刚柔/刚刚混合多羧酸稀土配位聚合物的合成、结构及荧光特性
|
摘要
本论文主要针对混合多羧酸配体为主的系列稀土配位聚合物的合成、结构及其性质进行研究,旨在研究混合多羧酸稀土配合物结构的多样性,热稳定性和荧光特性。本文将对具有新颖构型的有机配体构筑的22种混合多羧酸稀土配位聚合物进行描述和探讨。我们利用X-射线单晶衍射测定了配合物1-22的晶体结构,利用元素分析和红外光谱对配合物进行了表征,并用热分析方法研究了配合物的热稳定性。同时,对Eu,Tb,Sm,Dy配合物的荧光性质进行了系统的研究,并且详细探讨了配合物的结构与荧光性质之问的关系。我们合成的22种配合物的分子式如下所示：注：H4bta=1,2,4,5-均苯四甲酸；HBSA=苯磺酸；H2bdc=1,4-对苯二甲酸；H20x=草酸；H2glu=戊二酸；H2ad=己二酸
本文第三章和第四章主要着手研究了在刚性配体不变的情况下,通过引进系列柔性配体作为第二连接体来构筑系列多功能刚柔混合多羧酸稀土配合物。目的在于研究混合多羧酸稀土配合物在含有相同刚性配体时,不同柔性配体对配合物的结构、荧光及热分解性质等的影响。我们在传统的“刚柔”体系的设计理念启发下,尝试设计“刚刚”体系期望得到结构新颖发光性能更好的稀土配合物。本文第五章中我们合成了几例刚刚混合多羧酸稀土配合物,并且探讨了刚刚混合配体对配合物荧光性质的影响。
The synthesis, structures and properties of multi-functional lanthanide coordination polymers based on the construction of mixed polycarboxylate-containing ligands are our mainly work. The aim is to study the structural variety, the thermal stabilities and the fluorescence of mixed-polycarboxylate lanthanide coordination polymers. In the paper,22 lanthanide polycarboxylate polymers constructed from different novel organic ligands were described and discussed in detail. The structures of the complexes 1-22 were determined by the X-ray crystal diffractometer. All complexes are characterized by elemental analysis and IR spectrum. The thermal stabilities for some complexes were also analysized. For the complexes regarding Eu, Tb, Sm and Dy, we have a systematic investigation of the photoluminescence for them and also discuss the relationship between the structure and the photoluminescence properties. The chemical formulas of 22 complexes are as following: Note:H4bta = 1,2,4,5-Benzenetetracarboxylic acid; HBSA = benzene sulfonic acid; H2bdc =1,4-benzene-dicarboxylic acid; H2ox= oxalic acid; H2glu= glutaric acid; H2ad= adipic acid
In chapter three and four, we investigate the mixed-polycarboxylate lanthanide coordination polymers with novel structure and unique properties which were constructed from the same rigid ligand and three different flexible ligands. The aim is to discuss the effection of different flexible ligands on the conformation, photoluminescence properties and thermal stabilities of these complexes when the rigid linker is the same. Encouraged by the tranditional design notion of Ln+R+F(R = rigid ligand, F = flexible ligand), we have attempted to design some Ln+R+R complexes formed by two rigid-polycarboxylate ligands inorder to obtain lanthanide complexes with novel structure and higher photoluminescence efficiency. In chapter five, Some Ln+R+R complexes have been synthesized and the inflence of the mixed-rigid ligands on the photoluminescence properties have also been discussed.
本文第三章和第四章主要着手研究了在刚性配体不变的情况下,通过引进系列柔性配体作为第二连接体来构筑系列多功能刚柔混合多羧酸稀土配合物。目的在于研究混合多羧酸稀土配合物在含有相同刚性配体时,不同柔性配体对配合物的结构、荧光及热分解性质等的影响。我们在传统的“刚柔”体系的设计理念启发下,尝试设计“刚刚”体系期望得到结构新颖发光性能更好的稀土配合物。本文第五章中我们合成了几例刚刚混合多羧酸稀土配合物,并且探讨了刚刚混合配体对配合物荧光性质的影响。
The synthesis, structures and properties of multi-functional lanthanide coordination polymers based on the construction of mixed polycarboxylate-containing ligands are our mainly work. The aim is to study the structural variety, the thermal stabilities and the fluorescence of mixed-polycarboxylate lanthanide coordination polymers. In the paper,22 lanthanide polycarboxylate polymers constructed from different novel organic ligands were described and discussed in detail. The structures of the complexes 1-22 were determined by the X-ray crystal diffractometer. All complexes are characterized by elemental analysis and IR spectrum. The thermal stabilities for some complexes were also analysized. For the complexes regarding Eu, Tb, Sm and Dy, we have a systematic investigation of the photoluminescence for them and also discuss the relationship between the structure and the photoluminescence properties. The chemical formulas of 22 complexes are as following: Note:H4bta = 1,2,4,5-Benzenetetracarboxylic acid; HBSA = benzene sulfonic acid; H2bdc =1,4-benzene-dicarboxylic acid; H2ox= oxalic acid; H2glu= glutaric acid; H2ad= adipic acid
In chapter three and four, we investigate the mixed-polycarboxylate lanthanide coordination polymers with novel structure and unique properties which were constructed from the same rigid ligand and three different flexible ligands. The aim is to discuss the effection of different flexible ligands on the conformation, photoluminescence properties and thermal stabilities of these complexes when the rigid linker is the same. Encouraged by the tranditional design notion of Ln+R+F(R = rigid ligand, F = flexible ligand), we have attempted to design some Ln+R+R complexes formed by two rigid-polycarboxylate ligands inorder to obtain lanthanide complexes with novel structure and higher photoluminescence efficiency. In chapter five, Some Ln+R+R complexes have been synthesized and the inflence of the mixed-rigid ligands on the photoluminescence properties have also been discussed.
