大气压辉光放电等离子体的产生及灭菌应用
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摘要
大气压辉光放电等离子体技术有着广泛的应用前景。本文旨在通过研究大气压辉光放电等离子体的生成特性,总结出稳定的大气压下辉光放电的产生方法。并对产生的等离子体的灭菌特性进行研究,以便为大气压辉光放电的灭菌应用提供理论依据。
本文首先设计制作了用于大气压下介质阻挡辉光放电的高频高压电源。然后利用这一电源分别进行了平行板结构和同轴电极结构的介质阻挡辉光放电实验。
在平行板电极的大气压辉光放电实验中,不仅详细分析了电压、频率对辉光放电产生的影响因素,还简要分析了工作气体、介质性质和极板间距对产生辉光放电的作用规律。
在同轴电极的辉光放电等离子体实验中,详细讨论了电压、流速、频率等因素对等离子体喷焰产生效果的影响。总结出了有利于辉光放电等离子体产生的放电条件。
最后利用两种电极结构产生的等离子体分别进行了杀菌实验,验证了辉光放电等离子体灭菌的有效性,并总结出一些有关辉光放电等离子体灭菌的初步规律。
Atmospheric pressure glow discharge plasma technology has a broad application prospects. This paper studies the atmospheric pressure glow discharge plasma formation characteristics and summarizes the formation methods of stable glow discharge at atmospheric pressure. We also studied the characteristics of plasma sterilization of glow discharge at atmospheric pressure, to provide a theoretical basis of the application on sterilization.
We first designed a high-frequency high-voltage power source for dielectric barrier discharge (DBD) under atmospheric pressure. Then use this power to conduct parallel plate structure and coaxial electrode structure of the dielectric barrier glow discharge experiment.
In the parallel plate electrode experiment, not only the impact from the power voltage and frequency to glow discharge is detailed analyzed , but we also briefly discussed how the working gas, the barrier characteristic , and the gap distance between the plate electrodes impacts the atmospheric pressure glow discharge.
In the Coaxial electrode experiment, we discussed voltage, flow rate, frequency and other factors which have an effect impact on plasma puff. Summed up the conditions favorable for APGD.
Finally we used the two electrode structure of the plasma to carry out the sterilization experiments. Verified the effectiveness of glow discharge plasma sterilization. Summarized some preliminary laws of glow discharge plasma on sterilization.
本文首先设计制作了用于大气压下介质阻挡辉光放电的高频高压电源。然后利用这一电源分别进行了平行板结构和同轴电极结构的介质阻挡辉光放电实验。
在平行板电极的大气压辉光放电实验中,不仅详细分析了电压、频率对辉光放电产生的影响因素,还简要分析了工作气体、介质性质和极板间距对产生辉光放电的作用规律。
在同轴电极的辉光放电等离子体实验中,详细讨论了电压、流速、频率等因素对等离子体喷焰产生效果的影响。总结出了有利于辉光放电等离子体产生的放电条件。
最后利用两种电极结构产生的等离子体分别进行了杀菌实验,验证了辉光放电等离子体灭菌的有效性,并总结出一些有关辉光放电等离子体灭菌的初步规律。
Atmospheric pressure glow discharge plasma technology has a broad application prospects. This paper studies the atmospheric pressure glow discharge plasma formation characteristics and summarizes the formation methods of stable glow discharge at atmospheric pressure. We also studied the characteristics of plasma sterilization of glow discharge at atmospheric pressure, to provide a theoretical basis of the application on sterilization.
We first designed a high-frequency high-voltage power source for dielectric barrier discharge (DBD) under atmospheric pressure. Then use this power to conduct parallel plate structure and coaxial electrode structure of the dielectric barrier glow discharge experiment.
In the parallel plate electrode experiment, not only the impact from the power voltage and frequency to glow discharge is detailed analyzed , but we also briefly discussed how the working gas, the barrier characteristic , and the gap distance between the plate electrodes impacts the atmospheric pressure glow discharge.
