新型水泥基自流平修补砂浆的研究
摘要
修补、加固已成为当今建筑行业的一个重要领域。由于建筑物受损原因和修补环境的复杂性使修补材料的性能不可一概而论。因此,开发不同性能的修补材料以适应不同的修补情况具有重要意义。基于“性能相容性”及“修补的系统设计”等概念,本研究将无机类和有机类修补材料的性能特点相结合,这既使得修补材料有较高的粘结强度,又因为有机成分所占比重相对较小,因而保证了修补材料与基材性能的相容性。
本工作采用了超塑化剂和矿物掺合料的“双掺”的技术,以磨细矿渣为主要矿物掺合料,复合掺入了锂渣、石灰石粉等,并针对材料的性能以适当的外加剂(激发剂、乳胶粉、膨胀剂等)改性。通过运用通用的工艺手段和标准养护方式,研究了不同矿物掺合料的复合效应和复合掺合料、外加剂等对修补砂浆工作性能、力学性能及耐久性等的影响。
在实验室条件下制备了两种具有不同性能的修补砂浆,可用于对流动性要求较高的修补环境,如钢筋密集区、薄壁构件、复杂型体以及水平地面的修补。且EJ-1修补砂浆还可用于对抗折强度要求相对较高的桥面、路面的修补。EJ-2可用于对早期抗压强度要求相对低的修补环境。
以粘结抗剪强度作为新老材料粘结性能的评定指标,配制了四种界面剂。两种修补砂浆均适于分别掺锂渣和膨胀剂的界面剂M2、M3。且界面剂M2的效果优于界面剂M3。扫描电镜和XRD试验表明:以锂渣制备的界面剂M2水化形成的产物呈乱向纤维状,钙矾石细小,有利于界面过渡区的粘结;而以膨胀剂制备的界面剂M3有结晶粗大、择优取向的CH生成,不利于界面粘结。
最后研究了矿物掺合料种类、掺量、外加剂等对修补砂浆耐久性能的影响。试验表明,所制得的修补砂浆具有一定的微膨胀性,较好的抗氯离子渗透性和抗硫酸盐腐蚀性。
Repair and reinforcement of constructions has been an important field in Construct. It can not be undifferentiated that properties of repair materials considering the complexity of factors resulting deterioration of constructions and environment of repairing. Hence, it has great significance to explore repair materials with different properties in order to adapt to varied repairing situation. Based on the concepts of“compatibility”and“system design in repairing the repairs”, the paper combined the properties of inorganic and organic repair materials, which not only assured the high bond strength of repair materials, but the compatibility of the repair materials and based materials, as the comparing low proportion of organic components.
The work exerted“both added”technic of superplasticizer and mineral admixtures, used grinded blast slag as the main admixture, added with lithium slag and limestone etc. and modified the repair materials’properties by some proper agents(accelerating agents, polymer-dispersion additives, expanding agents etc.). By exerting common technics and curing ways, the compound effects of different mineral admixtures and influence of compound admixtures, agents etc. on workability, mechanical properties, durability of the repair mortars had been researched.
Two kinds of repair mortars with different properties had been prepared on the condition of lab, which can be self-leveling. So they could be used in the environment of high fluidity required, such as dense steel zone, thin members, complicated form and structures, road surface repairing. Besides EJ-1 can be used in the repair of bridge and road surface which require high flexible strength. EJ-2 can be used in the environment of comparing low compressive strength but good tenacity required.
Using bond shearing strength as appraisal index to evaluate the bond properties between new and based materials, four kinds of interfacial agents had been prepared which had different effects on the repair materials. Yet the two kinds of repair materials both are suitable to interfacial agents of M2 and M3 which are added with lithium slag and expansive agents respectively. Interfacial agent M2 is more effective than M3 to the repair mortars .SEM and XRD trials have showed that the hydrate of interfacial agent M2 added with lithium slag admixture appeared shape of disorder fibers, fine AFt, which was beneficial to the bond of interfacial zone(IZ); but interfacial agent M3 added with expansive agent had big crystals, favoring direction CH, which were adverse to the bond of IZ.
At last, the influence of sorts, proportion of mineral admixtures and agents on durability of the repair mortars. The trials showed that the repair mortars prepared had been a bit expansive, good resistance of chlorine ion pervision and erosion of sulphate.
