表面活性剂有机聚集体对甲烷的吸收及应用研究
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摘要
本文针对瓦斯危险问题,以甲烷作为瓦斯模型气体,探讨了用表面活性剂有机聚集体增溶吸收甲烷,降低甲烷浓度的可行性。研究了单一表面活性剂体系及表面活性剂复配体系对甲烷的吸收作用。通过对吸收剂吸收性能和稳定性的综合分析,筛选出对甲烷吸收效果好的吸收剂体系—十二烷基硫酸钠(SDS)、蓖麻油、水吸收体系。进而使用激光光散射、透射电镜、荧光光谱、荧光寿命、紫外光谱的方法对该吸收剂中聚集体的形态和微环境极性进行表征,并利用溶液热力学理论及Mukerjee胶束模型分析了该体系增强吸收甲烷的机理；而后利用气液传质双膜理论对该体系吸收动力学进行研究；最后使用该吸收剂进行雾化吸收、模拟抑爆及现场吸收试验。研究表明十二烷基硫酸钠、蓖麻油、水吸收体系对甲烷有良好的吸收作用,并对甲烷与空气混合物的爆炸有抑制作用。体系增强吸收甲烷的机理是：体系中聚集体微环境极性减少及聚集体/水界面Laplace压力效应减少促使体系对甲烷吸收作用的增强。
To solve the danger of mine gas, this paper used methane as a model of mine gas and studied the feasibility of decreasing methane concentration by absorbing methane using organic surfactant aggregates. The effects of single surfactant system and mixed surfactant system on methane absorption were studied. By comprehensive analysis of the absorptive effect and the stability of different absorbents, SDS-castor oil-water combination system was determined as good methane absorbent. Furthermore, the morphology and the microenvironment polarity of organic aggregate in SDS-castor oil-water system were characterized using laser light scattering, TEM, fluorescence spectrum, fluorescence life time and UV spectrum. Then the enhanced absorption mechanism of this absorbent was analyzed based on solution thermodynamics theory and micelle model proposed by Mukerjee. Moreover, the absorption kinetics of this system was studied by double-membrane model. Finally, the effect of this absorbent on methane absorption in atomization condition was studied in the laboratory and in air-return and the explosion surpression effect of this absorbent was studied by simulated explosion test. The result indicated that SDS-castor oil-water system had good effect on methane absorption and could inhibit methane explosion. The decrease of microenvironment polarity of organic aggregate in SDS-castor oil-water system and the decrease of Laplace pressure effect at aggregate-water interface enhanced the absorption of methane by this system.
To solve the danger of mine gas, this paper used methane as a model of mine gas and studied the feasibility of decreasing methane concentration by absorbing methane using organic surfactant aggregates. The effects of single surfactant system and mixed surfactant system on methane absorption were studied. By comprehensive analysis of the absorptive effect and the stability of different absorbents, SDS-castor oil-water combination system was determined as good methane absorbent. Furthermore, the morphology and the microenvironment polarity of organic aggregate in SDS-castor oil-water system were characterized using laser light scattering, TEM, fluorescence spectrum, fluorescence life time and UV spectrum. Then the enhanced absorption mechanism of this absorbent was analyzed based on solution thermodynamics theory and micelle model proposed by Mukerjee. Moreover, the absorption kinetics of this system was studied by double-membrane model. Finally, the effect of this absorbent on methane absorption in atomization condition was studied in the laboratory and in air-return and the explosion surpression effect of this absorbent was studied by simulated explosion test. The result indicated that SDS-castor oil-water system had good effect on methane absorption and could inhibit methane explosion. The decrease of microenvironment polarity of organic aggregate in SDS-castor oil-water system and the decrease of Laplace pressure effect at aggregate-water interface enhanced the absorption of methane by this system.
引文
1. 李学来,刘见中.瓦斯灾害治理新技术.中国安全科学学报,2004,14(7)：101-104
2. 煤矿安全生产现状分析[EB/OL].http://www.hbsafetv.com.cn/article/12/241/389/200711/35094.shtmL.2007-11-7
3. 林柏泉,崔恒信.矿井瓦斯防治理论与技术.徐州：中国矿业大学出版社,1998：1-200
4. 徐梓铭,刘然,刘志坚.煤矿瓦斯爆炸的条件与预防措施.煤炭科技,2007,(3)：67-50
5. 胡千庭,蒋时才,苏文叔.我国煤矿瓦斯灾害防治对策.矿业安全与环保,2000,27(1)：1-5
6. 赵铁锤.搞好瓦斯抽放利用促进煤矿安全生产.中国煤层气,2005,2(2)：3-5
7. 李国彪.充分发挥监测装置作用确保高瓦斯矿井安全生产.矿业安全与环保,2004,31(6)：63-65
8. 许石青,吴华帮.煤与瓦斯突出预测方法研究现状与进展.矿业快报,2008,(5)：21-24
9. 孙文标,刘辉,赵宏伟.煤层注水在煤矿安全中的应用及效果浅析.煤矿安全,2004,35(12)：24-25
10. 张永吉,李占德,秦伟瀚,等.煤层注水技术.北京：煤炭工业出版社,2001：1-300
11. 王惠宾,汪远东,卢平.煤层注水中添加湿润剂的研究.煤炭学报,1994,14(4)：151-160
12. 彭起文.粉尘防治技术最新进展.矿业安全与环保,1999,24(1)：42-45
13. 傅贵.煤体预湿机理及注水防尘技术研究.北京：中国矿业大学北京研究生部,1994：1-100
14. 张永吉,李占德,秦伟瀚,等.煤层注水技术.北京：煤炭工业出版社,2001：1-12
15. 张保勇,吴强.表面活性剂在瓦斯水合物生成过程中动力学作用.中国矿业大学学报,2007,36(4)：478-451
16. WU Qiang, HE Xue-qiu. Preventing coal and gas outburst using methane hydration. Journal of China University of Mining & Technology,2003,13 (1):7-10
17. 江传力,张国宏,吴强,等.在井下温度合成瓦斯水合物的实验.黑龙江科技学院学报,2004,14(4)：203-205
18. 吴强,李成林,江传力.瓦斯水合物生成控制因素探讨.煤炭学报,2005,30(3)：283-287
19.吴强.煤层瓦斯水合机理实验研究.徐州：中国矿业大学,2005：1-100
20.吴强,张保勇,王永敬.瓦斯水合物分解热力学研究.北国矿业大学学报,2006,35(5)：658-661
21. 吴强,张保勇.表面活性剂在瓦斯水合中的作用机理.煤炭学报,2006,31(6)：716-720
22. 赵建忠,石定贤,赵阳升.喷射方式下表面活性剂对水合物生成实验研究.天然气工业,2007,27(1)：114-117
23. 韩小辉,王胜杰,陈孝彦,等.表面活性剂加速天然气水合物生成实验研究.天然气工业,2002,22(5)：90-92
24. 胡汉华,刘道平,谢应明,等.喷雾反应器中表面活性剂对制备天然气水合物的影响.齐鲁石油化工,2006,34(3)：256-257
25.秦宪礼,吴强,张保勇.十二烷基硫酸钠对甲烷水合物生成过程影响研究.化学通报,2006,(7)：519-523
26. Gayeta P, Dicharrya C, Mariona G, et al. Experimental determination of methane hydrate dissociation curve up to 55MPa by using a small amount of surfactant as hydrate promoter. Chemical Engineering Science, 2005,60:5751-5758
27. Zhong Y, Rogers R E. Surfactant effects on gas hydrates formation. Chemical Engineering Science,2000,5 (19):4175-4187
28. 章春笋,樊栓狮,郑新.非离子表面活性剂对天然气水合物形成过程的影响.天然气与石油,2003,21(3)：31-35
29.赵义,丁静,杨晓西.天然气水合物及其生成促进与抑制研究进展.天然气工业,2004,24(12)：132-135
