聚丙烯酸盐在地下水环境介质中微观变化与性能研究
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摘要
本文在查阅了大量国内外文献的基础上以聚丙烯酸盐喷膜防水材料为研究对象,着重讨论了聚丙烯酸盐的合成条件、应用、在盐碱溶液中受腐蚀情况以及发展前景等问题。本文设计了三种喷射距离喷射成膜,探讨喷射距离对成膜质量的影响。同时,进一步研究三种引发剂浓度对成膜性能的影响。
研究从防水膜的吸水性能包括吸收水溶液的能力(即吸收水溶液倍率)和吸收水溶液的速度(即吸收水溶液速率)等进行。根据水溶液的组成主要分为吸收去离子水、吸盐水等性能。因此本文设计了防水膜在去离子水中的浸泡实验。由于防水膜长期受到地下工程水环境介质的影响,可能会对防水膜性能造成影响,因此本研究模拟地下水环境,设计了防水膜在不同浓度盐碱溶液中的静态浸泡实验。根据溶胀曲线和溶胀度的测定,研究防水膜吸收不同浓度溶液的能力和吸收溶液的速度。并且观察防水膜在溶液中受腐蚀的状况。
为了研究水环境介质对防水膜性能的影响,本文对浸泡后防水膜的交联密度进行测定,从而反映出防水膜的交联结构的变化。最后采用红外,扫描电镜手段,对防水膜的微观结构进行了表征。
In this paper, a large number of domestic and foreign access to basic literature on Polyacrylate spraying membrane to waterproof material as the research object, focused on the synthesis of Polyacrylate, applications, in the saline solution by corrosion, as well as such issues as development prospects. Three types of spray distance from the film were designed to explore the quality of spray distance on the impact of film. At the same time, further study of the three initiator concentration on the film-forming properties.
Absorbent of waterproofing membranes include the ability to absorb aqueous solution (aqueous solution absorption ratio) and the absorption rate of aqueous solution (rate of speed for absorption of aqueous solution) and so on. The composition of aqueous solution is mainly divided into the absorption of distilled water, saline absorption properties. Therefore, in this article , waterproof membrane in distilled water in the immersion test is designed, and simulate the groundwater environment, the design of a waterproofing membrane at different concentrations of saline solution immersion test. According to the swelling degree of swelling curves and the determination to study the waterproof membrane solutions of different concentrations of absorption capacity and absorption rate of the solution. And observe the waterproof membrane in solution by the state of corrosion.
In order to further study the effects of groundwater environment to the waterproof membrane, this article measured waterproof membrane crosslinking density after immersion, reflecting the waterproof membrane changes in the structure of cross-linking. Finally, through Fourier transform infrared spectroscopy (FTIR) , scanning electron microscopy (SEM) , waterproof membrane on the micro-structure for further characterization to determine the salt solution of waterproof membrane material crosslinked structure.
研究从防水膜的吸水性能包括吸收水溶液的能力(即吸收水溶液倍率)和吸收水溶液的速度(即吸收水溶液速率)等进行。根据水溶液的组成主要分为吸收去离子水、吸盐水等性能。因此本文设计了防水膜在去离子水中的浸泡实验。由于防水膜长期受到地下工程水环境介质的影响,可能会对防水膜性能造成影响,因此本研究模拟地下水环境,设计了防水膜在不同浓度盐碱溶液中的静态浸泡实验。根据溶胀曲线和溶胀度的测定,研究防水膜吸收不同浓度溶液的能力和吸收溶液的速度。并且观察防水膜在溶液中受腐蚀的状况。
为了研究水环境介质对防水膜性能的影响,本文对浸泡后防水膜的交联密度进行测定,从而反映出防水膜的交联结构的变化。最后采用红外,扫描电镜手段,对防水膜的微观结构进行了表征。
In this paper, a large number of domestic and foreign access to basic literature on Polyacrylate spraying membrane to waterproof material as the research object, focused on the synthesis of Polyacrylate, applications, in the saline solution by corrosion, as well as such issues as development prospects. Three types of spray distance from the film were designed to explore the quality of spray distance on the impact of film. At the same time, further study of the three initiator concentration on the film-forming properties.
Absorbent of waterproofing membranes include the ability to absorb aqueous solution (aqueous solution absorption ratio) and the absorption rate of aqueous solution (rate of speed for absorption of aqueous solution) and so on. The composition of aqueous solution is mainly divided into the absorption of distilled water, saline absorption properties. Therefore, in this article , waterproof membrane in distilled water in the immersion test is designed, and simulate the groundwater environment, the design of a waterproofing membrane at different concentrations of saline solution immersion test. According to the swelling degree of swelling curves and the determination to study the waterproof membrane solutions of different concentrations of absorption capacity and absorption rate of the solution. And observe the waterproof membrane in solution by the state of corrosion.