本工作采用了超塑化剂和矿物掺合料的“双掺”的技术,以磨细矿渣为主要矿物掺合料,复合掺入了锂渣、石灰石粉等,并针对材料的性能以适当的外加剂(激发剂、乳胶粉、膨胀剂等)改性。通过运用通用的工艺手段和标准养护方式,研究了不同矿物掺合料的复合效应和复合掺合料、外加剂等对修补砂浆工作性能、力学性能及耐久性等的影响。
在实验室条件下制备了两种具有不同性能的修补砂浆,可用于对流动性要求较高的修补环境,如钢筋密集区、薄壁构件、复杂型体以及水平地面的修补。且EJ-1修补砂浆还可用于对抗折强度要求相对较高的桥面、路面的修补。EJ-2可用于对早期抗压强度要求相对低的修补环境。
以粘结抗剪强度作为新老材料粘结性能的评定指标,配制了四种界面剂。两种修补砂浆均适于分别掺锂渣和膨胀剂的界面剂M2、M3。且界面剂M2的效果优于界面剂M3。扫描电镜和XRD试验表明:以锂渣制备的界面剂M2水化形成的产物呈乱向纤维状,钙矾石细小,有利于界面过渡区的粘结;而以膨胀剂制备的界面剂M3有结晶粗大、择优取向的CH生成,不利于界面粘结。
最后研究了矿物掺合料种类、掺量、外加剂等对修补砂浆耐久性能的影响。试验表明,所制得的修补砂浆具有一定的微膨胀性,较好的抗氯离子渗透性和抗硫酸盐腐蚀性。
Repair and reinforcement of constructions has been an important field in Construct. It can not be undifferentiated that properties of repair materials considering the complexity of factors resulting deterioration of constructions and environment of repairing. Hence, it has great significance to explore repair materials with different properties in order to adapt to varied repairing situation. Based on the concepts of“compatibility”and“system design in repairing the repairs”, the paper combined the properties of inorganic and organic repair materials, which not only assured the high bond strength of repair materials, but the compatibility of the repair materials and based materials, as the comparing low proportion of organic components.
The work exerted“both added”technic of superplasticizer and mineral admixtures, used grinded blast slag as the main admixture, added with lithium slag and limestone etc. and modified the repair materials’properties by some proper agents(accelerating agents, polymer-dispersion additives, expanding agents etc.). By exerting common technics and curing ways, the compound effects of different mineral admixtures and influence of compound admixtures, agents etc. on workability, mechanical properties, durability of the repair mortars had been researched.
Two kinds of repair mortars with different properties had been prepared on the condition of lab, which can be self-leveling. So they could be used in the environment of high fluidity required, such as dense steel zone, thin members, complicated form and structures, road surface repairing. Besides EJ-1 can be used in the repair of bridge and road surface which require high flexible strength. EJ-2 can be used in the environment of comparing low compressive strength but good tenacity required.
Using bond shearing strength as appraisal index to evaluate the bond properties between new and based materials, four kinds of interfacial agents had been prepared which had different effects on the repair materials. Yet the two kinds of repair materials both are suitable to interfacial agents of M2 and M3 which are added with lithium slag and expansive agents respectively. Interfacial agent M2 is more effective than M3 to the repair mortars .SEM and XRD trials have showed that the hydrate of interfacial agent M2 added with lithium slag admixture appeared shape of disorder fibers, fine AFt, which was beneficial to the bond of interfacial zone(IZ); but interfacial agent M3 added with expansive agent had big crystals, favoring direction CH, which were adverse to the bond of IZ.
At last, the influence of sorts, proportion of mineral admixtures and agents on durability of the repair mortars. The trials showed that the repair mortars prepared had been a bit expansive, good resistance of chlorine ion pervision and erosion of sulphate.
引文
[1] 曹双寅 邱洪兴 王恒华. 结构可靠性鉴定与加固技术[M]. 北京.中国水利水电出版社. 2002.2 序
[2] Roland Bayer, Hermann Lutz. Ullman 工业化学百科全书第 6 版.