30.章春笋,樊栓狮,郭彦坤,等.不同类型表面活性剂对天然气水合物形成过程的影响.天然气工业,2002,23(1)：91-97
31.孙志高,郭开华,樊栓狮.天然气水合物形成促进技术实验研究.天然气工业,2004,24(12)：41-46
32. 孙志高,樊栓狮.气体水合物生成特性实验研究.科学技术与工程,2006,23(6)：4798-4800
33. Khokhar A A, Gudmundsson J S, Sloan E D. Gas storage in structure hydrates. Fluid Phase Equilibria,1998, 150-151:383-392
34. Ganji H, Manteghian M, Szadeh K, et al. Effect of different surfactants on methane hydrates formation rate stability and storage capacity. Flue,2007,86:434-441
35. Ganandran N, Amin R. The effect of hydrotropes on gas hydrates formation. J Pet Sci Eng,2003,40:37-46
36. Zhang C S, Fan S S, Liang D Q, et al. Effect of additives on formation of natural gas hydrates. Fuel,2004, 83:2115-2121
37. Karaaslan U, Uluneye E, Parlaktuna M. Effect of an anionic surfactant on different type of hydrate structures. Journal of Petroleum Science and Engineering,2002,35:49-57
38. Link D D, Ladner E P, Elsen H A, Formation and dissociation studies for optimizing the uptake of methane by methane hydrates. Fluid Phase Equilibrium,2003,211:1-10
39. 肖普朝.煤层延化防突的机理与实践.煤炭工程师,1994,(4)：16-21
40. 岳之学.固化防突技术原理及其应用.江西煤炭科技,1998,(4)：37-39
41. 陈金玉.固化防突材料的开发与应用.中州煤炭,1997(2)：37-39
42. 张超英,肖普朝,陈金玉,等.应用固化液防止煤与瓦斯突出的理论与实践.煤炭学报,1995, (增刊)：70-76
43.刘泽功,孙家斌,李伟.松软煤层固化防突技术与实践.1998,26(3)：33-35
44. 徐西亮.石门揭煤固化防突技术.陕西煤炭,2006,(3)：37-38
45. Hanson R S, Hanson T E. Methanotrophic bacteria. Microbiol. Rev,1996,60(2):439-471
46. Martin Kru¨ger, Tina Treude, Heike Wolters, et al. Microbial methane turnover in different marine habitats. Colloids and Surfaces A:Physicochem. Eng. Aspects,2006,273:117-120
47.柯为.治理煤矿瓦斯爆炸的微生物生物技术.生物工程学报,2005,21(3)：460
48. 王璐,金龙哲.利用微生物技术治理煤矿瓦斯的研究展望.中国安全科学学报,2005,15(10)：97-99
49. 陈东科,王璐,金龙哲.利用微生物技术治理煤矿瓦斯的研究展望.矿业安全和环保,2005,32(6)：49-50
50. 陈东科,王璐,金龙哲.微生物降解煤矿瓦斯的研究.煤炭学报,2006,31(5)：607-609
51. 侯晨涛,王生全,聂文杰,等.微生物技术治理煤矿瓦斯的初步研究,矿业安全和环保,2008,35(2)：11-14
52. 费国云,周奠邦.新型隔爆棚抑制弱爆炸的研究.煤炭工程师,1998,(3)：7-9
53.王云海,何学秋,王恩元.煤矿隔爆棚隔爆作用分析.江苏煤炭,2003,(1)：30-32
54. 蔡东红,杜贤流.矿井隔爆水袋棚实用安装方法探讨.煤矿安全,2003,33(3)：52-53
55. 蔡周全.MGS型密封式隔爆水袋的研究.矿业安全与环保,2004,6：11-14
56. Daniel N, Michael S, Aldo F. Coal dust and gas explosion suppression by barriers. ASTM:Special Technical Publication,1987:958
57. Ewan B C R, Moatamedi M. The study of induced water flow devices in the suppression of gas explosions. Process Safety and Environmental Protection,2002,80(B3):126-134
58. Hideo T, Takeshi H, Ikuhide T. Suppression of methane explosion by Halon 1301. Saiko to Hoan,1981, 27(6):281-290
59. Hideo T, Takeshi H, Ikuhide T. Suppression of explosion of methane gas by halon (CF3Br). Nippon Kogyo Kaishi,1982,98:1007-1009
60. 崔德润.利用惰性气体缩短火区封闭时间.煤矿安全,1993,(5)：58-61
61. 驹井武,杜立华.关于惰性气体与泡沫组合灭火技术的研究.煤炭技术,1990,(4)：29-34
62. Hideo O, Shinsuke N. Experimental study on inhibition effect of CF3I over methane/air combustion in an explosion vessel. Nihon Nensho Gakkaishi,2002,44(129):166-170
63. 邱雁,高广伟,罗海珠.充注惰气抑制矿井火区瓦斯爆炸机理.煤矿安全,2003,34(2)：8-11
64. Lisochkin Y A, Poznyak V I. Inserting of methane-air mixtures by compositions based on carbon dioxide and nitrogen with additions of halocarbons. Fizika Goreniyai Vzryva,2005,41(5):23-28
65. Martin H, Kenneth L, Charles P. Inhibition and extinction of coal dust and methane explosions. Pittsburgh: Res. Cent. Rep. Invest.-U. S., Bur. Mines,1982:1-33
66. Martin H, Kenneth L, Isaac Z, et al. Symposium (International) on Combustion. Pittsburgh:Res. Cent., Bur. Mines,1984,20:1691-1700
67. Ryzhkov V S, Krasnyanskii M E, Koshcheev, G Q et al. Agent for preventing methane and coal dust explosion in mines. SU 977822,1982-11-30
68. Amyotte P R, Mintz K J, Pegg M J. Effect of rock dust particle size on suppression of coal dust explosions. Process Safety and Environmental Protection,1995,73(B2):89-100
69. Datsenko D F, Kuprienok P A, Gryadushchii B A, et al. Powder for suppressing explosion of methane-air mixtures. SU 1460331,1986-12-22
70. Datsenko D F, Kuprienok P A, Zabuga V Ya, et al. Agent for inhibiting explosion of methane-air mixtures. SU 1244344,1986-07-15
71. Glazkova A P. Inhibition of methane-air mixtures and the problem of the safety of explosives. Kinetikai Kataliz,1971,12(1):16-20
72. Datsenko D F, Zabuga V Ya, Dolinskaya L P, et al. Heat-absorbing properties of explosion-suppressing powders. Zhurnal Prikladnoi Khimii,1982,55(3):595-598
73. Corecki J, Szkred T. Influence of inorganic additives on explosion hazard of a coal dust. Proceedings of the Shenyang international symposium on dust explosions, China:Combustion Inst,1987:528-538
74. Amyotte P R, Mintz K J, Pegg M J. Effect of rock dust particle size on suppression of coal dust explosions. Process Safety and Environmental Protection,1995,73(B2):89-100
75. Laffitte P, Bouchet R. Suppression of explosion wave in gaseous mixtures by means of fine powders. In:7th Symposium (International) on Combustion. Pittsburgh. London:Combustion Inst,1959:504-508
76. Kauffman C, Wolanski P, Arisoy A, et al. Dust, hybrid, and dusty detonations. In:Dynamics of shock wave, explosion and defonations, Progress in astronauties and aeronautics. New York:AIAA,1984:100
77. Krasnyansky M. Prevention and suppression of explosions in gas-air and dust-air mixtures using powder aerosol-inhibitor. Journal of Loss Prevention in the Process Industries,2006,19:729-735
78.董刚,邱榕,蒋勇,等.惰性颗粒抑制CH4/O2/N2爆炸过程的二维数值模拟与实验验证.燃烧科学与技术,2005,11(4)：329-335
79. Dong G, Fan B C, Xie B, et al. Experimental investigation and numerical validation of explosion suppression by inert particles in large-scale duct. Proceedings of the Combustion Institute. China:Elsevier,2004,30(Pt. 2):2361-2368