In order to further study the effects of groundwater environment to the waterproof membrane, this article measured waterproof membrane crosslinking density after immersion, reflecting the waterproof membrane changes in the structure of cross-linking. Finally, through Fourier transform infrared spectroscopy (FTIR) , scanning electron microscopy (SEM) , waterproof membrane on the micro-structure for further characterization to determine the salt solution of waterproof membrane material crosslinked structure.
引文
[1]馥林编著.建筑防水材料及防水施工新技术[M],中国建筑工业出版社.1997.8
[2]Alan Pell,Yvonne Mcdonald.Tunnel Waterproofing[J].Concrete.2001
[3]Amanda Foley.Water Control-tried and Tested Products[J].Tunnels &Tunnelling International.2003
[4]Dave Hindle.Special Linings and Waterproofing[J].World Tunneling.2001
[5]池迪夫等编著,王庆修,李先瑞译.最新建筑防水设计施工手册[M].地震出版社.1992.11
[6]杨其新.隧道与地下工程水环境理论及防排水技术[M].西南交通大学(讲义).2003.9
[7]杨其新,刘东民,盛草樱.隧道与地下工程喷膜防水技术[J].铁道学报.2002.2
[8]蒋雅君.隧道工程喷膜防水系统技术及效能研究[M].西南交通大学(博士诊文).2008
[9]Ph.Rietmann,P.Zwicky.Test Methods for Sealing System[J].Tunnel.2002
[10]D.De.Vries.PEHD Seal for The Goggelsbuch Rail Tunnel[J].Tunnel.2002
[11]Dr.-ing,J.Schreyer.Seals for Monocoque Segmental Linings With Sealing Gaskets[J].Tunnel,2002
[12]J.D.Chabot.Draining Underground Tunnel[J].Tunnel.2002,(2
[13]Under Diffcult Condition in Seismically Affected Grou M.-F.Chang,S.Lemke.Taiwan High-speed Railway:Sealing Worknd[J].Tunnel.2002,(8)
[14]蒋雅君,杨其新.粘着型高分子防水层力学特征与防水效能探讨[J].新型建筑材料,2005.9
[15]刘东民,盛草樱,杨其新.隧道喷膜防水施工[J].铁道建筑技术.2003.6
[16]杨其新,刘东民,盛草樱等.用于形成防水膜层的喷射材料.专利号ZL 00120645.1
[17]盛草樱,杨其新,刘东民.膨润土对丙烯酸喷膜防水材料性能的影响[J].新型建筑材料.2004.2
[18]韩哲文.高分子科学教程[M].上海:华东理工大学出版社,2001
[19]王槐三,寇晓康.高分子化学教程[M].北京:科学出版社.2002
[20]杨其新,刘东民,盛草樱.地下工程喷膜防水材料的研究[J].新型建筑材料.2002.1
[21]杨其新,刘东民,盛草樱.喷膜防水材料设备及工艺研究[J].新型建筑材料.2003.3
[22]蒋雅君,杨其新.自粘防水卷材在隧道防水中的适应性探讨[J].新型建筑材料.2007,(2)
[23]发明人,和田节等,公开特许公报(A).平3-137182,发明名称:防水用吹膜形成法.日本株式会社鸿池组
[24]发明人.竹内雄幸.公开特许公报(A)昭61-19683发明名称:喷射剂的构成物.东亚合成化学工业株式会社研究所
[25]发明人.田俊介.公开特许公报(A)昭64-48885.发明名称:止水剂制造方法.日东化学工业株式会社中央研究所
[26]M.Breidenstein,Dr.WKeuser.Quality Assurance during the Planning and Execution of Permanent Linings for Two-shell Tunnels Produced by Shoctcreting.Tunnel.2002,(8)
[27]Peter Reina(London) & Naoaki Usui(Tokyo).Sunken tube tunnels proliferate.Engineering News-Record,Vol 223,No.2,July 13,1989
[28]http://www.UGC.com:MASTERSEAL~(?)345 sprayable membrane for undrained waterproofing of a 4m diameter bored tunnel
[29]http://www.degussa-ugc.com
[30]http://www.grace.com
[31]http://www.metflex.uk.com
[32]http://www.Stirlinglloyd.com
[33]http://ITA-aites.org
[34]Sprayed on waterproofing in San Diego.T&T North America.December 2002
[35]杨其新,刘东民,盛草樱,等.用于形成防水膜层的喷射材料:中国,ZL 00120645.1[P].2004年8月25号.
