. Preparation of polystyrene silica nanoparticles by two-steps UV induced reaction[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2004,167(2-3):237-240.
[153]Liu P. Hyperbranched aliphatic polyester grafted attapulgite via a melt polycondensation process[J]. Applied Clay Science,2007,35(1-2):11-16.
[154]任俊.颗粒分散科学与技术[M].北京：化学工业出版社,2005.
[155]Mine E, Yamada A, Kobayashi Y. Direct coating of gold nanoparticles with silica by a seeded polymerization technique[J]. J Colloid Interface Sci,2003, 264(2):385-390.
[156]Cheng B, Zhao L, Yu J. Facile fabrication of SiO2/Al2O3 composite microspheres with a simple electrostatic attraction strategy[J]. Materials Research Bulletin,2008,43(3-4):714-722.
[157]张昭.无机精细化工工艺学[M].北京：化学工业出版社,2009.
[158]Veeramasuneni S, Yalamanchili MR, Miller JD. Use of atomic force microscopy in particle science and technology research [J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,1998,133(5):77-88.
[159]Kavitha SY, Costas T. Copper uptake by inorganic particles-equilibrium, kinetics, and particle interactions:experimental [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2000,177(2):14.
[160]Wendon GW. Aluminium and bronze flake powders[M]. Ayr:Electrochemical publications limited,1983.
[161]戚栋明.聚丙烯酸酯/纳米SiO2复合粒子的原位(细)乳液聚合法制备及其应用[D].杭州：浙江大学,2006.
[162]秦宗会,谭蓉.用刚果红分光光度法测定阳离子表面活性剂[J].分析测度学报,2007,26(1)：113-116.
[163]秦宗会,胡武洪.刚果红-溴化十六烷基吡啶光度法测定阴离子表面活性剂[J].化学研究与应用,2008,20(7)：879-882.
[164]曲岩涛,李继山,王宗礼.CTAB改变固体表面润湿性的机理探讨[J].大庆石油地质与开发,2006,25(2)：52-53.
[165]Sanchez-Martim MJ, Dorado MC, Hoyo Cd. Influence of clay mineral structure and surfactant nature on the adsorption capacity of surfactants by clays[J]. Journal of Hazardous Materials,2008, (150):115-123.
[166]Marsalek R, Pospisil J, Taraba B. The influence of temperature on the adsorption of CTAB on coals[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2011,383:80-85.
[167]Giirsesa A, Karacab S, Acikyildiz M. Thermodynamics and mechanism of cetyltrimethylammonium adsorption onto clayey soil from aqueous solutions [J]. Chemical Engineering Journal,2009,147:194-201.
[168]朱友益,韩冬,沈平平.表面活性剂结构与性能的关系[D].北京：石油工业出版社,2003.
[169]胡鸣.铁氧化物与普鲁士蓝类化合物的形貌可控合成与非经典结晶机理研究[D].上海：华东师范大学,2010.
[2]Sabine S, Christoph S. Colored pigments[P]. United States, US6884289, 2005-04-26.
[3]Matthias K, Reiner D, Rodney R. Optically variable marking[P]. United States, US20030012935,2003-01-16.
[4]Carsten H, Thomas R, Herwig B. Particles comprising an anion-binding layer containing anion-forming organic active compounds, and method of making and using thereof[P]. United States, US7914893,2011-03-29.
[5]Yukitaka W. Cosmetic body pigment and process for preparing the same[P]. United States, US20030147819,2003-08-07.
[6]Hans-jurgen B, Manfred K, Emil A. Plastic part comprising lustrous pigments and filler particles[P]. United States, US20020120051,2002-08-29.
[7]Gerhard E. Laser-markable plastics and their preparation and use[P]. United States, US20020107305,2002-08-08.
[8]Ulrich K, Peter S, Thomas L. Metallic ink, and use thereof for improving prints[P]. United States, US20070022901,2007-02-01.
[9]Sabine S, Reiner V, Norbert S. Pigment preparation and its use especially in printing inks[P]. United States, US20020056399,2002-05-16.
