煤层气吸附解吸机理研究
|
摘要
煤层气在煤基吸附剂上的解吸机理是当前煤层气开采面临的核心问题之一。鉴于当前国内外对解吸作用理论研究的缺乏,确定论文研究内容:
(1)通过当前吸附设备的调研,设计、制造、检验、使用大样量煤层气吸附解吸仿真实验仪;
(2)通过大样量煤层气吸附解吸实验,获得我国主要的煤层气勘探开发地区煤的吸附解吸数据;
(3)对实验数据进行数学分析、拟合,归纳可信度较高的吸附解吸数学模型;
(4)对吸附质、吸附剂及其界面特征进行分析,利用物理化学的基础理论,推导可以反映煤层气吸附解吸过程的数学模型。对建立的数学模型进行检验分析,对模型中的参数进行分析、物理意义核定。
研究结论:
(1)煤层气的解吸过程与吸附过程不可逆。
(2)煤层气的吸附曲线、解吸曲线皆为Brunauer吸附等温线的Ⅰ型。利用SPSS对实验数据拟合较好(R2≥0.9)的数学式有Langmuir方程、指数函数、对数函数、Weibull函数,其中Weibull函数拟合的可信度最高(R2≥0.99),相对误差较小(Δ<0.5%)。
(3)以Lenard-Jones介质表面势函数分布分析入手,引入覆盖度θ函数。确立多孔型固体吸附剂(煤)与吸附质(CH4)的作用强度由半孔宽度r决定,煤的表面能量分布非对称,服从Weibull函数,推导获得吸附、解吸作用的数学模型:V = V0 ?[1?exp(?bPq)]。
(4)根据引起Weibull函数模型中吸附焓(b)的变化因素,将解吸作用进行初步分类:降压解吸、置换解吸、扩散解吸、升温解吸、电磁场诱发解吸等。
(5)确立煤层气的解吸量与吸附量无关。煤层气的解吸量与压力关系可用相应的数学表达式描述;
(6)对煤层气采收率进行分析后认为:煤层气的采收率仅与解吸过程的吸附热有关,与其他因素无关。
The desorption mechanism of Coal bed methane (CBM) in coal-based adsorbents is one of the critical problems in today’s exploitation of CBM. In view of the lack of theoretical research on desorption home and abroad, the research includes the following several main aspects:
1. Based on a survey of the available adsorption equipment, a simulated super-weight equipment of adsorption and desorption is designed, manufactured, tested and used;
2. Through super-weight experiments on absorption and desorption of CBM, data of absorption and desorption of the coal in the major CBM exploitation areas in our country are collected;
3. Through mathematical analysis,and the fitting of the experimental data, reliable mathematical models of absorption and desorption are derived;
4. Through the analysis of adsorbate, sorbent and their interface features, mathematical models reflecting the process of the adsorption and desorption of CBM are derived, using the fundamental theories of physical chemistry, and the established models are checked, the parameters are analyzed and confirmed in terms of physical significance.
Conclusions:
1. The processes of adsorption and desorption of CBM are irreversible. The process of desorption lags behind that of adsorption;
2. The adsorption and desorption curves of CBM are all of ModelⅠof Brunauer adsorption isotherm. The mathematical expressions that fit well into the experimental results(R2≥0.9) include Langmuir equation, exponential function, logarithmic function,and Weibull function, among which Weibull function is of the highest fitting degree(R2≥0.99)with the smallest relative error (Δ<0.5%);
3. Based on the analysis of the Lenard-Jones potential function of medium surface and the use of coverageθfunction, it is established that the intensity of the porous solid sorbent(coal) and the adsorbate(CH4) is determined by the scale of molecules (The width of half pore is r),and that the surface energy distribution of coal, in agreement with Weibull function, is unsymmetrical, thus the mathematical models of adsorption and desorption are derived: V = V0 ?[1?exp(?bPq)] V0 = the largest adsorption amount b= change of adsorption heat q= the unsymmetry of pores
4. According to the change factors of adsorption enthalpy (b)in Weibull function model, the desorption is classified into decompression desorption, metathesis desorption, pervasion desorption, heating-up desorption and electromagnetically induced desorption, etc.;
5. It is confirmed that desorption amount and adsorption amount of CBM are not interrelated. The relation between desorption amount and pressure can be formulated by mathematical expressions;
6. Based on the analysis of the CBM exploitation rate, it is concluded that the rate is solely determined by adsorption heat in desorption process.
(1)通过当前吸附设备的调研,设计、制造、检验、使用大样量煤层气吸附解吸仿真实验仪;
(2)通过大样量煤层气吸附解吸实验,获得我国主要的煤层气勘探开发地区煤的吸附解吸数据;
(3)对实验数据进行数学分析、拟合,归纳可信度较高的吸附解吸数学模型;
(4)对吸附质、吸附剂及其界面特征进行分析,利用物理化学的基础理论,推导可以反映煤层气吸附解吸过程的数学模型。对建立的数学模型进行检验分析,对模型中的参数进行分析、物理意义核定。
研究结论:
(1)煤层气的解吸过程与吸附过程不可逆。
(2)煤层气的吸附曲线、解吸曲线皆为Brunauer吸附等温线的Ⅰ型。利用SPSS对实验数据拟合较好(R2≥0.9)的数学式有Langmuir方程、指数函数、对数函数、Weibull函数,其中Weibull函数拟合的可信度最高(R2≥0.99),相对误差较小(Δ<0.5%)。
(3)以Lenard-Jones介质表面势函数分布分析入手,引入覆盖度θ函数。确立多孔型固体吸附剂(煤)与吸附质(CH4)的作用强度由半孔宽度r决定,煤的表面能量分布非对称,服从Weibull函数,推导获得吸附、解吸作用的数学模型:V = V0 ?[1?exp(?bPq)]。
(4)根据引起Weibull函数模型中吸附焓(b)的变化因素,将解吸作用进行初步分类:降压解吸、置换解吸、扩散解吸、升温解吸、电磁场诱发解吸等。
(5)确立煤层气的解吸量与吸附量无关。煤层气的解吸量与压力关系可用相应的数学表达式描述;
(6)对煤层气采收率进行分析后认为:煤层气的采收率仅与解吸过程的吸附热有关,与其他因素无关。
The desorption mechanism of Coal bed methane (CBM) in coal-based adsorbents is one of the critical problems in today’s exploitation of CBM. In view of the lack of theoretical research on desorption home and abroad, the research includes the following several main aspects:
1. Based on a survey of the available adsorption equipment, a simulated super-weight equipment of adsorption and desorption is designed, manufactured, tested and used;
2. Through super-weight experiments on absorption and desorption of CBM, data of absorption and desorption of the coal in the major CBM exploitation areas in our country are collected;
3. Through mathematical analysis,and the fitting of the experimental data, reliable mathematical models of absorption and desorption are derived;
4. Through the analysis of adsorbate, sorbent and their interface features, mathematical models reflecting the process of the adsorption and desorption of CBM are derived, using the fundamental theories of physical chemistry, and the established models are checked, the parameters are analyzed and confirmed in terms of physical significance.
Conclusions:
1. The processes of adsorption and desorption of CBM are irreversible. The process of desorption lags behind that of adsorption;
2. The adsorption and desorption curves of CBM are all of ModelⅠof Brunauer adsorption isotherm. The mathematical expressions that fit well into the experimental results(R2≥0.9) include Langmuir equation, exponential function, logarithmic function,and Weibull function, among which Weibull function is of the highest fitting degree(R2≥0.99)with the smallest relative error (Δ<0.5%);
3. Based on the analysis of the Lenard-Jones potential function of medium surface and the use of coverageθfunction, it is established that the intensity of the porous solid sorbent(coal) and the adsorbate(CH4) is determined by the scale of molecules (The width of half pore is r),and that the surface energy distribution of coal, in agreement with Weibull function, is unsymmetrical, thus the mathematical models of adsorption and desorption are derived: V = V0 ?[1?exp(?bPq)] V0 = the largest adsorption amount b= change of adsorption heat q= the unsymmetry of pores
4. According to the change factors of adsorption enthalpy (b)in Weibull function model, the desorption is classified into decompression desorption, metathesis desorption, pervasion desorption, heating-up desorption and electromagnetically induced desorption, etc.;
5. It is confirmed that desorption amount and adsorption amount of CBM are not interrelated. The relation between desorption amount and pressure can be formulated by mathematical expressions;
6. Based on the analysis of the CBM exploitation rate, it is concluded that the rate is solely determined by adsorption heat in desorption process.