[3] P. H. Emmons, A. M. Vaysburd. System Concept in Design and Construction of Durable Concrete Repairs. Construction and Building Materials. 1996.Vol.10, No.1 pp69~75
[4] 李富山. 聚合物水泥修补砂浆 建筑材料 1999,No.1pp18~19
[5] Victor C.Li, H.Horii, P.Kabele, T.Kanda, Y.M.Lim. Repair and retrofit with engineered cementitious composites. Engineering Fracture Mechanics. 2000. No.65 pp317~334
[6] J.G.Cabrera, A.S. Al-Hasan. Performance properties of concrete repair materials. Construction and Building Materials. 1997. Vol. 11, No.5-6, pp283~290
[7] 许贤敏 高聚英. 国外钢筋混凝土结构修补方法简介 公路 2004. No. 4 pp61~63
[8] 汪澜. 水泥混凝土组成性能应用[M]. 北京. 中国建材工业出版社. 2005. No.1 pp486~651
[9] 王燕谋 苏慕珍. 第三系列水泥在中国.第三届北京国际水泥与混凝土会议交流材料.1993.6
[10] 蒋元駉 韩素芳. 混凝土工程病害与修补加固[M]. 海洋出版社. 1996. pp215~241
[11] D.W.Fowler.Polymers in Concrete: a Vision for the 21st Century. Cement and Concrete Composites. 1999. No.21.pp449-552
[12] 许贤敏 付庚. 国外预填骨料混凝土简介. 中外公路. 2005. No.25.pp2
[13] Polymer-based materials for repair and improved durability: Japanese experience. Construction and Building Materials. 1996, Vol.10, No.1. pp77~82
[14] Oral Buyukozturk,Oguz Gunes,Erdem Karaca. Progress on understanding debonding problems in reinforced concrete and steel members strengthened using FRP composites. Construction and Building Materials. 2004. No.18.pp9~19
[15] J.Lanas , J.I.Alvarez. Masonry repair lime-based mortars: Factors affecting the mechanical behavior. Cement and Concrete Research. 2003. No.33.pp1867~1876
[16] P.Maravelaki-Kalaitzaki, A.Bakolas, I.Karatasios, V.Kilikoglou. Hydraulic lime mortars for the restoration of historic masonry in Crete. Cement and Concrete Research 2005. No.35 .pp1577~1586
[17] D.R.Morgan. Compatibility of concrete repair materials and systems. Construction and Building Materials. 1996. Vol.10. No.1.pp57~67
[18] JamesE. Mcdonald. 混 凝 土 耐 久 性 修 补 材 料 的 选 择 工 程 建 设 中 国 三 峡 建 设2002.No.2.pp29~30
[19] Brill, L..Komlos, K..and Majzlan,B.. Early Shrinkage of Cement Paste, Mortars and Concrete. Materials and Structures. 1980. No. 13(1).
[20] M.M.Al-Zahrani,M. Maslehuddin, S.U.Al-Dulaijan, M.Ibrahim. Mechanical Properties and durability characteristics of polymer- and cement-based repair materials. Cement and Concrete Composites 2003.No.25 pp527-537
[21] K.E.Hassan, P.C.Robery, L.Al-Alawi.Effect of hot-dry environment on the intrinsic properties of repair materials. Cement & Concrete Composites 2000.No.22 .pp 453~458
[22] A.M.Vaysburd, P.H.Emmons.How to make today’s repairs durable for tomorrow-corrosion protection in concrete repair. Construction and Building Materials. 2000.No.14.pp189~197
[23] Emberson, N. K.and Mays, G.C.Significance of Property Mismatch in the Patches of Structural Concrete-Part 1 ∶ Properties of Repair Systems. Magazine of Concrete Research.1990.No.48
[24] 代 新 祥 文 梓 芸 . 水 泥 混 凝 土 路 面 损 坏 原 因 分 析 及 修 补 材 料 的 选 择 公 路 2000.No.11.pp71~76
[25] 张纯禹. 新型高性能修补材料 上海建材 2002.No.4.pp27~28
[26] 朱伯龙 刘祖华. 建筑改造工程学[M]. 上海. 同济大学出版社 1998.8.pp87~90
[27] 陈珮林. 聚合物型混凝土修补材料 PCR 研究[D]. 长安大学硕士学位论文 2000. pp1~6
[28] JTG D40-2002. 公路水泥混凝土路面设计规范 附录
[29] 陈剑雄. 高效减水剂的改良与发展 化学建材 1994. No.6.pp261~264.
[30] 徐定华. 混凝土材料学概论[M]. 中国标准出版社 2002 pp3, pp288
[31] 贾祥道. 水泥主要特性对水泥与减水剂适应性影响的研究[D]. 中国建筑材料科学研究院硕士学位论文 2002, pp1 ~pp7
[32] 王善拔. 关于水泥与超塑化剂相适应性的几个问题 水泥 2000.No.1.pp7~11
[33] 蒋家奋. 矿渣微分在水泥混凝土中应用的概述 混凝土与水泥制品 2002.No.3.pp3~6
[34] 孙振平 蒋正武. 矿渣粉大量替代水泥对高效减水剂作用的影响 建筑材料学报 2003.Vol.6.No.3.pp231~236
[35] Wenzhong. Zhu, John C. Gibbs. Use of different limestone and chalk powders in self-compacting concrete. Cement and Concrete Research. 2005.No.35.pp1457~1462
[36] Jcan Pcra,Sophic Husson,Bernard Guilhot. Influence of finely ground limestone on cement hydration. Cement and Concrete Composites. 1999.No.21. pp99~105
[37] 马保国 元萌 李宗津. 碱-矿渣水泥快速凝结的影响因素与机理研究 建筑材料学报 1999.Vol.2No2. pp99-104
[38] 蒲心诚. 超高强高性能混凝土[M]. 重庆大学出版社 2004.12.pp32
[39] コンクリ-ト便覧第二版/日本工学協会編,技報堂出版. 1996.No.2.pp.109.