[36]袁昆.高分子水凝胶材料及吸水膨胀弹性体的制备与性能研究[M].西北师范大学(硕士学位论文)
[37]赵彦兵,陈万煜,杨亚江等 离子键交联的聚两性电解质凝胶在不同pH和不同电解质溶液中溶胀行为研究[J].高分子学报,2006,7
[38]李玲,林建明,徐玉文,吴季怀 耐盐性吸水树脂的制备及其溶胀性能的研究[J].研究与开发2006,13(1)
[39]张小红,催英德,张维刚等.聚[丙烯酸钠/2-丙烯酰胺基-2-甲基丙磺酸]/蒙脱石三元复合高吸水性树脂的合成与性能研究[J].精细石油化工2004,4
[40]赵三平,冯增国.基于丙烯酸酯封端PCL-PEG-PCL光聚合水凝胶的合成和表征[J].北京理工大学学报2002,22(6)
[41]Flory P J.Principles of polymer chemistry[M].New York:Cornell University Press,1953.20-40
[42]李国清,林建明,吴季怀.超吸水材料交联密度测定及对吸水性能的影响[J].华侨大学学报(自然科学版)2000.7,21(3)
[43]刑传波.丙烯酸型高吸水性树脂的制备及改性研究[M].山东大学(硕士学位论文)
[44]任七华.海洋环境下抗腐蚀材料开发与性能研究[M].浙江大学(硕士学位论文)
[45]刘嵩,顾广新,万震.丙烯酸系高吸水聚合物的结构表征[J].化工新型材料,2001,29(5)
[46]柳明珠,詹发禄,江洪申.超强吸水剂结构与性能研究[J].兰州大学学报(自然科学版),2003,39(3)
[47]Lin Jianming,Wu Jinhuai,Yang Zhengfan,et al.Synthesis and properties of poly-acrylic acid/mica superabsorbent nanocomposite [J].Macromolecular Rapid Communications,2001,(6)
[48]谢奕明.膨润土/聚丙烯酸钠超吸水性复合材料的合成和导电水凝胶研究.[M].华侨大学(硕士学位论文)
[49]邓芹英,刘岚,邓慧敏编著.波谱分析教程[M].科学出版社
[50]R.J.Anderson,D.J.Bendell,P.W.Groundwater 编著.唐川江 译.有机波谱分析[M].中国纺织出版社
[51]胡晖.聚N-异丙基丙烯酰胺类聚合物的合成与表征[M].西北工业大学(硕士学位论文)
[2]Alan Pell,Yvonne Mcdonald.Tunnel Waterproofing[J].Concrete.2001
[3]Amanda Foley.Water Control-tried and Tested Products[J].Tunnels &Tunnelling International.2003
[4]Dave Hindle.Special Linings and Waterproofing[J].World Tunneling.2001
[5]池迪夫等编著,王庆修,李先瑞译.最新建筑防水设计施工手册[M].地震出版社.1992.11
[6]杨其新.隧道与地下工程水环境理论及防排水技术[M].西南交通大学(讲义).2003.9
[7]杨其新,刘东民,盛草樱.隧道与地下工程喷膜防水技术[J].铁道学报.2002.2
[8]蒋雅君.隧道工程喷膜防水系统技术及效能研究[M].西南交通大学(博士诊文).2008
[9]Ph.Rietmann,P.Zwicky.Test Methods for Sealing System[J].Tunnel.2002
[10]D.De.Vries.PEHD Seal for The Goggelsbuch Rail Tunnel[J].Tunnel.2002
[11]Dr.-ing,J.Schreyer.Seals for Monocoque Segmental Linings With Sealing Gaskets[J].Tunnel,2002
[12]J.D.Chabot.Draining Underground Tunnel[J].Tunnel.2002,(2
[13]Under Diffcult Condition in Seismically Affected Grou M.-F.Chang,S.Lemke.Taiwan High-speed Railway:Sealing Worknd[J].Tunnel.2002,(8)
[14]蒋雅君,杨其新.粘着型高分子防水层力学特征与防水效能探讨[J].新型建筑材料,2005.9
[15]刘东民,盛草樱,杨其新.隧道喷膜防水施工[J].铁道建筑技术.2003.6
[16]杨其新,刘东民,盛草樱等.用于形成防水膜层的喷射材料.专利号ZL 00120645.1
[17]盛草樱,杨其新,刘东民.膨润土对丙烯酸喷膜防水材料性能的影响[J].新型建筑材料.2004.2