In the Coaxial electrode experiment, we discussed voltage, flow rate, frequency and other factors which have an effect impact on plasma puff. Summed up the conditions favorable for APGD.
Finally we used the two electrode structure of the plasma to carry out the sterilization experiments. Verified the effectiveness of glow discharge plasma sterilization. Summarized some preliminary laws of glow discharge plasma on sterilization.
引文
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[2]M.Laroussi.Nonthermal Decontamination of Biological Media by Atmospheric - PressurePlasma:Review.Analysis and Prospects.2002
[3]徐旭.大气压介质阻挡放电三种模式的电学特征.高电压技术.2006.32(1).63-65
[4]孟月东.低温等离子体灭菌技术.中国医疗器械信息.2004.10(5).4-6
[5]曹金祥.低温等离子体灭菌方法与特点.现代物理知识.2002.11(1).11-12
[6]王锡录.水野彰.一种新灭菌方法的研究.东北师范大学报自然科学版.1999.2.27-30
[7]倪萍.过氧化氢低温等离子灭菌系统的工作原理及使用注意事项.医疗设备信息.2005.50(7).62-74
[8]王新新,芦明泽,蒲以康.空气中大气压下均匀辉光放电的可能性.物理学报.2002.51(12).2778-2784
[9]菅井秀郎.张海波.等离子体工学.第1版.北京.科学出版社.2002.2-10
[10]李成榕,王新新,詹花茂.等离子体表面处理与大气压下的辉光放电.高压电气.2003.39(4).46-48
[11]孙岩洲等.介质阻挡放电杀灭枯草杆菌芽孢的电镜观察.高电压技术.2005.41(1):10-12
[12]Montie T C.Roth J R.2000 IEEE Trans.plasma Sci.28-41
[13]Massines F.Rabehi A.Decomps P.Gadri R.Segur P.Mayoux C.J.Appl.phys.1998.
[14]Takehiko Sato,Akiko Doi,Takuya Urayama,Tatsuyuki Nakatani,and Takashi Miyahara.IEEETansactions on industry applications.2007.43.(5).1159-1165
[15]白希尧,张之涛,白敏东,高气压强放电等离子体学科的行成及应用展望.自然.2000.22(3).156-160
[16]蒲以康等.迈克尔·A 力伯曼等.等离子体放电原理与材料处理.第1版.北京.科学出版社.2007.
[17]甄汉生.等离子体加工技术.第1版.北京.清华大学出版社.1990.5-8
[18]潘应年.等离子体技术在材料中的应用.版1.武汉.湖北科学出版社.2003.12-24
[19]Roth J R.Industrial Plasma Engineering:Vol.2,Institute of Physics Publishing,Bristol andPhiladelphia,2001
[20]杨津基.气体放电.版本.北京.科学出版社.1983.18-26
[21]徐学基.诸定昌.气体放电物理.版本.上海.复旦大学出版社.1996.14-19
[22]Okazaki S.Kogomat M.Ueharat M.et al.Appearance od stable glow discharge in air,argon,oxygen and nitrogen at atmospheric pressure using 50 Hz source.Journal of Applied Physics.1993.26.889-892
[23]方志等.空气中介质阻挡放电大气压辉光放电特性的研究.高压电器.2006.42(2).105-108
[24]A Vongle,R Seeliger,and M Steenback.Zeit Fur Physik.1933.
[25]Kunhartdt E.2000 IEEE Trans.Plasma Sci.2000
[26]王新新等.用50Hz工频电压产生大气压下辉光放电.高电压技术.2002.28(120).39
铩颷27]Thomas C M.Kimberly K W.J Roth OAUGDP for Sterilization of Surface and Materials.IEEETrans plasma SCI.VOL.28.NQ.1.2000
[28]Roth J R.Laroussi.Liu C.1992 Proc.19~(th)IEEE Int.Conf.on plasma Sci.1992
[29]Gadri R B 1999 IEEE Trans.plasma Sci.1999.27-36
[30]Roth J R.Sherman D M and Willkinson S P 1998 AIAA Aerospace Sciences Meeting.RenoNV.1998
[31]Roth J R.Sherman D M and Willkinson S P 2000 AIAA Journal.2000.