[10]Ralf A, Klaus A, Marcus M. Effect pigments based on coated glass flakes[P]. United States, US7226503,2007-06-05.
[11]Veronika H, Sabine S. Pigment mixture, and the use thereof in cosmetics and in the foods and pharmaceuticals sector[P]. United States, US7485183,2009-02-03.
[12]Silvia R, Guido O, Dieter H. Infrared-reflective material [P]. United States, US20030215627,2003-10-20.
[13]Glausch R. Pigment preparation for anticorrosion paints[P]. United States, US20020148390,2002-10-17.
[14]Glausch R. Process for preparing electrically conductive pigments[P]. United States, US20020053661,2002-05-09.
[15]Griessmann C, Rathschlag T. Stabilized BiOCl pigments[P]. United States, US7318862,2008-02-15.
[16]Stephanie A, Gerald F, Martin F. Multilayered luster pigments[P]. United States, US7060126,2006-06-13.
[17]Elke S, Hans-Dieter B, Gerhard P. Transparent medium having angle-selective transmission or reflection properties and/or absorption properties[P]. United States, US6767633,2004-07-27.
[18]Gerhard P, Cornelia F, Doreen W. Effect pigments having a strong color flop[P]. United States, US7169223,2007-01-30.
[19]Gerhard P, Cornelia F, Doreen W. Intensely colored red effect pigments[P]. United States, US7156913,2007-02-02.
[20]Stephanie A, Sabine G, Margarete H. Multilayer pigments based on coated metal platelets[P]. United States, US6776835,2004-08-17.
[21]Clarke T, Francis A. Mica containing pigment and method of making the same[P]. United States,1942-4-7.
[22]Katuhisa N, Ming ST, Jun S. Flaky aluminum oxide and pearlescent pigment, and production thereof[P]. European Patent, EP0763573,2001-07-04.
[23]Gerhard P, Sabine S, Nishimagi A. Pigment mixture[P]. United States, US6267810,2001-07-31.
[24]Teaney S, Pfaff G, Nitta K. New effect pigments using innovative substrates silica and alumina platelets extend the product variety and performance range of pearlescent pigments[J]. Eur Coat J 1999,51(4):90-96.
[25]Bauer G, Karl O, Christoph S. Colored and coated plateletlike pigments[P]. United States, US6630018,2003-10-07.
[26]Pfaff G, Reynders P. Angle-dependent optical effects deriving from submicron structures of films and pigments[J]. Chem Rev 1999,39(99):1963-1981.
[27]Burkhard K, Matthias K, Rein R. Optically variable pigments of high electrical conductivity[P]. United States, US20100258769,2010-10-14.
[28]Sabine S, Reiner V, Norbert S. Pigment mixture[P]. United States, US20030177950,2003-09-25.
[29]Gerhard P, Helge K, Peter R. Multilayered interference pigments[P]. United States, US20030039836,2003-02-27.
[30]Gerhard P, Doreen W, Johann D. Effect pigments based on thin SiO2 flakes[P]. United States, US7255736,2007-08-14.
[31]Stephanie A, Gerd B, Gunt B. Multilayer interference pigments[P]. United States, US20010001174,2001-05-17.
[32]Stephanie A, Gerd B, Gunter B. Metal oxide coated titanium dioxide lamellas[P]. United States, US6238472,2001-05-29.
[33]Linton HR. Nacreous pigment compositions[P]. United States, US3087828, 1963-04-30.
[34]王世荣.云母钛珠光颜料及其有机着色[D].天津：天津大学,1994.
[35]Horst B, Kurt M. Dyed lustrous pigments[P]. United States, US4084983, 1978-04-18.
[36]Stephanie A, Gerald F, Martin F. Multilayered luster pigments[P]. United States, US20030005859,2003-01-09.
[37]Lilia H, Manuela L, Nicole S. Coloured interference pigments[P]. United States, US20030097965,2003-05-29.