引文
[1]Yu Q Y, Zhou X X, Liu M S, et al. Syntheses, characterization, and luminescence of two lanthanide complexes [Ln2(acetate)6(H2O)4]-4H2O (Ln=Tb(1), Sm(2)). J. Rare Earth.,2008, 26:178-184.
[2]Wang X F, Wang J, Gao J, et al. Syntheses and structural determination of the nine-coordinate rare earth metal complexes:[TbⅢ(Eg3a)(H2O)2]-4.5H2O and K[TbⅢ (Edta)(H2O)3]-5H2O. Russ. J. Coord. Chem.,2008,34:350-399.
[3]Guo X D, Zhu G S, Sun F X, et al. Synthesis, structure, and luminescent properties of microporous lanthanide metal-organic frameworks with inorganic rod-shaped building units. Inorg. Chem.,2006,45:2581-2587.
[4]Baur W H. Microporous materials:Frameworks under pressure. Nature. Materials.2003,2: 17-18.
[5]Tang R R, Yan Z E, Guo C C. Synthesis of Eu(Ⅲ) and Tb(Ⅲ) complexes with novel pyridine-2,6-dicarboxylic acid derivatives and their fluorescence properties. Frontiers of Chemistry in China.,2006,27:472-477.
[6]Scotognella F, Meinardi F, Ottonelli M, et al. Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3. J. Lumin.,2009,129:746-750.
[7]Champness N R, Schroder M. Extended networks formed by coordination polymers in the solid state. Curr. Opin. Solid State Mater. Sci.,1998,3:419-424.
[8]Eddaoudi M, Moler D B, Li H L, et al. Modular chemistry:Secondary building units as a basis for the design of highly porous and orbust metal-organic carboxylate frameworks. Acc. Chem. Res.,2001,34:319-330.
[9]Rowsell J L C, Yaghi O M. Metal-organic frameworks:a new class of porous materials. Micro.Meso.Mater.,2004,73:3-14.
[10]Eddaoudi M, Kim J, Rosi N, et al. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage. Science.,2002,295:469-472.
[11]Parker C A. With applications to photochemistry and analytical chemistry. Amsterdam: Elsevier Pub. Co.,1968:470-475.
[12]Sabbatini N, Guardigli M, Lehn J M. Luminescent lanthanide complexes as photochemical supramolecular devices. Coord. Chem. Rev.,1993,123:201-228.
[13]Richardson F S. Terbium(Ⅲ) and europium(Ⅲ) ions as luminescent probes and stains for biomolecular systems. Chem. Rev.,1982,82:541-552.
[14]Chandler B D, Cramb D T, G Shimizu K H. Microporous Metal-Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks. J. Am. Chem. Soc.,2006, 32:10403-10412.
[15]Berlman I B. Handbook of Fluorescence Spectra of Aromatic Molecules, New York: Academic Pr.,1971.
[16]Xu H T, Li Y D. The organic ligands as template:the synthesis, structures and properties of a series of the layered structure rare-earth coordination polymers. J. Mol. Struct.,2004,690: 137-143.
[17]Yue Q, Yang J, Li G. H, et al. Structures, Photoluminescence, Up-Conversion, and Magnetism of 2D and 3D Rare-Earth Coordination Polymers with Multicarboxylate Linkages. Inorg.Chem.,2006,45:2857-2865.
[18]Zhang X J, Xing Y H, Sun Z, et al. A Series of Two-Dimensional Metal-Organic Frameworks Based on the Assembly of Rigid and Flexible Carboxylate-Containing Mixed Ligands with Lanthanide Metal Salts. Cryst. Growth Des.,2007,7:2041-2046.
[19]Huang Y G, Jiang F L, Yuan D Q, et al. A Prototypical Zeolitic Lanthanide - Organic Framework with Nanotubular Structure. Cryst. Growth Des.,2008,8:166-168.
[20]Chandler B D, Yu J O, Cramb D T. Series of Lanthanide-Alkali Metal-Organic Frameworks Exhibiting Luminescence and Permanent Microporosity. Chem. Mater.2007,19:4467-4473.
[21]Mahata P, Ramya K V, Natarajan. S. Synthesis, structure and optical properties of rare-earth benzene carboxylates. Dalton Trans.,2007,4017-4026.
[22]Huang Y, Yan B, Shao M, et al. A new family of dimeric lanthanide (Ⅲ) complexes: Synthesis, structures and photophysical property. J. Mol. Struct.,2007,871:59-66.
[23]Mahata P, Natarajan S. A New Series of Three-Dimensional Metal-Organic Framework, [M2(H2O)][C5N1H3(COO)2]3-2H2O, M = La, Pr, and Nd:Synthesis, Structure, and Properties. Inorg. Chem.,2007,46:1250-1258.
[24]Gandara F, Garcia-Cortes A., Cascales C, et al. Rare Earth Arenedisulfonate Metal-Organic Frameworks:An Approach toward Polyhedral Diversity and Variety of Functional Compounds. Inorg. Chem,2007,46:3475-3484.
[25]Sonnauer A, Nather C, Hoppe H A, et al. Systematic Investigation of Lanthanide Phosphonatoethanesulfonate Framework Structures by High-Throughput Methodes, Ln(O3P-C2H4-SO3)(H2O) (Ln = La-Dy). Inorg. Chem.2007,46:9968-9974.
[26]Song X Q, Liu W S, Dou W, et al. Structure Variation and Luminescence Properties of Lanthanide Complexes Incorporating a Naphthalene-Derived Chromophore Featuring Salicylamide Pendant Arms. Eur. J. Inorg. Chem.2008:1901-1912.
[27]Vander Horst M G, Van Albada G A, Ion R M, et al. Extended Networks Generated from the Interaction of Rare-Earth(III) Ions and Pyridine-2-carboxamide-Based Ligands. Eur. J. Inorg. Chem.2008,2170-2176.