[32]Massines F and Gouda G.1999 Proc.Conf.Electrical Insulation and Dielectric phenomena
[33]Massines F.Messaoudi.andMayoux C.Plasmas and Polymers.1998.3(43)
[34]Gherardi N.Martin S and Massines F.J.phys.D:Appl.phys.2000.33
[35]Gat E.Gherardi N.Lemoing S.and Massines F 2000 J.phys.2000 plasma Sources
[36]Vidmar R J 1990 IEEE trans.Plasma Sei.18 733
[37]Gadri R,Rabehi A,Massines F and Segur P 1994 Proc.Ⅻth ESCAMPIG.Netherlands.1994.
[38]Gherardi N,Gouda G,Gat E,Ricard A,and Massines F.2000 Plasma Sources.Sci.Technol.2000.9(34)
[39]Okazaki S.Kogoma M.Uehara M and Y.Kimura.J.Phys.D:Appl.Phys.1993.26
[40]Kataoka Y,Kanoh M,Makino N,Suzuki.K,Saitoh S,Miyajima H,and Mori Y.2000 Jpn.J.Appl.Phys.2000.
[41]Tanner.Scott D.Holland.Grenville.Plasma source mass spectrometry:new development andapplications.International conference on Plasma Source Mass Spectrometry.6~(th):1998.University of Durham.1998
[42]Slotine J J.Li W.Applied nonlineat control.Engleword Cliffs.Nj.Prentice-Hall.1991.
[43]U.Kogelschatz and J Salge.High pressure plasma:Dielectric-barrier and discharges.Propertiesand technical applications.Low Temperature Plasma Physics.New York.Wiley.2001.331-357
[44]F Massines.R Messaoudi.and C Mayoux.Comparison between air filamentary and heliumglow dielectric barrier discharges for the polypropylene surface treatment.Plasmas Polymers.1998.3.43-59
[45]杨华明.焦岩松.王长德.新型复方戊二醛消毒剂生物效应研究.军事科学院院刊.2003.27(5)
[46]Moisan M.Barbeau J.Moreau S.et al.international journal of Pharmaceutics.2001.226.1-21
[47]The Tu Chau.Kwan Chi Kao.Gregory Blank.Et al.biomaterial.1996.17.1273-1277
[48]刘秋秋.李思等.等离子体灭菌器在手术室工作中的应用.中华医院感染学杂志.2006.16(3).305-306
[49]李胜利等.中频高压变压器动态过程分析及设计结构.高电压技术.2001.27(6).28-30
[50]刘钟阳.吴彦.王宁会.DBD型中高频臭氧发生器的动态负载特性.中国机电工程学报.2002.22(5).61-64
[51]刘万东.大气压放电等离子体及其应用.全国第十三届等离子体会议.成都.2007.成都.核工业部西南物理研究院.2007
[52]赵彩凤.于志.王智勇.高频功率脉冲变压器的设计.变压器.2003.40.(10).6-7
[53]江中和.大气压下沿面辉光放电的理论与实践研究[学位论文].武汉.华中科技大学.2003.87-102
[54]王水平.开关稳压电源-原理、设计与实用电路.第1版.西安.西安电子科技大学出版社.1999.12.146
铩颷55]张占松 蔡宣三.开关电源的原理与设计.修订版.北京.电子工业出版社.2004.
[56]倪海东等.高频开关电源集成控制器.第1版 北京.机械工业出版社.2005.46-59
[57]龙海峰等.高频链中高频变压器的分析与设计.电源应用技术.2004.7(4)197-199
[58]黄石生.逆变理论与弧焊逆变器.北京.机械工业出版社.1995.1-20
[59]李雪辰.董丽芳.大气压介质阻挡辉光放电研究综述.自然科学进展 2006.16(12).1521-1530
[60]Menashi W P.Treatment of Surface.[p].US.1968.