[38]Carsten H, Marcus M, Nicole S. Pearlescent Pigments[P]. United States, US20100021565,2010-01-28.
[39]Christoph S, Andrea H, Claudia F. Silver-colored luster pigment[P]. United States, US20030205170,2003-10-06.
[40]Sabine S, Klaus B, Christoph S. Intensely colored interference pigments[P]. United States, US6692561,2004-02-17.
[41]Christoph S, Andrea H, Sabine S. Five-layered pigments[P]. United States, US20040052743,2004-03-18.
[42]Glausch R. After coating of pearl luster pigments with hydrophobic coupling reagents[P]. United States, US6488757,2002-12-03.
[43]Reiner V, Hans-dieter B. Interference pigments having a blue mass tone[P]. United States, US6238471,2001-05-29.
[44]Gerhard P, Matthias K, Reiner V. Sulfide and oxysulphide pigments[P]. United States, US6419736,2002-07-16.
[45]钟盛文,匡敬忠,叶雪均.珠光颜料的研究方法与新进展[J].中国矿业,2001,16(4)：33-36.
[46]彭同江,宋功保,刘福生.国内外云母珠光颜料的生产研究进展[J].中国非金属矿业导刊,2000,(5)：25-29.
[47]王显祥,章娴君.国内外云母珠光颜料研究进展[J].西南师范大学学报自然科学版,2002,(3).
[48]韩云芳,谭俊茹,侯文祥.着色型云母系珠光颜料的制备工艺进展[J].化学工业与工程,2001,18(3)：167-172.
[49]张德文,韩明友.金色云母钛珠光颜料的制备[J].1998,(8)：402-405.
[50]张德文,孙淑清.蓝色云母钛珠光颜料的制备[J].辽宁化工,1996,(3)：35-36.
[51]Raimund S, Norbert M. Luster pigments with a metal sulfide coating[P]. United States, US5401306,1995-03-28.
[52]朱永成,刘文砥.一种光变油墨及其印刷方法[P].中国,201010183086.8,2010-05-26.
[53]Linton HR. Micaceous pigment composition[P]. United States, Patent US3087829,1963-04-30.
[54]章娴君,王显祥,郑慧雯.用MOCVD法制备TiO2/Fe2O3双包覆层珠光颜料[J].西南师范大学学报(自然科学版)2004,29(2)：245-248.
[55]伯恩斯.颜色技术原理[M].北京：化学工业出版社,2002.
[56]Li-Pin S, Mcknight ME. Optical reflectance of matallic coatings:effect of aluminum flake orientation[J]. Journal of Coatings Technology,2002, 932(74):55-63.
[57]付义平.铝粉颜料的制备及其改性研究[D].江苏南京：南京理工大学,2005.
[58]金晓鸿.防腐涂料和涂装技术(Ⅲ)[J].材料开发与应用,2001,16(3)：42-46.
[59]王锡春.高装饰性金属色汽车面漆涂装工艺[J].涂料工业,2004,34(8)：41-50.
[60]付义平,李凤生,付廷明.闪光铝粉颜料的制备研究[J].轻合金加工技术,2005,(33)：3.
[61]钱伯容.非浮型铝粉及珠光颜料在闪光漆中的应用[J].现代涂料与涂装,1998,(3)：30-35.
[62]郑水林.粉体表面改性[M].北京：中国建材工业出版社,1995.
[63]朱骥良,吴申年.颜料工艺学[M].北京：化学工业出版社,2002.
[64]吴和元.闪光铝颜料球磨工艺的研究[J].湖南冶金,1998,(1)：11-14.
[65]李会莉,陈岁元,刘常升.球磨法制备微细A1片的研究[J].有色矿冶,2001,17(6)：39-42.
[66]袁诚,何煜.振动磨法制备金属颜料[J].涂料工业,1999,(3)：18-20.
[67]陈振兴.特种粉体[M].北京：化学工业出版社,2004.
[68]Wheeler I. Metallic pigments in polymers[M]. London:Rapra Technology Limited,1999.