[28]Sun Y Q, Yang G Y. Organic-inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid. Dalton Trans.,2007, 3771-3781.
[29]Cheng J W, Zheng S T, Yang G Y. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction. Dalton Trans.,2007,4059-4066.
[30]Chen B L, Yang Y, Zapata F, et al. Enhanced Near-Infrared-Luminescence in an Erbium Tetrafluoroterephthalate Framework. Inorg. Chem.,2006,45:8882-8886.
[31]Serre C, Millange F, Thouvenot C, et al. Synthesis, characterisation and luminescent properties of a new three-dimensional lanthanide trimesate:M((C6H3)-(CO2)3)(M = Y, Ln) or MIL-78. Mater. Chem.,2004,14:1540-1543.
[32]Chen Z, Zhao B, Zhang Y, et al. Construction and Characterization of Several New Lanthanide-Organic Frameworks:From 2D Lattice to 2D Double-Layer and to Porous 3D Net with Interweaving Triple-Stranded Helixes. Cryst.Growth.Des.,2008,8:2291-2298.
[33]Lill D T, Bettencourt-Dias A, Cahill C L. Exploring lanthanide luminescence in metal-organic frameworks:synthesis, structure, and guest-sensitized luminescence of a mixed europium/terbium-adipate framework and a terbium-adipate framework. Inorg. Chem. 2007,46:3960-3965.
[34]DeLill D T, Gunning N S, Cahill C L. Toward Templated Metal-Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide-Adipate Frameworks. Inorg.Chem.2005,44:258-266.
[35]Soares-Santos P C R, Cunha-Silva L, Almeida Paz F A, et al. Photoluminescent 3D lanthanide-organic frameworks with 2,5-pyridinedicarboxylic and 1,4-phenylenediacetic acids. Cryst. Growth Des.,2008,8:2505-2516.
[36]黄玲,黄春辉.稀土配合物的光致发光合电致发光研究[J].化学学报.,2000,58：1493-1498.
[37]Tatjana N, Parac V, Karen D, et al. Lanthanide(III) complexes of aromatic sulfonic acids as catalysts for the nitration of toluene. J. Alloys Compd.,2004,374:46-49.
[38]Lu Z, Wen L, Yao J, et al. Two types of novel layer framework structures assembled from 5-sulfosalicylic acid and lanthanide ions. CrystEngComm.,2006,8:847-853.
[39]Tang S F, Mudring A V. The Missing Link Crystallized from the Ionic Liquid 1-Ethyl-3-methylimidazoliumTosylate:Bis-aqua-(p-toluenesulfonato-O)-europium(Ⅲ)-bis-p-toluenesulfonate Dihydrate. Cryst. Growth Des.2009,9:2549-2551.
[40]Zhou R S, Ye L, Ding H, et al. Syntheses, structures, luminescence, and magnetism of four 3D lanthanide 5-sulfosalicylates. Solid State Chem.2008,181:567-575.
[41]Wang Z, Bai F Y, Xing Y H, et al. Two New 3D Lanthanide Coordination Polymers with Benzenesulfonic and Adipic Acids:Synthesis, Structure and Luminescent Properties. Z. Anorg. Allg. Chem.,2010,636:1570-1575.
[42]Daiguebonne C, Kerbellec N, Guillou O, et al. Structural and luminescent properties of micro- and nanosized particles of lanthanide terephthalate coordination polymers. Inorg. Chem.,2008,47:3700-3708.
[43]Thirumurugan A, Natarajan S. Inorganic-organic hybrid compounds:Synthesis and structures of new Metal organic polymers synthesized in the presence of mixed dicarboxylates. Eur. J. Inorg. Chem.,2004,762-770.
[44]Yang X P, Jones R A, Rivers J H, et al. Syntheses, structures and luminescent properties of new lanthanide-based coordination polymers based on 1,4-benzenedicarboxylate (bdc). Dalton Trans.,2007,3936-3942.
[45]Daiguebonne C, Kerbellec N, Bernot K, et al. Synthesis, Crystal structure, and porosity estimation of hydrated erbium terephthalate coordination polymers. Inorg. Chem.,2006, 45:5399-5406.
[46]Weng D, Zheng X, Jin L. Assembly and Upconversion Properties of Lanthanide Coordination Polymers Based on Hexanuclear Building Blocks with (μ3-OH) Bridges. Eur. J. Inorg. Chem.,2006,4184-4190.
[47]Wan Y, Zhang L, Jin L, et al. High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions with Benzenedicarboxylates and 1,10-Phenanthroline. Inorg. Chem.,2003, 42:4985-4994.
[48]Eddaoudi M, Kim J, Wachter J B, et al. Porous Metal-Organic Polyhedral:25 A Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks. J. Am. Chem. Soc.,2001,123:4368-4369.
[49]Wan Y H, Jin L P, Wang K Z. Hydrothermal synthesis and structural characterization of two novel lanthanide supramolecular coordination polymers with nano-chains. J. Mol. Struct., 2003,649:85-93.
[50]Reineke T M, Eddaoudi M, O'Keeffe M, et al. A microporous lanthanide-organic framework. Angewandte Chemie-International Edition.,1999,38:2590-2594.
[51]Zhang Z H, Okamura T, Hasegawa Y, et al. Syntheses, Structures, and Luminescent and Magnetic Properties of Novel Three-Dimensional Lanthanide Complexes with 1,3,5-benzenetriacetate. Inorg. Chem.,2005,44:6219-6227.
[52]Zhang Z H, Shen Z L, Odamura T, et al. Syntheses and Structures of Two Series of Coordination Frameworks Based on the Assembly of 1,3,5-Benzenetriacetic Acid with Lanthanide Metal Salts. Cryst. Growth Des.,2005,5:1191-1197.