80. 张辉.矿井瓦斯爆炸控制材料的实验研究.西安：西安科技大学,2005：1-100
81. 苏俊杰.超细无机阻燃材料对瓦斯控爆效能的实验研究.西安：西安科技大学,2006：1-100
82. 黄超.燃爆消减剂的理论与应用基础研究.南京：南京理工大学,2006：1-100
83. 蒋新生,杜扬,高建丰,等.受限空间可燃气体爆炸抑爆实验系统研究.后勤工程学院学报,2007,23(2)：97-104
84. Edwards K L. Material and constructions used in devices to prevent the spread of flames in pipelines and
vessels. Material and Design,1999,20:245-252
85.周崇,喻健良,刘润杰,等.多层网孔结构抑爆性能的研究进展.煤矿安全,2004,35(3)：6-8
86. 喻健良,孟伟,王雅杰.多层丝网结构抑制管内气体爆炸的试验.天然气工业,2005,25(6)：116-118
87. 吴征艳,蒋曙光,王兰云,等.多层丝网结构抑制瓦斯爆炸传播的数学模型.工业安全与环保,2006,32(12)：1-3
88. Thomas, G O, Jones A, Edwards M J. Influence of water sprays on explosion development in fuel-air mixtures. Combustion Science and Technology,1991,80(1-3):47-61
89. Grant G, Brenton J, Drysdale D. Fire suppression by water sprays. Progr Energy Combust Sci.,2000,26: 79-130
90. 陆守香,何杰,于春红,等.水抑制瓦斯爆炸的机理研究.煤炭学报,1998,23(4)：417-421
91. Qin Y H, Shen Z W, Lu S X, et al. Experimental study of the effect of water sprays on gas flames propagation. Journal of Safety and Environment,2001,1(1):27-29
92. Acton M R, Sutton P, Wickens M J. Lessons for cycle safety management. Symposium Series NO. UK: IChemE, Rugby,1990:122
93. Thomas G O. On the conditions required for explosion migration by water sprays. Institution of Chemical Engine Trans Ichem E Part B,2000,78:9
94. Kees Wingerden, Brian Wilkins. The influence of water sprays on gas explosions.Part:water-spray-generated turbulence. Loss Prevention Process Ind,1995,8(2):54
95. Ndubizu C C, Ananth R, Tatem P A, et al. On water mist fire suppression mechanisms in a gaseous diffusion flame. Fire Safety Journal,1998,31:253-276
96. Sapko M J, Furno A L, Kuchta J M, Quenching methane-air ignitions with water sprays. Report of Investigations RI-8214 (US Department of Interior),1977:1-10
97. Shimizu H, Tsuzuki M, Yamazaki Y, et al. Experiments and numerical simulation on methane flame quenching by water mist. Journal of Loss Prevention in the Process Industries,2001,14:603-608
98. Parra T, Castro F, Mendez C, et al. Extinction of premixed methane-air flames by water mist. Fire Safety Journal,2004,39:581-600
99.刘暄亚,陆守香,秦俊.水雾作用下气体爆炸火焰传播的实验研究.火灾科学,2003,12(1)：11-17
100.刘暄亚,陆守香,秦俊.水雾抑制气体爆炸火焰传播的实验研究.中国安全科学学报,2003,13(8)：71-77
101.刘暄亚.水雾作用下甲烷/空气层流预混火焰燃烧特性研究.合肥：中国科技大学,2006：1-100
102.秦友花.甲烷、煤尘混杂爆炸及水雾抑制的实验与理论研究.淮南：淮南工业学院,1999：1-100
103.谢波,范宝春,王克全.大型通道中被动式水雾抑爆效果的实验研究.实验力学,2002,17(4)：511-516
104.谢波,范宝春,夏自柱,等.大型通道中主动式水雾抑爆现象的实验研究.爆炸与冲击,2003,23(2)：151-156
105. Jingfang Ye, Zhihua Chen, Baochun Fan. Suppression of methane explosions in a field-scale pipe. Journal of Loss Prevention in the Process Industries,2005,18:89-95
106. Zheng R, Bray K C, Rogg B. Effect of sprays of water and NaCl-water solution on the extinction of laminar premixed methane-air counterblow flames. Combustion Science and Technology,1997,126(1-6):389-401
107.陈晓坤,林滢,罗振敏.水系抑制剂控制瓦斯爆炸的实验研究.煤炭学报,2006,31(5)：603-606
108.林滢.瓦斯爆炸水系抑制剂的实验研究.西安：西安科技大学,2006：1-100
109.王伟,毋林元.一种治理煤矿瓦斯气的液体及装置.中国专利：1594837.2005-3-16
110.张喜平,刘振海,李云堂.一种预防瓦斯爆炸的液体.中国专利：1483493.2004-3-24
111.刘长飞.煤矿瓦斯防爆降尘阻化剂-中国专利：1746261,2006-3-15
112. Ediz I G, Seyfettinoglu M A, Dixon-Hardy D W. Environmental issues and waste management in energy and mineral production, Proceedings of the International Symposium on Environmental Issues and Waste Management in Energy and Mineral Production,5th. Ankara:Balkema, Rotterdam, Neth,1998:375-379
113.蒋宝城,张永春,周锦霞,等.天然气吸附剂研究进展.化工进展,2007,26(5)：632-635
114. Isabel A A C, Esteves, Marta S S, et al. Adsorption of natural gas and biogas components on activated carbon. Separation and Purification Technology,2008,62:281-296
115.徐文东,华贲,陈进富.吸附天然气技术研究进展及发展前景.天然气工业,2006,26(6)：127-131
116.傅国旗,周理.甲烷在活性炭上吸附等温线的测定及分析.天然气工业,2004,24(1)：92-96
117.张淮浩,陈进富,郭绍辉,等.原料组成对石油焦基天然气吸附剂性能的影响.天然气工业,2007,27(4)：104-109
118. Ya ping Zhou, Yuxin Wang, Haihua Chen, et al. Methane storage in wet activated carbon:Studies on the charging/discharging process. Carbon,2005,43:2007-2012
119. Lozano-Castello'D, Cazorla-Amoro's D, Linares-Solano A. Influence of pore size distribution on methane storage at relatively low pressure:preparation of activated carbon with optimum pore size. Carbon,2002, 40:989-1002
120. Alcaniz-Monge J. Methane storage in activated carbon fibres. Carbon,1997,35 (2):291-297
121. Feng bo Li, Qingli Qian, Shufeng Zhang, et al. Porous silicon carbide/carbon composite microspherules for methane storage. Journal of Natural Gas Chemistry,2007,16:363-370
122.温兴宏,马东民.甲烷吸附材料的制备与性能研究.中国煤层气,2007,4(2)：33-36
123.魏文英,方键,孔海宁,等.金属有机骨架材料的合成及应用.化学进展,2005,17(6)：1110-1115
124.武凯.对煤层气(甲烷)有吸附选择性的材料制备及其吸附性能研究.重庆：重庆大学,2006：1-100
125.周子娥,薛春瑜,阳庆元,等.新型储甲烷金属-有机骨架材料的设计.化学学报,2009,67(6)：477-482
126.刘秀伍.有序介孔材料吸附功能研究.天津：天津大学,2005：1-100
127. Xiuwu Liu, Jingwen Li, Li Zhou, et al. Adsorption of CO2, CH4 and N2 on ordered mesoporous silica molecular sieve. Chemical Physics Letters,2005,415:198-201
128. Xiuwu Liu, Li Zhou, Jingwen Li, et al. Methane sorption on ordered mesoporous carbon in the presence of water. Carbon,2006,44:1386-1392
129. Xiuwu Liu, Li Zhoua, Xin Fu, et al. Adsorption and regeneration study of the mesoporous adsorbent SBA-15 adapted to the capture/separation of CO2 and CH4. Chemical Engineering Science,2007,62:1101-1110
130. Piresa J, Araujo A C, Carvalhoa A P, et al. Porous materials from clays by the gallery template approach: synthesis, characterization and adsorption properties. Microporous and Mesoporous Materials,2004,73: 175-180