[40] 陈剑雄 崔洪涛 陈寒斌 肖斐. 掺入超细石灰石粉的混凝土性能研究. 施工技术.2004.No.4.pp39-41.
[41] 蒲心诚 王勇威. 新效活性矿物掺合料与混凝土的高性能化. 混凝土. 2002.No.2. pp3-6
[42] 高 树 军 吴 其 胜 张 少 明 . 高 能 球 磨 矿 渣 的 形 貌 及 其 活 性 . 建 筑 材 料 学 报 2003.Vol.2.No.2.pp157~161
[43] 张建国. 电厂灰渣在港口工程中的应用研究与计算分析[D]. 学位论文. 天津大学.pp36~57
[44] 章春梅. 碳酸钙微集料对硅酸三钙水化的影响. 硅酸盐学报.1988.No.2.pp110~17.
[45] 张永娟 张雄. 石灰石微粉矿物外加剂性能研究. 房材与应用. 2001.Vol.29.No.4.pp34~37
[46] 张大康. 高细石灰石粉用作水泥混合材料的试验研究 水泥 2005.No.7.pp7~11
[47] J.Skalny and J.F.Young, 7th Intern. Congr. on the Chem. of Cement, Paris, 1980.Vol.ⅠⅡ-1/3
[48] 潘钢华 孙伟 丁大钧. 高强和超高强水泥基复合材料中的微集料效应的试验研究 工业建筑 1997.Vol.27.No.12.pp33~35
[49] 安 明 喆 朱 金 铨 覃 维 祖 . 高 性 能 混 凝 土 的 自 收 缩 问 题 建 筑 材 料 学 报 2001.Vol.4.No.2.pp159~166
[50] 管学茂 杨雷 姚燕. 低水灰比高性能混凝土的耐久性研究 混凝土 2004.No.10.pp3~4
[51] 宫泽伸吾 田泽荣一 佐藤刚. 钢筋约束による超高强度コンクリ—ト自己收缩应力[A].コンクリ—ト工学年次论文报告集[C].东京:日本コンクリ—ト工学协会,1993.pp57-62.
[52] 何真 陈美祝 罗谦 马保国. 高碱度水泥基材料早期开裂敏感性研究 建筑材料学报2005.Vol.8.No.2.pp121~127
[53] Jakob Wolfisberg 张量. 用于干拌砂浆产品的添加剂和可再分散聚合物粉末的作用
[54] 谢勇诚. 水泥混凝土路面超薄层快速修补技术 公路 2000.No.7.pp62~65
[55] 唐辉宇. 混凝土膨胀剂的应用 福建建材 2003.No.4.pp32~33
[56] 张向军 郑秀夫 叶青. 掺超细矿渣和膨胀剂的高性能混凝土试验研究 新型建筑材料 2004.No.7.pp20~22
[57] 王栋民 金欣 欧阳世翕. 水泥—膨胀剂—磨细矿渣复合胶凝材料膨胀与强度发展的协调性 硅酸盐学报 2002.Vol.30.No.10 增刊
[58] Emmons, P.H. A.M.Vaysburd. Factors affecting the durability of concrete repair: the contractors’ viewpoint. Construction and Building Materials. Vol.8.No.1.1994.pp5~16
[59] 赵志方. 新老混凝土粘结机理和测试方法[D]. 大连理工大学博士论文 1998.
[60] 竺亮. 新老混凝土粘结的抗拉性能研究[D]. 大连理工大学博士学位论文 2001.pp2-9
[61] 李庚英 谢慧才 熊光晶(LI Gengying,et al).新老混凝土的粘结模型及微观结构分析. 混凝土(Concrete),1999.No.6.pp 13-18
[62] 田稳苓 赵国藩. 新老混凝土的粘结机理初探 河北理工学院学报 1998.No.2.pp78~82
[63] Bickley JA, 17scio R. Repair and protection system for parking structures. ConcreteInternational, D.&C. 1988. Vol.10.No.4.pp21~28
[64] Carles-Gibergues A, Saucier F, Grande 门&Pigeon M. New-to-old concrete bonding: Influence of sulfates type of new concrete on interface nucmsttucture. Cement and Concrete Research. 1993. Vol..23.pp431~444
[65] 管大庆 陈章洪 石谧珠.界面处理对新老混凝粘结性能的影响 混凝土 1994.No.5.pp.16~22
[66] 田稳苓 赵志方 赵国藩 黄承逵. 新老混凝土的粘结机理和测试方法研究综述 1998 Vol.20.No.1.pp85~93
[67] 高剑平 潘景龙 王雨光. 检验新旧混凝土粘结强度合适的试件形 2001 Vol.34No.2pp32~34
[68] 廉慧珍 童良 陈恩义. 建筑材料物相研究基础[M]. 北京. 清华大学出版社. 1991.pp63~70