[53]Souza E R, Silva I G N, Teotonio E E S, et al. Opitcal properties of red, green and blue emitting rare earth benzenetricarboxylate compounds. J. Lumin.,2010,130:283-291.
[54]Cheng D, Khan M A, Houser R P. Novel sandwich coordination polymers composed of cobalt(Ⅱ),1,2,4,5-benzenetetracarboxylato ligands, and homopiperazonium cations. Cryst. Growth Des.,2002,2:415-420.
[55]Si S F, Wang R J, Li Y D. Synthesis and crystal structure of three dimensional complex from copper(Ⅱ) and 1,2,4,5-benzenetetracarboxylate. Inorg. Chem. Commun.,2003,6:1152-1155.
[56]Wen Y H, Zhang Q W, He Y H, et al. Highly thermal stable zinc complex with unusual (4,8)-connected topology. Inorg. Chem. Commun.,2007,10:543-546.
[57]Fabelo O, Pasan J, Canadillas-Delgado L, et al. (4,4) Rectangular lattices of cobalt(Ⅱ) with 1,2,4,5-benzenetetracarboxylic acid:Influence of the packing in the crystal structure. Cryst. Growth Des.2008,8:3984-3992.
[58]Karabach Y Y, Kirillov A M, Haukka M, et al. Multicopper(Ⅱ) pyromellitate compounds: Self-assembly synthesis, structural topologies, and magnetic features. Cryst. Growth Des., 2008,8:4100-4108.
[59]Majumder A, Gramlich V, Rosair G M, et al. Five new cobalt(Ⅱ) and copper(Ⅱ)-1,2,4,5-benzenetetracarboxylate supramolecular architectures:Syntheses, structures, and magnetic properties. Cryst. Growth Des.,2006,6:2355-2368.
[60]Ganesan S. V and Natarajan S. Synthesis and structures of new pyromellitate coordination polymers with piperazine as a ligand. Inorg. Chem.,2004,43:198-205.
[61]Prajapati R, Mishra L, Kimura K, et al. Metal-organic frameworks (MOFs) constructed from Zn11/Cd"-2,2'-bipyridines and polycarboxylic acids:Synthesis, characterization and microstructural studies. Polyhedron.,2009,28:600-608.
[62]Hou Y, Wang S, Shen E, et al. A novel three-dimensional metal-organic network, Zn2(btec)(pipz)(H2O) (btec = 1,2,4,5-benzenetetracarboxylate, Pipz = piperazine), with blue fluorescent emission. Inorg. Chim. Acta.,2004,357:3155-3161.
[63]Fabelo O, Pasan J, Delgado F. S, et al. Novel cobalt(Ⅱ) coordination polymers based on 1,2,4,5-benzenetetracarboxylic acid and extended bis-monodentate ligands. CrystEngComm., 2009,11:2169-2179.
[64]Liu Z Q, Li Y T, Wu Z Y, et al. [Cu4(H2O)4(dmapox)2(btc)]n-10nH2O:The first two-dimensional polymeric copper(II) complex with bridging 1-trans-oxamidate and μ4-1,2,4,5-benzentetracarboxylato ligands:Synthesis, crystal structure and DNA binding studies Inorg. Chim. Acta.,2009,362:71-77.
[65]Hao N, Li Y, Wang E, et al. Hydrothermal synthesis and crystal structure of an infinite 1D ladderlike metal-organic compound:[Cu2(btec)(2,20-bipy)2]∞ (btec = 1,2,4,5-benzenet-etracarboxylate). J. Mol. Struct.,2004,697:1-8.
[66]Wu C D, Lu C Z, Lu S F, et al. Structure and physical properties of a novel three-dimensional nickel coordinated polymer with mixed ligands resulting from hydrothermal reaction. Inorg. Chem. Commun.,2002,5:171-174.
[67]Zhang N, Li M X, Wang Z X, et al. Synthesis, structures and thermal stabilities of five copper(II) coordination polymers based on 2,4,6-tris(pyridyl)-1,3,5-triazine and 1,2,4,5-benzenetetracarboxylate ligands. Inorg. Chim. Acta.,2010,363:8-14.
[68]Yang E C, Feng W, Wang J Y, et al. Crystal structure, thermal stability and theoretical investigation on four 1,3-bis(1,2,4-triazol-1-yl)propane-based copper(II) complexes. Inorg. Chim. Acta.,2010,363:308-316.
[69]Karabach Y Y, Kirillov A M, Guedes da Silva M F C, et al. An aqua-soluble copper(II)-sodiumtwo-dimensional coordination polymer with intercalated infinite chains of decameric water clusters. Cryst. Growth Des.,2006,6:2200-2203.
[70]Daiguebonne C, Deluzet A, Camara M, et al. Lanthanide-based molecular materials:Gel medium induced polymorphism. Cryst. Growth Des.,2003,3:1015-1020.
[71]Wang Y B, Zhuang W J, Jin L P et al. New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4'-bipyridine with 1D channels. J. Mol. Struct., 2005,737:165-172.
[72]Canadillas-Delgado L, Fabelo O, Ruiz-Perez C, et al. Zeolite-like nanoporous gadolinium complexes incorporating alkaline cations. Cryst. Growth Des.,2006,6:87-93.
[73]Li X H, Wang Y P, Ma Z Y, et al. Synthesis and characterization of two 3-D polymeric lanthanide complexes constructed from 1,2,4,5-benzenetetracarboxylic acid. J. Coord. Chem., 2010,63:1029-1037.
[74]Yao Y, Che Y, Zheng J. The Coordination Chemistry of Benzimidazole-5,6-dicarboxylic Acid with Mn(II), Ni(II), and Ln(III) Complexes (Ln = Tb, Ho, Er, Lu). [J]. Cryst. Growth Des., 2008,8:2299-2306.
[75]Deng Z P, Huo L H, Gao S. A series of three-dimensional lanthanide metal-organic frameworks with biphenylethene-4,40-dicarboxylic acid:Hydrothermal syntheses and structures. CrystEngComm.,2010,12:1526-1535.