131. Winsor P A. Solvent properties of amphiphilic compounds. London:Butterworths Scientific Publications, 1954:1-207
132. McBain M E L. Solubilization and related phenomena. New York:Academic Press,1955:1-259
133. Elworthy P H, Florence A T, Macfarlane C B. Solubilization by surface-active agents and its applications on chemistry and the biological sciences. London:Chapman & Hall,1968:1-335
134. Tanford C. The hydrophobic effect. New York:Wiley,1973:1-200
135. Naim B A, Wilf J. Solubilization of paraffin gases in aqueous solution of sodium octanoate. Journal of Solution Chemistry,1983,12(9):671-683
136. Naim B A, Battino R. Solubilization of methane, ethane, propane and n-butane in aqueous solution of solutions of sodium dodecylsulfate. Journal of Solution Chemistry,1985,14(14):245-253
137. Matheson I B C, King A D. Solubility of gases in micellar solutions. J. Colloid. Interface. Sci.,1978,66(3):
464-469
138. Bolden P L, Hoskins J C, King A D. The solubility of gases in solutions containing alkylsulfates of various chain lengths. J. Colloid. Interface. Sci.,1983,91 (2):455-463
139. Prapaitrakul W, King A D. The solubility of gases in solutions of decyltrimenthyl and cetyltrimethylammonium bromide. J. Colloid. Interface. Sci.,1985,106(1):186-193
140. Prapaitrakul W, King A D. The solubility of gases in solutions of sodium 1-heptanesulfonate and sodium perfluorooctanoate. J. Colloid. Interface. Sci.,1986,112(2):387-395
141. Prapaitrakul W, Shwikhat A, King A D, The influence of pH on gas solubilities in aqueous solutions of sodium octanoate at 25℃. J. Colloid. Interface. Sci.,1987,115(2):443-449
142. Prapaitrakul W, King A D. The solubility of gases in solutions of lithium perfluorooctanoate and lithium perfluorodecanoate. J. Colloid. Interface. Sci.,1987,118(1):224-232
143. King A D. Solubilization of gases by polyethoxylated nonyl phenols. J. Colloid. Interface. Sci.,1990, 137(2):577-582
144. King A D. Solubilization of gases by polyethoxylated lauryl alcohols. J. Colloid. Interface. Sci.,1992, 148(1):142-147
145. Radwan N, King A D. Solubilization of gases by polyethoxylated octyl phenols. J. Colloid. Interface. Sci., 1997,194:120-126
146. Roy S, Mehra A, Bhowmick D. Prediction of solubility of nonpolar gases in micellar solutions of ionic surfactants. J. Colloid. Interface. Sci.,1997,196:53-61
147. Hai, M T, Han B X, Yang G Y, et al. Effect of NaCl, NaOH, and Poly(ethylene oxide) on methane solubilization in sodium dodecyl sulfate solutions. Langmuir,1999,15:1640-1643
148. Mukerjee P. Odd-even alternation in the chain length variation of micelle properties.Kolloid Z. Z.Polym., 1970,236:76-79
149. Wilhelm E, Battino R, Wilcock R J. Low pressure solubility of gases in liquid Water. Chem. Rev.,1977, 77(2):219
150. Lannung A, Gjaldbaek J. The Solubility of methane in hydrocarbons,alcohols,water and other solvents. Acta. Chem. Scand.,1960,14:1124
151. Makranczy J, Megyery-Balog K, Rusz L, et al. The solubility of methane in hydrocarbons. Hung. J. Ind. Chem.,1976,4:269
152. Kobatake Y, Hildebrand J H.Solubility and entropy of solution of He,N2,Ar,O2,CH4,C2H6,CO2 and SF6 in various solvents; Regularity of gas solubility. J. Phys. Chem.,1961,65:331
153. King JR. The solubility of gases in aqueous solutions of polyethylene glycol. J. Colloid. Interface. Sci.,1991, 144(2):579-585
154. King JR., The solubility of gases in aqueous solutions of Poly (propylene glycol). J. Colloid. Interface. Sci., 2001,243:457-462
155. Jo¨nsson B, Wennerstrom H. Thermodynamics of ionic amphiphil-water system. J. Colloid Interface Sci., 1981,80:482
156. Miller K W, Hammond L, Porter E G The solubility of hydrocarbon gases in lipid bilayers. Chemistry and Physics of Lipids,1977,20:229-241
157.王永华.顶空气相色谱分析原理与技术.中国环境监测,2006,22(2)：7-13
158.郭威,王少云.顶空气相分析技术及其应用.食品与药品,2007,9(10A)：47-50
159.刘虎威.气相色谱方法及应用(第二版).北京：化学工业出版社,2007：124-165
160.汪正范.色谱定性与定量.北京：化学工业出版社,2007：1-100
161.赵景红,王海龙,刘文民,等.改变相比/顶空气相色谱法测定变压器油中溶解气体的分配常数.色谱, 2004,24(3)：193-196
162.蒋兵.阴非混合表面活性剂增溶洗脱PAHs的作用及机理研究.兰州：兰州交通大学,2007：1-100
163.章建民,孟志刚.某些两性表面活性剂结构与性能的研究.上海大学学报(自然科学版),1998,4(6)：703-706
164. Edwards D A, Luthy R G, Liu Z B. Solubilization of polycyclic aromatic hydrocarbons in micellar nonionic surfactant solutions. Environ. Sci. Technol.,1991,25:127-133
165.冯少良.混合表面活性剂对多环芳烃的增溶作用机理及影响因素.杭州：浙江大学,2003：1-100
166.高士祥.环糊精和表面活性剂对有机污染物的增溶及在土壤修复中的应用研究.南京：南京大学,1999：1-100
167. Javert C T. Sediment-and saturated-soil-associated reactions involving an anionic surfactant (dodecylsulfate): partion of PAH compounds among phases. Environ Sci Technol,1991,25:1039
168.金谷.表面活性剂化学.合肥：中国科学技术大学出版社,2008：1-400
169.赵国玺.表面活性剂作用原理.北京：中国轻工业出版社,2003：1-500
170. Nicoli D F, Debuzzaccarini F, Romsted L S, et al. The concept that large colloidal particles of ionic surfactant present at high salinities are aggregates of small micelles has recently received support from light scattering experiments involving oil/water microemulsion. Chem.Phys.Lett.,1981,80:422
171.吴顺年,范会梅,王连生.表面活性剂及助溶剂对环境污染物蕙的增溶作用.环境科学技术,1996,(4)：1-4
172.朱利中,,冯少良.混合表面活性剂对多环芳烃的增溶作用及机理.环境科学学报,2002,22(6)：774-778
173.巩育军,薛元英.正负离子表面活性剂混合溶液的增溶作用.西北大学学报(自然科学版),2000,30(1)：28-31
174.张志庆,徐桂英,叶繁,等.十二烷基甜菜碱/十二烷基硫酸钠复配体系的表面活性.物理化学学报,2001,17(12)：1122-1125
175.赵红芳,杨亚玲,刘东辉,等.阴离子-两性离子表面活性剂复配体系及NaCl对其表面活性的影响.应用化工,2006,35(7)：535-537
176.张雪勤,蔡怡,杨亚江.两性离子/阴离子表面活性剂复配体系协同作用的研究.胶体与聚合物,2002,20(3)：1-5
177.赵国玺.表面活性剂作用原理.北京：中国轻工业出版社,2003：618-621