引文
[1] 赵庆波,刘兵.世界煤层气工业发展现状[M] .北京: 地质出版社,1998.
[2] 孙茂远,朱超.国外煤层气开发特点及鼓励政策[J].中国煤炭,2001,27(2):55-58.
[3] 张全国.国内外煤层气的开发与进展[J] .中国沼气,1999,17(2):42-44.
[4] 叶建平,秦勇,林大扬主编.中国煤层气资源[M].江苏徐州:中国矿业大学出版社,1998.
[5] 钱凯,赵庆波,汪泽成,等.煤层甲烷气勘探开发理论与实验测试技术[M].北京:石油工业出版社,1997.
[6] 孙茂远,黄盛初.煤层气开发利用手册[M].北京:煤炭工业出版社,1998.
[7] 王慎言.煤层气将成为中国新的“接替能源”[J] .中国煤层气,1996,(1):15.
[8] 陈永武,胡爱梅.中国煤层气产业形成和发展面临的机遇与挑战[J] .天然气工业,2000,20(4):19-23.
[9] 鲜学福.我国煤层气开采利用现状及其产业化展望[J].重庆大学学报(自然科学版),2000,23(增刊):1-5.
[10] 张艳玉,魏晓霞.煤层气开采技术与发展趋势[J] .河南石油,2001,15(2):24-27.
[11] 徐永昌.天然气成因理论及应用[M].北京:科学出版社,1994:189-223.
[12] 李宝芳.煤层气及生储原理略述(第一讲)[J] .中国煤田地质,1996,8(1):89-94.
[13] 余申翰.煤层内瓦斯的赋存状态.煤炭学报,1981,(2): 1-4.
[14] 陈昌国,鲜晓红,张代钧等.微孔填充理论研究无烟煤和炭对甲烷的吸附特性.重庆大学学报,1998,21(2);75 -79
[15] 赵志根,唐修义;对煤吸附甲烷的 Langmuir 方程的讨论.焦作工学院学报,2002,21(1):1-4.
[16] 张晓东,秦勇,桑树勋.煤储层吸附气体研究现状及展望[J].中国煤田地质,2005,17(1):16-22.
[17] 张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J].煤炭学报,1999,24 (6):300-570.
[18] 叶振华,化工吸附分离过程,北京:中国石化出版社,1992:4-6
[19] 叶振华,吸着分离过程基础,北京:化学工业出版社,1988:9-10
[20] 古共伟,陈健,魏玺群,吸附分离技术在现代工业中的应用,合成化学,1999,7(4):346-353
[21] 傅国旗,天然气吸附存储的研究[博士学位论文],天津:天津大学,2001
[22] 陈海华,在湿活性炭上存储甲烷的充放气过程研究[硕士学位论文],天津:天津大学,2002
[23] 严继民,张启元,高敬琮,吸附与凝聚:固体的表面与孔,北京:科学出版社,1986:2-3
[24] 孙艳,储气材料及其储能性质的实验研究[硕士学位论文],天津:天津大学,2001
[25] 周亚平,杨斌,气体超临界吸附研究进展,化学通报,2000,63(9):8-13
[26] 杨斌,气体跨越临界温度吸附行为研究[硕士学位论文],天津:天津大学,2000
[27] 顾惕人,朱瑶,李外郎等,表面化学,北京:科学出版社,1994:275-277
[28] 严继民,张启元,吸附与凝聚:固体的表面与孔,北京:科学出版社,1979:24-55
[29] 白书培,临界温度附近 CO2 在多孔固体上吸附行为的研究[博士学位论文],天津:天津大学,2002
[30] 周亚平,周理,超临界氢在活性炭上的吸附等温线研究,物理化学学报,1997,13(2):119-127
[31] 杨俊,大温度范围内氧在活性炭上的吸附平衡研究[硕士学位论文],天津:天津大学,2003
[32] Moffat D H,Weale K E. Sorption by coal of methane at high pressure.[J].Fuel,34,1955:417-428.
[33] Yang R T,Saunders J T. Adsorption of gases on coals and heat-treated coals at elevated tempreature and pressure[J].Fuel,1985:314-327.
[34] Joubert J 1,Grein C T,Bienatock D. Sorption of methane in moist coal. Fuel,1973,52:181~185.
[35] Ruthven D.M.,Past Progress and Future Challenges in Adsorption Research,Ind.Eng.Chem.Res.,2000,39(7):2127-2131
[36] Ruthven D.M.,Farooq S.,Knabel K.S.,Pressure Swing Adsorption,New York:VCH Publishers,1994:5-7
[37] Mota J.P.B.,Rodrigues A.E.,et al.,Dynamic of Natural Gas Adsorption
[38] Storage System Employing Activated Carbon,Carbon,1997,35(9):1259-1270
[39] Wang,K.,Do,D.D.Single and Multicomponent Adsorption Equilibria of Hydrocarbons on
[40] Activated Carbon:The Role of Micropore size Distribution,Surfactant Sci.Ser.,1999,78,391-441
[41] Hu X.,Multicomponent Adsorption Equilibrium of Gases in Zeolite:Effect of Pore Size
[42] Distribution.Chem.Eng.Commun.,1999,174(1):201-214
[43] IUPAC“Definitions,Terminology and Symbols in Colloid and Surface Chemistry,PartⅠ”,Pure and Appl.Chem.,1972,41(4):597-638
[44] H.F.Stoeckli,A Generalization of the Dubinin-Radushkevich Equation for fillingof Heterogeneous Micropore Systems,J.Colloid Interface Sci.,1977,59(1):184-185
[45] P.G.Menon,Adsorption at High Pressure,Chemical Review,1968,68(3):277-294
[46] F.Rouquerol,J.Rouqerol,K.Sing,Adsorption by Powders and Porous solids,London:Academic Press,1999
[47] T.K.Bose,R.Chahine,L.Machildon,New Dielectric Method for Measurement of Physical Adsorption of Gases at High Pressure , Rev.Sci.Instrum. , 1987 , 58(12):2279-2283
[48] Zhou li,Su wei,Sun Yan,et al,Supercritical Adsorption:Challenges in Theory,Analysis and Modeling.Guan Yixin,Yao Shanjing,Zhu Ziqiang,eds,Proceeding of CKCSST’2001,Hangzhou:China,2001,379-384
[49] L Zhou,Yaping Zhou,Ming Li,Ping Chen,Yu Wang,Experimental and Modeling Study of the Adsorption of Supercritical Methane on a High Surface Activated Carbon,Langmuir,2000,16(14):5955-5959
[50] G.H.Findenegg.High Pressure Physical Adsorption of Gases on Homogeneous Surfaces,Fundamental of Adsorption,Schloas Elmau,Bavaria,West Germany,1983:207-218.
[51] Li Zhou,Sh.P.Bai,Y.P.Zhou,B.Yang,Adsorption of Nitrogen on Silica Gel over a Large Range of Temperature,Adsorption,2002,8(1):79-87
[52] Li Zhou,Y.P.Zhou,Sh.P.Bai,B.Yang,Studies on the Transition Behavior of Physical Adsorption from the Sub-to the Superritical Region:Experimentals onSilica Gel.J.of Colloid and Interface Science.2002,253(1):9-15.