[76]Lill D T, Bettencourt-Dias A, Cahill C L. Exploring lanthanide luminescence in metal-organic frameworks:synthesis, structure, and guest-sensitized luminescence of a mixed europium/terbium-adipate framework and a terbium-adipate framework. Inorg. Chem., 2007,46:3960-3965.
[77]V. Kiritsis, A. Michaelides, S. Skoulika, et al. Assembly of a Porous Three-Dimensional Coordination Polymer:Crystal Structure of{[La2(adipate)3(H2O)4]6H2O}n Inorg. Chem. 1998,37:3407-3410.
[78]Borkowski L A, Cahill C L, Poly[[aquanedymium(III)-μ3-decane-1,10-dicarboxylato-μ3-9-carboxynonanecarboxylato. Acta Crystal C.,2004,60:m159-m161.
[79]王春光.刚柔多羧酸稀土配位聚合物的合成、结构及性能研究(辽宁师范大学硕士研究生学位论文).大连：辽宁师范大学.2009.
[80]Wang C G, Xing Y H, Li Z P, et al. A Series of Three-Dimensional Lanthanide Rigid-Flexible Frameworks:Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid. Cryst. Growth Des.,2009,9:1525-1530.
[81]Sun Y G, Yu W, Wang L, et al. Synthesis, structures, and luminescence of lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylate and oxalate ligands. Inorg. Chem. Comm.,2010,13:479-483.
[82]Wang Z, Xing Y H, Wang C G, et al. Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands. CrystEngComm.,2010,12:762-773.
[83]Wang Z, Bai F Y, Xing Y H, et al. Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate. Inorg. Chim. Acta., 2010,363:669-675.
[84]Chen W, Wang J Y, Chen C, et al. Photoluminescent Metal-Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates. Inorg. Chem.,2003,42:944-946.
[85]Chen S S, Fan J, Okamura T, et al. Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands. Cryst. Growth Des.,2010,10:812-822.
[86]Thirumurugan A, Natarajan S. Inorganic-Organic Hybrid Compounds:Synthesis and Structures of New Metal Organic Polymers Synthesized in the Presence of Mixed Dicarboxylates. Eur. J. Inorg. Chem.,2004,762-770.
[87]任宜霞.间苯二羧酸类稀土配位聚合物的构筑及性质研究.西北大学.2007.
[88]Sheldrick GM (1996), SADABS, Program for Empirical Absorption Correction for Area Detector Data; University of Gottingen:Gottingen, Germany.
[89]Sheldrick GM (1997), SHELXS 97, Program for Crystal Structure Refinement; University of Gottingen:Gottingen, Germany.
[2]Wang X F, Wang J, Gao J, et al. Syntheses and structural determination of the nine-coordinate rare earth metal complexes:[TbⅢ(Eg3a)(H2O)2]-4.5H2O and K[TbⅢ (Edta)(H2O)3]-5H2O. Russ. J. Coord. Chem.,2008,34:350-399.
[3]Guo X D, Zhu G S, Sun F X, et al. Synthesis, structure, and luminescent properties of microporous lanthanide metal-organic frameworks with inorganic rod-shaped building units. Inorg. Chem.,2006,45:2581-2587.
[4]Baur W H. Microporous materials:Frameworks under pressure. Nature. Materials.2003,2: 17-18.
[5]Tang R R, Yan Z E, Guo C C. Synthesis of Eu(Ⅲ) and Tb(Ⅲ) complexes with novel pyridine-2,6-dicarboxylic acid derivatives and their fluorescence properties. Frontiers of Chemistry in China.,2006,27:472-477.
[6]Scotognella F, Meinardi F, Ottonelli M, et al. Photophysical analysis of the organic complex [Eu(C12H8N2)2](NO3)3. J. Lumin.,2009,129:746-750.
[7]Champness N R, Schroder M. Extended networks formed by coordination polymers in the solid state. Curr. Opin. Solid State Mater. Sci.,1998,3:419-424.
[8]Eddaoudi M, Moler D B, Li H L, et al. Modular chemistry:Secondary building units as a basis for the design of highly porous and orbust metal-organic carboxylate frameworks. Acc. Chem. Res.,2001,34:319-330.
[9]Rowsell J L C, Yaghi O M. Metal-organic frameworks:a new class of porous materials. Micro.Meso.Mater.,2004,73:3-14.
[10]Eddaoudi M, Kim J, Rosi N, et al. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage. Science.,2002,295:469-472.
[11]Parker C A. With applications to photochemistry and analytical chemistry. Amsterdam: Elsevier Pub. Co.,1968:470-475.
[12]Sabbatini N, Guardigli M, Lehn J M. Luminescent lanthanide complexes as photochemical supramolecular devices. Coord. Chem. Rev.,1993,123:201-228.
[13]Richardson F S. Terbium(Ⅲ) and europium(Ⅲ) ions as luminescent probes and stains for biomolecular systems. Chem. Rev.,1982,82:541-552.
[14]Chandler B D, Cramb D T, G Shimizu K H. Microporous Metal-Organic Frameworks Formed in a Stepwise Manner from Luminescent Building Blocks. J. Am. Chem. Soc.,2006, 32:10403-10412.
[15]Berlman I B. Handbook of Fluorescence Spectra of Aromatic Molecules, New York: Academic Pr.,1971.
[16]Xu H T, Li Y D. The organic ligands as template:the synthesis, structures and properties of a series of the layered structure rare-earth coordination polymers. J. Mol. Struct.,2004,690: 137-143.
[17]Yue Q, Yang J, Li G. H, et al. Structures, Photoluminescence, Up-Conversion, and Magnetism of 2D and 3D Rare-Earth Coordination Polymers with Multicarboxylate Linkages. Inorg.Chem.,2006,45:2857-2865.