[69]Pertays KM, Thompson GE, Alexander MR. Self-assembly of stearic acid on aluminium:the importance of oxide surface chemistry [J]. Surf Interface Anal, 2004,41(36):1361-1366.
[70]Wolfgang G, Lothar B. Water-dispersible aluminium pastes[P]. United States, US3970577,1976-07-20.
[71]Gunter S, Colin A. Metal pigment dispersions, process for the production thereof and use thereof[P]. United States, US5849072,1998-12-15.
[72]Ferguson RL. Lamellar pigment particle dispersion[P]. United States, US6177486,2001-01-23.
[73]付义平,李凤生,付廷明.闪光铝粉颜料的制备研究[J].轻合金加工技术,2005,33(7)：33-36.
[74]周毅,贾延刚.铝粉化学着色初探[J].阴山学刊,1995,13(2)：30-33.
[75]Wolfgang R. Oxidized colored aluminium pigments, process for their production and their use[P]. United States, US5964936,1999-10-12.
[76]Frieser RG, Station N. Gold colored metallic pigments[P]. United States, US 3067052,1962-12-04.
[77]Keemer C, Jenkins WG, Lamborn TH. Water resistant metal pigment particles[P]. United States, US5215579,1991-08-21.
[78]Tetsufumi K, Toshiaki B, Takashi M. Aluminum pigment composition[P]. United States, US 4869754,1989-11-26.
[79]Tom K. Inhibitive treatment for aluminum pigments[P]. United States, US4808231,1989-02-28.
[80]Kondis T. Aluminum particles resistant to reaction with water[P]. United States, US 4693754,1987-11-15.
[81]Oppen D, Lampatzer K. Chromium-free surface treatment[P]. United States, US4264378,1981-04-28.
[82]Hashizume R, Yoshiki W. Colored aluminium pigments and the preparation process thereof[P]. United States, US5944886,1999-08-31.
[83]Yamamoto T, Uenishi M, Katoh H. Aluminum pigments[P]. United States, US5494512,1996-02-27.
[84]Jenkins WG, Lamborn KC, Taylor H. Aqueous resistant metal pigment-containing paste and method for making [P]. United States, US5356469, 1994-02-19.
[85]Keemer CB, Taylor H. Inhibited metal pigment pastes containing molybdate pigments and suitable for aqueous coating compositions [P]. United States, US5993523,1999-10-30.
[86]Cape R, Thomas W. Process and composition for sealing a conversion coated surface with a solution containing vanadium[P]. United States, US4828615, 1989-05-09.
[87]Souma T, Ishidoya M. Chromatic-color metal flake pigment and colored composition compounded therewith[P]. United States, US5091010,1992-02-25.
[88]Wolfgang R, Sommer G Synthetic resin-coated metal pigment, process for the production thereof and use thereof[P]. United States, US 5332767,1994-07-26.
[89]Eiji U, Koushiro K. Flaky pigments coated with a coupling agent and a perfluoroalkyl phosphate[P]. United States, US7160374,2007-01-09.
[90]Uchiyama T, Hasegawa M. Process for preparing colored aluminum powder[P]. United States, US 4158074,1979-06-12.
[91]Garrigues PN, Dabosi F. An investigation of the corrosion inhibition of pure aluminum in neutral and acidic chloride solution[J]. Electrochimica Actra,1996, (41):1209.
[92]Szunerits S. Aluminum surface corrosion and the mechanism of inhibitors using pH and metal ion selective imaging fiber bundles[J]. Anal Chem,2002, (74):9.
[93]Huerta-Vilca D, Sandra R. Role of a chelating agent in the formation of polyaniline films on aluminum[J]. J Appl Polym Sci,2003,19(90):819-823.
[94]Das M, Mahiuddin S. Kinetics and adsorption behaviour of benzoate and phthalate at the a-alumina-water interface:Influence of functionality[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2005,27(264):90-100.
[95]Kummert R. The surface complexation of organic acids on hydrous-Al2O3[J]. J Colloid Interface Sci,1980, (75):13.