[53] Keller J.U.,Dreisbach F.,Rave H.,Staudt R.,Tomalla M.,Measurements of Gas Mixture Adsorption Equilibria of Natural Gas Compounds on Microporous Sorbents,Adsorption,1999,5(3):199-214
[54] Dreisbach F.,Staudt R.,Keller J.U.,High Pressure Adsorption Data of Methane,Nitrogen,Carbon Dioxide and their Binary and Ternary Mixtures on Activated Carbon,Adsorption,1999,5(3):215-227
[55] Malek A.,Farooq S.,Comparison of Isotherm Models for Hydrocarbon Adsorption on Activated Carbon,AIChE.Journal,1996,42(11):3191-3201
[56] Ahmadpour A.,Wang K.,Do D.D.,Comparison of Models on the Prediction of Binary Equilibrium Data of Activated Carbons,AIChE.Journal,1998,44(3):740-752
[57] Grant R.J.,Manes M.,Adsorption of Binary Hydrocarbon Gas Mixtures on Activated Carbon,Ind.Eng.Chem.Fund.,1966,5(4):490-498
[58] Friekerich R.O.,Mullins J.C.,Adsorption equilibria of binary hydrocarbon mixtures on homogeneous carbon black at 25℃,Ind.Eng.Chem.Fundam.,1972,11(4):439-445
[59] Siddiqi K.S.,Thomas W.J.,The Adsorption of Methane-Ethane Mixtures on Activated Carbon,Carbon,1982,20(6):473-479
[60] Tondeur D.,Kabir H.,Luo L.A.,Grander J.,Multicomponent Adsorption Equilibria from Impulse Response Chromatography,Chem.Eng.Sci.,1996,51(15):3781-3799
[61] .Haydel J.J.,Kobayashi R.,Adsorption equilibrium in the methane-propane-silica gel system at high pressures,Ind.Eng.Chem.Fundam.,1967,6(4):546-554
[62] Reich R.,Ziegier W.T.,Rogers K.A.,Adsorption of Methane,Ethane,and Ethylene Gases and Their Binary and Ternary Mixtures and Carbon Dioxide on Activated Carbon at 212-301K and Pressures to 35 Atmospheres,Ind.Eng. Chem.Process Des.Dev.,1980,19(3):336-344
[63] Talu O.,Zweibel I.,Multicomponent Adsorption Equilibria of Nonideal Mixtures,AIChE.Journal,1986,32(8):1263-1276
[64] Gusev V.,O'Brien J.A.,Jensen C.R.C.,Seaton N.A.,Theory for Multicomponent Adsorption Equilibrium:Multispace Adsorption Model,AIChE.Journal,1996,42(10):2773-2783
[65] Carlson N.W.,Dranoff J.S.,On the Adsorption of Ethane by 4A Zeolite Pellets,Ind.Eng.Chem.Process Des.Dev.,1985,24(4):1300-1302
[66] Do D.D.,Wang K.,A New Model for the Description of adsorption Kinetics in Heterogeneous Activated Carbon,Carbon,1998,36(6):1539-1554
[67] Hu X.,Do D.D.,Role of Energy Distribution in Multicomponent Sorption Kinetics in Bidispersed Solids,AIChE Journal,1993,39(10):1628-1640
[68] Hu X.,G.N.Rao,Do D.D.,Effect of Energy Distribution on Sorption Kinetics in Bidispersed Paricles,AIChE J.,1993,39(2):249-261
[69] Mayfield P.L.J.,Do D.D.,Measurement of the Single-Component Adsorption Kinetics of Ethane,Butane,and Pentane onto Activated Carbon Using a Differential Adsorption Bed,Ind.Eng.Chem.Res.,1991,30(6):1262-1270
[70] O.Kadlec,The History and Present State of Dubinin’s Theory of Adsorption of Vapous and Gases on Microporous Solids,Adsorption Science and Technology,2001,19(1):1-28
[71] D.M.Ruthven,Principles of Adsorption and Adsorption Processes,New York:John Wiley&Sons,1984:65-70
[72] S.Ozawa,S.Kusumi,Y.Ogino,Physical Adsorption of Gases at High PressureⅣAnImprovement of the Dubinin-Astakhov Adsorption Equation,J.of Colloidand interface Science,1976,56(1):83-91.
[73] R.K.Agarwal,J.A.Schwarz,Analysis of High Pressure Adsorption of Gases on Activated Carbon by Potential Theory,Carbon,1988,26(2):873-887.
[74] K.A.G..Amankwah,J.A.Schwarz,A Modified Approach for Estimating Pesudo-Vapor Pressures in the Application of the Dubinin-Astakhov Equation,Carbon,1995,33(9):1313-1319.
[75] Zhou Y.and L.Zhou,Experimental Study on High-Pressure Adsorption of Hydrogen on Activated Carbon,Science in China(Series B),1996,39(6):598-607
[76] 52.Zhou Li,Li Ming,and Zhou Yaping,Measurement and Theoretical Analysis of the
[77] Adsorption of Supercritical Methane on Superactivated Carbon,Science in China (Series B),2000,43(2):143-153
[78] Li Zhou,Yaping Zhou,Shupei Bai,Changzhong Lü,Bin Yang,Determination of the Adsorption Phase Volume and Its Application in Isotherm Modeling for the Adsorption of Supercritical Nitrogen on Activated Carbon,Journal of Colloid and Interface Science,2001,239(1):33-38
[79] Zhou Yaping,Bai Shupei,Zhou Li,Yang Bin,Studies on the physical adsorption equilibria of gases on porous solids over a wide temperature range spanning the critical region-adsorption on microporous activated carbon,Chinese Journal of Chemistry,2001,19(10):943-948
[80] Li Zhou,Yaping Zhou,A Comprehensive Model for the Adsorption of Supercritical Hydrogen on Activated Carbon,Ind.Eng.Chem.Res.,1996,35(11):4166-4168
[81] Li Zhou,Yaping Zhou,Linearization of Adsorption Isotherms for High-Pressure Applications,Chemical Engineering Science,1998,53(14):2531-2536
[82] .Zhou Li,Zhou Yaping,A Mathematical Method for Determination of Absolute Adsorption from Experimental Isotherms of Supercritical Gases , Chinese J.of Chem.Eng.,2001,9(1):110-115
[83] L.Zhou,P.Chen,M.Li,Y.Sun,Y.Zhou,Prying the nature of supercritical adsorption via isotherm space transformations,edited Duong D Do,Proceeding of the second pacific basin conference on adsorption science and technology,Australia,World Scientific Publishing Co.,2000,717-721
[84] L Zhou,Yaping Zhou,Ming Li,Ping Chen,Yu Wang,Experimental and Modeling Study of the Adsorption of Supercritical Methane on a High Surface Activated Carbon,Langmuir,2000,16(14):5955-5959
[85] 周理,吕昌忠,王怡林,姚金花,王瑜,述评超临界温度气体在多孔固体上的物理吸附,化学进展,1999,11(3):221-226
[86] 周理,吴芹,周亚平,孙艳,论高压吸附的边界与气体的吸附存储,中国太阳能学会 2001 年学术会议,231-235
[87] 周理,超临界吸附研究:疑惑、问题与分析,第四届全国氢能学术会议论文集,155-162
[88] 杨向平,李阳初,沈复,能量不均匀固体表面上多元非理想溶液的吸附等温线模型,化工学报,1998,49(2):155-161
[89] 刘晓勤,姚虎卿,时钧,二元液体混合物非理想吸附平衡数据的预测,化工学报,2002,53(4):412-417
[90] 居沈贵,刘晓勤,马正飞,姚虎卿,时钧,含 CO 体系在载铜吸附剂上的吸附平衡,南京化工大学学报,1998,20(3):79-82
[91] 韩振为,周明,用晶格模型预测多组元固液界面上的吸附平衡,化工学报,1996,47(1):1-7
[92] 胡英,近代化工热力学—应用研究的新进展,上海:上海科学技术文献出版社,1994,261-268
[93] 李明,含有超临界组分的多元气/固吸附平衡研究[博士学位论文],天津:天津大学,2001
[94] 蒋维钧,雷良恒,刘茂林,化工原理(下册),北京:清华大学出版社 1993,552-557
[95] 吴芹,多组分超临界气体混合物在多孔固体上吸附平衡的研究[博士学位论文],天津:天津大学,2003
[96] 熊洪允,曾绍标,毛云英,应用数学基础,天津:天津大学出版社,1994
[97] J.A.Dean(美)主编,兰氏化学手册,尚久方,操时杰等译,北京:科学出版社,1991
[98] 郭天民,多元汽液平衡和精馏,北京:化学工业出版社,1983:250-256
[99] 张遂安.有关煤层气开采过程中煤层气解吸作用类型的探索.中国煤层气,2004,1(1):26-29
[100] 傅雪海,秦勇,叶建平,等.中国部分煤储层解吸特性及甲烷采收率.煤田地质与勘探,2000,28(2):19-22
[101] 李小彦等.煤储层吸附时间参数变化及影响因素[J].天然气地球科学,2003,14(6):502-505
[102] 关平,伍天洪.热成因甲烷同位素分布的形成机制.沉积学报,2003,21(1):175-182
[103] 陈践发,李春园,沈平,等.煤型气烃类组分的稳定碳、氢同位素组成研究.沉积学报,1995,13(2):59-69.
