具有MFI结构分子筛的可控生长
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摘要
MFI型分子筛具有独特的孔道结构和容易调变的骨架组成,在多相酸催化和氧化反应中表现出优异的择形催化能力,被广泛应用于石油炼制与精细化工等领域。本论文在MFI结构分子筛的合成中,使用胶态晶种控制分子筛的形貌与多级孔结构,有利于在催化应用过程中建立良好的构效关系;并从减少含氮废水排放、简化合成步骤和降低生产成本和能耗等多个角度,研究胶态晶种在MFI型分子筛合成过程中的作用。
     论文第一部分研究了具有多级孔道结构的纳米ZSM-5沸石聚集体的合成。首先以硅溶胶为硅源,四丙基氢氧化铵做模板剂制备了胶态TPA-silicalite-1,并采用该胶态TPA-silicalite-1作为晶种一步制备具有多级孔结构的纳米ZSM-5聚集体。其中有机模板剂的使用量减少至TPA/SiO2仅为0.005,而所制备纳米ZSM-5球形聚集体的尺寸在2μm左右,还拥有高达0.2cm3g-1的介孔体积。讨论胶态晶种的用量、合成体系的SiO2/Al2O3比、Na2O/SiO2比等对该合成过程以及产物性质的影响。通过对晶化过程中硅铝凝胶的形貌、结构以及硅铝配位状态的变化研究,探讨了纳米ZSM-5聚集体的形成机制。
     常规ZSM-5沸石的合成过程中大多使用碱金属的氢氧化物作为碱源,而碱金属离子会留在产物中以平衡骨架中铝氧四面体的负电荷。在酸催化反应前必须使用酸溶液或铵盐溶液对分子筛进行交换,以除去其中的碱金属离子;若使用有机模板剂合成分子筛,通常在交换前还需要焙烧除去有机模板剂,这样使得制备工艺相当复杂。从减少合成步骤、降低合成成本的目的出发,我们在第二部分中研究了氨水体系中以胶态silicalite-1做晶种合成小晶粒NH4-ZSM-5沸石。考察了硅源、SiO2/Al2O3比、晶种的用量以及氨水的用量对分子筛合成及其结构性质的影响。该方法制备的小晶粒NH4-ZSM-5沸石可通过简单焙烧直接转化成具有酸性的HZSM-5沸石,其物理化学性质与常规方法制备的HZSM-5沸石类似。
     在第三部分中,以胶态Silicalite-1作为晶种,添加少量四丙基溴化铵或四乙基溴化铵做辅助模板剂,合成了SiO2/Al2O3高于100的ZSM-5沸石。其中改变胶态晶种的用量即可简单地调变高硅ZSM-5的晶粒尺寸在儿十纳米到数微米之间。此外,不同硅源制备的胶态晶种以及不同辅助模板剂对沸石晶粒的形貌也有明显的影响。
     在第四部分中,添加相同量的胶态晶种,使用四乙基溴化铵为辅助模板剂合成了一系列具有相似形貌和晶粒尺寸但SiO2/Al2O3比不同的ZSM-5沸石,并对其形貌、晶粒尺寸、酸性质及水热稳定性等进行了表征。将这些ZSM-5沸石与磷酸铝载体等组分通过喷雾成型制得微球催化剂,考察其作为助剂在催化裂化过程中提高丙烯产率中的作用。加入含ZSM-5沸石的助剂均可以提高丙烯的收率和改善汽油的辛烷值。由于分子筛的形貌和晶粒尺寸非常相似,主要考察硅铝比对丙烯收率的影响。随着助剂中ZSM-5沸石SiO2/Al2O3比的提高,丙烯收率呈现先升高后下降的趋势。
     论文的最后一部分通过加入胶态silicalite-1作为晶种,采用廉价的氨水和其它有机碱替代价格昂贵的四丙基氢氧化铵(TPAOH)合成了TS-1分子筛,可明显降低TPAOH的使用量。考察了投料顺序、晶种使用量、SiO2/TiO2比、有机胺、有机二胺或者氨水的种类及用量对合成的影响。并以正已烯的环氧化反应作为探针反应考察了所合成的TS-1分子筛的催化氧化性能。此外还尝试了使用Ti(SO4)2代替TBOT作钛源合成TS-1分子筛,期待以一种更为廉价的合成路线得到具有-定活性的TS-1分子筛。
Zeolites with MFI topology possess excellent shape-selectivity due to its special pore structure. The diversity of framework atoms makes it good acidic or oxidative catalysts, widely used in fields of petroleum refining and fine chemicals. In this dissertation, colloidal seeds were used for the synthesis of MFI zeolites with controllable morphology and hierarchical porosity, which may be benefit to better understanding of the structure-activity relationship. In order to reduce N-containing wastewater, simplify synthesis procedure and reduce production costs and energy consumption during the synthesis of MFI zeolites, the role of colloidal seeds was studied.
     Firstly, synthesis of nanocrystalline ZSM-5aggregates with hierarchical porosity was investigated. Colloidal TPA-silicalite-1was firstly prepared using colloidal silica as silica source and TPAOH as template. Using this colloidal TPA-silicalite-1as seeds, nanocrystalline ZSM-5aggregates with hierarchical porosity were synthesized. TPA+/SiO2ratio can be reduced to as low as0.005while the as-prepared ZSM-5aggregates were in size of about2μm, possessing mesopore volume as large as0.2cm3g-1. The influence of seeding amount, batch SiO2/Al2O3ratio and Na2O/SiO2ratio was discussed. By tracking the structure and morphology changes during crystallization, new insight into the formation mechanism of the ZSM-5aggregates was obtained.
     In general, as-synthesized ZSM-5usually contains Na+for the compensation of the negative charge of the tetrahedral aluminum, which should be transformed to the H-form before being used as acid catalyst. In the second part, we focused on the one-step synthesis of nano-sized NH4-ZSM-5using colloidal silicalite-1as seeds. The influence of SiO2/AlO3ratio, the amount of seeding suspension and ammonia was investigated. Crystal sizes ranging from~200nm to~1μm could be controlled by simply adjusting the amount of seeding suspension. The as-prepared NH4-ZSM-5could be directly transformed to the H-form ZSM-5by a simple calcination. Compared to the conventional method, this process was fast and facile and possessed considerable potential for the large-scaled production.
     In the third part, the morphological control of the ZSM-5zeolites with high SiO2/Al2O3ratios was studied. Using colloidal silicalite-1as seeds and a small amount of TPABr or TEABr as auxiliary template, we synthesized highly crystallized ZSM-5zeolites with SiO2/Al2O3ratios higher than100. Crystal size of the synthesized ZSM-5could be controlled in the range of tens of nanometers and several micrometers by varying the seeding amount. Colloidal silicalite-1prepared from different silica sources also influenced the crystal sizes.
     ZSM-5with similar morphology and size but different SiO2/Al2O3ratios was synthesized with above method. The synthesized ZSM-5was transformed to the H-form and mixed with aluminum phosphate matrix to prepare microspheric catalysts via spray drying. The influence of the ZSM-5-containing additive for maximizing propylene in the FCC process was investigated. The yield of propylene and the octane number of the gasoline increased with the addition of ZSM-5additive. Influence of SiO2/AlO3ratio on the propylene yield was stressed, as the zeolite ZSM-5used was similar in morphology and size. With the increase of SiO2/AlO3ratio, the yield of propylene first increased and then decreased.
     The last part focused on the cost effective synthesis of zeolite TS-1. In this part, colloidal silicalite-1was used as seed for the synthesis of TS-1, largely reducing the amount of expensive template, TPAOH. The influence of feeding sequence, seeding amount, the species and the amount of amines or ammonia was investigated. Epoxidation of1-hexene was used as probe reaction to evaluate the catalytic performance of the synthesized TS-1. Besides, inorganic Ti(SO4)2was used as titanium source instead of organic TBOT, in order to further reduce the synthetic cost.
引文
[1]D. W. Breck, Zeolite molecular sieves:Structure, Chemistry, and Use, Wiley in New York,1973.
    [2]J.V. Smith, Zeolites,4 (1984) 309.
    [3]A.F. Cronstedt, Kong. Vet. Acad. Handlingar 17 (1756) 120.
    [4]C. Colella and A.F. Gualtieri, Microporous Mesoporous Mater.,105 (2007) 213.
    [5]F. Grandjean, Compt. Rend.149 (1910) 866.
    [6]J. W. McBain, The Sorption of Gases and Vapors by Solids, Rutledge and Sons, London,1932.
    [7]B. K. Marcus and W. E. Cormier, Chem. Eng. Prog.,95 (1999) 47.
    [8]Zeolites and Catalysis, Wiley-VCH Verlag GmbH & Co. KGaA,2010, p. I.
    [9]R.Thompson, Vol.1, Springer Berlin/Heidelberg,1998, p.1.
    [10]徐如人,庞文琴,屠昆岗等,沸石分子筛的结构与合成,吉林大学出版社,吉林,1 987.