[69] 敖进涛 谢慧才 熊光晶 陈肇元. 影响新老混凝土界面粘结强度的主要因素.工程力学1997.Vol.2 增刊.pp328~333
[70] Andtea Saccani, Vittorio Magnaghi. Durability of Epoxy Resin-Based Materials for the Repair of Damaged Cementitious Composites. Cement and Concrete Research, 1999.No.1.pp95~98
[71] 熊光晶 姜浩 陈立强 刘金伟 谢慧才. 新老混凝土修补界面粘结质量的改善途径. 工业建筑. 2001.Vol31.No.11.pp70~72
[72] 何真 梁文泉 陈美祝 李宗津 马保国. 碱对水泥基材料早期收缩性能的影响. 硅酸盐学报. 2004.Vol.32.No.10.pp1293~1298
[73] 杨 医 博 文 梓 芸 . 高 效 减 水 剂 对 砂 浆 干 燥 收 缩 性 能 的 影 响 建 筑 材 料 学 报 2002.Vol.5.No.4.pp331~341
[74] 蒲心诚, 王勇威. 高效活性矿物掺料与混凝土的高性能化 混凝土 2002.No.2.pp3~6
[75] 李悦 吴科如 王胜先 张雄. 掺加混合材的水泥石自收缩特性研究 建筑材料学报 2001.Vol.4.No.1.pp7~11
[76] 阎培渝 廉慧珍 覃肖. 使用膨胀剂配制补偿混凝土时需要注意的几个问题 硅酸盐学报2000.Vol.28 增刊.pp42~45
[77] 姜正平 韩静云 张秀志. 不同养护条件下膨胀剂对水泥砂浆收缩性影响的研究 混凝土与水泥制品 2003. No.6.pp12~14
[78] 冷发光 冯乃谦. 高性能混凝土渗透性和耐久性及评价方法研究 低温建筑技术2000.No.4.pp14~16
[79] Concentration dependence of diffusion and migration of chloride ions Part 1. Theoretical considerations Luping Tang Cement and Concrete Research 1999.No.29 .pp1463~1468
[80] 李伟文 荷载作用下混凝土氯离子渗透性研究 第一部分:研究现状和研究方法 中国建材科技.2002.No.3.pp19~25
[81] 巴恒静 张武满 邓宏卫. 评价高性能混凝土耐久性综合指标-抗氯离子渗透性及其研究现状 混凝土 2006.No.3 .pp3~4
[82] 刘斯凤. 氯离子扩散测试方法演变和理论研究背景 混凝土 2002.No.10.pp21~24
[83] Rongtang Liu. Development and Evaluation of Cement-based Materials for Repair of Corrosion-Damaged Reinforced Concrete Slabs[D]. Purdue University. 2000.8. pp52~53
[84] 张德成 丁铸 侯宪钦 冯乃谦. 超细矿渣高性能混凝土试验及水化研究. 山东建材学院学报 1998.Vol.12.No.2.pp99~102
[85] 梁咏宁 袁迎曙. 硫酸盐侵蚀环境因素对混凝土性能的影响-研究现状综述 混凝土 2005.No.3.pp27~30
[86] Manu Santhanam. Sulfate attack research-whither now[J]. Cement and Concrete Research. 2001.No.31.pp845~851.
[87] 冯乃谦 各种矿物质超细粉对硫酸盐腐蚀的影响 施工技术 1995.No.10.pp42~44
[88] Omar S.Baghabra Al-Amoudi.Attack on plain and blended cements exposed to aggressive sulfate environments[J].Cement & ConcreteComposites 2002.Vol.24.pp305-316.
[89] 沈洋 许仲梓 吴承祯 唐明述. 界面区结构对水泥砂浆抗硫酸盐侵蚀性能的影响 硅酸盐学报 1996.Vol.24.No.2.pp119~124
[91] E.F.Irassar. Sulphate Resistance of Type V Cements with Limestone Filler and Natural Pozzolana. Cement & Concrete Composites. 2000.No.22.pp361-368
[92] Bertil Persson. Sulphate Resistance of Self-Compacting Concrete. Cement and Concrete Research. 2003.No.33.pp1933-1938
[2] Roland Bayer, Hermann Lutz. Ullman 工业化学百科全书第 6 版.