[104] 程克明,熊英,J M Moldowan,等.吐哈盆地煤成烃研究新进展.沉积学报,2002,20(3):456-461
[105] 刘文汇,宋岩,刘全有,等.煤岩及其主显微组份热解气碳同位素组成的演化.沉积学报,2003,21(1):183-190
[106] 张同伟,陈践发,王先彬,等.天然气运移的气体同位素地球化学示踪.沉积学报,1995,13(2):70-76.
[107] 徐永昌,刘文汇,沈平.含油气盆地油气同位素地球化学研究概述.沉积学报,2001,19(2):161-16873
[108] 戴金星.中国煤成气研究二十年的重大进展.石油勘探与开发,1999,26(3):1-10
[109] 戴金星,裴锡古,戚厚发.中国天然气地质学(卷一).北京:石油工业出版社,1992
[110] 戴金星.鉴别煤成气和油型气若干指标的初步探讨.石油学报,1995,16(2):31-38
[111] 徐永昌,沈平.中国化石燃料同位素地球化学.中国科学,B 辑,1991,(4):409-418
[112] 沈平等.气源岩和天然气地球化学特征及成烃机理研究.兰州:甘肃科学技术出版社,1991
[113] 傅家谟.煤成烃地球化学.北京:科学出版社,1990
[114] 张义纲.天然气的生成聚集和保存.南京:河海大学出版社,1991
[115] 黄第藩,熊传武,杨俊杰,等.鄂尔多斯盆地中部大气田的气源判识.科学通报,1996,41(17):1588-1592
[116] 刘文汇,徐永昌.煤型气碳同位素演化二阶段分馏模式及机理.地球化学.1999,28(4):359-366
[117] 钱凯,赵庆波,汪泽成,等编著.煤层甲烷气勘探开发理论与实验测试技术[Ml.北京:石油上业出版社,1996
[118] Stahl W J.Geochemische daten nordwest-deutscher Oberkarbon,Zechstein und Buntsandsteingase.Erdoel und Kohle-Erdgas-Petrochemie,1979,32(Heftz):74 65-70
[119] Scott A R.Composition and origin of coalbed gases from selected basins in the United States , Proceeding of the 1993 International Coalbed Methane Symposium.Birmingham,Alabama,1993
[120] 李晶莹,陶明信.国际煤层气组成和成因研究.地球科学进展,1998,13(5):467-473
[121] 张建博,陶明信.煤层甲烷碳同位素在煤层气勘探中的地质意义——以沁水盆地为例.沉积学报,2000,18(4):611-614
[122] 胡国艺,刘顺生,李景明,等.沁水盆地晋城地区煤层气成因.石油与天然气地质,2001,22(4):319-321
[123] 王彦龙,解光新,张培元.沁水盆地煤层气同位素特征及成因类型初探.煤田地质与勘探,2005,33(1):32-34
[124] 刘冬梅,张玉贵,唐修义.煤层气中甲烷δ13C 值偏轻的机理探讨.焦作工学院学报,1997,16(2):89-94
[125] 秦勇,唐修义,叶建平.华北上古生界煤层甲烷稳定碳同位素组成与煤层气解吸—扩散效应.高校地质学报,1998,4(2):127-132
[126] 秦勇,唐修义,叶建平,等.中国煤层甲烷稳定碳同位素分布与成因探讨.中国矿业大学学报,2000,29(2):113-119
[127] 李明潮,张伍剂.中国主要煤田浅层煤成气.北京:科学出版社,1990.
[128] 吴俊.中国煤成烃基本理论与实践.北京:煤炭工业出版社,1994
[129] 冯福铠,王廷斌,张士亚,等.中国天然气地质.北京:地质出版社,1995
[130] 戴金星,戚厚发,宋岩.我国煤层气组分、碳同位素类型及其成因意义.中国科学(B 辑),1986,(12):1317-1326
[131] 秦胜飞,宋岩,唐修义,等.水动力对煤层甲烷碳同位素的影响.天然气工业,2005,25(11):30-32
[132] 陶明信,徐永昌,陈践发,等.中国煤型气区的构造环境、典型气藏及勘探方向—上古生界煤型气.沉积学报,1998,16(3):25-30
[133] 段玉成.我国煤的稳定同位素组成特征.煤田地质与勘探,1995,23(1):29-3575
[134] 张建博.沁水盆地南部煤层气藏水文地质特征.煤田地质与勘探,2001,29(5):33-37 中国煤田地质总局.中国煤层气资源[M].北京:中国矿业大学出版社,1998
[135] 张新民,庄军,张遂安.中国煤层气地质与资源评价[M].北京:科学出版社,2002
[136] 苏现波,陈江峰,孙俊民,等.煤层气地质学与勘探开发[M].北京:科学出版社,2001
[137] 黄景城.煤层甲烷开采概述[Al.见:煤层气译文集[C].郑州:河南科技出版社.1990
[138] 蔡炳心.基础物理化学[M].北京:科学出版社,2001
[139] 陈昌国.煤的物理化学结构和吸附(解吸)机理的研究[D].重庆:重庆大学.1995
[140] Yang R T Saunders J T.Adsorption of gases on coals and head-treated coals at elevated tempreature and pressure.[J].Fue1,1985
[141] 陈宗淇,王光信,徐桂英,编.胶体与界面化学[M].北京:高等教育出版社.2001
[142] M.Jaroniec,R Madey.非均匀固体上的物理吸附[M].加璐译.北京:化学工业出版社.2000
[143] 刘常洪,杨思敬.关于煤甲烷吸附体系吸附规律的研究[J].煤矿安全,1992,(4):1-5
[144] Crosdale P J,Beamish B B,Valix M.Coalbed methane sorption related to coal compostion[J].International,Journal of Geology,1998,35:147 一 158
[145] 赵志根,唐修义.对煤吸附甲烷的 Langmuir 方程的讨论[J].焦作工学院学报,2002,21(1):1-4
[146] 陈昌国,鲜晓红,张代钧,等.微孔填充理论研究无烟煤和炭对甲烷的吸附特性[J].重庆大学学报,1998,21(2):75-79
[147] 艾鲁尼 A T.煤矿瓦斯动力现象的预测和预防[M].唐修义,等译.北京:煤炭工业出版社.1992
[148] 霍多特 B B.煤与瓦斯突出[M].宋世钊,等译.北京:中国上业出版社.1996.76
[149] 陈萍,唐修义.低温氮吸附法与煤中微孔隙特征的研究[J].煤炭学报,2001,26(5):552-556
[150] 桑树勋,秦勇,郭晓波,等.准噶尔和吐哈盆地侏罗系煤层气特征[J].高校地质学报,2003,9(3):365-371
[151] 傅雪海,秦勇,李贵中,等.特高煤级煤平衡水条件下的吸附实验[J].石油实验地质,2002,24(2):177-180
[152] 秦勇,傅雪海,叶建平,等.中国煤储层岩石物理学因素控气特征及机理[J].中国矿业大学学报,1999,28(1):14-19
[153] Ettinger I,Zimakov B,Yanovskaya.Natural factors influencing coal sorption properties-petrography and the sorption properties of coals[J].Fuel , 1996 ,(45):243-259
[154] 傅雪海,秦勇.多相介质煤层气储层渗透率预测理论与方法[M].徐州:中国矿业大学出版社,2003
[155] 张新民,庄军,张遂安 . 中国煤层气地质与资源评价 [M]. 科学技术出版社.2002:38-46
[156] 桑树勋,朱炎铭,张井.煤层气储集与三态动平衡[A].见:宋岩,张新民.煤层气研究新进展[C].北京:科学出版社,2004
[157] 唐书恒.晋城地区煤储层特征及多元气体的吸附一解吸特征.[D].徐州:中国矿业大学,2001
[158] 张力,何学秋,王恩兀,等.煤吸附特性的研究[F].太原理工大学学报,2001,32(4):449-451
[159] 霍永忠.煤储层的气体解吸特性研究.天然气工业,2004,24(5):24～26
[160] 刘洪林,王红岩,张建博.煤层气吸附时间计算及其影响因素分析.石油实验地质,2000,22(4):365-368
[161] 李小彦,司胜利.我国煤储层煤层气解吸特征.煤田地质与勘探,2004,32(3):27-29
[162] 张彦平.国外煤层气开发技术译文集[C].北京:石油工业出版社,1996
[163] 许卫,崔庆田,颜明友,等.煤层甲烷气勘探开发工艺技术进展[M].北京:石油工业出版社,2001
[164] 曹成润,牛伟,张遂安,等.煤层气在煤储层中的扩散及其影响因素.世界地质,2004:23(3):266-270
[165] 张力,何学秋,李侯全.煤层气渗流方程数值模拟「J].天然气工业,2002,22(1):23-26
[166] 吴世跃,郭勇义.煤层气运移特征的研究「J].煤炭学报,1999.24(1):65-69
[167] 卢双舫,付广,工朋岩,等.天然气富集主控因素的定量研究「M」.北京:石油工业出版社,2002
[168] 赵孟军,宋岩,苏现波。决定煤层气地球化学特征的关键地质时期.天然气工业,2005,25(1):51～54
[169] 高波,陶明信,张建博,等.煤层气甲烷碳同位素的分布特征与控制因素.煤田地质与勘探.2002,30(3):14-17
[170] 刘洪林,王红岩,赵国良,等.稳定碳同位素δ13C1 在煤层气田勘探中的应用.西安科技大学学报.2004,24(4):442-447
[171] 张殿伟,刘文汇,刘全有,等.煤系源岩显微组分对天然气碳同位素组成影响的应用.天然气地球科学,2005,16(6):92-97
[172] 秦胜飞,宋岩,唐修义,等.流动的地下水对煤层含气性的破坏机理.科学通报,2005,50(1):99-104
[173] 傅雪海,秦勇,王万贵,等.煤储层水溶气研究及褐煤含气量预测.天然气地球科学,2005,16(2):153-157
[174] 刘焕杰,秦勇,桑树勋.山西南部煤层气地质.徐州:中国矿业大学出版社,1998
[175] 吴俊.表面能的吸附法计算及研究意义[J].煤田地质与勘探,1994,22(4):18-23.