    [11]L.B. McCusker and C. Baerlocher, in H.v.B.A.C. Jiri Cejka and S. Ferdi (Editors), Stud. Surf. Sci. Catal., Vol. Volume 168, Elsevier,2007, p.13.
    [12]C. Baerlocher, L. B. McCusker, http://www.iza-structure.org/databases
    [13]W. Vermeiren and J.P. Gilson, Top. Catal.,52 (2009) 1131.
    [14]G.T. Kokotailo, S.L. Lawton, D.H. Olson and W.M. Meier, Nature,272 (1978) 437.
    [15]D.H. Olson, G.T. Kokotailo, S.L. Lawton and W.M. Meier, J. Phys. Chem.,85 (1981)2238.
    [16]Grose R W, Flanigen E M, US Patent 4061724,1979.
    [17]J.I. Villegas, N. Kumar, T. Heikkila, V.P. Lehto, T. Salmi and D.Y. Murzin, Chem. Eng. J.,120(2006)83.
    [18]P. Canizares, A. De Lucas, J. L. Valverde and F. Dorado, Ind. Eng. Chem. Res., 36(1997)4797.
    [19]R. Roldan, F.J. Romero, C. Jimenez-Sanchidrian, J.M. Marinas and J.P. Gomez, Appl. Catal., A,288(2005) 104.
    [20]A. Soualah, J.L. Lemberton, L. Pinard, M. Chater, P. Magnoux and K. Moljord, Appl. Catal., A,336 (2008) 23.
    [21]J.A. Martens, R. Ravishankar, I.E. Mishin and P.A. Jacobs, Angew. Chem. Int. Ed.,39 (2000) 4376.
    [22]M. Yamamura, K. Chaki, T. Wakatsuki, H. Okado and K. Fujimoto, Zeolites,14 (1994)643.
    . [23] A. Corma, US Pat.6709572 B2, (2004).
    [24]Y. Fujiyama, M.H. Al-Tayyar, C.F. Dean, A. Aitani and H.H. Redhwi, in M.L. Ocelli (Editor), Stud. Surf. Sci. Catal., Vol. Volume 166, Elsevier,2007, p.1.
    [25]X. Zhu, S. Liu, Y. Song, S. Xie and L. Xu, Appl. Catal., A,290 (2005) 191.
    [26]A. Corma, V. Martinez-Soria and E. Schnoeveld, J. Catal.,192 (2000) 163.
    [27]J. M. Serra, A. Corma, E Guillon, US Pat.7419931 B2,(2008).
    [28]A. Corma, J M Serra, V Fornes and R Castaneda, US Pat.2008/0021253 Al, (2008).
    [29]V. Kanazirev, G.L. Price and K..M. Dooley, J. Chem. Soc, Chem. Commun., (1990)712.
    [30]V.R. Choudhary, A.K. Kinage and T.V. Choudhary, Chem. Commun., (1996) 2545.
    [31]Y. Ono, Cat. Rev.,34 (1992) 179.
    [32]G. Sirokman, Y. Sendoda and Y. Ono, Zeolites,6 (1986) 299.
    [33]D.B. Lukyanov and T. Vazhnova, Appl. Catal., A,316 (2007) 61.
    [34]E.G. Derouane, P. Dejaifve, Z. Gabelica and J.C. Vedrine, Faraday Discuss. Chem. Soc,72(1981)331.
    [35]Z. da Silva Barros, F. Maria Zanon Zotin and C. Assumpcao Henriques, in M.S. Fabio Bellot Noronha and S.-A. Eduardo Falabella (Editors), Stud. Surf. Sci. Catal., Vol. Volume 167, Elsevier,2007, p.255.
    [36]M. Taramasso, S. D. Milanese, US Pat.4410501, (1983).
    [37]B. Notari, in R.K. Grasselli and A.W. Sleight (Editors), Stud. Surf. Sci. Catal., Vol. Volume 67, Elsevier,1991, p.243.
    [38]B. Notari, in W.J.M.E.F.V. P.J. Grobet and G. Schulz-Ekloff (Editors), Stud. Surf. Sci. Catal., Vol. Volume 37, Elsevier,1988, p.413.
    [39]A. Esposito, M. Taramasso, C Neri, F Buonomo, UK Patent 2116974.
    [40]A.J.H.P. van der Pol, A.J. Verduyn and J.H.C. van Hooff, Appl. Catal., A,92 (1992)113.
    [41]C. Neri, B. Anfossi, F. Buonomo, Euro Pat.100118, (1984).
    [42]C.Neri, A. Esposito, B. Anfossi, F. Buonomo, Euro Pat.100119,(1984).
    [43]T. Tatsumi, M. Nakamura, S. Negishi and H.-o. Tominaga, J. Chem. Soc, Chem. Commun., (1990)476.
    [44]F. Maspero, U. Romano, Patent Pend.
    [45]A. Esposito, C.Neri, F Buonomo, US Pat.t 4480135, (1984).
    [46]A.F. Masters and T. Maschmeyer, Microporous Mesoporous Mater.,142 (2011) 423.
    [47]C.S. Cundy and P.A. Cox, Microporous Mesoporous Mater.,82 (2005) 1.
    [48]G.T. Kerr, J. Phys. Chem.,70 (1966) 1047.
    [49]G.T. Kerr, J. Phys. Chem.,72 (1968) 1385.
    [50]E. Narita, K. Sato, N. Yatabe and T. Okabe, Ind. Eng. Chem. Prod. Res. Dev.,24 (1985)507.
    [51]E. Narita, J. Cryst. Growth,78 (1986) 1.
    [52]Mirskii YaV, Pirozhkov V V, Russ J Phys Chem,44, (1970),1508.
    [53]J. Warzywoda and R.W.Thompson, Zeolites,11 (1991)577.
    [54]徐如人,庞文琴,无机合成与制备化学,高等教育出版社,北京,2001
    [55]V. Valtchev, J.L. Paillaud, H. Kessler and E.J. Creyghton, Microporous Mesoporous Mater.,33 (1999) 143.
    [56]Z. Wu, J. Song, Y. Ji, L. Ren and F.-S. Xiao, Chem. Mater.,20 (2007) 357.
    [57]H. Pan, Q. Pan, Y. Zhao, Y. Luo, X. Shu and M. He, Ind. Eng. Chem. Res.,49 (2010)7294.
    [58]熊晓云,范峰滔,马军等,高等学校化学学报,28,(2007),21.
    [59]耿晨晨,马波,秦波,张喜文,石油炼制与化工,42,(2011),77.
    [60]陈媛媛,马波,张志智等,工业催化,18,(2010),28.
    [61]C. V. McDaniel, US pat.738116, (1968).
    [62]N.N. Feoktistova and L.M. Vtyurina, Russ. Chem. Bull.,43 (1994) 740.
    [63]C. V. McDaniel, P. K. Maher, J. M. Pilato, US Pat.4166099, (1979).
    [64]徐如人,张建民,高等学校化学学报,3,(1982),287.
    [65]M.T. Melchior, D.E.W. Vaughan and C.F. Pictroski, J. Phys. Chem.,99 (1995) 6128.
    [66]A. Thangaraj and R. Kumar, Zeolites,10 (1990) 117.
    [67]G. Xiong, Y. Yu, Z.-c. Feng, Q. Xin, F.-S. Xiao and C. Li, Microporous Mesoporous Mater.,42 (2001) 317.
    [68]胡汉祥,施其宏,南吕大学学报(工科版),20,(1998),80.
    [69]刘兴玉,谢传欣,赵静等,石油大学学报(自然科学版),28,(2004),1 03.
    [70]V. J. Frilette G. T. Kerr, US Pat.3071434, (1963).
    [71]G. T. Kerr, US Pat.3228969, (1966).
    [72]C.-H. Chi and L.B. Sand, Nature,304 (1983) 255.
    [73]D. E. W. Vaughan, G. C. Edwards, US Pat.3966883, (1976).
    [74]徐文旸,李文渊,曹景慧等,太原工业大学学报,4,(1984),21-30.
    [75]M. Shibata, J. Gerard and Z. Gabelica, Microporous Mater.,12 (1997) 141.
    [76]H. Kacirek and H. Lechert, J. Phys. Chem.,79 (1975) 1589.
    [77]王清遐,蔡光宇,李时瑶等,催化学报,7,(1986),54.
    [78]S. Ueda and M. Koizumi, American Mineralogist,64 (1979) 172.
    [79]X. Wang, X. Zhang, Y. Wang, H. Liu, J. Qiu, J. Wang, W. Han and K.L. Yeung, Chem. Mater.,23 (2011) 4469.
    [80]M.E. Davis and R.F. Lobo, Chem. Mater.,4 (1992) 756.
    [81]C.S. Cundy and P.A. Cox, Chem. Rev.,103 (2003) 663.
    [82]H. Zhang, Y. Liu, Z. Jiao, M. He and P. Wu, Ind. Eng. Chem. Res.,48 (2009) 4334.
    [83]Y. Zuo, X. Wang and X. Guo, Ind. Eng. Chem. Res.,50 (2011) 8485.