[3] P. H. Emmons, A. M. Vaysburd. System Concept in Design and Construction of Durable Concrete Repairs. Construction and Building Materials. 1996.Vol.10, No.1 pp69~75
[4] 李富山. 聚合物水泥修补砂浆 建筑材料 1999,No.1pp18~19
[5] Victor C.Li, H.Horii, P.Kabele, T.Kanda, Y.M.Lim. Repair and retrofit with engineered cementitious composites. Engineering Fracture Mechanics. 2000. No.65 pp317~334
[6] J.G.Cabrera, A.S. Al-Hasan. Performance properties of concrete repair materials. Construction and Building Materials. 1997. Vol. 11, No.5-6, pp283~290
[7] 许贤敏 高聚英. 国外钢筋混凝土结构修补方法简介 公路 2004. No. 4 pp61~63
[8] 汪澜. 水泥混凝土组成性能应用[M]. 北京. 中国建材工业出版社. 2005. No.1 pp486~651
[9] 王燕谋 苏慕珍. 第三系列水泥在中国.第三届北京国际水泥与混凝土会议交流材料.1993.6
[10] 蒋元駉 韩素芳. 混凝土工程病害与修补加固[M]. 海洋出版社. 1996. pp215~241
[11] D.W.Fowler.Polymers in Concrete: a Vision for the 21st Century. Cement and Concrete Composites. 1999. No.21.pp449-552
[12] 许贤敏 付庚. 国外预填骨料混凝土简介. 中外公路. 2005. No.25.pp2
[13] Polymer-based materials for repair and improved durability: Japanese experience. Construction and Building Materials. 1996, Vol.10, No.1. pp77~82
[14] Oral Buyukozturk,Oguz Gunes,Erdem Karaca. Progress on understanding debonding problems in reinforced concrete and steel members strengthened using FRP composites. Construction and Building Materials. 2004. No.18.pp9~19
[15] J.Lanas , J.I.Alvarez. Masonry repair lime-based mortars: Factors affecting the mechanical behavior. Cement and Concrete Research. 2003. No.33.pp1867~1876
[16] P.Maravelaki-Kalaitzaki, A.Bakolas, I.Karatasios, V.Kilikoglou. Hydraulic lime mortars for the restoration of historic masonry in Crete. Cement and Concrete Research 2005. No.35 .pp1577~1586
[17] D.R.Morgan. Compatibility of concrete repair materials and systems. Construction and Building Materials. 1996. Vol.10. No.1.pp57~67
[18] JamesE. Mcdonald. 混 凝 土 耐 久 性 修 补 材 料 的 选 择 工 程 建 设 中 国 三 峡 建 设2002.No.2.pp29~30
[19] Brill, L..Komlos, K..and Majzlan,B.. Early Shrinkage of Cement Paste, Mortars and Concrete. Materials and Structures. 1980. No. 13(1).
[20] M.M.Al-Zahrani,M. Maslehuddin, S.U.Al-Dulaijan, M.Ibrahim. Mechanical Properties and durability characteristics of polymer- and cement-based repair materials. Cement and Concrete Composites 2003.No.25 pp527-537
[21] K.E.Hassan, P.C.Robery, L.Al-Alawi.Effect of hot-dry environment on the intrinsic properties of repair materials. Cement & Concrete Composites 2000.No.22 .pp 453~458
[22] A.M.Vaysburd, P.H.Emmons.How to make today’s repairs durable for tomorrow-corrosion protection in concrete repair. Construction and Building Materials. 2000.No.14.pp189~197
[23] Emberson, N. K.and Mays, G.C.Significance of Property Mismatch in the Patches of Structural Concrete-Part 1 ∶ Properties of Repair Systems. Magazine of Concrete Research.1990.No.48
[24] 代 新 祥 文 梓 芸 . 水 泥 混 凝 土 路 面 损 坏 原 因 分 析 及 修 补 材 料 的 选 择 公 路 2000.No.11.pp71~76
[25] 张纯禹. 新型高性能修补材料 上海建材 2002.No.4.pp27~28
[26] 朱伯龙 刘祖华. 建筑改造工程学[M]. 上海. 同济大学出版社 1998.8.pp87~90
[27] 陈珮林. 聚合物型混凝土修补材料 PCR 研究[D]. 长安大学硕士学位论文 2000. pp1~6
[28] JTG D40-2002. 公路水泥混凝土路面设计规范 附录
[29] 陈剑雄. 高效减水剂的改良与发展 化学建材 1994. No.6.pp261~264.
[30] 徐定华. 混凝土材料学概论[M]. 中国标准出版社 2002 pp3, pp288
[31] 贾祥道. 水泥主要特性对水泥与减水剂适应性影响的研究[D]. 中国建筑材料科学研究院硕士学位论文 2002, pp1 ~pp7
[32] 王善拔. 关于水泥与超塑化剂相适应性的几个问题 水泥 2000.No.1.pp7~11
[33] 蒋家奋. 矿渣微分在水泥混凝土中应用的概述 混凝土与水泥制品 2002.No.3.pp3~6
[34] 孙振平 蒋正武. 矿渣粉大量替代水泥对高效减水剂作用的影响 建筑材料学报 2003.Vol.6.No.3.pp231~236
[35] Wenzhong. Zhu, John C. Gibbs. Use of different limestone and chalk powders in self-compacting concrete. Cement and Concrete Research. 2005.No.35.pp1457~1462
[36] Jcan Pcra,Sophic Husson,Bernard Guilhot. Influence of finely ground limestone on cement hydration. Cement and Concrete Composites. 1999.No.21. pp99~105
[37] 马保国 元萌 李宗津. 碱-矿渣水泥快速凝结的影响因素与机理研究 建筑材料学报 1999.Vol.2No2. pp99-104
[38] 蒲心诚. 超高强高性能混凝土[M]. 重庆大学出版社 2004.12.pp32
[39] コンクリ-ト便覧第二版/日本工学協会編,技報堂出版. 1996.No.2.pp.109.
