优质Ⅱa型宝石级金刚石的高温高压合成及机理研究
|
摘要
本文是利用温度梯度法在国产六面顶压机上进行优质Ⅱa型宝石级金刚石单晶的合成研究。在稳定性实验组装确立后,提出了调整温度梯度的新方法。在此基础上,对除氮剂Al或Ti(Cu)分别在NiMnCo触媒和FeNiCo触媒中合成Ⅱa型宝石级金刚石的生长特性与机理进行了详细研究,取得结果如下:
1.针对Φ14mm和Φ10mm两种腔体组装,通过二者高温高压下长时间稳定性及叶蜡石内部高温处温度的比较,实验确定Φ10组装来生长Ⅱa型宝石级金刚石。
2.实验在已有传统调节温度梯度方法的基础上,首次提出了新方法——特型石墨管的使用。
3.选用Al作除氮剂、NiMnCo或FeNiCo作触媒,分别研究了在这两种添加Al的触媒中Ⅱa型宝石级金刚石的生长特性。通过在FeNiCo触媒中添加AlN,首次验证了高温高压下合金触媒中AlN的分解,进而全面分析了Al在合成宝石级金刚石中的除氮机理。
4.选用Ti(Cu)作除氮剂、NiMnCo或FeNiCo作触媒,分别研究了在这两种添加Ti(Cu)的触媒中Ⅱa型宝石级金刚石单晶的生长特性。优化生长工艺沿{111}面合成出尺寸达4.3mm的无色优质Ⅱa型宝石级金刚石大单晶。
5.本文详细研究了在生长Ⅱa型宝石级金刚石过程中所产生的黑色微晶石墨粉末对金刚石晶体生长的影响及其产生机理。改进生长工艺消除微晶石墨对金刚石生长的影响,实验沿{100}面合成出尺寸达3.4mm的无色优质Ⅱa型宝石级金刚石大单晶。
6.将除氮剂Ti(Cu)添加到FeNiCo触媒中采用多晶种法合成出尺寸在2mm左右的优质Ⅱa型宝石级金刚石单晶。
High-quality large diamond crystals have been synthesized by temperature gradient method (TGM) under high pressure and high temperature (HPHT) in China-made cubic anvil high-pressure apparatus in this paper. After ascertaining the stability assembly of the experiments, the new method of the adjusting temperature gradient was put forward. The growth traits of typeⅡa large diamonds, which have been synthesized in the NiMnCo or FeNiCo with the additive of Al or Ti (Cu) as a nitrogen getter on the basis of above works, were researched. The conclusions of the research are as follows:
1. As to both assembly whose diameter of the bath areΦ14mm andΦ10mm, the assembly ofΦ10mm has been ascertained to grow typeⅡa large diamonds by the stability of long time under HPHT and the compare of the temperature in the high temperature of the pyrophyllite.
2. The new method of the adjusting temperature gradient, which was the use of special shape graphite tube, was put forward firstly on the traditional methods of the adjusting temperature gradient.
3. While Al as a nitrogen getter was added into the NiMnCo or FeNiCo. the growth traits of typeⅡa large diamonds in the both alloy solvent were investigated respectively. The decomposition of A1N in the alloy solvent under HPHT was firstly validated then the mechanism of Al for eliminating nitrogen in synthesizing large diamonds was analysed entirely by A1N added into FeNiCo solvent.
4. While Ti (Cu) as a nitrogen getter was added into the NiMnCo or FeNiCo. the growth traits of typeⅡa large diamonds in the both alloy solvent were investigated respectively. The colorless high quality typeⅡa large diamond crystal whose size is 4.3mm was synthesized by optimizing the growth process.
5. The effect of black micro-crystal graphite on the crystal growth and the producing mechanism of micro-crystal graphite, which was producing in the course of growing typeⅡa large diamonds, have been researched.
6. While Ti (Cu) as a nitrogen getter was added into FeNiCo, the high quality typeⅡa large diamond crystals whose size is about 2mm were synthesized by multiple seeds method.
1.针对Φ14mm和Φ10mm两种腔体组装,通过二者高温高压下长时间稳定性及叶蜡石内部高温处温度的比较,实验确定Φ10组装来生长Ⅱa型宝石级金刚石。
2.实验在已有传统调节温度梯度方法的基础上,首次提出了新方法——特型石墨管的使用。
3.选用Al作除氮剂、NiMnCo或FeNiCo作触媒,分别研究了在这两种添加Al的触媒中Ⅱa型宝石级金刚石的生长特性。通过在FeNiCo触媒中添加AlN,首次验证了高温高压下合金触媒中AlN的分解,进而全面分析了Al在合成宝石级金刚石中的除氮机理。
4.选用Ti(Cu)作除氮剂、NiMnCo或FeNiCo作触媒,分别研究了在这两种添加Ti(Cu)的触媒中Ⅱa型宝石级金刚石单晶的生长特性。优化生长工艺沿{111}面合成出尺寸达4.3mm的无色优质Ⅱa型宝石级金刚石大单晶。
5.本文详细研究了在生长Ⅱa型宝石级金刚石过程中所产生的黑色微晶石墨粉末对金刚石晶体生长的影响及其产生机理。改进生长工艺消除微晶石墨对金刚石生长的影响,实验沿{100}面合成出尺寸达3.4mm的无色优质Ⅱa型宝石级金刚石大单晶。
6.将除氮剂Ti(Cu)添加到FeNiCo触媒中采用多晶种法合成出尺寸在2mm左右的优质Ⅱa型宝石级金刚石单晶。
High-quality large diamond crystals have been synthesized by temperature gradient method (TGM) under high pressure and high temperature (HPHT) in China-made cubic anvil high-pressure apparatus in this paper. After ascertaining the stability assembly of the experiments, the new method of the adjusting temperature gradient was put forward. The growth traits of typeⅡa large diamonds, which have been synthesized in the NiMnCo or FeNiCo with the additive of Al or Ti (Cu) as a nitrogen getter on the basis of above works, were researched. The conclusions of the research are as follows:
1. As to both assembly whose diameter of the bath areΦ14mm andΦ10mm, the assembly ofΦ10mm has been ascertained to grow typeⅡa large diamonds by the stability of long time under HPHT and the compare of the temperature in the high temperature of the pyrophyllite.
2. The new method of the adjusting temperature gradient, which was the use of special shape graphite tube, was put forward firstly on the traditional methods of the adjusting temperature gradient.
3. While Al as a nitrogen getter was added into the NiMnCo or FeNiCo. the growth traits of typeⅡa large diamonds in the both alloy solvent were investigated respectively. The decomposition of A1N in the alloy solvent under HPHT was firstly validated then the mechanism of Al for eliminating nitrogen in synthesizing large diamonds was analysed entirely by A1N added into FeNiCo solvent.