    [84]L. Chen, Y.M. Wang and M.-Y. He, Mater. Res. Bull.,46 (2011) 698.
    [85]周朋燕,李晓峰,王裕鑫等,石油学报(石油加工),24(B10),(2008),226.
    [86]J. P. McWilliams, M. K. Rubin, US Pat.4894212, (1987).
    [87]A. Moini, E. W. Valyocsik, US Pat.5192521, (1991).
    [88]G. Majano, L. Delmotte, V. Valtchev and S. Mintova, Chem. Mater.,21 (2009) 4184.
    [89]S. I. Zones, D. L. Holtermann, R. A. Innes, US Pat.5200377, (1992).
    [90]Y. Nakagawa, S. I. Zones, US Pat.5707600, (1996).
    [91]Y. Nakagawa, US Pat.5316753, (1992).
    [92]李赫咺,项寿鹤,吴德明等,高等学校化学学报,2,1981,517.
    [93]王福生,程文才,张式,催化学报,2,1981,282.
    [94]S.B. Kulkarni, V.P. Shiralkar, A.N. Kotasthanc, R.B. Borade and P. Ratnasamy, Zeolites,2(1982)313.
    [95]A.N. Kotasthane, V.P. Shiralkar, S.G. Hegde and S.B. Kulkarni, Zeolites,6 (1986) 253.
    [96]Z. Gabelica, M. Cavez-Bierman, P. Bodart, A. Gourgue and J.B. Nagy, in S.H. B. Drzaj and S. Pejovnik (Editors), Stud. Surf. Sci. Catal., Vol. Volume 24, Elsevier, 1985, p.55.
    [97]王清遐,蔡光宇,周智远等,催化学报,3,1982,284.
    [98]H. Kalipcilar and A. Culfaz, Cryst. Res. Technol.,36 (2001) 1197.
    [99]V.P. Shiralkar and A. Clearfield, Zeolites,9 (1989) 363.
    [100]傅聪忍,张芷,崔欣欣等,燃料化学学报,2,(1993),8.
    [101]高敏,刘春燕,王刃等,化学通报,72,(2009),1097.
    [102]S. Ernst, P.A. Jacobs, J.A. Martens and J. Weitkamp, Zeolites,7 (1987) 458.
    [103]B.H. Chiche, R. Dutartre, F. Renzo, F. Fajula, A. Katovic, A. Regina and G. Giordano, Catal. Lett.,31 (1995) 359.
    [104]S. Ritsch, N. Ohnishi, T. Ohsuna, K. Hiraga, O. Terasaki, Y. Kubota and Y. Sugi, Chem. Mater.,10(1998)3958.
    [105]S. Gopal, K. Yoo and P.G. Smirniotis, Microporous Mesoporous Mater.,49 (2001) 149.
    [106]K. Yoo, R. Kashfi, S. Gopal, P.G. Smirniotis, M. Gangoda and R.N. Bose, Microporous Mesoporous Mater.,60 (2003) 57.
    [107]K. Iyoki, Y. Kamimura, K. Itabashi, A. Shimojima and T. Okubo, Chem. Lett., 39(2010)730.
    [108]Y. Kamimura, K. Itabashi and T. Okubo, Microporous Mesoporous Mater.,147 (2012)149.
    [109]M.M.J. Treacy and J.M. Newsam, Nature,332 (1988) 249.
    [110]G. Bellussi, G. Pazzuconi, C. Perego, G. Girotti and G. Terzoni, J. Catal.,157 (1995)227.
    [111]B. Xie, J. Song, L. Ren, Y. Ji, J. Li and F.-S. Xiao, Chem. Mater.,20 (2008) 4533.
    [112]B. Xie, H. Zhang, C. Yang, S. Liu, L. Ren, L. Zhang, X. Meng, B. Yilmaz, U. Muller and F.-S. Xiao, Chem. Commun.,47 (2011) 3945.
    [113]Y. Kamimura, W. Chaikittisilp, K. Itabashi, A. Shimojima and T. Okubo, Chem. Asian J.,5 (2010)2182.
    [114]Y. Kamimura, S. Tanahashi, K. Itabashi, A. Sugawara, T. Wakihara, A. Shimojima and T. Okubo, J. Phys. Chem. C,115 (2011) 744.
    [115]L. Zhang, C. Yang, X. Meng, B. Xie, L. Wang, L. Ren, S. Ma and F.-S. Xiao, Chem. Mater.,22(2010)3099.
    [116]B.O. Hincapie, L.J. Garces, Q. Zhang, A. Sacco and S.L. Suib, Microporous Mesoporous Mater.,67 (2004) 19.
    [117]W. Zhang, Y. Wu, J. Gu, H. Zhou and J. Wang, Mater. Res. Bull.,46 (2011) 1451.
    [118]T. Yokoi, M. Yoshioka, H. Imai and T. Tatsumi, Angew. Chem. Int. Ed.,48 (2009)9884.
    [119]Z. Adem, F. Guenneau, M.-A. Springuel-Huet and A. Gedeon, Microporous Mesoporous Mater.,114 (2008) 337.
    [120]M. Firoozi, M. Baghalha, M.Asadi, Catal. Commun.,10(2009) 1582.
    [121]M. Sugimoto, H. Katsuno, K. Takatsu and N. Kawata, Zeolites,7 (1987) 503.
    [122]C.S. Triantafillidis, N.P. Evmiridis, L. Nalbandian and I.A. Vasalos, Ind. Eng. Chem. Res.,38(1999)916.
    [123]L. Bonetto, M.A. Camblor, A. Corma and J. Perez-Pariente, Appl. Catal., A,82 (1992)37.
    [124]A.G. Dixon and R.W. Thompson, Zeolites,6 (1986) 154.
    [125]J.E. Gilbert and A. Mosset, Mater. Res. Bull.,33 (1998) 997.
    [126]T. Sano, S. Wakabayashi, Y. Oumi and T. Uozumi, Microporous Mesoporous Mater.,46(2001)67.
    [127]J. Warzywoda, A.G. Dixon, R.W. Thompson, A. Sacco Jr and S.L. Suib, Zeolites, 16(1996) 125.
    [128]Y. Sun, T. Song, S. Qiu, W. Pang, J. Shen, D. Jiang and Y. Yue, Zeolites,15 (1995)745.
    [129]U. Diaz, V. Fornes and A. Corma, Microporous Mesoporous Mater.,90 (2006) 73.
    [130]C.S. Cundy, J.O. Forrest and R.J. Plaisted, Microporous Mesoporous Mater.,66 (2003)143.
    [131]S.D. Kim, S.H. Noh, J.W. Park and W.J. Kim, Microporous Mesoporous Mater., 92(2006) 181.
    [132]G. Reding, T. Maurer and B. Kraushaar-Czarnetzki, Microporous Mesoporous Mater.,57 (2003) 83.
    [133]G. Majano, A. Darwiche, S. Mintova and V. Valtchev, Ind. Eng. Chem. Res.,48 (2009) 7084.
    [134]N. Ren, Z.-J. Yang, X.-C. Lv, J. Shi, Y.-H. Zhang and Y. Tang, Microporous Mesoporous Mater.,131 (2010) 103.
    [135]N. Ren, J. Bronic, B. Subotic, X.-C. Lv, Z.-J. Yang and Y. Tang, Microporous Mesoporous Mater.,139(2011) 197.
    [136]N. Ren, J. Bronic, B. Subotic, Y.-M. Song, X.-C. Lv and Y. Tang, Microporous Mesoporous Mater.,147 (2012) 229.
    [137]Y. Liu, W. Zhang and T.J. Pinnavaia, J. Am. Chem. Soc.,122 (2000) 8791.
    [138]Y. Liu, W. Zhang and T.J. Pinnavaia, Angew. Chem. Int. Ed.,40 (2001) 1255.
    [139]Y. Liu and T.J. Pinnavaia, Chem. Mater.,14 (2002) 3.
    [140]S.A. Bagshaw, S. Jaenicke and C.G. Khuan, Catal. Commun.,4 (2003) 140.
    [141]Y. Xia and R. Mokaya, J. Mater. Chem.,14 (2004) 3427.
    [142]Y. Zhu, Z. Hua, J. Zhou, L. Wang, J. Zhao, Y. Gong, W. Wu, M. Ruan and J. Shi, Chem. Eur. J.,17(2011)14618.
    [143]D.P. Serrano, J. Aguado, J.M. Escola, J.M. Rodriguez and A. Peral, Chem. Mater.,18 (2006) 2462.
    [144]J. Aguado, D.P. Serrano and J.M. Rodriguez, Microporous Mesoporous Mater., 115(2008)504.
    [145]D.P. Serrano, J. Aguado, G. Morales, J.M. Rodriguez, A. Peral, M. Thommes, J.D. Epping and B.F. Chmelka, Chem. Mater.,21 (2009)641.
    [146]M. Hartmann, Angew. Chem. Int. Ed.,43 (2004) 5880.