[40] 陈剑雄 崔洪涛 陈寒斌 肖斐. 掺入超细石灰石粉的混凝土性能研究. 施工技术.2004.No.4.pp39-41.
[41] 蒲心诚 王勇威. 新效活性矿物掺合料与混凝土的高性能化. 混凝土. 2002.No.2. pp3-6
[42] 高 树 军 吴 其 胜 张 少 明 . 高 能 球 磨 矿 渣 的 形 貌 及 其 活 性 . 建 筑 材 料 学 报 2003.Vol.2.No.2.pp157~161
[43] 张建国. 电厂灰渣在港口工程中的应用研究与计算分析[D]. 学位论文. 天津大学.pp36~57
[44] 章春梅. 碳酸钙微集料对硅酸三钙水化的影响. 硅酸盐学报.1988.No.2.pp110~17.
[45] 张永娟 张雄. 石灰石微粉矿物外加剂性能研究. 房材与应用. 2001.Vol.29.No.4.pp34~37
[46] 张大康. 高细石灰石粉用作水泥混合材料的试验研究 水泥 2005.No.7.pp7~11
[47] J.Skalny and J.F.Young, 7th Intern. Congr. on the Chem. of Cement, Paris, 1980.Vol.ⅠⅡ-1/3
[48] 潘钢华 孙伟 丁大钧. 高强和超高强水泥基复合材料中的微集料效应的试验研究 工业建筑 1997.Vol.27.No.12.pp33~35
[49] 安 明 喆 朱 金 铨 覃 维 祖 . 高 性 能 混 凝 土 的 自 收 缩 问 题 建 筑 材 料 学 报 2001.Vol.4.No.2.pp159~166
[50] 管学茂 杨雷 姚燕. 低水灰比高性能混凝土的耐久性研究 混凝土 2004.No.10.pp3~4
[51] 宫泽伸吾 田泽荣一 佐藤刚. 钢筋约束による超高强度コンクリ—ト自己收缩应力[A].コンクリ—ト工学年次论文报告集[C].东京:日本コンクリ—ト工学协会,1993.pp57-62.
[52] 何真 陈美祝 罗谦 马保国. 高碱度水泥基材料早期开裂敏感性研究 建筑材料学报2005.Vol.8.No.2.pp121~127
[53] Jakob Wolfisberg 张量. 用于干拌砂浆产品的添加剂和可再分散聚合物粉末的作用
[54] 谢勇诚. 水泥混凝土路面超薄层快速修补技术 公路 2000.No.7.pp62~65
[55] 唐辉宇. 混凝土膨胀剂的应用 福建建材 2003.No.4.pp32~33
[56] 张向军 郑秀夫 叶青. 掺超细矿渣和膨胀剂的高性能混凝土试验研究 新型建筑材料 2004.No.7.pp20~22
[57] 王栋民 金欣 欧阳世翕. 水泥—膨胀剂—磨细矿渣复合胶凝材料膨胀与强度发展的协调性 硅酸盐学报 2002.Vol.30.No.10 增刊
[58] Emmons, P.H. A.M.Vaysburd. Factors affecting the durability of concrete repair: the contractors’ viewpoint. Construction and Building Materials. Vol.8.No.1.1994.pp5~16
[59] 赵志方. 新老混凝土粘结机理和测试方法[D]. 大连理工大学博士论文 1998.