4. While Ti (Cu) as a nitrogen getter was added into the NiMnCo or FeNiCo. the growth traits of typeⅡa large diamonds in the both alloy solvent were investigated respectively. The colorless high quality typeⅡa large diamond crystal whose size is 4.3mm was synthesized by optimizing the growth process.
5. The effect of black micro-crystal graphite on the crystal growth and the producing mechanism of micro-crystal graphite, which was producing in the course of growing typeⅡa large diamonds, have been researched.
6. While Ti (Cu) as a nitrogen getter was added into FeNiCo, the high quality typeⅡa large diamond crystals whose size is about 2mm were synthesized by multiple seeds method.
引文
1. A.A. Altukhov, M.S. Afanas'ev, V.B. Kvaskov, V.E. Lyubchenko, A.Yu. Mityagin, E.N. Murav'ev, L.A. Pomortsev, V.A. Potapov, and B.V. Spitsyn, "Application of diamond in high technology", Inorganic Materials, Vol.40, Suppl. 1 (2004) S50-S70
2. S. Koizumi, K. Watanabe, M. Hasegawa, H. Kanda, "Ultraviolet Emission from a Diamond pn Junction", SCIENCE, Vol. 292, 8 JUNE (2001)1899-1901
3. Eric J. Lerner, "Industrial diamonds gather strength", The Industrial Physicist, August/September (2002) 8-11
4. H. Kanda and T. Ohsawa, "Effect of solvent metals upon the morphology of synthetic diamonds", Journal of Crystal Growth, 94 (1989) 115-124
5. I. Sunagawa, "Growth and morphology of diamond crystals under stable and metastable conditions", Journal of Crystal Growth, 99 (1990) 1156-1161
6. L.J. Giling and W.J.P. Van Enckevort, "On the influence of surface reconstruction on crystal growth processes", Surface Science, 161(1985) 567-583
7. H. Kanda, T. Ohsawa, O. Fukunaga and I. Sunagawa, in: Morphology and Growth unit of Crystals, Ed. I. Sunagawa , Terra, Tokyo, 1984
8. M. Moore and A.R. Lang, "On the origin of the rounded dodecahedral habit of natural diamond", J. Crystal Growth, 26(1974) 133-139
9. A.R. Lang, "Glimpses into the growth history of natural diamonds", J. Crystal Growth, 24/25 (1974) 108-115
10. S.Yamaoka, H. Komatsu, H. Kanda and N. Setaka, "Growth of diamond with rhombic dodecahedral faces", J. Crystal Growth, 37(1977) 349-352
11. A.T. Collins, "The color of diamond and how it may be changed", Journal of Gemmology, Vol.27, No.6 (2001) 341-359
12. A.T. Collins, "Colour cetres in diamond", Journal of Gemmolo- gy, Vol.18, No.1 (1982) 37-75
13. R.C. DeVries, "A comparison of diamonds and diamond-making by nature and man", GE Res. Rep., 85CRD177, 1985
14. Appendix B, in: Properties of Natural and Synthetic Diamond, Ed. J.E. Field, Academic Press, London, 1992, p.669
15. S. Vagarali, M. Lee and R.C. Devries, "Progress of large diamond growth technology and future prospects", The Fourth International Conference on the Science of Hard Materials, Madeira, Portugal, 10-15 November 1991, p. 233-245
16. G. Davies, "The optical properties of diamond", Phys. Chem. Carbon, 13 (1977) 1
17. W. Kaiser and W.L. Bond, "Nitrogen, a Major Impurity in common type I diamond", Phys. Rev., 115 (1959) 857
18. H. Sumiya, N. Toda, S. Satoh, "High-quality large diamond crystals", New Diamond and Frontier Carbon Technology, 10 (2000) 233-251
19. H. Sumiya, S. Satoh, Y. Nishibayashi, Y. Goda, "Development of high-purity synthetic diamonds", Sumitomo Electric Technical Review, number 39, January (1995) 69
20. S. Satoh, H. Sumiya, K. Tsuji, Y. Gouda, "Process for the synth- esis of diamond", U.S. Patent, No.6,129,900, Oct.10, 2000
21. H.M. Strong, R.M. Chrenko, R.E. Tuft, "Annealing type Ib or mixed type Ib-Ia Natural diamond crystal", U.S. Patent, No. 4,124,690, Nov.7, 1978
22. R.M. Chrenko, R.E. Tuft, H.M. Strong, "Transformation of the state of nitrogen in diamond", Nature, 270 (1977) 141-144
23. A.A. Chepurov, J.M. Dereppe, I.I. Fedorov, A.I. Chepurov, "The change of Fe-Ni alloy inclusions in synthetic diamond crystals due to annealing", Diamond and Related Materials, 9 (2000) 1374-1379
24. H. Kanda, X. Jia, "Change of luminescence character of Ib diamonds with HPHT treatment",Diamond and Related Mater-ials,10(2001)1665-1669
25.I.Kiflawi,H.Kanda,D.Fisher,S.C.Lawson,"The aggregation of nitrogen and the formation of A centers in diamonds",Diamond and Related Materials,6(1997) 1643-1649
26.I.Kiflawi,J.Bruley,"The nitrogen aggregation sequence and the formation of voidites in diamond",Diamond and Related Materials,9(2000) 87-93
27.T.Evans,"Aggregation of Nitrogen in Diamond",in:Properties of Natural and Synthetic Diamond,Ed.J.E.Field,Academic Press,London,1992,p.259
28.H.Kanda,T.Ohsawa and S.Yamaoka,Proceedings of the First International Conference on New Diamond Science and Technology(S.Saito,O.Fukunaga and M.Yoshikawa,eds),Tokyo,Japan,1990,p.339-344
29.C.D.Clark,A.T.Collins,G.S.Woods,"Absorption and lumines-cence spectroscopy",in:Properties of Natural and Synthetic Diamond,Ed.J.E.Field,Academic Press,London,1992,p.259
30.M.N.Yoder,in Diamond and Diamond-Like Films and Coatings,Edited by R.E.Clausing,L.L.Horton,J.C.Angus,and P.Koidl,Plenum Press,New York,1991,Page 1-16
31.Chris Owers and Philip Bex,“工业金刚石的应用、效益与展望”,超硬材料与工程.1(2000)2
32.W.Tillmann,"Trends and market perspectives for diamond tools in the construction industry",International Journal of Refractory Metals&Hard Materials,8(2000) 301-306
33.C.M.Sung,"Brazed diamond grid:a revolutionary design for diamond saws",Diamond and Related Materials,8(1999) 1540-1543
34.贾晓鹏,“宝石级金刚石的合成”,香山会议,2000年北京
35.A.K.Freund,J.Hoszowska,J.P.F.Sellschop,R.C.Burns,M.Rebak. "Recent developments of high-quality synthetic diamond single crystals for synchrotron X-ray monochromators",Nuclear Instruments and Methods in Physics Research A,467-468(2001) 384-387
36.R.J.Tapper,"Diamond detectors in particle physics",Rep.Prog.Phys..63(2000) 1273
37.H.Sumiya,"Super-hard diamond indenter prepared from high-purity synthetic diamond crystal",REVIEW OF SCIENTIFIC INSTRUMENTS,76,026112(2005) 1-3
38.T.Tanaka,J.Kaneko,D.Takeuchi,H.Sumiya et al,"Diamond radiation detector made of an ultrahigh-purity type Ⅱa diamond crystal grown by high-pressure and high-temperature synthesis",REVIEW OF SCIENTIFIC INSTRUMENTS,Vol.76,Num.2(2001) 1406-1410
39.贾晓鹏.高温高压下用溶剂法合成金刚石单晶及杂质分析[D].日本筑波:筑波大学工学研究科,1996.