    [147]P. B. Venuto, Microporous Materials,2 (1994) 297.
    [148]H. Yang, Z. Liu, H. Gao and Z. Xie, J. Mater. Chem.,20 (2010) 3227.
    [149]W. Souverijns, J.A. Martens, L. Uytterhoeven, G.F. Froment and P.A. Jacobs, in S.-K.I. Hakze Chon and U. Young Sun (Editors), Stud. Surf. Sci. Catal., Vol. Volume 105, Elsevier,1997, p.1285.
    [150]C.S. Cundy, B.M. Lowe and D.M. Sinclair, Faraday Discuss.,95 (1993) 235.
    [151]N.N. Feoktistova, S.P. Zhdanov, W. Lutz and M. Bullow, Zeolites,9 (1989) 136.
    [152]E.F. Freund, J. Cryst. Growth,34 (1976) 11.
    [153]S. Alfaro, C. Rodriguez, M.A. Valenzuela and P. Bosch, Mater. Lett.,61 (2007) 4655.
    [154]H. J. Koroglu, A. Sarioglan, M. Tatlier, A. Erdem-Senatalar and O.T. Savasci, J. Cryst. Growth,241 (2002) 481.
    [155]J.D. Cook and R.W. Thompson, Zeolites,8 (1988) 322.
    [156]S. Gontier and A. Tuel, Zeolites,16(1996) 184.
    [157]I. Guray, J. Warzywoda, N. Bac and A. Sacco Jr, Microporous Mesoporous Mater.,31 (1999)241.
    [158]R. Selvin, H.L. Hsu, L.S. Roselin and M. Bououdina, Synth. React. Inorg. Met.-Org. Nano-Metal Chem.,41 (2011) 1028.
    [159]M. A. Camblor, A. Mifsud and J. Perez-Pariente, Zeolites,11 (1991) 792.
    [160]A.J.H.P. van der Pol and J.H.C. van Hooff, Appl. Catal., A,92 (1992) 93.
    [161]M. Gharibeh, G.A. Tompsett, W.C. Conner and K.S. Yngvesson, ChemPhysChem,9 (2008) 2580.
    [162]R. Mostowicz and J.M. Berak, in S.H. B. Drzaj and S. Pejovnik (Editors), Stud. Surf. Sci. Catal., Vol. Volume 24, Elsevier,1985, p.65.
    [163]S.G. Fegan and B.M. Lowe, J. Chem. Soc., Faraday Trans.1,82 (1986) 785.
    [164]F. Di Renzo, F. Remoue, P. Massiani, F. Fajula, F. Figueras and C. Thierry Des, Zeolites,11 (1991)539.
    [165]V. N. Romannikov, V.M. Mastikhin, S. Hocevarand B. Drzaj, Zeolites,3 (1983) 311.
    [166]M.A. Camblor, J. Pe'rez-Pariente and V. Fornes, Zeolites,12 (1992) 280.
    [167]G. Giannetto, R. Monque, J. Perez, J. Papa and L. Garcia, Zeolites,13 (1993) 557.
    [168]M. Derewinski, F.D. Renzo, P. Espiau, F. Fajula and M.-A. Nicolle, in N.I.J.L.K. P.A. Jacobs and B. Wichterlov (Editors), Stud. Surf. Sci. Catal., Vol. Volume 69, Elsevier,1991, p.127.
    [169]J. Patarin, M. Soulard, H. Kessler, J.L. Guth and J. Baron, Zeolites,9 (1989) 397.
    [170]M. Choi, K. Na, J. Kim, Y. Sakamoto, O. Terasaki and R. Ryoo, Nature,461 (2009) 246.
    [171]Z. Shan, H. Wang, X. Meng, S. Liu, L. Wang, C. Wang, F. Li, J.P. Lewis and F.-S. Xiao, Chem. Commun.,47 (2011) 1048.
    [172]G. Bonilla, I. Diaz, M. Tsapatsis, H.-K. Jeong, Y. Lee and D.G. Vlachos, Chem. Mater.,16(2004)5697.
    [173]K. Na, M. Choi and R. Ryoo, J. Mater. Chem.,19 (2009) 6713.
    [174]L.Chen, S.Y. Zhu, Y.M. Wang and M.-Y. He, New J. Chem.,34(2010)2328.
    [175]T. O. Drews and M. Tsapatsis, Curr. Opin. Colloid Interface Sci.,10 (2005) 233.
    [176]M. S. Holm, E. Taarning, K. Egeblad and C.H. Christensen, Catal. Today,168 (2011)3.
    [177]S. van Donk, A.H. Janssen, J.H. Bitter and K.P. de Jong, Catal. Rev.-Sci. Eng., 45 (2003)297.
    [178]A. H. Janssen, A.J. Koster and K.P. de Jong, J. Phys. Chem. B,106 (2002) 11905.
    [179]C. Choifeng, J.B. Hall, B.J. Huggins and R.A. Beyerlein, J. Catal.,140 (1993) 395.
    [180]A. Corma, M.J. Diaz-Cabanas, J. Martinez-Triguero, F. Rey and J. Rius, Nature, 418(2002)514.
    [181]K.-H. Lee and B.-H. Ha, Microporous Mesoporous Mater.,23 (1998)211.
    [182]J.A. van Bokhoven, M. Tromp, D.C. Koningsberger, J.T. Miller, J.A.Z. Pieterse, J.A. Lercher, B.A. Williams and H.H. Kung, J. Catal.,202 (2001) 129.
    [183]R.M. Lago, W.O. Haag, R.J. Mikovsky, D.H. Olson, S.D. Hellring, K.D. Schmitt and G.T. Kerr, in A.I. Y. Murakami and J.W. Ward (Editors), Stud. Surf. Sci. Catal., Vol. Volume 28, Elsevier,1986, p.677.
    [184]R.J. Pellet, D.G. Casey, H.M. Huang, R.V. Kessler, E.J. Kuhlman, C.L. Oyoung, R.A. Sawicki and J.R. Ugolini, J. Catal.,157 (1995) 423.
    [185]M.M.L. Ribeiro Carrott, P.A. Russo, C. Carvalhal, P.J.M. Carrott, J.P. Marques, J.M. Lopes, I. Gener, M. Guisnet and F. Ramoa Ribeiro, Microporous Mesoporous Mater.,81 (2005)259.
    [186]R. Giudici, H.W. Kouwenhoven and R. Prins, Appl. Catal., A,203 (2000) 101.
    [187]R. M. Barrer and M.B. Makki, Can. J.'Chem.,42 (1964) 1481.
    [188]M. R. Apelian, A.S. Fung, G.J. Kennedy and T.F. Degnan, J. Phys. Chem.,100 (1996)16577.
    [189]M. Muller, G. Harvey and R. Prins, Microporous Mesoporous Mater.,34 (2000) 135.
    [190]H. K. Beyer and I. Belenykaja, in C.N.Y.B.T.J.C.V.G.C. B. Imelik and H. Praliaud (Editors), Stud. Surf. Sci. Catal., Vol. Volume 5, Elsevier,1980, p.203.
    [191]Q. L. Wang, M. Torrealba, G. Giannetto, M. Guisnet, G. Perot, M. Cahoreau and J. Caisso, Zeolites,10 (1990) 703.
    [192]A. Corma and M.T. Navarro, in G.G. R. Aiello and F. Testa (Editors), Stud. Surf. Sci. Catal., Vol. Volume 142, Elsevier,2002, p.487.
    [193]J. Kim, M. Choi and R. Ryoo, J. Catal.,269 (2010) 219. [194] J. C. Groen, J.C. Jansen, J.A. Moulijn and J. Perez-Ramirez, J. Phys. Chem. B, 108(2004) 13062.
    [195]J. C. Groen, L.A.A. Peffer, J.A. Moulijn and J. Perez-Ramirez, Chem. Eur. J., 11 (2005)4983.
    [196]R. M. Dessau, E.W. Valyocsik and N.H. Goeke, Zeolites,12 (1992) 776.
    [197]J. C. Groen, T. Bach, U. Ziese, A.M. Paulaime-van Donk, K.P. de Jong, J.A. Moulijn and J. Perez-Ramirez, J. Am. Chem. Soc.,127 (2005) 10792.
    [198]N. Danilina, F. Krumeich, S.A. Castelanelli and J.A. van Bokhoven, J. Phys. Chem.C,114(2010)6640.
    [199]D. Verboekend and J. Perez-Ramirez, Chem. Eur. J.,17 (2011) 1137.
    [200]J. Perez-Ramirez, D. Verboekend, A. Bonilla and S. Abello, Adv. Funct. Mater., 19(2009)3972.
    [201]A. H. Janssen, A.J. Koster and K.P. de Jong, Angew. Chem. Int. Ed.,40 (2001) 1102.
    [202]C. J. H. Jacobsen, C. Madsen, J. Houzvicka, I. Schmidt and A. Carlsson, J. Am. Chem. Soc.,122(2000)7116.
    [203]M.Y. Kustova, P. Hasselriis and C.H. Christensen, Catal. Lett.,96 (2004) 205.