178. Todorov P D, Kralchevsky P A, Denkov N D, et al. Kinetics of solubilization of n-decane and benzene by micellar solutions of sodium dodecyl sulfate. Journal of Colloid and Interface Science,2002,245:371-382
179. Shah R, Neogi P. Interfacial resistance in solubilization kinetics. Journal of Colloid and Interface Science, 2002,253:443-454
180. Chen B H, Clarence A, Peter R. Rates of solubilization of triolein into nonic surfactant solutions. Colloid and surfaces A,1997,128:129-143
181.崔正刚,殷福珊.微乳化技术及应用.北京：中国轻工业出版社,1999：188
182.李方,李千佐,汪汉卿.荧光和动态光散射方法研究两性表面活性剂胶束的聚集和相互作用.高等学校化学学报,1998,19(7)：1117-1120
183.祝荣先,靳志强,张路,等.稳态荧光探针研究Guerbet醇聚氧乙烯醚羧酸钠的聚集行为.感光科学与光化学,2006,24(2)：110-117
184.吴丹.阳离子Gemini型表面活性剂与蛋白质的相互作用.济南：山东大学,2007：1-100
185.郑少君,袁钊,曾毅.芘和蒽作为荧光探针探测树枝形聚合物微环境.物理化学学报,2008,24(10)：1785-1789
186.胡惠龄,许虎君.荧光探针法研究N-月桂酰基-N’-羟乙基乙二胺乙酸盐的微极性.光谱实验室,2008,
25(5)：792-795
187.李东旭,许潇,李娜,等.时间分辨荧光技术与荧光寿命测量.大学化学,2008,24(4)：1-11
188.房喻,王辉.荧光寿命测定的现代方法与应用.化学通报,2001,(10)：631-636
189.王晓春.离子型疏水缔合聚合物溶液的增粘稳粘研究.江汉石油科技,2007,17(4)：19-23
190.闫鸣艳,李八方,赵雪.芘荧光探针法研究鳕鱼皮胶原蛋白临界聚集质量浓度.精细化工,2009,26(2)：182-186
191.霍霄鹏,许春建,张丹.水溶液中甲苯分散相增强难溶气体吸收.化学工业与工程,2006,23(4)：291-296
192.刘新爱.石灰浆荷电雾化脱硫中雾滴吸收SO2的传质机理研究.南京：江苏大学,2007：1-100
193. Huang H L, Lee W M G. Enhanced naphthalene solubility in the presence of sodium dodecyl sulfate:effect of critical micelle concentration. Chemosphere,2001,44:963-972
194.程世贤,龚福忠,吴家文.Span80的水解与液膜溶胀的关系.广西大学学报(自然科学版),2001,26(3)：175-178
195. Chai J L, Mu J H. Effects of various additives on the cloud point of dodecyl polyoxyethylene polyoxypropylene ether. Colloid J,2002,64(5):550-555
196. Musarat J, Aijaz A D, Adil A, et al. Clouding behavior of nonionic-cationic and nonionic-anionic mixed surfactant systems in presence of carboxylic acids and their sodium salts. Colloid Polym Sci,2007,285: 631-640
197.孙静静.瓦斯吸附控制系统的设计与雾化实验研究.北京：中国矿业大学(北京),2009：44-54
198.关国强.运动微液滴表面瞬态传质研究.成都：四川大学,2004：1-100
2. 煤矿安全生产现状分析[EB/OL].http://www.hbsafetv.com.cn/article/12/241/389/200711/35094.shtmL.2007-11-7
3. 林柏泉,崔恒信.矿井瓦斯防治理论与技术.徐州：中国矿业大学出版社,1998：1-200
4. 徐梓铭,刘然,刘志坚.煤矿瓦斯爆炸的条件与预防措施.煤炭科技,2007,(3)：67-50
5. 胡千庭,蒋时才,苏文叔.我国煤矿瓦斯灾害防治对策.矿业安全与环保,2000,27(1)：1-5
6. 赵铁锤.搞好瓦斯抽放利用促进煤矿安全生产.中国煤层气,2005,2(2)：3-5
7. 李国彪.充分发挥监测装置作用确保高瓦斯矿井安全生产.矿业安全与环保,2004,31(6)：63-65
8. 许石青,吴华帮.煤与瓦斯突出预测方法研究现状与进展.矿业快报,2008,(5)：21-24
9. 孙文标,刘辉,赵宏伟.煤层注水在煤矿安全中的应用及效果浅析.煤矿安全,2004,35(12)：24-25
10. 张永吉,李占德,秦伟瀚,等.煤层注水技术.北京：煤炭工业出版社,2001：1-300
11. 王惠宾,汪远东,卢平.煤层注水中添加湿润剂的研究.煤炭学报,1994,14(4)：151-160
12. 彭起文.粉尘防治技术最新进展.矿业安全与环保,1999,24(1)：42-45
13. 傅贵.煤体预湿机理及注水防尘技术研究.北京：中国矿业大学北京研究生部,1994：1-100
14. 张永吉,李占德,秦伟瀚,等.煤层注水技术.北京：煤炭工业出版社,2001：1-12
15. 张保勇,吴强.表面活性剂在瓦斯水合物生成过程中动力学作用.中国矿业大学学报,2007,36(4)：478-451
16. WU Qiang, HE Xue-qiu. Preventing coal and gas outburst using methane hydration. Journal of China University of Mining & Technology,2003,13 (1):7-10
17. 江传力,张国宏,吴强,等.在井下温度合成瓦斯水合物的实验.黑龙江科技学院学报,2004,14(4)：203-205
18. 吴强,李成林,江传力.瓦斯水合物生成控制因素探讨.煤炭学报,2005,30(3)：283-287
19.吴强.煤层瓦斯水合机理实验研究.徐州：中国矿业大学,2005：1-100
20.吴强,张保勇,王永敬.瓦斯水合物分解热力学研究.北国矿业大学学报,2006,35(5)：658-661
21. 吴强,张保勇.表面活性剂在瓦斯水合中的作用机理.煤炭学报,2006,31(6)：716-720
22. 赵建忠,石定贤,赵阳升.喷射方式下表面活性剂对水合物生成实验研究.天然气工业,2007,27(1)：114-117
23. 韩小辉,王胜杰,陈孝彦,等.表面活性剂加速天然气水合物生成实验研究.天然气工业,2002,22(5)：90-92
24. 胡汉华,刘道平,谢应明,等.喷雾反应器中表面活性剂对制备天然气水合物的影响.齐鲁石油化工,2006,34(3)：256-257
25.秦宪礼,吴强,张保勇.十二烷基硫酸钠对甲烷水合物生成过程影响研究.化学通报,2006,(7)：519-523
26. Gayeta P, Dicharrya C, Mariona G, et al. Experimental determination of methane hydrate dissociation curve up to 55MPa by using a small amount of surfactant as hydrate promoter. Chemical Engineering Science, 2005,60:5751-5758
27. Zhong Y, Rogers R E. Surfactant effects on gas hydrates formation. Chemical Engineering Science,2000,5 (19):4175-4187
28. 章春笋,樊栓狮,郑新.非离子表面活性剂对天然气水合物形成过程的影响.天然气与石油,2003,21(3)：31-35
29.赵义,丁静,杨晓西.天然气水合物及其生成促进与抑制研究进展.天然气工业,2004,24(12)：132-135
30.章春笋,樊栓狮,郭彦坤,等.不同类型表面活性剂对天然气水合物形成过程的影响.天然气工业,2002,23(1)：91-97
31.孙志高,郭开华,樊栓狮.天然气水合物形成促进技术实验研究.天然气工业,2004,24(12)：41-46
32. 孙志高,樊栓狮.气体水合物生成特性实验研究.科学技术与工程,2006,23(6)：4798-4800
33. Khokhar A A, Gudmundsson J S, Sloan E D. Gas storage in structure hydrates. Fluid Phase Equilibria,1998, 150-151:383-392
34. Ganji H, Manteghian M, Szadeh K, et al. Effect of different surfactants on methane hydrates formation rate stability and storage capacity. Flue,2007,86:434-441
35. Ganandran N, Amin R. The effect of hydrotropes on gas hydrates formation. J Pet Sci Eng,2003,40:37-46
36. Zhang C S, Fan S S, Liang D Q, et al. Effect of additives on formation of natural gas hydrates. Fuel,2004, 83:2115-2121
37. Karaaslan U, Uluneye E, Parlaktuna M. Effect of an anionic surfactant on different type of hydrate structures. Journal of Petroleum Science and Engineering,2002,35:49-57
38. Link D D, Ladner E P, Elsen H A, Formation and dissociation studies for optimizing the uptake of methane by methane hydrates. Fluid Phase Equilibrium,2003,211:1-10
39. 肖普朝.煤层延化防突的机理与实践.煤炭工程师,1994,(4)：16-21
40. 岳之学.固化防突技术原理及其应用.江西煤炭科技,1998,(4)：37-39
41. 陈金玉.固化防突材料的开发与应用.中州煤炭,1997(2)：37-39
42. 张超英,肖普朝,陈金玉,等.应用固化液防止煤与瓦斯突出的理论与实践.煤炭学报,1995, (增刊)：70-76
43.刘泽功,孙家斌,李伟.松软煤层固化防突技术与实践.1998,26(3)：33-35
44. 徐西亮.石门揭煤固化防突技术.陕西煤炭,2006,(3)：37-38
45. Hanson R S, Hanson T E. Methanotrophic bacteria. Microbiol. Rev,1996,60(2):439-471
46. Martin Kru¨ger, Tina Treude, Heike Wolters, et al. Microbial methane turnover in different marine habitats. Colloids and Surfaces A:Physicochem. Eng. Aspects,2006,273:117-120
47.柯为.治理煤矿瓦斯爆炸的微生物生物技术.生物工程学报,2005,21(3)：460
48. 王璐,金龙哲.利用微生物技术治理煤矿瓦斯的研究展望.中国安全科学学报,2005,15(10)：97-99
49. 陈东科,王璐,金龙哲.利用微生物技术治理煤矿瓦斯的研究展望.矿业安全和环保,2005,32(6)：49-50
50. 陈东科,王璐,金龙哲.微生物降解煤矿瓦斯的研究.煤炭学报,2006,31(5)：607-609