[176] 周胜国,郭淑敏.煤储层吸附/解吸等温线测试技术[J].石油实验地质,1999,21(1):76-80.
[177] 崔永君.煤等温吸附特性测试中体积校正方法探讨[J].煤田地质与勘探,1999,27(5):29-32.
[178] 刘红林,王红岩,张建博.煤层气吸附时间计算及其影响因素分析[J].石油实验地质,2000,23(4):365-367.
[179] 辜敏,陈昌国,鲜学福.抽放煤层气变压吸附过程的数学模拟[J].煤炭学报,2001,26(3):323-326.
[180] 辜敏,陈昌国,鲜学福.混合气体的吸附特征[J].天然气工业,2001,21(4):91-94.
[181] 蔺金太,郭勇义,吴世跃.煤层气注气开采中煤对不同气体的吸附作用[J].太原理工大学学报,2001,32(1):18-20.
[182] 欧成华,易敏,郭平,等.用孔隙度测定仪测量室温低压下 N2、CO2 和天然气在人造岩芯孔隙内表面的吸附量[J].石油学报,2000,21(5):39-42.
[183] 欧成华,李士伦,易敏,等.高温高压下多种气体在储层岩心中的吸附等温线的测定[J].石油学报,2002,22(1):72-76.
[184] 欧成华,李士伦,易敏,等.高温高压下三元混合气体(N2-CH4-C2H6)在储层岩心中的吸附等温线的测定[J].天然气工业,2001,(4):72-74.
[185] 欧成华.高温高压下烃类气体在储层孔隙介质表面吸附的实验与理论研究[D].西南石油学院,2000:16-40.
[186] 欧成华,李士伦,郭平,等.储层孔隙介质气体吸附理论模型研究探讨[J].西南石油学院学报,2002,24(1):53-56.
[187] 欧成华,易敏,李士伦,等.XF-1 型高温高压储层孔隙介质气体吸脱附测试仪的研制[J].石油仪器,2002,16(1):11-14.
[188] 欧成华.储层孔隙介质单组分气体吸附理论模型研究[J].钻采工艺,2002,25(2):69-70.
[2] 孙茂远,朱超.国外煤层气开发特点及鼓励政策[J].中国煤炭,2001,27(2):55-58.
[3] 张全国.国内外煤层气的开发与进展[J] .中国沼气,1999,17(2):42-44.
[4] 叶建平,秦勇,林大扬主编.中国煤层气资源[M].江苏徐州:中国矿业大学出版社,1998.
[5] 钱凯,赵庆波,汪泽成,等.煤层甲烷气勘探开发理论与实验测试技术[M].北京:石油工业出版社,1997.
[6] 孙茂远,黄盛初.煤层气开发利用手册[M].北京:煤炭工业出版社,1998.
[7] 王慎言.煤层气将成为中国新的“接替能源”[J] .中国煤层气,1996,(1):15.
[8] 陈永武,胡爱梅.中国煤层气产业形成和发展面临的机遇与挑战[J] .天然气工业,2000,20(4):19-23.
[9] 鲜学福.我国煤层气开采利用现状及其产业化展望[J].重庆大学学报(自然科学版),2000,23(增刊):1-5.
[10] 张艳玉,魏晓霞.煤层气开采技术与发展趋势[J] .河南石油,2001,15(2):24-27.
[11] 徐永昌.天然气成因理论及应用[M].北京:科学出版社,1994:189-223.
[12] 李宝芳.煤层气及生储原理略述(第一讲)[J] .中国煤田地质,1996,8(1):89-94.
[13] 余申翰.煤层内瓦斯的赋存状态.煤炭学报,1981,(2): 1-4.
[14] 陈昌国,鲜晓红,张代钧等.微孔填充理论研究无烟煤和炭对甲烷的吸附特性.重庆大学学报,1998,21(2);75 -79
[15] 赵志根,唐修义;对煤吸附甲烷的 Langmuir 方程的讨论.焦作工学院学报,2002,21(1):1-4.
[16] 张晓东,秦勇,桑树勋.煤储层吸附气体研究现状及展望[J].中国煤田地质,2005,17(1):16-22.
[17] 张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J].煤炭学报,1999,24 (6):300-570.
[18] 叶振华,化工吸附分离过程,北京:中国石化出版社,1992:4-6
[19] 叶振华,吸着分离过程基础,北京:化学工业出版社,1988:9-10
[20] 古共伟,陈健,魏玺群,吸附分离技术在现代工业中的应用,合成化学,1999,7(4):346-353
[21] 傅国旗,天然气吸附存储的研究[博士学位论文],天津:天津大学,2001
[22] 陈海华,在湿活性炭上存储甲烷的充放气过程研究[硕士学位论文],天津:天津大学,2002
[23] 严继民,张启元,高敬琮,吸附与凝聚:固体的表面与孔,北京:科学出版社,1986:2-3
[24] 孙艳,储气材料及其储能性质的实验研究[硕士学位论文],天津:天津大学,2001
[25] 周亚平,杨斌,气体超临界吸附研究进展,化学通报,2000,63(9):8-13
[26] 杨斌,气体跨越临界温度吸附行为研究[硕士学位论文],天津:天津大学,2000
[27] 顾惕人,朱瑶,李外郎等,表面化学,北京:科学出版社,1994:275-277
[28] 严继民,张启元,吸附与凝聚:固体的表面与孔,北京:科学出版社,1979:24-55
[29] 白书培,临界温度附近 CO2 在多孔固体上吸附行为的研究[博士学位论文],天津:天津大学,2002
[30] 周亚平,周理,超临界氢在活性炭上的吸附等温线研究,物理化学学报,1997,13(2):119-127
[31] 杨俊,大温度范围内氧在活性炭上的吸附平衡研究[硕士学位论文],天津:天津大学,2003
[32] Moffat D H,Weale K E. Sorption by coal of methane at high pressure.[J].Fuel,34,1955:417-428.
[33] Yang R T,Saunders J T. Adsorption of gases on coals and heat-treated coals at elevated tempreature and pressure[J].Fuel,1985:314-327.