    [204]X. Wei and P.G. Smimiotis, Microporous Mesoporous Mater.,89 (2006) 170.
    [205]I. Schmidt, A. Boisen, E. Gustavsson, K. Stahl, S. Pehrson, S. Dahl, A. Carlsson and C.J.H. Jacobsen, Chem. Mater.,13 (2001) 4416.
    [206]A. Boisen, I. Schmidt, A. Carlsson, S. Dahl, M. Brorson and C.J.H. Jacobsen, Chem. Commun., (2003) 958.
    [207]A. H. Janssen, I. Schmidt, C.J.H. Jacobsen, A.J. Koster and K.P. de Jong, Microporous Mesoporous Mater.,65 (2003) 59.
    [208]J. Perez-Ramirez, C.H. Christensen, K. Egeblad, C.H. Christensen and J.C. Groen, Chem. Soc. Rev.,37 (2008) 2530.
    [209]Z.X. Yang, Y.D. Xia and R. Mokaya, Adv. Mater.,16 (2004) 727.
    [210]Y. Tao, H. Kanoh and K. Kaneko, Adv. Mater.,17 (2005) 2789.
    [211]Y. Fang and H. Hu, J. Am. Chem. Soc.,128 (2006) 10636.
    [212]Y. Fang, H. Hu and G. Chen, Chem. Mater.,20 (2008) 1670.
    [213]H. Li, Y. Sakamoto, Z. Liu, T. Ohsuna, O. Terasaki, M. Thommes and S. Che, Microporous Mesoporous Mater.,106 (2007) 174.
    [214]Y. Tao, H. Kanoh and K. Kaneko, J. Am. Chem. Soc.,125 (2003) 6044.
    [215]Y. Tao, H. Kanoh and K. Kaneko, J. Phys. Chem. B,107 (2003) 10974.
    [216]Y. Tao, H. Kanoh and K. Kaneko, Langmuir,21 (2004) 504.
    [217]F. S. Xiao, L. Wang, C. Yin, K. Lin, Y. Di, J. Li, R. Xu, D.S. Su, R. Schlogi, T. Yokoi and T. Tatsumi, Angew. Chem.,118 (2006) 3162.
    [218]L. Wang, Z. Zhang, C. Yin, Z. Shan and F.-S. Xiao, Microporous Mesoporous Mater.,131 (2010)58.
    [219]S. Liu, X. Cao, L. Li, C. Li, Y. Ji and F.-S. Xiao, Colloids Surf., A,318 (2008) 269.
    [220]F. Liu, T. Willhammar, L. Wang, L. Zhu, Q. Sun, X. Meng, W. Carrillo-Cabrera, X. Zou and F. S. Xiao, J. Am. Chem. Soc.,134 (2012) 4557.
    [221]H. Wang and T.J. Pinnavaia, Angew. Chem. Int. Ed.,45 (2006) 7603. [222] H. Zhu, Z. Liu, D. Kong, Y. Wang and Z. Xie, J. Phys. Chem. C,112 (2008) 17257.
    [223]M. Choi, H.S. Cho, R. Srivastava, C. Venkatesan, D.-H. Choi and R. Ryoo, Nat. Mater.,5(2006)718.
    [224]G.V. Shanbhag, M. Choi, J. Kim and R. Ryoo, J. Catal.,264 (2009) 88.
    [225]M. Choi, R. Srivastava and R. Ryoo, Chem. Commun., (2006) 4380.
    [226]R. Srivastava, M. Choi and R. Ryoo, Chem. Commun., (2006) 4489.
    [227]A. Inayat,1. Knoke, E. Spiecker and W. Schwieger, Angew. Chem. Int. Ed.,51 (2012)1962.
    [228]J. Hua and Y. Han, Chem. Mater.,21 (2009) 2344.
    [229]J. Zhao, Z. Hua, Z. Liu, Y. Li, L. Guo, W. Bu, X. Cui, M. Ruan, H. Chen and J. Shi, Chem. Commun., (2009) 7578.
    [230]J. Vernimmen, V. Meynen, S.J.F. Herregods, M. Mertens, O.I. Lebedev, G. Van Tendeloo and P. Cool, Eur. J. Inorg. Chem., (2011) 4234.
    [231]K. Na, M. Choi, W. Park, Y. Sakamoto, O. Terasaki and R. Ryoo, J. Am. Chem. Soc.,132(2010)4169.
    [232]K. Na, C. Jo, J. Kim, W.-S. Ahn and R. Ryoo, ACS Catalysis,1 (2011) 901.
    [233]K. Na, C. Jo, J. Kim, K. Cho, J. Jung, Y. Seo, R.J. Messinger, B.F. Chmelka and R. Ryoo, Science,333 (2011) 328.
    [234]M. Choi, K. Na and R. Ryoo, Chem. Commun., (2009) 2845.
    [235]T. M. Davis, T.O. Drews, H. Ramanan, C. He, J. Dong, H. Schnablegger, M.A. Katsoulakis, E. Kokkoli, A.V. McCormick, R.L. Penn and M. Tsapatsis, Nat. Mater.,5 (2006) 400.
    [236]A. Petushkov, S. Yoon and S.C. Larsen, Microporous Mesoporous Mater.,137 (2011)92.
    [1]M. Bari Siddiqui, A. Aitani, M. Saeed and S. Al-Khattaf, Top. Catal.,53 (2010) 1387.
    [2]W. Vermeiren and J.P. Gilson, Top. Catal.,52 (2009) 1131.
    [3]B.K. Marcus and W.E. Cormier, Chem. Eng. Prog.,95 (1999) 47.
    [4]M.E. Davis, Nature,417 (2002) 813.
    [5]K. Egeblad, C.H. Christensen and M. Kustova, Chem. Mater.,20 (2008) 946.
    [6]J. Perez-Ramirez, C.H. Christensen, K. Egeblad and J.C. Groen, Chem. Soc. Rev., 37 (2008) 2530.
    [7]C.E.A. Kirschhock, S.P.B. Kremer, J. Vermant, G. Van Tendeloo, P.A. Jacobs and J.A. Martens, Chem. Eur. J.,11 (2005) 4306.
    [8]S. van Donk, A.H. Janssen, J.H. Bitter and K.P. de Jong, Catal. Rev.-Sci. Eng.,45 (2003)297.
    [9]X.J. Meng, F. Nawaz and F.S. Xiao, Nano Today,4 (2009) 292.
    [10]C.J.H. Jacobsen, C. Madsen, J. Houzvicka, I. Schmidt and A. Carlsson, J. Am. Chem. Soc.,122(2000)7116.
    [11]A. Boisen, I. Schmidt, A. Carlsson, S. Dahl, M. Brorson and C.J.H. Jacobsen, Chem. Commun., (2003)958.
    [12]I. Schmidt, A. Boisen, E. Gustavsson, K. Stahl, S. Pehrson, S. Dahl, A. Carlsson and C.J.H. Jacobsen, Chem. Mater.,13 (2001) 4416.
    [13]Y.S. Tao, H. Kanoh and K. Kaneko, J. Am. Chem. Soc.,125 (2003) 6044.
    [14]F.S. Xiao, L. Wang, C. Yin, K. Lin, Y. Di, J. Li, R. Xu, D.S. Su, R. Schlogl, T. Yokoi and T. Tatsumi, Angew. Chem. Int. Ed.,45 (2006) 3090.
    [15]R. Wang, W. Liu, S. Ding, Z. Zhang, J. Li and S. Qiu, Chem. Commun.,46 (2010) 7418.
    [16]M. Choi, H.S. Cho, R. Srivastava, C. Venkatesan, D.H. Choi and R. Ryoo, Nat. Mater.,5 (2006)718.
    [17]R. Srivastava, M. Choi and R. Ryoo, Chem. Commun.,43 (2006) 4489.
    [18]J.C. Groen, L.A.A. Peffer, J.A. Moulijn and J. Perez-Ramirez, Chem. Eur. J.,11 (2005) 4983.
    [19]J. Perez-Ramirez, S. Abello, A. Bonilla and J.C. Groen, Adv. Funct. Mater.,19 (2009) 164.
    [20]R. Caicedo-Realpe and J. Perez-Ramirez, Microporous Mesoporous Mater.,128 (2010)91.
    [21]S. van Donk, A.H. Janssen, J.H. Bitter and K.P. de Jong, Catal. Rev.,45 (2003) 297.
    [22]J.C. Groen, T. Bach, U. Ziese, A.M. Paulaime-van Donk, K.P. de Jong, J.A. Moulijn and J. Perez-Ramirez, J. Am. Chem. Soc.,127 (2005) 10792.
    [23]Y. Tao, H. Kanoh, L. Abrams and K. Kaneko, Chem. Rev.,106 (2006) 896.
    [24]B.J. Schoeman, J. Sterte and J.E. Otterstedt, Zeolites,14 (1994) 110.
    [25]B. Kalita and A.K. Talukdar, Mater. Res. Bull.,44 (2009) 254.