51. 侯晨涛,王生全,聂文杰,等.微生物技术治理煤矿瓦斯的初步研究,矿业安全和环保,2008,35(2)：11-14
52. 费国云,周奠邦.新型隔爆棚抑制弱爆炸的研究.煤炭工程师,1998,(3)：7-9
53.王云海,何学秋,王恩元.煤矿隔爆棚隔爆作用分析.江苏煤炭,2003,(1)：30-32
54. 蔡东红,杜贤流.矿井隔爆水袋棚实用安装方法探讨.煤矿安全,2003,33(3)：52-53
55. 蔡周全.MGS型密封式隔爆水袋的研究.矿业安全与环保,2004,6：11-14
56. Daniel N, Michael S, Aldo F. Coal dust and gas explosion suppression by barriers. ASTM:Special Technical Publication,1987:958
57. Ewan B C R, Moatamedi M. The study of induced water flow devices in the suppression of gas explosions. Process Safety and Environmental Protection,2002,80(B3):126-134
58. Hideo T, Takeshi H, Ikuhide T. Suppression of methane explosion by Halon 1301. Saiko to Hoan,1981, 27(6):281-290
59. Hideo T, Takeshi H, Ikuhide T. Suppression of explosion of methane gas by halon (CF3Br). Nippon Kogyo Kaishi,1982,98:1007-1009
60. 崔德润.利用惰性气体缩短火区封闭时间.煤矿安全,1993,(5)：58-61
61. 驹井武,杜立华.关于惰性气体与泡沫组合灭火技术的研究.煤炭技术,1990,(4)：29-34
62. Hideo O, Shinsuke N. Experimental study on inhibition effect of CF3I over methane/air combustion in an explosion vessel. Nihon Nensho Gakkaishi,2002,44(129):166-170
63. 邱雁,高广伟,罗海珠.充注惰气抑制矿井火区瓦斯爆炸机理.煤矿安全,2003,34(2)：8-11
64. Lisochkin Y A, Poznyak V I. Inserting of methane-air mixtures by compositions based on carbon dioxide and nitrogen with additions of halocarbons. Fizika Goreniyai Vzryva,2005,41(5):23-28
65. Martin H, Kenneth L, Charles P. Inhibition and extinction of coal dust and methane explosions. Pittsburgh: Res. Cent. Rep. Invest.-U. S., Bur. Mines,1982:1-33
66. Martin H, Kenneth L, Isaac Z, et al. Symposium (International) on Combustion. Pittsburgh:Res. Cent., Bur. Mines,1984,20:1691-1700
67. Ryzhkov V S, Krasnyanskii M E, Koshcheev, G Q et al. Agent for preventing methane and coal dust explosion in mines. SU 977822,1982-11-30
68. Amyotte P R, Mintz K J, Pegg M J. Effect of rock dust particle size on suppression of coal dust explosions. Process Safety and Environmental Protection,1995,73(B2):89-100
69. Datsenko D F, Kuprienok P A, Gryadushchii B A, et al. Powder for suppressing explosion of methane-air mixtures. SU 1460331,1986-12-22
70. Datsenko D F, Kuprienok P A, Zabuga V Ya, et al. Agent for inhibiting explosion of methane-air mixtures. SU 1244344,1986-07-15
71. Glazkova A P. Inhibition of methane-air mixtures and the problem of the safety of explosives. Kinetikai Kataliz,1971,12(1):16-20
72. Datsenko D F, Zabuga V Ya, Dolinskaya L P, et al. Heat-absorbing properties of explosion-suppressing powders. Zhurnal Prikladnoi Khimii,1982,55(3):595-598
73. Corecki J, Szkred T. Influence of inorganic additives on explosion hazard of a coal dust. Proceedings of the Shenyang international symposium on dust explosions, China:Combustion Inst,1987:528-538
74. Amyotte P R, Mintz K J, Pegg M J. Effect of rock dust particle size on suppression of coal dust explosions. Process Safety and Environmental Protection,1995,73(B2):89-100
75. Laffitte P, Bouchet R. Suppression of explosion wave in gaseous mixtures by means of fine powders. In:7th Symposium (International) on Combustion. Pittsburgh. London:Combustion Inst,1959:504-508
76. Kauffman C, Wolanski P, Arisoy A, et al. Dust, hybrid, and dusty detonations. In:Dynamics of shock wave, explosion and defonations, Progress in astronauties and aeronautics. New York:AIAA,1984:100
77. Krasnyansky M. Prevention and suppression of explosions in gas-air and dust-air mixtures using powder aerosol-inhibitor. Journal of Loss Prevention in the Process Industries,2006,19:729-735
78.董刚,邱榕,蒋勇,等.惰性颗粒抑制CH4/O2/N2爆炸过程的二维数值模拟与实验验证.燃烧科学与技术,2005,11(4)：329-335
79. Dong G, Fan B C, Xie B, et al. Experimental investigation and numerical validation of explosion suppression by inert particles in large-scale duct. Proceedings of the Combustion Institute. China:Elsevier,2004,30(Pt. 2):2361-2368
80. 张辉.矿井瓦斯爆炸控制材料的实验研究.西安：西安科技大学,2005：1-100
81. 苏俊杰.超细无机阻燃材料对瓦斯控爆效能的实验研究.西安：西安科技大学,2006：1-100
82. 黄超.燃爆消减剂的理论与应用基础研究.南京：南京理工大学,2006：1-100
83. 蒋新生,杜扬,高建丰,等.受限空间可燃气体爆炸抑爆实验系统研究.后勤工程学院学报,2007,23(2)：97-104
84. Edwards K L. Material and constructions used in devices to prevent the spread of flames in pipelines and
vessels. Material and Design,1999,20:245-252
85.周崇,喻健良,刘润杰,等.多层网孔结构抑爆性能的研究进展.煤矿安全,2004,35(3)：6-8
86. 喻健良,孟伟,王雅杰.多层丝网结构抑制管内气体爆炸的试验.天然气工业,2005,25(6)：116-118
87. 吴征艳,蒋曙光,王兰云,等.多层丝网结构抑制瓦斯爆炸传播的数学模型.工业安全与环保,2006,32(12)：1-3
88. Thomas, G O, Jones A, Edwards M J. Influence of water sprays on explosion development in fuel-air mixtures. Combustion Science and Technology,1991,80(1-3):47-61
89. Grant G, Brenton J, Drysdale D. Fire suppression by water sprays. Progr Energy Combust Sci.,2000,26: 79-130
90. 陆守香,何杰,于春红,等.水抑制瓦斯爆炸的机理研究.煤炭学报,1998,23(4)：417-421
91. Qin Y H, Shen Z W, Lu S X, et al. Experimental study of the effect of water sprays on gas flames propagation. Journal of Safety and Environment,2001,1(1):27-29
92. Acton M R, Sutton P, Wickens M J. Lessons for cycle safety management. Symposium Series NO. UK: IChemE, Rugby,1990:122
93. Thomas G O. On the conditions required for explosion migration by water sprays. Institution of Chemical Engine Trans Ichem E Part B,2000,78:9
94. Kees Wingerden, Brian Wilkins. The influence of water sprays on gas explosions.Part:water-spray-generated turbulence. Loss Prevention Process Ind,1995,8(2):54
95. Ndubizu C C, Ananth R, Tatem P A, et al. On water mist fire suppression mechanisms in a gaseous diffusion flame. Fire Safety Journal,1998,31:253-276
96. Sapko M J, Furno A L, Kuchta J M, Quenching methane-air ignitions with water sprays. Report of Investigations RI-8214 (US Department of Interior),1977:1-10