[2]M.Laroussi.Nonthermal Decontamination of Biological Media by Atmospheric - PressurePlasma:Review.Analysis and Prospects.2002
[3]徐旭.大气压介质阻挡放电三种模式的电学特征.高电压技术.2006.32(1).63-65
[4]孟月东.低温等离子体灭菌技术.中国医疗器械信息.2004.10(5).4-6
[5]曹金祥.低温等离子体灭菌方法与特点.现代物理知识.2002.11(1).11-12
[6]王锡录.水野彰.一种新灭菌方法的研究.东北师范大学报自然科学版.1999.2.27-30
[7]倪萍.过氧化氢低温等离子灭菌系统的工作原理及使用注意事项.医疗设备信息.2005.50(7).62-74
[8]王新新,芦明泽,蒲以康.空气中大气压下均匀辉光放电的可能性.物理学报.2002.51(12).2778-2784
[9]菅井秀郎.张海波.等离子体工学.第1版.北京.科学出版社.2002.2-10
[10]李成榕,王新新,詹花茂.等离子体表面处理与大气压下的辉光放电.高压电气.2003.39(4).46-48
[11]孙岩洲等.介质阻挡放电杀灭枯草杆菌芽孢的电镜观察.高电压技术.2005.41(1):10-12
[12]Montie T C.Roth J R.2000 IEEE Trans.plasma Sci.28-41
[13]Massines F.Rabehi A.Decomps P.Gadri R.Segur P.Mayoux C.J.Appl.phys.1998.
[14]Takehiko Sato,Akiko Doi,Takuya Urayama,Tatsuyuki Nakatani,and Takashi Miyahara.IEEETansactions on industry applications.2007.43.(5).1159-1165
[15]白希尧,张之涛,白敏东,高气压强放电等离子体学科的行成及应用展望.自然.2000.22(3).156-160
[16]蒲以康等.迈克尔·A 力伯曼等.等离子体放电原理与材料处理.第1版.北京.科学出版社.2007.
[17]甄汉生.等离子体加工技术.第1版.北京.清华大学出版社.1990.5-8
[18]潘应年.等离子体技术在材料中的应用.版1.武汉.湖北科学出版社.2003.12-24
[19]Roth J R.Industrial Plasma Engineering:Vol.2,Institute of Physics Publishing,Bristol andPhiladelphia,2001
[20]杨津基.气体放电.版本.北京.科学出版社.1983.18-26
[21]徐学基.诸定昌.气体放电物理.版本.上海.复旦大学出版社.1996.14-19
[22]Okazaki S.Kogomat M.Ueharat M.et al.Appearance od stable glow discharge in air,argon,oxygen and nitrogen at atmospheric pressure using 50 Hz source.Journal of Applied Physics.1993.26.889-892
[23]方志等.空气中介质阻挡放电大气压辉光放电特性的研究.高压电器.2006.42(2).105-108
[24]A Vongle,R Seeliger,and M Steenback.Zeit Fur Physik.1933.
[25]Kunhartdt E.2000 IEEE Trans.Plasma Sci.2000
[26]王新新等.用50Hz工频电压产生大气压下辉光放电.高电压技术.2002.28(120).39
铩颷27]Thomas C M.Kimberly K W.J Roth OAUGDP for Sterilization of Surface and Materials.IEEETrans plasma SCI.VOL.28.NQ.1.2000
[28]Roth J R.Laroussi.Liu C.1992 Proc.19~(th)IEEE Int.Conf.on plasma Sci.1992
[29]Gadri R B 1999 IEEE Trans.plasma Sci.1999.27-36
[30]Roth J R.Sherman D M and Willkinson S P 1998 AIAA Aerospace Sciences Meeting.RenoNV.1998
[31]Roth J R.Sherman D M and Willkinson S P 2000 AIAA Journal.2000.