    [26]G. Reding, T. Maurer and B. Kraushaar-Czarnetzki, Microporous Mesoporous Mater.,57 (2003) 83.
    [27]D.P. Serrano, J. Aguado, J.M. Escola, J.M. Rodriguez and A. Peral, Chem. Mater., 18(2006)2462.
    [28]G.T. Vuong and T.O. Do, J. Am. Chem. Soc.,129 (2007) 3810.
    [29]G. Majano, A. Darwiche, S. Mintova and V. Valtchev, Ind. Eng. Chem. Res.,48 (2009) 7084.
    [30]N. Ren, Z.J. Yang, X.C. Lv, J. Shi, Y.H. Zhang and Y. Tang, Microporous Mesoporous Mater.,131 (2010) 103.
    [31]S. Frisch, L.M. Rosken, J. Caro and M. Wark, Microporous Mesoporous Mater., 120(2009)47.
    [32]C.J.H. Jacobsen, C. Madsen, T.V.W. Janssens, H.J. Jakobsen and J. Skibsted, Microporous Mesoporous Mater.,39 (2000) 393.
    [33]W.C. Yoo, S. Kumar, Z. Wang, N.S. Ergang, W. Fan, G.N. Karanikolos, A.V. McCormick, R.L. Penn, M. Tsapatsis and A. Stein, Angew. Chem.,120 (2008) 9236.
    [34]J. Hua and Y. Han, Chem. Mater.,21 (2009) 2344.
    [35]K. Na, M. Choi and R. Ryoo, J. Mater. Chem.,19 (2009) 6713.
    [36]M. Choi, K. Na and R. Ryoo, Chem. Commun., (2009) 2845.
    [37]L. Chen, S.Y. Zhu, Y.M. Wang and M.Y. He, New J. Chem.,34 (2010) 2328.
    [38]Y.M. Fang, H.Q. Hu and G.H. Chen, Chem. Mater.,20 (2008) 1670.
    [39]R. Kumar, A. Bhaumik, R.K. Ahedi and S. Ganapathy, Nature,381 (1996) 298.
    [40]L.I. Meza, M.W. Anderson, J.R. Agger, C.S. Cundy, C.B. Chong and R.J. Plaisted, J. Am. Chem. Soc.,129(2007) 15192.
    [41]G.T. Kerr, J. Phys. Chem.,70 (1966) 1047.
    [42]G.T. Kerr, J. Phys. Chem.,72 (1968) 1385.
    [43]A.E.W. Maher P K, Mcdaniel C V, US Pat.3671191,(1972).
    [44]徐如人,张建民,高等学校化学学报,3(1982)287.
    [45]M.T. Melchior, D.E.W. Vaughan and C.F. Pictroski, J. Phys. Chem.,99 (1995) 6128.
    [46]A. Thangaraj and R. Kumar, Zeolites,10 (1990) 117.
    [47]F. Fan, Z. Feng and C. Li, Chem. Soc. Rev.,39 (2010).
    [48]胡汉祥,施其宏,南昌大学学报(工科版),20(1998)80.
    [49]T.A.J. Hardenberg, L. Mertens, P. Mesman, H.C. Muller and C.P. Nicolaides, Zeolites,12(1992)685.
    [50]R. Caicedo-Realpe and J. Perez-Ramirez, Microporous Mesoporous Mater.,128 (2010)91.
    [51]C.S. Cundy and P.A. Cox, Microporous Mesoporous Mater.,82 (2005) 1.
    [52]J. Aguado, D.P. Serrano, J.M. Escola and J.M. Rodriguez, Microporous Mesoporous Mater.,75 (2004) 41.
    [53]X.J. Cheng, X.S. Wang and H.Y. Long, Microporous Mesoporous Mater.,119 (2009)171.
    [54]S.Y. Sang, F.X. Chang, Z.M. Liu, C.Q. He, Y.L. He and L. Xu, Catal. Today,93-5 (2004) 729.
    [55]H.H. Pan, Q.X. Pan, Y.S. Zhao, Y.B. Luo, X.T. Shu and M.Y. He, Ind. Eng. Chem. Res.,49(2010)7294.
    [56]F.X. Feng and K.J. Balkus, J. Porous Mater.,10 (2003) 235.
    [57]N.Y. Kang, B.S. Song, C.W. Lee, W.C. Choi, K.B. Yoon and Y.K. Park, Microporous Mesoporous Mater.,118 (2009) 361.
    [58]P.-S. Lee, X. Zhang, J.A. Stoeger, A. Malek, W. Fan, S. Kumar, W.C. Yoo, S. Al Hashimi, R.L. Penn, A. Stein and M. Tsapatsis, J. Am. Chem. Soc.,133 (2010)493.
    [59]P. Morales-Pacheco, F. Alvarez-Ramirez, P. DelAngel, L. Bucio and J.M. Dominguez, J. Phys. Chem. C,111 (2007) 2368.
    [60]R. Ravishankar, C.E.A. Kirschhock, P.P. Knops-Gerrits, E.J.P. Feijen, P.J. Grobet, P. Vanoppen, F.C. De Schryver, G. Miehe, H. Fuess, B.J. Schoeman, P.A. Jacobs and J.A. Martens, J. Phys. Chem. B,103 (1999) 4960.
    [61]E. Oldfield, J. Haase, K.D. Schmitt and S.E. Schramm, Zeolites,14 (1994) 101.
    [62]D.P. Serrano, J. Aguado, G. Morales, J.M. Rodriguez, A. Peral, M. Thommes, J.D. Epping and B.F. Chmelka, Chem. Mater.,21 (2009) 641.
    [63]R. von Ballmoos and W.M. Meier, Nature,289 (1981) 782.
    [64]E.G. Derouane, J.P. Gilson, Z. Gabelica, C. Mousty-Desbuquoit and J. Verbist, J. Catal.,71 (1981)447.
    [65]M. Niederberger and H. Colfen, Phys. Chem. Chem. Phys.,8 (2006) 3271.
    [1]C. Fernandez, I. Stan, J.-P. Gilson, K. Thomas, A. Vicente, A. Bonilla and J. Perez-Ramirez, Chem. Eur. J.,16 (2010) 6224.
    [2]H. Krannila, W.O. Haag and B.C. Gates, J. Catal.,135 (1992) 115.
    [3]M.A. Bari Siddiqui, A.M. Aitani, M.R. Saeed and S. Al-Khattaf, Top. Catal.53 (2010) 1387.
    [4]T. Odedairo and S. Al-Khattaf, Chem. Eng. J.,167 (2011) 240.
    [5]D. Mores, E. Stavitski, M.H.F. Kox, J. Kornatowski, U. Olsbye and B.M. Weckhuysen, Chem. Eur. J.,14 (2008) 11320.
    [6]M. Bjorgen, S. Svelle, F. Joensen, J. Nerlov, S. Kolboe, F. Bonino, L. Palumbo, S. Bordiga and U. Olsbye, J. Catal.,249 (2007) 195.
    [7]D.M. Bibby, N.B. Milestone and L.P. Aldridge, Nature,285 (1980) 30.
    [8]韩淑芸,徐如人,高等学校化学学报,1982,3(3)430.
    [9]韩淑芸,徐如人,左丽华等,高等学校化学学报,1984,5(2)255-256.
    [10]韩淑芸,史苏华,梁启等,高等学校化学学报,1983,4(5)540-544.
    [11]M.Ghamami and L.B. Sand, Zeolites,3(1983) 155.
    [12]L.-Y. Hou, L.B. Sand and R.W. Thompson, in A.I. Y. Murakami and J.W. Ward (Editors), Studies in Surface Science and Catalysis, Vol. Volume 28, Elsevier,1986, p. 239.
    [13]S. Brandani, M. Jama and D. Ruthven, Microporous Mesoporous Mater.,35-6 (2000)283.
    [14]B. Vogel, C. Schneider and E. Klemm, Catal. Lett.,79 (2002) 107.
    [15]L. Tosheva and V.P. Valtchev, Chem. Mater.,17 (2005) 2494. [16] S.C. Larsen, J. Phys. Chem. C,111 (2007) 18464.
    [17]C.S. Cundy and P.A. Cox, Microporous Mesoporous Mater.,82 (2005) 1.
    [18]L.-Y. Hou and R.W. Thompson, Zeolites,9(1989) 526.
    [19]E.A. Tsokanis and R.W. Thompson, Zeolites,12 (1992) 369.
    [20]G. Reding, T. Maurer and B. Kraushaar-Czarnetzki, Microporous Mesoporous Mater.,57 (2003) 83.
    [21]G. Majano, A. Darwiche, S. Mintova and V. Valtchev, Ind. Eng. Chem. Res.,48 (2009) 7084.
    [22]N. Ren, Z.-J. Yang, X.-C. Lv, J. Shi, Y.-H. Zhang and Y. Tang, Microporous Mesoporous Mater.,131 (2010) 103.
    [23]N. Ren, J. Bronic, B. Subotic, X.-C. Lv, Z.-J. Yang and Y. Tang, Microporous Mesoporous Mater.,139 (2011) 197.