97. Shimizu H, Tsuzuki M, Yamazaki Y, et al. Experiments and numerical simulation on methane flame quenching by water mist. Journal of Loss Prevention in the Process Industries,2001,14:603-608
98. Parra T, Castro F, Mendez C, et al. Extinction of premixed methane-air flames by water mist. Fire Safety Journal,2004,39:581-600
99.刘暄亚,陆守香,秦俊.水雾作用下气体爆炸火焰传播的实验研究.火灾科学,2003,12(1)：11-17
100.刘暄亚,陆守香,秦俊.水雾抑制气体爆炸火焰传播的实验研究.中国安全科学学报,2003,13(8)：71-77
101.刘暄亚.水雾作用下甲烷/空气层流预混火焰燃烧特性研究.合肥：中国科技大学,2006：1-100
102.秦友花.甲烷、煤尘混杂爆炸及水雾抑制的实验与理论研究.淮南：淮南工业学院,1999：1-100
103.谢波,范宝春,王克全.大型通道中被动式水雾抑爆效果的实验研究.实验力学,2002,17(4)：511-516
104.谢波,范宝春,夏自柱,等.大型通道中主动式水雾抑爆现象的实验研究.爆炸与冲击,2003,23(2)：151-156
105. Jingfang Ye, Zhihua Chen, Baochun Fan. Suppression of methane explosions in a field-scale pipe. Journal of Loss Prevention in the Process Industries,2005,18:89-95
106. Zheng R, Bray K C, Rogg B. Effect of sprays of water and NaCl-water solution on the extinction of laminar premixed methane-air counterblow flames. Combustion Science and Technology,1997,126(1-6):389-401
107.陈晓坤,林滢,罗振敏.水系抑制剂控制瓦斯爆炸的实验研究.煤炭学报,2006,31(5)：603-606
108.林滢.瓦斯爆炸水系抑制剂的实验研究.西安：西安科技大学,2006：1-100
109.王伟,毋林元.一种治理煤矿瓦斯气的液体及装置.中国专利：1594837.2005-3-16
110.张喜平,刘振海,李云堂.一种预防瓦斯爆炸的液体.中国专利：1483493.2004-3-24
111.刘长飞.煤矿瓦斯防爆降尘阻化剂-中国专利：1746261,2006-3-15
112. Ediz I G, Seyfettinoglu M A, Dixon-Hardy D W. Environmental issues and waste management in energy and mineral production, Proceedings of the International Symposium on Environmental Issues and Waste Management in Energy and Mineral Production,5th. Ankara:Balkema, Rotterdam, Neth,1998:375-379
113.蒋宝城,张永春,周锦霞,等.天然气吸附剂研究进展.化工进展,2007,26(5)：632-635
114. Isabel A A C, Esteves, Marta S S, et al. Adsorption of natural gas and biogas components on activated carbon. Separation and Purification Technology,2008,62:281-296
115.徐文东,华贲,陈进富.吸附天然气技术研究进展及发展前景.天然气工业,2006,26(6)：127-131
116.傅国旗,周理.甲烷在活性炭上吸附等温线的测定及分析.天然气工业,2004,24(1)：92-96
117.张淮浩,陈进富,郭绍辉,等.原料组成对石油焦基天然气吸附剂性能的影响.天然气工业,2007,27(4)：104-109
118. Ya ping Zhou, Yuxin Wang, Haihua Chen, et al. Methane storage in wet activated carbon:Studies on the charging/discharging process. Carbon,2005,43:2007-2012
119. Lozano-Castello'D, Cazorla-Amoro's D, Linares-Solano A. Influence of pore size distribution on methane storage at relatively low pressure:preparation of activated carbon with optimum pore size. Carbon,2002, 40:989-1002
120. Alcaniz-Monge J. Methane storage in activated carbon fibres. Carbon,1997,35 (2):291-297
121. Feng bo Li, Qingli Qian, Shufeng Zhang, et al. Porous silicon carbide/carbon composite microspherules for methane storage. Journal of Natural Gas Chemistry,2007,16:363-370
122.温兴宏,马东民.甲烷吸附材料的制备与性能研究.中国煤层气,2007,4(2)：33-36
123.魏文英,方键,孔海宁,等.金属有机骨架材料的合成及应用.化学进展,2005,17(6)：1110-1115
124.武凯.对煤层气(甲烷)有吸附选择性的材料制备及其吸附性能研究.重庆：重庆大学,2006：1-100
125.周子娥,薛春瑜,阳庆元,等.新型储甲烷金属-有机骨架材料的设计.化学学报,2009,67(6)：477-482
126.刘秀伍.有序介孔材料吸附功能研究.天津：天津大学,2005：1-100
127. Xiuwu Liu, Jingwen Li, Li Zhou, et al. Adsorption of CO2, CH4 and N2 on ordered mesoporous silica molecular sieve. Chemical Physics Letters,2005,415:198-201
128. Xiuwu Liu, Li Zhou, Jingwen Li, et al. Methane sorption on ordered mesoporous carbon in the presence of water. Carbon,2006,44:1386-1392
129. Xiuwu Liu, Li Zhoua, Xin Fu, et al. Adsorption and regeneration study of the mesoporous adsorbent SBA-15 adapted to the capture/separation of CO2 and CH4. Chemical Engineering Science,2007,62:1101-1110
130. Piresa J, Araujo A C, Carvalhoa A P, et al. Porous materials from clays by the gallery template approach: synthesis, characterization and adsorption properties. Microporous and Mesoporous Materials,2004,73: 175-180
131. Winsor P A. Solvent properties of amphiphilic compounds. London:Butterworths Scientific Publications, 1954:1-207
132. McBain M E L. Solubilization and related phenomena. New York:Academic Press,1955:1-259
133. Elworthy P H, Florence A T, Macfarlane C B. Solubilization by surface-active agents and its applications on chemistry and the biological sciences. London:Chapman & Hall,1968:1-335
134. Tanford C. The hydrophobic effect. New York:Wiley,1973:1-200
135. Naim B A, Wilf J. Solubilization of paraffin gases in aqueous solution of sodium octanoate. Journal of Solution Chemistry,1983,12(9):671-683
136. Naim B A, Battino R. Solubilization of methane, ethane, propane and n-butane in aqueous solution of solutions of sodium dodecylsulfate. Journal of Solution Chemistry,1985,14(14):245-253
137. Matheson I B C, King A D. Solubility of gases in micellar solutions. J. Colloid. Interface. Sci.,1978,66(3):
464-469
138. Bolden P L, Hoskins J C, King A D. The solubility of gases in solutions containing alkylsulfates of various chain lengths. J. Colloid. Interface. Sci.,1983,91 (2):455-463
139. Prapaitrakul W, King A D. The solubility of gases in solutions of decyltrimenthyl and cetyltrimethylammonium bromide. J. Colloid. Interface. Sci.,1985,106(1):186-193
140. Prapaitrakul W, King A D. The solubility of gases in solutions of sodium 1-heptanesulfonate and sodium perfluorooctanoate. J. Colloid. Interface. Sci.,1986,112(2):387-395
141. Prapaitrakul W, Shwikhat A, King A D, The influence of pH on gas solubilities in aqueous solutions of sodium octanoate at 25℃. J. Colloid. Interface. Sci.,1987,115(2):443-449
142. Prapaitrakul W, King A D. The solubility of gases in solutions of lithium perfluorooctanoate and lithium perfluorodecanoate. J. Colloid. Interface. Sci.,1987,118(1):224-232