40.P.W.May,"Diamond thin films:a 21st-century material",Phil.Trans.R.Soc.Lond.A,358(2000) 473-495
41.C.H.Desch,"The problem of artificial production of diamond",Nature,121(1928) 799
42.Lord Reyleigh,"J.B.Hanay and the artificial production of diamond",Nature,152(1943) 597
43.F.D.Rossini and R.S.Jessup,"Heat and free energy of formation of CO_2 and the transition between graphite and diamond",J.Res.Nat.Bur.Stand.Sect.C,21(1938) 491
44.P.W.Bridgman,"An experimental contribution to the problem of diamond synthesis",J.Chem.Phys,15(1947) 92
45.C.Guy Suits,"Man-Made Diamonds—a Progress Report",Proc.Am.Philos.Soc.,108(1964) 443
46.S.Ferro,"Synthesis of diamond",J.Mater.Chem.,12(2002) 2843-2855
47.H.M.Strong,"Early diamond making at General Electric",Am.J.Phys., 57(1989) 794
48. H.T. Hall, "The synthesis of diamond", Journal of Chemical Education. Vol. 38 (1961)484-491
49. F. P. Bundy, H. T. Hall, H. M. Strong and R.H. Wentorf, Jr., "Man-made diamonds", Nature, 176 (1955) 51
50. H.P. Bovenkerk, F.P. Bundy, H.T. Hall, H.M. Strong, and R.H. Wentorf, Jr., "Preparation of diamond", Nature, 184 (1959) 1094
51. H.M. Strong, "Diamond synthesis with Ferrous metal alloys", U.S. Patent, 2,947,609(1960)
52. H.T. Hall, H.M. Strong, and R.H. Wentorf, Jr., "Method of making diamonds", (single metals from ferrous, platinum or chromium groups), U.S. Patent, 2,947,610(1960)
53. H.M. Strong, "Catalytic effects in the transformation graphite to diamond", J. Phys. Chem., 39(1963) 2057
54. H.T. Hall, "Diamond synthesis", U.S. Patent, 2,947,608 (1960)
55. H.M. Strong and R.H. Wentorf, Jr., "The growth of large diamond crystals", Naturwissenschaften, 59 (1972) 1-7
56. R.H. Wentorf, Jr., "Some studies of diamond growth rates", J. Phys. Chem., 75 (1971) 1833
57. H.M. Strong and R.M. Chrenko, "Further studies on diamond growth rates and physical properties of laboratory-made diamond", J. Phys. Chem., 75 (1971) 1838
58. H.M. Strong, "Manufacture of diamond products", U.S. Patent , 4,082,185 (1978)
59. H.M. Strong, "Method and high pressure reaction vessel for quality control of diamond growth on diamond seed", U.S. Patent, 4,034,066 (1977)
60. A. Hara, Seimitsukikai, 51 (1985) 1497 ( in Japanese )
61.J.E. Shigley, E. Fritsch, C.M. Stockton, J.I. Koivula, C.W. Fryer and R.E. Kane, Gems & Gemmol, 22-4(1986)192
62. S. Satoh and H. Sumiya, The Review of High Pressure Science and Technology, 2 (1993) 315 (in Japanese)
63.R.C. Burns, S. Kessler, M. Sibanda, C.M. Welbourn, D.L. Welch, "Large synthetic diamonds", Proc. 3rd NIRIM Int. Symp. Advanced Materials, 1996, p.105-111
64. H. Kanda, "Large diamonds grown at high pressure conditions ", Brazilian Journal of Physics, Vol.30, No. 3 (2000) 482-489
65. J.E. Shigley, R. Abbaschian, C. Clarke, "Gemesis laboratory- created diamonds", Gems & Gemology, Vol.38, No.2 (2002) 301-309
66. J.E. Shigley, S.F. McClure, C.M. Breeding, A.H. Shen, S.M. Muhlmeister, Gems & Gemology, Vol.40, No.2 (2004) 128-145
67. J.E. Shigley, E. Fritsch, J.I. Koivula, N.V. Sobolev, I.Y. Malinovsky, Y. Palyanov, "The gemological properties of Russian gem-quality synthetic diamonds", Gems & Gemology, Vol.29, No.4 (1993) 228-248
68. T.R. Anthony, W.F. Banholzer, J.F. Fleischer, L.Wei, P.K. Kuo, R.L. Thomas and R.W. Pryor, Phys. Rev. B, 42 (1990) 1104
69. H. Sumiya, S. Satoh, "High-pressure synthesis of high-purity diamond crystal", Diamond Rel. Mater. 5 (1996) 1359
70. H. Sumiya, N. Toda, Y. Nishibayashi, S. Satoh, "Crystalline perfection of high purity synthetic diamond crystal", J. Crystal Growth, 178 (1997) 485
71. H. Sumiya, N. Toda, S. Satoh, "Growth rate of high-quality large diamond crystals", Journal of Crystal Growth, 237-239 (2002) 1281
72. R.C. De Vries, "Synthesis of diamond under metastable condition", Ann. Rev. Mater. Sci., 17 (1987) 161
73. Amanda Yarnell, "The many facets of man-made diamonds", Cenear, Vol.82, Num. 05 (2004)26-31
74. C.S. Yan. Y.C Chen, S.S. Ho, H.K. Mao and R.J. Hemley, "Large single crystal CVD diamonds at rapid growth rates", The 10th International Conference on New Diamond Science and Technology (AIST, Tsukuba, Japan,May 11-14,2005)
75.C.S.Yan,Y.C.Chen,S.S.Ho,H.K.Mao and R.J.Hemley,"Large single crystal CVD diamonds at rapid growth rates",8th Applied Diamond Conference,NanoCarbon 2005(Argonne National Laboratory,Argonne,Illinois,May 15-19,2005)
76.C.S.Yan,Y.C.Chen,S.S.Ho,H.K.Mao and R.J.Hemley,"Characterization of single-crystal diamonds grown by high growth rate chemical vapor deposition",8th Applied Diamond Conference,NanoCarbon 2005(Argonne National Laboratory,Argonne,Illinois,May 15-19,2005)
77.Y.C.Chen,C.S.Yan,H.K.Mao and R.J.Hemley,"Characte-rization of gem-quality diamond single crystals using chemical vapor deposition at very high growth rate",First Annual SSAAP Symposium(Albuquerque,NM,March 29-31,2004)
78.C.S.Yan,H.K.Mao,W.Li,J.Qian,Y.Zhao,and R.J.Hemley,"Ultrahard diamond single crystals from chemical vapor deposition",Physica Status Solidi A,201(2004) R24-R27
79.郝兆印,邹广田等,《人工合成金刚石》,吉林大学出版社,长春,1996
80.望贤成.优质Ⅱa型宝石级金刚石单晶的合成[D].长春:吉林大学超硬材料国家重点实验室,2005.