    [24]A.J. Peter and A.M. Johan, Chapter I:Synthesis of ZSM-5 Zeolites in the Presence of Tetrapropylammonium Ions, in:A.J. Peter and A.M. Johan (Eds), Stud. Surf. Sci. Catal., Vol.33, Elsevier,1987, p.47.
    [25]P.A. Jacobs, E.G. Derouane and J. Weitkamp, J. Chem. Soc, Chem. Commun., (1981)591.
    [26]P.A. Jacobs, H.K. Beyer and J. Valyon, Zeolites,1 (1981) 161.
    [27]J.C. Jansen, F.J. van der Gaag and H. van Bekkum, Zeolites,4 (1984) 369.
    [28]V.N. Romannikov, V.M. Mastikhin, S. Hocevar and B. Drzaj, Zeolites,3 (1983) 311.
    [29]V.N. Shetti, J. Kim, R. Srivastava, M. Choi and R. Ryoo, J. Catal.,254 (2008) 296.
    [30]S. Sang, F. Chang, Z. Liu, C. He, Y. He and L. Xu, Catal. Today,93-95 (2004) 729.
    [31]R. Van Grieken, J.L. Sotelo, J.M. Menendez and J.A. Melero, Microporous Mesoporous Mater.,39 (2000) 135.
    [32]C.A. Fyfe, G.C. Gobbi, J. Klinowski, J.M. Thomas and S. Ramdas, Nature,296 (1982)530.
    [33]D.P. Serrano, R. van Grieken, J. Antonio Melero, A. Garcia and C. Vargas, J. Mol. Catal. A:Chem.,318 (2010) 68.
    [34]N. Viswanadham, R. Kamble, M. Singh, M. Kumar and G.M. Dhar, Catal. Today, 141 (2009) 182.
    [1]R.J. Argauer and G.R. Landolt, US Pat.3702886, (1972).
    [2]D. Goto, Y. Harada, Y. Furumoto, A. Takahashi, T. Fujitani, Y. Oumi, M. Sadakane and T. Sano,Appl. Catal., A,383 (2010) 89.
    [3]S.B. Kulkarni, V.P. Shiralkar, A.N. Kotasthanc, R.B. Borade and P. Ratnasamy, Zeolites,2(1982)313.
    [4]C. Herrmann, J. Haas and F. Fetting, Appl. Catal.,35 (1987) 299.
    [5]C. Xu, H. Liu, M. Jia, J. Guan, S. Wu, T. Wu and Q. Kan, Appl. Surf. Sci.,257 (2011)2448.
    [6]M. Hartmann, Angew. Chem. Int. Ed.,43 (2004) 5880.
    [7]F.G. Dwyer and E.E. Jenkins, US Pat.3941871, (1976).
    [8]J.C. Groen, J.A. Moulijn and J. Perez-Ramirez, J. Mater. Chem.,16 (2006) 2121.
    [9]J.C. Groen, L.A.A. Peffer, J.A. Moulijn and J. Perez-Ramirez, Chem. Eur. J.,11 (2005) 4983.
    [10]A. Cimek, B. Subotic, I. Smit, A. Tonejc, R. Aiello, F. Crea and A. Nastro, Microporous Mater.,8 (1997) 159.
    [11]S. Choi, J. Coronas, E. Jordan, W. Oh, S. Nair, F. Onorato, D.F. Shantz and M. Tsapatsis, Angew. Chem. Int. Ed.,47 (2008) 552.
    [12]D.P. Serrano, R. van Grieken, J. Antonio Melero, A. Garcia and C. Vargas, J. Mol. Catal. A:Chem.,318(2010)68.
    [13]N. Viswanadham, R. Kamble, M. Singh, M. Kumar and G.M. Dhar, Catal. Today, 141 (2009) 182.
    [14]M. Firoozi, M. Baghalha and M. Asadi, Catal. Commun.,10 (2009) 1582.
    [15]A. Bressel, T. Donauer, S. Sealy and Y. Traa, Microporous Mesoporous Mater., 109(2008)278.
    [16]B. Subotic, J. Bronic in:Handbook of Zeolite Science and Technology, S.M. Auerbach, K.A Carrado and P.K. Dutta, eds., Marcel Dekker Inc, New York-Basel, (2003)129.
    [17]P. Ratnasamy, G.P. Babu, A.J. Chandwadkar and S.B. Kulkarni, Zeolites,6 (1986) 98.
    [18]S. Hill, K. Kinson, D. Seddon, Aust. J. Chem.41 (1988)783.
    [19]H. Mochizuki, T. Yokoi, H. Imai, R. Watanabe, S. Namba, J.N. Kondo and T. Tatsumi, Microporous Mesoporous Mater.,145 (2011) 165.
    [20]V.P. Shiralkar, P.N. Joshi, M.J. Eapen and B.S. Rao, Zeolites,11 (1991) 511.
    [21]G. Debras, A. Gourgue, J.B. Nagy and G.D. Clippeleir, Zeolites,5 (1985) 369.
    [22]V.N. Romannikov, V.M. Mastikhin, S. Hocevar and B. Drzaj, Zeolites,3 (1983) 311.
    [23]A.E. Persson, B.J. Schoeman, J. Sterte and J.E. Otterstedt, Zeolites,15 (1995) 611.
    [24]M. Ghiaci, F. Seyedeyn-Azad and R. Kia, Mater. Res. Bull,39 (2004) 1257.
    [25]C. Falamaki, M. Edrissi and M. Sohrabi, Zeolites,19 (1997) 2.
    [26]L.L. Korobitsyna, L.M. Velichkina, A.V. Vosmerikov, V.I. Radomskaya, E.S. Astapova, N.V. Ryabova and O.A. Agapyatova, Russ. J. Inorg. Chem.,53 (2008) 169.
    [27]K. Na, M. Choi and R. Ryoo, J. Mater. Chem.,19 (2009) 6713.
    [28]S. Narayanan, A. Sultana, Q. Thinh Le and A. Auroux,Appl. Catal., A,168 (1998) 373.
    [29]M.A. Uguina, A. de Lucas, F. Ruiz and D.P. Serrano, Ind. Eng. Chem. Res.,34 (1995)451.
    [30]J. Warzywoda, R.D. Edelman and R.W. Thompson, Zeolites,11 (1991) 318.
    [31]C.S. Cundy and P.A. Cox, Microporous Mesoporous Mater.,82 (2005) 1.
    [32]K. Suzuki and T. Hayakawa, Microporous Mesoporous Mater.,77 (2005) 131.
    [33]B. Hincapie, Microporous Mesoporous Mater.,67 (2004) 19.
    [34]G. Reding, T. Maurer and B. Kraushaar-Czarnetzki, Microporous Mesoporous Mater.,57 (2003) 83.
    [35]C.J. Plank, E.J. Rosinski, M.K. Rubin, US Patent 4175114 (1979).
    [36]S. Gonthier and R.W. Thompson, in M.S.H.G.K. J.C. Jansen and J. Weitkamp (Editors), Studies in Surface Science and Catalysis, Vol. Volume 85, Elsevier,1994, p. 43.
    [37]H. Kacirek and H. Lechert, J. Phys. Chem.,79 (1975) 1589.
    [38]C.S. Cundy, M.S. Henty and R.J. Plaisted, Zeolites,15 (1995) 353.
    [39]C.S. Cundy, J.O. Forrest and R.J. Plaisted, Microporous Mesoporous Mater.,66 (2003) 143.
    [40]C. S. Cundy and J. Ping Zhao, Chem. Commun., (1998) 1465.
    [41]G. Majano, A. Darwiche, S. Mintova and V. Valtchev, Ind. Eng. Chem. Res.,48 (2009) 7084.
    [42]D. Wang, X. Li, Z. Liu, Y. Zhang, Z. Xie and Y. Tang, J. Colloid Interface Sci., 350(2010)290.
    [43]N. Ren, Z.-J. Yang, X.-C. Lv, J. Shi, Y.-H. Zhang and Y. Tang, Microporous Mesoporous Mater.,131 (2010) 103.
    [44]N. Ren, J. Bronic, B. Subotic, X.-C. Lv, Z.-J. Yang and Y. Tang, Microporous Mesoporous Mater.,139(2011) 197.
    [45]N. Ren, J. Bronic, B. Subotic, Y.-M. Song, X.-C. Lv and Y. Tang, Microporous Mesoporous Mater.,147(2012)229.
    [46]J.C. Groen, T. Bach, U. Ziese, A.M. Paulaime-van Donk, K.P. de Jong, J.A. Moulijn and J. Perez-Ramirez, J. Am. Chem. Soc.,127 (2005) 10792.
    [47]W. Schmidt, U. Wilczok, C. Weidenthaler, O. Medenbach, R. Goddard, G. Buth and A. Cepak, J. Phys. Chem. B.,111 (2007) 13538.
    [48]H. Pan, Q. Pan, Y. Zhao, Y. Luo, X. Shu and M. He, Ind. Eng. Chem. Res.,49 (2010)7294.