[18]Zhang X J, Xing Y H, Sun Z, et al. A Series of Two-Dimensional Metal-Organic Frameworks Based on the Assembly of Rigid and Flexible Carboxylate-Containing Mixed Ligands with Lanthanide Metal Salts. Cryst. Growth Des.,2007,7:2041-2046.
[19]Huang Y G, Jiang F L, Yuan D Q, et al. A Prototypical Zeolitic Lanthanide - Organic Framework with Nanotubular Structure. Cryst. Growth Des.,2008,8:166-168.
[20]Chandler B D, Yu J O, Cramb D T. Series of Lanthanide-Alkali Metal-Organic Frameworks Exhibiting Luminescence and Permanent Microporosity. Chem. Mater.2007,19:4467-4473.
[21]Mahata P, Ramya K V, Natarajan. S. Synthesis, structure and optical properties of rare-earth benzene carboxylates. Dalton Trans.,2007,4017-4026.
[22]Huang Y, Yan B, Shao M, et al. A new family of dimeric lanthanide (Ⅲ) complexes: Synthesis, structures and photophysical property. J. Mol. Struct.,2007,871:59-66.
[23]Mahata P, Natarajan S. A New Series of Three-Dimensional Metal-Organic Framework, [M2(H2O)][C5N1H3(COO)2]3-2H2O, M = La, Pr, and Nd:Synthesis, Structure, and Properties. Inorg. Chem.,2007,46:1250-1258.
[24]Gandara F, Garcia-Cortes A., Cascales C, et al. Rare Earth Arenedisulfonate Metal-Organic Frameworks:An Approach toward Polyhedral Diversity and Variety of Functional Compounds. Inorg. Chem,2007,46:3475-3484.
[25]Sonnauer A, Nather C, Hoppe H A, et al. Systematic Investigation of Lanthanide Phosphonatoethanesulfonate Framework Structures by High-Throughput Methodes, Ln(O3P-C2H4-SO3)(H2O) (Ln = La-Dy). Inorg. Chem.2007,46:9968-9974.
[26]Song X Q, Liu W S, Dou W, et al. Structure Variation and Luminescence Properties of Lanthanide Complexes Incorporating a Naphthalene-Derived Chromophore Featuring Salicylamide Pendant Arms. Eur. J. Inorg. Chem.2008:1901-1912.
[27]Vander Horst M G, Van Albada G A, Ion R M, et al. Extended Networks Generated from the Interaction of Rare-Earth(III) Ions and Pyridine-2-carboxamide-Based Ligands. Eur. J. Inorg. Chem.2008,2170-2176.
[28]Sun Y Q, Yang G Y. Organic-inorganic hybrid materials constructed from inorganic lanthanide sulfate skeletons and organic 4,5-imidazoledicarboxylic acid. Dalton Trans.,2007, 3771-3781.
[29]Cheng J W, Zheng S T, Yang G Y. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction. Dalton Trans.,2007,4059-4066.
[30]Chen B L, Yang Y, Zapata F, et al. Enhanced Near-Infrared-Luminescence in an Erbium Tetrafluoroterephthalate Framework. Inorg. Chem.,2006,45:8882-8886.
[31]Serre C, Millange F, Thouvenot C, et al. Synthesis, characterisation and luminescent properties of a new three-dimensional lanthanide trimesate:M((C6H3)-(CO2)3)(M = Y, Ln) or MIL-78. Mater. Chem.,2004,14:1540-1543.
[32]Chen Z, Zhao B, Zhang Y, et al. Construction and Characterization of Several New Lanthanide-Organic Frameworks:From 2D Lattice to 2D Double-Layer and to Porous 3D Net with Interweaving Triple-Stranded Helixes. Cryst.Growth.Des.,2008,8:2291-2298.
[33]Lill D T, Bettencourt-Dias A, Cahill C L. Exploring lanthanide luminescence in metal-organic frameworks:synthesis, structure, and guest-sensitized luminescence of a mixed europium/terbium-adipate framework and a terbium-adipate framework. Inorg. Chem. 2007,46:3960-3965.
[34]DeLill D T, Gunning N S, Cahill C L. Toward Templated Metal-Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide-Adipate Frameworks. Inorg.Chem.2005,44:258-266.
[35]Soares-Santos P C R, Cunha-Silva L, Almeida Paz F A, et al. Photoluminescent 3D lanthanide-organic frameworks with 2,5-pyridinedicarboxylic and 1,4-phenylenediacetic acids. Cryst. Growth Des.,2008,8:2505-2516.
[36]黄玲,黄春辉.稀土配合物的光致发光合电致发光研究[J].化学学报.,2000,58：1493-1498.
[37]Tatjana N, Parac V, Karen D, et al. Lanthanide(III) complexes of aromatic sulfonic acids as catalysts for the nitration of toluene. J. Alloys Compd.,2004,374:46-49.
[38]Lu Z, Wen L, Yao J, et al. Two types of novel layer framework structures assembled from 5-sulfosalicylic acid and lanthanide ions. CrystEngComm.,2006,8:847-853.
[39]Tang S F, Mudring A V. The Missing Link Crystallized from the Ionic Liquid 1-Ethyl-3-methylimidazoliumTosylate:Bis-aqua-(p-toluenesulfonato-O)-europium(Ⅲ)-bis-p-toluenesulfonate Dihydrate. Cryst. Growth Des.2009,9:2549-2551.
[40]Zhou R S, Ye L, Ding H, et al. Syntheses, structures, luminescence, and magnetism of four 3D lanthanide 5-sulfosalicylates. Solid State Chem.2008,181:567-575.
[41]Wang Z, Bai F Y, Xing Y H, et al. Two New 3D Lanthanide Coordination Polymers with Benzenesulfonic and Adipic Acids:Synthesis, Structure and Luminescent Properties. Z. Anorg. Allg. Chem.,2010,636:1570-1575.