[96]Hidber PC, Gauckler LJ. Influence of the dispersant structure on properties of electrostatically stabilized aqueous alumina suspensions[J]. J Eur Ceram Soc, 1997,(17):11.
[97]Muller B. Corrosion inhibition of different metal pigments in aqueous alkaline media[J]. Corrosion Science,2001,43(6):1155-1164.
[98]Muller B, Kubitzki G, Kinet G Aromatic 2-Hydroxy-Oximes as corrosion inhibitors for aluminium and zinc pigments[J]. Corrosion Science,1998, 40(9):1469-1476.
[99]Muller B. Amino and polyamino acids as corrosion inhibitors for aluminum and zinc pigments[J]. Pigment & Resin Technology,2002, (31):4.
[100]Muller B. Corrosion inhibition of aluminium and zinc pigments by saccharides[J]. Corrosion Science,2002,44(7):1583-1591.
[101]Muller B, Kubitzki G, Kinet G. Citric acid as corrosion inhibitor for aluminium pigmen[J]. Corrosion Science,2004,46(1):159-167.
[102]Muller B, Shahid M, Kinet G Nitro-and aminophenols as corrosion inhibitors for aluminium and zinc pigments[J]. Corrosion Science,1999, 41(7):1323-1331.
[103]Wolfgang R, Guenter S. Synthetic resin-coated metal pigment, process for the production thereof and use thereof[P]. United States, US5332767,1994-07-24.
[104]Klaus G, Alfried K. Effect pigments coated with reactive orientation aids[P]. United States, US6761762,2004-07-13.
[105]Keemer CB, Jenkins WG Colored metallic pigments [P]. United States, US5558705 1996-12-24.
[106]潘卓,赵振声,何华辉.低红外发射率材料的研究[J].华中科技大学学报,2003,31(7)：28-30.
[107]Raimund S, Norbert M. Multiply coated metallic luster pigments[P]. United States, US5624486,1997-04-29.
[108]Bujard P, Rebbergweg O. Flake-form pigments based on aluminum coated with SiOz[P]. Canada, WO 2004/052999 A2,2004-06-24.
[109]Kaupp G, Neuhaus Q. Corrosion-stable aluminum pigments and process for the production thereof[P]. United States, US 6287695 B1,1997-07-08.
[110]Sato ST, Ryoji P. Fe2O3 particles coated with silica using TEOS[J]. Bulletin of the Chemical Society of Japan,2003, (1):7.
[111]Giinter S. Nacreous pigment and method for the manufacture thereof[P]. United States, US7217318,2007-05-15.
[112]Ostertag W, Gruenstadt F. Metal oxide coated aluminum pigments[P]. United States, US 4978394,1990-12-18.
[113]Werner O, Knut B, Gustav B. Preparation of metallic pigments having a metallic luster[P]. United States, US 4328042,1982-05-04.
[114]Armanini T, Louis W. Metal oxide platelets as nacreous pigments[P]. United States, US4192691,1980-03-11.
[115]Gale R, Jeannine M. Pearlescent pigments exhibiting color travel[P]. United States, US6165260,2000-12-20.
[116]Deluca JR. Interference pigments [P]. United States US6485556 2002-12-26.
[117]Rozumek ME. Pigments having a viewing angle dependent shift of color, method for producing said pigments, use of said pigments in security applications, coating composition comprising said pigments and a detecting device[P]. United States, US6695905,2004-02-24.
[118]Fu WY, Yang HB, Chang LX. Preparation and characteristics of core-shell structure nickel/silica nanoparticles[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2005,262:6.
[119]Mine E, Yamad A, Kobayashi Y. Direct coating of gold nanoparticles with silica by a seeded polymerization technique[J]. Journal of Colloid and Interface Science,2003,264(2):385-390.
[120]Li BY, Nobuaki N, Katsuhisa N. Highly anti-corrosive metal pigments[P]. United States, US7419538,2008-09-02.