81.萄清泉,吉林大学学报,2(1974)62
82.萄清泉,《人造金刚石合成机理研究》,成都科技大学出版社,1986年
83.贾晓鹏,金刚石合成的溶剂理论及当今行业热点问题的探讨,中国超硬材料,特刊3(2001)1(全国超硬材料及制品研讨会特邀报告)
84.F.P.Bundy,"Pressure-temperature phase diagram of elemental carbon",Physica A,156(1989) 169-178
85.H.M.Strong and R.E.Hanneman,"Crystallization of diamond and graphite",J.Chem.Phys.,46(1967) 3668
86. F.P. Bundy, H.P. Bovenkerk, H.M. Strong, and R.H. Wentorf, Jr., "Diamond-graphite equilibrium line from growth and graphitization of diamond", J. Chem. Phys., 35 (1961) 383-391
87. M. Wakatsuki and K. Takano, " Suppression of spontaneous nucleation and seeded growth of diamond", High-Pressure Research in Mineral Physics, edited by M.H. Manghnani and Y. Syono, 1987, pp. 203-207
88. M. Wakatsuki and K. Ichinose, "A wedge-type cubic anvil high-pressure apparatus and its application to material synthesis research", in: High-Pressure Research in Geophysics, edited by S. Akimoto and M.H. Manghnani, 1982, pp. 13-26
89. H. T. Hall, "Guided high pressure presses", U.S. Patent, 5,744,170 (1998)
90. H.T. Hall, "Ultra-high-pressure, high temperature apparatus: The 'belt' ", Rev. Sci. Instrum., 31 (1960) 125-131
91. F.P. Bundy, "Direct conversion of graphite to diamond in static pressure apparatus", J. Chem. Phys., 38 (1963) 631
92. S. Naka, K. Horii, Y. Takeda, T. Hanawa, "Direct conversion of graphite to diamond under static pressure", Nature, 259 (1976) 38
93. R. C. Burns, J. O. Hansen, R. A. Spits, M. Sibanda, C.M. Welbourn, D.L. Welch, "Growth of high purity large synthetic diamond crystals", Diamond Relat. Mater., 8 (1999) 1433-1437
94. H. Sumiya, N. Toda, S. Satoh, "Development of high-purity large-size synthetic diamond crystals", Sumitomo Electric Technical Review, number 60, June (2005) 10
95. F.P. Bundy, H.M. Strong, R.H. Wentorf, Jr., "Methods and mechanisms of synthetic diamond growth", Phys. Chem. Carbon, 10 ( 1973) 213-263
96. H.Sumiya. Synthetic of high-purity and high-quality diamond crystal and its characterization [D]. Japan: Toky university, 1986/1993.
97. R.C. Burns, G.J. Davies, "Growth of synthetic diamond", in: Properties of Natural and Synthetic Diamond, Ed. J.E. Field, Academic Press, London,1992,p.395
98.H.Kanda,"Temperature effect on impurities in high pressure synthetic diamonds",Proc.3rd NIRIM International Symposium on Advanced Materials,Japan,1996,p.113
99.Xiaopeng Jia and M.Wakatsuki,"Growth of diamond single crystal at stabilized condition for the growth",Proc.3rd NIRIM International Symposium on Advanced Materials,Japan,1996,p.267
100.R.C.Burns,V.Cvetkovic and C.N.Dodge,"Growth-sector dependence of optical features in large synthetic dimaonds" J.Crystal Growth,104(1990) 257-279
101.X.Jia,S.Hayakawa,K.Ugajin,et al.,"Iron and Chromium as Impurities in Artificial Diamonds",Review of High Pressure Science and Technology,Vol.7(1998) 998
102.X.Jia,S.Hayakawa,W.Li,Y.Gohshi and M.Wakatsuki:"Cobalt impurities in synthetic diamond",Diamond and Related Materials,8(1999) 1895
103.陈立学.高温高压合成条件稳定性的研究以及宝石级金刚石单晶的合成[D].长春:吉林大学超硬材料国家重点实验室,2003.
104.周东晨,赵国权.《金刚石合成工艺》,机械工业出版社,1998
105.付星球.纯Fe触媒合成Ⅱa型宝石级金刚石[M].长春:吉林大学超硬材料国家重点实验室,2004.
106.李尚升.用NiMnCo触媒合成优质Ⅱa型宝石级金刚石[M].焦作:河南理工大学材料工程与科学学院,2006.
107.任国仲.热电材料 PbTe 电学性质的高温高压在位测量及性质研究[D].长春:吉林大学超硬材料国家重点实验室,2004.
108.臧传义.优质Ⅰb型宝石级金刚石单晶的合成及机理研究[D].长春:吉林大学超硬材料国家重点实验室,2006.
109.方啸虎.中国超硬材料新技术与进展.合肥:中国科学技术大学出版社,2003.12-18
110.V.D.Blank,M.S.Kuznetsov,S.A.Nosukhin.S.A.Terentiev,V.N. Denisov.The influence of crystallization temperature and boron concentration in growth environment on its distribution in growth sectors of type lib diamond[J].Diamond & Related Materials 16(2007)800.