[32]Massines F and Gouda G.1999 Proc.Conf.Electrical Insulation and Dielectric phenomena
[33]Massines F.Messaoudi.andMayoux C.Plasmas and Polymers.1998.3(43)
[34]Gherardi N.Martin S and Massines F.J.phys.D:Appl.phys.2000.33
[35]Gat E.Gherardi N.Lemoing S.and Massines F 2000 J.phys.2000 plasma Sources
[36]Vidmar R J 1990 IEEE trans.Plasma Sei.18 733
[37]Gadri R,Rabehi A,Massines F and Segur P 1994 Proc.Ⅻth ESCAMPIG.Netherlands.1994.
[38]Gherardi N,Gouda G,Gat E,Ricard A,and Massines F.2000 Plasma Sources.Sci.Technol.2000.9(34)
[39]Okazaki S.Kogoma M.Uehara M and Y.Kimura.J.Phys.D:Appl.Phys.1993.26
[40]Kataoka Y,Kanoh M,Makino N,Suzuki.K,Saitoh S,Miyajima H,and Mori Y.2000 Jpn.J.Appl.Phys.2000.
[41]Tanner.Scott D.Holland.Grenville.Plasma source mass spectrometry:new development andapplications.International conference on Plasma Source Mass Spectrometry.6~(th):1998.University of Durham.1998
[42]Slotine J J.Li W.Applied nonlineat control.Engleword Cliffs.Nj.Prentice-Hall.1991.
[43]U.Kogelschatz and J Salge.High pressure plasma:Dielectric-barrier and discharges.Propertiesand technical applications.Low Temperature Plasma Physics.New York.Wiley.2001.331-357
[44]F Massines.R Messaoudi.and C Mayoux.Comparison between air filamentary and heliumglow dielectric barrier discharges for the polypropylene surface treatment.Plasmas Polymers.1998.3.43-59
[45]杨华明.焦岩松.王长德.新型复方戊二醛消毒剂生物效应研究.军事科学院院刊.2003.27(5)
[46]Moisan M.Barbeau J.Moreau S.et al.international journal of Pharmaceutics.2001.226.1-21
[47]The Tu Chau.Kwan Chi Kao.Gregory Blank.Et al.biomaterial.1996.17.1273-1277
[48]刘秋秋.李思等.等离子体灭菌器在手术室工作中的应用.中华医院感染学杂志.2006.16(3).305-306
[49]李胜利等.中频高压变压器动态过程分析及设计结构.高电压技术.2001.27(6).28-30
[50]刘钟阳.吴彦.王宁会.DBD型中高频臭氧发生器的动态负载特性.中国机电工程学报.2002.22(5).61-64
[51]刘万东.大气压放电等离子体及其应用.全国第十三届等离子体会议.成都.2007.成都.核工业部西南物理研究院.2007
[52]赵彩凤.于志.王智勇.高频功率脉冲变压器的设计.变压器.2003.40.(10).6-7
[53]江中和.大气压下沿面辉光放电的理论与实践研究[学位论文].武汉.华中科技大学.2003.87-102
[54]王水平.开关稳压电源-原理、设计与实用电路.第1版.西安.西安电子科技大学出版社.1999.12.146
铩颷55]张占松 蔡宣三.开关电源的原理与设计.修订版.北京.电子工业出版社.2004.
[56]倪海东等.高频开关电源集成控制器.第1版 北京.机械工业出版社.2005.46-59
[57]龙海峰等.高频链中高频变压器的分析与设计.电源应用技术.2004.7(4)197-199
[58]黄石生.逆变理论与弧焊逆变器.北京.机械工业出版社.1995.1-20
[59]李雪辰.董丽芳.大气压介质阻挡辉光放电研究综述.自然科学进展 2006.16(12).1521-1530
[60]Menashi W P.Treatment of Surface.[p].US.1968.