[121]Kiehl A, Greiwe K. Encapsulated aluminium pigments[J]. Progress in Organic Coatings,1999,37:179-183.
[122]Supplit R, Schubert U. Corrosion protection of aluminum pigments by sol-gel coatings[J]. Corrosion Science,2007,49(8):3325-3332.
[123]Li LJ, Wen XF. Optimization of sol-gel coatings on the surface of aluminum pigments for corrosion protection[J]. Corrosion Science,2008,50:9.
[124]Batzar K, Piscataway R. Preparation of dense silica-encapsulated aluminum flake pigment treated with a carboxylic chromic chloride[P]. United States, US3954496,1976-05-04.
[125]Nadkarni SK, Mass L. Coloring aluminum flakes[P]. United States, US 5261955,1993-10-16.
[126]刘海峰,彭同江,孙红娟.α-Fe2O3-Mica纳米薄膜的制备[J].传感技术学报,2007,20(4)：755-759.
[127]侯文祥,付谭.古铜色珠光颜料的制备及动力学研究[J].硅酸盐学报,2003,(2)：81-85.
[128]侯文祥,谭俊茹,陈秀增.彩色云母系珠光颜料的制备机理研究及性能表征[J].现代涂料与涂装,2000,(2)：3-6.
[129]陈秀增,侯文祥,谭俊茹.虹彩型云母钛珠光颜料的制备与表征[J].化学工业与工程,1997,14(4)：1-5.
[130]谭俊茹,侯文祥,陈秀增.双包覆层Cr2O3/TiO2/MiCa彩色珠光颜料的制备机理及表征[J].现代涂料与涂装,1999,(1)：11-15.
[131]Rieger CJ. Exterior grade titanium dioxide coated mica [P]. United States US4134776,1979-01-16.
[132]Djur B, Mcgarry D, Pickering S. The preparation of ultra fine ceria-stabilized zircons particle coated with yttrium[J]. Ater Sci Lett,1993,23(12):1320-1323.
[133]孙家跃,郭萌萌,杜海燕.氧化钕改性云母钛光干涉颜料的制备及表征[J]. 硅酸盐学报,2006,25(6)：5-9.
[134]沈腊珍,谭俊茹,付贤松.纳米(1-x)SnO2.xSb2O3复合云母钛导电珠光颜料的制备[J].硅酸盐学报,2004,(4)：36-39.
[135]张德文,孙淑清.彩虹型云母钛珠光颜料的制备[J].石油化工高等学校学报,1999,(2)：42-44.
[136]刘永峙,韩爱军,叶明泉.均匀沉淀法制备Al/ZnS复合粒子[J].化工进展,2004,23(9)：990-992.
[137]李校远.片状铝粉和金属氧化物复合粒子的制备研究[D].南京：南京理工大学,2003.
[138]Glebov YL, Krishtopa LG, Usov OM. Coating of metal powders with polymers in supercritical carbon dioxide[J]. Ind Eng Chem Res,,2001,40:11.
[139]Miiller B. Polymeric corrosion inhibitors for aluminium pigment[J]. Reactive & Functional Polymers,1999,39(4):165-177.
[140]Liu H, Ye HQ, Zhang YC. Preparation and characterization of PMMA/flaky aluminum composite particle in the presence of MPS[J]. Colloids and Surfaces A:Physicochem Eng Aspects,2008,315(1):1-6.
[141]Liu H, Ye HQ, Tang XD. Aluminum pigment encapsulated by in situ copolymerization[J]. Applied Surface Science,2007,2545.
[142]Liu H, Ye HQ, Zhang YC. Synthesis and property of poly(trimethylolpropane triacrylate)/Al nanocomposite particle by in situ solution polymerization[J]. Applied Surface Science,2008,254(15):4432-4438.
[143]Batzilla TH. Preparation of Encapsulated Aluminum Pigments by Emulsion Polymerization and their Characterization[J]. J Coat Technol,1998,70:7.