[42]Daiguebonne C, Kerbellec N, Guillou O, et al. Structural and luminescent properties of micro- and nanosized particles of lanthanide terephthalate coordination polymers. Inorg. Chem.,2008,47:3700-3708.
[43]Thirumurugan A, Natarajan S. Inorganic-organic hybrid compounds:Synthesis and structures of new Metal organic polymers synthesized in the presence of mixed dicarboxylates. Eur. J. Inorg. Chem.,2004,762-770.
[44]Yang X P, Jones R A, Rivers J H, et al. Syntheses, structures and luminescent properties of new lanthanide-based coordination polymers based on 1,4-benzenedicarboxylate (bdc). Dalton Trans.,2007,3936-3942.
[45]Daiguebonne C, Kerbellec N, Bernot K, et al. Synthesis, Crystal structure, and porosity estimation of hydrated erbium terephthalate coordination polymers. Inorg. Chem.,2006, 45:5399-5406.
[46]Weng D, Zheng X, Jin L. Assembly and Upconversion Properties of Lanthanide Coordination Polymers Based on Hexanuclear Building Blocks with (μ3-OH) Bridges. Eur. J. Inorg. Chem.,2006,4184-4190.
[47]Wan Y, Zhang L, Jin L, et al. High-Dimensional Architectures from the Self-Assembly of Lanthanide Ions with Benzenedicarboxylates and 1,10-Phenanthroline. Inorg. Chem.,2003, 42:4985-4994.
[48]Eddaoudi M, Kim J, Wachter J B, et al. Porous Metal-Organic Polyhedral:25 A Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks. J. Am. Chem. Soc.,2001,123:4368-4369.
[49]Wan Y H, Jin L P, Wang K Z. Hydrothermal synthesis and structural characterization of two novel lanthanide supramolecular coordination polymers with nano-chains. J. Mol. Struct., 2003,649:85-93.
[50]Reineke T M, Eddaoudi M, O'Keeffe M, et al. A microporous lanthanide-organic framework. Angewandte Chemie-International Edition.,1999,38:2590-2594.
[51]Zhang Z H, Okamura T, Hasegawa Y, et al. Syntheses, Structures, and Luminescent and Magnetic Properties of Novel Three-Dimensional Lanthanide Complexes with 1,3,5-benzenetriacetate. Inorg. Chem.,2005,44:6219-6227.
[52]Zhang Z H, Shen Z L, Odamura T, et al. Syntheses and Structures of Two Series of Coordination Frameworks Based on the Assembly of 1,3,5-Benzenetriacetic Acid with Lanthanide Metal Salts. Cryst. Growth Des.,2005,5:1191-1197.
[53]Souza E R, Silva I G N, Teotonio E E S, et al. Opitcal properties of red, green and blue emitting rare earth benzenetricarboxylate compounds. J. Lumin.,2010,130:283-291.
[54]Cheng D, Khan M A, Houser R P. Novel sandwich coordination polymers composed of cobalt(Ⅱ),1,2,4,5-benzenetetracarboxylato ligands, and homopiperazonium cations. Cryst. Growth Des.,2002,2:415-420.
[55]Si S F, Wang R J, Li Y D. Synthesis and crystal structure of three dimensional complex from copper(Ⅱ) and 1,2,4,5-benzenetetracarboxylate. Inorg. Chem. Commun.,2003,6:1152-1155.
[56]Wen Y H, Zhang Q W, He Y H, et al. Highly thermal stable zinc complex with unusual (4,8)-connected topology. Inorg. Chem. Commun.,2007,10:543-546.
[57]Fabelo O, Pasan J, Canadillas-Delgado L, et al. (4,4) Rectangular lattices of cobalt(Ⅱ) with 1,2,4,5-benzenetetracarboxylic acid:Influence of the packing in the crystal structure. Cryst. Growth Des.2008,8:3984-3992.
[58]Karabach Y Y, Kirillov A M, Haukka M, et al. Multicopper(Ⅱ) pyromellitate compounds: Self-assembly synthesis, structural topologies, and magnetic features. Cryst. Growth Des., 2008,8:4100-4108.
[59]Majumder A, Gramlich V, Rosair G M, et al. Five new cobalt(Ⅱ) and copper(Ⅱ)-1,2,4,5-benzenetetracarboxylate supramolecular architectures:Syntheses, structures, and magnetic properties. Cryst. Growth Des.,2006,6:2355-2368.
[60]Ganesan S. V and Natarajan S. Synthesis and structures of new pyromellitate coordination polymers with piperazine as a ligand. Inorg. Chem.,2004,43:198-205.
[61]Prajapati R, Mishra L, Kimura K, et al. Metal-organic frameworks (MOFs) constructed from Zn11/Cd"-2,2'-bipyridines and polycarboxylic acids:Synthesis, characterization and microstructural studies. Polyhedron.,2009,28:600-608.
[62]Hou Y, Wang S, Shen E, et al. A novel three-dimensional metal-organic network, Zn2(btec)(pipz)(H2O) (btec = 1,2,4,5-benzenetetracarboxylate, Pipz = piperazine), with blue fluorescent emission. Inorg. Chim. Acta.,2004,357:3155-3161.
[63]Fabelo O, Pasan J, Delgado F. S, et al. Novel cobalt(Ⅱ) coordination polymers based on 1,2,4,5-benzenetetracarboxylic acid and extended bis-monodentate ligands. CrystEngComm., 2009,11:2169-2179.
[64]Liu Z Q, Li Y T, Wu Z Y, et al. [Cu4(H2O)4(dmapox)2(btc)]n-10nH2O:The first two-dimensional polymeric copper(II) complex with bridging 1-trans-oxamidate and μ4-1,2,4,5-benzentetracarboxylato ligands:Synthesis, crystal structure and DNA binding studies Inorg. Chim. Acta.,2009,362:71-77.