111.V.D.Blank,M.S.Kuznetsov,S.A.Nosukhin,S.A.Terentiev,V.N.Denisov,The influence of crystallization temperature and boron concentration in growth environment on its distribution in growth sectors of type Ⅱb diamond[J].Diamond & Related Materials 16(2007)800
112.V.D.Blank,S.G.Buga,V.S.Bormashov etc,Pulse thermometers based on synthetic single crystal boron-doped diamonds[J].Diamond &Related Materials 16(2007)970
113.B.N.Mavrin,V.N.Denisov,D.M.Popova etc,Boron distribution in the subsurface region of heavily doped Ⅱb type diamond[J].Physics Letters A 372(2008) 3914-3918
114.Run Long,Ying Dai,Meng Guo etc.Effect of B-complexes on lattice structure and electronic properties[J].Diamond & Related Materials 17(2008) 234
115.李和胜,刘宪刚,李木森,周贵德 含硼金刚石单晶制备的研究进展[J],材料科学与工程 2006,24(60)944
116.臧建兵,李爱武,王艳辉,黄浩,.含硼金刚石的合成与性能[J].金刚石与磨料磨具工程,2003,(6):19
117.张健琼,马红安,臧传义,姜一平,贾晓鹏,.添加剂硼对纯铁粉末触媒合成金刚石的影响[J].金刚石与磨料磨具工程,2005,(5):5
118.A.C齐克利斯.高压和超高压物理-化学研究技术.北京:科学出版社,1983.208-210
119.顾学民,龚毅生等.无机化学丛书第二卷 铍 碱土元素 硼铝镓 分族.北京:科学出版社,1996.420-425
120.Yafei Zhang,Chuanyi Zang,Hongan Ma,Zhongzhu Liang,Lin Zhou,Shangsheng Li,Xiaopeng Jia HPHT synthesis of large single crystal diamond doped with high nitrogen concentration[J]. Diamond & Related Materials 17 (2008) 209
121.I. Kiflawi, A.E. Mayer, P.M. Spear, J.A. van Wyk and G.S. Woods, "Infrared absorption by the single nitrogen and A defect centers in diamond", Phil. Mag. B, 69 (1994) 1141-1147
122. S.R. Boyd, I. Kiflawi and G.S. Woods, "The relationship between absorption and the A defect concentration in daimond", Phil. Mag. B, 69 (1994)1149-1153
123. S.R. Boyd, I. Kiflawi and G.S. Woods, "Infrared absorption by the B aggregate in diamond'1, Phil. Mag. B, 72 (1995) 351-361
124. W.S. Woods, J.A. Van Wyk, A.T. Collins, "The nitrogen content of type Ib synthetic diamond", Phil. Mag. B, 62 (1990) 589-595
125. R.G. Blossey, R.D. Pehlke, Trans., Metallurgical Soc. AIME 236(1966)28,66
126. X.L. Li, H.A. Ma, G.H. Zuo, W.Q. Liu, Y.J. Zheng, J.G. Li , S.S. Li, X. Jia, Low-temperature sintering of high-density aluminium nitride ceramics without additives at high pressure. Scripta Materialia, 2007, 56: 1015-1018.
127. Xiao hong-Yu, JIA Xiao-Peng, ZANG Chuan-Yi, LI Shang-Sheng. TIAN Yu, ZHANG Ya-Fei, Huang Guo-Feng, MA Li-Qiu, MA Hong-An, Dependence of Crystal Quality and β Value on Synthesis [J]. Chinese Physics Letters, Vol.25, No.4 (2008) 1469-1471
128. WANG Xiang-Cheng, MA Hong-an, ZANG Chuan-Yi, TIAN Yu, LI Shang-sheng,, JIA Xiao-Peng , Growth of Large High-Quality Type-II a diamond crystals [J]. Chinese Physics Letters, Vol.22, No.7 (2005)1800-1802
129. ZANG Chuan-Yi, JIA Xiao-Peng, MA Hong-An, TIAN Yu, XIAO Hong-Yu Effect of Regrown Graphite on the Growth of Large Gem Diamonds by Temperature Gradient Method [J] Chinese Physics Letters, Vol.22, No.9(2005) 2415
130.臧传义,马红安,黄国锋,贾晓鹏.再结晶石墨的形成机制[J].吉林大学学报(工学版).Vol.37 No.5 1097-1100
131.黄国锋,臧传义,马红安,李尚升,田宇,肖宏宇,张亚飞,马利秋,李勇,陈孝洲,贾晓鹏,大尺寸Ⅰb型宝石级金刚石的合成[C].第五届郑州国际超硬材料及制品研讨会论文集.主编:李志宏,2008.
2. S. Koizumi, K. Watanabe, M. Hasegawa, H. Kanda, "Ultraviolet Emission from a Diamond pn Junction", SCIENCE, Vol. 292, 8 JUNE (2001)1899-1901
3. Eric J. Lerner, "Industrial diamonds gather strength", The Industrial Physicist, August/September (2002) 8-11
4. H. Kanda and T. Ohsawa, "Effect of solvent metals upon the morphology of synthetic diamonds", Journal of Crystal Growth, 94 (1989) 115-124
5. I. Sunagawa, "Growth and morphology of diamond crystals under stable and metastable conditions", Journal of Crystal Growth, 99 (1990) 1156-1161
6. L.J. Giling and W.J.P. Van Enckevort, "On the influence of surface reconstruction on crystal growth processes", Surface Science, 161(1985) 567-583
7. H. Kanda, T. Ohsawa, O. Fukunaga and I. Sunagawa, in: Morphology and Growth unit of Crystals, Ed. I. Sunagawa , Terra, Tokyo, 1984
8. M. Moore and A.R. Lang, "On the origin of the rounded dodecahedral habit of natural diamond", J. Crystal Growth, 26(1974) 133-139
9. A.R. Lang, "Glimpses into the growth history of natural diamonds", J. Crystal Growth, 24/25 (1974) 108-115
10. S.Yamaoka, H. Komatsu, H. Kanda and N. Setaka, "Growth of diamond with rhombic dodecahedral faces", J. Crystal Growth, 37(1977) 349-352
11. A.T. Collins, "The color of diamond and how it may be changed", Journal of Gemmology, Vol.27, No.6 (2001) 341-359
12. A.T. Collins, "Colour cetres in diamond", Journal of Gemmolo- gy, Vol.18, No.1 (1982) 37-75
13. R.C. DeVries, "A comparison of diamonds and diamond-making by nature and man", GE Res. Rep., 85CRD177, 1985
14. Appendix B, in: Properties of Natural and Synthetic Diamond, Ed. J.E. Field, Academic Press, London, 1992, p.669
15. S. Vagarali, M. Lee and R.C. Devries, "Progress of large diamond growth technology and future prospects", The Fourth International Conference on the Science of Hard Materials, Madeira, Portugal, 10-15 November 1991, p. 233-245
16. G. Davies, "The optical properties of diamond", Phys. Chem. Carbon, 13 (1977) 1
17. W. Kaiser and W.L. Bond, "Nitrogen, a Major Impurity in common type I diamond", Phys. Rev., 115 (1959) 857