[144]Kimura TY, Yoshii H, Tanaka M. Encapsulation of aluminum flakes by dispersion polymerization of styrene in a nonaqueous system with reactive surfactants[J]. J Appl Polym Sci,2001,81(3):9.
[145]Kern GM. Resin compositions containing metals such as aluminum[P]. United States, US4544600,1985-10-01.
[146]何国兴.颜色科学[M].上海：东华大学出版社,2004.
[147]顺青.色度学[M].北京：北京理工大学出版社,1990.
[148]宋加金,刘长维,陈红军.耐腐蚀环氧粉末涂料的改性研究[J].热固性树脂,2007,(4).
[149]薛俊国.金、银与SiO2和α-Fe2O3复合纳米颗粒的制备[D].长春：东北师范大学,2007.
[150]Xu J, Carole C. A novel approach to Au@SiO2 core-shell spheres[J]. Journal of Non-Crystalline Solids,2007,353(5):1212-1215.
[151]袁俊杰.有机颜料的表面纳米包覆改性及其在涂料中的应用研究[D].上海：复旦大学,2006.
[152]Liu P, Su ZX. Preparation of polystyrene silica nanoparticles by two-steps UV induced reaction[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2004,167(2-3):237-240.
[153]Liu P. Hyperbranched aliphatic polyester grafted attapulgite via a melt polycondensation process[J]. Applied Clay Science,2007,35(1-2):11-16.
[154]任俊.颗粒分散科学与技术[M].北京：化学工业出版社,2005.
[155]Mine E, Yamada A, Kobayashi Y. Direct coating of gold nanoparticles with silica by a seeded polymerization technique[J]. J Colloid Interface Sci,2003, 264(2):385-390.
[156]Cheng B, Zhao L, Yu J. Facile fabrication of SiO2/Al2O3 composite microspheres with a simple electrostatic attraction strategy[J]. Materials Research Bulletin,2008,43(3-4):714-722.
[157]张昭.无机精细化工工艺学[M].北京：化学工业出版社,2009.
[158]Veeramasuneni S, Yalamanchili MR, Miller JD. Use of atomic force microscopy in particle science and technology research [J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,1998,133(5):77-88.
[159]Kavitha SY, Costas T. Copper uptake by inorganic particles-equilibrium, kinetics, and particle interactions:experimental [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2000,177(2):14.
[160]Wendon GW. Aluminium and bronze flake powders[M]. Ayr:Electrochemical publications limited,1983.
[161]戚栋明.聚丙烯酸酯/纳米SiO2复合粒子的原位(细)乳液聚合法制备及其应用[D].杭州：浙江大学,2006.
[162]秦宗会,谭蓉.用刚果红分光光度法测定阳离子表面活性剂[J].分析测度学报,2007,26(1)：113-116.
[163]秦宗会,胡武洪.刚果红-溴化十六烷基吡啶光度法测定阴离子表面活性剂[J].化学研究与应用,2008,20(7)：879-882.
[164]曲岩涛,李继山,王宗礼.CTAB改变固体表面润湿性的机理探讨[J].大庆石油地质与开发,2006,25(2)：52-53.
[165]Sanchez-Martim MJ, Dorado MC, Hoyo Cd. Influence of clay mineral structure and surfactant nature on the adsorption capacity of surfactants by clays[J]. Journal of Hazardous Materials,2008, (150):115-123.
[166]Marsalek R, Pospisil J, Taraba B. The influence of temperature on the adsorption of CTAB on coals[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2011,383:80-85.
[167]Giirsesa A, Karacab S, Acikyildiz M. Thermodynamics and mechanism of cetyltrimethylammonium adsorption onto clayey soil from aqueous solutions [J]. Chemical Engineering Journal,2009,147:194-201.
[168]朱友益,韩冬,沈平平.表面活性剂结构与性能的关系[D].北京：石油工业出版社,2003.
[169]胡鸣.铁氧化物与普鲁士蓝类化合物的形貌可控合成与非经典结晶机理研究[D].上海：华东师范大学,2010.