[34] Joubert J 1,Grein C T,Bienatock D. Sorption of methane in moist coal. Fuel,1973,52:181~185.
[35] Ruthven D.M.,Past Progress and Future Challenges in Adsorption Research,Ind.Eng.Chem.Res.,2000,39(7):2127-2131
[36] Ruthven D.M.,Farooq S.,Knabel K.S.,Pressure Swing Adsorption,New York:VCH Publishers,1994:5-7
[37] Mota J.P.B.,Rodrigues A.E.,et al.,Dynamic of Natural Gas Adsorption
[38] Storage System Employing Activated Carbon,Carbon,1997,35(9):1259-1270
[39] Wang,K.,Do,D.D.Single and Multicomponent Adsorption Equilibria of Hydrocarbons on
[40] Activated Carbon:The Role of Micropore size Distribution,Surfactant Sci.Ser.,1999,78,391-441
[41] Hu X.,Multicomponent Adsorption Equilibrium of Gases in Zeolite:Effect of Pore Size
[42] Distribution.Chem.Eng.Commun.,1999,174(1):201-214
[43] IUPAC“Definitions,Terminology and Symbols in Colloid and Surface Chemistry,PartⅠ”,Pure and Appl.Chem.,1972,41(4):597-638
[44] H.F.Stoeckli,A Generalization of the Dubinin-Radushkevich Equation for fillingof Heterogeneous Micropore Systems,J.Colloid Interface Sci.,1977,59(1):184-185
[45] P.G.Menon,Adsorption at High Pressure,Chemical Review,1968,68(3):277-294
[46] F.Rouquerol,J.Rouqerol,K.Sing,Adsorption by Powders and Porous solids,London:Academic Press,1999
[47] T.K.Bose,R.Chahine,L.Machildon,New Dielectric Method for Measurement of Physical Adsorption of Gases at High Pressure , Rev.Sci.Instrum. , 1987 , 58(12):2279-2283
[48] Zhou li,Su wei,Sun Yan,et al,Supercritical Adsorption:Challenges in Theory,Analysis and Modeling.Guan Yixin,Yao Shanjing,Zhu Ziqiang,eds,Proceeding of CKCSST’2001,Hangzhou:China,2001,379-384
[49] L Zhou,Yaping Zhou,Ming Li,Ping Chen,Yu Wang,Experimental and Modeling Study of the Adsorption of Supercritical Methane on a High Surface Activated Carbon,Langmuir,2000,16(14):5955-5959
[50] G.H.Findenegg.High Pressure Physical Adsorption of Gases on Homogeneous Surfaces,Fundamental of Adsorption,Schloas Elmau,Bavaria,West Germany,1983:207-218.
[51] Li Zhou,Sh.P.Bai,Y.P.Zhou,B.Yang,Adsorption of Nitrogen on Silica Gel over a Large Range of Temperature,Adsorption,2002,8(1):79-87
[52] Li Zhou,Y.P.Zhou,Sh.P.Bai,B.Yang,Studies on the Transition Behavior of Physical Adsorption from the Sub-to the Superritical Region:Experimentals onSilica Gel.J.of Colloid and Interface Science.2002,253(1):9-15.
[53] Keller J.U.,Dreisbach F.,Rave H.,Staudt R.,Tomalla M.,Measurements of Gas Mixture Adsorption Equilibria of Natural Gas Compounds on Microporous Sorbents,Adsorption,1999,5(3):199-214
[54] Dreisbach F.,Staudt R.,Keller J.U.,High Pressure Adsorption Data of Methane,Nitrogen,Carbon Dioxide and their Binary and Ternary Mixtures on Activated Carbon,Adsorption,1999,5(3):215-227
[55] Malek A.,Farooq S.,Comparison of Isotherm Models for Hydrocarbon Adsorption on Activated Carbon,AIChE.Journal,1996,42(11):3191-3201
[56] Ahmadpour A.,Wang K.,Do D.D.,Comparison of Models on the Prediction of Binary Equilibrium Data of Activated Carbons,AIChE.Journal,1998,44(3):740-752
[57] Grant R.J.,Manes M.,Adsorption of Binary Hydrocarbon Gas Mixtures on Activated Carbon,Ind.Eng.Chem.Fund.,1966,5(4):490-498
[58] Friekerich R.O.,Mullins J.C.,Adsorption equilibria of binary hydrocarbon mixtures on homogeneous carbon black at 25℃,Ind.Eng.Chem.Fundam.,1972,11(4):439-445
[59] Siddiqi K.S.,Thomas W.J.,The Adsorption of Methane-Ethane Mixtures on Activated Carbon,Carbon,1982,20(6):473-479
[60] Tondeur D.,Kabir H.,Luo L.A.,Grander J.,Multicomponent Adsorption Equilibria from Impulse Response Chromatography,Chem.Eng.Sci.,1996,51(15):3781-3799
[61] .Haydel J.J.,Kobayashi R.,Adsorption equilibrium in the methane-propane-silica gel system at high pressures,Ind.Eng.Chem.Fundam.,1967,6(4):546-554
[62] Reich R.,Ziegier W.T.,Rogers K.A.,Adsorption of Methane,Ethane,and Ethylene Gases and Their Binary and Ternary Mixtures and Carbon Dioxide on Activated Carbon at 212-301K and Pressures to 35 Atmospheres,Ind.Eng. Chem.Process Des.Dev.,1980,19(3):336-344
[63] Talu O.,Zweibel I.,Multicomponent Adsorption Equilibria of Nonideal Mixtures,AIChE.Journal,1986,32(8):1263-1276
[64] Gusev V.,O'Brien J.A.,Jensen C.R.C.,Seaton N.A.,Theory for Multicomponent Adsorption Equilibrium:Multispace Adsorption Model,AIChE.Journal,1996,42(10):2773-2783
[65] Carlson N.W.,Dranoff J.S.,On the Adsorption of Ethane by 4A Zeolite Pellets,Ind.Eng.Chem.Process Des.Dev.,1985,24(4):1300-1302
[66] Do D.D.,Wang K.,A New Model for the Description of adsorption Kinetics in Heterogeneous Activated Carbon,Carbon,1998,36(6):1539-1554
[67] Hu X.,Do D.D.,Role of Energy Distribution in Multicomponent Sorption Kinetics in Bidispersed Solids,AIChE Journal,1993,39(10):1628-1640
[68] Hu X.,G.N.Rao,Do D.D.,Effect of Energy Distribution on Sorption Kinetics in Bidispersed Paricles,AIChE J.,1993,39(2):249-261
[69] Mayfield P.L.J.,Do D.D.,Measurement of the Single-Component Adsorption Kinetics of Ethane,Butane,and Pentane onto Activated Carbon Using a Differential Adsorption Bed,Ind.Eng.Chem.Res.,1991,30(6):1262-1270
[70] O.Kadlec,The History and Present State of Dubinin’s Theory of Adsorption of Vapous and Gases on Microporous Solids,Adsorption Science and Technology,2001,19(1):1-28
[71] D.M.Ruthven,Principles of Adsorption and Adsorption Processes,New York:John Wiley&Sons,1984:65-70
[72] S.Ozawa,S.Kusumi,Y.Ogino,Physical Adsorption of Gases at High PressureⅣAnImprovement of the Dubinin-Astakhov Adsorption Equation,J.of Colloidand interface Science,1976,56(1):83-91.
[73] R.K.Agarwal,J.A.Schwarz,Analysis of High Pressure Adsorption of Gases on Activated Carbon by Potential Theory,Carbon,1988,26(2):873-887.
[74] K.A.G..Amankwah,J.A.Schwarz,A Modified Approach for Estimating Pesudo-Vapor Pressures in the Application of the Dubinin-Astakhov Equation,Carbon,1995,33(9):1313-1319.