18. H. Sumiya, N. Toda, S. Satoh, "High-quality large diamond crystals", New Diamond and Frontier Carbon Technology, 10 (2000) 233-251
19. H. Sumiya, S. Satoh, Y. Nishibayashi, Y. Goda, "Development of high-purity synthetic diamonds", Sumitomo Electric Technical Review, number 39, January (1995) 69
20. S. Satoh, H. Sumiya, K. Tsuji, Y. Gouda, "Process for the synth- esis of diamond", U.S. Patent, No.6,129,900, Oct.10, 2000
21. H.M. Strong, R.M. Chrenko, R.E. Tuft, "Annealing type Ib or mixed type Ib-Ia Natural diamond crystal", U.S. Patent, No. 4,124,690, Nov.7, 1978
22. R.M. Chrenko, R.E. Tuft, H.M. Strong, "Transformation of the state of nitrogen in diamond", Nature, 270 (1977) 141-144
23. A.A. Chepurov, J.M. Dereppe, I.I. Fedorov, A.I. Chepurov, "The change of Fe-Ni alloy inclusions in synthetic diamond crystals due to annealing", Diamond and Related Materials, 9 (2000) 1374-1379
24. H. Kanda, X. Jia, "Change of luminescence character of Ib diamonds with HPHT treatment",Diamond and Related Mater-ials,10(2001)1665-1669
25.I.Kiflawi,H.Kanda,D.Fisher,S.C.Lawson,"The aggregation of nitrogen and the formation of A centers in diamonds",Diamond and Related Materials,6(1997) 1643-1649
26.I.Kiflawi,J.Bruley,"The nitrogen aggregation sequence and the formation of voidites in diamond",Diamond and Related Materials,9(2000) 87-93
27.T.Evans,"Aggregation of Nitrogen in Diamond",in:Properties of Natural and Synthetic Diamond,Ed.J.E.Field,Academic Press,London,1992,p.259
28.H.Kanda,T.Ohsawa and S.Yamaoka,Proceedings of the First International Conference on New Diamond Science and Technology(S.Saito,O.Fukunaga and M.Yoshikawa,eds),Tokyo,Japan,1990,p.339-344
29.C.D.Clark,A.T.Collins,G.S.Woods,"Absorption and lumines-cence spectroscopy",in:Properties of Natural and Synthetic Diamond,Ed.J.E.Field,Academic Press,London,1992,p.259
30.M.N.Yoder,in Diamond and Diamond-Like Films and Coatings,Edited by R.E.Clausing,L.L.Horton,J.C.Angus,and P.Koidl,Plenum Press,New York,1991,Page 1-16
31.Chris Owers and Philip Bex,“工业金刚石的应用、效益与展望”,超硬材料与工程.1(2000)2
32.W.Tillmann,"Trends and market perspectives for diamond tools in the construction industry",International Journal of Refractory Metals&Hard Materials,8(2000) 301-306
33.C.M.Sung,"Brazed diamond grid:a revolutionary design for diamond saws",Diamond and Related Materials,8(1999) 1540-1543
34.贾晓鹏,“宝石级金刚石的合成”,香山会议,2000年北京
35.A.K.Freund,J.Hoszowska,J.P.F.Sellschop,R.C.Burns,M.Rebak. "Recent developments of high-quality synthetic diamond single crystals for synchrotron X-ray monochromators",Nuclear Instruments and Methods in Physics Research A,467-468(2001) 384-387
36.R.J.Tapper,"Diamond detectors in particle physics",Rep.Prog.Phys..63(2000) 1273
37.H.Sumiya,"Super-hard diamond indenter prepared from high-purity synthetic diamond crystal",REVIEW OF SCIENTIFIC INSTRUMENTS,76,026112(2005) 1-3
38.T.Tanaka,J.Kaneko,D.Takeuchi,H.Sumiya et al,"Diamond radiation detector made of an ultrahigh-purity type Ⅱa diamond crystal grown by high-pressure and high-temperature synthesis",REVIEW OF SCIENTIFIC INSTRUMENTS,Vol.76,Num.2(2001) 1406-1410
39.贾晓鹏.高温高压下用溶剂法合成金刚石单晶及杂质分析[D].日本筑波:筑波大学工学研究科,1996.
40.P.W.May,"Diamond thin films:a 21st-century material",Phil.Trans.R.Soc.Lond.A,358(2000) 473-495
41.C.H.Desch,"The problem of artificial production of diamond",Nature,121(1928) 799
42.Lord Reyleigh,"J.B.Hanay and the artificial production of diamond",Nature,152(1943) 597
43.F.D.Rossini and R.S.Jessup,"Heat and free energy of formation of CO_2 and the transition between graphite and diamond",J.Res.Nat.Bur.Stand.Sect.C,21(1938) 491
44.P.W.Bridgman,"An experimental contribution to the problem of diamond synthesis",J.Chem.Phys,15(1947) 92
45.C.Guy Suits,"Man-Made Diamonds—a Progress Report",Proc.Am.Philos.Soc.,108(1964) 443
46.S.Ferro,"Synthesis of diamond",J.Mater.Chem.,12(2002) 2843-2855
47.H.M.Strong,"Early diamond making at General Electric",Am.J.Phys., 57(1989) 794
48. H.T. Hall, "The synthesis of diamond", Journal of Chemical Education. Vol. 38 (1961)484-491
49. F. P. Bundy, H. T. Hall, H. M. Strong and R.H. Wentorf, Jr., "Man-made diamonds", Nature, 176 (1955) 51
50. H.P. Bovenkerk, F.P. Bundy, H.T. Hall, H.M. Strong, and R.H. Wentorf, Jr., "Preparation of diamond", Nature, 184 (1959) 1094
51. H.M. Strong, "Diamond synthesis with Ferrous metal alloys", U.S. Patent, 2,947,609(1960)
52. H.T. Hall, H.M. Strong, and R.H. Wentorf, Jr., "Method of making diamonds", (single metals from ferrous, platinum or chromium groups), U.S. Patent, 2,947,610(1960)
53. H.M. Strong, "Catalytic effects in the transformation graphite to diamond", J. Phys. Chem., 39(1963) 2057
54. H.T. Hall, "Diamond synthesis", U.S. Patent, 2,947,608 (1960)
55. H.M. Strong and R.H. Wentorf, Jr., "The growth of large diamond crystals", Naturwissenschaften, 59 (1972) 1-7
56. R.H. Wentorf, Jr., "Some studies of diamond growth rates", J. Phys. Chem., 75 (1971) 1833
57. H.M. Strong and R.M. Chrenko, "Further studies on diamond growth rates and physical properties of laboratory-made diamond", J. Phys. Chem., 75 (1971) 1838
58. H.M. Strong, "Manufacture of diamond products", U.S. Patent , 4,082,185 (1978)