[60] 竺亮. 新老混凝土粘结的抗拉性能研究[D]. 大连理工大学博士学位论文 2001.pp2-9
[61] 李庚英 谢慧才 熊光晶(LI Gengying,et al).新老混凝土的粘结模型及微观结构分析. 混凝土(Concrete),1999.No.6.pp 13-18
[62] 田稳苓 赵国藩. 新老混凝土的粘结机理初探 河北理工学院学报 1998.No.2.pp78~82
[63] Bickley JA, 17scio R. Repair and protection system for parking structures. ConcreteInternational, D.&C. 1988. Vol.10.No.4.pp21~28
[64] Carles-Gibergues A, Saucier F, Grande 门&Pigeon M. New-to-old concrete bonding: Influence of sulfates type of new concrete on interface nucmsttucture. Cement and Concrete Research. 1993. Vol..23.pp431~444
[65] 管大庆 陈章洪 石谧珠.界面处理对新老混凝粘结性能的影响 混凝土 1994.No.5.pp.16~22
[66] 田稳苓 赵志方 赵国藩 黄承逵. 新老混凝土的粘结机理和测试方法研究综述 1998 Vol.20.No.1.pp85~93
[67] 高剑平 潘景龙 王雨光. 检验新旧混凝土粘结强度合适的试件形 2001 Vol.34No.2pp32~34
[68] 廉慧珍 童良 陈恩义. 建筑材料物相研究基础[M]. 北京. 清华大学出版社. 1991.pp63~70
[69] 敖进涛 谢慧才 熊光晶 陈肇元. 影响新老混凝土界面粘结强度的主要因素.工程力学1997.Vol.2 增刊.pp328~333
[70] Andtea Saccani, Vittorio Magnaghi. Durability of Epoxy Resin-Based Materials for the Repair of Damaged Cementitious Composites. Cement and Concrete Research, 1999.No.1.pp95~98
[71] 熊光晶 姜浩 陈立强 刘金伟 谢慧才. 新老混凝土修补界面粘结质量的改善途径. 工业建筑. 2001.Vol31.No.11.pp70~72
[72] 何真 梁文泉 陈美祝 李宗津 马保国. 碱对水泥基材料早期收缩性能的影响. 硅酸盐学报. 2004.Vol.32.No.10.pp1293~1298
[73] 杨 医 博 文 梓 芸 . 高 效 减 水 剂 对 砂 浆 干 燥 收 缩 性 能 的 影 响 建 筑 材 料 学 报 2002.Vol.5.No.4.pp331~341
[74] 蒲心诚, 王勇威. 高效活性矿物掺料与混凝土的高性能化 混凝土 2002.No.2.pp3~6
[75] 李悦 吴科如 王胜先 张雄. 掺加混合材的水泥石自收缩特性研究 建筑材料学报 2001.Vol.4.No.1.pp7~11
[76] 阎培渝 廉慧珍 覃肖. 使用膨胀剂配制补偿混凝土时需要注意的几个问题 硅酸盐学报2000.Vol.28 增刊.pp42~45
[77] 姜正平 韩静云 张秀志. 不同养护条件下膨胀剂对水泥砂浆收缩性影响的研究 混凝土与水泥制品 2003. No.6.pp12~14
[78] 冷发光 冯乃谦. 高性能混凝土渗透性和耐久性及评价方法研究 低温建筑技术2000.No.4.pp14~16
[79] Concentration dependence of diffusion and migration of chloride ions Part 1. Theoretical considerations Luping Tang Cement and Concrete Research 1999.No.29 .pp1463~1468
[80] 李伟文 荷载作用下混凝土氯离子渗透性研究 第一部分:研究现状和研究方法 中国建材科技.2002.No.3.pp19~25
[81] 巴恒静 张武满 邓宏卫. 评价高性能混凝土耐久性综合指标-抗氯离子渗透性及其研究现状 混凝土 2006.No.3 .pp3~4
[82] 刘斯凤. 氯离子扩散测试方法演变和理论研究背景 混凝土 2002.No.10.pp21~24
[83] Rongtang Liu. Development and Evaluation of Cement-based Materials for Repair of Corrosion-Damaged Reinforced Concrete Slabs[D]. Purdue University. 2000.8. pp52~53
[84] 张德成 丁铸 侯宪钦 冯乃谦. 超细矿渣高性能混凝土试验及水化研究. 山东建材学院学报 1998.Vol.12.No.2.pp99~102
[85] 梁咏宁 袁迎曙. 硫酸盐侵蚀环境因素对混凝土性能的影响-研究现状综述 混凝土 2005.No.3.pp27~30
[86] Manu Santhanam. Sulfate attack research-whither now[J]. Cement and Concrete Research. 2001.No.31.pp845~851.
[87] 冯乃谦 各种矿物质超细粉对硫酸盐腐蚀的影响 施工技术 1995.No.10.pp42~44
[88] Omar S.Baghabra Al-Amoudi.Attack on plain and blended cements exposed to aggressive sulfate environments[J].Cement & ConcreteComposites 2002.Vol.24.pp305-316.
[89] 沈洋 许仲梓 吴承祯 唐明述. 界面区结构对水泥砂浆抗硫酸盐侵蚀性能的影响 硅酸盐学报 1996.Vol.24.No.2.pp119~124
[91] E.F.Irassar. Sulphate Resistance of Type V Cements with Limestone Filler and Natural Pozzolana. Cement & Concrete Composites. 2000.No.22.pp361-368
[92] Bertil Persson. Sulphate Resistance of Self-Compacting Concrete. Cement and Concrete Research. 2003.No.33.pp1933-1938