[75] Zhou Y.and L.Zhou,Experimental Study on High-Pressure Adsorption of Hydrogen on Activated Carbon,Science in China(Series B),1996,39(6):598-607
[76] 52.Zhou Li,Li Ming,and Zhou Yaping,Measurement and Theoretical Analysis of the
[77] Adsorption of Supercritical Methane on Superactivated Carbon,Science in China (Series B),2000,43(2):143-153
[78] Li Zhou,Yaping Zhou,Shupei Bai,Changzhong Lü,Bin Yang,Determination of the Adsorption Phase Volume and Its Application in Isotherm Modeling for the Adsorption of Supercritical Nitrogen on Activated Carbon,Journal of Colloid and Interface Science,2001,239(1):33-38
[79] Zhou Yaping,Bai Shupei,Zhou Li,Yang Bin,Studies on the physical adsorption equilibria of gases on porous solids over a wide temperature range spanning the critical region-adsorption on microporous activated carbon,Chinese Journal of Chemistry,2001,19(10):943-948
[80] Li Zhou,Yaping Zhou,A Comprehensive Model for the Adsorption of Supercritical Hydrogen on Activated Carbon,Ind.Eng.Chem.Res.,1996,35(11):4166-4168
[81] Li Zhou,Yaping Zhou,Linearization of Adsorption Isotherms for High-Pressure Applications,Chemical Engineering Science,1998,53(14):2531-2536
[82] .Zhou Li,Zhou Yaping,A Mathematical Method for Determination of Absolute Adsorption from Experimental Isotherms of Supercritical Gases , Chinese J.of Chem.Eng.,2001,9(1):110-115
[83] L.Zhou,P.Chen,M.Li,Y.Sun,Y.Zhou,Prying the nature of supercritical adsorption via isotherm space transformations,edited Duong D Do,Proceeding of the second pacific basin conference on adsorption science and technology,Australia,World Scientific Publishing Co.,2000,717-721
[84] L Zhou,Yaping Zhou,Ming Li,Ping Chen,Yu Wang,Experimental and Modeling Study of the Adsorption of Supercritical Methane on a High Surface Activated Carbon,Langmuir,2000,16(14):5955-5959
[85] 周理,吕昌忠,王怡林,姚金花,王瑜,述评超临界温度气体在多孔固体上的物理吸附,化学进展,1999,11(3):221-226
[86] 周理,吴芹,周亚平,孙艳,论高压吸附的边界与气体的吸附存储,中国太阳能学会 2001 年学术会议,231-235
[87] 周理,超临界吸附研究:疑惑、问题与分析,第四届全国氢能学术会议论文集,155-162
[88] 杨向平,李阳初,沈复,能量不均匀固体表面上多元非理想溶液的吸附等温线模型,化工学报,1998,49(2):155-161
[89] 刘晓勤,姚虎卿,时钧,二元液体混合物非理想吸附平衡数据的预测,化工学报,2002,53(4):412-417
[90] 居沈贵,刘晓勤,马正飞,姚虎卿,时钧,含 CO 体系在载铜吸附剂上的吸附平衡,南京化工大学学报,1998,20(3):79-82
[91] 韩振为,周明,用晶格模型预测多组元固液界面上的吸附平衡,化工学报,1996,47(1):1-7
[92] 胡英,近代化工热力学—应用研究的新进展,上海:上海科学技术文献出版社,1994,261-268
[93] 李明,含有超临界组分的多元气/固吸附平衡研究[博士学位论文],天津:天津大学,2001
[94] 蒋维钧,雷良恒,刘茂林,化工原理(下册),北京:清华大学出版社 1993,552-557
[95] 吴芹,多组分超临界气体混合物在多孔固体上吸附平衡的研究[博士学位论文],天津:天津大学,2003
[96] 熊洪允,曾绍标,毛云英,应用数学基础,天津:天津大学出版社,1994
[97] J.A.Dean(美)主编,兰氏化学手册,尚久方,操时杰等译,北京:科学出版社,1991
[98] 郭天民,多元汽液平衡和精馏,北京:化学工业出版社,1983:250-256
[99] 张遂安.有关煤层气开采过程中煤层气解吸作用类型的探索.中国煤层气,2004,1(1):26-29
[100] 傅雪海,秦勇,叶建平,等.中国部分煤储层解吸特性及甲烷采收率.煤田地质与勘探,2000,28(2):19-22
[101] 李小彦等.煤储层吸附时间参数变化及影响因素[J].天然气地球科学,2003,14(6):502-505
[102] 关平,伍天洪.热成因甲烷同位素分布的形成机制.沉积学报,2003,21(1):175-182
[103] 陈践发,李春园,沈平,等.煤型气烃类组分的稳定碳、氢同位素组成研究.沉积学报,1995,13(2):59-69.
[104] 程克明,熊英,J M Moldowan,等.吐哈盆地煤成烃研究新进展.沉积学报,2002,20(3):456-461
[105] 刘文汇,宋岩,刘全有,等.煤岩及其主显微组份热解气碳同位素组成的演化.沉积学报,2003,21(1):183-190
[106] 张同伟,陈践发,王先彬,等.天然气运移的气体同位素地球化学示踪.沉积学报,1995,13(2):70-76.
[107] 徐永昌,刘文汇,沈平.含油气盆地油气同位素地球化学研究概述.沉积学报,2001,19(2):161-16873
[108] 戴金星.中国煤成气研究二十年的重大进展.石油勘探与开发,1999,26(3):1-10
[109] 戴金星,裴锡古,戚厚发.中国天然气地质学(卷一).北京:石油工业出版社,1992
[110] 戴金星.鉴别煤成气和油型气若干指标的初步探讨.石油学报,1995,16(2):31-38
[111] 徐永昌,沈平.中国化石燃料同位素地球化学.中国科学,B 辑,1991,(4):409-418
[112] 沈平等.气源岩和天然气地球化学特征及成烃机理研究.兰州:甘肃科学技术出版社,1991
[113] 傅家谟.煤成烃地球化学.北京:科学出版社,1990
[114] 张义纲.天然气的生成聚集和保存.南京:河海大学出版社,1991
[115] 黄第藩,熊传武,杨俊杰,等.鄂尔多斯盆地中部大气田的气源判识.科学通报,1996,41(17):1588-1592
[116] 刘文汇,徐永昌.煤型气碳同位素演化二阶段分馏模式及机理.地球化学.1999,28(4):359-366
[117] 钱凯,赵庆波,汪泽成,等编著.煤层甲烷气勘探开发理论与实验测试技术[Ml.北京:石油上业出版社,1996
[118] Stahl W J.Geochemische daten nordwest-deutscher Oberkarbon,Zechstein und Buntsandsteingase.Erdoel und Kohle-Erdgas-Petrochemie,1979,32(Heftz):74 65-70
[119] Scott A R.Composition and origin of coalbed gases from selected basins in the United States , Proceeding of the 1993 International Coalbed Methane Symposium.Birmingham,Alabama,1993
[120] 李晶莹,陶明信.国际煤层气组成和成因研究.地球科学进展,1998,13(5):467-473
[121] 张建博,陶明信.煤层甲烷碳同位素在煤层气勘探中的地质意义——以沁水盆地为例.沉积学报,2000,18(4):611-614
[122] 胡国艺,刘顺生,李景明,等.沁水盆地晋城地区煤层气成因.石油与天然气地质,2001,22(4):319-321
[123] 王彦龙,解光新,张培元.沁水盆地煤层气同位素特征及成因类型初探.煤田地质与勘探,2005,33(1):32-34
[124] 刘冬梅,张玉贵,唐修义.煤层气中甲烷δ13C 值偏轻的机理探讨.焦作工学院学报,1997,16(2):89-94
[125] 秦勇,唐修义,叶建平.华北上古生界煤层甲烷稳定碳同位素组成与煤层气解吸—扩散效应.高校地质学报,1998,4(2):127-132
[126] 秦勇,唐修义,叶建平,等.中国煤层甲烷稳定碳同位素分布与成因探讨.中国矿业大学学报,2000,29(2):113-119
[127] 李明潮,张伍剂.中国主要煤田浅层煤成气.北京:科学出版社,1990.