59. H.M. Strong, "Method and high pressure reaction vessel for quality control of diamond growth on diamond seed", U.S. Patent, 4,034,066 (1977)
60. A. Hara, Seimitsukikai, 51 (1985) 1497 ( in Japanese )
61.J.E. Shigley, E. Fritsch, C.M. Stockton, J.I. Koivula, C.W. Fryer and R.E. Kane, Gems & Gemmol, 22-4(1986)192
62. S. Satoh and H. Sumiya, The Review of High Pressure Science and Technology, 2 (1993) 315 (in Japanese)
63.R.C. Burns, S. Kessler, M. Sibanda, C.M. Welbourn, D.L. Welch, "Large synthetic diamonds", Proc. 3rd NIRIM Int. Symp. Advanced Materials, 1996, p.105-111
64. H. Kanda, "Large diamonds grown at high pressure conditions ", Brazilian Journal of Physics, Vol.30, No. 3 (2000) 482-489
65. J.E. Shigley, R. Abbaschian, C. Clarke, "Gemesis laboratory- created diamonds", Gems & Gemology, Vol.38, No.2 (2002) 301-309
66. J.E. Shigley, S.F. McClure, C.M. Breeding, A.H. Shen, S.M. Muhlmeister, Gems & Gemology, Vol.40, No.2 (2004) 128-145
67. J.E. Shigley, E. Fritsch, J.I. Koivula, N.V. Sobolev, I.Y. Malinovsky, Y. Palyanov, "The gemological properties of Russian gem-quality synthetic diamonds", Gems & Gemology, Vol.29, No.4 (1993) 228-248
68. T.R. Anthony, W.F. Banholzer, J.F. Fleischer, L.Wei, P.K. Kuo, R.L. Thomas and R.W. Pryor, Phys. Rev. B, 42 (1990) 1104
69. H. Sumiya, S. Satoh, "High-pressure synthesis of high-purity diamond crystal", Diamond Rel. Mater. 5 (1996) 1359
70. H. Sumiya, N. Toda, Y. Nishibayashi, S. Satoh, "Crystalline perfection of high purity synthetic diamond crystal", J. Crystal Growth, 178 (1997) 485
71. H. Sumiya, N. Toda, S. Satoh, "Growth rate of high-quality large diamond crystals", Journal of Crystal Growth, 237-239 (2002) 1281
72. R.C. De Vries, "Synthesis of diamond under metastable condition", Ann. Rev. Mater. Sci., 17 (1987) 161
73. Amanda Yarnell, "The many facets of man-made diamonds", Cenear, Vol.82, Num. 05 (2004)26-31
74. C.S. Yan. Y.C Chen, S.S. Ho, H.K. Mao and R.J. Hemley, "Large single crystal CVD diamonds at rapid growth rates", The 10th International Conference on New Diamond Science and Technology (AIST, Tsukuba, Japan,May 11-14,2005)
75.C.S.Yan,Y.C.Chen,S.S.Ho,H.K.Mao and R.J.Hemley,"Large single crystal CVD diamonds at rapid growth rates",8th Applied Diamond Conference,NanoCarbon 2005(Argonne National Laboratory,Argonne,Illinois,May 15-19,2005)
76.C.S.Yan,Y.C.Chen,S.S.Ho,H.K.Mao and R.J.Hemley,"Characterization of single-crystal diamonds grown by high growth rate chemical vapor deposition",8th Applied Diamond Conference,NanoCarbon 2005(Argonne National Laboratory,Argonne,Illinois,May 15-19,2005)
77.Y.C.Chen,C.S.Yan,H.K.Mao and R.J.Hemley,"Characte-rization of gem-quality diamond single crystals using chemical vapor deposition at very high growth rate",First Annual SSAAP Symposium(Albuquerque,NM,March 29-31,2004)
78.C.S.Yan,H.K.Mao,W.Li,J.Qian,Y.Zhao,and R.J.Hemley,"Ultrahard diamond single crystals from chemical vapor deposition",Physica Status Solidi A,201(2004) R24-R27
79.郝兆印,邹广田等,《人工合成金刚石》,吉林大学出版社,长春,1996
80.望贤成.优质Ⅱa型宝石级金刚石单晶的合成[D].长春:吉林大学超硬材料国家重点实验室,2005.
81.萄清泉,吉林大学学报,2(1974)62
82.萄清泉,《人造金刚石合成机理研究》,成都科技大学出版社,1986年
83.贾晓鹏,金刚石合成的溶剂理论及当今行业热点问题的探讨,中国超硬材料,特刊3(2001)1(全国超硬材料及制品研讨会特邀报告)
84.F.P.Bundy,"Pressure-temperature phase diagram of elemental carbon",Physica A,156(1989) 169-178
85.H.M.Strong and R.E.Hanneman,"Crystallization of diamond and graphite",J.Chem.Phys.,46(1967) 3668
86. F.P. Bundy, H.P. Bovenkerk, H.M. Strong, and R.H. Wentorf, Jr., "Diamond-graphite equilibrium line from growth and graphitization of diamond", J. Chem. Phys., 35 (1961) 383-391
87. M. Wakatsuki and K. Takano, " Suppression of spontaneous nucleation and seeded growth of diamond", High-Pressure Research in Mineral Physics, edited by M.H. Manghnani and Y. Syono, 1987, pp. 203-207
88. M. Wakatsuki and K. Ichinose, "A wedge-type cubic anvil high-pressure apparatus and its application to material synthesis research", in: High-Pressure Research in Geophysics, edited by S. Akimoto and M.H. Manghnani, 1982, pp. 13-26
89. H. T. Hall, "Guided high pressure presses", U.S. Patent, 5,744,170 (1998)
90. H.T. Hall, "Ultra-high-pressure, high temperature apparatus: The 'belt' ", Rev. Sci. Instrum., 31 (1960) 125-131
91. F.P. Bundy, "Direct conversion of graphite to diamond in static pressure apparatus", J. Chem. Phys., 38 (1963) 631
92. S. Naka, K. Horii, Y. Takeda, T. Hanawa, "Direct conversion of graphite to diamond under static pressure", Nature, 259 (1976) 38
93. R. C. Burns, J. O. Hansen, R. A. Spits, M. Sibanda, C.M. Welbourn, D.L. Welch, "Growth of high purity large synthetic diamond crystals", Diamond Relat. Mater., 8 (1999) 1433-1437
94. H. Sumiya, N. Toda, S. Satoh, "Development of high-purity large-size synthetic diamond crystals", Sumitomo Electric Technical Review, number 60, June (2005) 10
95. F.P. Bundy, H.M. Strong, R.H. Wentorf, Jr., "Methods and mechanisms of synthetic diamond growth", Phys. Chem. Carbon, 10 ( 1973) 213-263
96. H.Sumiya. Synthetic of high-purity and high-quality diamond crystal and its characterization [D]. Japan: Toky university, 1986/1993.