[65]Hao N, Li Y, Wang E, et al. Hydrothermal synthesis and crystal structure of an infinite 1D ladderlike metal-organic compound:[Cu2(btec)(2,20-bipy)2]∞ (btec = 1,2,4,5-benzenet-etracarboxylate). J. Mol. Struct.,2004,697:1-8.
[66]Wu C D, Lu C Z, Lu S F, et al. Structure and physical properties of a novel three-dimensional nickel coordinated polymer with mixed ligands resulting from hydrothermal reaction. Inorg. Chem. Commun.,2002,5:171-174.
[67]Zhang N, Li M X, Wang Z X, et al. Synthesis, structures and thermal stabilities of five copper(II) coordination polymers based on 2,4,6-tris(pyridyl)-1,3,5-triazine and 1,2,4,5-benzenetetracarboxylate ligands. Inorg. Chim. Acta.,2010,363:8-14.
[68]Yang E C, Feng W, Wang J Y, et al. Crystal structure, thermal stability and theoretical investigation on four 1,3-bis(1,2,4-triazol-1-yl)propane-based copper(II) complexes. Inorg. Chim. Acta.,2010,363:308-316.
[69]Karabach Y Y, Kirillov A M, Guedes da Silva M F C, et al. An aqua-soluble copper(II)-sodiumtwo-dimensional coordination polymer with intercalated infinite chains of decameric water clusters. Cryst. Growth Des.,2006,6:2200-2203.
[70]Daiguebonne C, Deluzet A, Camara M, et al. Lanthanide-based molecular materials:Gel medium induced polymorphism. Cryst. Growth Des.,2003,3:1015-1020.
[71]Wang Y B, Zhuang W J, Jin L P et al. New lanthanide coordination polymers of 1,2,4,5-benzenetetracarboxylic acid and 4,4'-bipyridine with 1D channels. J. Mol. Struct., 2005,737:165-172.
[72]Canadillas-Delgado L, Fabelo O, Ruiz-Perez C, et al. Zeolite-like nanoporous gadolinium complexes incorporating alkaline cations. Cryst. Growth Des.,2006,6:87-93.
[73]Li X H, Wang Y P, Ma Z Y, et al. Synthesis and characterization of two 3-D polymeric lanthanide complexes constructed from 1,2,4,5-benzenetetracarboxylic acid. J. Coord. Chem., 2010,63:1029-1037.
[74]Yao Y, Che Y, Zheng J. The Coordination Chemistry of Benzimidazole-5,6-dicarboxylic Acid with Mn(II), Ni(II), and Ln(III) Complexes (Ln = Tb, Ho, Er, Lu). [J]. Cryst. Growth Des., 2008,8:2299-2306.
[75]Deng Z P, Huo L H, Gao S. A series of three-dimensional lanthanide metal-organic frameworks with biphenylethene-4,40-dicarboxylic acid:Hydrothermal syntheses and structures. CrystEngComm.,2010,12:1526-1535.
[76]Lill D T, Bettencourt-Dias A, Cahill C L. Exploring lanthanide luminescence in metal-organic frameworks:synthesis, structure, and guest-sensitized luminescence of a mixed europium/terbium-adipate framework and a terbium-adipate framework. Inorg. Chem., 2007,46:3960-3965.
[77]V. Kiritsis, A. Michaelides, S. Skoulika, et al. Assembly of a Porous Three-Dimensional Coordination Polymer:Crystal Structure of{[La2(adipate)3(H2O)4]6H2O}n Inorg. Chem. 1998,37:3407-3410.
[78]Borkowski L A, Cahill C L, Poly[[aquanedymium(III)-μ3-decane-1,10-dicarboxylato-μ3-9-carboxynonanecarboxylato. Acta Crystal C.,2004,60:m159-m161.
[79]王春光.刚柔多羧酸稀土配位聚合物的合成、结构及性能研究(辽宁师范大学硕士研究生学位论文).大连：辽宁师范大学.2009.
[80]Wang C G, Xing Y H, Li Z P, et al. A Series of Three-Dimensional Lanthanide Rigid-Flexible Frameworks:Synthesis, Structure, and Luminescent Properties of Coordination Polymers with 2,5-Pyridine Dicarboxylic Acid and Adipic Acid. Cryst. Growth Des.,2009,9:1525-1530.
[81]Sun Y G, Yu W, Wang L, et al. Synthesis, structures, and luminescence of lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylate and oxalate ligands. Inorg. Chem. Comm.,2010,13:479-483.
[82]Wang Z, Xing Y H, Wang C G, et al. Synthesis, structure and luminescent properties of coordination polymers with 1,2-benzenedicarboxylic acid and a series of flexible dicarboxylate ligands. CrystEngComm.,2010,12:762-773.
[83]Wang Z, Bai F Y, Xing Y H, et al. Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate. Inorg. Chim. Acta., 2010,363:669-675.
[84]Chen W, Wang J Y, Chen C, et al. Photoluminescent Metal-Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates. Inorg. Chem.,2003,42:944-946.
[85]Chen S S, Fan J, Okamura T, et al. Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands. Cryst. Growth Des.,2010,10:812-822.
[86]Thirumurugan A, Natarajan S. Inorganic-Organic Hybrid Compounds:Synthesis and Structures of New Metal Organic Polymers Synthesized in the Presence of Mixed Dicarboxylates. Eur. J. Inorg. Chem.,2004,762-770.
[87]任宜霞.间苯二羧酸类稀土配位聚合物的构筑及性质研究.西北大学.2007.
[88]Sheldrick GM (1996), SADABS, Program for Empirical Absorption Correction for Area Detector Data; University of Gottingen:Gottingen, Germany.
[89]Sheldrick GM (1997), SHELXS 97, Program for Crystal Structure Refinement; University of Gottingen:Gottingen, Germany.