[128] 吴俊.中国煤成烃基本理论与实践.北京:煤炭工业出版社,1994
[129] 冯福铠,王廷斌,张士亚,等.中国天然气地质.北京:地质出版社,1995
[130] 戴金星,戚厚发,宋岩.我国煤层气组分、碳同位素类型及其成因意义.中国科学(B 辑),1986,(12):1317-1326
[131] 秦胜飞,宋岩,唐修义,等.水动力对煤层甲烷碳同位素的影响.天然气工业,2005,25(11):30-32
[132] 陶明信,徐永昌,陈践发,等.中国煤型气区的构造环境、典型气藏及勘探方向—上古生界煤型气.沉积学报,1998,16(3):25-30
[133] 段玉成.我国煤的稳定同位素组成特征.煤田地质与勘探,1995,23(1):29-3575
[134] 张建博.沁水盆地南部煤层气藏水文地质特征.煤田地质与勘探,2001,29(5):33-37 中国煤田地质总局.中国煤层气资源[M].北京:中国矿业大学出版社,1998
[135] 张新民,庄军,张遂安.中国煤层气地质与资源评价[M].北京:科学出版社,2002
[136] 苏现波,陈江峰,孙俊民,等.煤层气地质学与勘探开发[M].北京:科学出版社,2001
[137] 黄景城.煤层甲烷开采概述[Al.见:煤层气译文集[C].郑州:河南科技出版社.1990
[138] 蔡炳心.基础物理化学[M].北京:科学出版社,2001
[139] 陈昌国.煤的物理化学结构和吸附(解吸)机理的研究[D].重庆:重庆大学.1995
[140] Yang R T Saunders J T.Adsorption of gases on coals and head-treated coals at elevated tempreature and pressure.[J].Fue1,1985
[141] 陈宗淇,王光信,徐桂英,编.胶体与界面化学[M].北京:高等教育出版社.2001
[142] M.Jaroniec,R Madey.非均匀固体上的物理吸附[M].加璐译.北京:化学工业出版社.2000
[143] 刘常洪,杨思敬.关于煤甲烷吸附体系吸附规律的研究[J].煤矿安全,1992,(4):1-5
[144] Crosdale P J,Beamish B B,Valix M.Coalbed methane sorption related to coal compostion[J].International,Journal of Geology,1998,35:147 一 158
[145] 赵志根,唐修义.对煤吸附甲烷的 Langmuir 方程的讨论[J].焦作工学院学报,2002,21(1):1-4
[146] 陈昌国,鲜晓红,张代钧,等.微孔填充理论研究无烟煤和炭对甲烷的吸附特性[J].重庆大学学报,1998,21(2):75-79
[147] 艾鲁尼 A T.煤矿瓦斯动力现象的预测和预防[M].唐修义,等译.北京:煤炭工业出版社.1992
[148] 霍多特 B B.煤与瓦斯突出[M].宋世钊,等译.北京:中国上业出版社.1996.76
[149] 陈萍,唐修义.低温氮吸附法与煤中微孔隙特征的研究[J].煤炭学报,2001,26(5):552-556
[150] 桑树勋,秦勇,郭晓波,等.准噶尔和吐哈盆地侏罗系煤层气特征[J].高校地质学报,2003,9(3):365-371
[151] 傅雪海,秦勇,李贵中,等.特高煤级煤平衡水条件下的吸附实验[J].石油实验地质,2002,24(2):177-180
[152] 秦勇,傅雪海,叶建平,等.中国煤储层岩石物理学因素控气特征及机理[J].中国矿业大学学报,1999,28(1):14-19
[153] Ettinger I,Zimakov B,Yanovskaya.Natural factors influencing coal sorption properties-petrography and the sorption properties of coals[J].Fuel , 1996 ,(45):243-259
[154] 傅雪海,秦勇.多相介质煤层气储层渗透率预测理论与方法[M].徐州:中国矿业大学出版社,2003
[155] 张新民,庄军,张遂安 . 中国煤层气地质与资源评价 [M]. 科学技术出版社.2002:38-46
[156] 桑树勋,朱炎铭,张井.煤层气储集与三态动平衡[A].见:宋岩,张新民.煤层气研究新进展[C].北京:科学出版社,2004
[157] 唐书恒.晋城地区煤储层特征及多元气体的吸附一解吸特征.[D].徐州:中国矿业大学,2001
[158] 张力,何学秋,王恩兀,等.煤吸附特性的研究[F].太原理工大学学报,2001,32(4):449-451
[159] 霍永忠.煤储层的气体解吸特性研究.天然气工业,2004,24(5):24～26
[160] 刘洪林,王红岩,张建博.煤层气吸附时间计算及其影响因素分析.石油实验地质,2000,22(4):365-368
[161] 李小彦,司胜利.我国煤储层煤层气解吸特征.煤田地质与勘探,2004,32(3):27-29
[162] 张彦平.国外煤层气开发技术译文集[C].北京:石油工业出版社,1996
[163] 许卫,崔庆田,颜明友,等.煤层甲烷气勘探开发工艺技术进展[M].北京:石油工业出版社,2001
[164] 曹成润,牛伟,张遂安,等.煤层气在煤储层中的扩散及其影响因素.世界地质,2004:23(3):266-270
[165] 张力,何学秋,李侯全.煤层气渗流方程数值模拟「J].天然气工业,2002,22(1):23-26
[166] 吴世跃,郭勇义.煤层气运移特征的研究「J].煤炭学报,1999.24(1):65-69
[167] 卢双舫,付广,工朋岩,等.天然气富集主控因素的定量研究「M」.北京:石油工业出版社,2002
[168] 赵孟军,宋岩,苏现波。决定煤层气地球化学特征的关键地质时期.天然气工业,2005,25(1):51～54
[169] 高波,陶明信,张建博,等.煤层气甲烷碳同位素的分布特征与控制因素.煤田地质与勘探.2002,30(3):14-17
[170] 刘洪林,王红岩,赵国良,等.稳定碳同位素δ13C1 在煤层气田勘探中的应用.西安科技大学学报.2004,24(4):442-447
[171] 张殿伟,刘文汇,刘全有,等.煤系源岩显微组分对天然气碳同位素组成影响的应用.天然气地球科学,2005,16(6):92-97
[172] 秦胜飞,宋岩,唐修义,等.流动的地下水对煤层含气性的破坏机理.科学通报,2005,50(1):99-104
[173] 傅雪海,秦勇,王万贵,等.煤储层水溶气研究及褐煤含气量预测.天然气地球科学,2005,16(2):153-157
[174] 刘焕杰,秦勇,桑树勋.山西南部煤层气地质.徐州:中国矿业大学出版社,1998
[175] 吴俊.表面能的吸附法计算及研究意义[J].煤田地质与勘探,1994,22(4):18-23.
[176] 周胜国,郭淑敏.煤储层吸附/解吸等温线测试技术[J].石油实验地质,1999,21(1):76-80.
[177] 崔永君.煤等温吸附特性测试中体积校正方法探讨[J].煤田地质与勘探,1999,27(5):29-32.
[178] 刘红林,王红岩,张建博.煤层气吸附时间计算及其影响因素分析[J].石油实验地质,2000,23(4):365-367.
[179] 辜敏,陈昌国,鲜学福.抽放煤层气变压吸附过程的数学模拟[J].煤炭学报,2001,26(3):323-326.
[180] 辜敏,陈昌国,鲜学福.混合气体的吸附特征[J].天然气工业,2001,21(4):91-94.
[181] 蔺金太,郭勇义,吴世跃.煤层气注气开采中煤对不同气体的吸附作用[J].太原理工大学学报,2001,32(1):18-20.
[182] 欧成华,易敏,郭平,等.用孔隙度测定仪测量室温低压下 N2、CO2 和天然气在人造岩芯孔隙内表面的吸附量[J].石油学报,2000,21(5):39-42.
[183] 欧成华,李士伦,易敏,等.高温高压下多种气体在储层岩心中的吸附等温线的测定[J].石油学报,2002,22(1):72-76.
[184] 欧成华,李士伦,易敏,等.高温高压下三元混合气体(N2-CH4-C2H6)在储层岩心中的吸附等温线的测定[J].天然气工业,2001,(4):72-74.
[185] 欧成华.高温高压下烃类气体在储层孔隙介质表面吸附的实验与理论研究[D].西南石油学院,2000:16-40.
[186] 欧成华,李士伦,郭平,等.储层孔隙介质气体吸附理论模型研究探讨[J].西南石油学院学报,2002,24(1):53-56.
[187] 欧成华,易敏,李士伦,等.XF-1 型高温高压储层孔隙介质气体吸脱附测试仪的研制[J].石油仪器,2002,16(1):11-14.
[188] 欧成华.储层孔隙介质单组分气体吸附理论模型研究[J].钻采工艺,2002,25(2):69-70.