97. R.C. Burns, G.J. Davies, "Growth of synthetic diamond", in: Properties of Natural and Synthetic Diamond, Ed. J.E. Field, Academic Press, London,1992,p.395
98.H.Kanda,"Temperature effect on impurities in high pressure synthetic diamonds",Proc.3rd NIRIM International Symposium on Advanced Materials,Japan,1996,p.113
99.Xiaopeng Jia and M.Wakatsuki,"Growth of diamond single crystal at stabilized condition for the growth",Proc.3rd NIRIM International Symposium on Advanced Materials,Japan,1996,p.267
100.R.C.Burns,V.Cvetkovic and C.N.Dodge,"Growth-sector dependence of optical features in large synthetic dimaonds" J.Crystal Growth,104(1990) 257-279
101.X.Jia,S.Hayakawa,K.Ugajin,et al.,"Iron and Chromium as Impurities in Artificial Diamonds",Review of High Pressure Science and Technology,Vol.7(1998) 998
102.X.Jia,S.Hayakawa,W.Li,Y.Gohshi and M.Wakatsuki:"Cobalt impurities in synthetic diamond",Diamond and Related Materials,8(1999) 1895
103.陈立学.高温高压合成条件稳定性的研究以及宝石级金刚石单晶的合成[D].长春:吉林大学超硬材料国家重点实验室,2003.
104.周东晨,赵国权.《金刚石合成工艺》,机械工业出版社,1998
105.付星球.纯Fe触媒合成Ⅱa型宝石级金刚石[M].长春:吉林大学超硬材料国家重点实验室,2004.
106.李尚升.用NiMnCo触媒合成优质Ⅱa型宝石级金刚石[M].焦作:河南理工大学材料工程与科学学院,2006.
107.任国仲.热电材料 PbTe 电学性质的高温高压在位测量及性质研究[D].长春:吉林大学超硬材料国家重点实验室,2004.
108.臧传义.优质Ⅰb型宝石级金刚石单晶的合成及机理研究[D].长春:吉林大学超硬材料国家重点实验室,2006.
109.方啸虎.中国超硬材料新技术与进展.合肥:中国科学技术大学出版社,2003.12-18
110.V.D.Blank,M.S.Kuznetsov,S.A.Nosukhin.S.A.Terentiev,V.N. Denisov.The influence of crystallization temperature and boron concentration in growth environment on its distribution in growth sectors of type lib diamond[J].Diamond & Related Materials 16(2007)800.
111.V.D.Blank,M.S.Kuznetsov,S.A.Nosukhin,S.A.Terentiev,V.N.Denisov,The influence of crystallization temperature and boron concentration in growth environment on its distribution in growth sectors of type Ⅱb diamond[J].Diamond & Related Materials 16(2007)800
112.V.D.Blank,S.G.Buga,V.S.Bormashov etc,Pulse thermometers based on synthetic single crystal boron-doped diamonds[J].Diamond &Related Materials 16(2007)970
113.B.N.Mavrin,V.N.Denisov,D.M.Popova etc,Boron distribution in the subsurface region of heavily doped Ⅱb type diamond[J].Physics Letters A 372(2008) 3914-3918
114.Run Long,Ying Dai,Meng Guo etc.Effect of B-complexes on lattice structure and electronic properties[J].Diamond & Related Materials 17(2008) 234
115.李和胜,刘宪刚,李木森,周贵德 含硼金刚石单晶制备的研究进展[J],材料科学与工程 2006,24(60)944
116.臧建兵,李爱武,王艳辉,黄浩,.含硼金刚石的合成与性能[J].金刚石与磨料磨具工程,2003,(6):19
117.张健琼,马红安,臧传义,姜一平,贾晓鹏,.添加剂硼对纯铁粉末触媒合成金刚石的影响[J].金刚石与磨料磨具工程,2005,(5):5
118.A.C齐克利斯.高压和超高压物理-化学研究技术.北京:科学出版社,1983.208-210
119.顾学民,龚毅生等.无机化学丛书第二卷 铍 碱土元素 硼铝镓 分族.北京:科学出版社,1996.420-425
120.Yafei Zhang,Chuanyi Zang,Hongan Ma,Zhongzhu Liang,Lin Zhou,Shangsheng Li,Xiaopeng Jia HPHT synthesis of large single crystal diamond doped with high nitrogen concentration[J]. Diamond & Related Materials 17 (2008) 209
121.I. Kiflawi, A.E. Mayer, P.M. Spear, J.A. van Wyk and G.S. Woods, "Infrared absorption by the single nitrogen and A defect centers in diamond", Phil. Mag. B, 69 (1994) 1141-1147
122. S.R. Boyd, I. Kiflawi and G.S. Woods, "The relationship between absorption and the A defect concentration in daimond", Phil. Mag. B, 69 (1994)1149-1153
123. S.R. Boyd, I. Kiflawi and G.S. Woods, "Infrared absorption by the B aggregate in diamond'1, Phil. Mag. B, 72 (1995) 351-361
124. W.S. Woods, J.A. Van Wyk, A.T. Collins, "The nitrogen content of type Ib synthetic diamond", Phil. Mag. B, 62 (1990) 589-595
125. R.G. Blossey, R.D. Pehlke, Trans., Metallurgical Soc. AIME 236(1966)28,66
126. X.L. Li, H.A. Ma, G.H. Zuo, W.Q. Liu, Y.J. Zheng, J.G. Li , S.S. Li, X. Jia, Low-temperature sintering of high-density aluminium nitride ceramics without additives at high pressure. Scripta Materialia, 2007, 56: 1015-1018.
127. Xiao hong-Yu, JIA Xiao-Peng, ZANG Chuan-Yi, LI Shang-Sheng. TIAN Yu, ZHANG Ya-Fei, Huang Guo-Feng, MA Li-Qiu, MA Hong-An, Dependence of Crystal Quality and β Value on Synthesis [J]. Chinese Physics Letters, Vol.25, No.4 (2008) 1469-1471
128. WANG Xiang-Cheng, MA Hong-an, ZANG Chuan-Yi, TIAN Yu, LI Shang-sheng,, JIA Xiao-Peng , Growth of Large High-Quality Type-II a diamond crystals [J]. Chinese Physics Letters, Vol.22, No.7 (2005)1800-1802
129. ZANG Chuan-Yi, JIA Xiao-Peng, MA Hong-An, TIAN Yu, XIAO Hong-Yu Effect of Regrown Graphite on the Growth of Large Gem Diamonds by Temperature Gradient Method [J] Chinese Physics Letters, Vol.22, No.9(2005) 2415
130.臧传义,马红安,黄国锋,贾晓鹏.再结晶石墨的形成机制[J].吉林大学学报(工学版).Vol.37 No.5 1097-1100
131.黄国锋,臧传义,马红安,李尚升,田宇,肖宏宇,张亚飞,马利秋,李勇,陈孝洲,贾晓鹏,大尺寸Ⅰb型宝石级金刚石的合成[C].第五届郑州国际超硬材料及制品研讨会论文集.主编:李志宏,2008.