    [49]N.Y. Kang, B.S. Song, C.W. Lee, W.C. Choi, K.B. Yoon and Y.-K. Park, Microporous Mesoporous Mater.,118 (2009) 361.
    [50]J. Aguado, D.P. Serrano, J.M. Escola and J.M. Rodriguez, Microporous Mesoporous Mater.,75 (2004) 41.
    [51]O.C. Gobin, S.J. Reitmeier, A. Jentys and J.A. Lercher, J. Phys. Chem. C,113 (2009)20435.
    [52]E.G. Derouane, S. Determmerie, Z. Gabelica and N. Blom, Appl. Catal.,1 (1981) 201.
    [53]A.J. Peter and A.M. Johan, in A.J. Peter and A.M. Johan (Editors), Studies in Surface Science and Catalysis, Vol. Volume 33, Elsevier,1987, p.47.
    [54]K. Nakai, J. Sonoda, M. Yoshida, M. Hakuman and H. Naono, Adsorption,13 (2007)351.
    [55]J. Groen,Appl. Catal., A,268 (2004) 121.
    [56]J.C. Groen, L.A.A. Peffer and J. Perez-Ramirez, Microporous Mesoporous Mater., 60 (2003) 1.
    [57]R. Thompson, Recent Advances in the Understanding of Zeolite Synthesis Synthesis, Springer, Berlin/Heidelberg,1998, p.1.
    [58]R.M. Dessau, E.W. Valyocsik and N.H. Goeke, Zeolites,12 (1992) 776.
    [59]B.M. Lok, T.R. Cannan and C.A. Messina, Zeolites,3 (1983) 282.
    [60]F. Testa, F. Crea, A. Nastro, R. Aiello, R. Mostowicz and J.B. Nagy, Zeolites,11 (1991)633.
    [1]李雅丽,当代石油石化,9(2001)31.
    [2]卢文李,石油化工技术经济,20(2004)26.
    [3]J. Knight, R. Mehlberg, Hydrocarbon Processing, Sept. (2011),91.
    [4]王瀚舟,钱伯章,石汕化工,29(2000)705.
    [5]T. Tago, H. Konno, Y. Nakasaka and T. Masuda, Catalysis Surveys from Asia,16 (2012)148.
    [6]Y. Yosimura, N. Kijima, T. Hayakawa, K. Murata, K. Suzuki, F. Mizukami, K. Matano, T. Konishi, T. Oikawa, M. Saito, T. Shiojima, K. Shiozawa, K. Wakui, G. Sawada, K. Sato, S. Matsuo, N. Yamaoka, Catal Surv Jpn,4 (2000) 157.
    [7]余本德,施至诚,许友好,石油炼制与化工,26(1995)7213.
    [8]Y. J. Liu, J. Long, H. P. Tian, Y. Xu, L. Z. Zhao, China Petroleum Processing and Petrochemical Technology,13 (2011) 1.
    [9]谢朝钢,汪燮卿,郭志雄,石油炼制与化工,32(2001)7.
    [10]许友好,张久顺,马建国,龙军,石油炼制与化工,35(2004)1.
    [11]L. Y. Wang, G. L. Wang, J. L. Wei, Oil Gas J,101 (2003) 52.
    [12]J. Hairston, Chem Eng,106 (1999) 30.
    [13]顾道斌,石油化工技术与经济,28(2012)57.
    [14]T. Amano, J. Wilcox, C. Pouwels and T. Matsuura, www.eptq.com, PTQ Q3 (2012) 1.
    [15]T.F. Degnan, G.K. Chitnis and P.H. Schipper, Microporous and Mesoporous Mater.,35-36(2000)245.
    [16]C.S. Triantafillidis, N.P. Evmiridis, L. Nalbandian and I.A. Vasalos, Ind. Eng. Chem. Res.,38(1999)916.
    [17]J.M. Arandes, I. Abajo, I. Fernandez, M.J. Azkoiti and J. Bilbao, Ind. Eng. Chem. Res.,39 (2000) 1917.
    [18]J.S. Buchanan, Catal. Today,55 (2000) 207.
    [19]X. Gao, Z. Tang, H. Zhang, D. Ji, G. Lu, Z. Wang and Z. Tan, J. Mol. Catal. A: Chem.,325(2010)36.
    [20]T. Degnan, Top. Catal.,13 (2000) 349.
    [1]M. Taramasso, G. Pergo, B. Notari, U.S. Pat.4410501, (1983).
    [2]J.A. Martens, P. Buskens, P.A. Jacobs, A.v.d. Pol, J.H.C.v. Hooff, C. Ferrini, H.W. Kouwenhoven, P.J. Kooyman and H.v. Bekkum, Hydroxylation of phenol with hydrogen peroxide on EUROTS-1 catalyst,1993.
    [3]F. Maspero and U. Romano, J. Catal.,146 (1994) 476.
    [4]M. G. Clerici, Appl. Catal.,68 (1991) 249.
    [5]A. Thangaraj, S. Sivasanker and P. Ratnasamy, J. Catal.,131 (1991) 394.
    [6]M.G. Clerici, G. Bellussi and U. Romano, J. Catal.,129(1991) 159.
    [7]G. Li, X. Wang, H. Yan, Y. Liu and X. Liu, Appl. Catal., A:General,236 (2002) 1.
    [8]U.Muller and W. Steck, in H.G.K.H.P. J. Weitkamp and W. Holderich (Editors), Stud. Surf. Sci. Catal., Vol. Volume 84, Elsevier,1994, p.203.
    [9]X.-s. Wang and X.-w. Guo, Catal. Today,51 (1999) 177.
    [10]L. Gang, G. Xinwen, W. Xiangsheng, Z. Qi, B. Xinhe, H. Xiuwen and L. Liwu, Appl. Catal., A:General,185 (1999) 11.
    [11]M. Shibata, J. Gerard and Z. Gabelica, in S.-K.I. Hakze Chon and U. Young Sun (Editors), Stud. Surf. Sci. Catal. Vol. Volume 105, Elsevier,1997, p.245.
    [12]A. Tuel, Zeolites,16(1996) 108.
    [13]Q.H. Xia and Z. Gao, Mater. Chem. Phys.,47 (1997) 225.
    [14]H. Zhang, Y. Liu, Z. Jiao, M. He and P. Wu, Ind. Eng. Chem. Res.,48 (2009) 4334.
    [15]Y. Zuo, X.Wang and X. Guo, Ind. Eng. Chem. Res.,50(2011)8485.
    [16]L. Chen, Y.M. Wang and M.-Y. He, Mater. Res. Bull.,46 (2011) 698.
    [17]A. Zecchina, S. Bordiga, C. Lamberti, G. Ricchiardi, D. Scarano, G. Petrini, G. Leofanti and M. Mantegazza, Catal. Today,32 (1996) 97.
    [18]C. Li, J. Catal.,216 (2003) 203.
    [19]F. Geobaldo, S. Bordiga, A. Zecchina, E. Giamello, G. Leofanti and G. Petrini, Catal. Lett.,16(1992) 109.
    [20]A.M. Prakash, H.M. Sung-Suh and L. Kevan, J. Phys. Chem. B,102 (1998) 857.
    [21]L. Marchese, T. Maschmeyer, E. Gianotti, S. Coluccia and J.M. Thomas, The J. Phys. Chem. B,101 (1997) 8836.
    [22]P. Ratnasamy, D. Srinivas and H. Knozinger, Advances in Catalysis, Vol.48, Academic Press,2004, p.1.
    [23]张义华,郭新闻,王祥生,李钢,陈永英,石油学报(石油加工),16(2000)41.
    [24]T. Blasco, M.A. Camblor, A. Corma and J. Perez-Pariente, JACS,115 (1993) 11806.
    [25]M. Wang, J. Zhou, G. Mao and X. Zheng, Ind. Eng. Chem. Res., (2012).
    [26]R. Millini, E.P. Massara, G. Perego and G. Bellussi, J. of Catal,137 (1992) 497.
    [27]C.B. Khouw, C.B. Dartt, J.A. Labinger and M.E. Davis, J. of Catal.,149 (1994) 195.
    [28]R.B. Khomane, B.D. Kulkarni, A. Paraskar and S.R. Sainkar, Mater. Chem. Phys., 76 (2002) 99.
    [29]F. Xu, M. Dong, W. Gou, J. Li, Z. Qin, J. Wang and W. Fan, Microporous Mesoporous Mater.,163 (2012) 192.
    [30]F.X. Feng and K.J. Balkus, J. Porous Mater.,10 (2003) 235.
    [31]N.Y. Kang, B.S. Song, C.W. Lee, W.C. Choi, K.B. Yoon and Y.-K. Park, Microporous Mesoporous Mater.,118 (2009) 361.
    [32]E. Jorda, A. Tuel, R. Teissier and J. Kervennal, Zeolites,19 (1997) 238.
    [33]M. Shibata and Z. Gabelica, Zeolites,19 (1997) 246.

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