[18]韩哲文.高分子科学教程[M].上海:华东理工大学出版社,2001
[19]王槐三,寇晓康.高分子化学教程[M].北京:科学出版社.2002
[20]杨其新,刘东民,盛草樱.地下工程喷膜防水材料的研究[J].新型建筑材料.2002.1
[21]杨其新,刘东民,盛草樱.喷膜防水材料设备及工艺研究[J].新型建筑材料.2003.3
[22]蒋雅君,杨其新.自粘防水卷材在隧道防水中的适应性探讨[J].新型建筑材料.2007,(2)
[23]发明人,和田节等,公开特许公报(A).平3-137182,发明名称:防水用吹膜形成法.日本株式会社鸿池组
[24]发明人.竹内雄幸.公开特许公报(A)昭61-19683发明名称:喷射剂的构成物.东亚合成化学工业株式会社研究所
[25]发明人.田俊介.公开特许公报(A)昭64-48885.发明名称:止水剂制造方法.日东化学工业株式会社中央研究所
[26]M.Breidenstein,Dr.WKeuser.Quality Assurance during the Planning and Execution of Permanent Linings for Two-shell Tunnels Produced by Shoctcreting.Tunnel.2002,(8)
[27]Peter Reina(London) & Naoaki Usui(Tokyo).Sunken tube tunnels proliferate.Engineering News-Record,Vol 223,No.2,July 13,1989
[28]http://www.UGC.com:MASTERSEAL~(?)345 sprayable membrane for undrained waterproofing of a 4m diameter bored tunnel
[29]http://www.degussa-ugc.com
[30]http://www.grace.com
[31]http://www.metflex.uk.com
[32]http://www.Stirlinglloyd.com
[33]http://ITA-aites.org
[34]Sprayed on waterproofing in San Diego.T&T North America.December 2002
[35]杨其新,刘东民,盛草樱,等.用于形成防水膜层的喷射材料:中国,ZL 00120645.1[P].2004年8月25号.
[36]袁昆.高分子水凝胶材料及吸水膨胀弹性体的制备与性能研究[M].西北师范大学(硕士学位论文)
[37]赵彦兵,陈万煜,杨亚江等 离子键交联的聚两性电解质凝胶在不同pH和不同电解质溶液中溶胀行为研究[J].高分子学报,2006,7
[38]李玲,林建明,徐玉文,吴季怀 耐盐性吸水树脂的制备及其溶胀性能的研究[J].研究与开发2006,13(1)
[39]张小红,催英德,张维刚等.聚[丙烯酸钠/2-丙烯酰胺基-2-甲基丙磺酸]/蒙脱石三元复合高吸水性树脂的合成与性能研究[J].精细石油化工2004,4
[40]赵三平,冯增国.基于丙烯酸酯封端PCL-PEG-PCL光聚合水凝胶的合成和表征[J].北京理工大学学报2002,22(6)
[41]Flory P J.Principles of polymer chemistry[M].New York:Cornell University Press,1953.20-40
[42]李国清,林建明,吴季怀.超吸水材料交联密度测定及对吸水性能的影响[J].华侨大学学报(自然科学版)2000.7,21(3)
[43]刑传波.丙烯酸型高吸水性树脂的制备及改性研究[M].山东大学(硕士学位论文)
[44]任七华.海洋环境下抗腐蚀材料开发与性能研究[M].浙江大学(硕士学位论文)
[45]刘嵩,顾广新,万震.丙烯酸系高吸水聚合物的结构表征[J].化工新型材料,2001,29(5)
[46]柳明珠,詹发禄,江洪申.超强吸水剂结构与性能研究[J].兰州大学学报(自然科学版),2003,39(3)
[47]Lin Jianming,Wu Jinhuai,Yang Zhengfan,et al.Synthesis and properties of poly-acrylic acid/mica superabsorbent nanocomposite [J].Macromolecular Rapid Communications,2001,(6)
[48]谢奕明.膨润土/聚丙烯酸钠超吸水性复合材料的合成和导电水凝胶研究.[M].华侨大学(硕士学位论文)
[49]邓芹英,刘岚,邓慧敏编著.波谱分析教程[M].科学出版社
[50]R.J.Anderson,D.J.Bendell,P.W.Groundwater 编著.唐川江 译.有机波谱分析[M].中国纺织出版社
[51]胡晖.聚N-异丙基丙烯酰胺类聚合物的合成与表征[M].西北工业大学(硕士学位论文)