143. King A D. Solubilization of gases by polyethoxylated nonyl phenols. J. Colloid. Interface. Sci.,1990, 137(2):577-582
144. King A D. Solubilization of gases by polyethoxylated lauryl alcohols. J. Colloid. Interface. Sci.,1992, 148(1):142-147
145. Radwan N, King A D. Solubilization of gases by polyethoxylated octyl phenols. J. Colloid. Interface. Sci., 1997,194:120-126
146. Roy S, Mehra A, Bhowmick D. Prediction of solubility of nonpolar gases in micellar solutions of ionic surfactants. J. Colloid. Interface. Sci.,1997,196:53-61
147. Hai, M T, Han B X, Yang G Y, et al. Effect of NaCl, NaOH, and Poly(ethylene oxide) on methane solubilization in sodium dodecyl sulfate solutions. Langmuir,1999,15:1640-1643
148. Mukerjee P. Odd-even alternation in the chain length variation of micelle properties.Kolloid Z. Z.Polym., 1970,236:76-79
149. Wilhelm E, Battino R, Wilcock R J. Low pressure solubility of gases in liquid Water. Chem. Rev.,1977, 77(2):219
150. Lannung A, Gjaldbaek J. The Solubility of methane in hydrocarbons,alcohols,water and other solvents. Acta. Chem. Scand.,1960,14:1124
151. Makranczy J, Megyery-Balog K, Rusz L, et al. The solubility of methane in hydrocarbons. Hung. J. Ind. Chem.,1976,4:269
152. Kobatake Y, Hildebrand J H.Solubility and entropy of solution of He,N2,Ar,O2,CH4,C2H6,CO2 and SF6 in various solvents; Regularity of gas solubility. J. Phys. Chem.,1961,65:331
153. King JR. The solubility of gases in aqueous solutions of polyethylene glycol. J. Colloid. Interface. Sci.,1991, 144(2):579-585
154. King JR., The solubility of gases in aqueous solutions of Poly (propylene glycol). J. Colloid. Interface. Sci., 2001,243:457-462
155. Jo¨nsson B, Wennerstrom H. Thermodynamics of ionic amphiphil-water system. J. Colloid Interface Sci., 1981,80:482
156. Miller K W, Hammond L, Porter E G The solubility of hydrocarbon gases in lipid bilayers. Chemistry and Physics of Lipids,1977,20:229-241
157.王永华.顶空气相色谱分析原理与技术.中国环境监测,2006,22(2)：7-13
158.郭威,王少云.顶空气相分析技术及其应用.食品与药品,2007,9(10A)：47-50
159.刘虎威.气相色谱方法及应用(第二版).北京：化学工业出版社,2007：124-165
160.汪正范.色谱定性与定量.北京：化学工业出版社,2007：1-100
161.赵景红,王海龙,刘文民,等.改变相比/顶空气相色谱法测定变压器油中溶解气体的分配常数.色谱, 2004,24(3)：193-196
162.蒋兵.阴非混合表面活性剂增溶洗脱PAHs的作用及机理研究.兰州：兰州交通大学,2007：1-100
163.章建民,孟志刚.某些两性表面活性剂结构与性能的研究.上海大学学报(自然科学版),1998,4(6)：703-706
164. Edwards D A, Luthy R G, Liu Z B. Solubilization of polycyclic aromatic hydrocarbons in micellar nonionic surfactant solutions. Environ. Sci. Technol.,1991,25:127-133
165.冯少良.混合表面活性剂对多环芳烃的增溶作用机理及影响因素.杭州：浙江大学,2003：1-100
166.高士祥.环糊精和表面活性剂对有机污染物的增溶及在土壤修复中的应用研究.南京：南京大学,1999：1-100
167. Javert C T. Sediment-and saturated-soil-associated reactions involving an anionic surfactant (dodecylsulfate): partion of PAH compounds among phases. Environ Sci Technol,1991,25:1039
168.金谷.表面活性剂化学.合肥：中国科学技术大学出版社,2008：1-400
169.赵国玺.表面活性剂作用原理.北京：中国轻工业出版社,2003：1-500
170. Nicoli D F, Debuzzaccarini F, Romsted L S, et al. The concept that large colloidal particles of ionic surfactant present at high salinities are aggregates of small micelles has recently received support from light scattering experiments involving oil/water microemulsion. Chem.Phys.Lett.,1981,80:422
171.吴顺年,范会梅,王连生.表面活性剂及助溶剂对环境污染物蕙的增溶作用.环境科学技术,1996,(4)：1-4
172.朱利中,,冯少良.混合表面活性剂对多环芳烃的增溶作用及机理.环境科学学报,2002,22(6)：774-778
173.巩育军,薛元英.正负离子表面活性剂混合溶液的增溶作用.西北大学学报(自然科学版),2000,30(1)：28-31
174.张志庆,徐桂英,叶繁,等.十二烷基甜菜碱/十二烷基硫酸钠复配体系的表面活性.物理化学学报,2001,17(12)：1122-1125
175.赵红芳,杨亚玲,刘东辉,等.阴离子-两性离子表面活性剂复配体系及NaCl对其表面活性的影响.应用化工,2006,35(7)：535-537
176.张雪勤,蔡怡,杨亚江.两性离子/阴离子表面活性剂复配体系协同作用的研究.胶体与聚合物,2002,20(3)：1-5
177.赵国玺.表面活性剂作用原理.北京：中国轻工业出版社,2003：618-621
178. Todorov P D, Kralchevsky P A, Denkov N D, et al. Kinetics of solubilization of n-decane and benzene by micellar solutions of sodium dodecyl sulfate. Journal of Colloid and Interface Science,2002,245:371-382
179. Shah R, Neogi P. Interfacial resistance in solubilization kinetics. Journal of Colloid and Interface Science, 2002,253:443-454
180. Chen B H, Clarence A, Peter R. Rates of solubilization of triolein into nonic surfactant solutions. Colloid and surfaces A,1997,128:129-143
181.崔正刚,殷福珊.微乳化技术及应用.北京：中国轻工业出版社,1999：188
182.李方,李千佐,汪汉卿.荧光和动态光散射方法研究两性表面活性剂胶束的聚集和相互作用.高等学校化学学报,1998,19(7)：1117-1120
183.祝荣先,靳志强,张路,等.稳态荧光探针研究Guerbet醇聚氧乙烯醚羧酸钠的聚集行为.感光科学与光化学,2006,24(2)：110-117
184.吴丹.阳离子Gemini型表面活性剂与蛋白质的相互作用.济南：山东大学,2007：1-100
185.郑少君,袁钊,曾毅.芘和蒽作为荧光探针探测树枝形聚合物微环境.物理化学学报,2008,24(10)：1785-1789
186.胡惠龄,许虎君.荧光探针法研究N-月桂酰基-N’-羟乙基乙二胺乙酸盐的微极性.光谱实验室,2008,
25(5)：792-795
187.李东旭,许潇,李娜,等.时间分辨荧光技术与荧光寿命测量.大学化学,2008,24(4)：1-11
188.房喻,王辉.荧光寿命测定的现代方法与应用.化学通报,2001,(10)：631-636
189.王晓春.离子型疏水缔合聚合物溶液的增粘稳粘研究.江汉石油科技,2007,17(4)：19-23
190.闫鸣艳,李八方,赵雪.芘荧光探针法研究鳕鱼皮胶原蛋白临界聚集质量浓度.精细化工,2009,26(2)：182-186
191.霍霄鹏,许春建,张丹.水溶液中甲苯分散相增强难溶气体吸收.化学工业与工程,2006,23(4)：291-296
192.刘新爱.石灰浆荷电雾化脱硫中雾滴吸收SO2的传质机理研究.南京：江苏大学,2007：1-100
193. Huang H L, Lee W M G. Enhanced naphthalene solubility in the presence of sodium dodecyl sulfate:effect of critical micelle concentration. Chemosphere,2001,44:963-972
194.程世贤,龚福忠,吴家文.Span80的水解与液膜溶胀的关系.广西大学学报(自然科学版),2001,26(3)：175-178
195. Chai J L, Mu J H. Effects of various additives on the cloud point of dodecyl polyoxyethylene polyoxypropylene ether. Colloid J,2002,64(5):550-555
196. Musarat J, Aijaz A D, Adil A, et al. Clouding behavior of nonionic-cationic and nonionic-anionic mixed surfactant systems in presence of carboxylic acids and their sodium salts. Colloid Polym Sci,2007,285: 631-640
197.孙静静.瓦斯吸附控制系统的设计与雾化实验研究.北京：中国矿业大学(北京),2009：44-54
198.关国强.运动微液滴表面瞬态传质研究.成都：四川大学,2004：1-100