煤自燃阶段特征及其临界点变化规律的研究
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摘要
为了研究煤自燃阶段特征及其临界点的变化规律，通过对10个不同变质程度的煤进行同步热分析实验、红外官能团测试、程序升温实验，得到了煤自燃过程中不同影响因素对特征参数的影响以及燃烧过程中低温、高温时期各个阶段的阶段特征和临界温度点。程序升温实验、同步热分析实验在宏观上测量煤自然发火过程中其低温、高温时期的各特征参数，并得出煤的耗氧量、活化能值、吸氧量、热焓值的变化规律，最后根据煤活化能值的变化情况对燃烧温度进行分段，找出煤各个阶段的临界温度值。傅里叶红外分析技术从微观上测试了煤在低温氧化过程中其内部官能团数量、种类的变化情况，并根据测试结果总结出煤低温时期官能团的宏观与微观临界点。同时为了考察煤特征参数与临界温度点间的关系，分别对它们的关联度进行拟合，并得出其数学公式，从而进一步的考察了各影响参数之间关系。
In order to research the stage characteristic of coal spontaneous combustion andthe critical temperature point, through the study of10different metamorphic degreeof coals about the simultaneous thermal analysis experiment, the infrared functionaltest and the temperature programmed to access the impact of the differentinfluencing factors to the characteristic parameters in the process of coalspontaneous combustion, and the each stage characteristics, the critical temperaturepoint in low and high temperature period. The temperature programmed experimentsand the simultaneous thermal analysis experiments are used to measure thecharacteristic parameters during the low-temperature and the high temperature in theprocess of coal spontaneous combustion. The variation law of oxygen consumption,activation energy value, and oxygen intake and heat enthalpy are obtained. At last,the temperature is sectioned according to the changes of the activation energy valueof coal, and the critical temperature in various stages is found. The internal changesof the number and the species the functional groups in the process oflow-temperature oxidation are tested by Fourier infrared analysis technology. Andthen the macro and micro critical temperature are summarized by the results of thetests. At the same time, in order to inspect the relationship between characteristicparameters of coal and the critical temperature point, the correlation between thecharacteristic parameters of coal and the critical temperature point is fitted, the mathematical formula is also got and the further investigation of the relationshipbetween the influence parameters is preceded.
In order to research the stage characteristic of coal spontaneous combustion andthe critical temperature point, through the study of10different metamorphic degreeof coals about the simultaneous thermal analysis experiment, the infrared functionaltest and the temperature programmed to access the impact of the differentinfluencing factors to the characteristic parameters in the process of coalspontaneous combustion, and the each stage characteristics, the critical temperaturepoint in low and high temperature period. The temperature programmed experimentsand the simultaneous thermal analysis experiments are used to measure thecharacteristic parameters during the low-temperature and the high temperature in theprocess of coal spontaneous combustion. The variation law of oxygen consumption,activation energy value, and oxygen intake and heat enthalpy are obtained. At last,the temperature is sectioned according to the changes of the activation energy valueof coal, and the critical temperature in various stages is found. The internal changesof the number and the species the functional groups in the process oflow-temperature oxidation are tested by Fourier infrared analysis technology. Andthen the macro and micro critical temperature are summarized by the results of thetests. At the same time, in order to inspect the relationship between characteristicparameters of coal and the critical temperature point, the correlation between thecharacteristic parameters of coal and the critical temperature point is fitted, the mathematical formula is also got and the further investigation of the relationshipbetween the influence parameters is preceded.
引文
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